CN1229428C - Preparing method for carbon nano-tube additive base metal and products thereof, rigid poly section material with said base metal - Google Patents
Preparing method for carbon nano-tube additive base metal and products thereof, rigid poly section material with said base metal Download PDFInfo
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- CN1229428C CN1229428C CN 03120907 CN03120907A CN1229428C CN 1229428 C CN1229428 C CN 1229428C CN 03120907 CN03120907 CN 03120907 CN 03120907 A CN03120907 A CN 03120907A CN 1229428 C CN1229428 C CN 1229428C
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Abstract
The present invention relates to a manufacture method for carbon nanotube adjunction parent materials and products. The present invention is characterized in that the preparation method comprises the following steps: (1) firstly, carrying out surface modification for carbon nanotube (2) jointly blending the carbon nanotube processed by the surface modification with polyvinyl chloride resin; (3) manufacturing blend composition into granules. Modified rigid polyvinyl chloride proximate matter of the carbon nanotube can be manufactured by adding the parent materials. The present invention has the advantages of uniform dispersal of the carbon nanotube in the rigid polyvinyl chloride, low dosage of the carbon nanotube and simple, convenient and practical method for manufacturing the modified rigid polyvinyl chloride proximate matter of the carbon nanotube.
Description
(1) technical field:
The present invention relates to preparation method and product that a kind of carbon nanotube that is used for polyvinyl chloride adds masterbatch, particularly a kind of carbon nanotube adds the preparation method of masterbatch and product and with the prepared hard pvc sheet material of this masterbatch.
(2) background technology:
Rigid PVC has the good mechanical performance, and therefore good anti-corrosion and insulativity, and low price are widely used at chemical industry, building trade etc., also be it is believed that it is one of relatively more suitable good material that replaces timber.But rigid polyvinyl chloride exists the deficiency on some performances, as: (1) shock strength is low, very easily embrittlement when being hit; (2) resistance toheat is relatively poor, only can use below 65 ℃ usually.In order to overcome the shortcoming of rigid polyvinyl chloride, people add some material therein, make its performance obtain changing.Advanced at present method is to add nano material.But because the nano material particle diameter is little, be very easy to reunite, thus to make nano material homodisperse in rigid polyvinyl chloride very difficult, often owing to can not disperse well, the nano material that causes adding can not play effective effect that improves performance, causes very big waste of material.
(3) summary of the invention:
The objective of the invention is to design that a kind of carbon nanotube adds the preparation method of masterbatch and product and with the prepared hard pvc sheet material of this masterbatch, it is solved the problem of above-mentioned said nano material homodisperse difficulty in rigid polyvinyl chloride.
Technical scheme of the present invention: a kind of carbon nanotube adds the preparation method of masterbatch, it is characterized in that it is made of following steps:
(1) at first carbon nanotube is carried out surface modification treatment, promptly in per 100 gram carbon nanotubes, add polymer dispersant 1～5 gram, titanate coupling agent 1～5 gram, wherein polymer dispersant dissolves with proper amount of acetone, the an amount of petroleum ether dissolution of titanate coupling agent, it is mixed, put into dry the removing of loft drier and desolvate;
(2) with carbon nanotube and polyvinyl chloride (PVC) RESINS blend through surface modification treatment, wherein the mixing ratio of carbon nanotube and polyvinyl chloride (PVC) RESINS is 1: 0.7～1.3 with mass ratio;
(3) blend composition is made into particle, is required carbon nanotube and adds masterbatch.
A kind of product that adds masterbatch by the resulting carbon nanotube of above-mentioned preparation method, it is to be made into particulate material with carbon nanotube and polyvinyl chloride (PVC) RESINS blend through surface modification treatment, and the mixing ratio of said carbon nanotube and polyvinyl chloride (PVC) RESINS is 1: 0.7～1.3 with mass ratio.
The prepared hard polychloroethylene section bar of the above-mentioned carbon nanotube masterbatch of a kind of usefulness, it is made of rigid PVC and above-mentioned interpolation masterbatch, and the addition of above-mentioned interpolation masterbatch is that benchmark accounts for wherein 2-10% with the rigid PVC quality.
Above-mentioned carbon nanotube add masterbatch adopt directly add, with the mode of rigid PVC melt blending, adopt twin screw extruder to finish the making of hard polychloroethylene section bar.
The above-mentioned carbon nanotube of above-mentioned said usefulness adds the prepared hard polychloroethylene section bar of masterbatch and can be sheet material, also can be tubing, bar and other section bar.
Superiority of the present invention is: the avidity that 1, can improve carbon nanotube and organic phase, not only carbon nanotube is uniformly dispersed, can also reduce the consumption of carbon nanotube, have the effect of saving the carbon nanotube consumption, under the constant situation of rigid PVC sheet material modifying function, the carbon nanotube consumption is reduced; 2, adopt this masterbatch to make the method for making carbon nano-tube modification hard polychloroethylene section bar simple, convenient, practical; 3, the production of convenient various rigid polyvinyl chloride products; 4, the carbon nanotube that adopts present method to produce adds masterbatch, reduce production cost, easy to operate, production efficiency is high; 5, adopt this carbon nanotube to add the modified hard polyethylene chloride section bar that masterbatch is produced, the good dispersity of its carbon nanotube in rigid polyvinyl chloride, can obtain high performance carbon nano-tube modification rigid polyvinyl chloride, studies show that, the modified hard polyethylene chloride section bar that adopts this method to produce, when the content of carbon nanotube when 4% (mass percent) is following, promptly can improve the shock resistance and the resistance toheat of rigid polyvinyl chloride significantly, improve its socle girder notched Izod impact strength of back and can reach 10-30kJ/m
2, vicat softening temperature can reach 90～160 ℃, so this method is a kind of Perfected process of transforming traditional product with nanotechnology.
(4) embodiment:
Embodiment: a kind of carbon nanotube adds the preparation method of masterbatch, it is characterized in that it is made of following steps:
(1) at first carbon nanotube is carried out surface modification treatment, promptly in per 100 gram carbon nanotubes, add polymer dispersant 4 grams, titanate coupling agent 3 grams, wherein polymer dispersant dissolves with proper amount of acetone, the an amount of petroleum ether dissolution of titanate coupling agent, it is mixed, put into dry the removing of loft drier and desolvate;
(2) with carbon nanotube and polyvinyl chloride (PVC) RESINS blend through surface modification treatment, wherein the mixing ratio of carbon nanotube and polyvinyl chloride (PVC) RESINS is 1: 1 with mass ratio;
(3) blend composition is made into particle, is required carbon nanotube and adds masterbatch.
A kind of product that adds masterbatch by the resulting carbon nanotube of above-mentioned preparation method, it is to be made into particulate material with carbon nanotube and polyvinyl chloride (PVC) RESINS blend through surface modification treatment, and the mixing ratio of said carbon nanotube and polyvinyl chloride (PVC) RESINS is 1: 1 with mass ratio.
The above-mentioned carbon nanotube of a kind of usefulness adds the prepared hard polychloroethylene section bar of masterbatch, it is made of rigid PVC and above-mentioned interpolation masterbatch, and the addition that above-mentioned carbon nanotube adds masterbatch is that benchmark accounts for the rigid PVC quality wherein is 4%.
Above-mentioned carbon nanotube add masterbatch adopt directly add, with the mode of rigid PVC melt blending, adopt twin screw extruder to finish the making of hard polychloroethylene section bar.
The prepared hard polychloroethylene section bar of the above-mentioned carbon nanotube masterbatch of above-mentioned said usefulness can be a sheet material.
Claims (4)
1, a kind of carbon nanotube adds the preparation method of masterbatch, it is characterized in that it is made of following steps:
(1) at first carbon nanotube is carried out surface modification treatment, promptly in per 100 gram carbon nanotubes, add polymer dispersant 1～5 gram, titanate coupling agent 1～5 gram, wherein polymer dispersant dissolves with proper amount of acetone, the an amount of petroleum ether dissolution of titanate coupling agent, it is mixed, put into dry the removing of loft drier and desolvate;
(2) with carbon nanotube and polyvinyl chloride (PVC) RESINS blend through surface modification treatment, wherein the mixing ratio of carbon nanotube and polyvinyl chloride (PVC) RESINS is 1: 0.7～1.3 with mass ratio;
(3) blend composition is made into particle, is required carbon nanotube and adds masterbatch.
2, a kind of product that adds masterbatch by the resulting carbon nanotube of above-mentioned preparation method, it is to be made into particulate material with carbon nanotube and polyvinyl chloride (PVC) RESINS blend through surface modification treatment, and the mixing ratio of said carbon nanotube and polyvinyl chloride (PVC) RESINS is 1: 0.7～1.3 with mass ratio.
3, a kind of prepared hard polychloroethylene section bar of above-mentioned carbon nanotube masterbatch that adds, it is made of rigid PVC and above-mentioned interpolation masterbatch, and the addition that above-mentioned carbon nanotube adds masterbatch is that benchmark accounts for wherein 2-10% with the rigid PVC quality.
4,, it is characterized in that saidly can being sheet material, also can being tubing, bar and other section bar with adding the prepared hard polychloroethylene section bar of above-mentioned carbon nanotube masterbatch according to the said a kind of prepared hard polychloroethylene section bar of above-mentioned carbon nanotube masterbatch that adds of claim 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03120907 CN1229428C (en) | 2003-03-25 | 2003-03-25 | Preparing method for carbon nano-tube additive base metal and products thereof, rigid poly section material with said base metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03120907 CN1229428C (en) | 2003-03-25 | 2003-03-25 | Preparing method for carbon nano-tube additive base metal and products thereof, rigid poly section material with said base metal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1456592A CN1456592A (en) | 2003-11-19 |
| CN1229428C true CN1229428C (en) | 2005-11-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 03120907 Expired - Fee Related CN1229428C (en) | 2003-03-25 | 2003-03-25 | Preparing method for carbon nano-tube additive base metal and products thereof, rigid poly section material with said base metal |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580243B (en) * | 2009-06-03 | 2013-03-27 | 惠州市沃特新材料有限公司 | Surface treatment method of carbon nanotube and method for preparing composite plastic by using the same |
| CN107057176A (en) * | 2017-04-19 | 2017-08-18 | 深圳职业技术学院 | A kind of carbon nanotube masterbatch and preparation method thereof |
| CN107177129A (en) * | 2017-06-16 | 2017-09-19 | 东莞市联洲知识产权运营管理有限公司 | A kind of preparation method of new polychloroethylene pipes for discharge of wastewater |
| CN107746519A (en) * | 2017-10-18 | 2018-03-02 | 哈尔滨金纳科技有限公司 | A kind of CNT composite plastic and preparation method thereof |
| CN109438973A (en) * | 2018-09-25 | 2019-03-08 | 朱强 | A kind of polyamide master-batch and preparation method and the plastics and preparation method being modified with it |
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