CN1237549A - Composite cement - Google Patents
Composite cement Download PDFInfo
- Publication number
- CN1237549A CN1237549A CN99109932A CN99109932A CN1237549A CN 1237549 A CN1237549 A CN 1237549A CN 99109932 A CN99109932 A CN 99109932A CN 99109932 A CN99109932 A CN 99109932A CN 1237549 A CN1237549 A CN 1237549A
- Authority
- CN
- China
- Prior art keywords
- cement
- compound
- gypsum
- complex cement
- exciting agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The present invention relates to a composite cement made up by using (wt%) 23%-45% of cement clinker, 4-5% of gypsum, 42-66.5% of mixture material formed from slag and pulverized fuel ash and 6-10% of calcium hydroxide and sodium carbonate mixture throug a certain mixing process. Said invention can effectively raise the early-strength and after-strength of the composite cement, improve the toughness and brittleness of cement, raise the crack resistance of concrete and greatly reduce the production cost of the cement.
Description
The present invention relates to a kind of complex cement, particularly a kind of admixture has a large amount of flyash and scoriaceous cement.
Flyash is a large amount of refuses of discharging of modern industry boiler, and its harm to environment is well-known, and people make a large amount of effort in the hope of it is turned waste into wealth as the gelling material in the cement for this reason, and one can reduce environmental pollution; Two can reduce cement cost, as Chinese patent CN1063856A, a kind of rehydration mud and adulterating agent thereof were just once disclosed, in this complex cement admixture a large amount of flyash, made good try, but it is poor that this invention does not solve toughness that cement had and fragility that the prior art that comprises Portland cement produces, thereby make poor, the easy fissured difficult problem of crack-resistant performance of concrete, and can this invention do not add the later strength that improve cement yet and indicate.
The objective of the invention is to overcome above-mentioned shortcoming, provide a kind of new admixture coal ash in a large number and in early days, later stage strength of cement and bending and compressive strength be improved, cement toughness and fragility are significantly improved, thereby also can effectively improve the NEW TYPE OF COMPOSITE cement of crack-resistant performance of concrete.
The solution of the present invention is such:
A kind of complex cement, formulated by cement clinker, gypsum mixture and exciting agent, wherein compound is made by slag and flyash, and exciting agent is by calcium hydroxide [Ca (OH)
2] and yellow soda ash (NaCO
3) make.
The proportion relation of complex cement is as follows:
1. No. 525 Portland clinker 23-45%
2. compound is 42-66.5%
Wherein: slag is the 40-60% of compound gross weight
Flyash is the 60-40% of compound gross weight
The cement that the present invention produced, not only flyash mixed dosage is big, and early stage, the later strength of cement all be higher than the complex cement with label, and can improve the toughness of cement, reduces its fragility, thereby improves concrete resistance to cleavage, reduces the crack.
Test case is as follows:
1. hydration heat is low, and 7 days thermal value is respectively 219.9 and 205KJ/KG, and 230KJ/KG is low than the low-heat slag cement.
2. intensity index (F represents slag in the table, and S represents flyash) as shown in the table:
28 days intensity indexs
Numbering | Grog (%) | Mixing material volume (F+s) | Exciting agent (%) | Folding strength (MPa) | Ultimate compression strength (MPa) | |||||
3 days | 7 days | 28 days | 3 days | 7 days | 28 days | |||||
????1 | ?25 | ?????????66.5% | ????8 | ????6.5 | ????7.6 | ??9.3 | ??26.3 | ??33.2 | ??50.1 | |
???F60% | S40% | |||||||||
????2 | ?35 | ?????????60% | ????8 | ????6.9 | ????8.8 | ??10.0 | ??32.4 | ??38.1 | ??55.2 | |
???F40% | S60% | |||||||||
????3 | ?45 | ?????????50% | ????8 | ????5.1 | ????6.8 | ??9.5 | ??28.8 | ??38.8 | ??52.2 | |
???F60% | S40% |
Embodiment 1: with accounting for No. 525 Portland clinkers of gross weight 25%, by be mixed 66.5% compound of general cement production process, 5% gypsum and 8% exciting agent can be produced complex cement No. 325.
Embodiment 2: with No. 525 Portland clinkers that account for gross weight 35%, the compound of admixture 60%, 5% gypsum and 8% exciting agent can be used for producing complex cement No. 425.
Embodiment 3: with No. 525 Portland clinkers that account for gross weight 45%, 50% compound, 5% gypsum and 8% exciting agent can be produced complex cement No. 525.
Claims (5)
1. complex cement by cement clinker, gypsum, compound and exciting agent preparation, is characterized in that compound made by slag and flyash, and the exciting agent major ingredient is calcium hydroxide [Ca (OH)
2] and yellow soda ash (NaCO
3).
2. complex cement according to claim 1 is characterized in that the prescription of complex cement is:
1. No. 525 Portland clinker 23-45%
2. compound is 42-66.5
Wherein: slag is the 40-60% of compound gross weight
Flyash is the 60-40% of compound gross weight
3. gypsum 4-5%
4. exciting agent 6-10%
Wherein: calcium hydroxide [Ca (OH)
2] be 60%, yellow soda ash (NaCO
3) be 40%
3. complex cement according to claim 2 is characterized in that: account for No. 525 Portland clinkers of gross weight 25%, admixture compound 66.5%; Gypsum 5%, exciting agent 8% is used to produce complex cement No. 325.
4. complex cement according to claim 2 is characterized in that accounting for No. 525 Portland clinkers of gross weight 35%, and the compound of admixture 60%, 5% gypsum and 8% exciting agent are used to produce complex cement No. 425.
5. complex cement according to claim 2 is characterized in that compound, 5% gypsum and 8% the exciting agent of No. 525 Portland clinker admixtures 50% of gross weight 45% being used to produce complex cement No. 525.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN99109932A CN1110460C (en) | 1999-06-25 | 1999-06-25 | Composite cement |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN99109932A CN1110460C (en) | 1999-06-25 | 1999-06-25 | Composite cement |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1237549A true CN1237549A (en) | 1999-12-08 |
CN1110460C CN1110460C (en) | 2003-06-04 |
Family
ID=5274252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99109932A Expired - Fee Related CN1110460C (en) | 1999-06-25 | 1999-06-25 | Composite cement |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1110460C (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100450949C (en) * | 2006-08-15 | 2009-01-14 | 中国石油天然气集团公司 | High-activity alkali ore slag fly ash inorganic polymer gel material and manufacturing method thereof |
CN100457662C (en) * | 2002-10-14 | 2009-02-04 | 吴发辉 | Method for producing compound cement blended directly with separated flyash and the made compound cement thereby |
CN102701777A (en) * | 2012-05-29 | 2012-10-03 | 山东京博控股股份有限公司 | Method for preparing high strength structural brick |
CN103880309A (en) * | 2014-02-20 | 2014-06-25 | 辽宁石化职业技术学院 | Portland fly-ash cement and preparation method thereof |
CN105272070A (en) * | 2015-11-23 | 2016-01-27 | 湖南联智桥隧技术有限公司 | Cement grouting material |
CN106277869A (en) * | 2016-08-31 | 2017-01-04 | 高州市新力水泥制品有限公司 | A kind of wear-resisting cement and application thereof |
CN108455885A (en) * | 2017-12-28 | 2018-08-28 | 主义 | A kind of composite Portland cement and the preparation method and application thereof |
CN110746167A (en) * | 2019-09-16 | 2020-02-04 | 福州市宇心建材科技有限公司 | Antirust environment-friendly cement-based material and preparation method and application thereof |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1012951B (en) * | 1987-02-18 | 1991-06-26 | 云南省建筑材料科学研究设计院 | Process for producing cement by hypercalcium powdered coal ash |
CN1029116C (en) * | 1988-01-21 | 1995-06-28 | 国家建材局苏州混凝土水泥制品研究院 | Method of excitation of the activity of powdery cinder |
CN1036940A (en) * | 1988-04-13 | 1989-11-08 | 李绍模 | The compound method of high-strength special pulverized fuel ash cement and compound thereof early |
CN1068554A (en) * | 1992-06-13 | 1993-02-03 | 河北省东光县水泥厂 | A kind of alkali exciting slag cement and method for making |
CN1029469C (en) * | 1992-09-29 | 1995-08-09 | 武汉工业大学 | Method for mfg. cement with highearly strength and high slag content |
-
1999
- 1999-06-25 CN CN99109932A patent/CN1110460C/en not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100457662C (en) * | 2002-10-14 | 2009-02-04 | 吴发辉 | Method for producing compound cement blended directly with separated flyash and the made compound cement thereby |
CN100450949C (en) * | 2006-08-15 | 2009-01-14 | 中国石油天然气集团公司 | High-activity alkali ore slag fly ash inorganic polymer gel material and manufacturing method thereof |
CN102701777A (en) * | 2012-05-29 | 2012-10-03 | 山东京博控股股份有限公司 | Method for preparing high strength structural brick |
CN102701777B (en) * | 2012-05-29 | 2014-03-05 | 山东京博控股股份有限公司 | Method for preparing high strength structural brick |
CN103880309A (en) * | 2014-02-20 | 2014-06-25 | 辽宁石化职业技术学院 | Portland fly-ash cement and preparation method thereof |
CN103880309B (en) * | 2014-02-20 | 2016-01-06 | 辽宁石化职业技术学院 | A kind of Portland fly ash cement and preparation method thereof |
CN105272070A (en) * | 2015-11-23 | 2016-01-27 | 湖南联智桥隧技术有限公司 | Cement grouting material |
CN106277869A (en) * | 2016-08-31 | 2017-01-04 | 高州市新力水泥制品有限公司 | A kind of wear-resisting cement and application thereof |
CN108455885A (en) * | 2017-12-28 | 2018-08-28 | 主义 | A kind of composite Portland cement and the preparation method and application thereof |
CN108455885B (en) * | 2017-12-28 | 2021-05-18 | 承德金隅水泥有限责任公司 | Composite portland cement and preparation method and application thereof |
CN110746167A (en) * | 2019-09-16 | 2020-02-04 | 福州市宇心建材科技有限公司 | Antirust environment-friendly cement-based material and preparation method and application thereof |
CN110746167B (en) * | 2019-09-16 | 2021-09-07 | 福州市宇心建材科技有限公司 | Antirust environment-friendly cement-based material and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CN1110460C (en) | 2003-06-04 |
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