CN1225916A - Non-incendive water-in oil emulsive explosion composition - Google Patents
Non-incendive water-in oil emulsive explosion composition Download PDFInfo
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- CN1225916A CN1225916A CN 98100807 CN98100807A CN1225916A CN 1225916 A CN1225916 A CN 1225916A CN 98100807 CN98100807 CN 98100807 CN 98100807 A CN98100807 A CN 98100807A CN 1225916 A CN1225916 A CN 1225916A
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- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 238000004880 explosion Methods 0.000 title claims description 9
- 150000003839 salts Chemical class 0.000 claims abstract description 32
- 239000002360 explosive Substances 0.000 claims abstract description 31
- 239000000446 fuel Substances 0.000 claims abstract description 23
- 239000002019 doping agent Substances 0.000 claims abstract description 17
- 239000007800 oxidant agent Substances 0.000 claims abstract description 17
- 239000007864 aqueous solution Substances 0.000 claims abstract description 16
- 239000007787 solid Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims description 23
- 239000000839 emulsion Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000001993 wax Substances 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 230000001590 oxidative effect Effects 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- -1 alkano amines Chemical class 0.000 claims description 7
- 239000005662 Paraffin oil Substances 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 229940005740 hexametaphosphate Drugs 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004147 Sorbitan trioleate Substances 0.000 claims description 4
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims description 4
- 238000005273 aeration Methods 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 239000004200 microcrystalline wax Substances 0.000 claims description 4
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 235000019337 sorbitan trioleate Nutrition 0.000 claims description 4
- 229960000391 sorbitan trioleate Drugs 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- MKYLOMHWHWEFCT-UHFFFAOYSA-N Manthidine Natural products C1C2=CC=3OCOC=3C=C2C2C3=CC(OC)C(O)CC3N1C2 MKYLOMHWHWEFCT-UHFFFAOYSA-N 0.000 claims description 3
- SNFRINMTRPQQLE-JQWAAABSSA-N Montanin Chemical compound O[C@H]([C@@]1(CO)O[C@H]1[C@H]1[C@H]2O3)[C@]4(O)C(=O)C(C)=C[C@H]4[C@]11OC3(CCCCCCCCCCC)O[C@@]2(C(C)=C)C[C@H]1C SNFRINMTRPQQLE-JQWAAABSSA-N 0.000 claims description 3
- SNFRINMTRPQQLE-OFGNMXNXSA-N Montanin Natural products O=C1[C@@]2(O)[C@@H](O)[C@@]3(CO)O[C@H]3[C@@H]3[C@H]4[C@@]5(C(=C)C)O[C@](CCCCCCCCCCC)(O4)O[C@@]3([C@H](C)C5)[C@@H]2C=C1C SNFRINMTRPQQLE-OFGNMXNXSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- QTZPBQMTXNEKRX-UHFFFAOYSA-N Voacristine pseudoindoxyl Natural products N1C2=CC=C(OC)C=C2C(=O)C21CCN(C1)C3C(C(C)O)CC1CC32C(=O)OC QTZPBQMTXNEKRX-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 239000010953 base metal Substances 0.000 claims description 3
- 235000013871 bee wax Nutrition 0.000 claims description 3
- 239000012166 beeswax Substances 0.000 claims description 3
- 229960005215 dichloroacetic acid Drugs 0.000 claims description 3
- 239000002283 diesel fuel Substances 0.000 claims description 3
- 229910001960 metal nitrate Inorganic materials 0.000 claims description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 239000012177 spermaceti Substances 0.000 claims description 3
- 229940084106 spermaceti Drugs 0.000 claims description 3
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 claims description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004166 Lanolin Substances 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 150000002461 imidazolidines Chemical class 0.000 claims description 2
- 235000019388 lanolin Nutrition 0.000 claims description 2
- 229940039717 lanolin Drugs 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 229940083466 soybean lecithin Drugs 0.000 claims description 2
- 150000003431 steroids Chemical class 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 229910052728 basic metal Inorganic materials 0.000 claims 5
- 150000003818 basic metals Chemical class 0.000 claims 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims 3
- 229910052723 transition metal Inorganic materials 0.000 claims 3
- 150000003624 transition metals Chemical class 0.000 claims 3
- 239000005864 Sulphur Substances 0.000 claims 2
- 229910021386 carbon form Inorganic materials 0.000 claims 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 claims 2
- 239000000295 fuel oil Substances 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 239000007859 condensation product Substances 0.000 claims 1
- 230000000994 depressogenic effect Effects 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000003245 coal Substances 0.000 abstract description 4
- 239000007762 w/o emulsion Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 238000005422 blasting Methods 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 238000005474 detonation Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 229940001516 sodium nitrate Drugs 0.000 description 3
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 3
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 3
- 239000002341 toxic gas Substances 0.000 description 3
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 229920005652 polyisobutylene succinic anhydride Polymers 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 241000283153 Cetacea Species 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 239000001955 polyclycerol esters of fatty acids Substances 0.000 description 1
- 239000003996 polyglycerol polyricinoleate Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- LUPNKHXLFSSUGS-UHFFFAOYSA-M sodium;2,2-dichloroacetate Chemical compound [Na+].[O-]C(=O)C(Cl)Cl LUPNKHXLFSSUGS-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Liquid Carbonaceous Fuels (AREA)
Abstract
A non-incendive, water-in-oil emulsion explosive composition is disclosed for use as P-5 permitted explosives in inter alia underyround coal mines. The explosive comprises from 50-80% by weight of an a aqueous solution of inorganic oxidiser salts, from 3-60% by weight of fuel phase and from 5-50% by weight of one or more solid dopants.
Description
The present invention relates in the underground coal mine of III degree inflation, to can be used as the oil-in-water emulsify blasting explosives composition of the explosive that P-5 allows.
More particularly, the present invention relates to nonflammable, oil-in-water emulsify blasting explosives composition and prepare the method for said composition.
P-5 type explosive is generally used for the underground coal mine of hyperinflation.These explosives are also through the special solid explosion that confirms to be applied in I degree and the II degree mine.Use NG type explosive at present.Yet these conventional explosives have some inherent shortcomings.These shortcomings comprise high poison gas and the detonation feature of physiological effect and blast back of using the NG explosive.
In the trial that overcomes more above mentioned shortcomings, use water gel to obtain limited achievement.Water gel demonstrates poison gas after the blast that has reduced and low detonation tendency.Yet the performance of this hydrogel is normally insecure.
The P-5 emulsion explosive is expected to overcome these problems, and the advantage of poison gas after the very low blast is provided simultaneously.They also are non-detonating.
The design of P-5 explosive itself is a kind of skill, because the relevant requirements of rules approval and performance is conflicted.In order to use a large amount of inert substance doping explosives by strict tunnel experiment.Yet, with inert substance doping explosive often to the susceptibility of explosive with and performance have a negative impact.Therefore, when carrying out this type of test, must reach best balance.
The oil-in-water emulsify explosive that can be used for P1 and P3 condition, for example I degree and II degree inflation mine is disclosed in the prior art.These explosives need refrigerant, because the explosion gas of the heat that discharges will certainly be lighted the gaseous mixture of the methane/air in the underground mine.This type of refrigerant is water and salt normally.US P 5017251 has illustrated the application of salt in P1 type explosive.
Similar prior art document has also been reported very high doping salt and has been used glass microsphere (the glass microballons of high capacity, GMBs) susceptibility (patent No.: the ZA 043516 to reach expectation, US 6017261M, AU 0067072M, AU 8656181, US 4976793M, CN1031363).The GMB that uses high capacity like this is infeasible economically suggestion.
Therefore, basic purpose of the present invention provides the P-5 emulsion explosive of the shortcoming and defect that overcomes prior art compositions.
The clearer and more definite purpose of the present invention provides (chemicallygassed) explosive P-5 oil-in-water type composition of the chemical aeration of viable commercial.
Further aim of the present invention provides the P-5 composition, wherein except utilizing water and an alkali metal salt as refrigerant, has clearly established the needs to the flame quencher.
Another object of the present invention provides the P-5 emulsion explosive composition, and when using when approval is used for the commercially available detonator of underground coal mine, said composition is responsive to ignition in the diameter of 32mm.
So, the invention provides nonflammable, oil-in-water emulsify blasting explosives composition, it comprises the aqueous solution of for example inorganic oxidant salt described here of 50-80% (weight), the fuel phase of 3-60% (weight) and such solid dopants one or more for example described here of 5-50% (weight).
Inorganic oxidant salt (it constitutes the discontinuous phase of P-5 emulsion explosive composition of the present invention in the aqueous solution) is selected from ammonium nitrate, base metal nitrate such as SODIUMNITRATE or saltpetre.And, can comprise the perchlorate of chemical sensitizer such as sodium, potassium or ammonium, preferred person is a sodium perchlorate.
Said composition also comprises the flame quencher.This flame quencher is selected from preferred phosphoric acid salt, and as list, disodium salt, ammonium salt and hexametaphosphate, most preferably the person is an ammonium salt.The oxidizing agent solution that flame quencher of the present invention both can be used for the P-5 emulsion formulations mutually in, also can be used as one of composition of solid dopants, or both all can.
Water ratio in the aqueous solution of this inorganic oxidant salt is preferably based on the 5-16% of blasting explosives composition gross weight (weight).
Fuel comprises the mixture of the waxy substance (usually indication be Microcrystalline Wax and paraffin) of straight chain and side chain mutually, emulsifying agent and comprise paraffin oil alone or with commerce in be known as the fuel that the residue of crude oil of the low sulfur content of LSHS cooperates.Known this fuel makes bilayer more pliable and tougher when suffering pressure, therefore helps to reduce the shear-sensitive degree of doping emulsion.
Because a large amount of doping agents, the emulsifying agent that uses in composition of the present invention is given the stability of composition height especially.The emulsifying agent that uses with the predetermined molar ratio example according to other raw material comprises particularly preferred condenses based on maleation polyisobutene tensio-active agent and alkanolamine, and produces with code name E-475/E-476.Its amount ranges is 0.5-3.0%, and preferable range is 1.0-3.0%.
Other emulsifying agent comprises by long-chain fat family carboxylic acid and molecular weight being the polymkeric substance of the polyoxyethylene glycol condensation prepared between the 400-3000, the ester of sorbyl alcohol and longer chain fatty acid, as polyoxyethylene-sorbitan mono-oleate (SMO), sorbitan trioleate (STO) or Arlacel-83 (SSO), phosphatide, as soybean lecithin (Qi oxazoline of SL) Huo or imidazolidine derivatives, lanolin, the tensio-active agent compatible that a kind of steroid product that obtains from wool fat or phosphoric acid ester can be buied with different trade marks with other with paraffinic fuel.
The improved emulsion explosive composition of the present invention can comprise the combination of one or more other conventional carbonaceous fuels except the highly branched paraffinic hydrocarbons fuel of the uniqueness of top indication, this depends on the desired denseness of final emulsifying composition.As embodiment, these additional carbonaceous fuels comprise Microcrystalline Wax, slack wax, paraffin, montanin wax, spermaceti (whale wax), beeswax, soil wax (agro wax), ceresine, diesel oil, paraffin oil, Yatall MA and contain other hydrocarbon fuel of paraffinic hydrocarbons, aromatic hydrocarbons, alkene or nitro carbon (nitrocarbons).
The flame quencher that uses in P-5 emulsifying composition of the present invention is selected from the secondary salt of phosphoric acid, as sodium salt, ammonium salt and sylvite, and preferred ammonium salt and/or hexametaphosphate.These salt both can have been sneaked in the aqueous solution and also can have been added with solid dopants adding or combination in two ways.Amount ranges is 0.1-10.0%, and preferable range is 0.5-8.0%, and most preferred range is 1.0-6.0%.
Except flame quencher salt of the present invention, when carrying out the tunnel experiment, comprise an alkali metal salt with other flame quencher of giving this oil-in-water emulsify explosive noninflammability, the muriate of preferred sodium or potassium with the solid dopants adding by IS:6609 (II part/the 2nd joint)-1974.Amount ranges is 5-50%, and preferable range is 10-35%.In addition, also can comprise as the flame quencher salt that describes in detail above as solid dopants.
The present invention also provides the method for producing non-incendive water-in oil emulsive explosion composition, this method comprises the aqueous solution that forms one or more inorganic oxidant salts as the described herein with arbitrary currently known methods, with arbitrary currently known methods the described aqueous solution is mixed mutually with the blend of at least a fuel, in described mixture, add one or more such solid dopants as the described herein, and with the described mixture of arbitrary currently known methods emulsification to obtain described emulsion explosive composition, in said composition, the aqueous solution of described inorganic oxidant salt constitutes 50-80% (weight), described fuel constitutes 3-60% (weight) mutually, and described solid dopants constitutes 5-50% (weight).
Preferably, in adding emulsifier unit, carry out emulsification before, the aqueous solution of oxidizer salt maintains 60 ℃-100 ℃ temperature and fuel-emulsifier mixture keeps 70 ℃-90 ℃ temperature.Emulsifier unit both the fixed static mixer also rotate emulsifying device.
With described mixture blending and this mixture of emulsification before, the flame quencher is added in the aqueous solution of described inorganic oxidant salt.
According to further feature of the present invention, in this emulsion, add as chemical gassing agent described here (gassing agent) after the emulsification to control its density.More preferably in described emulsion, add aeration agent so that it thoroughly disperses therein and promotes aeration agent and be present in interaction between the oxidizer salt in the droplet by shearing action.
If desired, the emulsion of gained can be further with arbitrary known method purifying.Depend on the purpose and the end-use of product, this emulsion can be cooled to be lower than the temperature desired of production temperature.
At last, this emulsion explosive is made into cartridge with the suitable packing of desired diameter.
Must remember that described embodiment only is to explanation of the present invention, the specific embodiment that the present invention is not limited to mention herein.
To the present invention be described by unrestriced illustrative embodiment now.
Embodiment 1
The composition weight percentage
Ammonium nitrate 45.4
SODIUMNITRATE 7.7
Sodium perchlorate (100%) 5.6
Water 7.7
PIBSA tensio-active agent 2.1
Polyoxyethylene-sorbitan mono-oleate 0.14
Paraffin oil 2.24
Latex 0.07
Sodium Nitrite 0.10
Sodium-chlor 30.00
Embodiment 2
Ammonium nitrate 42.6
SODIUMNITRATE 7.0
Sodium perchlorate (100%) 5.6
Secondary ammonium phosphate 2.8
Water 7.7
PIBSA tensio-active agent 2.1
Polyoxyethylene-sorbitan mono-oleate 0.14
Paraffin oil 1.89
Latex 0.07
Sodium Nitrite 0.10
Sodium-chlor 30.00
Carry out the inflammableness experiment by IS:6609 (II part/the 2nd joint)-1974 to be applicable to the method for filling explosive that the P5 group allows, the result is as follows:
Embodiment 1 embodiment 2 that bullet allows
Number detonation 1) under the limiting condition to methane/air 20 balls, 020 reverse ignition 565g2) directly ignite 5 balls in methane/air, 0 does not do 0
1030g3) reverse ignition 5 balls in the coal dust, 0 does not do 0
565g
Top embodiment has clearly illustrated that the effect of phosphoric acid salt in giving the nonflammable characteristic of prescription.
Claims (25)
1, non-incendive water-in oil emulsive explosion composition, comprise 50-80% (weight) the aqueous solution as inorganic oxidant salt described here, 3-60% (weight) fuel mutually and one or more of 5-50% (weight) as such solid dopants described here.
2, as desired composition in the claim 1, wherein, described oxidizer salt is selected from the perchlorate of ammonium nitrate or base metal nitrate or sodium, potassium, ammonium.
3, as desired composition in claim 1 or 2, wherein, described oxygenant comprises mutually as such flame quencher described here.
4, as desired composition in the claim 3, wherein, described flame quencher is selected from the salt of ammonium, basic metal or alkaline-earth metal or transition metal, the secondary salt of preferably phosphoric acid, more preferably hexametaphosphate.
5, as desired composition in claim 1 or 2, wherein, described doping agent comprises a kind of flame quencher.
6, as desired composition in the claim 5, wherein, described flame quencher is selected from the salt of ammonium, basic metal or alkaline-earth metal or transition metal, the secondary salt of preferably phosphoric acid, more preferably hexametaphosphate.
7, as desired composition in claim 3 or 4, wherein, described flame quencher is present in the aqueous solution of oxidizer salt, and its amount is 0.1-10% (weight).
8, as desired composition in the arbitrary claim in front, wherein said solid dopants is selected from one or more in basic metal or the alkaline earth salt.
9, as desired composition in the claim 8, wherein, described salt is the muriatic halogenide that is selected from sodium, potassium and ammonium.
10, as desired composition in the claim 5, wherein, described flame quencher exists as described doping agent, and its amount is 10-35% (weight), preferred 20-40% (weight).
11, as desired composition in the arbitrary claim in front, wherein, the water content of described composition is in the scope of 5-16% (weight).
12, as desired composition in the arbitrary claim in front, wherein, described organic-fuel comprises and being selected from by carbonaceous fuel, as low sulphur heavy oil, Microcrystalline Wax, slack wax, paraffin, montanin wax, spermaceti, beeswax, soil wax, ceresine, diesel oil, paraffin oil, Yatall MA with contain in the group that other hydrocarbon fuel of paraffinic hydrocarbons, aromatic hydrocarbons, alkene or nitro carbon forms one or more.
13, in fact as at this with reference to the described non-incendive water-in oil emulsive explosion composition of the foregoing description.
14, produce method as desired non-incendive water-in oil emulsive explosion composition in the arbitrary claim in front, this method comprises the aqueous solution that forms one or more inorganic oxidant salts as the described herein with arbitrary currently known methods, with arbitrary currently known methods the described aqueous solution is mixed mutually with the blend of at least one fuel, in described mixture, add one or more such solid dopants as the described herein and with the described mixture of arbitrary currently known methods emulsification to obtain described emulsion explosive composition, the aqueous solution at inorganic oxidant salt described in the said composition constitutes 0-80% (weight), described fuel constitutes 3-60% (weight) mutually, and described solid dopants constitutes 5-50% (weight).
15, as desired method in the claim 14, wherein, described oxidizer salt is selected from the perchlorate of ammonium nitrate or base metal nitrate or sodium, potassium, ammonium.
16, as desired method in claim 14 or 15, wherein, described oxygenant comprises mutually as such flame quencher described here.
17,, wherein, the flame quencher is added in the described solid dopants as desired method in claim 14 or 15.
18, as desired method in claim 16 or 17, wherein, described flame quencher is selected from the salt of ammonium, basic metal or alkaline-earth metal or transition metal, the secondary salt of preferably phosphoric acid, more preferably hexametaphosphate.
19, as desired method in the claim 16, wherein, described flame quencher is present in the aqueous solution of oxidizer salt, and its amount is 0.1-10% (weight).
20, as any one desired method among the claim 14-19, wherein, described solid dopants is selected from one or more in basic metal or the alkaline earth salt.
21, as any one desired method among the claim 14-20, wherein, described organic-fuel comprises and being selected from by carbonaceous fuel, as low sulphur heavy oil, Microcrystalline Wax, slack wax, paraffin, montanin wax, spermaceti, beeswax, soil wax, ceresine, diesel oil, paraffin oil, Yatall MA with contain in the group that other hydrocarbon fuel of paraffinic hydrocarbons, aromatic hydrocarbons, alkene or nitro carbon forms one or more.
22, as any one desired method among the claim 14-21, wherein, the blend of described at least a fuel comprises highly branched paraffinic hydrocarbons and/or their isomer that contains 14-40 carbon atom and one or more are as such conventional emulsifier described here.
23, as any one desired method among the claim 14-22, wherein, described emulsifying effect is to carry out in the presence of emulsifying agent, described emulsifying agent comprises that to be selected from by polyisobutene tensio-active agent and alkanolamine (alkano amines) and long-chain fat family carboxylic acid and molecular weight be the condensation product of the polyoxyethylene glycol between the 400-3000, the ester of sorbyl alcohol and longer chain fatty acid, as polyoxyethylene-sorbitan mono-oleate (SMO), sorbitan trioleate (STO) or Arlacel-83 (SSO), phosphatide, as soybean lecithin (Qi oxazoline of SL) Huo or imidazolidine derivatives, lanolin, one or more in the group that the tensio-active agent compatible with paraffinic fuel that a kind of steroid product that obtains from wool fat or phosphoric acid ester can be buied with different trade marks with other formed.
24, as any one desired method among the claim 14-23, wherein, described emulsifying effect is to carry out in the presence of conventional additives such as aeration agent and/or density depressant.
25, in fact as at this with reference to the described method for preparing non-incendive water-in oil emulsive explosion composition of the foregoing description.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 98100807 CN1225916A (en) | 1998-02-10 | 1998-02-10 | Non-incendive water-in oil emulsive explosion composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 98100807 CN1225916A (en) | 1998-02-10 | 1998-02-10 | Non-incendive water-in oil emulsive explosion composition |
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| CN1225916A true CN1225916A (en) | 1999-08-18 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102452864A (en) * | 2010-10-14 | 2012-05-16 | 中国石油化工股份有限公司 | Preparation method of powdery emulsion explosive oil phase material |
| CN102731227A (en) * | 2011-04-11 | 2012-10-17 | 四川雅化实业集团股份有限公司 | Composite emulsifier used for emulsion explosive |
| CN104355953A (en) * | 2014-10-30 | 2015-02-18 | 葛洲坝易普力湖北昌泰民爆有限公司 | Composite emulsifier for emulsion explosive and preparation method for composite emulsifier |
-
1998
- 1998-02-10 CN CN 98100807 patent/CN1225916A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102452864A (en) * | 2010-10-14 | 2012-05-16 | 中国石油化工股份有限公司 | Preparation method of powdery emulsion explosive oil phase material |
| CN102731227A (en) * | 2011-04-11 | 2012-10-17 | 四川雅化实业集团股份有限公司 | Composite emulsifier used for emulsion explosive |
| CN104355953A (en) * | 2014-10-30 | 2015-02-18 | 葛洲坝易普力湖北昌泰民爆有限公司 | Composite emulsifier for emulsion explosive and preparation method for composite emulsifier |
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