CN1211456C - Furnace core and its production method - Google Patents
Furnace core and its production method Download PDFInfo
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- CN1211456C CN1211456C CN 03133686 CN03133686A CN1211456C CN 1211456 C CN1211456 C CN 1211456C CN 03133686 CN03133686 CN 03133686 CN 03133686 A CN03133686 A CN 03133686A CN 1211456 C CN1211456 C CN 1211456C
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- coal
- coke
- caking
- bottle
- coking
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000003245 coal Substances 0.000 claims abstract description 155
- 239000000571 coke Substances 0.000 claims abstract description 59
- 238000004939 coking Methods 0.000 claims abstract description 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000002956 ash Substances 0.000 claims description 25
- 239000000470 constituent Substances 0.000 claims description 25
- 229910052717 sulfur Inorganic materials 0.000 claims description 23
- 239000011593 sulfur Substances 0.000 claims description 23
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 19
- 239000010883 coal ash Substances 0.000 claims description 4
- 238000005272 metallurgy Methods 0.000 claims description 4
- 235000019580 granularity Nutrition 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 230000009257 reactivity Effects 0.000 abstract description 6
- 238000007670 refining Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 239000004079 vitrinite Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
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- Coke Industry (AREA)
Abstract
The present invention discloses metallurgical coke and a production method thereof, which is characterized in that the metallurgical coke is prepared from the following mixing coal raw materials: fat coal, gas coal, weakly caking coal, coking coal and coke powder; secondary metallurgical coke is produced by adopting the processes of tamping, coking and coaling. The present invention has the characteristic that the metallurgical coke has the measured indexes that the coke reactivity is at most 39%, and the post-reaction strength is at least 52%. Because the coke can satisfy the requirements of ironmaking production, the raw materials for coal mixing and coking are increased, and the coking cost is reduced. Thus, resources can be reasonably used.
Description
Technical field
The present invention relates to refine the metallurgical coke technical field, particularly a kind of metallurgical coke and production method thereof.
Background technology
Coal-blending coking is generally all based on gas, fertilizer, Jiao, lean coal, but China has a lot of weak caking coal resources, rationally utilizes these weak caking coal coal blendings, saves caking coal, and reducing production costs in China will be a great research topic.Datong District's coal is low ash, low-sulfur, volatile matter height, calorific value height, high-quality steam coal and coal for gasification that ash fusion point is high, and from coal classification angle, Datong District's coal belongs to weakly caking coal or non-caking coal, and promptly non-coking coal is difficult to participate in coking production.For making full use of the low ash of these weakly caking coals or non-caking coal, doctor negative characteristics, based on these weakly caking coals or non-caking coal, making refining I and II metallurgical coke firm by ramming promptly is rationally to utilize local resources, is again the research project that reduces production costs.
Summary of the invention
The purpose of this invention is to provide the local coal resource of a kind of reasonable utilization, carry out the science coal blending based on weakly caking coal or non-caking coal, make firm by ramming and refine a kind of metallurgical coke and production method thereof, produce the metallurgical coke that meets national Specification.
A kind of metallurgical coke, it is characterized in that metallurgical coke is made up of following coal blending raw materials by weight: rich coal 35%-40%, bottle coal, weakly caking coal 35%-45%, coking coal 15%-25%, coke powder 5-10% produces secondary metallurgical, the index that metallurgical coke is measured, coke reactivity≤39%, post-reaction strength 〉=52%, coke can satisfy ironmaking and produce needs.
Bottle coal, weakly caking coal are formed, and the weight part ratio is: bottle coal: weakly caking coal=1: 0.5-2.5.
Coke powder fineness is carse, medium and small three kinds of granularities, and coarse grain:＜0.5mm accounts for 95%, and middle grain:＜0.2mm accounts for 65%, particulate:＜0.2mm accounts for 95%.
It is the best that coke powder fineness accounts for 95% with particulate:＜0.2mm.
The coal sample of coal blending should meet column data down:
The ash 8.06% of bottle coal, sulfur are 0.70%, and fugitive constituent is 32.76%, and caking index is 7, and thickness of colloidal matter layer is 7.0mm.The coal vitrinite content of weakly caking coal is low, inertinite content height, so cohesiveness is very poor, and silk quality group content height in the macerals.
Weakly caking coal ash 6.25%, fugitive constituent 31.03%, caking index 5, thickness of colloidal matter layer 3.0mm, sulfur are 0.64%, this coal is for hanging down ash, low-sulfur, high its cohesiveness index of fugitive constituent near gas-fat coal.
The ash 9.27% of rich coal, fugitive constituent 26.72%, caking index 94, thickness of colloidal matter layer are 32.0mm, sulfur 0.92%.
The ash 7.44% of coking coal, fugitive constituent 24.97%, caking index 93, thickness of colloidal matter layer are 25.0mm, sulfur 0.43%.
The ash 10.97% of coke powder, fugitive constituent 1.12%, moisture content 1.33%.Coke powder is the commercially available prod, and metallurgical coke is by the screen underflow after sieving.
Above-mentioned coal blending is as follows by the index of the metallurgical coke of stamp charging refining:
The moisture content 1.10% of metallurgical coke, ash 10.55%, fugitive constituent 0.98%, sulfur 0.65%.Coke falls back size composition:＞80mm37.4%, 80-60mm35.4%, 60-40mm18.6%, 40-20mm3.6%, 20-10mm0.5%,＜10mm4.5%, coke strenth (rotary drum method), M
4072.7%, M
2588.7%, M
108.3%, coke reactivity≤40.8%, post-reaction strength 〉=52.0%.
The production method of metallurgical coke recited above is characterized in that:
1) preparation of raw material: rich coal, bottle coal, weakly caking coal, coking coal powder are broken to＜3mm accounts for more than 80%, and coke powder prepares separately, is mixed evenly, and mixed coal moisture content reaches 10-12%;
2) coal blending is formed: rich coal 35%-40%, and bottle coal, weakly caking coal 35%-45%, bottle coal, weakly caking coal are formed, and the weight part ratio is: bottle coal: weakly caking coal=1: 0.5-2.5, coking coal 15%-25%, coke powder 5-10%;
3) production method:
Adopt the coal blending method of making firm by ramming to coaling, use conventional coke oven production metallurgy Jiao.
Characteristics of the present invention are: with bottle coal and weakly caking coal serves as that the metallurgical coke that the main coal blending of forming is refined meets state specified standards, can be applied to ironmaking and produce.Based on weakly caking coal, the blending ratio of refining metallurgical coke is feasible, can improve coke strenth by a relatively large margin, obtains qualified metallurgical secondary Jiao.Expanded the raw material of coal-blending coking, reduced the coking cost, resource is received rational application.Employing based on weakly caking coal, make firm by ramming the refining metallurgical coke method be suitable for coking production of the present invention, conventional coking is compared with tamping coking, tamping coking can improve coke strenth, same blending ratio M by a relatively large margin
40Can improve 2.7～6.2 percentage points, M
10Can improve 3.9～5 percentage points.So with weak caking coal is that the burnt employing of main production metallurgy tamping coking production technique is rational.
Embodiment
Embodiment 1
A kind of metallurgical coke, form (weight percent) by following coal blending raw material: rich coal 40%, bottle coal, weakly caking coal 35%, coking coal 15%, coke powder 10% is produced secondary metallurgical, the index that metallurgical coke is measured, coke reactivity≤39%, post-reaction strength 〉=52%, coke can satisfy ironmaking and produce needs.
Bottle coal, weakly caking coal are formed, and the weight part ratio is: bottle coal: weakly caking coal=1: 2.5.
Coke powder fineness is carse, medium and small three kinds of granularities, and coarse grain:＜0.5mm accounts for 95%, and middle grain:＜0.2mm accounts for 65%, particulate:＜0.2mm accounts for 95%.
It is the best that coke powder fineness accounts for 95% with particulate:＜0.2mm.
The coal sample of coal blending should meet column data down:
The ash 8.06% of bottle coal, sulfur are 0.70%, and fugitive constituent is 32.76%, and caking index is 7, and thickness of colloidal matter layer is 7.0mm.The coal vitrinite content of weakly caking coal is low, inertinite content height, so cohesiveness is very poor, and silk quality group content height in the macerals.
Weakly caking coal ash 6.25%, fugitive constituent 31.03%, caking index 5, thickness of colloidal matter layer 3.0mm, sulfur are 0.64%, this coal is for hanging down ash, low-sulfur, high its cohesiveness index of fugitive constituent near gas-fat coal.
The ash 9.27% of rich coal, fugitive constituent 26.72%, caking index 94, thickness of colloidal matter layer are 32.0mm, sulfur 0.92%.
The ash 7.44% of coking coal, fugitive constituent 24.97%, caking index 93, thickness of colloidal matter layer are 25.0mm, sulfur 0.43%.
The ash 10.97% of coke powder, fugitive constituent 1.12%, moisture content 1.33%.Coke powder is the commercially available prod, and metallurgical coke is by the screen underflow after sieving.
Above-mentioned coal blending is as follows by the index of the metallurgical coke of stamp charging refining:
The moisture content 1.10% of metallurgical coke, ash 10.55%, fugitive constituent 0.98%, sulfur 0.65%.Coke falls back size composition:＞80mm 37.4%, 80-60mm35.4%, 60-40mm18.6%, 40-20mm3.6%, 20-10mm0.5%,＜10mm4.5%, coke strenth (rotary drum method), M
4072.7%, M
2588.7%, M
108.3%, coke reactivity≤40.8%, post-reaction strength 〉=52.0%.
The production method of above-mentioned described metallurgical coke:
1) preparation of raw material: above-mentioned three kinds of coal dusts are broken to＜and 3mm accounts for more than 80%, and coke powder prepares separately, is mixed evenly, and mixed coal moisture reaches 10%;
2) coal blending is formed: rich coal 40%, and bottle coal, weakly caking coal 35%, bottle coal, weakly caking coal are formed, and the weight part ratio is: bottle coal: weakly caking coal=1: 2.5, coking coal 15%, coke powder 10%;
3), production method:
Adopt the coal blending method of making firm by ramming to coaling, use conventional coke oven production metallurgy Jiao.
The coal sample of coal blending should meet column data down:
The ash 8.06% of bottle coal, sulfur are 0.70%, and fugitive constituent is 32.76%, and caking index is 7, and thickness of colloidal matter layer is 7.0mm.The coal vitrinite content of weakly caking coal is low, inertinite content height, so cohesiveness is very poor, and silk quality group content height in the macerals.
Weakly caking coal ash 6.25%, fugitive constituent 31.03%, caking index 5, thickness of colloidal matter layer 3.0mm, sulfur are 0.64%, this coal is for hanging down ash, low-sulfur, high its cohesiveness index of volatile matter near gas-fat coal.
The ash 9.27% of rich coal, fugitive constituent 26.72%, caking index 94, thickness of colloidal matter layer are 32.0mm, sulfur 0.92%.
The ash 7.44% of coking coal, fugitive constituent 24.97%, caking index 93, thickness of colloidal matter layer are 25.0mm, sulfur 0.43%.
The ash 10.97% of coke powder, fugitive constituent 1.12%, moisture content 1.33%.Coke powder is the commercially available prod, and metallurgical coke is by the screen underflow after sieving.
Above-mentioned coal blending is as follows by the index of the metallurgical coke of stamp charging refining:
The moisture content 1.10% of metallurgical coke, ash 10.55%, fugitive constituent 0.98%, sulfur 0.65%.Coke falls back size composition:＞80mm 37.4%, 80-60mm35.4%, 60-40mm18.6%, 40-20mm3.6%, 20-10mm0.5%,＜10mm4.5%, coke intensity (rotary drum method), M
4072.7%, M
2588.7%, M
108.3%, coke reactivity≤40.8%, post-reaction strength 〉=52.0%.
Embodiment 2
A kind of metallurgical coke, form (weight percent) by following coal blending raw material: rich coal 35%, bottle coal, weakly caking coal 40%, coking coal 20%, coke powder 5% is produced secondary metallurgical.
Bottle coal, weakly caking coal are formed, and the weight part ratio is: bottle coal: weakly caking coal=1: 2.
Coke powder fineness is with particulate:＜0.2mm accounts for 95%.Production method, coal and coke index are with embodiment 1.
Embodiment 3
A kind of metallurgical coke is formed (weight percent) by following coal blending raw material: rich coal 36%, and bottle coal, weakly caking coal 37%, coking coal 21%, coke powder 6% is produced secondary metallurgical.
Bottle coal, weakly caking coal are formed, and the weight part ratio is: bottle coal: weakly caking coal=1: 1.5.
Coke powder fineness is with particulate:＜0.2mm accounts for 95%.
The index of the production method of above-mentioned described metallurgical coke, the index of coal and coke is with embodiment 1 or 2.
Claims (4)
1, a kind of metallurgical coke, it is characterized in that metallurgical coke is made up of following coal blending raw materials by weight: rich coal 35%-40%, bottle coal, weakly caking coal 35%-45%, bottle coal, weakly caking coal weight part ratio are: bottle coal: weakly caking coal=1: 0.5-2.5, coking coal 15%-25%, coke powder 5-10% coalings through stamping and to produce secondary metallurgical;
The coal sample of coal blending should meet column data down:
The ash 8.06% of bottle coal, sulfur are 0.70%, and fugitive constituent is 32.76%, and caking index is 7, and thickness of colloidal matter layer is 7.0mm;
Weakly caking coal ash 6.25%, fugitive constituent 31.03%, caking index 5, thickness of colloidal matter layer 3.0mm, sulfur are 0.64%;
The ash 9.27% of rich coal, fugitive constituent 26.72%, caking index 94, thickness of colloidal matter layer are 32.0mm, sulfur 0.92%;
The ash 7.44% of coking coal, fugitive constituent 24.97%, caking index 93, thickness of colloidal matter layer are 25.0mm, sulfur 0.43%;
The ash 10.97% of coke powder, fugitive constituent 1.12%, moisture content 1.33%.
2, a kind of metallurgical coke according to claim 1 is characterized in that: coke powder fineness is carse, medium and small three kinds of granularities, and coarse grain:＜0.5mm accounts for 95%, and middle grain:＜0.2mm accounts for 65%, particulate:＜0.2mm accounts for 95%.
3, a kind of metallurgical coke according to claim 2 is characterized in that: coke powder fineness is with particulate:＜0.2mm accounts for 95%.
4, the production method of metallurgical coke according to claim 1 is characterized in that:
1) preparation of raw material: rich coal, bottle coal, weakly caking coal, coking coal powder are broken to＜3mm accounts for more than 80%, and coke powder prepares separately, is mixed evenly, and mixed coal moisture reaches 10-12% and is as the criterion;
2) coal blending is formed: rich coal 35%-40%, and bottle coal, weakly caking coal 35%-45%, bottle coal, weakly caking coal are formed, and the weight part ratio is: bottle coal: weakly caking coal=1: 0.5-2.5, coking coal 15%-25%, coke powder 5-10%;
3) production method:
Adopt the coal blending method of making firm by ramming to coaling, use conventional coke oven production metallurgy Jiao.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03133686 CN1211456C (en) | 2003-08-12 | 2003-08-12 | Furnace core and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03133686 CN1211456C (en) | 2003-08-12 | 2003-08-12 | Furnace core and its production method |
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|---|---|
| CN1513948A CN1513948A (en) | 2004-07-21 |
| CN1211456C true CN1211456C (en) | 2005-07-20 |
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| CN 03133686 Expired - Fee Related CN1211456C (en) | 2003-08-12 | 2003-08-12 | Furnace core and its production method |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100441662C (en) * | 2004-12-30 | 2008-12-10 | 武汉钢铁(集团)公司 | Coal blending and coking method for metallurgical coke |
| JP4950527B2 (en) * | 2006-03-15 | 2012-06-13 | 株式会社神戸製鋼所 | Coke manufacturing method and pig iron manufacturing method |
| RU2352605C1 (en) * | 2008-01-09 | 2009-04-20 | Борис Анатольевич Мусохранов | Development method of coal mixtures for production of chargte for carbonisation and composition of such mixtures (versions) |
| CN101880541B (en) * | 2010-06-25 | 2013-11-06 | 神华集团有限责任公司 | Method for producing primary metallurgical coke by using 1/3 charred coal in west Mongolia region as main blending coal |
| EA022518B1 (en) * | 2012-10-22 | 2016-01-29 | Открытое Акционерное Общество "Губахинский Кокс" | Method of coke producing for non-ferrous metals smelting |
| CN111303922A (en) * | 2020-03-20 | 2020-06-19 | 武汉科技大学 | Coking coal and coking method for top-loaded coke by using same |
| CN113637510B (en) * | 2020-04-27 | 2022-10-21 | 宝山钢铁股份有限公司 | Production method of high-value formed coke from waste coke powder |
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Owner name: ZHANG YINHENG Free format text: FORMER OWNER: SHANXI TONGJIA IRON AND STEEL CO., LTD. Effective date: 20130220 Free format text: FORMER OWNER: NATIONAL ZHONGWEI COKING TECHN ENGINEERING RESEARCH CENTER CO., LTD. ZHANG YINHENG Effective date: 20130220 |
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Free format text: CORRECT: ADDRESS; FROM: 037018 DATONG, SHAANXI PROVINCE TO: 037000 DATONG, SHAANXI PROVINCE |
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Effective date of registration: 20130220 Address after: 037000, 6-3-7, compound 40, grand springs, Shanxi, Datong Patentee after: Zhang Yinheng Address before: 037018 ancient inn village, Shanxi, Datong Patentee before: Shanxi Tongjia Iron and Steel Co., Ltd. Patentee before: National Zhongwei Coking Techn Engineering Research Center Co., Ltd. Patentee before: Zhang Yinheng |
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Granted publication date: 20050720 Termination date: 20160812 |