CN1245854A - Processed timber - Google Patents
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- CN1245854A CN1245854A CN 99108594 CN99108594A CN1245854A CN 1245854 A CN1245854 A CN 1245854A CN 99108594 CN99108594 CN 99108594 CN 99108594 A CN99108594 A CN 99108594A CN 1245854 A CN1245854 A CN 1245854A
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Abstract
The present invention is directed to a processed lumber material containing a compound of the formula: A-CH2m-* I, A-H2C-* II or A-H2C-*-R3 III, wherein A is 6-chloro-3-pyridyl, 2-chloro-5-thiazolyl, tetrahydrofuran-3-yl or the like; R1 is hydrogen, methyl, ethyl or the like; R2 is methyl, methylamino or the like; R3 is methyl or the like; X is nitrogen or CH; Y is cyano, vitro or trifluoroacetyl; Z is NH or sulfur; D is oxygen or -N(CH3)-; m is 0 or 1; and n is 2 or 3. The processed lumber material of the present invention is extremely insect-proof.
Description
The present invention relates to for example timber of the processing of veneer and plank; The insect protected method of the adhesive of the timber that is used to process and the timber of processing.
Usually, veneer has along its length direction and has the characteristic of little difference along the intensity between its width, and it is in fact insensitive to doing wet condition, its outstanding advantage is, the wide cut plate of no joint, fault and other any shortcoming can be easily made, and high yield can be reached from log.From the viewpoint of protecting national resource, for example with adhesive and little wood chip or lumber fibre shaping, the plank of flakeboard of hot pressing (Partilebroad) and fiberboard has attracted to note widely then.
These timber as the processing of veneer and plank have been used as building, decoration and furniture material.Because they are easy to suffer damage insect such as the termite and the destruction of eating into wooden insect of timber, so need carry out insect-prevention treatment.Yet the timber of these processing will be exposed under the high temperature and high pressure in its manufacturing process unavoidably, and uses employed adhesive for this reason and be confined to the disclosed specific pesticide as JP-A9-136304.
The present invention is by using the following specific anabasine compound of structural formula, for example cyanic acidization, nitrification, and perhaps the amidine of trifluoroacetylation or guanidine obtain the excellent insect protected of the timber of processing.
Therefore, the invention provides a kind of timber of processing, it comprises the following formula: compound of effective dose;
Or
Wherein, A is 6-chloro-3-pyridine radicals, 2-chloro-5-thiazolyl, oxolane-2-base, oxolane-3-base, 5-methyltetrahydrofuran-3-base, 3-pyridine radicals, 6-bromo-3-pyridine radicals, 3-cyano-phenyl, 2-methyl-5-thiazole base, 2-phenyl-5-thiazolyl or 2-bromo-5-thiazolyl; R
1Be hydrogen, methyl, ethyl, formoxyl or acetyl group; R
2Be methyl, amino, methylamino, N, N-dimethylamino, ethylamino, N, N-lignocaine, N-methyl-N-ethylamino, 1-pyrrolidinyl, (6-chloro-3-pyridine radicals) methylamino or N-methyl-N-(6-chloro-3-pyridine radicals) methylamino; R
3Be methyl, ethyl, propyl group, acrylic or propinyl; X is nitrogen or CH; Y is cyano group, nitro or trifluoroacetyl group; Z is NH or sulphur; D be oxygen or-N (CH
3)-; M is 0 or 1; And n is 2 or 3; A kind of insect protected adhesive that comprises formula I, II or III compound also is provided; And the timber of processing is with the method for such insect protected adhesive insect protected.
The compound of formula I, II or III is known pesticide activity medicament, and is for example disclosing among USP-5532365, USP-4742060, USP-4849432, USP-5034404, USP-5750548, USP-5304566 and the EP-428941A.
The compound of formula I can comprise for example N
1-[(6-chloro-3-pyridine radicals) methyl)]-N
2-cyano group-N
1-methyl ethanamidine; N-[(6-chloro-3-pyridine radicals) methyl)]-N-ethyl-N-methyl-2-nitro-1; the 1-ethylene diamine; 1-(6-chloro-3-pyridine radicals) methyl-3-methyl-2-cyanoguanidines; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid; 3-dimethyl-2-cyanoguanidines; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid-ethyl-3-methyl-2-cyanoguanidines; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid; 3-dimethyl-3-(6-chloro-3-pyridine radicals) methyl-2-cyanoguanidines; 1-(6-chloro-3-pyridine radicals) methyl-3-methyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl-3; 3-dimethyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid-methyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid; 3-dimethyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl-3-ethyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl-3-(6-chloro-3-pyridine radicals)-methyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl-3-methyl-2-trifluoroacetyl group guanidine; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid-ethyl-3-methyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid; 3; 3-trimethyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid-ethyl-2-nitroguanidine; 1-(3-pyridine radicals) methyl-3-methyl-2-nitroguanidine; 1-(6-bromo-3-pyridine radicals) methyl-3-methyl-2-nitroguanidine; 1-(2-fluoro-5-thiazolyl) methyl-3-methyl-2-nitroguanidine; 1-(3-cyano-phenyl)-3-methyl-2-nitroguanidine; 1-(4-chlorphenyl) methyl-3-methyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl-3; 3-dimethyl-1-formoxyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl-3; 3-dimethyl-1-acetyl group-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals)-3-methyl-2-cyanoguanidines; 1-(2-chloro-5-thiazolyl) methyl-3; 3-dimethyl-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl isophthalic acid-ethyl-3-methyl-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl isophthalic acid-acetyl group-3; 3-dimethyl-2-nitroguanidine; 1-(6-chloro-3-pyridine radicals) methyl isophthalic acid-methyl-2-trifluoroacetyl group guanidine; 1-(2-chloro-5-thiazolyl) methyl isophthalic acid; 3-dimethyl-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl isophthalic acid-methyl-2-nitroguanidine; 1-(5-thiazolyl) methyl-3-methyl-2-nitroguanidine; 1-(2-methyl-5-thiazole base) methyl-3; 3-dimethyl-2-nitroguanidine; 1-(2-methyl-5-thiazole base) methyl-3-methyl-2-nitroguanidine; 1-(2-phenyl-5-thiazolyl) methyl-3-methyl-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl-3; 3-diethyl-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl-3-methyl-3-ethyl-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl-3-(1-pyrrolidinyl)-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl isophthalic acid; 3; 3-trimethyl-2-nitroguanidine; 1-(2-bromo-5-thiazolyl) methyl-3-methyl-2-nitroguanidine; 1-(2-bromo-5-thiazolyl) methyl-3,3-dimethyl-2-nitroguanidine; 1-(2-chloro-5-thiazolyl) methyl-3-methyl-2-cyanoguanidines; 1-(oxolane-3-yl) methyl-3-methyl-2-nitroguanidine and 1-(oxolane-2-yl) methyl-3-methyl-2-nitroguanidine.
The compound of formula II for example can comprise, 1-(2-chloro-5-pyridylmethyl)-2-cyanoimino thiazoline and 1-[(6-chloro-3-pyridine radicals) methyl]-N-nitro tetrahydropyrimidine-2-imines.
The compound of formula III for example can comprise, 3-[(2-chloro-5-thiazolyl) methyl]-5-methyl-4-cyanoimino tetrahydrochysene-1,3, the 5-oxadiazine, 3,5-dimethyl-1-[(6-chloro-3-pyridine radicals) methyl]-N-nitro six hydrogen-1,3,5-triazine-2-imines, 3,5-dimethyl-1-[(2-chloro-5-thiazolyl) methyl]-2-nitro imino group six hydrogen-1,3, the 5-triazine, 3-ethyl-5-methyl isophthalic acid-[(6-chloro-3-pyridine radicals) methyl]-N-nitro six hydrogen-1,3,5-triazines-2-imines, 3-n-pro-pyl-5-methyl isophthalic acid-[(6-chloro-3-pyridine radicals) methyl]-N-nitro six hydrogen-1,3,5-triazine-2-imines, 3-n-pro-pyl-5-methyl isophthalic acid-[(2-chloro-5-thiazolyl) methyl]-N-nitro six hydrogen-1,3,5-triazines-2-imines, 3-(2-acrylic)-5-methyl isophthalic acid-[(6-chloro-3-pyridine radicals) methyl]-N-nitro six hydrogen-1,3,5-triazine-2-imines and 3-(2-propynyl)-5-methyl isophthalic acid-[(6-chloro-3-pyridine radicals) methyl]-N-nitro six hydrogen-1,3,5-triazines-2-imines.
The wood borers that can effectively prevent and treat by the present invention can comprise those insects that for example belong to following order, section and genus:
Isoptera: Mastotermitidae, Termopsidae (the ancient Cryptotermes in the Pacific Ocean for example, big termite belongs to, Hodotermopsis, Porotermes, the pine mushroom Cryptotermes), (for example kalotermitid belongs to Kalotermitidae, new Cryptotermes, latent kalotermitid belongs to, Incisiterms, Glyptotermes), Hodotermitidae (for example careless Cryptotermes, little careless Cryptotermes, kalotermitid belongs to (Anacanthotermes)), Rhinotermitidae (Reticulitermes for example, different Cryptotermes, the family ant belongs to, Schedolinotermes), white hair Formicidae and Termitidae (Amitididae for example, sickle Cryptotermes (Drepanotermes), Hopitalitermes, Trinervitermes, Mactotermes, odontotermes, little Cryptotermes, reticulitermes lucifugus belongs to, Pericapritermes, Anoplotermes).
Coleoptera: Scolytidae (Dendroctonus for example, (apple bullet) hole bark beetle belongs to), Cerambycidae (day Bos for example, house longhorn beetle belongs to (Hylotrupes), Hesperophanus, tiger day Bos, ancient day Bos (Palaeocallidium), China fir sky Bos, purple day Bos, (oak) psacotheahilaris belongs to), Rynchophoridae (for example Sipalinus), (for example pig-hole borer belongs to Platypodidae, the platypus pig-hole borer belongs to (Platypus)), Lyctidae (for example powder is moth-eaten belongs to), (for example dinoderus minutus belongs to Bostrichidae, long moth-eaten the genus, long moth-eaten belong to (Sinoderus) of China), Anobiidae (Ernobius for example, death watch beetle belongs to, Xyletinus, Xestobium, Ptilinus, the Nico death watch beetle belongs to (Nicobium), the Dali death watch beetle belongs to) and buprestid.
Term " timber of processing " is meant the wooden material of the veneer timber (LVL) that comprises plank, veneer, glued plate and lamination as used herein, and these materials are by making veneer or making as the little wood chip integration of wood chip, sawmilling clout, sawdust and screenings.
Term " plank " is meant by little wood chip and utilizes flakeboard that adhesive re-constructs or the fiberboard that utilizes adhesive to re-construct by wood fiber as used herein, the timber that for example bonds, parallel in conjunction with timber (parallel strand lumber) (PSL), the adhesive glue plywood, directed in conjunction with timber (orientedstrand lumber) (OSL), sheet knot plate (waferboard), strand-board, directed flakeboard, shaving board, flakeboard, directed medium density fibreboard, sound insulation (heat) plate, medium density fibreboard and hardboard.For example can comprise wood chip, wood shavings, half wood shavings, small pieces, fines, shavings, strands, bar and particle at this available little wood chip.The kind of timber for example can comprise, originates from the timber as Liu An in Southeast Asia; Broadleaf tree such as aspen and conifer trees are as the south pine.Lumber fibre for example can comprise as used herein, silk tree or radiata pine.
As used herein term " veneer " be meant by by odd number laminated wood veneer so that the adjacent mutual rectangular plank of machine direction of veneer.Usually the veneer number is at least three and can find various plates for example five-ply board or seven plywood.Usually by coating adhesive on the surface of veneer, lamination, heating and these veneers that bond under pressure are made veneer then.The kind of timber for example can comprise, willow Eucalyptus, linden, Japanese oak, Japanese Ash, birch, beech and Japanese cedar.Common sticking temperature is that 100 ℃～250 ℃ and cohesive pressure are generally 5～40 kg/cm
2
As used herein term " glued plate " and " the veneer timber of lamination " be meant respectively by swanwood boards or fillet lamination and by the veneer lamination so that the plank that their machine directions are parallel to each other and obtain.Use the method identical and make these planks with the trees of identical type with producing veneer.
Make the timber of these processing with the adhesive that comprises formula I, II or III compound.By this compound of direct usefulness or with its solution by for example soaking, be coated with or spray the timber of this processing of surfacing; By under pressure or under the decompression this compound or its injection of solution are gone into the timber of this processing; Perhaps in the surface finishing agent of the timber by this compound being added to this processing this compound can be attached in the timber of this processing.
Formula I, II or III compound mix with adhesive when using, and for example, this compound mixes with solid or liquid-carrier, and if desired to wherein adding surface-active medicament and other auxiliary agent.This mixture of making is mixed with suitable form such as missible oil, wettable powder, flowable (for example aqueous suspension agent, aqueous emulsion), pulvis, foaming agent, paste or granula then, and mix with the adhesive of routine, obtain to contain the insect protected adhesive of this compound.
Conventional adhesive for example can comprise, starch, glue, casein glue, rubber made from soybean cake, japan, the resorcinol resin adhesive, urea formaldehyde resin adhesive, vinylacetate resin emulsion adhesive, crosslinked vinylacetate resin emulsion adhesive, waterborne polymeric-isocyanates (polymer-isocyanate) adhesive, alpha-olefin-copolymer-maleic anhydride adhesive, hotmelt, rubber adhesive, epobond epoxyn, the cyano-acrylate resin adhesive, the frankincense adhesive, aerodux, melamine-urea cocondensation resin binder and melamine-phenol cocondensation resin binder.
The amount of the formula I that contains in the timber of this processing, II or III compound is usually at 0.01-500 gram/rice
3Scope in.For example, a kind of insect protected adhesive is used for the timber of processing constructed in accordance routinely, in this insect protected adhesive, has comprised whole binder wt 0.001%-50% weight in advance, this compound of preferred 0.01%-10% weight.
Make the conventional timber of processing such as the conventional method of veneer and plank by using; for example by disclosed method in " Mokuzai-hozon-gaku Nyumon (wood protection guiding) " literary composition of being published by Japanese wood protection association, the enough insect protected adhesives that contains formula I, II or III compound of energy be made the timber of processing of the present invention.
Disclosed method even can be used for this compound itself or its solution in above-mentioned article through for example soaking, be coated with or spray the timber of surfacing processing; Under pressure or under the decompression this compound or its injection of solution are gone into the timber of this processing; Perhaps this compound is added in the surface finishing agent of timber of this processing.In these cases, the amount of compound used therefor is generally each surperficial 0.003-200 gram/rice of the timber of processing in the processing
2
Except formula I, II or III compound, the timber of this processing may further include the insecticidal activity medicament that is used for insect protected timber, for example cyphenothrin, Permethrin, cypermethrin or the fenvalerate of the disclosed improvement vermins-proof effect of JP-A9-136304.
Except formula I, II or III compound, the timber of this processing may further include at least a of following microbicidel and/or Antimicrobe compound, makes it might prevent the infringement that fungi, bacterium and/or algae cause.
Three halogen sulfinyl compounds (for example; Euparen; trifluanid; folpet; fluorine folpet (fluorofolpet)); iodine compound (for example; IPBC; Amical 48 (Abbott production); IF 1000 (Nagase Sangyo production); EBIP); phenolic compounds (for example; laurate pentachlorobenzene phenolic ester; DCBP; tribromphenol); nitrogen heterocyclic (for example; Fenarimol; flurprimidol; flutrimazole; triadimefon; Triadimenol; dichlorobtrazol; paclobutrazol; alkene azoles alcohol; uniconazole P; fluorine bacterium azoles; Flutriafol; Flusilazole; penconazole; prochloraz; triarimol; Fenarimol; Bitertanol; press down mould azoles; etaconazole; fenapanil; alkene frost benzyl azoles Difenoconazole; bromuconazole; nitrile bacterium azoles; own azoles alcohol; fluconazole-cis; fenethanil; Tebuconazole; propiconazole; penta ring azoles; cyproconazole); carbamate compounds (for example; zineb; maneb; benomyl; thiophanate methyl; cyanogen penta benzene miaow; carbendazim; the chlorine phoxim; the mould prestige of second); Antibiotique composition (for example; Validacin (Takeda); kasugarnycin; rice is that mycin doubly); the N-anilides (for example; mebenil; flutolanil; Pencycuron; carboxin; oxycarboxin; pyracarbolid; mebenil; the furan spirit (sterilization amine) of withering; ring bacterium amine; benodanil; metalaxyl; fenfuram; the spirit of M 9834 Evil frost; cyprofuram; metsulfovax; tecloftalam); organic compound (for example; ediphenphos; IBP; Ppyrazophos; aliette; tolelofos-methyl); the dicarboximide compound (for example; dichlozolin; iprodione; vinclozolin; the third ring imido ketone; microzolin; chlorine fluorine sclex (fluoroimide)); tin compound (for example; sad tributyl tin; the oleic acid tributyl tin; two-the tributyl tin oxide; the aphthenic acids tributyl tin; the tricresyl phosphate butyl tin; the benzoic acid tributyl tin); sulfocyanate compound (for example; the di-2-ethylhexylphosphine oxide thiocyanates; 2-thiocyanogen methyl mercapto benzo thiazole; quaternary ammonium compound (for example; the benzyl dimethyl tetradecyl ammonium chloride; benzyl dimethyl dodecyl chlorination ammonium); benzimidazole compound (for example; furidazol; BCM; probenazole; benomyl); iso thiazoline ketone compound; morpholinium compound (for example; cyclomorpholine (tridemorf)); pyridine compounds; N-cyclohexyldiadinium dioxy compound; the aphthenic acids compound (for example; zinc naphthenate; copper naphthenate); quinoline compound; boron compound (for example; boric acid; borax; borate); carbamide compound and furan derivatives are (for example, furmecyclox).
The fungi that can prevent and treat by above-mentioned microbicidel and/or Antimicrobe compound can comprise, for example belongs to those fungies of following section and genus:
Timber decolouring bacterium: sac fungus (for example Caratocystis), deuteromycetes are (for example, aspergillus, golden basidiomycetes (Aureobasidium), Dactyleum, Penicillium notatum, Aclerophoma, sweep mould genus (Scopularia), Tricoderma) and Zygomycetes is (for example, Mucor).Wood failure bacterium: sac fungus, (for example, chaetocin, humicolin (Humicola), Petriella, needle belong to), basidiomycetes (for example, powder lead fungi genus, Coriolus, Donbiopora, Glenospora, sticking gill fungus genus, lentinus, timber pile Pseudomonas, Pleurotus, the hole genus that crouches, imperial cyprid genus, Tyromyces) and deuteromycetes (for example, Blastocladia).
Embodiment
Further set forth the present invention by following production example and experimental example; But, the invention is not restricted to these embodiment.
Production example 1
(a) preparation of adhesive
By in 18 gram flour, adding 100 gram melamine-urea resins (the Ohshika Resin PWP-60 that Ohshika Shinkoh produces) and fully rubbing the material of acquisition through rubbing.Then, 0.1309 gram 1-(oxolane-3-yl) methyl-3-methyl-2-nitroguanidine (hereinafter referred to as compd A) or 0.6572 is restrained 20% N
1-[(6-chloro-3-pyridine radicals) methyl)]-N
2-cyano group-N
1-methyl ethanamidine (hereinafter referred to as compd B) solution (the Mospilan SP that Japan system alkali company produces) mixes with 12 gram water, and this mixture is added above-mentioned material through rubbing, and stirs then.Further add 0.8 gram hardener, this hardener is mixed to obtain a kind of adhesive.
(b) preparation of veneer
Is that 30 * 30 centimetres, thickness are respectively 0.85,2.4 and 0.85 millimeter red lauan veneer lamination in this order with above-mentioned (a) prepared adhesive with three areas.At this moment, the amount (promptly totally 36 restraining) with 18 grams applies this adhesive on each face of central layer.At room temperature with 10 kg/cm
2Cold pressing this lamination 20 minutes of pressure, then in 120 ℃ with 10 kg/cm
2Pressure hot pressing 2 minutes, be 100 gram/rice to obtain desired active agents (being compd A or B) containing ratio
3Thick 4.1 millimeters three-ply board.
Production example 2
The urea formaldehyde resin adhesive of 63 weight portions, the paraffin of 3 weight portions, the hardener (ammonium chloride) of 0.95 weight portion and the compd B of 0.63 weight portion are mixed a kind of glue of acquisition.With this glue by in the radiata pine sheet that spray to add 630 weight portions, this mixture is configured as tabular, then with it in maximum compression pressure 30 kg/cm
2Compress 4 minutes to obtain a kind of thick 12 millimeters flakeboard in 150 ℃ down.
Production example 3
The compd B of accelerator (sodium carbonate), 1.2 weight portion iodine propinyl butyl mephenesin Carbamates and 0.63 weight portion of the phenol resin adhesive of 63 weight portions, 0.95 weight portion mixed obtain a kind of glue.With this glue by in the radiata pine sheet that spray to add 630 weight portions, this mixture is configured as tabular, then with it in maximum compression pressure 30 kg/cm
2Compress 7 minutes to obtain a kind of thick 12 millimeters flakeboard in 170 ℃ down.
Experimental example 1
Will be as the veneer of production example 1 preparation with the about 1 centimetre width cutting of each face, cut into 8 of the veneer side of the test plates of 5 * 10 centimeter square then.To there be the aluminium sheet of 5 * 10 cm sizes in 3 millimeters holes of 32 diameters to be placed into contiguously on each veneer breadboard.In each hole, put into the ripe larva of an European bamboo powder moth at random.With artificial mash feed (EBIOS: flour: powdered cellulose=3: 7: 10) fill wherein each hole, and another piece veneer breadboard put thereon and with rubber strip fix.After one month, check on this veneer breadboard that adult by hatching penetrates this veneer breadboard and the quantity of the perforation that forms.The results are shown in down tabulation 1.
Table 1
| The test agent | Amount (gram/the rice of active agents 3) | The quantity of perforation |
| Compd A | 100 | 0 |
| 20% compd B solution | 100 | 0 |
| Compound C | 100 | 0 |
| Do not add | ?- | 3 |
Compd A: 1-(oxolane-3-yl) methyl-3-methyl-2-nitroguanidine
Compd B: N
1-[(6-chloro-3-pyridine radicals) methyl)]-N
2-cyano group-N
1-methyl ethanamidine
Compound C: methyl 3-[(2-chloro-5-thiazolyl)]-5-methyl-4-cyanoimino tetrahydrochysene-1,3, the 5-oxadiazine
Experimental example 2
To cut with the about 1 centimetre width of each face as the veneer of production example 1 preparation, cut into 25 * 25 millimeters square veneers test squares then.Packing in the polyethylene cup of 8 centimetres high 4 centimetres of diameters in 9 about 2 millimeters holes of diameter is arranged at the bottom covers the emplastrum of bottom, and this veneer breadboard is placed on this emplastrum.In this polyethylene cup, put into 15 of 150 of the worker ants of coptotermes formosanus (Coptotermes formosanus) and soldier ants at random, and on this polyethylene cup, cover the lid in 18 about 2 millimeters holes of diameter.This polyethylene cup of adding a cover is placed into a bottom is coated with on the container of absorbent cotton, make it to remain on room temperature then.After 3 weeks, observe the number (survival rate) of getting food infringement and survival termite of this veneer breadboard.The results are shown in down tabulation 2.
Table 2
| The test agent | Amount (gram/the rice of active agents 3) | Average survival rate (%) | On average get the food infringement * |
| Compd A | 100 | 4.8 | 0.4 |
| Do not add | - | 92?7 | 4 |
Compd A: 1-(oxolane-3-yl) methyl-3-methyl-2-nitroguanidine
*On average get the food infringement and be decided to be 0 (nothing is got the food infringement) to 4 (infringement is eaten in getting of the area when being substantially equal to be untreated).
Claims (11)
1. the timber of the processing of an insect protected, described timber contains the following formula: compound of effective dose,
Or
Wherein, A is 6-chloro-3-pyridine radicals, 2-chloro-5-thiazolyl, oxolane-2-base, oxolane-3-base, 5-methyltetrahydrofuran-3-base, 3-pyridine radicals, 6-bromo-3-pyridine radicals, 3-cyano-phenyl, 2-methyl-5-thiazole base, 2-phenyl-5-thiazolyl or 2-bromo-5-thiazolyl; R
1Be hydrogen, methyl, ethyl, formoxyl or acetyl group; R
2Be methyl, amino, methylamino, N, N-dimethylamino, ethylamino, N, N-lignocaine, N-methyl-N-ethylamino, 1-pyrrolidinyl, (6-chloro-3-pyridine radicals) methylamino or N-methyl-N-(6-chloro-3-pyridine radicals) methylamino; R
3Be methyl, ethyl, propyl group, acrylic or propinyl; X is nitrogen or CH; Y is cyano group, nitro or trifluoroacetyl group; Z is NH or sulphur; D be oxygen or-N (CH
3)-; M is 0 or 1; And n is 2 or 3.
2. the timber of processing as claimed in claim 1, described timber is veneer, flakeboard or fiberboard.
3. the timber of processing as claimed in claim 1, described timber is veneer.
4. the timber of processing as claimed in claim 1, described timber is flakeboard or fiberboard.
5. the timber of processing as claimed in claim 1, the compound of its Chinese style I, II or III is 1-(oxolane-3-yl) methyl-3-methyl-2-nitroguanidine.
6. the timber of processing as claimed in claim 1, the compound of its Chinese style I, II or III is N
1-[(6-chloro-3-pyridine radicals) methyl)]-N
2-cyano group-N
1-methyl ethanamidine.
7. the timber of processing as claimed in claim 1, the compound of its Chinese style I, II or III is a 3-[(2-chloro-5-thiazolyl) methyl]-5-methyl-4-nitro imino group tetrahydrochysene-1,3, the 5-oxadiazine.
8. method of making the timber of moth resistant finish, this method comprise with containing just like claim 1 to be described and the adhesive of formula I, the II of definition or III compound forms veneer, little wood chip or wood fiber the timber of processing.
9. method as claimed in claim 5, wherein this adhesive is selected from starch, glue, casein glue, rubber made from soybean cake, japan, the resorcinol resin adhesive, urea formaldehyde resin adhesive, vinylacetate resin emulsion adhesive, crosslinked vinylacetate resin emulsion adhesive, waterborne polymeric-isocyanate adhesive, alpha-olefin-copolymer-maleic anhydride adhesive, hotmelt, rubber adhesive, epobond epoxyn, the cyano-acrylate resin adhesive, the frankincense adhesive, aerodux, melamine-urea cocondensation resin binder and melamine-phenol cocondensation resin binder.
10 1 kinds contain just like claim 1 description and formula I, the II of definition or the insect protected adhesive of III compound.
11. formula I, II or the application of III compound in the timber of the processing of making insect protected as claim 1 description and definition.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18037498 | 1998-06-26 | ||
| JP180374/1998 | 1998-06-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1245854A true CN1245854A (en) | 2000-03-01 |
Family
ID=16082133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99108594 Pending CN1245854A (en) | 1998-06-26 | 1999-06-25 | Processed timber |
Country Status (5)
| Country | Link |
|---|---|
| CN (1) | CN1245854A (en) |
| AU (1) | AU3584199A (en) |
| CA (1) | CA2273545A1 (en) |
| ID (1) | ID23009A (en) |
| MY (1) | MY151096A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1328024C (en) * | 2001-02-01 | 2007-07-25 | 木聚合物技术有限公司 | Furan polymer impregnated wood |
| CN102248569A (en) * | 2011-07-21 | 2011-11-23 | 江苏快乐木业集团有限公司 | Oriented shaving box board and machining process thereof |
| CN111231035A (en) * | 2020-03-05 | 2020-06-05 | 彰武章古台固沙造林实验林场 | Blue-stain preventing method for pinus sylvestris wood |
| CN112959448A (en) * | 2021-02-06 | 2021-06-15 | 国际竹藤中心 | Green and environment-friendly bamboo mildew-proof method |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001316211A (en) * | 2000-05-08 | 2001-11-13 | Sumitomo Chem Co Ltd | Method for preventing pest damage of clothing and agent therefor |
| US7439280B2 (en) | 2004-04-06 | 2008-10-21 | Basf Corporation | Lignocellulosic composite material and method for preparing the same |
-
1999
- 1999-05-11 MY MYPI9901864 patent/MY151096A/en unknown
- 1999-05-18 ID IDP990457A patent/ID23009A/en unknown
- 1999-06-03 CA CA 2273545 patent/CA2273545A1/en not_active Abandoned
- 1999-06-23 AU AU35841/99A patent/AU3584199A/en not_active Abandoned
- 1999-06-25 CN CN 99108594 patent/CN1245854A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1328024C (en) * | 2001-02-01 | 2007-07-25 | 木聚合物技术有限公司 | Furan polymer impregnated wood |
| CN102248569A (en) * | 2011-07-21 | 2011-11-23 | 江苏快乐木业集团有限公司 | Oriented shaving box board and machining process thereof |
| CN102248569B (en) * | 2011-07-21 | 2012-11-28 | 江苏快乐木业集团有限公司 | Oriented shaving box board and machining process thereof |
| CN111231035A (en) * | 2020-03-05 | 2020-06-05 | 彰武章古台固沙造林实验林场 | Blue-stain preventing method for pinus sylvestris wood |
| CN112959448A (en) * | 2021-02-06 | 2021-06-15 | 国际竹藤中心 | Green and environment-friendly bamboo mildew-proof method |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2273545A1 (en) | 1999-12-26 |
| ID23009A (en) | 1999-12-30 |
| AU3584199A (en) | 2000-01-13 |
| MY151096A (en) | 2014-04-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |