CN1223564A - Aqueous nacreous lustre concentrates - Google Patents
Aqueous nacreous lustre concentrates Download PDFInfo
- Publication number
- CN1223564A CN1223564A CN 97195236 CN97195236A CN1223564A CN 1223564 A CN1223564 A CN 1223564A CN 97195236 CN97195236 CN 97195236 CN 97195236 A CN97195236 A CN 97195236A CN 1223564 A CN1223564 A CN 1223564A
- Authority
- CN
- China
- Prior art keywords
- alkyl
- carbon atoms
- nacreous lustre
- alcohol
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
A novel aqueous nacreous lustre concentrates contains, in relation to the non-aqueous proportion, (a) 1 to 99.1% wt. of fats selected from the group formed by fatty alcohols, fatty ketones, fatty ethers and fatty carbonates, provided that the substances contain at total of at least 18 carbon atoms, (b) 0.1 to 90% wt. of anionic, non-ionic, cationic, ampholytic and/or zwitterionic emulsifiers, and(c) 0 to 40% wt. of polyols, provided that the quantities add up to 100% wt.
Description
The present invention relates to a kind of aqueous nacreous lustre concentrates that comprises selected aliphatic compound, emulsifying agent and polyhydric alcohol in case of necessity, its preparation method uses the preparation of this concentrate that the method for surface activity preparation of nacreous lustre and this aliphatic compound purposes as nacreous lustre wax is arranged.
Centuries, the gloss soft, flash of light of Margarita produces special captivation to the mankind.Therefore, the manufacturer of cosmetics attempt to give its product attractive, famous and precious with gorgeous feature be no wonder.The nacreous lustre that use at first Middle Ages in cosmetics is the unguentum of being made by natural fish scale that nacreous lustre is arranged.Find that bismuth oxychloride can produce nacreous lustre equally the beginning of this century.In contrast, for up-to-date cosmetics, what play important meaning is pearlescent waxes, particularly ethylene glycol fatty acid ester and di fatty acid ester, and they mainly use in shampoo and body lotion to produce nacreous lustre.At the Parf.Kosm.75 of A.Ansmann and R.Kawa, delivered the general introduction of modern nacreous lustre preparation in 578 (1994).
Prior art discloses many preparations that surfactant with desired nacreous lustre is provided.Here, for example German patent application DE-A13843572 and DE-A14103551 (Henkel) disclose a kind of nacreous lustre concentrates that exists with flowable aqueous dispersion form, and it comprises the component of the nacreous lustre of 15～40 weight %, the emulsifying agent of 5～55 weight % and the polyhydric alcohol of 0.1～5 or 15～40 weight %.Nacreous lustre wax is saturated fatty acid of poly alkylene glycol, strand alkanolamide, the straight chain of acyl groupization or ketone group sulfone class.At European patent application EP-B10181773 and EP-B10285389 (Pricter﹠amp; A kind of shampoo composite that contains surfactant, non-volatile silicone and nacreous lustre wax is proposed Gamble).The content of European patent application EP-A20205922 (Henkel) is the flowable nacreous lustre concentrates of the nonionic emulsifier of the fatty monoethanol amide of a kind of acyl group polyglycols that comprises 5～15 weight %, 1～6 weight % and 1～5 weight %.According to European patent EP-B10569843 (Hoechst) described by 5～30 weight % the acyl group polyglycols and the mixture of the selectivity non-ionic surface active agent preparation of 0.1～20 weight % equally also can obtain a kind of non-ionic, flowable nacreous lustre dispersion.Disclose the nacreous lustre dispersion of another kind of flowable, preservative free by European patent application EP-A20581193 (Hoechst), it contains polyglycol ether, betanin, anion surfactant and the glycerol of acyl groupization.At last, polyglycerin ester is proposed as the purposes of crystallization auxiliary at European patent application EP-A10684302 (Th.Goldschmidt) at the preparation nacreous lustre concentrates.
Although many preparations are arranged; but on market, still need a kind of new nacreous lustre wax; this nacreous lustre wax is for example different with the polyglycols of acyl groupization; it does not contain ethylene oxide unit; and be with the different of product of the prior art; when less use amount, still has outstanding especially gloss; therefore allow common key component such as the silicone of using; and can not damage stability of formulation; contain ester group simultaneously, therefore can guarantee enough biological degradabilities, especially; be easy to when existing flow with conc forms, and thereby easy operating.The purpose of this invention is to provide a kind of new nacreous lustre concentrates that satisfies various requirement.
Theme of the present invention is a kind of aqueous nacreous lustre concentrates, and with dry weight basis, it comprises:
(a) 1～99.1 weight % is selected from the aliphatic category chemical compound in aliphatic alcohol, aliphatic ketone, fatty ether and the aliphatic acid ester carbonate, and wherein this chemical compound contains at least 18 altogether, and preferred 24,32～48 carbon atoms especially,
(b) anionic, non-ionic, cationic, the amphoteric and/or zwitterionic emulsifying agent of 0.1～90 weight % and
(c) 0～40 weight % polyhydric alcohol, its condition are that total amount is 100 weight %.
Be surprisingly found out that above-mentioned long-chain fat same clan chemical compound has outstanding nacreous lustre, even and be to use less amount with the difference of prior art products, higher gloss, particularly fineness of the particles and storage stability still had.This nacreous lustre wax is to be easy to biodegradablely, has good mobile and allow to be mixed with difficult component such as silicone in cosmetics when existing with conc forms.
Aliphatic alcohol
The long-chain fatty alcohol of formula I is as component (al), R
1OH (I)
R wherein
1Be to have 18 carbon atoms, preferred 24～48 carbon atoms and the particularly straight chained alkyl of 32～36 carbon atoms at least.The chemical compound that can mention is the oxidation product of Shi behenyl alcohol or long chain paraffins for example.
Aliphatic ketone
The aliphatic ketone of formula II, as component (a2),
R
2-CO-R
3????(Ⅱ)
Wherein, R
2And R
3Alkyl with 1～22 carbon atom and/or the alkenyl that is replaced by hydroxyl in case of necessity independently of each other, its condition is that they have 18 altogether at least, preferred 24 and 32～48 carbon atoms particularly.This ketone can be according to known method preparation of the prior art, and for example the pyrolysis by corresponding fatty acid magnesium salt prepares.This ketone can be symmetric or asymmetrical, preferably two substituent R
2And R
3Difference only be 1 carbon atom and be by the fatty acid derived that contains 16～22 carbon atoms.Here decane ketone, laurone and stearone have particularly advantageous nacreous lustre performance.
Fatty ether
The fatty ether of formula III is as component (a3),
R
4-O-R
5????(Ⅲ)
R wherein
4And R
5Be alkyl and/or the alkenyl with 1～22 carbon atom independently of each other, its condition is that they contain 18 altogether at least, and is preferred 24, particularly 32～48 carbon atoms.Above-mentioned fatty ether normally acid condensation by corresponding aliphatic alcohol prepares.Fatty ether with particularly advantageous nacreous lustre performance is that the condensation by the aliphatic alcohol with 16～22 carbon atoms such as spermol, spermaceti fragrant and mellow (Cetearylalkohol), stearyl alcohol, isooctadecanol, oleyl alcohol, behenyl alcohol and/or erucyl alcohol makes.Especially preferably use distearyl ether.
Aliphatic acid ester carbonate
The aliphatic acid ester carbonate of formula IV is as component (a4),
R
6O-CO-OR
7????(Ⅳ)
R wherein
6And R
7Be alkyl and/or the alkenyl with 1～22 carbon atom independently of each other, its condition is that they have 18 altogether at least, and is preferred 24, particularly 32～48 carbon atoms.This chemical compound prepares with known method reaction own with corresponding aliphatic alcohol or hydroxyl alcohol by for example DMC dimethyl carbonate or diethylester.Therefore aliphatic carbonate ester can be symmetric or asymmetric.Yet, preferably use wherein R
6And R
7Be identical and expression has the carbonic ester of alkyl group of 16～22 carbon atoms.Particularly preferably be transesterification product and its mechanical impurity with its monoesters and diester form of DMC dimethyl carbonate or diethylester and spermol, spermaceti fragrant and mellow (Cetearylalkohol), stearyl alcohol, isooctadecanol, oleyl alcohol, 12-hydroxyl stearyl alcohol, behenyl alcohol and/or erucyl alcohol.
The use amount of this fatty compound is counted 1～99.9 weight % with this concentrate, 5～75 weight % normally, preferred 10～50 weight %, preferred especially 15～30 weight %.
Emulsifying agent
Nacreous lustre concentrates of the present invention can contain following at least a non-ionic surface active agent as emulsifying agent.
(b1) 2～30 moles oxirane and/or 0～5 mole of expoxy propane and have 8～22 carbon atoms straight-chain fatty alcohol, with the fatty acid with 12～22 carbon atoms, with alkyl group in have 8～15 carbon atoms alkyl phenol and with the addition compound product of triglyceride;
(b2) C of the addition compound product of 1～30 moles of ethylene oxide and glycerol
12/18-fatty-acid monoester and diester;
(b3) have the monoglyceride of 6～22 carbon atoms and saturated and unsaturated fatty acid and diester and its sorbitan monoesters and diester with and the addition compound product of oxirane;
(b4) in alkyl group, have the alkyl list glycosides of 8～22 carbon atoms and the analog of few glycosides and its ethoxylation;
(b5) addition compound product of 15～60 moles of ethylene oxide and Oleum Ricini and/or castor oil hydrogenated;
(b6) polyol ester, particularly polyglycerin ester such as polyglycerol polyricinoleate or polyglycereol gather-the 12-hydroxy stearic acid ester.The mixture that a plurality of these compounds are formed also is fit to;
(b7) addition compound product of 2～15 moles of ethylene oxide and Oleum Ricini and/or castor oil hydrogenated;
(b8) based on straight chain, side chain, saturated or unsaturated C
12/22The partial ester of the glycerol of-fatty acid, castor oil acid and 12-hydroxy stearic acid, polyglycereol, tetramethylolmethane, dipentaerythritol, sugar alcohol (for example minashi sugar alcohol) and polyglucoside (for example cellulose);
(b9) trialkylphosphate
(b10) wool wax alcohol
(b11) polysiloxanes-poly-alkyl-polyethers-copolymer and corresponding derivant;
(b12) mixed ester of forming according to the tetramethylolmethane of DE-PS1165574, fatty acid, citric acid and aliphatic alcohol and
(b13) poly alkylene glycol.
The sorbitan monoesters of the monoglyceride of oxirane and/or expoxy propane and aliphatic alcohol, fatty acid, alkyl phenol, fatty acid and diester and fatty acid and the addition compound product of diester or and the addition compound product of Oleum Ricini be to be known as commercial general product.They are homology mixture, and its average extent of alkoxylation is equivalent to oxirane and/or expoxy propane and carries out the ratio of the substrate of additive reaction with it.Known by DE-PS2024051, the C of the addition compound product of oxirane and glycerol
12/18-fatty-acid monoester and diester can be used as the agent of fat again (Ruckfettungsmittel) of cosmetics.
At US 3,839,318, US 3,707,535, US 3,547,828, DE-OS1943689, DE-OS 2036472 and DE-A13001064 and EP-A0077167 disclose C
8/18Alkyl list glycosides or few glycosides, its preparation method and its purposes as surfactant.Especially, be prepared by glucose or oligosaccharide and primary alconol reaction with 8～18 carbon atoms.As for its glycosides group, the single glycosides by glycosidic bond bonding ring-type glycosyl on aliphatic alcohol not only, and have to the oligomeric glycosides up to about 8 low polymerization degree and also be fit to.This low polymerization degree is a kind of assembly average, this meansigma methods be common homology with this industrial product distribute (Homologenverteilung) be basis.
In addition, can use zwitterionic surfactant as emulsifying agent.This surface active cpd is the zwitterionic surfactant that has a quaternary ammonium group and at least one carboxylate and a sulfonate ester group in its molecule at least.Specially suitable zwitterionic surfactant is so-called betanin; as N-alkyl-N; N-Dimethyl Ammonium glycinate; Cortex cocois radicis alkyl dimethyl ammonium glycinate for example; N-acyl amino propyl group-N; N-Dimethyl Ammonium glycinate as Cortex cocois radicis acyl amino propyl group-Dimethyl Ammonium glycinate, reaches the 2-alkyl-3-carboxy methyl-3-hydroxyethyl imidazoline and the Cortex cocois radicis acyl amino ethyl hydroxyethyl carboxyl methylglycine ester that respectively have 8～18 carbon atoms in alkyl or carboxyl groups.Particularly preferably be with CTFA the fatty acid amide derivant of the AMPHORAM C30 (Cocamidopropyl Betaine) that is trade name.Same suitable emulsifying agent is an amphoteric surfactant, and amphoteric surfactant is except C
8/18At least also contain on the external molecule of-alkyl or carboxyl groups a free amino and at least one-COOH-or-surface active cpd of SOH-group, and be easy to form inner salt.Suitable examples of amphoteric surfactants is N-alkyl glycine, N-alkyl propanoic acid, N-alkyl amino butanoic acid, N-alkyl imino dipropionic acid, N-hydroxyethyl-N-alkyl amido propyl group glycine, N-alkyl taurine, N-alkyl sarcosine, 2-alkyl aminopropionic acid and the alkyl amino acetic acid that respectively has about 8～18 carbon atoms in alkyl group.Preferred especially amphoteric surfactant is N-Cortex cocois radicis alkyl aminopropionic acid ester, Cortex cocois radicis acyl amino ethylamino propionic ester and C
12/18-acyl group sarcosine.Except that amphoteric emulsifier, it is also conceivable that quaternized emulsifying agent, in this ester quaternary amine type (esterquat) emulsifying agent, the special quaternary ammoniated difatty acid triethanolamine ester salts of preferable methyl.
Nacreous lustre concentrates of the present invention can contain 0.1～90 weight %, the emulsifying agent of preferred 5～50 weight % and preferred especially 10～40 weight %.
Polyhydric alcohol
The polyhydric alcohol that preferably has 2～15 carbon atoms and at least two oh groups by the present invention as the polyhydric alcohol of component (c) use.Typical example is
Glycerol;
Aklylene glycol, for example ethylene glycol, diethylene glycol, propylene glycol, butanediol, hexanediol and mean molecule quantity are 100～1,000 daltonian Polyethylene Glycol;
From condensation degree is 1.5～10 industrial few glycerol mixture, is mixture of industrial two glycerol of 40～50 weight % as two glycerol contents;
Methylol compound is as particularly trimethylolethane, trimethylolpropane, tri hydroxy methyl butane, tetramethylolmethane and dipentaerythritol;
Has 1～8 carbon atom in the low alkyl androstanediol, particularly those alkyl, as methyl and butyl glucoside;
Sugar alcohol with 5～12 carbon atoms is as sugar alcohol or mannitol.
Sugar with 5～12 carbon atoms, for example glucose or sucrose;
Amino sugar, for example glycosamine.
Nacreous lustre concentrates of the present invention can comprise 0.1～40 weight %, preferred 0.5～15 weight %, the polyhydric alcohol of preferred especially 1～5 weight %, preferably glycerol, propylene glycol, T glycol, hexanediol and mean molecule quantity are 100～1,000 Polyethylene Glycol.
Preparation method
In the embodiment preferred that is content of the present invention equally, be prepared as follows nacreous lustre concentrates: preparation component (a) and (b) and mixture (c), with this mixture heated to the temperature that is higher than 1～30 ℃ of this mixture fusing point, the water that adds the aequum of substantially the same temperature then is cooled to room temperature.In addition, also can add spissated moisture (anion) surfactant cream in advance, under heating, be stirred into nacreous lustre wax and then make water with this mixture diluted to desirable concentration or can in the presence of polymeric hydrophilic thickening agent such as hydroxy propyl cellulose, xanthan gum (Xanthan Gum) or carbopol preparation (Carbomer) base polymer, mix and prepare.
Commercial Application
Nacreous lustre concentrates of the present invention is suitable for regulating for example the have one's hair wash opacity of hair-care shampoo or artificial dish washing agent of surperficial active product.
Therefore, another content of the present invention relates to the opaque and method that the liquid aqueous preparation of nacreous lustre is arranged of the material for preparing water-soluble surface-active, wherein under 0～40 ℃, in transparent aqueous compositions, add and account for said preparation 0.5～40, the nacreous lustre concentrates of preferred 1～20 weight %, and it is dispersed in wherein.
Surfactant
Usually have 1～50, the surface activity preparation of the non-moisture component of preferred 5～35 weight % can comprise non-ionic, anionic, cationic and/or amphoteric or zwitterionic surfactant, the content of this reagent in preparation is normally about 50～99, preferred 70～90 weight %.The example of anion surfactant is a soap; the benzene sulfonamide acid esters; the alkane sulfonic acid ester; the alkene sulfonic acid ester; the alkyl ether sulphonic acid ester; the glycerin ether sulphonic acid ester; the Alpha-Methyl sulphonic acid ester; sulfo-fatty acid; the alkyl sodium sulfate ester; fatty alcohol ether sulfate; the glycerin ether sulfuric ester; the blended ether sulfuric ester of hydroxyl; single glycerol (ether) sulfuric ester; fatty acid amide (ether) sulfuric ester; 2-Sulfosuccinic acid list and dialkyl; sulfosuccinic amide list and dialkyl; the sulfo group triglyceride; the amide soap; ether carboxylic acid and its salt; the fatty acid isethionic acid ester; the fatty acid sarcosinate; fatty acid taurine ester (taruide); N-acylamino acid, for example acyl lactylates; the acyl group tartaric acid ester; acyl glutamic acid ester and acylaspartic acid ester; the few glucoside sulfuric ester of alkyl; the albumen fatty acid condensation substance plant product of Semen Tritici aestivi (particularly based on) and alkyl (ether) phosphate ester.In addition, anion surfactant comprises and has conventional homology and distribute, however the polyglycol ether chain that preferably narrow homology distributes.The representative instance of non-ionic surface active agent is a fatty alcohol polyglycol ether, alkyl phenol polyethylene glycol ethers, fatty acid polyethylene glycol ester, the fatty acid amide polyglycol ether, the fatty amine polyglycol ether, alkoxylated triglyceride, compound ether and mixing methylal, the few glucoside of alkyl, the few glucoside of alkenyl, fatty acid-N-alkyl glucose amide, the protein hydrolysate plant product of Semen Tritici aestivi (particularly based on), polyol fatty acid ester, sugar ester, sorbitan ester, poly-sorbose acid esters and amido oxide.In addition, non-ionic surface active agent also contains and has routine, yet the polyglycol ether chain that preferably narrow homologue distributes. the representative instance of cationic surfactant is quaternary ammonium compound and ester quat, particularly quaternised fatty acid trialkanolamine ester salt.Both sexes and zwitterionic surfactant are alkyl betaine, alkylamidoalkyl betanin, alanine ester, amino glycinate, imidazolinium betaine and sulfobetaines.Mentioned surfactant all is a compound known.Preparation method about its structure and this pledge, can consult relevant outline article and for example consult J.Falbe, " surfactant in the consumer goods " (" Surfactants in Consumer Products "), Springer Verlag, Berlin, 1987, the 54th～124 page or J.Falbe, " catalyst, surfactant and mineral oil additive " (" Katalysatoren; Tenside und Mineraloladditive "), Thieme Verlag, Stuttgart, 1978, the 123～217 pages.Also can directly use identical surfactant with the preparation nacreous lustre concentrates, anion surfactant is suitable for too as emulsifying agent.In this article, preferably use alkyl ether sulfate as anion emulsifier.
Auxiliary agent and additive
The surface activity preparation that can add nacreous lustre concentrates of the present invention also can comprise other auxiliary agent and additive, for example oil body, superfatting agent, stabilizing agent, wax, consistency modifiers, thickening agent, cationic polymer, silicone material, biogenic chemical compound, dandruff removing agent, film former, antiseptic, hydrotropic agent, cosolvent, UV absorbent, pigment and spice.
Oil body for example is based on has 6～18, the Guerbet alcohol of the aliphatic alcohol of preferred 8～10 carbon atoms, straight chain C
6-C
20-fatty acid and straight chain C
6-C
20The ester of-aliphatic alcohol, side chain C
6-C
13-carboxylic acid and straight chain C
6-C
20The ester of-aliphatic alcohol, straight chain C
6-C
18The ester of the ester of-fatty acid and branched-chain alcoho, particularly 2-Ethylhexyl Alcohol, straight chain and/or branched chain fatty acid and polyhydric alcohol (dimer diol and trimerization triol) and/or Guerbet alcohol, based on C
6-C
10The primary alconol of the triglyceride of-fatty acid, vegetable oil, side chain, the cyclohexane extraction of replacement, Guerbet carbonic ester, dialkyl ether and/or aliphatic and clicyclic hydrocarbon.
Superfatting agent can be such material; for example lanoline and lecithin and polyethoxylated or acyl group lanoline and lecithin derivant, polyol fatty acid ester monoglyceride and fatty acid join alkanolamide, and wherein the latter can be used as foam stabiliser simultaneously.Used consistency modifiers mainly is based on 12～22, the aliphatic alcohol of preferred 16～18 carbon atoms. and the fatty acid-N-methyl glucose amide of these materials and oligomeric alkyl glucoside and/or identical chain length and/or polyglycereol be poly--and the compositions of 12-hydroxy stearic acid is preferred.Suitable thickening is a polysaccharide for example, particularly xanthan gum, guar gum, agar, alginate and tylose, have alcohol ethoxylate and the oligomeric heteroside of alkyl and electrolyte such as Sal and ammonium chloride that narrow homology distributes at the ester of carboxymethyl cellulose and hydroxyethyl-cellulose, other the Polyethylene Glycol monoesters of higher molecular weight of fatty acid and diester, polyacrylate, polyvinyl alcohol and polyvinylpyrrolidone, surfactant such as ethoxylated fatty acid glyceride, fatty acid and polyhydric alcohol such as tetramethylolmethane or trimethylolpropane.
Suitable cationic polymers is a cationic cellulose derivative for example, the copolymer of cationic starch, diallyl ammonium salt and acrylamide, quaternised vinylpyrrolidone/ethylene imidazoles polymer such as Luviquat
@(BASF AG, Ludwigshafen/FRG), polyglycols and the condensation product of amine, quaternised collagen polypeptide Laurel diammonium (dimonium) hydroxypropyl hydrolytic collagen (Lamequat for example
L, GrunauGmbH), for example poly-first silicone (methicone) of amide or DC sludge dispersant (Dow Corning) of quaternised Semen Tritici aestivi polypeptide, polymine, cationic silicone polymer, Dow Coming Co/US, the copolymer (Cartaretine of adipic acid and dimethylamino hydroxypropyl diethylenetriamines
Sandoz/CH), as the poly-amino polyamide in FR-A2252840, described with and the cross-linked, water-soluble polymer, the cation chitin derivatives, as quaternized chitosan, as needs with the crystallite distribution form, saturated dihalide such as dibromobutane and two dialkylamine such as Bis-dimethylamino-1, the Jaguar of the condensation product of 3-propane, cationic guar gum such as Celanese/US
CBS.Jaguar
C-17, Jaguar
C-16, the Mirapol of quaternized ammonium salt polymer such as Mirapol/US
A-15, Mirapol
AD-1, Mirapol
AZ-1.
Suitable silicone compounds be for example dimethyl polysiloxane, methyl-phenyl polysiloxane, annular siloxane and amino-, fatty acid-, alcohol-, polyethers-, epoxy radicals-, the silicone compounds of fluoro-and/or alkyl-modification, at room temperature they can be liquid also can be resinoid.The representative instance of fat is a glyceride, and wax is Cera Flava, paraffin or microwax, if desired with the combination of hydrophilic wax such as cetyl stearyl alcohol.In scope of the present invention, except that fatty compounds, can also use the mono fatty acid ester of other known nacreous lustre wax, particularly Polyethylene Glycol and the ester of di fatty acid ester, partial glyceride and triglyceride and aliphatic alcohol and polybasic carboxylic acid or hydroxy carboxylic acid.Stabilizing agent can be the slaine of fatty acid, for example magnesium stearate, aluminium stearate and/or zinc stearate. the biogenic formulation example is bisabolol, allantoin, phytantriol, panthenol (Panthenol), AHA-acid, plant extraction liquid and vitamin coordination compound in this way.Dandruff removing agent is Climbazol, Octopirox and zinc pyrethion.Film former commonly used is polymer, quaternary salt cellulose derivative, collagen, hyaluronic acid and its salt and the similar compounds of for example chitosan, crystallite chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymer, oleic series.For improve liquidity can, the hydrotropic agent that can use other is ethanol, isopropyl alcohol, propylene glycol or glucose for example.Antiseptic for example be phenyl phenol, formalin, metagin, pentanediol or sorbic acid, pigment can be suitable for that cosmetics use with the chemical compound that allows, for example at publication " cosmetic pigment " (" KosmetischeFarbemittel "), Farbstoffkommission der Deutschen orschungsgemeinschaft, VerlagChemie, Weinheim, cited in 1984, the 81～106.In the total amount of mixture, the concentration of this pigment is 0.001～0.1 weight % normally.
In said preparation, the total amount of auxiliary agent and additive is 1～50 weight %, and the preparation of preferred 5～40 weight %. said preparations can be carried out according to the cold or by the use of thermal means of routine; Preferably carry out according to the phase inversion temperature method.
At last, content of the present invention also relates to mentioned fats compound as the purposes of nacreous lustre wax in preparation surface activity preparation.
Embodiment
Nacreous lustre concentrates R1～R7 of the present invention and control mixture R8 were placed 14 days down at 40 ℃, according to Bu Luoke Field (Bookfield) method in the RVT viscosity apparatus, measure viscosity (23 ℃, 10Upm, Spindel5).Then, prepare the shampoo water formulation by mixing additive under 20 ℃, every kind of preparation contains 2 gram nacreous lustre concentrates R1～R7,15 gram Cortex cocois radicis aliphatic alcohol+2EO-sodium sulfate salts, 3 gram dimethyl polysiloxanes, 5 gram Cortex cocois radicis alkyl androstanediol and 1.5 gram ester quats (adding water to 100 weight %).At microscopically, the crystalline fineness of nacreous lustre in the standard rating shampoo of the very thin crystal of scale 1=-5=coarse crystal is pressed on range estimation ground.The same matt evaluation of the 1=light～5=nacreous lustre degree of pressing; The range estimation opacity, and evaluate by (+)=opacity or (-)=transparency.List in table 1 and form and the result: all content is that % counts by weight:
Table 1
The composition of nacreous lustre concentrates and performance
| Form | ????R1 | ?R2 | ????R3 | ?R4 | ????R5 | ?R6 | ????R7 | ???R8 |
| C 32/48Aliphatic alcohol | ????25 | ?- | ????20 | ?20 | ????- | ?- | ????- | ????- |
| Stearone | ????- | ?25 | ????- | ?- | ????- | ?- | ????- | ????- |
| Distearyl ether | ????- | ?- | ????- | ?- | ????25 | ?- | ????7 | ????- |
| List/distearyl carbonic ester | ????- | ?- | ????- | ?- | ????- | ?25 | ????- | ????- |
| Glycol distearate | ????- | ?- | ????5 | ?5 | ????- | ?- | ????- | ????25 |
| Coconut alcohol+4EO | ????5 | ?5 | ????5 | ?- | ????5 | ?5 | ????- | ????5 |
| The Cortex cocois radicis alkyl androstanediol | ????9 | ?9 | ????9 | ?15 | ????9 | ?9 | ????- | ????9 |
| The coconut fatty acid betanin | ????5 | ?5 | ????5 | ?4 | ????5 | ?5 | ????- | ????5 |
| Coconut alcohol+2EO sodium sulfate salt | ????- | ?- | ????- | ?- | ????- | ?- | ????65 | ????- |
| Glycerol | ????5 | ?5 | ????5 | ?5 | ????5 | ?5 | ????4 | ????5 |
| Propylene glycol/butanediol (1: 5) | ????- | ?- | ????- | ?- | ????- | ?- | ????23 | ????- |
| Water | Be added to 100 | |||||||
| The viscosity of concentrate (m Pas) | ||||||||
| After one day, 40 ℃ | ????8,100 | ?8,200 | ????6,400 | ?7,900 | ????8,100 | ?8,100 | ????8,300 | ????9,500 |
| After 14 days, 40 ℃ | ????7,900 | ?7,800 | ????5,900 | ?7,800 | ????7,800 | ?7,700 | ????8,100 | ????7,200 |
| Nacreous lustre in the preparation | ||||||||
| Glossiness | ????1.5 | ?1.5 | ????1.0 | ?1.0 | ????1.5 | ?1.5 | ????1.0 | ????2.0 |
| Fineness | ????1.5 | ?1.5 | ????1.5 | ?2.0 | ????1.5 | ?1.0 | ????1.0 | ????3.0 |
| Opacity | ????- | ?- | ????- | ?- | ????- | ?- | ????- | ????+ |
Claims (11)
1. aqueous nacreous lustre concentrates, with dry weight basis, it contains:
(a) 1～99.1 weight % is selected from the aliphatic category chemical compound in aliphatic alcohol, aliphatic ketone, fatty ether and the aliphatic acid ester carbonate, and wherein this chemical compound contains at least 18 carbon atoms altogether,
(b) anionic, non-ionic, cationic, the amphoteric and/or zwitterionic emulsifying agent of 0.1～90 weight % and
(c) 0～40 weight % polyhydric alcohol, wherein condition is that its total amount is added to 100 weight %.
2. according to the nacreous lustre concentrates of claim 1, it is characterized in that, contain the aliphatic alcohol of formula I, as component (a), R
1OH (I)
R wherein
1It is straight chained alkyl with 18～48 carbon atoms.
3. according to the nacreous lustre concentrates of claim 1 and 2, it is characterized in that, contain the aliphatic ketone of formula II, as component (a),
R
2-CO-R
3????(Ⅱ )
Wherein, R
2And R
3Independently of each other, have the alkyl and/or the alkenyl of 1～22 carbon atom, they contain at least 18 carbon atoms altogether.
4. according to the nacreous lustre concentrates of claim 1～3, it is characterized in that the fatty ether that contains formula III is as component (a),
R
4-O-R
5????(Ⅲ)
R wherein
4And R
5Be alkyl and/or the alkenyl with 1～22 carbon atom independently of each other, its condition is to have at least 18 carbon atoms altogether.
5. according to the nacreous lustre concentrates of claim 1～4, it is characterized in that the aliphatic acid ester carbonate that contains formula IV is as component (a),
R
6O-CO-OR
7????(Ⅳ)
R wherein
6And R
7Be alkyl and/or the alkenyl with 1～22 carbon atom independently of each other, its condition is to have at least 18 carbon atoms altogether.
6. according to the nacreous lustre concentrates of claim 1～5, it is characterized in that contain the emulsifying agent as component (b), this emulsifying agent is selected from following composition:
(b1) 2～30 moles oxirane and/or 0～5 mole of expoxy propane and have 8～22 carbon atoms straight-chain fatty alcohol, with the fatty acid with 12～22 carbon atoms, with alkyl group in have 8～15 carbon atoms alkyl phenol and with the addition compound product of triglyceride;
(b2) C of the addition compound product of 1～30 moles of ethylene oxide and glycerol
12/18-fatty-acid monoester and diester;
(b3) have the monoglyceride of 6～22 carbon atoms and saturated and unsaturated fatty acid and the addition compound product of two fat and its sorbitan monoesters and diester and its oxirane;
(b4) in alkyl group, have the alkyl list glycosides of 8～22 carbon atoms and the analog of few glycosides and its ethoxylation;
(b5) addition compound product of 15～60 moles of ethylene oxide and Oleum Ricini and/or castor oil hydrogenated;
(b6) polyol ester;
(b7) addition compound product of 2～15 moles of ethylene oxide and Oleum Ricini and/or castor oil hydrogenated;
(b8) based on straight chain, side chain, saturated or undersaturated C
12/22The partial ester of-fatty acid, ricinoleic acid and 12-hydroxy stearic acid and glycerol, polyglycereol, tetramethylolmethane, dipentaerythritol, sugar alcohol and glucoside;
(b9) trialkyl phosphates
(b10) wool wax alcohol
(b11) polysiloxanes-poly-alkyl-polyethers-copolymer and corresponding derivant;
(b12) mixed ester of forming by tetramethylolmethane, fatty acid, citric acid and aliphatic alcohol and
(b13) poly alkylene glycol.
7. according to the nacreous lustre concentrates of claim 1～6, it is characterized in that the emulsifying agent that contains the alkyl ether sulphate class is as component (b).
8. according to the nacreous lustre concentrates of claim 1～7, it is characterized in that contain 0.1～40 weight % glycerol, 1,2-propylene glycol, butanediol, hexanediol and/or mean molecule quantity are 100～1,000 daltonian Polyethylene Glycol is as component (C).
9. the method for preparing the nacreous lustre concentrates of claim 1, it is characterized in that, preparation component (a) and (b) and mixture (c), with this mixture heated to the temperature that is higher than 1～30 ℃ of this mixture fusing point, add the water of the aequum of about uniform temp, then be cooled to room temperature.
10. the method opacity of preparation water-soluble surface-active material and that the liquid aqueous preparation of nacreous lustre is arranged, wherein under 0～40 ℃, in transparent aqueous compositions, add the nacreous lustre concentrates of the claim 1～8 that accounts for said preparation 0.5～40 weight %, and it is dispersed in wherein.
11. the purposes of the aliphatic compound of claim 1～8, it is used to prepare the surface activity preparation as nacreous lustre wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97195236 CN1223564A (en) | 1996-06-07 | 1997-05-30 | Aqueous nacreous lustre concentrates |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19622968.5 | 1996-06-07 | ||
| CN 97195236 CN1223564A (en) | 1996-06-07 | 1997-05-30 | Aqueous nacreous lustre concentrates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1223564A true CN1223564A (en) | 1999-07-21 |
Family
ID=5179169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97195236 Pending CN1223564A (en) | 1996-06-07 | 1997-05-30 | Aqueous nacreous lustre concentrates |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1223564A (en) |
-
1997
- 1997-05-30 CN CN 97195236 patent/CN1223564A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4108710B2 (en) | Aqueous pearlescent concentrate | |
| US3578719A (en) | Surface active agents | |
| CN1092995C (en) | Oil-water emulsifiers | |
| JPH08510442A (en) | Detergent mixture with improved conditioning effect | |
| US20180071198A1 (en) | Liquid thickener composition comprising polyalkoxylated polyols polyester for personal care, dermatological, and pharmaceutical preparations | |
| CN105530995A (en) | Use of special n-alkyl-n-acylglucamines for conditioning hair in hair washing agents | |
| CN104540494A (en) | Use of N-methyl-N-acylglucamines as solubilizers | |
| US20190224107A1 (en) | Liquid thickener composition comprising polyalkoxylated polyols polyester for personal care, dermatological, and pharmaceutical preparations having guerbet acid moieties | |
| JP2013537520A (en) | New oligoester | |
| JP2002510609A (en) | Manufacturing method of highly viscous cosmetic cleaner | |
| JP2000512286A (en) | Cosmetic formulations containing cationic and nonionic surfactants | |
| EP3714945A1 (en) | Liquid thickener composition comprising polyalkoxylated polyols polyester having guerbet acid moieties | |
| CN1168107A (en) | Emulsifying agents | |
| JP4227731B2 (en) | Manufacturing method of hair dye preparation with improved viscosity | |
| JP4181217B2 (en) | Aqueous pearlescent agent concentrate | |
| CN1244786A (en) | Cosmetic PIT emulsions | |
| JP4037908B2 (en) | Aqueous pearl luster concentrate | |
| JP2002538193A (en) | Oil bath powder | |
| CN1323196A (en) | Cosmetic preparations | |
| JP2002541178A (en) | Cosmetic and / or pharmaceutical preparations | |
| US20220313592A1 (en) | Liquid Thickener Composition Comprising Polyalkoxylated | |
| CN1223564A (en) | Aqueous nacreous lustre concentrates | |
| JP2000515174A (en) | Use of hydroxycarboxylic acid esters as thickeners | |
| US3877955A (en) | Cosmetic compositions | |
| JP2002514618A (en) | Ethoxylated ester quart |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |