CN1226447C - Production device and preparation method of foamed aluminum rolled blanket - Google Patents

Production device and preparation method of foamed aluminum rolled blanket Download PDF

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CN1226447C
CN1226447C CN 03134168 CN03134168A CN1226447C CN 1226447 C CN1226447 C CN 1226447C CN 03134168 CN03134168 CN 03134168 CN 03134168 A CN03134168 A CN 03134168A CN 1226447 C CN1226447 C CN 1226447C
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type metal
arc type
base material
foamed aluminium
roll blanket
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CN1515700A (en
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孙伟成
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Abstract

A production device of foamed aluminum roll blanket and a preparation method thereof are provided, the production device comprises a machine body, a winding mechanism assembled in the machine body and an arc type metal evaporator, and the technical points are as follows: the device is characterized in that shaft roller radius measuring sensors are respectively arranged beside a base material uncoiling shaft roller and a coiling shaft roller of the coiling mechanism, at least an upper row and a lower row of arc type metal evaporators are uniformly arranged on the upper surface and the lower surface of the base material tensioned by guide rollers, at least 4 arc type metal evaporators are arranged in parallel in each row, and a tension measuring sensor is respectively arranged beside each guide roller. The device has simple structure, convenient operation and safe use, and the method for preparing the foamed aluminum roll blanket by using the production device fundamentally solves the problems of producing the through hole foamed aluminum with stable structure, small and uniform large-area aperture and high porosity.

Description

Production equipment of a kind of foamed aluminium roll blanket and preparation method thereof
Technical field
Patent of the present invention relates to a kind of technology of producing foamed aluminium, and particularly a kind of production aperture is tiny, even, porosity is high, the production equipment of large-area through-hole foam aluminium roll blanket and utilize this production equipment to prepare the method for foamed aluminium roll blanket.
Background technology
Foamed aluminium is the most common in the porous foam metal, that application prospect is best a kind of material, and it is that a kind of physical property of metallic surface of utilizing produces the structure function material of special role.Because it has special structure, so its Application Areas relates to material structure and physical some key areas.The application of configuration aspects is mainly in multiple industry such as automobile, space flight, building; Function is used and to be comprised: flow in damping in-fighting, acoustics, hot physics, the porous medium, electromagnetism etc.
Porous foam metal material has the history of five more than ten years, does the whipping agent foaming because of its original adoption mercury, and this foaming technology controlling and process is very difficult, so the development work of porous foam metal has stopped recent two decades.Up to finding new whipping agent, the development of porous foam metal just enters a new stage.Along with people recognize this gradually is a kind of crucial high-tech novel material, and very application prospects is arranged, and porous foam metal material has become the material of trying to be the first and develop in countries in the world.Japan, the U.S., West Europe are dropped into substantial contribution year after year and are studied this project, and on the preparation method, obtaining some impressive progress aspect the simulation of the important parameter of preparation process, on some patent documentations, disclose the technology contents of many this respects, made porous foam metal material in the nearly more than ten years, considerable progress arranged.The continuing to bring out of new preparation method, control techniques are gradually improved.
The main preparation methods of existing porous foam metal material can be divided into three major types:
One, foaming preparation technology (liquid, solid-state); Two, seepage flow casting preparation technology; Three, electrodeposition technology.
The first kind: liquid metal foaming preparation technology is: after the aluminum or aluminum alloy fusing, insulation is at a certain temperature stirred, and adds tackifier, adds whipping agent again, perhaps solidifies in crucible, perhaps is poured in the model and solidifies, and can obtain foamed aluminium; Solid-state foaming can be described as powder metallurgic method again.Pure aluminium powder or Al alloy powder together, be compacted into blank, be placed in the controlled atmosphere generator,, just can produce foamed aluminium by certain technology sintering with the whipping agent uniform mixing of certain proportion.Just know from above-mentioned production technique, the pore size of the foamed aluminium of Sheng Chaning in this way, degree of uniformity and porosity all have very big uncertainty.Therefore, scrap rate is higher.The foamed aluminium that this method is produced, the hole is not communicated with mutually, is called as closed-cell aluminum foam.
Second class: the technology that the seepage flow casting prepares foamed aluminium is to be deposited in together with controlled-size solid particle (as dissolved salt, glass, pottery etc.), then, molten aluminum liquid is poured in the slit of solid particulate, again solid particulate is removed after the condensation, just obtained foamed aluminium.The hole of the foamed aluminium that this method is produced is interconnected, and is called fine-crystal spume aluminium alloy.The homogeneity in its aperture can be accomplished, but its porosity is lower.
The 3rd class: electrodeposition technology can be described as electroplating technology again.Can be divided into wet electrochemical plating and dried electrochemical plating.Electroplating in water-soluble electroplate liquid is the main technique method of production nickel foam.In water-insoluble electroplate liquid, electroplate and can be used to produce foamed aluminium.And do electrochemical plating is that electroless plating liquid is electroplated, or claims physical vaporous deposition.
The constitutional features of the foamed aluminium of two kinds of explained hereafter of first and second class is as follows: aperture ratio is φ 0.3~8mm more greatly, and inhomogeneous, and voidage is 60~90%, specific surface area 1000~4500m 2/ m 3In the actual production, structure control is difficulty, and scrap rate is higher, and therefore, cost is higher.Because the performance of foamed aluminium depends primarily on its structure, therefore, the various performances of the foamed aluminium of producing with these two kinds of methods have been difficult to raising more.How the pore structure of control foam aluminium makes it more stable, more tiny, more even, and the rate of reducing the number of rejects and seconds is the target that production firm is pursued always.
Wet electroplating technology is the main technique method of current production nickel foam.The pore structure of the foamed metal of electrodip process production depends primarily on selected base material.What the structure that is to say selected porous plastics is, what sample is the structure of foamed metal be exactly.This has just fundamentally solved the structural stability problem of foamed metal.Stability Analysis of Structures, the stability problem of performance just has been readily solved.Because its structure depends on the structure of porous plastics, therefore, scrap rate is low, and cost is lower.Yet water-soluble electroplate liquid is electroplated and can only be used for metals such as nickel plating, iron, copper, cobalt, chromium.Electrodip process is produced foamed metal, once reports in some foreign patents, as mentioning the production nickel foam in EP-B1-0151064, the US5503941 patent; Relate in the DE10123585 patent and produce inflatable metal and foamed metal, but be metals such as copper, nickel, cobalt, iron, do not comprise aluminium; Relate in the EP921210 patent with covering and agglomerating method production nickel porous-Al alloy composite, wherein, nickel dam is to adopt electro-deposition method, and aluminium lamination then is to adopt the organic compound thermal decomposition method sedimentary.
The inventor once structure control at above-mentioned foaming or the existence of seepage flow casting is difficult, the scrap rate problem of higher, a kind of employing electrodip process is proposed, with water-insoluble plating bath---anhydrous Organoalkyl aluminium electrolyte is produced the method for foamed aluminium, fundamentally solve the structural stability problem of foamed aluminium, prepared the fine-crystal spume aluminium alloy that the aperture is tiny, even, porosity is high.But, because of organic plating bath all is inflammable, so it is the hidden danger of the maximum of safety in production.In addition, organic plating bath also can not be ignored the pollution problem of environment.Therefore, this preparation method needs further to improve.
Summary of the invention
The purpose of this invention is to provide production equipment of a kind of foamed aluminium roll blanket and preparation method thereof, this apparatus structure is simple, easy to operate, safe in utilization, it has fundamentally solved production structure fine-crystal spume aluminium alloy problem stable, that large-area aperture is tiny, even, porosity is high, compare with wet electrochemical plating, has the quality product of significantly improving, the rate of obviously reducing the number of rejects and seconds is guaranteed production safety, the advantage of environmentally safe.
The object of the present invention is achieved like this: this production equipment comprises body, assembles winding mechanism and arc type metal evaporator in it, its technical essential is: the other beaming roller radius measurement transmitter that is provided with respectively of the base material uncoiling beaming roller of winding mechanism and rolling beaming roller, evenly distributed upper and lower at least two row's arc type metal evaporators over against the upper and lower surface of the base material that utilizes the guide roller tensioning, whenever drain into less 4 arc type metal evaporators arranged side by side, at the other tonometry transmitter that is provided with respectively of each guide roller.
The target of the intravital arc type metal evaporator of above-mentioned production equipment machine is a commercial-purity aluminium, and working current is that 25~120A, negative bias voltage of supply are that 500~1000V, electric current are 20~40A.
Adopt above-mentioned production equipment to prepare the method for foamed aluminium roll blanket, adopt following operation steps:
Select for use porous plastics as base material, through degreasing, destressing, degas, after the pre-treatment of rolling, vacuum plastic sealing, place on the uncoiling beaming roller of body, remove plastic packaging, the volume head is fixed on the rolling beaming roller, closes the body door, the unlatching vacuum valve vacuumizes, when reaching 10 -4Behind the Pa, feed argon gas, argon pressure is 1.33 * 10Pa, start winding mechanism, meanwhile, the arc type metal evaporator ignites, open the negative bias power supply, base material moves with the linear velocity of setting, after deposition goes up the aluminium of requirement uniformly, close winding mechanism, close the arc type metal evaporator, close the negative bias power supply, close vacuum valve, the body door is opened in venting, takes out the foamed aluminium roll blanket of making.
Base material is an organic foam material in the aforesaid method, selects poly-inferior peace fat, polyester, polystyrene, polyphenol, polyethylene and poly-third ethene for use.
The foamed aluminium roll blanket that adopts method for preparing can carry out pyrolytic decomposition thermal treatment for improving its intensity and toughness under 400~500 ℃ of temperature under anaerobic (as vacuum, falling property gas, nitrogen or nitrogen and hydrogen mixture) condition.The organic foam material of removing the inside also can replace high-temperature decomposition with other heat treating method.Heat-treat condition also can be selected the metallic aluminium of sintering galvanic deposit, and the foamed aluminium roll blanket structural strength is strengthened.
Because the present invention adopts through pretreated foam materials as base material, utilize special-purpose production equipment to prepare foamed aluminium roll blanket, organic plating bath that need not be inflammable, eliminated the pollution problem of the hidden danger of maximum of safety in production and organic plating bath to environment, so this device is not only simple in structure, easy to operate, safe in utilization, and utilize this production equipment to prepare the method for foamed aluminium roll blanket, it is stable fundamentally to have solved production structure, large-area aperture is tiny, evenly, the fine-crystal spume aluminium alloy problem that porosity is high, compare with wet electrochemical plating, has the quality product of significantly improving, the rate of obviously reducing the number of rejects and seconds is guaranteed production safety, the advantage of environmentally safe.The primary structure characteristic of the foamed aluminium roll blanket that the present invention prepares is mainly determined according to actual needs, and is selected the control of base material, arc type metal evaporator working current and negative bias power supply, the movement velocity of base material etc. according to this.Its primary structure characteristic is as follows through the actual detected result:
2.5~30/cm of hole aperture, 0.1~3.2mm surface-area, 500~7500m 2/ m 3
Thickness 2~20mm density 0.10~0.34g/cm 2Thickness of coating 10~20 μ m
Description of drawings
Below in conjunction with accompanying drawing the present invention is further described.
Fig. 1 is a kind of production equipment concrete structure synoptic diagram of the present invention.
Fig. 2 selects for use polyurethane foam to make the scanning electron microscope picture of the foamed aluminium roll blanket of base material production.
Fig. 3 selects for use polyethylene to make the scanning electron microscope picture of the foamed aluminium roll blanket of base material production.
Fig. 4 selects for use polystyrene to make the foamed aluminium roll blanket picture in kind that base material is produced.
Embodiment
Describe concrete structure of the present invention and working process in detail according to Fig. 1 and embodiment.The specification of this production equipment should be according to prepared comprising body 1, assembling winding mechanism and conventional arc type metal evaporator 3 in it.Wherein winding mechanism is made of uncoiling beaming roller 2, rolling beaming roller 4 and the guide roller 7 thereof etc. of the base material 6 of transmission gear for electric motor (not shown) driving.Uncoiling beaming roller 2 and rolling beaming roller 4 sides are provided with beaming roller radius measurement transmitter 4 respectively, are used for monitoring the radius that batches of base material 6.Over against the upper and lower surface of the base material 6 that utilizes guide roller 7 tensionings, evenly distributed upper and lower at least two row's arc type metal evaporators whenever drain into less 4 arc type metal evaporators arranged side by side.On each guide roller 7 side tonometry transmitter 8 is set respectively, to control the suitable tension force of 7 pairs of base materials 6 of this guide roller.The target of the arc type metal evaporator 3 in body 1 is a commercial-purity aluminium, and working current is that 25~120A, negative bias voltage of supply are that 500~1000V, electric current are 20~40A.The control of the selection of its base material, arc type metal evaporator working current and negative bias power supply, the movement velocity of base material etc., the actual needs of the primary structure characteristic of the foamed aluminium roll blanket that main basis is prepared is determined.
Embodiment one:
Select for use polyurethane foam as base material, mean pore size is 0.60mm, porosity 90%, thickness 2mm, through degreasing, destressing, degas, after the rolling, vacuum plastic sealing, place on the uncoiling beaming roller of body, remove plastic packaging, the volume head is fixed on the rolling beaming roller, closes the body door, the unlatching vacuum valve vacuumizes, when reaching 10 -4Behind the Pa, feed argon gas, argon pressure is 1.33 * 10Pa.Start winding mechanism, 4 rows totally 16 arc type metal evaporators one by one meanwhile ignite.At this moment, open the negative bias power supply.Working current 27~the 35A of vaporizer, negative bias voltage of supply are that 500V, electric current are 40A.Polyurethane foam substrate material moves with the linear velocity of 1m/h, deposits last layer aluminium uniformly.After base material uses up, close winding mechanism, close the arc type metal evaporator one by one, close the negative bias power supply, to close vacuum and cut down door, fire door is opened in venting, takes out the foamed aluminium roll blanket of making.A production cycle finishes.Its structure as shown in Figure 1.Aperture 0.59mm, porosity 89.4%.The about 18 μ m of aluminium coat thickness.By on the photo shown in Figure 2 as can be seen the center of aluminium skeleton be empty, in other words the aluminium skeleton is to be that the aluminum pipe of 18 μ m constitutes by thickness.The porosity of the foamed aluminium roll blanket of producing in this way is bigger than the porosity of actual measurement in other words.Therefore, its use properties is better.
Embodiment two
Select for use polyethylene as base material, mean pore size is 0.80mm, porosity 92%.Thickness 2.5mm.Through degreasing, destressing, degas, after the rolling, vacuum plastic sealing, place on the uncoiling beaming roller of body, remove plastic packaging, the volume head is fixed on the rolling beaming roller, closes the body door, opens vacuum valve and vacuumizes, when reaching 10 -4Behind the Pa, feed argon gas, argon pressure is 1.33 * 10Pa.Start winding mechanism, 4 rows totally 16 arc type metal evaporators one by one meanwhile ignite.At this moment, open the negative bias power supply.Working current 35~the 50A of vaporizer, negative bias voltage of supply are that 1000V, electric current are 20A.Polyurethane foam substrate material moves with the linear velocity of 10m/h, deposits last layer aluminium uniformly.After base material uses up, close winding mechanism, close the arc type metal evaporator one by one, close the negative bias power supply, to close vacuum and cut down door, fire door is opened in venting, takes out the foamed aluminium roll blanket of making.A production cycle finishes.Its structure as shown in Figure 3, aperture 0.65mm, porosity 90.4%.The about 12 μ m of aluminium coat thickness.
Embodiment three
Select for use polystyrene foam as base material, mean pore size is 2.80mm, porosity 94%.Thickness 20mm.Through degreasing, destressing, degas, after the rolling, vacuum plastic sealing, place on the uncoiling beaming roller of body, remove plastic packaging, the volume head is fixed on the rolling beaming roller, closes the body door, opens vacuum valve and vacuumizes, when reaching 10 -4Behind the Pa, feed argon gas, argon pressure is 1.33 * 10Pa.Start winding mechanism, 6 rows totally 24 arc type metal evaporators one by one meanwhile ignite.At this moment, open the negative bias power supply.Working current 50~the 70A of vaporizer, negative bias voltage of supply are that 700V, electric current are 30A.The polystyrene foam base material moves with the linear velocity of 5m/h, deposits last layer aluminium uniformly.After base material uses up, close winding mechanism, close the arc type metal evaporator one by one, close the negative bias power supply, to close vacuum and cut down door, fire door is opened in venting, takes out foamed aluminium roll blanket.Under oxygen free condition, heat-treat under 400~500 ℃.A production cycle finishes.Its structure as shown in Figure 3, aperture 2.59mm, porosity 94.4%.The about 20 μ m of aluminium coat thickness.

Claims (5)

1, a kind of production equipment of foamed aluminium roll blanket, comprise body, assemble winding mechanism and arc type metal evaporator in it, it is characterized in that: the other beaming roller radius measurement transmitter that is provided with respectively of the base material uncoiling beaming roller of winding mechanism and rolling beaming roller, evenly distributed upper and lower at least two row's arc type metal evaporators over against the upper and lower surface of the base material that utilizes the guide roller tensioning, whenever drain into less 4 arc type metal evaporators arranged side by side, at the other tonometry transmitter that is provided with respectively of each guide roller.
2, the production equipment of foamed aluminium roll blanket according to claim 1 is characterized in that: the target of the intravital arc type metal evaporator of machine is a commercial-purity aluminium, and working current is that 25~120A, negative bias voltage of supply are that 500~1000V, electric current are 20~40A.
3, a kind of method of utilizing the described production equipment of claim 1 to prepare foamed aluminium roll blanket, it is characterized in that: adopt following operation steps: select for use porous plastics as base material, through degreasing, destressing, degas, after the pre-treatment of rolling, vacuum plastic sealing, place on the uncoiling beaming roller of body, remove plastic packaging, the volume head is fixed on the rolling beaming roller, closes the body door, the unlatching vacuum valve vacuumizes, when reaching 10 -4Behind the Pa, feed argon gas, argon pressure is 1.33 * 10Pa, start winding mechanism, meanwhile, the arc type metal evaporator ignites, open the negative bias power supply, base material moves with the linear velocity of setting, after deposition goes up the aluminium of requirement uniformly, close winding mechanism, close the arc type metal evaporator, close the negative bias power supply, close vacuum valve, the body door is opened in venting, takes out the foamed aluminium roll blanket of making.
4, the preparation method of foamed aluminium roll blanket according to claim 3 is characterized in that: base material is an organic foam material, selects poly-inferior peace fat, polyester, polystyrene, polyphenol, polyethylene and poly-third ethene for use.
5, the preparation method of foamed aluminium roll blanket according to claim 3 is characterized in that: this foamed aluminium is heat-treated under 400~500 ℃ of temperature under oxygen free condition.
CN 03134168 2003-08-26 2003-08-26 Production device and preparation method of foamed aluminum rolled blanket Expired - Fee Related CN1226447C (en)

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