CN1223729C - Process for producing super fine fiber non-woven composite reinforced artificial leather material - Google Patents
Process for producing super fine fiber non-woven composite reinforced artificial leather material Download PDFInfo
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Abstract
The present invention relates to a method for producing nonwoven composite reinforced artificial leather material of superfine fibers. Superfine fibers whose fiber cross sections are arranged into the shape of an island are used as the principal raw material of nonwoven fabric. Thin-layer reinforced material which has gaps and low compactness is additionally formed by processing polyester, or polyamide, or polgolefin and other material with a spun-bond method, a melt-spray method and a hot pressing method or processing processed silk by a weaving machine and a knitting machine. Superfine fiber nonwoven fabric is formed by compounding and reinforcing the superfine fibers and the thin-layer reinforced material which are tangled and combined in a needle punching mode or a water needle punching mode. Elastic body resin compositions are dipped or coated, and an artificial leather semi-finished product is formed after solidification, water wash, drying and quantity reduction. Artificial leather material which has true leather texture is made by carrying out strippable paper transfer sticking processing, or facing processing or embossing processing, or artificial leather material which imitates deer skin is made by milling and dyeing the artificial leather semi-finished product. The present invention can solve the problem that difference exists in longitudinal and transverse elongation rates. The present invention is suitable for making artificial leather.
Description
Technical field
The present invention is the manufacture method of relevant a kind of artificial leather material, the manufacture method of refering in particular to a kind of artificial leather material of superfine fibre non-woven complex intensifying.
Background technology
At present general superfine fibre artificial leather is mostly with the spinning of composite spinning mode, and its fineness can't be lower than 0.015 Denier (Denier), so that when being used in leather surface, can't obtain as the careful fine hair sense as the deerskin.The superfine fibre artificial leather that makes with the blend spinning mode of tradition and for example, though surperficial have as the careful fine hair sense as the deerskin, strength of leather is very poor.
Consult shown in Figure 1, superfine fibre is via impregnation polyurethane (polyurethane, hereinafter referred to as PU) resin combination, and make artificial leather is known, wherein used superfine fibre, for example: No. 152961 case of TaiWan, China patent announcement (application case number No. 78107985) name is called " the compound ultra tiny non-fiber fabric of similar corium ", its processing procedure as shown in Figure 1, its compound ultra tiny fiber that is to use the 0.8-30 Denier is through comb and parallel cotton fibers prior to spinning, folded cotton, tailor's cushion, condense after containing resin pickup and impregnation PU resin, washing and oven dry, with solvent with in the compound ultra tiny fiber one of composition flush away part, again through grinding and compound ultra tiny fiber Nonwovens and back processing.Its major defect is:
1, the ground non-woven of the traditional superfine fibre of this kind, vertically the percentage elongation difference with horizontal is very big because of it, and especially cross direction elongation is higher, problem that often need the consideration directionality uses in, and the inapplicable artificial leather of doing.
2, as another with liquid drugs injection rolling the superfine fibre non-woven, its non-woven surface has tangible liquid drugs injection vestige mostly, and interlaminar strength is not high, and improper as artificial leather.Composite spinning and fiber and formed superfine fibre and these various manufacture methods are known technologies.Composite spinning and fiber, generally be to give integrator by squeezing out at least two kinds of compatible fibre-forming polymers, make to generate optionally one of polymer dissolving of fiber, and form microfibre.
In addition, tradition is a known technology by the artificial leather of braided fabric through giving reinforcement, in for example Japanese special fair 4-1113 communique, discloses the technology that the braided fabric that has the above high twist yarn of twisting count 1000T/m to form is used as the reinforcement material.This technology is to adopt tailor's cushion, make when short cellucotton non-woven and being integral of reinforcement cloth and silk, with the reinforcement cloth and silk that suppresses to cause by tailor's cushion damage to Min. be purpose, high strength is proposed and the method for making of the artificial leather of softness.To adopting tailor's cushion to make short cellucotton non-woven and laminated being integral of reinforcement cloth and silk, bestow the contraction of a little after, make dipping adhere to polyvinyl alcohol again, then the part of part principal fiber is removed in extraction, floods elastic resin again and gets artificial leather.Its main pluses and minuses are:
1, since be with make the reinforcement cloth and silk have with the superfine fibre non-woven through giving incorporate higher cut-out intensity, and the tectosome with flexibility is a purpose, intensity level when artificial leather cuts off is higher, if when only the state of non-fiber fabric is compared, then because the effect of reinforcement material, the certain step-down of the morphotropism of artificial leather is even but so, the morphotropism of the scope 10% is also quite high.That is when aforesaid technology, the damage that the reinforcement cloth and silk generates when tailor's cushion though can give inhibition, is reached though the high strength of the artificial leather after the complexing can give, aspect the apparent density of the non-fiber fabric after complexing and improper.That is, the purpose that apparent density is improved, even adopt the skill make non-woven thermal contraction after the complexing, technical elements at this communique, non-fiber fabric is because of having shrinkage hardly, so only can obtain to be equivalent to a little kenel change process that the torque of heavy twist long fiber silk of the formation silk of reinforcement cloth and silk is removed by heat treatment.In fact, apparent density for the laminated thing of each sheet of improving non-woven and cloth and silk, if one of heat treatment non-woven, cloth and silk, and make contraction, make on laminated artificial leather by heat treatment curling or wrinkling, concave-convex surface etc. takes place, step thereafter perplexs, and the goods grade is reduced.
2, if again when making the three-layered lamination kenel of non-woven/cloth and silk one fabric, though have contraction, its degree becomes very little, and apparent density then almost improves.
3, again in above-mentioned communique, though record to make and adhere to PVA, but when giving PVA, fibre space portion is the filling of PVA institute, interfibrous spatial portion in this kind artificial leather becomes big, therefore the apparent density step-down of the artificial leather that makes when stretcher strain, also becomes the artificial leather structure of easy deformation.
Again, in Japanese kokai publication sho 55-57059 communique, announcement has by having the reinforcement cloth and silk that potential inotropic long fiber forms, this makes laminated being integral of the thing interlacing artificial leather of copying paper non-woven and this reinforcement cloth and silk that is formed by the staple fibre below the fibre length 10mm by High-Pressure Water after, the reinforcement cloth and silk is shunk, with the method for the apparent fibre density that improves artificial leather.Its main pluses and minuses are:
1, because it is to copy the paper non-woven about the reinforcement cloth and silk that formed by potential shrinkage long fiber and by what the staple fibre below the fibre length 10mm formed, through giving the cloth and silk that the current interlacing forms, because of being to copy the paper non-woven, it is less to constitute each interfibrous complexing, and and the reinforcement cloth and silk between complexing also low.Also only a little adheres to elastic resin, and when artificial leather was applied distortion, non-woven almost there is no deformation resistance and benefits, and the degree of the morphotropism of being reached itself promptly has the formation of having to lower.
When 2, observing the performance of goods again, because said method is, the shortcoming that also has fiber to come off easily than artificial leather.Separately after the complexing end with non-fiber fabric, when lamination reinforcement is used the method for cloth and silk overleaf, if when selecting back side applying material, all can control the deformation resistance of artificial leather whichsoever, more only with the state of non-woven, because of carrying out shrink process, if when adopting the shrinkage non-woven, though can make apparent density the higher person, between non-fiber fabric and reinforcement cloth and silk engage a little less than, add and can peel off man-hour, and need the step of usefulness for fitting, the shortcoming that therefore has manufacturing cost to improve exists.
For more effectively produce high deformation resistance (that is vertically and horizontal percentage elongation difference make laminated reinforcement cloth and silk when being the lower state of complexing degree in non-fiber fabric itself than engaging between person of low position's non-fiber fabric and reinforcement cloth and silk, make both mechanically very firm complexings promptly preferable by current or tailor's cushion.So by laminated complexing reinforcement cloth and silk, especially by fully selecting the reinforcement cloth and silk, the characteristic of the deformation resistance of end article artificial leather not only can be given and being invested, in the fabrication steps of majority, the kenel of fiber artificial leather changes the elongation that its processing procedure pulling force causes) can be suppressed, especially when making the artificial leather of imitation buckskin, surface fiber density is the most important factor of decision goods grade, improves the apparent density of combined artificial leather and the emphasis taked is:
1,, needs to improve apparent density by the contraction of non-fiber fabric;
2, it is more important need making the elongation that does not cause because of the processing procedure pulling force.
Yet, to so far technology, still fail to make kenel and change (especially processing procedure pulling force cause elongation) and can give inhibition, and apparent density the higher person.
Summary of the invention
The purpose of this invention is to provide the manufacture method of a kind of superfine fibre non-woven through the artificial leather material of complex intensifying, add the reinforcement material by the superfine fibre non-woven, make its superfine fibre non-woven that becomes compound kenel, can be for use as the superfine fibre non-woven of light weight, high strength, high flexibility artificial leather material through complex intensifying.
Use the superfine fibre non-woven after strengthening to be the artificial leather of ground, not only can improve the problem that differs greatly at vertical and cross direction elongation, also can make the superfine fibre artificial leather that higher pliability transitivity intensity is arranged, more can make the high-intensity superfine fibre non-woven of low weight, behind impregnation elastomer resin constituent, can alleviate the weight of former superfine fibre artificial leather, the elastomer resin constituent of manufacture process institute impregnation wherein, can add the colorant of multiple needs, increase diversified color and luster and select.
The object of the present invention is achieved like this: a kind of manufacture method of artificial leather material of superfine fibre non-woven complex intensifying, it is characterized in that: it is to be arranged in the superfine fibre of island shape via blend spinning method or the spun fiber section of composite spinning method, main raw material as non-woven, choose polyester in addition, polyamide or polyolefinic at least a, via spunbond, melt and spray, pressure sintering or by a processing silk warp-knit cloth machine, knitting machine and form and have space and loose thin layer Rankine, this thin layer Rankine rolls mode by tailor's cushion or liquid drugs injection, superfine fibre is tangled with the thin layer Rankine to be combined, the superfine fibre non-woven of formation behind complex intensifying, by impregnation or coating elastic resin constituent, through supersolidification, washing, after drying and the decrement, form the artificial leather semi-finished product, these artificial leather semi-finished product are made the artificial leather with corium lines through following process; This superfine fibre be configured to sea-island composite fiber, its fineness is the 1-10 Denier.This superfine fibre through molten go the sea composition after, the fibre bundle of its island composition disperses into the superfine fibre of 0.0001-0.1 Denier.
The thickness of this thin layer Rankine is that the weight of 0.01-1.0mm, unit are is 10-200g/m
2And the space is the 10-150 sieve mesh.This following process be included on these artificial leather semi-finished product coating one liquid type polyurethane constituent as investment precoat on release liners, be coated with two-liquid type polyurethane constituent again as adhesive linkage, on these artificial leather semi-finished product, impose the processing of fitting, make artificial leather.This following process is included in these artificial leather semi-finished product and imposes sand paper and grind out the mercerising filoplume, and the processing of being dyeed, and makes the superfine fibre artificial leather of imitation buckskin.This thin layer Rankine rolls mode by tailor's cushion or liquid drugs injection, superfine fibre is tangled with the thin layer Rankine to be combined, the superfine fibre non-woven of formation behind complex intensifying, by impregnation and after directly being coated with the PU resin combination, through solidify, after washing, drying and the decrement, form the artificial leather semi-finished product, these artificial leather semi-finished product are made diversified artificial leather through veneer processing or embossing processing or attrition process.
Further specify below in conjunction with preferred embodiment and accompanying drawing.
Description of drawings
Fig. 1 is the schematic diagram of fabrication technology of conventional method.
Fig. 2 is a schematic diagram of fabrication technology of the present invention.
Fig. 3 is another schematic diagram of fabrication technology of the present invention.
The specific embodiment
Consult Fig. 2-shown in Figure 3, superfine fibre non-woven of the present invention is through the manufacture method of the artificial leather material of complex intensifying, mainly be to be arranged in the main raw material of the superfine fibre of island shape as non-woven with spinning the fiber section via blend spinning method or composite spinning method, use polyester or materials such as polyamide or TPO in addition, through spunbond (spunbond), melt and spray (meltb1own), hot pressing (calender) method or by a processing silk warp-knit cloth machine, knitting machine, and be formed with space and loose thin layer Rankine, with above-mentioned thin layer Rankine, utilize tailor's cushion or liquid drugs injection to roll mode, superfine fibre is tangled with the thin layer Rankine combine, form the superfine fibre non-woven.Superfine fibre non-woven impregnation behind the complex intensifying or coating are with the elastomer resin constituent, through solidify, wash, after dry, the decrement, form the artificial leather semi-finished product, on the artificial leather semi-finished product, make release liners again and change subsides processing, or implement veneer and process, or embossing processing, and must have the artificial leather material of corium lines, or on the artificial leather semi-finished product, implement to grind, dyeing processing and the artificial leather material of imitation buckskin.
The superfine fibre non-woven relevant with the present invention, artificial leather material and method for making thereof through complex intensifying, it strengthens kenel and process, be with polyamide 6, polyamide such as polyamide 66 (NYLON) based polymer, or polyethylene terephthalate (PET), polytrimethylene terephthalate (PPT), polybutylene terephthalate (PBT) polyester based polymer, with polystyrene (PS), polyethylene (PE), polypropylene (PP), TPO such as polymethylpentene, or thermoplasticity polyvinyl alcohol, water-soluble copolyester, thermoplastic polyurethane, via blend spinning method or composite spinning method, spin the fiber section and be arranged in the main raw material of the superfine fibre of island shape as non-woven, wherein superfine fibre be configured to sea-island composite fiber, its Denier is a 1-10 Denier scope.Superfine fibre through molten remove its " sea component " after, the fibre bundle of " island component " that stays can be dispersed into ultra-fine fiber, its fineness is a 0.0001-0.1 Denier scope.
Use polyester or materials such as polyamide or TPO in addition, through spunbond, melt and spray, pressure sintering or be formed with the space by a processing silk warp-knit cloth machine, knitting machine, and loose thin layer Rankine, the weight 10-200g/m of its thickness 0.01-1.0mm, unit are
2, the 10-150 sieve mesh.Above-mentioned thin layer Rankine is added in non-woven tailor's cushion or the rolling journey of liquid drugs injection, utilize tailor's cushion or the liquid drugs injection mode of rolling that superfine fibre is tangled with the thin layer Rankine and combine, form the superfine fibre non-woven.
Superfine fibre non-woven impregnation elastomer resin constituent (comprising dissolution with solvents type elastomer resin and water-soluble type elastomer resin) after strengthening again, this elastomer resin constituent can add colorant according to required color, for example dissolution with solvents type elastomer resin constituent impregnation amount is the heavy 0.5-3.0 of base cloth times, again with the coagulating bath of the DMF of 5-50%, carry out the exchange interaction of DMF and water, with 70-100 ℃ of washing, 100-160 ℃ of baking temperature, form rubber-like sclerderm material, again through the decrement process, and form the artificial leather semi-finished product.These artificial leather semi-finished product are carried out release liners change subsides processing, and must have the artificial leather material of corium superficial makings, or implement to grind, dye and process, and the artificial leather material of imitation buckskin, also can be after the impregnation of superfine fibre non-woven, the PU resin combination directly is covered, to reduce processing procedure, and, can on formed artificial leather semi-finished product, implement veneer processing or embossing processing or attrition process, and get diversified artificial leather material again through the decrement process.
Wherein the artificial leather semi-finished product can be coated with a liquid type polyurethanes constituent as investment precoat on release liners, be coated with two-liquid type polyurethanes constituent again as adhesive linkage coating, on the artificial leather semi-finished product, impose veneer processing, and get artificial leather material.
Superfine fibre artificial leather goods and the method for making thereof relevant with the present invention, wherein employed superfine fibre non-woven can adopt the inventor's the superfine fiber fabric that makes in first to file No. 02140697.9 " manufacture method of high density superfine fiber fabric ", its used polymer has two kinds, wherein a kind of is can be by solvent or the molten polymer that removes of hot water, another kind of is by solvent or the hot water part is molten removes or the insoluble polymer that removes, mix according to the weight or volume ratio, and utilize the spinneret that is fan-shaped array to add another kind simultaneously and do not carried out composite spinning by solvent or the molten polymer that removes of hot water, and get the superfine fibre of two kinds of fineness degrees.Wherein can be polystyrene (PS), polyethylene (PE), thermoplastic polyurethane (TPU), can be thermoplasticity polyvinyl alcohol (TPVA) or water-soluble copolyester that wherein water-soluble copolyester is the co-polymer that contains M-phthalic acid (IPA), terephthalic acid (TPA) (TPA), acrylic acid (AA), sulfonate sodium (SIP) or polyethylene glycol (PEG) composition by the molten polymer that removes of solvent by the water-soluble polymer that removes.And thermoplasticity polyvinyl alcohol (TPVA) is added water decomposition 70-100% with polyvinyl acetate (PVAc), is preferably 75-95%, and the polyvinyl alcohol that gets.This polyvinyl alcohol is other water-soluble polymer that contains plasticizer class additive, PVP, poly-ethyl oxazoline, poly(ethylene oxide) class.
And, polyester polymer, polyamide polymers or polyolefin are arranged not by solvent or the molten polymer that removes of hot water.Above-mentioned polyester polymer is meant polyethylene terephthalate (PET) and polytrimethylene terephthalate (PPT) and polybutylene terephthalate (PBT);
Polyamide polymers is meant nylon 4 (Nylon4), nylon 6 (Nylon6), nylon 66 (Nylon66), NYLON610 (Nylon610) or nylon 11 (Nylon11);
The water-insoluble polyolefin is meant polyethylene, polypropylene, polystyrene, polyvinyl acetate, polybutene or these copolymer.
The superfine fibre non-woven relevant with the present invention is through the method for making of the artificial leather material of complex intensifying, wherein the decrement step is meant and utilizes as alkali lye, tetrachloro-ethylene, toluene, dimethyl formamide equal solvent or water, with before the spinning step with can by solvent molten remove or can by the water-soluble mixed with polymers of removing not by solvent or the molten polymer that removes of hot water (as polyamide polymers, polyester polymer or polypropylene) the branch fibre, fineness behind the branch fibre can reach the 0.0001-0.1 Denier, the microvilli of gained passes through grinding steps again, and its surface more can present very careful fine hair sense.
Generally speaking the derived product of using superfine fibre and getting, because the surface only has quite careful down, its rerum natura is (as peel strength, tensile strength or tearing strength) neither good, but fine hair of the present invention is except that having down, the long wool hair is also arranged, and this general superfine fibre of long wool hair Strengthenable and the not good shortcoming of rerum natura of derived product.
The present invention utilizes tailor's cushion or liquid drugs injection to roll mode, make through mix or the spun superfine fibre of composite spinning method with by materials such as polyester or polyamide or TPO, through spunbond, melt and spray, pressure sintering or by a processing silk warp-knit cloth machine, knitting machine and form have a space, and loose thin layer Rankine tangles combination, form the superfine fibre non-woven, this kind thin layer Rankine and superfine fibre maybe can give the complexing of the non-woven that the fiber of super-refinement forms, as long as handle or roll processing etc. in the High-Pressure Water complexing, in the time of can effectively carrying out the method for complexing processing, though which kind of method all can, its tailor's cushion processing method with high complexing is good.
Above-mentioned behind complex intensifying the cloth impregnation of superfine fibre non-woven or the coating with the elastomer resin constituent, through solidifying, wash, forming the artificial leather semi-finished product after dry, the decrement, on the artificial leather semi-finished product, make release liners again and change subsides processing, or implement veneer and process, or embossing processing, and must have the artificial leather material of corium lines, or on the artificial leather semi-finished product, implement to grind, dyeing processing, and the artificial leather material of imitation buckskin.So and the artificial leather material of superfine fibre non-woven complex intensifying, can solve vertically the problem with horizontal percentage elongation difference, be suitable for and make artificial leather.
The superfine fibre non-woven cloth institute's impregnation behind complex intensifying or the elastomer resin constituent of coating, can be rubber-like elastic bodies such as polyurethane, SBR, NBR, poly-Amino acid, interior olefin(e) acid ester system, with regard to the sense of touch of the artificial leather of gained, adding the comprehensive consideration of various rerum naturas, is best with polyurethane.Though the elastomer resin constituent should use in the solution mode, and can give the wet type person of solidifying, and then dislikes inferior slightly in the sense of touch aspect, aspect purposes, with separately or merge the water-based emulsion that uses polyurethane series or acrylic ester etc. and also can.
As for the amount of the rubber-like elastic body resin combination of giving, be advisable with the 10-25% of the fibre weight that constitutes artificial leather.
Moreover, the surface of the superfine fibre non-woven side of the artificial leather of gained is made its perpendicular hair with sand paper grinding etc., dyed processing can get the artificial leather material of imitation buckskin.Again in surface coated with resin, make the perpendicular hair in surface with replacement, embossing is handled or leveling is handled by carrying out, to the concave-convex surface that makes into the natural leather local flavor, can be with bright artificial leather.To the artificial leather of gained, moreover in response to needs, the processing of also can dyeing, or other arrangement processing.
The present invention spins superfine fibre with mixing or composite spinning method, other uses polyester or materials such as polyamide or TPO, through spunbond, melt and spray, pressure sintering or by a processing silk warp-knit cloth machine, knitting machine and form and have the space, and loose thin layer Rankine, roll through tailor's cushion or liquid drugs injection again, superfine fibre is tangled with the thin layer Rankine to be combined, formation is the superfine fibre non-woven behind complex intensifying, impregnation or coating are with the elastomer resin constituent, through solidifying, washing, in dry, after the decrement, form the artificial leather semi-finished product, on the artificial leather semi-finished product, make release liners again and change subsides processing, or implement veneer processing, or embossing processing, and must have the artificial leather material of corium lines, or on the artificial leather semi-finished product, implement to grind, dyeing is processed, and gets the artificial leather material of imitation buckskin.So and the artificial leather material of superfine fibre non-woven complex intensifying, can solve vertically the problem with horizontal percentage elongation difference, be suitable for and make artificial leather.
Above-mentioned Fig. 2 is that with the difference of Fig. 3 method for processing is different thereafter, can make the multiple artificial leather material with different-style.
Below describe example of the present invention in detail by specific embodiment, still, protection scope of the present invention is not limited by these embodiment.
Embodiment 1
Embodiments of the invention 1 be adopt polyamide 6 as island component and polystyrene (PS) as sea component, ratio with 50/50 is carried out composite spinning, the melt temperature of a nozzle of reeling off raw silk from cocoons is 280 ℃, coiling speed is 900m/min, the last drawn yarn that makes, stretch for 80 ℃ with draft temperature again, after the stretching again drying, cut steps such as cotton, making fiber number is that 4.0dpf, length are the sea-island composite fiber cotton of 51mm.
With its sea-island composite fiber cotton, be carded to even web through carding machine, and be overlapping with folded cotton forming machine, form the web laminate, with 100% nylon 6 processing yarns of 70denier, being woven into thickness with loom is 0.15mm, weight 35g/m again
2, 30mesh thin layer Rankine tailor's cushion combination, impose 700 times and add/m
2Roll pin density, form tool and divide 340g/m
2The superfine fibre non-woven of complex intensifying.
Again with the superfine fibre non-woven after 40 fens PU constituents and the above-mentioned reinforcement of coating impregnation that constituted of 60 fens dimethyl formamides (DMF), in PU resin combination impregnation amount is heavy 1.8 times of base cloth, and after adding red colorant, with 25% DMF, carry out coagulating bath again at 25 ℃, carry out the exchange interaction of DMF and water, with 100 ℃ of washings, after 125 ℃ of dryings, form rubber-like sclerderm material, again through the decrement process, and form the artificial leather semi-finished product.Coating one liquid type polyurethane constituent investment precoat on release liners, then be coated with two-liquid type polyurethane constituent adhesive linkage, on the artificial leather semi-finished product, impose the processing of fitting, that continues handles engineering through maturation, release surface, and obtains having the superfine fibre artificial leather goods of corium texture.
The superfine fibre artificial leather goods that the foregoing description 1 makes are more as shown in table 1 with the rerum natura of the superfine fibre artificial leather goods of general veneer.
Table 1
| Project | Artificial leather of the present invention | General superfine fibre artificial leather | Reference to standard |
| Thickness mm | 1.10 | 1.10 | ASTM D-1777 |
| Mass area ratio g/m 2 | 330 | 430 | ASTM D-751 |
| Percentage elongation (vertically) % | 79 | 68 | ASTM D-1682 |
| Percentage elongation (laterally) % | 87 | 119 | ASTM D-1682 |
| Draw resistance to spalling (vertically) kgf | 10.1 | 9.8 | ASTM D-1682 |
| Draw resistance to spalling (laterally) kgf | 13.5 | 12.5 | ASTM D-1682 |
| Rupture strength kgf/cm 2 | 31.3 | 29.6 | ASTM D-751 |
| Peel strength (laterally) N/cm | 32 | 25 | DIN 53273 |
Embodiment 2
Has a 340g/m with formed among the embodiment 1
2The superfine fibre non-woven of complex intensifying, the coating that forms with 40 parts of PU constituents and 60 parts of dimethyl formamides (DMF) contains the superfine fibre non-woven that is immersed in after the reinforcement again, after the PU resin is made into thing impregnation amount and is heavy 1.8 times of base cloth, carry out coagulating bath with 25%DMF at 25 ℃ again, carry out the exchange interaction of DMF and water, with 100 ℃ of washings, after 125 ℃ of dryings, form rubber-like sclerderm material, again through the decrement process, formation artificial leather semi-finished product implement to grind, dye processing in the artificial leather semi-finished product again, and get the superfine fibre artificial leather goods of imitation buckskin.
Embodiment 3
Has a 340g/m with formed among the embodiment 1
2The superfine fibre non-woven of complex intensifying, the coating that forms with 40 parts of PU constituents and 60 parts of dimethyl formamides (DMF) contains the superfine fibre non-woven that is immersed in after the reinforcement again, the PU resin be made into thing impregnation amount be base cloth heavy 1.8 times and add blue look colorant after, directly lining PU resin is made into thing, carry out coagulating bath with 25%DMF at 25 ℃ again, carry out the exchange interaction of DMF and water, with 100 ℃ of washings, after 125 ℃ of dryings, form rubber-like sclerderm material,, form the artificial leather semi-finished product again through the decrement process, and directly sentence embossing processing, form the superfine fibre artificial leather goods that the surface has the corium texture.
The method that TaiWan, China patent announcement the 152961st good " the compound ultra tiny fibre of similar corium is given non-woven " disclosed, fiber number only is the 0.015-0.6 Denier after its decrement; And this fiber number of superfine fibre artificial leather semi-finished product after decrement is the 0.0001-0.05 Denier, and, have characteristics such as in light weight, high flexibility, high object intensity.Above-mentioned two kinds more as shown in table 2.
Table 2
| Project | Superfine fibre semi-finished product of the present invention | The Taiwan patent application case | Reference to standard |
| Thickness mm | 1.0 | 1.0 | CNS1274 |
| Mass area ratio g/m 2 | 250 | 300 | ASTM D-751 |
| Tearing strength (vertically) kgf | 7.1 | 5.8 | CNS1279 |
| Tearing strength (laterally) kgf | 6.7 | 5.8 | |
| Tension intensity (vertically) kgf | 42 | 38 | CNS1278 |
| Tension intensity (laterally) kgf | 44 | 36 |
As known from Table 2, the superfine fibre artificial leather goods that the inventive method makes and the like product of conventional method are under same size, goods of the present invention have in light weight, high rerum natura intensity, the vertical and horizontal close effect of percentage elongation, and also have system and be the advantage that simplifies with diversified artificial leather, be applicable to the artificial leather of making gloves, clothing, shoes, chair cover, suitcase, sofa, ball and analog thereof.
Claims (5)
1, a kind of manufacture method of artificial leather material of superfine fibre non-woven complex intensifying, it is characterized in that: it is to be arranged in the superfine fibre of island shape via blend spinning method or the spun fiber section of composite spinning method, main raw material as non-woven, choose polyester in addition, polyamide or polyolefinic at least a, via spunbond, melt and spray, pressure sintering or by a processing silk warp-knit cloth machine, knitting machine and form and have space and loose thin layer Rankine, this thin layer Rankine rolls mode by tailor's cushion or liquid drugs injection, superfine fibre is tangled with the thin layer Rankine to be combined, the superfine fibre non-woven of formation behind complex intensifying, by impregnation or coating elastic resin constituent, through supersolidification, washing, after drying and the decrement, form the artificial leather semi-finished product, these artificial leather semi-finished product are made the artificial leather with corium lines through following process; This superfine fibre be configured to sea-island composite fiber, its fineness is the 1-10 Denier; This superfine fibre through molten go the sea composition after, the fibre bundle of its island composition disperses into the superfine fibre of 0.0001-0.1 Denier.
2, the manufacture method of the artificial leather material of superfine fibre non-woven complex intensifying according to claim 1 is characterized in that: the thickness of this thin layer Rankine is that the weight of 0.01-1.0mm, unit are is 10-200g/m
2And the space is the 10-150 sieve mesh.
3, the manufacture method of the artificial leather material of superfine fibre non-woven complex intensifying according to claim 1, it is characterized in that: this following process be included on these artificial leather semi-finished product coating one liquid type polyurethane constituent as investment precoat on release liners, be coated with two-liquid type polyurethane constituent again as adhesive linkage, on these artificial leather semi-finished product, impose the processing of fitting, make artificial leather.
4, the manufacture method of the artificial leather material of superfine fibre non-woven complex intensifying according to claim 1, it is characterized in that: this following process is included in these artificial leather semi-finished product and imposes sand paper and grind out the mercerising filoplume, and the processing of being dyeed, make the superfine fibre artificial leather of imitation buckskin.
5, the manufacture method of the artificial leather material of superfine fibre non-woven complex intensifying according to claim 1, it is characterized in that: this thin layer Rankine rolls mode by tailor's cushion or liquid drugs injection, superfine fibre is tangled with the thin layer Rankine to be combined, the superfine fibre non-woven of formation behind complex intensifying, by impregnation and after directly being coated with the PU resin combination, through solidify, after washing, drying and the decrement, form the artificial leather semi-finished product, these artificial leather semi-finished product are made diversified artificial leather through veneer processing or embossing processing or attrition process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021460833A CN1223729C (en) | 2002-10-25 | 2002-10-25 | Process for producing super fine fiber non-woven composite reinforced artificial leather material |
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| Application Number | Priority Date | Filing Date | Title |
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| CNB021460833A CN1223729C (en) | 2002-10-25 | 2002-10-25 | Process for producing super fine fiber non-woven composite reinforced artificial leather material |
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| Publication Number | Publication Date |
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| CN1492102A CN1492102A (en) | 2004-04-28 |
| CN1223729C true CN1223729C (en) | 2005-10-19 |
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| CNB021460833A Expired - Fee Related CN1223729C (en) | 2002-10-25 | 2002-10-25 | Process for producing super fine fiber non-woven composite reinforced artificial leather material |
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| CN (1) | CN1223729C (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100658097B1 (en) * | 2005-12-19 | 2006-12-14 | 주식회사 코오롱 | Suede like artificial leather with excellent strength and elongation properties |
| CN101575809B (en) * | 2009-06-01 | 2011-02-16 | 泉州万华世旺超纤有限责任公司 | Superfine fiber mirror crystal leather preparation method |
| CN101798764B (en) * | 2009-12-21 | 2012-10-10 | 厦门泓信超细纤维材料有限公司 | Dyeing method of artificial leather |
| CN102268821A (en) * | 2011-06-21 | 2011-12-07 | 浙江拓空实业有限公司 | Method for manufacturing artificial leather by utilizing two-component liquid polyurethane |
| CN102321979B (en) * | 2011-08-04 | 2013-01-30 | 华伦皮塑（苏州）有限公司 | Manufacturing method of backer-free synthetic leather |
| CN103437069A (en) * | 2013-09-06 | 2013-12-11 | 天津工业大学 | Production method of sea-island type superfine fiber artificial leather base cloth |
| CN103628267B (en) * | 2013-12-04 | 2015-09-30 | 北京富泰革基布股份有限公司 | Polyamide fiber and polyester fiber composite synthesis are removed from office and processing technology |
| TWI585251B (en) * | 2014-08-22 | 2017-06-01 | San Fang Chemical Industry Co | Composite long fiber textile and its use of the environmental protection of synthetic long fiber artificial leather |
| CN105133373B (en) * | 2015-10-19 | 2018-01-19 | 广州罗格朗皮具有限公司 | A kind of preparation method of artificial suede |
| CN105715627B (en) * | 2016-03-21 | 2018-02-06 | 西安天厚滤清技术有限责任公司 | A kind of method and apparatus for preventing hydraulic system oil leak |
| CN106073025B (en) * | 2016-07-23 | 2017-10-17 | 刘光有 | A kind of preventing wrinkle method and its application on preventing wrinkle vamp |
| CN110857534B (en) * | 2018-08-22 | 2022-05-06 | 三芳化学工业股份有限公司 | Artificial leather and method for producing same |
| CN109397824A (en) * | 2018-10-19 | 2019-03-01 | 江苏尚科聚合新材料有限公司 | A kind of soft abrasion-resistant artificial leather and preparation method thereof |
| CN110819127B (en) * | 2019-11-29 | 2022-06-17 | 诺博橡胶制品有限公司 | Door sealing strip LIP, door sealing strip manufacturing method and automobile |
| CN111926580A (en) * | 2020-08-03 | 2020-11-13 | 安安(中国)有限公司 | Polyester microfiber synthetic leather and processing method thereof |
| CN112281316B (en) * | 2020-09-27 | 2022-06-07 | 福建华阳超纤有限公司 | High-quality imitation cow leather superfine fiber leather processing system |
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2002
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| CN1492102A (en) | 2004-04-28 |
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