CN1239686C - Demoulding composition system for preparing polyisocyanate adhesive artificial board and process for preparation thereof - Google Patents
Demoulding composition system for preparing polyisocyanate adhesive artificial board and process for preparation thereof Download PDFInfo
- Publication number
- CN1239686C CN1239686C CN 200310105756 CN200310105756A CN1239686C CN 1239686 C CN1239686 C CN 1239686C CN 200310105756 CN200310105756 CN 200310105756 CN 200310105756 A CN200310105756 A CN 200310105756A CN 1239686 C CN1239686 C CN 1239686C
- Authority
- CN
- China
- Prior art keywords
- acid ester
- mold release
- release compositions
- wax
- wax emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 119
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 239000005056 polyisocyanate Substances 0.000 title abstract description 15
- 229920001228 polyisocyanate Polymers 0.000 title abstract description 15
- 238000000034 method Methods 0.000 title abstract description 12
- 230000001070 adhesive effect Effects 0.000 title abstract description 5
- 239000000853 adhesive Substances 0.000 title abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 101
- 239000000839 emulsion Substances 0.000 claims abstract description 71
- -1 fatty acid esters Chemical class 0.000 claims abstract description 54
- 150000003014 phosphoric acid esters Chemical class 0.000 claims abstract description 43
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 40
- 239000000194 fatty acid Substances 0.000 claims abstract description 40
- 229930195729 fatty acid Natural products 0.000 claims abstract description 40
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000001993 wax Substances 0.000 claims description 75
- 150000002148 esters Chemical class 0.000 claims description 49
- 239000003995 emulsifying agent Substances 0.000 claims description 26
- 239000002253 acid Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 claims description 12
- 241000305791 Commidendrum rugosum Species 0.000 claims description 11
- 238000005516 engineering process Methods 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 9
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 8
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000005642 Oleic acid Substances 0.000 claims description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 8
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 7
- 229960004232 linoleic acid Drugs 0.000 claims description 7
- 239000012874 anionic emulsifier Substances 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 5
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 claims description 5
- 239000012875 nonionic emulsifier Substances 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- JTXUVYOABGUBMX-UHFFFAOYSA-N didodecyl hydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCC JTXUVYOABGUBMX-UHFFFAOYSA-N 0.000 claims description 4
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 claims description 4
- 239000012184 mineral wax Substances 0.000 claims description 4
- 230000003068 static effect Effects 0.000 claims description 4
- 239000012178 vegetable wax Substances 0.000 claims description 4
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 239000012164 animal wax Substances 0.000 claims description 2
- SNAMIIGIIUQQSP-UHFFFAOYSA-N bis(6-methylheptyl) hydrogen phosphate Chemical compound CC(C)CCCCCOP(O)(=O)OCCCCCC(C)C SNAMIIGIIUQQSP-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- QTDSLDJPJJBBLE-PFONDFGASA-N octyl (z)-octadec-9-enoate Chemical compound CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC QTDSLDJPJJBBLE-PFONDFGASA-N 0.000 claims description 2
- IIGMITQLXAGZTL-UHFFFAOYSA-N octyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC IIGMITQLXAGZTL-UHFFFAOYSA-N 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 claims 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 3
- 239000002023 wood Substances 0.000 description 33
- 239000010902 straw Substances 0.000 description 17
- 241000209140 Triticum Species 0.000 description 15
- 235000021307 Triticum Nutrition 0.000 description 15
- 239000000463 material Substances 0.000 description 14
- 239000003292 glue Substances 0.000 description 11
- 239000010410 layer Substances 0.000 description 11
- 239000007921 spray Substances 0.000 description 8
- 239000012792 core layer Substances 0.000 description 7
- 238000007731 hot pressing Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 238000009775 high-speed stirring Methods 0.000 description 6
- 239000012948 isocyanate Substances 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 150000002632 lipids Chemical class 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 150000001733 carboxylic acid esters Chemical class 0.000 description 3
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 3
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 230000000754 repressing effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- MKYLOMHWHWEFCT-UHFFFAOYSA-N Manthidine Natural products C1C2=CC=3OCOC=3C=C2C2C3=CC(OC)C(O)CC3N1C2 MKYLOMHWHWEFCT-UHFFFAOYSA-N 0.000 description 1
- SNFRINMTRPQQLE-JQWAAABSSA-N Montanin Chemical compound O[C@H]([C@@]1(CO)O[C@H]1[C@H]1[C@H]2O3)[C@]4(O)C(=O)C(C)=C[C@H]4[C@]11OC3(CCCCCCCCCCC)O[C@@]2(C(C)=C)C[C@H]1C SNFRINMTRPQQLE-JQWAAABSSA-N 0.000 description 1
- SNFRINMTRPQQLE-OFGNMXNXSA-N Montanin Natural products O=C1[C@@]2(O)[C@@H](O)[C@@]3(CO)O[C@H]3[C@@H]3[C@H]4[C@@]5(C(=C)C)O[C@](CCCCCCCCCCC)(O4)O[C@@]3([C@H](C)C5)[C@@H]2C=C1C SNFRINMTRPQQLE-OFGNMXNXSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001219 Polysorbate 40 Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- QTZPBQMTXNEKRX-UHFFFAOYSA-N Voacristine pseudoindoxyl Natural products N1C2=CC=C(OC)C=C2C(=O)C21CCN(C1)C3C(C(C)O)CC1CC32C(=O)OC QTZPBQMTXNEKRX-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940092738 beeswax Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 235000021197 fiber intake Nutrition 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229940101027 polysorbate 40 Drugs 0.000 description 1
- 229940113124 polysorbate 60 Drugs 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- LUPNKHXLFSSUGS-UHFFFAOYSA-M sodium;2,2-dichloroacetate Chemical compound [Na+].[O-]C(=O)C(Cl)Cl LUPNKHXLFSSUGS-UHFFFAOYSA-M 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The present invention relates to a demoulding composition system for preparing artificial boards from polyisocyanate adhesives and a preparation technique, which belongs to the field of preparation products in chemical industry. An external demoulding agent or an internal demoulding agent comprises the following raw material components: wax emulsion and one or the mixture of two of fatty acid esters, phosphate esters and salts thereof, wherein the weight of the wax emulsion in the demoulding composition is not higher or lower than 50%, and the weight of one or the mixture of two of fatty acid esters, phosphate esters and salts thereof is not lower or higher than 50%. The external demoulding agent or the internal demoulding agent has the following preparation technique: preparing the wax emulsion, preparing one or the copolymerized mixture of two of fatty acid esters, phosphate esters and salts thereof, and mixing the wax emulsion with the copolymerized mixture so as to obtain the external demoulding agent or the internal demoulding agent of the demoulding composition system. The demoulding composition system of the present invention can ensure that an artificial board is completely demoulded from the surface of a hot pressboard or a conveyor belt under the precondition that the excellent adhesive property of polyisocyanate is ensured.
Description
One, affiliated technical field
The present invention relates to be used to prepare the mold release compositions system and the preparation technology thereof of polyisocyanic acid ester gum wood-based plate, more particularly the present invention relates to use polyisocyanates to prepare the employed mold release compositions system of wood-based plate inner pattern releasing agent applicable, external release agent and preparation technology thereof, belong to chemical industry formulation products technical field as tackiness agent.
Two, background technology
Organic multiple isocyanate is as a kind of high-performance environment-friendly tackiness agent, long-term tackiness agent as the lignocellulose-containing material is mainly used in agricultural crop straw shaving board, common wooden flake board, oriented wood chipboard, fiberboard and glued boards etc. such as making wheat straw, straw.This tackiness agent has characteristics such as adhesiveproperties is good, the formaldehydeless public hazards of goods.But in the pressing plate process, because the bond properties of polyisocyanates excellence, can cause lignocellulose-containing material and platen to stick together, needing to destroy the plate face could separate, grievous injury board quality, and cleaning clamp surface or travelling belt surface, consuming time, effort has had a strong impact on production efficiency.
In order to solve the haftplatte problem, people have adopted many methods.For example, (1) uses tetrafluoroethylene backing plate or kraft paper.(2) adopt the watch core layer separately to execute glue not of the same race, urea aldehyde or phenolic glue are executed in the top layer, and sandwich layer is executed the polyisocyanic acid ester gum.But this several method, perhaps influence is conducted heat, operation inconvenience in continuous production; Perhaps poor adhesion, goods have formaldehyde to discharge, and have influenced product properties, have reduced product specification.
In addition, the research of many companies is arranged, solve the haftplatte problem by using external release agent and inner pattern releasing agent applicable.External release agent such as United States Patent (USP) 4,110,297 disclosed metallic soap classes, the employed metallic soap class of this method spraying the tracheae that can stimulate the people when using, causes malaise symptoms such as cough.United States Patent (USP) 20030015122 uses the mixed emulsion of lipid acid and polyethylene wax to make external release agent, and lipid acid can be selected oleic acid for use, but this emulsion stripping result is general, and stripping result is poor continuously.Inner pattern releasing agent applicable such as United States Patent (USP) 5554438 mix paraffin and oleic acid, and 100 ℃ kept 2 minutes down, isocyanic ester and oleic acid were mixed down at 25 ℃ again.Wax/lipid acid is sprayed on the wood shavings, and consumption is 1.25% of a wood shavings consumption, isocyanic ester and oleic mixture is sprayed on the wood shavings again, and consumption is 2.0% of a wood shavings consumption, and hot pressing obtains shaving board then.But add the problem that wax and lipid acid can cause package stability in isocyanic ester, lipid acid can react with polyisocyanates again, has reduced the bond properties of tackiness agent.
Mostly the method that other improves the isocyanate adhesive demolding performace is directly to add the inner pattern releasing agent applicable material in polyisocyanates, these all inevitably cause the problem of package stability, and these methods are not gratifying methods.
Three, summary of the invention
The object of the present invention is to provide the mold release compositions system inner pattern releasing agent applicable, external release agent and the preparation technology thereof that are used to prepare polyisocyanic acid ester gum wood-based plate, make the haftplatte problem that tackiness agent is produced wood-based plate with solving polyisocyanates.The inner pattern releasing agent applicable of this system, external release agent guarantee that again wood-based plate is from the surface of heating platen or the demoulding fully of travelling belt surface under the bond properties prerequisite that guarantees the polyisocyanates excellence.
Use mold release compositions system inner pattern releasing agent applicable of the present invention, external release agent can be realized above-mentioned purpose, mold release compositions system external release agent of the present invention or inner pattern releasing agent applicable product: (A) wax emulsion, (B) one or both mixture in fatty acid ester, phosphoric acid ester and its esters for adopting following raw material components to make.
For avoiding the polyisocyanates tackiness agent storage stability to occur, mold release compositions can separate with polyisocyanates and sprays application in wood shavings or the fiber, but perhaps joins in the isocyanate emulsion, sprays application to together in wood shavings or the fiber.
Being used for organic multiple isocyanate of the present invention and comprising aromatic series, aliphatics and alicyclic polyisocyanates known to the polyurethane chemistry industry, preferably is the polyisocyanates of liquid under those room temperatures.Particularly suitable be poly methylene poly phenyl poly isocyanate, object lesson comprises: PM-200, PM-300 and PM-400 that Yantai Wanhua Polyurethane Co., Ltd produces.But also can be isocyanate emulsion.The consumption of isocyanic ester approximately is the 2%-8% of over dry wood shavings or fiber consumption, preferred 3-6%, and this need adjust according to the density and the performance requriements of goods.
Mold release compositions system external release agent of the present invention, the weight of wax emulsion is no more than 50% in mold release compositions, preferably 20-40%; Fatty acid ester or phosphoric acid ester and its esters can be selected one or both mixture for use, and weight is not less than 50% in mold release compositions, preferably 60-80%.The solid content of external release agent is its weight percent 1-20% that accounts for external release agent, and optimum is 5-10%, can directly spray during use on the surface of steel slab surface and travelling belt, also can dilute one times of surface that sprays at steel slab surface and travelling belt.
Mold release compositions system inner pattern releasing agent applicable of the present invention, the weight of wax emulsion is not less than 50% in mold release compositions, preferably 60-80%; Fatty acid ester or phosphoric acid ester and its esters can be selected one or both mixture for use, and weight is not higher than 50% in mold release compositions, preferably 20-40%.The solid content of inner pattern releasing agent applicable is its weight percent 10-40% that accounts for inner pattern releasing agent applicable, and optimum is 20-30%, needs independently spraying system during use, sprays inner pattern releasing agent applicable in applying glue.But perhaps be pre-mixed, together spray with isocyanate emulsion.
Wax used in the present invention comprises vegetable wax, animal wax, mineral wax, synthetic wax and other fusing point wax class between 40 ℃-170 ℃.Object lesson comprises: ceresine, paraffin, beeswax, spermaceti, palm wax, montanin wax, Microcrystalline Wax, polyethylene wax, oxidized polyethlene wax etc., the fusing point of wax requires greater than 40 ℃, less than 170 ℃.
The preparation method of mold release compositions system external release agent or inner pattern releasing agent applicable may further comprise the steps: the preparation of a, wax emulsion; The preparation of one or both copolymer mixture in b, fatty acid ester, phosphoric acid ester and its esters; C, above-mentioned wax emulsion are mixed with copolymer mixture and are obtained the outer demoulding releasing agent of mold release compositions system.
The used wax of the present invention must be made the wax emulsion, and emulsifying agent can use anionic emulsifier, cationic emulsifier, nonionic emulsifier and amphoteric emulsifier.Anionic emulsifier comprises metal carboxylate, Sulfates, Sulfonates and phosphoric acid salt, such as sodium lauryl sulphate, dodecyl sulphate potassium, sodium oleate, potassium oleate, sodium laurylsulfonate, Sodium dodecylbenzene sulfonate and sodium metnylene bis-naphthalene sulfonate, trolamine oleate etc.Cationic emulsifier comprises the salt of quaternary ammonium salt and other ammonium.Such as palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride and stearyl dimethyl benzyl ammonium chloride etc.Nonionic emulsifier comprises: polyoxyethylene carboxylicesters, polyoxyethylene polyol carboxylate, polyethylene oxide alkyl ethers, polyoxyethylene alkyl aryl ether etc.Such as polysorbas20, polysorbate40, polysorbate60, tween 80 and Nonyl pheno base ether etc.Amphoteric emulsifier comprises carboxylic-acid amphoteric emulsifier, sulfuric acid ester amphoteric emulsifier, phosphoric acid ester amphoteric emulsifier and sulfonic acid class amphoteric emulsifier.Such as carboxyl empgen BB etc.
The preparation method of wax emulsion can add wax, emulsifying agent and water in the emulsor earlier, stirs for some time under certain temperature and rotating speed.In order to prepare the wax emulsion of shelf-stable, the selection of emulsifying agent and the control of stir speed (S.S.) are very crucial.
Another feed composition of mold release compositions system external release agent or inner pattern releasing agent applicable is fatty acid ester, phosphoric acid ester and its esters.The alkyl carbon atoms number of fatty acid ester will be between 12-40, and solid or liquid all can.Can select the copolymer mixture of oleic acid monooctyl ester, octyl stearate, butyl oleate, butyl stearate, linolic acid monooctyl ester, linolic acid butyl ester and oleic acid or stearic acid and methyl acrylate or butyl acrylate.Phosphoric acid ester comprises phosphoric acid ester or their an alkali metal salts such as di (isooctyl) phosphate, Tryfac 5573, dilauryl phosphoric acid ester, hexadecanyl phosphate.Above-mentioned substance can select several materials composite to together, can make emulsion in advance, mixes in joining the wax emulsion, perhaps adds in the preparation wax emulsion stage, finally obtains the emulsion of shelf-stable.
Mold release compositions system of the present invention can guarantee that again wood-based plate is from the surface of heating platen or the demoulding fully of travelling belt surface under the bond properties prerequisite that guarantees the polyisocyanates excellence.
Four, embodiment
Embodiment 1:
1. the feed composition of mold release compositions system external release agent, inner pattern releasing agent applicable
The feed composition of external release agent is: (A) wax emulsion, (B) one or both mixture in fatty acid ester, phosphoric acid ester and its esters, the weight of wax emulsion is 20% in mold release compositions, and the mixture weight of one or both in fatty acid ester, phosphoric acid ester and its esters is 80% in mold release compositions; The solid content of external release agent is 2%; Wax in the wax emulsion is selected from vegetable wax, and emulsifying agent uses the dodecyl sulphate potassium in the anionic emulsifier, and fatty acid ester selects the copolymer mixture of oleic acid and butyl acrylate, and phosphoric acid ester (salt) class can be selected di-isooctyl.
The feed composition of inner pattern releasing agent applicable is: (A) wax emulsion, (B) one or both mixture in fatty acid ester, phosphoric acid ester and its esters, the weight of wax emulsion is 60% in mold release compositions, and the mixture weight of one or both in fatty acid ester, phosphoric acid ester and its esters is 40% in mold release compositions; The solid content of inner pattern releasing agent applicable is 10%; Wax in the wax emulsion is selected from vegetable wax, and emulsifying agent uses the dodecyl sulphate potassium in the anionic emulsifier, and fatty acid ester selects the copolymer mixture of oleic acid and butyl acrylate, and phosphoric acid ester (salt) class can be selected di-isooctyl.
2. the preparation technology of mold release compositions system external release agent or inner pattern releasing agent applicable
(1), the preparation of wax emulsion
Earlier a certain amount of Wax, water and emulsifying agent are joined in the emulsor, elevated temperature keeps certain temperature to 80-130 ℃ in 30min, after continuously stirring 1-2 hour, high-speed stirring 10min, stirring at low speed again, and logical water quench is to room temperature, static storage;
(2), the preparation of one or both mixture in fatty acid ester, phosphoric acid ester and its esters
A certain amount of oleic acid, butyl acrylate and polymerizing catalyst are joined in the reactor, and polymerizing catalyst is a peroxidation benzene first, and high-speed stirring and elevated temperature reacted 3-6 hour to 100-170 ℃, can make the oily liquids of homogeneous.Di-isooctyl and an amount of water are joined oily liquids, stirred 1-2 hour under the certain temperature, can obtain stable emulsion;
(3), the wax emulsion is joined in the above-mentioned emulsion, stir for some time, promptly obtain the releasing agent emulsion of shelf-stable.
3. the evaluation of stripping result
The wheat straw or the wood particle that crush are divided by the watch core layer, and thin wheat straw or wood particle are used in the top layer, and sandwich layer uses thick wheat straw or wood shavings.At first the top layer material is put into the glue mixer that has the glue spraying head that atomizes, the PM-200 that measures is sprayed application in wheat straw or the wood particle, stir.Resin added is 3% of over dry wheat straw or a wood shavings amount.Use the same method, spray PM-200 in sandwich layer wheat straw or wood particle, consumption is 3% of over dry wheat straw or a wood shavings amount, obtains having mixed the core layer material of glue.Coat releasing agent at the upper and lower steel plate of press respectively, releasing agent consumption (pressing solid content calculates) is 1.3g/m
2Top layer material, the core layer material of having mixed glue are mated formation on steel plate first precompressed, hot repressing, 170 ℃ of hot pressing temperatures, hot pressing time 17s/mm, pressure 3.5Mpa.After hot pressing is intact, take sheet material away, observe the wood shavings particulate situation that is bonded on the metal platen, estimate the stripping result of releasing agent.Be coated with releasing agent one time, its continuous stripping result is listed in table 1.
Table 1
| Plate number | The top board stripping result | The press table stripping result |
| 1 | 5 | 5 |
| 2 | 5 | 5 |
| 3 | 5 | 5 |
| 4 | 5 | 5 |
| 5 | 5 | 4.5 |
| 6 | 5 | 4.5 |
| 7 | 4.5 | 4.5 |
| 8 | 4.5 | 4 |
| 9 | 4 | 4 |
| 10 | 4 | 3 |
| 11 | 3 | 3 |
Standards of grading are estimated according to what and the complexity of taking out plate that are bonded at wood shavings amount on the metal platen, represented the complete demoulding in 5 minutes, the wood shavings bits that do not have adhesion, slightly be stained with a small amount of wood shavings bits in 4 minutes, take out not difficultly, be stained with more wood shavings bits in 3 minutes, take out difficulty, 2 fens local haftplattes, 1 fen complete haftplatte.
Embodiment 2:
1. the feed composition of mold release compositions system external release agent, inner pattern releasing agent applicable
The feed composition of external release agent is: (A) wax emulsion, (B) a kind of ester class in fatty acid ester, phosphoric acid ester and its esters or the mixture of two kinds of ester classes, the weight of wax emulsion is preferably 40% in mold release compositions, one or both mixture weight is preferably 60% in fatty acid ester, phosphoric acid ester and its esters in mold release compositions; The solid content of external release agent is 19%; Wax in the wax emulsion is selected from synthetic wax, and emulsifying agent uses the palmityl trimethyl ammonium chloride of cationic emulsifier, and fatty acid ester selects butyl oleate, and phosphoric acid ester (salt) class can be selected the dilauryl phosphoric acid ester.
The feed composition of inner pattern releasing agent applicable is: (A) wax emulsion, (B) one or both mixture in fatty acid ester, phosphoric acid ester and its esters, the weight of wax emulsion is preferably 80% in mold release compositions, one or both mixture weight is preferably 20% in fatty acid ester, phosphoric acid ester and its esters in mold release compositions; The solid content of inner pattern releasing agent applicable is 28%; Wax in the wax emulsion is selected from synthetic wax, and emulsifying agent uses the palmityl trimethyl ammonium chloride of cationic emulsifier, and fatty acid ester selects butyl oleate, and phosphoric acid ester (salt) class can be selected the dilauryl phosphoric acid ester.
2. the preparation technology of mold release compositions system external release agent or inner pattern releasing agent applicable
(1), the preparation of wax emulsion
Earlier a certain amount of Wax, water and emulsifying agent are joined in the emulsor, elevated temperature keeps certain temperature to 80-130 ℃ in 30min, after continuously stirring 1-2 hour, high-speed stirring 10min, stirring at low speed again, and logical water quench is to room temperature, static storage;
(2), the preparation of one or both mixture in fatty acid ester, phosphoric acid ester and its esters
A certain amount of butyl oleate is joined in the reactor, and high-speed stirring and elevated temperature reacted 3-6 hour to 100-170 ℃, can make the oily liquids of homogeneous.Dilauryl phosphoric acid ester and an amount of water are joined oily liquids, stirred 1-2 hour under the certain temperature, can obtain stable emulsion;
(3), the wax emulsion is joined in the above-mentioned emulsion, stir for some time, promptly obtain the releasing agent emulsion of shelf-stable.
3. the evaluation of stripping result
The wheat straw or the wood particle that crush are divided by the watch core layer, and thin wheat straw or wood particle are used in the top layer, and sandwich layer uses thick wheat straw or wood shavings.At first the top layer material is put into the glue mixer that has the glue spraying head that atomizes, PM-200 and the inner pattern releasing agent applicable composition that measures sprayed application in wheat straw or the wood particle, stir.Resin added is 3% of over dry wheat straw or a wood shavings amount, and the releasing agent consumption is 0.5% of over dry wheat straw or wood shavings.Use the same method, but do not add releasing agent, spray PM-200, consumption is 3% of over dry wheat straw or a wood shavings amount, obtains having mixed the core layer material of glue.Coat external release agent at the upper and lower steel plate of press respectively, releasing agent consumption (pressing solid content calculates) is 1.3g/m
2Top layer material, the core layer material of having mixed glue are mated formation on steel plate first precompressed, hot repressing, 170 ℃ of hot pressing temperatures, hot pressing time 17s/mm, pressure 3.5MPa.After hot pressing is intact, take sheet material away, observe the wood shavings particulate situation that is bonded on the metal platen, estimate the stripping result of releasing agent.Be coated with releasing agent one time, its continuous stripping result is listed in table 2.
Table 2
| Plate number | The top board stripping result | The press table stripping result |
| 1 | 5 | 5 |
| 2 | 5 | 5 |
| 3 | 5 | 5 |
| 4 | 5 | 5 |
| 5 | 5 | 5 |
| 6 | 5 | 5 |
| 7 | 5 | 5 |
| 8 | 5 | 4.5 |
| 9 | 5 | 4.5 |
| 10 | 4.5 | 4.5 |
| 11 | 4 | 4 |
| 12 | 4 | 4 |
| 13 | 4 | 4 |
| 14 | 4 | 4 |
| 15 | 4 | 4 |
| 16 | 4 | 4 |
| 17 | 4 | 4 |
| 18 | 4 | 3 |
| 19 | 4 | 3 |
| 20 | 3 | 3 |
Embodiment 3:
1. the feed composition of mold release compositions system external release agent, inner pattern releasing agent applicable
The feed composition of external release agent is: (A) wax emulsion, (B) a kind of ester class in fatty acid ester, phosphoric acid ester and its esters or the mixture of two kinds of ester classes, the weight of wax emulsion is preferably 30% in mold release compositions, the mixture weight of one or both in fatty acid ester, phosphoric acid ester and its esters is preferably 70% in mold release compositions; The solid content of external release agent is 10%; Wax in the wax emulsion is selected from mineral wax, and emulsifying agent uses nonionic emulsifier polyoxyethylene carboxylicesters, and fatty acid ester selects the linolic acid monooctyl ester, and phosphoric acid ester (salt) class can be selected hexadecanyl phosphate.
The feed composition of inner pattern releasing agent applicable is: (A) wax emulsion, (B) one or both mixture in fatty acid ester, phosphoric acid ester and its esters, the weight of wax emulsion is preferably 70% in mold release compositions, one or both mixture weight is preferably 30% in fatty acid ester, phosphoric acid ester and its esters in mold release compositions; The solid content of inner pattern releasing agent applicable is 40%; Wax in the wax emulsion is selected from mineral wax, and emulsifying agent uses nonionic emulsifier polyoxyethylene carboxylicesters, and fatty acid ester selects the linolic acid monooctyl ester, and phosphoric acid ester (salt) class can be selected hexadecanyl phosphate.
2. the preparation technology of mold release compositions system external release agent or inner pattern releasing agent applicable
(1), the preparation of wax emulsion
Earlier a certain amount of Wax, water and emulsifying agent are joined in the emulsor, elevated temperature keeps certain temperature to 80-130 ℃ in 30min, after continuously stirring 1-2 hour, high-speed stirring 10min, stirring at low speed again, and logical water quench is to room temperature, static storage;
(2), the preparation of one or both mixture in fatty acid ester, phosphoric acid ester and its esters
A certain amount of linolic acid monooctyl ester is joined in the reactor, and high-speed stirring and elevated temperature reacted 3-6 hour to 100-170 ℃, can make the oily liquids of homogeneous.Hexadecanyl phosphate and an amount of water are joined oily liquids, stirred 1-2 hour under the certain temperature, can obtain stable emulsion;
(3), the wax emulsion is joined in the above-mentioned emulsion, stir for some time, promptly obtain the releasing agent emulsion of shelf-stable.
3. the evaluation of stripping result
Judgement criteria is with embodiment 2.The present invention is not limited to the foregoing description, other does not depart from the embodiment of spirit of the present invention, practice by a series of as above embodiment, observation is bonded at the wood shavings particulate situation on the metal platen, all can draw the stripping result of above-mentioned evaluation releasing agent, thereby realize goal of the invention of the present invention.
Claims (8)
1, is used to prepare the mold release compositions system of polyisocyanic acid ester gum wood-based plate, the external release agent or the product of inner pattern releasing agent applicable that it is characterized in that the mold release compositions system: (A) wax emulsion, (B) one or both mixture in fatty acid ester, phosphoric acid ester and its esters for adopting following raw material components to make; The weight of the wax emulsion of mold release compositions system external release agent is no more than 50% in mold release compositions, one or both mixture weight is not less than 50% in fatty acid ester, phosphoric acid ester and its esters in mold release compositions; The weight of the wax emulsion of mold release compositions system inner pattern releasing agent applicable is not less than 50% in mold release compositions, a kind of ester class in fatty acid ester, phosphoric acid ester and its esters or the mixture weight of two kinds of ester classes are not higher than 50% in mold release compositions.
2, according to the described mold release compositions system that is used to prepare polyisocyanic acid ester gum wood-based plate of claim 1, the weight that it is characterized in that the wax emulsion of mold release compositions system external release agent is 20-40% in mold release compositions, one or both mixture weight is 60-80% in mold release compositions in fatty acid ester, phosphoric acid ester and its esters.
3,, it is characterized in that the solid content of external release agent accounts for the weight percent 1-20% of external release agent for it according to claim 1 or the 2 described mold release compositions systems that are used to prepare polyisocyanic acid ester gum wood-based plate.
4, according to the described mold release compositions system that is used to prepare polyisocyanic acid ester gum wood-based plate of claim 1, the weight that it is characterized in that the wax emulsion of mold release compositions system inner pattern releasing agent applicable is 60-80% in mold release compositions, one or both mixture weight is 20-40% in mold release compositions in fatty acid ester, phosphoric acid ester and its esters.
5,, it is characterized in that the solid content of inner pattern releasing agent applicable accounts for the weight percent 10-40% of inner pattern releasing agent applicable for it according to claim 1 or the 4 described mold release compositions systems that are used to prepare polyisocyanic acid ester gum wood-based plate.
6,, it is characterized in that wax in the wax emulsion is selected from a kind of in following: vegetable wax, animal wax, mineral wax, synthetic wax and other fusing point wax class between 40 ℃-170 ℃ according to the described mold release compositions system that is used to prepare polyisocyanic acid ester gum wood-based plate of claim 1; Fatty acid ester is selected from a kind of in following: the copolymer mixture of oleic acid monooctyl ester, octyl stearate, butyl oleate, butyl stearate, linolic acid monooctyl ester, linolic acid butyl ester and oleic acid/stearic acid and methyl acrylate/butyl acrylate; Phosphoric acid ester (salt) class is selected from a kind of in following: di (isooctyl) phosphate, Tryfac 5573, dilauryl phosphoric acid ester, hexadecanyl phosphate, double hexadecyl acid ester, octadecyl phosphoric acid ester, two octadecyl phosphoric acid ester and corresponding metal-salt.
7, be used to prepare the preparation technology of the mold release compositions system of polyisocyanic acid ester gum wood-based plate, the external release agent or the inner pattern releasing agent applicable preparation that it is characterized in that its mold release compositions system may further comprise the steps: the preparation of a, wax emulsion: Wax, water and emulsifying agent are joined in the emulsor, heat up, stir, the water flowing cool to room temperature, static storage; The preparation of a kind of ester class in b, fatty acid ester, phosphoric acid ester and its esters or the copolymer mixture of two kinds of ester classes: in fatty acid ester and its esters one or both are joined in the reactor, stir, react oily liquids, phosphoric acid ester and an amount of water are added, stir stable emulsion; C, above-mentioned wax emulsion are mixed by following requirement with copolymer mixture and obtained mold release compositions system external release agent and inner pattern releasing agent applicable: 1. the weight of the wax emulsion of external release agent is no more than 50% in mold release compositions, and one or both mixture weight is not less than 50% in fatty acid ester, phosphoric acid ester and its esters in mold release compositions; 2. the solid content of external release agent accounts for the weight percent 1-20% of external release agent for it; 3. the weight of the wax emulsion of inner pattern releasing agent applicable is not less than 50% in mold release compositions, and a kind of ester class in fatty acid ester, phosphoric acid ester and its esters or the mixture weight of two kinds of ester classes are not higher than 50% in mold release compositions; 4. the solid content of inner pattern releasing agent applicable accounts for the weight percent 10-40% of inner pattern releasing agent applicable for it.
8, according to the described preparation technology who is used to prepare the external release agent of polyisocyanic acid ester gum wood-based plate of claim 7, it is characterized in that the emulsifying agent in the described wax emulsion preparation uses anionic emulsifier, cationic emulsifier, nonionic emulsifier or amphoteric emulsifier, the wax emulsion can be made emulsion in advance with mixing of copolymer mixture, join again in the wax emulsion and mix, perhaps add, finally obtain the emulsion of shelf-stable in the preparation wax emulsion stage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310105756 CN1239686C (en) | 2003-11-29 | 2003-11-29 | Demoulding composition system for preparing polyisocyanate adhesive artificial board and process for preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310105756 CN1239686C (en) | 2003-11-29 | 2003-11-29 | Demoulding composition system for preparing polyisocyanate adhesive artificial board and process for preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1546621A CN1546621A (en) | 2004-11-17 |
| CN1239686C true CN1239686C (en) | 2006-02-01 |
Family
ID=34333887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310105756 Expired - Lifetime CN1239686C (en) | 2003-11-29 | 2003-11-29 | Demoulding composition system for preparing polyisocyanate adhesive artificial board and process for preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1239686C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103409218B (en) * | 2013-07-17 | 2015-04-22 | 安徽中铁工程材料科技有限公司 | Concrete mold release agent and preparation method thereof |
| CN104498161A (en) * | 2014-12-18 | 2015-04-08 | 蒙城县科技创业服务中心 | Concrete release agent prepared from animal fat |
| CN106281192B (en) | 2015-05-15 | 2019-05-14 | 万华禾香板业有限责任公司 | A kind of emulsifiable isocyanate composition and preparation method thereof |
| CN105602467B (en) * | 2016-01-28 | 2017-10-31 | 江西绿丰新材料股份有限公司 | Releasing agent for isocyanate adhesive and preparation method thereof |
| CN108326228B (en) * | 2018-02-07 | 2019-11-29 | 广州采润新材料有限公司 | Aqueous release agent and preparation method thereof for anodized aluminum alloy die casting thin pieces |
| CN113103396B (en) * | 2020-01-13 | 2023-01-13 | 万华化学集团股份有限公司 | Artificial board without aldehyde addition and manufacturing method thereof |
| CN113352511A (en) * | 2021-05-28 | 2021-09-07 | 南京理工大学 | Release agent and preparation method and application thereof |
-
2003
- 2003-11-29 CN CN 200310105756 patent/CN1239686C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1546621A (en) | 2004-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1235977C (en) | PMDI wood binders containing hydrophobic diluents | |
| US4110397A (en) | Composite bodies or sheets | |
| US10669424B2 (en) | Lignocellulosic composite articles | |
| CN1140105A (en) | Method of producing coating on reconstituted wood substrate | |
| CN102643556B (en) | Energy-conservation wood-plastic composite panel of new green environment protection for auto carriage board and preparation method thereof | |
| CN1079412C (en) | Self release binder system | |
| CA2547751A1 (en) | Wax emulsion for manufacture of composite boards | |
| CN1239686C (en) | Demoulding composition system for preparing polyisocyanate adhesive artificial board and process for preparation thereof | |
| JPS63165101A (en) | Quick curing phenol group resin | |
| CN103732710A (en) | Adhesive additive | |
| US20030165669A1 (en) | Precure consolidator | |
| US8882898B2 (en) | Emulsified release agent for composite panel | |
| CN105922427A (en) | Zero-formaldehyde particle board and preparation method thereof | |
| WO1990015834A1 (en) | Binder composition for chip like and/or fibrous material | |
| US8309503B2 (en) | Release agent for composite panel | |
| CN102241845A (en) | Composite material prepared by utilizing waste and preparation method thereof | |
| CN1761701A (en) | Adhesive composition | |
| KR101104532B1 (en) | Mold release agent composition for thermocompression molding and process for producing board | |
| JPS63153102A (en) | Method of bonding lignocellulose group material | |
| CN106118549A (en) | Solid gum | |
| CA2362750A1 (en) | Processes for preparing molded composite material and wax-based release agents | |
| JP4845535B2 (en) | Release agent composition for hot pressing and method for producing board | |
| CN106189948A (en) | Pur | |
| CN106182327A (en) | A kind of zero formaldehyde bamboo shaving plate and preparation method thereof | |
| MXPA02007710A (en) | Fatty acid and polyolefin wax release agent. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: WANHUA CHEMICAL GROUP CO., LTD. Free format text: FORMER NAME: YANTAI WANHUA POLYURETHANE CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 264002 Yantai City, Shandong province Zhifu District No. 7 Patentee after: Wanhua Chemical Group Co.,Ltd. Address before: 265616 No. 7 happy South Road, western suburbs, Shandong, Yantai Patentee before: YANTAI WANHUA POLYURETHANES Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180214 Address after: 102200 No. 5, Spark Street, Changping District science and Technology Park, Beijing Patentee after: WANHUA ECOBOARD Co.,Ltd. Address before: 264002 Yantai City, Shandong province Zhifu District No. 7 Patentee before: Wanhua Chemical Group Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180905 Address after: 434000 Hubei, Jingzhou, Gongan County, Qinghai Industrial Park, east of Xingye Road, south of Minsheng Road. Patentee after: Wanhua Hexiang Board Industry Co.,Ltd. Address before: No. 5, star fire street, Beijing Changping District science and Technology Park, Beijing Patentee before: WANHUA ECOBOARD Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230220 Address after: 464000 South of Weibei 1st Road and east of Jingbei 8th Road, Home Town, Yangshan New District, Xinyang City, Henan Province Patentee after: Wanhua Hexiang Group Co.,Ltd. Address before: East of Xingye Road and south of Minsheng Road, Qingji Industrial Park, Gong'an County, Jingzhou City, Hubei Province Patentee before: Wanhua Hexiang Board Industry Co.,Ltd. |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20060201 |