CN1263904C - Multifunctional negative ion health protein fibre and manufacturing method thereof - Google Patents
Multifunctional negative ion health protein fibre and manufacturing method thereof Download PDFInfo
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- CN1263904C CN1263904C CN 200410002692 CN200410002692A CN1263904C CN 1263904 C CN1263904 C CN 1263904C CN 200410002692 CN200410002692 CN 200410002692 CN 200410002692 A CN200410002692 A CN 200410002692A CN 1263904 C CN1263904 C CN 1263904C
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- protein
- shale
- fiber
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- tourmaline powder
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- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The present invention relates to a negative ion multifunctional health care protein fiber, particularly to a regenerative protein composite fiber containing 0.5 to 10% of tourmaline powder and 0.2 to 5% of protein shale silver-carried powder. The tourmaline powder in the fiber has the heath care functions of negative ion release and generation of bioelectric currents through excitation, and the protein shale silver-carried powder has a good absorption characteristic, and has the functions of bacteria resistance, bacteria elimination, odor elimination and abnormal flavor elimination. The fiber is suitable for weaving undergarments, bedroom articles, inner decorative cloth of automobiles, etc.
Description
Technical field
The present invention relates to a kind of have anion and a deodorization and sterilization plurality of health care functions reproduce protein composite fibre and manufacture method thereof.
Background technology
In recent years, along with the continuous improvement of people's living standard and developing rapidly of science and technology, the textile fabric of various health cares and goods emerge in multitude thereof, as: it is " a kind of negative ion health fiber and the manufacture method thereof " of carrier with the polyester that patent application 00127970.X discloses; It is carrier " rayon fiber and manufacture method thereof of containing tourmaline particle " etc. with the viscose glue that patent application 99103640.9 discloses, these all are to be the negative ion health fiber of carrier by composite fibre materials such as polyester, polyamide and viscose glue, do not find with the protein fibre raw material to be the negative ion health fiber of carrier as yet at present.
Summary of the invention
The objective of the invention is to make a kind of is carrier with protein composite fibre raw material, contains tourmaline powder and protein shale carries aluminium powder, and what have anion and deodorization and sterilization plurality of health care functions reproduces the protein composite fibre.
What the present invention relates to reproduces protein composite fibre carrier, realizes with me patent of invention ZL01106274.6 (manufacture method of milk protein and polyvinyl alcohol copolymerized fibre), ZL01138897.8 (soybean milk composite fibre and manufacture method thereof), 01128117.0 (composite kerating fiber and manufacture method thereof) disclosed technology and the manufacture method of application.
The protein shale that the present invention relates to has another name called tripoli, is a kind of peculiar ore, only finds in basin, China Nenjiang at present.Main component is made up of christobalite, phosphorus quartz, opal etc., contains a large amount of Estheria fossils.Ore gray argillaceous texture, the microbedding reason is constructed, quality is light, hardness is low, equigranular is frangible.Ore has a large amount of poriform microvoids, aperture 5～20nm, and specific area is big especially, can reach 277.3cm
2/ g has good adsorption.
The objective of the invention is to be achieved through the following technical solutions:
1. protein shale carries the processing of aluminium powder:
(1) with selected good protein shale mechanical crushing to particle diameter≤100um.
(2) with the protein shale powder of particle diameter≤100um and deionized water by 10～20: 80～90 weight ratio is mixed and is added in the ball mill, ball mill grinding processing 16～24 hours, after the end gained slurries are imported in the decanter type supercentrifuge, carry out centrifugal classification, isolate the protein shale slurry of particle diameter≤5um.Particle diameter is greater than the ball milling processing again in the ball mill of sending back to of 5um.
(3) the protein shale slurry of particle diameter≤5um is added in the stirred tank, add O.1 while stirring～the silver soluble salting liquid of 1mol/L, lucifuge adsorption treatment 1～2 hour is made protein shale and is carried silver paste.The addition of silver soluble salting liquid is controlled at the amount of silver ion and the weight ratio of protein shale is 0.5～5: 95～99.5.Soluble silver salt is preferentially selected AgNO for use
3
2. the processing of tourmaline powder:
(1) with selected high-quality tourmaline mechanical crushing to particle diameter≤100um.
(2) with the tourmaline powder of particle diameter≤100um and deionized water by 10～20: 80～90 weight ratio is mixed and is added in the ball mill, ball mill grinding processing 24～48 hours, after the end gained slurries are imported in the decanter type supercentrifuge, carry out centrifugal classification, isolated tourmaline powder slurry.Particle diameter is greater than the ball milling processing again in the ball mill of sending back to of 1um.Take all factors into consideration efficient and ball milling cost of processing that tourmaline produces anion, the processing particle diameter of tourmaline powder is controlled at 0.1～0.5um the best.
3. producing of anion multifunctional health protein fiber:
Utilize my patent ZL01106274.6, ZL01138897.8,01128117.0 disclosed technology and method, in the protein composite high-molecular spinning solution of making, add the above-mentioned protein shale of making and carry aluminium powder slurries and tourmaline powder slurries, in reactor, mixed 30～60 minutes, make it to mix, then after filtration, deaeration, spinning, drawing-off, arrangement make anion multifunctional health protein fiber.The addition that protein shale carries the aluminium powder slurry is: protein shale carry aluminium powder (dry weight) account for total weight of fiber O.2%～5%.The addition of tourmaline powder slurry is: tourmaline powder (dry weight) account for total weight of fiber O.5%～10%.Promptly the weight ratio that protein composite high-molecular, tourmaline powder, protein shale carry the aluminium powder component in this fiber is: 85～99.3: 0.510: 0.2～5.
This anion multifunctional health protein fiber is because the tourmaline powder physical efficiency that adds discharges anion and excites the generation bioelectricity; The nanometer level microporous adsorptivity of protein shale is fabulous, harmful substance or elements such as adsorbable chloride, nitrite, cyanide, lead, mercury, arsenic and airborne peculiar smell; Protein shale through the absorption silver ion treatment carries aluminium powder, can slowly discharge silver ion, have lasting, good antibiotic and sterilizing effect, so this fiber has good multi-function health-care effect, being applicable to weaving processing underwear, dormitory articles, vehicle internal decoration cloth etc.
The specific embodiment
Embodiment one:
Utilize my patent ZL01106274.6, ZL01138897.8,01128117.0 disclosed technology and method, in the protein composite high-molecular spinning solution of making, add account for total weight of fiber 2～3%, particle diameter≤2um protein shale carry the aluminium powder slurries and account for total weight of fiber 6～8%, particle diameter≤0.3um tourmaline powder slurries, in reactor, mixed 30～60 minutes, make it to mix, then after filtration, deaeration, spinning, drawing-off, arrangement make anion multifunctional health protein fiber.This embodiment is an optimal case.
Embodiment two:
Utilize my patent ZL01106274.6, ZL01138897.8,01128117.0 disclosed technology and method, in the protein composite high-molecular spinning solution of making, add account for total weight of fiber 0.2%, particle diameter≤5um protein shale carry the aluminium powder slurries and account for total weight of fiber 10%, particle diameter≤0.3um tourmaline powder slurries, in reactor, mixed 30～60 minutes, make it to mix, then after filtration, deaeration, spinning, drawing-off, arrangement make anion multifunctional health protein fiber.This embodiment is the embodiment that stresses the negative ion health function.
Embodiment three:
Utilize my patent ZL01106274.6, ZL01138897.8,01128117.0 disclosed technology and method, in the protein composite high-molecular spinning solution of making, add account for total weight of fiber 5%, particle diameter≤2um protein shale carry the aluminium powder slurries and account for total weight of fiber 0.5%, particle diameter≤1um tourmaline powder slurries, in reactor, mixed 30～60 minutes, make it to mix, then after filtration, deaeration, spinning, drawing-off, arrangement make anion multifunctional health protein fiber.This embodiment is the embodiment that stresses the deodorization and sterilization health care.
Claims (5)
1. anion multifunctional health protein fiber, it is characterized in that, it carries the aluminium powder component by protein composite high-molecular, tourmaline powder, protein shale and constitutes, above by weight percentage three kinds of following ratios of ingredients constitute: protein composite high-molecular 85～99.3, tourmaline powder 0.5～10, protein shale carries aluminium powder 0.2～5.
2. the manufacture method of anion multifunctional health protein fiber is characterized in that, this method comprises following processing step:
(1). select good protein shale, elder generation's machinery is ground into the particle of particle diameter≤100um, add in the ball mill ball milling processing 16～24 hours again, import in the decanter type supercentrifuge and carry out centrifugal classification, tell the protein shale slurry of particle diameter≤5um, particle diameter is greater than the ball milling processing again in the ball mill of sending back to of 5um; Protein shale slurry is added in the stirred tank, add the silver soluble salting liquid of 0.1～1mol/L while stirring, lucifuge adsorption treatment 1～2 hour is made protein shale and is carried the aluminium powder slurry;
(2). select the high-quality tourmaline powder of 50～100um particle diameter, ball milling processing is 24～48 hours in the adding ball mill, import in the decanter type supercentrifuge and carry out centrifugal classification, tell the tourmaline powder slurry of particle diameter≤1um, particle diameter is greater than the ball milling processing again in the ball mill of sending back to of 1um;
(3). protein shale is carried in aluminium powder slurry and the tourmaline powder slurry adding protein composite high-molecular spinning solution, stirred 30～60 minutes, mix, after filtration, deaeration, spinning, drawing-off, arrangement make anion multifunctional health protein fiber.
3. method according to claim 2 is characterized in that protein shale carries in the aluminium powder, and the amount of absorption silver ion and the weight ratio of protein shale are 0.5～5: 95～99.5.
4. method according to claim 2 is characterized in that, the addition that protein shale carries the aluminium powder slurry is: protein shale carries aluminium powder weight and accounts for 0.2%～5% of total weight of fiber under the drying regime.
5. method according to claim 2 is characterized in that, the addition of tourmaline powder slurry is: the tourmaline powder body weight accounts for 0.5%～10% of total weight of fiber under the drying regime.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410002692 CN1263904C (en) | 2004-02-01 | 2004-02-01 | Multifunctional negative ion health protein fibre and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410002692 CN1263904C (en) | 2004-02-01 | 2004-02-01 | Multifunctional negative ion health protein fibre and manufacturing method thereof |
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| Publication Number | Publication Date |
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| CN1558004A CN1558004A (en) | 2004-12-29 |
| CN1263904C true CN1263904C (en) | 2006-07-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 200410002692 Expired - Fee Related CN1263904C (en) | 2004-02-01 | 2004-02-01 | Multifunctional negative ion health protein fibre and manufacturing method thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102071510B (en) * | 2011-01-21 | 2014-11-26 | 北京京港恒星科技发展有限公司 | Bacteriostatic radiation protection material |
| CN109930233A (en) * | 2019-02-26 | 2019-06-25 | 杭州泰富纺织化纤有限公司 | A kind of long-acting high-elastic negative-ion fiber |
| CN113512822B (en) * | 2021-04-07 | 2024-05-28 | 福州老棉农科技有限公司 | Degradable non-woven fabric and preparation method thereof |
| CN113133565A (en) * | 2021-05-21 | 2021-07-20 | 浙江金蓝医疗科技有限公司 | Hot-melt skin-friendly mask and production process thereof |
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2004
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| Publication number | Publication date |
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| CN1558004A (en) | 2004-12-29 |
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