CN1273222A - Filler for concretion of sandy soil and production and application method - Google Patents

Filler for concretion of sandy soil and production and application method Download PDF

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Publication number
CN1273222A
CN1273222A CN99106222A CN99106222A CN1273222A CN 1273222 A CN1273222 A CN 1273222A CN 99106222 A CN99106222 A CN 99106222A CN 99106222 A CN99106222 A CN 99106222A CN 1273222 A CN1273222 A CN 1273222A
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Prior art keywords
concretion
sandy soil
slag
filler
sand
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CN99106222A
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CN1128772C (en
Inventor
孙恒虎
刘文永
徐维瑞
盖光举
赵福收
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Beijing Qing River Environmental Protection Technology Co., Ltd.
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GAOSHUI MINE ENGINEERING AND MATERIALS INST BEIJING
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)

Abstract

A filler for the consolidation of sandy soil is prepared from water quenched slags of blast furnace and fluidizing furnace, gypsum, lime, lime stone, clay and additive through grinding. It is suitable for filling and propping of mining well and strengthening of road subgrade. It is applied through mixing it with sandy soil and water to form grout and pumping the grout to the plate where filling is needed.

Description

Filler for concretion of sandy soil, production and using method
The present invention relates to a kind of is filler for concretion of sandy soil and the production and the using method of main raw material with the industrial residue, this material batching back directly grinding becomes powder material, need not calcine, production technique is simple, production cost and energy consumption are low, material non-toxic, harmless.
This material product be applicable to mine filling, supporting, every wind locking leak, reinforcing road bed etc., be specially adapted to the filling and support in mine and reinforcing road bed filler for concretion of sandy soil, especially the high sand of argillaceous amount is had very strong fixed ability.
The mine is generally carried out filling with cement as consolidating material now, and time of coagulation is long, and strength of filling mass is low, the filling cost height.When making consolidating material with cement, generally will adopt classified tailings to do casting resin, particle diameter can not utilize less than the fine-grained tailing of 37 (um), be sent to the mine tailing storehouse, has increased difficulty for the heap dam, has also improved the construction cost in mine tailing storehouse.At the ore grade height, the mine that the tailings productive rate is low, the filling aggregate wretched insufficiency replenishes with frosted or outsourcing sand, and filling cost is further improved.
In order to address the above problem, it is a kind of that we have studied success, cheaply filler for concretion of sandy soil.The major ingredient of cement is cement clinker and a small amount of gypsum, mixes into active material again, and its volume generally is less than 30%.Used active material has water-granulated slag, pozzolana mixed material, reaches other industrial residue, and these active materials are the fillers in the cement, and it improves strength of cement does not have promoter action, just reduces cement mark, reduces cement cost.The filler for concretion of sandy soil of our invention is to be main raw material with the industrial residue, adds a small amount of additive and makes, and replaces cement as cemented filling material, can reduce filling cost.And use this filler for concretion of sandy soil to carry out filling, and used tailings is without classification, and it can be fixed together fine-graded tailings and thin mud, and filling cost is further reduced.
Filler for concretion of sandy soil is to select major ingredient such as blast furnace slag, slag, boiling furnace slag, gypsum, lime, Wingdale, clay for use, adds a small amount of exciting agent again, through technologies such as levigate, homogenizing, a kind of pulverulent material of making.
Outstanding advantage of the present invention is: with the industrial residue be main raw material without calcination, save energy, facility investment is few, production process is simple, material produce cost and energy consumption are low, economy, benefit obviously, also can fully utilize industrial slag, reduce environmental pollution, and the high sand of argillaceous amount is had very strong fixed ability etc.
Filler for concretion of sandy soil, production and using method is characterized in that:
One, filler for concretion of sandy soil is characterized in that:
Industrial slag 40~95%
Gypsum 2~40%
Lime 3~20%
Additive 0.01~3%
1, in the filler for concretion of sandy soil can there be used industrial slag: the miscellany a kind of or that certain is several in blast furnace slag, slag, boiling furnace slag, ferromanganese blast furnace slag, flyash, phosphorus ore slag, titanium slag, the slag isoreactivity industrial residue is formed.
2, used gypsum comprises that a kind of in the gypsum such as dihydrate gypsum, natural anhydrite, semi-hydrated gypsum and chemical gypsum or the miscellany that certain is several form in the filler for concretion of sandy soil.
3, used lime comprises one or more compositions in unslaked lime, slaked lime and the chemical industry lime in the filler for concretion of sandy soil.Lime in its component, its efficient oxidation calcium add effective content of magnesia and are not less than 65%.
4, add a spot of exciting agent in the filler for concretion of sandy soil, can make carbohydrate, sweet class, boric acid and borate, citric acid and Citrate trianion, tartrate and tartrate, vitriol, chlorate, carbonate, wooden horizontal hydrochlorate by the one or more combination in following.Account for 0.01~3% of filler for concretion of sandy soil weight proportion.
5, used industrial slag in the filler for concretion of sandy soil can also mix the nonactive mixing material of part such as Wingdale, clay etc. and replace the part industrial slag.
Two, the production of filler for concretion of sandy soil is characterized in that:
1. the used raw material stoving of filler for concretion of sandy soil, fragmentation, grinding are become powder.
2. the fineness of filler for concretion of sandy soil tails over less than 8% with the square hole sieve of 0.08mm.
Three, the using method of filler for concretion of sandy soil is characterized in that:
1, water or water and add reinforced material or be mixed and made into filling slurry with the fixed casting resin of full sand respectively with containing the slurries that add reinforced material.
2, the reinforced material that adds of filler for concretion of sandy soil slip is made up of in mountain sand, river sand, extra large sand, Gobi desert sand, frosted, rubble, piece stone, barren rock, spoil, clay, phosphogypsum, fluorgypsum, mine grading sand and the full tailings one or more.
3, the weight ratio of filler for concretion of sandy soil slip is according to the difference of used solid material, and concentration is 40%~87%, and best weight ratio concentration range is 60%~82%.
4, the filler for concretion of sandy soil slip will be delivered to the filling place to slurries by gravity flow or pumping.
5, the filler for concretion of sandy soil slip can be used for mineral building, the underground cavity of mine worked-out section, afterwards filling, cavity, trench, geosyncline and the highway subgrade of hand digging.
6, the filler for concretion of sandy soil slurries enter the filling point, just form solid and produce intensity, under the prerequisite that guarantees the filler for concretion of sandy soil using property data, effectively reduce filling cost and mining cost or construction costs.
Example 1.
Under the situation that silt content, test temperature equate in cement-sand ratio, concentration, sand, with the plum scenery with hills and waters quench filler for concretion of sandy soil that slag 80%, anhydrite 5%, lime 95%, Wingdale 5%, calcium chloride 0.5% be made into as agglutinate and with common 425# cement as the intensity contrast of agglutinate shown in following table 1 and table 2:
(1), in the sand of river, add intensity such as the following table 1 of common 425# cement as agglutinate:
Table 1
Numbering Contain native % in the sand Cement-sand ratio Add cement % Use cement KG/M for every cube 3 Concentration % Ultimate compression strength (Mpa)
3 days 7 days 28 days
???1 ????5 ????25.7 ????3 ????60.5 ???80 ???0.1 ????0.14 ????0.32
???2 ???10 ????25.7 ????3 ????60.5 ???80 ???0.16 ????0.28 ????0.48
???3 ???15 ????25.7 ????3 ????60.5 ???80 ???0.26 ????0.34 ????0.56
???4 ???20 ????25.7 ????3 ????60.5 ???80 ???0.34 ????0.44 ????0.66
???5 ???25 ????25.7 ????3 ????60.5 ???80 ???0.36 ????0.45 ????0.5
???6 ???30 ????25.7 ????3 ????60.5 ???80 ???0.32 ????0.40 ????0.48
???7 ???40 ????25.7 ????3 ????60.5 ???80 ???0.30 ????0.41 ????0.45
???8 ???50 ????25.7 ????3 ????60.5 ???80 ???0.28 ????0.38 ????0.46
2. in the sand of river, add intensity such as the following table 2 of filler for concretion of sandy soil as agglutinate:
Table 2
Numbering Contain native % in the sand Cement-sand ratio Solidifying agent % Every cube of materials KG/M 3 Concentration % Ultimate compression strength (Mpa)
3 days 7 days 28 days 60 days
???1 ???5 ??25.7 ????3 ????60.5 ??80 ????0.15 ????0.26 ????0.4 ????0.96
???2 ??10 ??25.7 ????3 ????60.5 ??80 ????0.22 ????0.35 ????0.96 ????1.44
???3 ??15 ??25.7 ????3 ????60.5 ??80 ????0.26 ????0.7 ????1.1 ????1.6
???4 ??20 ??25.7 ????3 ????60.5 ??80 ????0.3 ????0.8 ????1.22 ????1.65
???5 ??25 ??25.7 ????3 ????60.5 ??80 ????0.32 ????0.82 ????1.25 ????1.73
???6 ??30 ??25.7 ????3 ????60.5 ??80 ????0.32 ????0.83 ????1.31 ????1.87
???7 ??40 ??25.7 ????3 ????60.5 ??80 ????0.34 ????0.85 ????1.33 ????1.9
???8 ??50 ??25.7 ????3 ????60.5 ??80 ????0.37 ????0.88 ????1.36 ????1.9
Example 2
Intensity such as following table 3 that the filler for concretion of sandy soil that is made into meishan iron mine water-granulated slag 60%, slag 15%, anhydrite 8%, lime 10%, flyash 6.5%, sodium sulfate 0.5% comes fixed medium sand:
Table 3
Numbering Contain native % in the sand Cement-sand ratio Solidifying agent % Every cube of materials KG/M 3 Concentration % Ultimate compression strength (Mpa)
3 days 7 days 28 days 60 days
??1 ???5 ??25.7 ????3 ????60.5 ??80 ????0.17 ????0.33 ????0.47 ????0.88
??2 ??15 ??25.7 ????3 ????60.5 ??80 ????0.3 ????0.79 ????1.32 ????1.56
??3 ??30 ??25.7 ????3 ????60.5 ??80 ????0.41 ????0.98 ????1.48 ????1.92
??4 ??50 ??25.7 ????3 ????60.5 ??80 ????0.42 ????0.95 ????1.46 ????1.9
Example 3
The fixed filling material of full sand that is made into water-granulated slag 40%, slag 30%, flyash 10%, anhydrite 10%, lime 9.4%, calcium chloride 0.5%, molasses class 0.1% comes the intensity such as the table 4 of fixed sand.
Table 4
Numbering Contain native % in the sand Cement-sand ratio Solidifying agent % Every cube of materials KG/M 3 Concentration % Ultimate compression strength (Mpa)
3 days 7 days 28 days 60 days
???1 ???5 ??25.7 ????3 ????60.5 ??80 ????0.18 ????0.35 ????0.45 ????0.98
???2 ??15 ??25.7 ????3 ????60.5 ??80 ????0.28 ????0.77 ????1.2 ????1.66
???3 ??30 ??25.7 ????3 ????60.5 ??80 ????0.4 ????0.88 ????1.64 ????2
???4 ??50 ??25.7 ????3 ????60.5 ??80 ????0.38 ????0.85 ????1.56 ????1.95
Example 4
The filler for concretion of sandy soil that is made into water-granulated slag 50%, slag 20%, clay 10%, dihydrate gypsum 10, lime 9.4%, calcium chloride 0.5%, molasses class 0.1% comes the intensity such as the table 5 of fixed sand.
Table 5
Numbering Contain native % in the sand Cement-sand ratio Solidifying agent % Every cube of materials KG/M 3 Concentration % Ultimate compression strength (Mpa)
3 days 7 days 28 days 60 days
???1 ??5 ??25.7 ????3 ????60.5 ??80 ????0.15 ????0.27 ????0.42 ????0.93
???2 ??15 ??25.7 ????3 ????60.5 ??80 ????0.26 ????0.67 ????1.1 ????1.56
???3 ??30 ??25.7 ????3 ????60.5 ??80 ????0.34 ????0.78 ????1.34 ????1.89
???4 ??50 ??25.7 ????3 ????60.5 ??80 ????0.37 ????0.88 ????1.36 ????1.85
Example 5
The filler for concretion of sandy soil that is made into water-granulated slag 60%, slag 10%, Wingdale 10%, dihydrate gypsum 10%, lime 9.4%, vitriol 0.5%, borate 0.1% comes the intensity such as the table 6 of fixed Shandong Jiaojia Glod Mine tailings.
Table 6
Numbering Tailings % Cement-sand ratio Solidifying agent % Every cube of materials KG/M 3 Concentration % Ultimate compression strength (Mpa)
3 days 7 days 28 days 60 days
???1 ??65 ???13 ????5 ???89 ??70 ????0.26 ????0.35 ????0.6 ???0.86
???2 ??70 ???14 ????5 ???95 ??75 ????0.28 ????0.38 ????0.65 ???0.95
Example 6
Intensity such as following table 7 that the filler for concretion of sandy soil that is made into water-granulated slag 80%, natural anhydrite 10%, lime 9.3%, chlorate 0.5%, borate 0.2% comes fixed meishan iron mine tailings.
Table 7
Numbering Fixed material % Cement-sand ratio Concentration % Degree of mobilization centimetre Slump centimetre Ultimate compression strength (MPa)
3 days 7 days 14 days 28 days 60 days
????1 ????5 ?????12 ???60 ????0.2 ???0.32 ????0.6 ????0.9 ????1.5
????2 ????6 ?????10 ???60 ???0.24 ????0.4 ????0.7 ???1.10 ????1.7
????3 ????3 ??20.66 ???65 ????0.2 ???0.24 ???0.50 ???0.55 ???0.82
????4 ????4 ??15.25 ???65 ???0.22 ????0.3 ???0.48 ????0.6 ????1.1
????5 ????5 ?????12 ???65 ???0.38 ????0.7 ???0.98 ???1.18 ????1.8
????6 ????6 ????9.8 ???65 ???0.45 ???0.92 ???1.18 ???1.59 ????2.1
????7 ????7 ????7.6 ???60 ???0.52 ???1.18 ???1.52 ????1.8 ????2.5
????8 ????8 ????6.5 ???60 ???0.52 ???1.26 ???1.85 ????2.2 ????3.0
????9 ????9 ??5.667 ???60 ???0.76 ???1.38 ???2.26 ???2.72 ????3.8
???10 ???10 ???60 ???0.78 ???1.46 ????2.8 ????3.6 ????4.9
???11 ???12 ???60 ???1.04 ???2.32 ???3.96 ???4.56 ????5.8
Example 7
The filler for concretion of sandy soil that is made into water-granulated slag 40%, steel 40%, dihydrate gypsum 8%, lime 11.5%, calcium chloride 0.4%, sodium sulfate 0.1% comes the intensity such as the table 8 of fixed clay.
Table 8
Numbering Fixed material % Clay comprises % Sand accounts for % Water content % Ultimate compression strength (Mpa)
3 days 7 days 28 days
????1 ????8 ????77 ????0 ???15 ????2.5 ????3 ????8.5
????2 ????9 ????76 ????0 ???15 ????3.5 ????4.8 ????12
????3 ???10 ????70 ????0 ???20 ????2.7 ????4.7 ????10
????4 ???11 ????69 ????0 ???20 ????2.4 ????6.2 ????11
????5 ???12 ????68 ????0 ???20 ????3.6 ????6.4 ????11
????6 ???13 ????67 ????0 ???20 ????4.5 ????8.3 ????14.5
????7 ???14 ????66 ????0 ???20 ????3.8 ????6.6 ????14
????8 ????8 ????35 ???47 ???10 ????4 ????7.8 ????16
????9 ???10 ????48 ???30 ???12 ????5 ????10.8 ????22
???10 ???10 ????30 ???50 ???10 ????8.2 ????13.6 ????22.5
???11 ???10 ????35 ???45 ???10 ????8.5 ????13 ????22.5
???12 ???10 ????30 ???50 ???10 ????8.8 ????13.2 ????30
Find out that from above test filler for concretion of sandy soil is good filling and support material, be applicable to the filling and support and the subgrade strengthening material in mine, especially the high sand of argillaceous amount is had very strong fixed ability.

Claims (12)

1. filler for concretion of sandy soil is characterized in that its component and content (weight ratio) are respectively:
Industrial slag 40~95%
Gypsum 2~40%
Lime 3~20%
Additive 0.01~3%
2,, it is characterized in that a kind of in available slag, slag, boiling furnace slag, ferromanganese blast furnace slag, flyash, phosphorus ore slag, titanium slag, the slag isoreactivity industrial residue or the miscellany that certain is several according to the industrial slag in the described filler for concretion of sandy soil of claim 1.
3,, it is characterized in that a kind of in available dihydrate gypsum, dehydrated gyp-, semi-hydrated gypsum and the chemical gypsum or the combination that certain is several according to the gypsum in the described filler for concretion of sandy soil of claim 1.
4,, it is characterized in that and to replace the part industrial slag with nonactive mixing material Wingdale, clay etc. according to the industrial slag in claim 1 or the 2 described filler for concretion of sandy soil.
5,, it is characterized in that a kind of in available unslaked lime, slaked lime and the chemical industry lime or the miscellany that certain is several according to the lime in the described filler for concretion of sandy soil of claim 1.
6. according to the described filler for concretion of sandy soil of claim 1, it is characterized in that the optimum fiting ratio of each component is:
Slag 65~~75%
Slag 10~~15%
Gypsum 8~~12%
Lime 8~~15%
Add power agent 0.5~~1%
7. according to claim 1 or 6 described filler for concretion of sandy soil, it is characterized in that said additive, can make carbohydrate, sweet class, boric acid and borate, citric acid and Citrate trianion, tartrate and tartrate, vitriol, chlorate, carbonate, wooden horizontal hydrochlorate by the one or more combination in following.
8. the production of filler for concretion of sandy soil, its special sex character is that raw material crushing, grinding are become powder, fineness tails over less than 8% for the 0.08mm square hole sieve.
9, the pulping process of filler for concretion of sandy soil is characterized in that water or water and adds reinforced material or be mixed and made into filling slurry with the fixed casting resin of full sand respectively with containing the slurries that add reinforced material.
10, according to the described filler for concretion of sandy soil of claim 9, the reinforced material that adds that it is characterized in that filling slurry is formed mountain sand, river sand, extra large sand, Gobi desert sand, frosted, rubble, piece stone, barren rock, spoil, clay, phosphogypsum, fluorgypsum, mine grading sand and full tailings by in following one or more.
11, according to the described filler for concretion of sandy soil of claim 9, the weight ratio concentration that it is characterized in that filling slurry is 40%~87%, and best weight ratio concentration range is 60%~82%.
12, according to the described filler for concretion of sandy soil of claim 9, it is characterized in that these filling slurries will by the gravity flow or pumping deliver to the filling place to slurries.
CN99106222A 1999-05-06 1999-05-06 Filler for concretion of sandy soil and production and application method Expired - Fee Related CN1128772C (en)

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Application Number Priority Date Filing Date Title
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CN1128772C CN1128772C (en) 2003-11-26

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Cited By (21)

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CN102190469A (en) * 2010-03-08 2011-09-21 淄博乾耀固结材料有限公司 Novel tailing consolidator and preparation method thereof
CN102241493A (en) * 2011-04-19 2011-11-16 广东红墙新材料股份有限公司 Pit backfill material, preparation method thereof and application method thereof
CN102434163A (en) * 2011-12-01 2012-05-02 山西阳泉盂县东坪煤业有限公司 Method for mining coal through comprehensive mechanized solid filling
CN102786241A (en) * 2012-04-24 2012-11-21 河北钢铁集团矿业有限公司 Gel material used for unclassified tailing cement
CN102924005A (en) * 2012-11-19 2013-02-13 北京科技大学 Cementing materials with micro-expansion effect for mine filling
CN102936102A (en) * 2012-09-20 2013-02-20 亓俊华 Cementation curing material and production method thereof, and filling material containing cementation curing material
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CN109956730A (en) * 2019-04-24 2019-07-02 山东佳运环保科技有限公司 Modified gypsum is native and its as the application and construction method in basic engineered packings
CN110451903A (en) * 2019-08-29 2019-11-15 深圳市中金岭南有色金属股份有限公司 A kind of composite cementitious materials and the cementing method of the ultra-fine tailings of lead-zinc ore of high-sulfur
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CN102190469A (en) * 2010-03-08 2011-09-21 淄博乾耀固结材料有限公司 Novel tailing consolidator and preparation method thereof
CN102241493A (en) * 2011-04-19 2011-11-16 广东红墙新材料股份有限公司 Pit backfill material, preparation method thereof and application method thereof
CN102241493B (en) * 2011-04-19 2012-11-14 广东红墙新材料股份有限公司 Pit backfill material, preparation method thereof and application method thereof
CN102434163A (en) * 2011-12-01 2012-05-02 山西阳泉盂县东坪煤业有限公司 Method for mining coal through comprehensive mechanized solid filling
CN102786241A (en) * 2012-04-24 2012-11-21 河北钢铁集团矿业有限公司 Gel material used for unclassified tailing cement
CN102936102A (en) * 2012-09-20 2013-02-20 亓俊华 Cementation curing material and production method thereof, and filling material containing cementation curing material
CN102924005A (en) * 2012-11-19 2013-02-13 北京科技大学 Cementing materials with micro-expansion effect for mine filling
CN103043965A (en) * 2012-12-18 2013-04-17 山西四建集团有限公司 Slag material for comprehensive soft foundation treatment
CN103485328B (en) * 2013-09-23 2015-04-08 河海大学 Method for performing ecological reinforcement on soil slope surface by utilizing composite curing agent
CN103485328A (en) * 2013-09-23 2014-01-01 河海大学 Method for performing ecological reinforcement on soil slope surface by utilizing composite curing agent
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CN106939796A (en) * 2017-05-03 2017-07-11 长沙矿山研究院有限责任公司 The method and system that filling slurry fills underground goaf are prepared using efflorescent sand
CN109142410A (en) * 2017-06-19 2019-01-04 天津大学 Consider the engineering classification method of the carbonate containing sand of each factor interaction
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