CN1250066A - Foamed damping, buffering and packing straw fiber material and its production process - Google Patents

Foamed damping, buffering and packing straw fiber material and its production process Download PDF

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Publication number
CN1250066A
CN1250066A CN 99115870 CN99115870A CN1250066A CN 1250066 A CN1250066 A CN 1250066A CN 99115870 CN99115870 CN 99115870 CN 99115870 A CN99115870 A CN 99115870A CN 1250066 A CN1250066 A CN 1250066A
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China
Prior art keywords
agent
buffering
agricultural crop
straw
damping
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Granted
Application number
CN 99115870
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Chinese (zh)
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CN1111568C (en
Inventor
周谋志
何庭树
陈恩忠
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Xian University of Architecture and Technology
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Xian University of Architecture and Technology
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Priority to CN99115870A priority Critical patent/CN1111568C/en
Publication of CN1250066A publication Critical patent/CN1250066A/en
Application granted granted Critical
Publication of CN1111568C publication Critical patent/CN1111568C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

By using crushed crop straw and adhesive as main material and cross linking agent, catalyst and foaming agent as additive, and through mixing, crosslinking, foaming, deposition, stoving to set and natural drying, damping and buffering packing material is produced. The present invention utilizes various crop straw as material to produce packing material at high efficiency and low cost. The packing material is easy to degrade, has good damping and buffering performance, and may be used for package of electric appliance, instrument and other commodity.

Description

Foamed damping, buffering and packing straw fiber material and production method thereof
The present invention relates to a kind of damping, buffering wrapping material and production method thereof, particularly a kind of usefulness agricultural crop straw and caking agent are as the damping, buffering wrapping material and the production method thereof of raw material.
At present, a large amount of wrapping material that use mostly are porous plastics such as EPS or EPE on the domestic and international market." white pollution " that these wrapping material are serious owing to its non-degradable brings eliminated " white pollution ", but seeks the wrapping material of new natural degradation, become a common research topic of countries in the world.Developed countries such as America and Europe drop into a large amount of funds, research degradable plastics (comprising two types of biological degradation and photodegradation), but mainly be limited to agricultural mulching, yet there are no successful Application on wrapping material.Since 1998, some developed countries forbade that the commodity that have EPS, EPE wrapping material enter its native country; Some country begins to replace EPS, EPE bubble wrap material with paper pulp moulded packaging material.But paper pulp moulding technology uses former carpentery workshop wood pulp, exist waste natural resources, shortcoming such as pulping pollution in early stage, make raw material even adopt to reclaim paper, also still have the manufacturing process complexity, many shortcomings such as efficient is low, cost and energy consumption height and use properties are restricted.In addition, because paper pulp moulded packaging material damping, buffering poor-performing though be useful on smallclothes household electrical appliances, instrument packing at present, also can't be used for packing such as staple commodities such as refrigerator, colour TVs.
The object of the present invention is to provide a kind of packing needs that can satisfy commodity, can reach environmental requirement again, foamed damping, buffering and packing straw fiber material that is easy to degrade and production method thereof.
Technical solution of the present invention is achieved in that and adopts agricultural crop straw crushed material and caking agent as raw material, after technologies such as mixing, crosslinking reaction, foaming, cast, baking typing, seasoning, promptly can be made into the damping, buffering wrapping material.The main component and the weight ratio of damping, buffering wrapping material of the present invention are: agricultural crop straw crushed material 50~70%, caking agent 15~30%, linking agent 5~20%, catalyzer 3~15%, whipping agent 0.5~3%.
The production method of damping, buffering wrapping material of the present invention is:
At first, with pulverizer agricultural crop straw is pulverized, the stalk length after it is pulverized is about 1~10cm, thereafter, manufactures by following processing step:
(1) preparation caking agent by the weight ratio of polyvinyl alcohol, starch and water is: 10~25%: 25~40%: 40~60%, and temperature is controlled between 70~100 ℃ when preparing caking agent; Make postcooling to room temperature;
(2) add agricultural crop straw crushed material and catalyzer in the caking agent for preparing, mixing and stirring adds linking agent and mixes crosslinking reaction 3~8 minutes;
(3) add whipping agent, after fully bubbling, be poured into mold cavity;
(4) mould being sent into temperature is in 60~100 ℃ the drying room, to toast 10~20 minutes, takes out the back demoulding;
(5) product seasoning at normal temperatures is 2~3 days, promptly makes the damping, buffering wrapping material.
Agricultural crop straw of the present invention mainly is meant the mixture of straw, wheat straw, maize straw, sorghum stalks, bagasse etc. or above-mentioned several agricultural crop straws, and described caking agent is the mixture of polyvinyl alcohol, starch and water; Described linking agent is a formaldehyde, and catalyzer is HCl or HNO 3, whipping agent is NaHCO 3Or NH 4HCO 3
Advantage of the present invention is:
1. owing to use natural phant such as agricultural crop straw as raw material, caking agent uses water miscible polyvinyl alcohol and starch, and raw material resources are abundant, and comprehensive cost is lower.The product of this invention is easy to degraded after using and discarding, and soil is had improving effect, is the green product of protection environment.
2. linking agent used in the present invention because its consumption is less, and with employed caking agent polyvinyl alcohol, whipping agent NH 4HCO 3Deng reacting, absorb free formaldehyde effectively, thereby can reach state specified standards, can not produce pollution to environment.
3. manufacturing process of the present invention is simple, the production efficiency height, and comprehensive cost is low, and the damping, buffering performance is good, and market application foreground is good.The present invention is expected to substitute EPS, the EPE bubble wrap material that uses in the market, can be widely used in the big or small commodity packagings such as household electrical appliances, instrument, instrument.
Below in conjunction with embodiment the present invention is described in further detail:
1. get polyvinyl alcohol 0.15kg, under 85 ℃ of conditions, be dissolved in the 600mml water, sneak into 0.25kg starch thereafter, make caking agent and be cooled to room temperature;
2. the wheat stalk 3.5kg of weighing length about 1~10cm is mixed evenly with caking agent, adds the catalyzer HCl of 200ml, after stirring, adds 250ml linking agent formaldehyde again, makes it crosslinking reaction about 5 minutes;
3. in above mixture, add whipping agent NH 4HCO 350g after making it fully to foam, pours in the mold cavity;
4. it is 80 ℃ drying room that the mould that will install material is sent into temperature, toasts about 15 minutes backs and takes out the demoulding;
5. with dry at normal temperatures 2~3 days of demoulding product, can obtain proportion was 0.10~0.13g/cm 3, the foam package material of damping, buffering excellent property.

Claims (4)

1. foamed damping, buffering and packing straw fiber material, it is characterized in that: its main component and weight ratio are agricultural crop straw crushed material 50~70%, caking agent 15~30%, linking agent 5~20%, catalyzer 3~15%, whipping agent 0.5~3%.
2. damping, buffering wrapping material according to claim 1 is characterized in that: described agricultural crop straw crushed material mainly is meant the mixture of straw, wheat straw, maize straw, sorghum stalks, bagasse or above several agricultural crop straws; Described caking agent is the mixing solutions of polyvinyl alcohol and starch; Described linking agent is a formaldehyde, and catalyzer is HCl or HNO 3, whipping agent is NaHCO 3Or NH 4HCO 3
3. the production method of a foamed damping, buffering and packing straw fiber material, it is characterized in that: the main component of these wrapping material and weight ratio are agricultural crop straw crushed material 50~70%, caking agent 15~30%, linking agent 5~20%, catalyzer 3~15%, whipping agent 0.5~3%, the method for producing these wrapping material comprises following processing step:
(1) preparation caking agent, by polyvinyl alcohol: starch: the weight ratio of water is 10~25%: 25~40%: 40~60% prepare caking agents, and temperature is controlled between 70~100 ℃ during preparation, makes postcooling to room temperature;
(2) in the caking agent for preparing, add agricultural crop straw crushed material and catalyzer, mixing and stirring; Add linking agent and mix crosslinking reaction 3~8 minutes;
(3) add whipping agent, after fully bubbling, be poured into mold cavity;
(4) mould being sent into temperature is in 60~100 ℃ the drying room, to toast 10~20 minutes, takes out the back demoulding;
(5) product seasoning at normal temperatures is 2~3 days, promptly makes the foamed damping, buffering wrapping material.
4. the production method of foamed damping, buffering wrapping material according to claim 3 is characterized in that: its stalk length of the agricultural crop straw crushed material that adds in caking agent is 1~10cm.
CN99115870A 1999-10-08 1999-10-08 Foamed damping, buffering and packing straw fiber material and production method thereof Expired - Fee Related CN1111568C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN99115870A CN1111568C (en) 1999-10-08 1999-10-08 Foamed damping, buffering and packing straw fiber material and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN99115870A CN1111568C (en) 1999-10-08 1999-10-08 Foamed damping, buffering and packing straw fiber material and production method thereof

Publications (2)

Publication Number Publication Date
CN1250066A true CN1250066A (en) 2000-04-12
CN1111568C CN1111568C (en) 2003-06-18

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CN99115870A Expired - Fee Related CN1111568C (en) 1999-10-08 1999-10-08 Foamed damping, buffering and packing straw fiber material and production method thereof

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CN (1) CN1111568C (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100386387C (en) * 2006-01-18 2008-05-07 大连轻工业学院 Method for producing package buffer material from pulp waste liquid and corn stalk pith
CN101898399A (en) * 2010-07-23 2010-12-01 深圳市美盈森环保科技股份有限公司 Technology for preparing composite package cushioning material from rice straw fibers
CN104592542A (en) * 2015-02-05 2015-05-06 齐鲁工业大学 Clean production method of foaming buffer material from waste paper fiber
CN105860556A (en) * 2016-04-01 2016-08-17 李宗泽 Packaging material and forming method thereof, package and package forming mould and special package for oil filter
CN106146032A (en) * 2016-07-12 2016-11-23 广西南宁桂尔创环保科技有限公司 A kind of ceramic material utilizing mud
CN106167416A (en) * 2016-07-12 2016-11-30 广西南宁桂尔创环保科技有限公司 A kind of novel environment friendly ceramic material utilizing mud
CN106167394A (en) * 2016-07-12 2016-11-30 广西南宁桂尔创环保科技有限公司 A kind of Environment-friendlyceramic ceramic material
CN109083354A (en) * 2018-07-27 2018-12-25 安徽继宏环保科技有限公司 A kind of environmental-friendly walling dalle and preparation method thereof
CN109438966A (en) * 2018-10-29 2019-03-08 浙江盛瑞环保科技有限公司 A kind of high-strength composite packaging material and preparation method thereof
CN110561849A (en) * 2019-08-06 2019-12-13 马少婷 preparation method of damp-proof buffer material
CN114619537A (en) * 2022-01-25 2022-06-14 西安理工大学 Production method of combined plant fiber buffer material

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1032654C (en) * 1992-06-13 1996-08-28 池洪 Pollutionless foaming material
CN1041527C (en) * 1994-05-10 1999-01-06 池洪 Biodegradable pollution-free sparkle water material
CN1060238C (en) * 1997-08-11 2001-01-03 谢进叁 Active cloth for environment protection and its production process

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100386387C (en) * 2006-01-18 2008-05-07 大连轻工业学院 Method for producing package buffer material from pulp waste liquid and corn stalk pith
CN101898399A (en) * 2010-07-23 2010-12-01 深圳市美盈森环保科技股份有限公司 Technology for preparing composite package cushioning material from rice straw fibers
CN104592542A (en) * 2015-02-05 2015-05-06 齐鲁工业大学 Clean production method of foaming buffer material from waste paper fiber
CN104592542B (en) * 2015-02-05 2017-10-27 齐鲁工业大学 A kind of method of waste paper fibre clean manufacturing foamed damping material
CN105860556A (en) * 2016-04-01 2016-08-17 李宗泽 Packaging material and forming method thereof, package and package forming mould and special package for oil filter
CN106167394A (en) * 2016-07-12 2016-11-30 广西南宁桂尔创环保科技有限公司 A kind of Environment-friendlyceramic ceramic material
CN106167416A (en) * 2016-07-12 2016-11-30 广西南宁桂尔创环保科技有限公司 A kind of novel environment friendly ceramic material utilizing mud
CN106146032A (en) * 2016-07-12 2016-11-23 广西南宁桂尔创环保科技有限公司 A kind of ceramic material utilizing mud
CN109083354A (en) * 2018-07-27 2018-12-25 安徽继宏环保科技有限公司 A kind of environmental-friendly walling dalle and preparation method thereof
CN109438966A (en) * 2018-10-29 2019-03-08 浙江盛瑞环保科技有限公司 A kind of high-strength composite packaging material and preparation method thereof
CN109438966B (en) * 2018-10-29 2021-08-27 叶友岳 High-strength composite packaging material and preparation method thereof
CN110561849A (en) * 2019-08-06 2019-12-13 马少婷 preparation method of damp-proof buffer material
CN114619537A (en) * 2022-01-25 2022-06-14 西安理工大学 Production method of combined plant fiber buffer material

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