CN1218694A - Technology for producing medical permeable adhesive tape by directly coating method - Google Patents
Technology for producing medical permeable adhesive tape by directly coating method Download PDFInfo
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- CN1218694A CN1218694A CN 97121834 CN97121834A CN1218694A CN 1218694 A CN1218694 A CN 1218694A CN 97121834 CN97121834 CN 97121834 CN 97121834 A CN97121834 A CN 97121834A CN 1218694 A CN1218694 A CN 1218694A
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- adhesive tape
- base material
- breathability
- sensitive adhesive
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Abstract
By means of direct coating, isolating agent, such as silicone, is coated on the back of permeable base material and then solidified, and medicinal hot melt pressure-sensitive adhesive is coated on the front of the base material. After rewinding and cutting, the permeable adhesive tape is produced.
Description
The present invention relates to a kind of production technology of medical permeable adhesive tape, is directly to be coated with sealing coat with direct rubbing method at substrate backside specifically, prepares the production technology of medical permeable adhesive tape at base material positive coating medical hot melt pressure sensitive adhesive.
The rubber plaster adhesive tape that at present domestic each medical institutions use, be to be base material with the cotton, making for binding agent with zinc oxide, natural rubber and Colophonium etc., will be glue partiting layer (sealing coat) with gauze eye gauze also, in order to keep not breaking away between binding agent and base material, require the toughness of glue to want evenly, certain thickness is arranged and must use fine and close cotton, so just lost the breathability of adhesive tape, and easily cause skin itching behind the adhering skin, the bonding redness that easily causes after for a long time, pimple or a vesicle.In order to make adhesive tape keep certain breathability and poisture-penetrability, carried out all research in recent years both at home and abroad.As making the breathability paster with the solvent-borne type rubbing method, be that binding agent is dissolved in earlier in the solvent as gasoline, dimethylbenzene etc., be coated on again after the dissolving on the primer (as kraft paper or polyethylene film), drying is handled reuse transfer coated method and is formed the breathability paster, in manufacturing process,, easily cause air pollution because of solvent evaporates, fire hazardous has been classified superseded method at present as.Work out the emulsion-type rubbing method in recent years again, be glue is made emulsion or to be dissolved in a certain proportion of water, and then be coated on the primer (kraft paper, polyethylene film, silicone), be coated on the breathability base material through the transfer coated method again, and form permeable adhesive tape through dried.Above-mentioned two kinds of methods all can not be on the breathability base material direct coating adhesive, can only just can make permeable adhesive tape with the transfer coated method.So-called transfer coated method, be exactly earlier with kraft paper as basal layer, on basal layer, be coated with one deck silane coupling agent (polyethylene kind) again, on silane coupling agent, be coated with one deck interleaving agent (silicone) again.After sealing coat solidifies, again pressure-sensitive (hot melt) glue is sprayed on insulation surface, simultaneously the breathability base material is pressed on the ground that scribbles silane coupling agent (polyethylene), sealing coat (silicone) and pressure sensitive adhesive kraft paper again, through rewinding, divide to cut into adhesive tape or paster, during use, breathability base material (as non-woven fabrics) is separated from kraft paper, pressure sensitive adhesive separates down from the sealing coat of kraft paper, and pressure sensitive adhesive is transferred on the non-woven fabrics.In above-mentioned transfer coated method, after being solidified, interleaving agent can form sealing coat, to show isolation effect.The technology of transfer coated manufactured adhesive tape has following shortcoming:
Although the scope of the isolation effect of 1 solvent-type organosilicon interleaving agent, solidification temperature and adjustable curing speed joint is wide, the coating process adaptability is big, and danger such as air pollution and fire are arranged.
2, emulsion-type organosilicon isolation effect is good, though there is not the danger of air danger and fire, the solidification temperature height, hardening time is long, and the coating process adaptability is little, also needs after fixing sometimes.
3, no-solvent type organosilicon isolation effect is good, and adjustable extent is wide, and performance is good, and energy resource consumption is little, and no air pollution does not have danger such as fire, but the coating process adaptability is little, and solidification temperature requires high.
4, can coating adhesive after above-mentioned rubbing method all needs organosilicon to solidify, as the silicone cure temperature requirement at 120-160 ℃, need 5-7 days (emulsion method) hardening time, the high-temperature water vapor volatilization, make the base material bubble or frill, directly influence the quality of coating adhesive, can cause the even permeability of crawling poor, the requirement that does not reach medical permeable adhesive tape.
5, the adhesive tape made of transfer coated method, can only use the adhesive tape (permeable adhesive tape) that is stained with pressure sensitive adhesive on the non-woven fabrics during use, other parts (as kraft paper, silane coupling agent, interleaving agent) are abandoned and need not, thereby increased the consumption of the cost and the energy of product, man power and material's waste, consider that from economic angle 50% of product will be wasted, increased the cost price of product, lose the power of striving unexpectedly of product.
Have on the base material of coating adhesive on the resin film in recent years yet and punch, adhesive tape of making and plaster, this adhesive tape do not have improvement in essence on permeability.
The present invention seeks to adopt direct rubbing method,, produce medical permeable adhesive tape at the positive coating of base material medical hot melt pressure sensitive adhesive at the back side of breathability base material coating sealing coat.
Production technology of the present invention is, interleaving agent directly is coated on the back side of breathability base material, after the curing, forms sealing coat, the medical hot melt pressure sensitive adhesive is painted on the front of breathability base material again, after rewinding, cutting, makes it to become medical permeable adhesive tape.
Breathability base material used in the present invention, can use permeability and water vapour permeability good, nontoxic, free from extraneous odour, non-irritating white breathability base material, the most normal use has non-woven fabrics, mulberry paper, dry goods and a staple fibre, after using binding agent, still keep the flexibility of base material, even wash or process, also can not damage binding agent, staple fibre can be polyurethane fiber, Fypro, polyester fiber, polypropylene fibre.
The present invention is in order to reduce improving the quality of products of product cost, adopt the direct rubbing method of hot-fusible pressure-sensitive adhesive to make medical permeable adhesive tape, with silicone as interleaving agent, silicone directly is coated on the back side of breathability base material (non-woven fabrics or mulberry paper), make it solidify the back and form sealing coat, but silicone cure needs certain condition, to just can finish curing at 120-160 ℃ of high temperature and 5-7 days time, form the good isolation layer, but body paper (base material) water evaporates under the high temperature will produce bubble on coating layer, base material will produce gauffer, it is inhomogeneous that sealing coat also becomes, and pressure sensitive adhesive will produce with the interface of base material and peel off, and directly influences product quality.
In order to improve above-mentioned shortcoming, the present invention uses the silicone cure principle of ultraviolet or applying electronic bundle, makes the silicone cure of substrate surface under the room temperature situation, lacks very much hardening time (instantaneous solidification).Wherein ultraviolet curing method will be used curing initiator such as benzoyl alkyl ether and inductor thereof, 1-Phenylethanone. and inductor thereof, and thia is feared and inductor, nitrogen etc.
Electron beam silicone cure method does not need curing initiator.
This constituent can use its 100% solid composition or use the diluent of toluene, ethyl acetate, hexane equal solvent, and the coating weight of radiation line style interleaving agent is 0.1g-1.5g/m
2Ultraviolet line style interleaving agent coating weight is 0.4-1.0g/m
2160W/cm
2Curing rate 20m/min.
Binding agent used in the present invention is the thermotropic pressure sensitive glue that does not contain aldehyde phenol.This pressure sensitive adhesive at room temperature is a solid state, and because of not containing solvent, so nontoxic, free from environmental pollution, nuisanceless, production safety is transported and stored conveniently, can be gluing fast, be fit to mechanical production line, and save space high yield, high efficiency and low-cost high-efficiency benefit.Thermosol can use repeatedly, does not have waste material substantially, and assembling and dismounting are wanted heat fused easily when PUR uses, need a locking equipment.
The equipment that the present invention uses is that the U.S. produces CT4030 type thermosol coating system, and this equipment is long: 3.1m, and wide: 1.1m, high: 1.725m, maximum width: the 0.375m that films, maximum base material width: 0.40m, maximum unreels diameter: 0.5m, maximum take-up diameter: 0.75m, unwinding device: 2; Wrap-up: 1, coating weight: 18-300g/m
2Maximum speed: 50-100-150m/min; Voltage 380V, peak power 5kw operating air pressure: 3-6bar, cooling shaft device: 2.
The hot-fusible pressure-sensitive adhesive that the present invention uses has acrylate and/or does not contain Molecularly Imprinted Polymer (U.S.'s product) 100% solid in the hot-fusible pressure-sensitive adhesive system of aldehyde phenol, outward appearance is little yellowish transparent flexible, viscosity CP (350F) 10,000-15,000 molten point: 100-110 ℃, non-volatile content: 100%.
Another kind of as homemade (Shanghai) TL8060PS hot-fusible pressure-sensitive adhesive, physical index, outward appearance are milky elastic solid (Hookean body) (allowing slightly faint yellow), ring and ball softening point: 95 ℃ ± 5 ℃; 180 ℃ of melt viscosity: 17.5pas ± 1.5pas, non-volatile content>99%.
Technological process of the present invention is: use the CT4030 type hot melt coating machine that the U.S. provides, or of home make silicone coating machine, dorsal surface coating silicone at breathability base material (non-woven fabrics or mulberry paper), the coating back is under nitrogen and ultraviolet radiation condition, carry out instantaneous solidification at room temperature, promptly be formed with the breathability base material of sealing coat after the curing.The another side (as the Cortex Mori recto) of this base material carries out the coating of acrylate copolymer binding agent or TL8060PS PUR with CT4030 type hot melt coating machine after, behind the wide 40cm of rewinding (axis diameter 25mm) length 9.14m rewinding area, cut into two kinds of specifications of 1.25cm and 2.5cm, promptly become medical permeable adhesive tape, through after the assay was approved, packing is put in storage again.
The main preferred equipment of the present invention:
1, silicone coating machine: homemade (Shanghai) or Germany.
2, hot melt coating machine: U.S. CT4030 type.
3, rewinding and cutting machine: Shanghai.
Preferred raw material of the present invention:
1, base material: homemade non-woven fabrics or homemade 18-25 gram/rice
2Mulberry paper.
2, silicone: organosilicon factory in Shanghai produces.
3, PUR: the Shanghai PUR TL8060ps of factory, or homemade (Beijing, Jilin) acrylic acid series hot-fusible pressure-sensitive adhesive.
Detailed production technology of the present invention is:
1, selected breathability base material: 18-25g/m
2Mulberry paper or non-woven fabrics.
2, coating interleaving agent: be coated with silane coupling agent (polyethylene kind) 1g/m earlier at the mulberry paper dorsal surface
2Repaste cloth 0.1-1.5g/m afterwards
2Silicone is 0.4-1.0g/m through its silicone amount of ultraviolet radiation type under the nitrogen effect
2, the ultraviolet amount is 160W/cm
2, curing rate 20m/ minute.Instantaneous solidification forms sealing coat at ambient temperature.
3, PUR coating: the present invention uses is that the solids hot melt pressure sensitive adhesive is molten some 100-110 ℃ of acrylic acid series and/or a TL8060PS hot-fusible pressure-sensitive adhesive, with 18-25g/m
2At mulberry paper or non-woven fabrics 18-25g/m
2(base material front) evenly coating on the base material, and form permeable adhesive tape.
4, rewinding: from permeable adhesive tape wrap-up (diameter of axle 7.5cm), go up the adhesive tape rewinding on 2.5cm axle core, rewinding length is 10 yards=9.14 meters, and width is 375cm.
5, cut: the adhesive tape after the rewinding is cut into wide 1.25cm and two kinds of specifications of 2.5cm.
6, packing after the assay was approved is a packing unit with 10 volumes.
The production technology of medical permeable adhesive tape of the present invention, compared with prior art, overcome the shortcoming of transfer coated method, and make the interleaving agent instantaneous solidification, reduced cost, good social benefit and economic benefit have been brought, from technology, production technology of the present invention breathability base material (non-woven fabrics, mulberry paper, dry goods) replaces cotton, replace the transfer coated method with direct rubbing method, replace solvent-borne type or emulsion-type pressure sensitive adhesive with hot-fusible pressure-sensitive adhesive, at room temperature moment makes the silicone cure method replace high temperature silicone solidification method with ultraviolet or electron beam, directly form sealing coat with silicone in the coating of breathability substrate back side face, replace the coating process that earlier silicone is coated on the kraft paper that contains silane coupling agent, the medical hot melt pressure sensitive adhesive is painted on the front of breathability base material, replacement is coated on transfer coated method on the kraft paper sealing coat with pressure sensitive adhesive, coating process of the present invention, can be direct, fast, be coated with continuously equably, equipment volume is little, few manpower, computer control is full-automatic, one man operation can be finished production technology, product is nontoxic, harmless, there is not irritated reaction, ventilative, energy resource consumption is little, the economic benefit height, product of the present invention meets the British Pharmacopoeia technical requirement, also meets simultaneously China 1996 about disposable use hygienic material required standard.
From clinical efficacy, the product of explained hereafter of the present invention obviously is better than rubber plaster, and following clinical experiment data further illustrate the advantage of production technology of the present invention.
1, uses medical permeable adhesive tape, select 18-45 year 50 person-times of normal healthy peoples, paste with wide 25mm10cm adhesive tape and pay in the partes corporis humani position, no skin itching symptom in 24 hours, paste to pay after 24 hours, remove and observe local skin after 1 hour behind the adhesive tape and do not have redness, no pimple does not have vesicle.Same healthy people, similar corresponding position, with zinc oxide adhesive plaster 25mm wide long 10cm, pasting to pay in 24 hours has skin to scratch oxygen symptom 8 people, paste pay remove after 24 hours the rubber plaster adhesive tape after 1 hour erubescence person 15 people wherein play the mound person of examining 5 people, play vesicle person 3 people.
2, use the wide 1.25mm of permeable adhesive tape, syringe needle was fixed 60 person-times when long 50mm did transfusion, set time was 4 hours person 35 people, 6 hours person 15 people, 8 hours person 10 people, skin allergies such as no skin itching, redness, pimple or vesicle, and matched group (rubber plaster) does not have irritated reaction in 4 hours, 6 hours person's 15 philtrums have erubescence person (little red) 3 people, 8 hours 10 philtrum erubescence person 3 people wherein have skin itching card shape person 1 people.
3, use the capable surgical wound dressing of permeable adhesive tape and fix 135 person-times, do not have irritated reaction in 24 hours to take place, and matched group person 25 people that have the skin itching, red swelling of the skin person 23 people, skin plays 15 person-times of vesicle persons.
4, permeable adhesive tape and rubber plaster all do not have obscission to the cohesive of skin.
5, behind permeable adhesive tape and the adhering skin, tape surface can have been seen perspiration and drain phenomenon, and the matched group rubber plaster does not have the drainage phenomenon.
6, permeable adhesive tape and adhering skin removed behind the adhesive tape that skin noresidue glue exists in 24 hours and rubber plaster has residual existence more than 80%.
As from the foregoing, permeable adhesive tape and rubber plaster all have excellent adhesion performance to the cohesive of skin, no significant difference.
And skin itching, a red and swollen and vesicle is reacted two groups significant difference, and this is owing to no phenol or hydroformylation material in the viscosifier of permeable adhesive tape binding agent and the age resistor, again because of breathability, water vapour permeability is good, and so not cutaneous physiological function is no skin allergy.Matched group then shows tangible skin allergy.
Embodiment 1
At 20g/m
2The non-woven fabrics back side, 1.0g/m
2After the polyethylene spraying with silicone 0.5g/m
2The spraying, under room temperature, nitrogen and ultraviolet condition with 160W/cm
2Setting rate is that 20m/min makes it to solidify, ultraviolet curing device is that Japan produces the UV4000 type, front at non-woven fabrics, with heat seeling coating machine (U.S.'s promise letter) CT4030 type, directly be coated on the non-woven fabrics continuously acrylic acid series hot-fusible pressure-sensitive adhesive (U.S.'s product), resulting permeable adhesive tape width is 375cm, through its width of rewinding is 375cm, length is 9140cm, and rewinding volume core diameter 2.5cm cuts into 1.25cm (wide) and 2.5cm (wide 2 kinds of specifications, promptly can be made into the package permeable adhesive tape, its performance and quality standard and detection method are seen technical standard of the present invention).
Embodiment 2
At 18g/m
2The dorsal surface of mulberry paper (Qian'an, Hebei) is with 1.0g/m
2After polyethylene spraying is solidified again with silicone 0.88/m
2, 20 ℃ of room temperatures, nitrogen and ultraviolet 160W/cm
2The spraying speed of a motor vehicle is 20m/min, solidify half an hour after, with hot melt coating machine (U.S.'s promise letter) CT4030 type, on the positive side of mulberry paper, with 18g/m
2TL-8060PS hot-fusible pressure-sensitive adhesive (Shanghai PUR factory) spraying after, through rewinding, cut, promptly can be made into permeable adhesive tape.
Embodiment 3
At 25g/m
2The dorsal surface of woven dacron (white, market sell) grinds institute's PUR spraying, rewinding, cuts and can be made into permeable adhesive tape with J-38 Heilungkiangization by the same procedure of example 1.
Claims (9)
1, the direct rubbing method of a kind of usefulness is made the method for medical permeable adhesive tape, it is characterized in that interleaving agent directly is coated on the back side of breathability base material, it is solidified, heat adhesive is painted on the front of breathability base material, through rewinding, divide and cut into the breathability medical adhesive tape.
2, be non-woven fabrics, mulberry paper, fabric according to the breathability base material that the process of claim 1 wherein.
3, according to the method for claim 2, fabric wherein is the fabric of polyurethane fiber, Fypro, polyester fiber, polypropylene fibre.
4, according to the method for claim 2, wherein said breathability base material quality is a 18-25 gram/rice
2
5, according to the process of claim 1 wherein that employed interleaving agent is silicone aqueous emulsion type or no-solvent type Organosilicon Release Agent, the consumption of interleaving agent is a 0.4-1.0 gram/rice
2
6, according to the method for claim 5, wherein the solidification temperature of aqueous emulsion type interleaving agent is 120-160 ℃, and be 5-7 days hardening time.
7, according to the method for claim 5, wherein said no-solvent type Organosilicon Release Agent has in room temperature under the condition of nitrogen current solidifies through ultraviolet radiation, and the ultraviolet amount is 160W/cm
2, coating speed is 20 meters/minute, or carries out electronic beam curing.
8, be thermosol pressure sensitive adhesive TL-8060psi and/or propylene ester list hot-fusible pressure-sensitive adhesive according to the binding agent that the process of claim 1 wherein.
9, be 9.14 meters according to the rewinding length that the process of claim 1 wherein, the volume core diameter is 2.5cm, and the volume core is hardboard or plastic tube, and its thickness is 2mm, and cutting width is 1.25cm and 2.5cm.
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CN97121834A CN1078481C (en) | 1997-12-03 | 1997-12-03 | Technology for producing medical permeable adhesive tape by directly coating method |
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CN97121834A CN1078481C (en) | 1997-12-03 | 1997-12-03 | Technology for producing medical permeable adhesive tape by directly coating method |
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CN1218694A true CN1218694A (en) | 1999-06-09 |
CN1078481C CN1078481C (en) | 2002-01-30 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100363452C (en) * | 2006-04-07 | 2008-01-23 | 上海永冠胶粘制品有限公司 | Process for making hot-melt pressure sensitive adhesive type fabric base adhesive tape |
CN104626703A (en) * | 2015-01-22 | 2015-05-20 | 江门新时代胶粘科技有限公司 | Compound non-woven fabric and preparation process thereof |
CN112281543A (en) * | 2020-11-05 | 2021-01-29 | 常州麦格尼特新材料科技有限公司 | Heat-sealing adhesive for medical dialyzing paper coating and preparation and coating methods thereof |
CN114917076A (en) * | 2022-06-15 | 2022-08-19 | 河南大兵实业有限公司 | Medical breathable adhesive tape and preparation process thereof |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2023097C (en) * | 1990-01-16 | 1999-07-06 | Kenji Tsubota | Method for producing an air-permeable adhesive tape |
US5613942A (en) * | 1994-10-04 | 1997-03-25 | Minnesota Mining And Manufacturing Company | Adhesive sheet material suitable for use on wet surfaces |
-
1997
- 1997-12-03 CN CN97121834A patent/CN1078481C/en not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100363452C (en) * | 2006-04-07 | 2008-01-23 | 上海永冠胶粘制品有限公司 | Process for making hot-melt pressure sensitive adhesive type fabric base adhesive tape |
CN104626703A (en) * | 2015-01-22 | 2015-05-20 | 江门新时代胶粘科技有限公司 | Compound non-woven fabric and preparation process thereof |
CN112281543A (en) * | 2020-11-05 | 2021-01-29 | 常州麦格尼特新材料科技有限公司 | Heat-sealing adhesive for medical dialyzing paper coating and preparation and coating methods thereof |
CN114917076A (en) * | 2022-06-15 | 2022-08-19 | 河南大兵实业有限公司 | Medical breathable adhesive tape and preparation process thereof |
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