CN1233416A - Oil-in-water type emulsion liquid - Google Patents
Oil-in-water type emulsion liquid Download PDFInfo
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- CN1233416A CN1233416A CN99100684A CN99100684A CN1233416A CN 1233416 A CN1233416 A CN 1233416A CN 99100684 A CN99100684 A CN 99100684A CN 99100684 A CN99100684 A CN 99100684A CN 1233416 A CN1233416 A CN 1233416A
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Abstract
The invention provides an oil-in-water type emulsion liquid having both resistance to refrigeration and thawing and resistance to heat, especially acidity oil-in-water type emulsion liquid is suitable for frozen food. This acidic O/W emulsion is produced by including (A) 8-50 wt.% oil phase; (B) 1-15 wt.% yolk of an egg treated with enzymes and (C) 20-80 wt.% aqueous phase.
Description
The present invention relates to oil-in-water emulsion, the acid oil-in-water emulsified thing that relates to mayonnaise, mustard mayonnaise, oil-in-water type sauce etc. in detail, even relate in more detail thaw after freezing and then heat, oil-in-water type emulsion has also that anti-freeze is thawed and the acid oil-in-water emulsified thing of anti-heating property.
The seasonings of using as food, the acid oil-in-water emulsified thing that mayonnaise that the egg raw material, vinegar, seasonings etc. of grease, yolk and shell egg and albumen etc. make for main raw material, mustard mayonnaise, oil-in-water type sauce etc. are arranged, these emulsifications also are being widely used at system dessert, system salad product except utilizing on the home cooking of fast food, salad etc., in recent years because the popularizing of food product refrigeration development of technology and microwave oven, and develop various frozen product, and on market, sell.In these frozen product, there are in the food flavouring with the poultry meat of freezing fried class or fish a red-spotted lizard class and mayonnaise, mustard mayonnaise etc. to wrap in the food two kinds of refrigerated again after adding packing back refrigerated and being added in the food flavouring of mayonnaise, mustard yolk, oil-in-water type sauce etc. on the food in advance.These food can be directly under the refrigerated state with fried or with baking oven barbecue, microwave oven heating under just edible, very convenient.
; the acid oil-in-water emulsified thing of common mayonnaise, mustard mayonnaise, oil-in-water type sauce etc.; when behind freezing, thawing, because the starting material, the particularly freezing denaturation of egg raw material that use, and make oil-in-water type emulsion stability unstable; and then when once heating by freezing state; the rising of moisture and the heat denatured of raw material, and cause that oil-in-water emulsifiers is destroyed, its result; oil content leaves, and influences outward appearance, sense of food, the local flavor of food significantly.When particularly heating with microwave oven, because microwave, food temperature sharply rises in several minutes, and moisture evaporates significantly, has also caused heat denatured, makes oil-in-water type emulsion further be damaged.
In order to address these problems, the scheme of various oil-in-water emulsions has been proposed, for example, the oil phase raw material that adds method (special public clear 53-44426 communique) with the phospholipoprotein matter of Phospholipid hydrolase modification, the method for using the part of trypsin treatment to add water decomposition yolk to make aqueous materials and oiliness emulsifying raw material (special fair 5-47186 communique), a part uses extremely the method for winterized stearin (the public clear 62-25340 communique of spy) etc.
, these methods are when being short period of time about several weeks between pool period, the anti-performance of thawing after freezing is good, but long more between pool period, because the freezing denaturation through day of the raw material that uses, oil-in-water type emulsion stability is reported to the leadship after accomplishing a task, behind the freeze-thaw, have to produce separating of oil tendency.And then owing to continue heating, oil-in-water type emulsion is destroyed significantly, and oil is separated fully, so, satisfy cold-resistant freeze thawing property and anti-heating property two aspect the part that still has some deficits.
The object of the present invention is to provide the acid oil-in-water emulsified thing of oil-in-water emulsion, particularly mayonnaise, mustard mayonnaise, oil-in-water type sauce etc., the frozen product after even oil-in-water emulsion that this emulsification moisture ratio is higher or use are long-time freezing, this oil-in-water type emulsion also is stable when freeze-thaw, even and then continue heating, because oil-in-water type emulsion is stable also can not cause oil separating.
Present inventors have carried out research with keen determination for existing the problems referred to above of acid oil-in-water emulsified thing of mayonnaise, mustard mayonnaise, oil-in-water type sauce etc., consequently, by specific material combination, can achieve the above object, thereby finish the present invention.
The present invention is based on above-mentioned opinion and finishes, and oil-in-water emulsion is provided, and it is characterized in that containing 8～50 weight % oil phases, 1～15 weight % enzyme processing yolk and 20～80 weight % waters.
Oil-in-water emulsion of the present invention has cold-resistant thawing property and the thermotolerance of freezing, and particularly acid oil-in-water emulsified thing is more suitable for the purposes of frozen product.
The raw material that oil-in-water emulsion of the present invention uses, be by with the yolk after phospholipase A and the protease treatment, so can provide from freezing back thawed state stable acid oil-in-water emulsified thing when heating with microwave oven, this technology is very difficult in the past.
Oil phase used in the present invention is to use grease, as long as the grease that is adapted to eat as this grease, for example the normal temperature of soybean oil, rapeseed oil, Semen Maydis oil, Oleum Gossypii semen, sweet oil, peanut oil, rice bran oil, Thistle oil, Sunflower Receptacle wet goods is the general grease of liquid down, and then do not get rid of solid greases at normal temperatures such as using plam oil, palm kernel oil, cocounut oil, ape consistent lubricant (サ Le fat), mango butter, butterfat yet, also can use through the grease of physical or chemical treatment for example winterized stearin, separating oil, transesterify wet goods.
As preferred oil phase be contain by saturated fatty acid 1 residue and the oil phase of the unsaturated fatty acids 2 residues tri-glyceride that constitute of the above carbon number of 1.5 weight % more than 20, more preferably contain more than the 1.5 weight % below the 15 weight %, saturated fatty acid 1 residue and the unsaturated fatty acids 2 residues oil phase that constitute of the carbon number below the 15 weight % more than 20 more than the 2 weight % most preferably.The saturated fatty acid of said carbon number more than 20 is eicosanoic acid, docosoic, 24 (alkane) acid etc. among the present invention.Can enumerate oleic acid, linolic acid, linolenic acid etc. as unsaturated fatty acids.But be not subjected to above restriction.The binding site of the saturated fatty acid residues of carbon number more than 20 is any position of 1,2,3 of tri-glyceride.
For example, when oil phase uses the salad oil of common mayonnaise class sauce class, because when freezing, water solidifies, volume expansion, makes liquid oil phase be subjected to compressing, distortion, aggegation mutually, oil phase separate easily when thawing.
In contrast, if in oil phase, cooperate saturated fatty acid 1 residue of carbon number more than 20 and the tri-glyceride of unsaturated fatty acids 2 residues formation, when freezing, oil phase becomes fine crystallization, even the water setting expansion, oil phase also can keep fine crystallization, do not deform, when it is thawed, just oil phase fusion, emulsification does not destroy.
In order to obtain containing tri-glyceride more than the 1.5 weight %, that can form above-mentioned best oil phase, can the fractionation rapeseed oil, after the peanut oil, fish oil, ape consistent lubricant, tori seed oil, mango butter, use its low melting point part, perhaps these greases are carried out transesterify or obtain by synthetic.Can obtain containing carbon number more than 1.5 weight % saturated fatty acid 1 residue more than 20 and the grease of the tri-glyceride that constitutes of unsaturated fatty acids 2 residues by above-mentioned method.In the grease itself of rapeseed oil, peanut oil, fish oil, ape consistent lubricant, tori seed oil, mango butter etc. owing to contain carbon number about 1.1 weight % saturated fatty acid 1 residue 20 or more and the tri-glyceride of unsaturated fatty acids 2 residues formation, so these natural fats and oils can not directly use.
As oil phase of the present invention, use contain the above carbon number of 1.5 weight % 20 or more saturated fatty acid 1 residue and during the tri-glyceride of unsaturated fatty acids 2 residues formation, can mix more than a kind or 2 kinds with aforesaid method obtain contain carbon number more than the 1.5 weight % more than 20 saturated fatty acid 1 residue and the tri-glyceride that constitutes of unsaturated fatty acids 2 residues as oil phase, and then also can mix and make this mixing oil and contain saturated fatty acid 1 residue of carbon number more than 20 and the tri-glyceride of unsaturated fatty acids 2 residues formation more than the 1.5 weight % with other food oils.
Tinting material, grease solvent components and the additive that also can add in addition, the antioxidant of tocopherol etc. and beta carotene etc. in the oil phase.
For making the stable of oil-in-water type emulsion and making local flavor, sense of food good, the cooperation ratio of above-mentioned oil phase is 8～50 weight %.15～40 weight % preferably.The cooperation ratio of oil phase is during greater than 50 weight %, and oil-in-water type emulsion is then unstable, in addition if during less than 8 weight %, and the sense of food variation of the oil-in-water emulsion that then obtains, particularly acid oil-in-water emulsified thing.
In the present invention, use the yolk handled with enzyme as emulsifying agent.If when not using the yolk of handling with enzyme, anti-thawing property, anti-heating property variation behind the oil-in-water emulsion that then obtains, particularly acid oil-in-water emulsified thing freezing.The yolk that enzyme is handled can use raw egg yolk, sterilization yolk, any with salt yolk, sugared egg yolk etc. as its matrix.The propagation of microorganism is considered during from the local flavor of the oil-in-water emulsion that obtains and inhibitory enzyme reaction, more suitable with salt yolk, for example preferably use added 3～20 weight % salt with salt yolk, more preferably add 5～8 weight % with salt yolk.
Among the present invention, employed enzyme when handling with enzyme is preferably and with phospholipase A and proteolytic enzyme.
Phospholipase A is also referred to as phosphatide and adds the water decomposition enzyme, is to promote phosphatide to resolve into the enzyme of molten phosphorus (リ ゾ リ Application) fat reaction.The sensu lato catalysis lipid of saying so of phospholipase A adds a kind of esterase of the enzyme of water reaction.Common said lipase is meant the three acyl group glycerol lipase that three acyl group glycerol catalytic decomposition become glycerine and fatty acid response, and employed phospholipase A is the enzyme that catalysis phosphatide adds the water decomposition catalyst for reaction among the present invention.Can use mammiferous pancreatic juice and the commercially available phospholipase A that originates from microorganism such as pig.Different according to phospholipase A with effect ester bonded position, can use phospholipase A
1(EC3.1.1.32) and phospholipase A
2(EC
3.1.1.4) two kinds, which uses all suitable, but use phospholipase A
2More suitable.
In addition, alleged proteolytic enzyme is that catalysis adds the proteinic enzyme of water decomposition, can use the enzyme that originates from plant, animal, microorganism, for example originate from pineapple bromeline (Block ロ メ ラ ィ ソ), originate from pawpaw papoid (パ パ ィ ソ), originate from mammals pancreatic juice trypsinase, originate from the stomach en-of mammals gastric juice, from mould commercially available proteolytic enzyme such as proteolytic enzyme, wherein bromeline is the most suitable.
When the enzyme of yolk is handled, the interpolation of phospholipase A and proteolytic enzyme, order that can be in any order or carry out simultaneously, but after preferably yolk being handled, carry out enzyme with proteolytic enzyme again and handle with phospholipase A.If earlier with after the protease treatment, again in the method with the phospholipase A processing, because proteolytic enzyme can make phospholipase A add water decomposition, so it is insufficient to the decomposition of molten phospholipid from phosphatide, when such enzyme processing yolk was used in oil-in-water emulsion, the stability of oil-in-water emulsion tended to descend.
As these enzymes, can use the enzyme of commercially available edible, powder or liquid.
The addition of phospholipase A is for preferably suitable 0.2～100 Phospholipid hydrolase unit of 1g yolk, the more preferably amount of 0.5～20 Phospholipid hydrolase units activity amount.The Phospholipid hydrolase unit is the unit of live vol of expression Phospholipid hydrolase, and 1 Phospholipid hydrolase unit is meant under pH8.0,40 ℃, when phospholipase A is acted on yolk, and the live vol of the 1 micromole's lipid acid that in yolk, dissociates in the phosphatidase 11 minute.
The addition of proteolytic enzyme is preferably to add suitable 0.01～10 proteolytic enzyme unit for 1g yolk, more preferably 0.1～5 proteolytic enzyme unit activity amount.Proteolytic enzyme unit is meant under pH7.0,37 ℃, when proteolytic enzyme is acted on milk casein, shows the live vol of the colour developing degree that is equivalent to 1 micromolar tyrosine in 1 minute.
In addition, when and when using the above-mentioned enzyme that constitutes by phospholipase A and proteolytic enzyme, can add by following standard.
That is, the addition of above-mentioned enzyme (total amount) preferably adds 0.001～0.8 weight part for the yolk of 100 weight parts, more preferably 0.01～0.3 weight part.At this moment, the weight ratio of phospholipase A and proteolytic enzyme preferably 20/80～90/10, more preferably 40/60～85/15.
During the enzyme of yolk is handled, should the protein of yolk and phospholipase A and proteolytic enzyme not because of the heated denaturalization condition under, be to carry out under the optimum temperuture of phospholipase A and proteolytic enzyme.Usually temperature of reaction is 20～60 ℃, more preferably carries out in 40～55 ℃ the scope.In addition, it is more favourable under stirring to be preferably in stirrer etc. in enzyme is handled.
In addition, the reaction times when the yolk enzyme is handled does not have special restriction, but preferably in 1～30 hour scope.
Handle the method for yolk as enzyme, can use batch-type, add the water decomposition method, but that employing adds the water decomposition method continuously is also passable with above-mentioned condition employing.
When the enzyme of yolk is handled, the pH matter of phospholipase A and proteolytic enzyme can be adjusted to best value, for reaching the employed pH regulator agent of this purpose so long as can be used as getting final product that food uses, do not have particular restriction for other, for example can use lactic acid, citric acid, gluconic acid, hexanodioic acid, succsinic acid, winestone glue, fumaric acid, oxysuccinic acid, phosphoric acid, xitix, the tart flavour condiment or the SODIUM PHOSPHATE, MONOBASIC of acetic acid etc., potassium primary phosphate, vinegar, fruit juice, the acidic substance of fermented-milk etc. or sodium hydroxide, potassium hydroxide, calcium hydroxide, Trisodium Citrate, sodium-acetate, Sodium phosphate dibasic, dipotassium hydrogen phosphate, tertiary sodium phosphate, sodium ascorbate etc.Preferably the pH value is adjusted to 6～9.In addition, when the enzyme of yolk is handled, can add the calcium salt of edible calcium chloride, monocalcium phosphate etc. as the stablizer of enzyme.
The phosphatide that makes yolk with phospholipase A is relevant with the addition of enzyme, temperature of reaction, the pH when reaction begins, the stablizer that has or not enzyme, reaction times etc. to the degree of decomposition of molten phosphatide with the proteinic water decomposition degree that adds that makes yolk with proteolytic enzyme, but without particular limitation.By in yolk, adding phospholipase A, make that the phospholipid in the yolk is broken down into molten phosphatide.Make phospholipid can quantitatively use phosphatidylcholine (PC), phosphatidylethanolamine (PE), molten phosphatidyl choline (the リ ゾ ホ ス Off ァ チ ジ Le コ リ ヲ of the reaction front and back of phospholipase A to the resolution (%) of molten phospholipid with this phospholipase A by high-speed liquid chromatography (oiling, 41 volumes, record in 1171 pages, 1992), LPC), molten phosphatide thanomin (リ ゾ ホ ス Off ア チ ジ Le エ ノ-Le ア ミ Application, LPE) time, can obtain with following formula:
(the weight % of the reacted LPE of weight %+ of reacted LPC) ÷ (the weight % of the PE before the weight %+ reaction of the PC before the reaction) * 100
To the resolution of molten phosphatide 30～100 weight % preferably, more preferably more than 70～100 weight %, 85～100 weight % most preferably preferably set out the reaction conditions in temperature of reaction and reaction times etc.Resolution is low more, and the emulsifying stability of oil-in-water emulsion is just insufficient more.
In addition, make the proteinic water decomposition degree that adds of yolk with proteolytic enzyme, the protein that preferably will be contained in the yolk decomposes the degree that the heating solidifiability loses fully.Heating solidifiability degree is to handle after the back adds entry in the yolk at enzyme, regulates yolk and forms branch admittedly and reach 40%, in the thermotolerance bag with this adding, kept 30 minutes in 80 ℃ work are bathed, then it is added in the cup, decomposing its hardness after 5 ℃ of one nights of cooling is 100g/cm
2Below, 50g/cm preferably
2Below.
Above-mentioned enzyme is handled the cooperation ratio of yolk, and the stability of the oil-in-water type emulsion of consideration, local flavor and sense of food are 1～15 weight %, preferably 3～12 weight %.When enzyme was handled the yolk ratio greater than 15 weight %, the oil-in-water emulsion that obtains, the particularly viscosity of sour water bag type emulsification significantly rose, in addition, during less than 1 weight %, the oil-in-water type emulsion instability.
In the oil-in-water emulsion of the present invention, the cooperation ratio of water is 20～80 weight %, 50～70 weight % preferably.Oil-in-water emulsion of the present invention also is stable under so very high water ratio state, and it is cold-resistant to freeze thawing property and excellent heat resistance, particularly acid oil-in-water emulsified thing are more suitable.
When preparing oil-in-water emulsion of the present invention, can contain above-mentioned enzyme and handle the above-mentioned water of yolk modulation, but the enzyme of this moment is handled yolk and is not included in the cooperation ratio of above-mentioned water.
Therefore, aqueous phase of the present invention, do not influencing under the object of the invention, can at random use the auxiliary material of acidic flavoring agent commonly used such as common mayonnaise, mustard mayonnaise, oil-in-water type food flavouring, tackify stablizer, chemical starch, seasonings, spice, spices, salt, carbohydrate, dextrin milk protein, tinting material etc.Can enumerate lactic acid, citric acid, gluconic acid, hexanodioic acid, succsinic acid, tartrate, fumaric acid, oxysuccinic acid, xitix, vinegar, fruit juice, fermented-milk etc. as acidic flavoring agent; Can enumerate xanthan gum, Sodium Alginate, more sore glue (グ ア-ガ system), tara gum ( ラ ガ Application ト ガ system), Viscogum BE, western blue glue (ジ ェ ラ Application ガ system), gelatin, micro fiber shape Mierocrystalline cellulose etc. as the tackify stablizer; Can enumerate shallow lake things such as corn, cured corn, tapioca (flour), potato, sweet potato, wheat, rice as chemical starch, these starch are handled with enzymes such as amylase, or hand over physics, the chemically treated material of signization, heating, wet heat treatment etc., and then also can enumerate and make it be heated into the material of pasty state in advance these chemical starches soluble in waterly with acid, alkali, esterification, phosphoric acid.
Oil-in-water emulsion of the present invention can obtain with following method.
At first, the spice dispersing and dissolving of the carbohydrate of the food flavouring agent of the yolk that enzyme is handled, vinegar etc., salt, malt sugar etc., Chinese prickly ash etc. makes water in water, chemical starch, tackify stablizer are dispersed in make oil phase in the soybean oil in addition.Then under the stirring water, add oil phase, obtain oil-in-water-type preparation emulsification.With these mechanical process that homogenizes with mulsers such as colloidal mill, clarifixator etc., carry out emulsification, obtain oil-in-water emulsion of the present invention.
Further specify the present invention by the following examples, but of the present inventionly not limited by these.
Embodiment 1
What will contain 7% weight salt is adjusted to pH8.5 with salt yolk with sodium hydroxide, for the phospholipase A of 100kg adding from Pancreas Sus domestica
2600,000 Phospholipid hydrolase units handled 4 hours down for 45 ℃, then added bromeline 200,000 units and reacted 7 hours down for 45 ℃, were cooled to 10 ℃, obtained the yolk (yolk forms branch 45% admittedly) that enzyme is handled.The phosphatide of the Phospholipase A2 of the yolk that this enzyme is handled is 92% to the resolution of molten Phospholipid hydrolase.In addition, the heating solidifiability degree of the yolk that this enzyme is handled is (after adding entry in the yolk that enzyme is handled, yolk forms branch admittedly and is adjusted to 40%, put it in the thermotolerance bag, in bathing, 80 ℃ work kept 30 minutes, then it is joined in the cup hardness after cooling off a night under 5 ℃) be 10g/cm
2
The yolk of 31% weight water, 10% weight malt sugar (moisture 30 weight %), 6% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, the above-mentioned processing of 10% weight is carried out hybrid modulation become water.In addition, after the chemical starch that 40% weight soybean oil, the cured matter kind of 1% weight cornmeal mush are changed into crosslinked phosphoric acid mixes, be modulated into oil phase.Then, stir adding oil under the water, obtaining oil-in-water-type preparation emulsification, using colloidal mill emulsification, obtaining oil-in-water emulsion of the present invention.This oil-in-water emulsion 100g is sealed in the bag of polyethylene system, freezing under-20 ℃, the state of microwave oven heat treated after 60 seconds of 500W exported in the state when " Invest, Then Investigate " thawed in 2 months and the back of then breaking a seal with high frequency.Its result is as shown in table 1.
Comparative example 1
7% of 31% weight water, 10% weight malt sugar (moisture 30 weight %), 6% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, the above-mentioned processing of 10% weight carried out hybrid modulation with salt yolk become water.In addition, after the chemical starch that 40% weight soybean oil, the cured matter kind of 1% weight cornmeal mush are changed into crosslinked phosphoric acid mixes, be modulated into oil phase.Then, under the stirring water, add oil phase, obtain oil-in-water-type preparation emulsification, use colloidal mill emulsification, obtain oil-in-water emulsion of the present invention.
This oil-in-water emulsion 100g is sealed in the bag of polyethylene system ,-20 ℃ down freezing, the state when thawing under the " Invest, Then Investigate " room temperature in 2 months and then the back, Kaifeng with the state of microwave oven heat treated after 60 seconds of high frequency output 500W.Its result is as shown in table 1.
Embodiment 2
After the enzyme identical with embodiment 1 that 52.8% weight water, 12% weight malt sugar (moisture 30 weight %), 7% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, 0.2% weight are kibbled pepper, 8% weight handled yolk and mixed, be modulated into water.In addition, after the chemical starch that 15% weight rape salad oil, the cured matter kind of 3% weight cornmeal mush are changed into crosslinked phosphoric acid mixes, be modulated into oil phase.Then, under the stirring water, add oil phase, obtain oil-in-water-type preparation emulsification, homogenize, obtain oil-in-water emulsion of the present invention with pressure-even pulp crusher.
This oil-in-water emulsion 100g is sealed in the bag of polyethylene system ,-20 ℃ down freezing, the state when thawing under the " Invest, Then Investigate " room temperature in 2 months and then the back, Kaifeng with the state of microwave oven heat treated after 60 seconds of high frequency output 500W.Its result is as shown in table 1.
Comparative example 2
52.8% weight water, 12% weight malt sugar (moisture 30 weight %), 7% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, 0.2% weight are kibbled being mixed into salt 7 weight % yolk of pepper, 8% weight, be modulated into water.In addition, after the chemical starch that 15% weight rape salad oil, the cured matter kind of 3% weight cornmeal mush are changed into crosslinked phosphoric acid mixes, be modulated into oil phase.Then, under the stirring water, add oil phase, obtain oil-in-water-type preparation emulsification, homogenize, obtain oil-in-water emulsion of the present invention with pressure-even pulp crusher.
This oil-in-water emulsion 100g is sealed in the bag of polyethylene system ,-20 ℃ down freezing, the state when thawing under the " Invest, Then Investigate " room temperature in 2 months and then the back, Kaifeng with the state of microwave oven heat treated after 60 seconds of high frequency output 500W.Its result is as shown in table 1.
Embodiment 3
After the enzyme identical with embodiment 1 that 23.8% weight water, 10% weight malt sugar (moisture 30 weight %), 7% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, 0.1% weight are kibbled pepper, 0.1% weight egg pastil, 12% weight handled yolk and mixed, be modulated into water.In addition, 45% weight rape salad oil is modulated into oil phase.Then, under the stirring water, add oil phase, obtain oil-in-water-type preparation emulsification, homogenize, obtain oil-in-water emulsion of the present invention with pressure-even pulp crusher.
This oil-in-water emulsion 100g is sealed in the bag of polyethylene system ,-20 ℃ down freezing, the state when thawing under the " Invest, Then Investigate " room temperature in 2 months and then the back, Kaifeng with the state of microwave oven heat treated after 60 seconds of high frequency output 500W.Its result is as shown in table 1.
Embodiment 4
What contain 8% weight salt is adjusted to pH8.0 with salt yolk with sodium hydroxide, for the phospholipase A of this material adding of 100kg from Pancreas Sus domestica
2300,000 Phospholipid hydrolase units handled 5 hours down for 45 ℃, then added bromeline 80,000 units, and 45 ℃ were reacted 10 hours down, were cooled to 10 ℃, obtained enzyme and handled yolk (yolk forms branch 44% admittedly).The phospholipase A of the yolk that this enzyme is handled
2Phosphatide be 85% to the resolution of molten phosphatide.In addition, the heating solidifiability degree of the yolk that this enzyme is handled is (after adding entry in the yolk that enzyme is handled, yolk forms branch admittedly and is adjusted to 40%, put it in the thermotolerance bag, in bathing, 80 ℃ work kept 30 minutes, then it is joined in the cup hardness after cooling off a night under 5 ℃) be 25g/cm
2
After 23.8% weight water, 10% weight malt sugar (moisture 30 weight %), 7% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, 0.1% weight kibbled yolk that the above-mentioned enzyme of pepper, 0.1 weight % egg pastil, 12% weight handles and mix, be modulated into water.In addition, 45% weight rape salad oil is modulated into oil phase.Then, under the stirring water, add oil phase, obtain oil-in-water-type preparation emulsification, homogenize, obtain oil-in-water emulsion of the present invention with pressure-even pulp crusher.
This oil-in-water emulsion 100g is sealed in the bag of polyethylene system ,-20 ℃ down freezing, the state when thawing under the " Invest, Then Investigate " room temperature in 2 months and then the back, Kaifeng with the state of microwave oven heat treated after 60 seconds of high frequency output 500W.Its result is as shown in table 1.
Embodiment 5
After the yolk that the identical enzyme with embodiment 1 uses of 31% weight water, 10% weight malt sugar (moisture 30 weight %), 6% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, 12% weight is handled mixes, be modulated into water.In addition, after low-melting separating oil of dissolved ape consistent lubricant (approximately containing glycerinate 10% weight that 10 ℃ of fusing points, iodine number 60, eicosanoic acid 1 residue and oleic acid 2 residues constitute) 10% weight becomes the chemical starch of crosslinked phosphoric acid to mix with soybean oil 30 weight %, the cured matter kind of 1% weight corn starch pasting in advance, be modulated into oil phase.Then, under the stirring water, add oil phase, obtain oil-in-water-type preparation emulsification, use colloidal mill emulsification, obtain oil-in-water emulsion of the present invention.
This oil-in-water emulsion 100g is sealed in the bag of polyethylene system ,-20 ℃ down freezing, the state when thawing under the " Invest, Then Investigate " room temperature in 2 months and then the back, Kaifeng with the state of microwave oven heat treated after 60 seconds of high frequency output 500W.Its result is as shown in table 1.
Embodiment 6
After 23.8% weight water, 10% weight malt sugar (moisture 30 weight %), 7% weight vinegar, 1.8% weight salt, 0.2% weight Sodium Glutamate, 0.1% weight kibbled yolk that the identical enzyme with embodiment 4 uses of pepper, 0.1 weight egg pastil, 12% weight handles and mix, be modulated into water.In addition, after the extreme winterized stearin 5 weight % of high sinapinic acid rapeseed oil (more than the ratio 40 weight % of sinapinic acid) and the random ester-exchanged oil weight of soybean salad oil 95 weight % (approximately contain behenic acid 1 residue and, the tri-glyceride 33 weight % that constitute of oleic acid, linolic acid, linolenic any unsaturated fatty acids 2 residues) 5 weight % and rapeseed oil 40 weight % mix, be modulated into oil phase.Then, under the stirring water, add oil phase, obtain oil-in-water emulsion, use colloidal mill emulsification, obtain oil-in-water emulsion of the present invention.
This oil-in-water emulsion 100g is sealed in the bag of polyethylene system ,-20 ℃ down freezing, the state when thawing under the " Invest, Then Investigate " room temperature in 2 months and then the back, Kaifeng with the state of microwave oven heat treated after 60 seconds of high frequency output 500W.Its result is as shown in table 1.
Table 1
| The state that thaws | State after the heating | ||
| Embodiment | 1 | Do not see oil separating, the uniformly emulsify state | Do not see oil separating, the uniformly emulsify state, rerum natura is a paste |
| 2 | Do not see oil separating, the uniformly emulsify state | Do not see oil separating, the uniformly emulsify state, rerum natura is a paste | |
| 3 | Do not see oil separating, the uniformly emulsify state | Oil separating is seen at the end, the uniformly emulsify state, and rerum natura is a paste | |
| 4 | Do not see oil separating, the uniformly emulsify state | Do not see oil separating, the uniformly emulsify state, rerum natura is a paste | |
| 5 | Do not see oil separating, the uniformly emulsify state | Do not see oil separating, the uniformly emulsify state, rerum natura is a paste | |
| 6 | Do not see oil separating, the uniformly emulsify state | Do not see oil separating, the uniformly emulsify state, rerum natura is a paste | |
| Comparative example | 1 | See that a part is separating of oil, uneven state | The oil separating amount is bigger, and is very inhomogeneous |
| 2 | See that a part is separating of oil, uneven state | The oil separating amount is bigger, and is very inhomogeneous | |
Embodiment 7～10
The enzyme that obtains below using is handled yolk and is replaced embodiment 1～3 employed enzyme to handle the yolk, and other and embodiment 1～3 operate in the same manner, obtain oil-in-water emulsion of the present invention (being respectively embodiment 7～9) respectively.
What will contain 7% weight salt is adjusted to pH8.5 with salt yolk with sodium hydroxide, add the phospholipase A of 0.01 weight part for this material of 100kg from Pancreas Sus domestica, handled 7 hours down for 40 ℃, then add bromeline 0.002 weight part, 45 ℃ were reacted 5 hours down, be cooled to 10 ℃, obtain enzyme and handle yolk.
The enzyme that obtains below using is handled yolk and is replaced embodiment 4 employed enzymes to handle the yolk, and other and embodiment 4 operate in the same manner, obtain oil-in-water emulsion of the present invention (embodiment 10) respectively.
What will contain 8% weight salt is adjusted to pH8.0 with salt yolk with sodium hydroxide, add the phospholipase A of 0.01 weight part for this material of 100kg from Pancreas Sus domestica, handled 3 hours down for 50 ℃, then add from mould proteinase-10 .01 weight part, 50 ℃ were reacted 3 hours down, be cooled to 10 ℃, obtain enzyme and handle yolk.
Each oil-in-water emulsion and the embodiment 1～4 that obtain respectively for embodiment 7～10 estimate in the same manner, obtain identical effect.
Claims (6)
1, oil-in-water emulsion is characterized in that containing 8～50 weight % oil phases, 1～15 weight % enzyme processing yolk and 20～80 weight % waters.
2, oil-in-water emulsion according to claim 1 is characterized in that it is that the enzyme that obtains with phospholipase A and protease treatment yolk is handled yolk that enzyme is handled yolk.
3, oil-in-water emulsion according to claim 1 and 2 is characterized in that it is to handle yolk with the enzyme that phospholipase A is handled, then obtained with protease treatment yolk that enzyme is handled yolk.
4,, it is characterized in that described proteolytic enzyme is bromeline according to the described oil-in-water emulsion of one of claim 1～3.
5, according to the described oil-in-water emulsion of one of claim 1～4, it is characterized in that oil phase contain 1.5% weight above by saturated fatty acid 1 residue and the unsaturated fatty acids 2 residues tri-glyceride that constitute of carbon number more than 20.
According to the described oil-in-water emulsion of one of claim 1～5, it is characterized in that 6, it is acid oil-in-water emulsified thing.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP031774/1998 | 1998-02-13 | ||
| JP3177498 | 1998-02-13 | ||
| JP031774/98 | 1998-02-13 | ||
| JP213845/1998 | 1998-07-29 | ||
| JP10213845A JPH11289979A (en) | 1998-02-13 | 1998-07-29 | O/w emulsion |
| JP213845/98 | 1998-07-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1233416A true CN1233416A (en) | 1999-11-03 |
| CN1170485C CN1170485C (en) | 2004-10-13 |
Family
ID=26370292
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991006844A Expired - Fee Related CN1170485C (en) | 1998-02-13 | 1999-02-13 | Oil-in-water type emulsion liquid |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH11289979A (en) |
| CN (1) | CN1170485C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1298245C (en) * | 2002-03-18 | 2007-02-07 | 丘比株式会社 | Packaged oil-in-water type emulsion food and process for producing the same |
| CN102958374A (en) * | 2011-01-31 | 2013-03-06 | 日清奥利友集团株式会社 | Palm fraction soft oil and processed emulsified food product using the same |
| CN102960774A (en) * | 2012-12-07 | 2013-03-13 | 北京二商健力食品科技有限公司 | Instant yolk powder and preparation method thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4098276B2 (en) * | 2003-06-16 | 2008-06-11 | 花王株式会社 | Acid oil-in-water emulsified composition |
| JP4853433B2 (en) * | 2007-09-06 | 2012-01-11 | 株式会社カネカ | Acid oil-in-water emulsified oil and fat composition |
| US20090246319A1 (en) | 2008-03-31 | 2009-10-01 | Kraft Foods Holdings, Inc. | Process And Formulation For Making An Egg Product With Increased Functionality And Flavor |
| JP5252997B2 (en) * | 2008-05-30 | 2013-07-31 | 太陽油脂株式会社 | Oil-in-water emulsified oil / fat composition for whipped cream |
| CN102960772A (en) * | 2012-12-07 | 2013-03-13 | 北京二商健力食品科技有限公司 | Instant yolk powder and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0622461B2 (en) * | 1985-07-31 | 1994-03-30 | キユーピー株式会社 | Method for producing oil-in-water emulsified food |
| JP3440388B2 (en) * | 1994-08-23 | 2003-08-25 | 旭電化工業株式会社 | Acid-paste oil-in-water emulsified fat for salad |
| JP3508038B2 (en) * | 1995-11-06 | 2004-03-22 | 旭電化工業株式会社 | Emulsifier using egg yolk |
| JPH09220065A (en) * | 1996-02-14 | 1997-08-26 | Kanegafuchi Chem Ind Co Ltd | Pasty oil-in-water type oil and fat emulsion composition |
-
1998
- 1998-07-29 JP JP10213845A patent/JPH11289979A/en active Pending
-
1999
- 1999-02-13 CN CNB991006844A patent/CN1170485C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1298245C (en) * | 2002-03-18 | 2007-02-07 | 丘比株式会社 | Packaged oil-in-water type emulsion food and process for producing the same |
| CN102958374A (en) * | 2011-01-31 | 2013-03-06 | 日清奥利友集团株式会社 | Palm fraction soft oil and processed emulsified food product using the same |
| CN102958374B (en) * | 2011-01-31 | 2014-05-28 | 日清奥利友集团株式会社 | Palm fraction soft oil and processed emulsified food product using the same |
| CN102960774A (en) * | 2012-12-07 | 2013-03-13 | 北京二商健力食品科技有限公司 | Instant yolk powder and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1170485C (en) | 2004-10-13 |
| JPH11289979A (en) | 1999-10-26 |
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