CN1208438C - Method for producing smoke-prevention, dust-contorl and energy saving combustion improver - Google Patents

Method for producing smoke-prevention, dust-contorl and energy saving combustion improver Download PDF

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CN1208438C
CN1208438C CN 02136449 CN02136449A CN1208438C CN 1208438 C CN1208438 C CN 1208438C CN 02136449 CN02136449 CN 02136449 CN 02136449 A CN02136449 A CN 02136449A CN 1208438 C CN1208438 C CN 1208438C
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CN1473914A (en
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王林泉
王士云
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Abstract

The present invention relates to a manufacturing method for a smoke elimination dust removing and energy saving combustion supporting agent, which comprises the following steps: a) after 4.0 to 6.0 parts of potassium chloride, 3.0 to 4.0 parts of magnesium chloride and 4.5 to 5.5 parts of Fe2O3 are crushed, ground, and mixed, the mixture is arranged in one reaction pot, and water is added for reaction through agitation; b) 6.0 to 8.0 parts of nitramine is pulverized and is arranged in the other reaction pot, water is added for reaction through agitation, the final reactant in the step a) is added, and then the uniform mixing is carried out for reaction through agitation; c) after 25 to 30 parts of coarse whiting is pulverized, the coarse whiting is arranged in the reaction pot, 0.5 to 1.0 parts of nitric acid is added, and water is added for uniform agitation; after the dewatering is carried out, calcium nitrate is generated, and then, is uniformly agitated with the reactant obtained in the step b), the reaction and the drying are carried out, and rare earth quartz barite carbonate is added; after the reaction is carried out, kaolin mine is added for uniform mixing, and the reaction is carried out so as to obtain the combustion supporting agent which can be used industrially. (the parts are weight parts.) the combustion supporting agent obtained by the present invention can perform the functions of catalysis and heat release in coal combustion, and simultaneously, the present invention has a certain sulfur solidifying function. The pollution for environment can be lightened.

Description

The manufacture method of a kind of smoke elimination, dedusting, combustion energy-saving combustion adjuvant
Technical field:
The invention belongs to chemical field, particularly the fuel in the coal-mining industry is the manufacture method of a kind of smoke elimination, dedusting, combustion energy-saving combustion adjuvant specifically.
Background technology:
China is one and uses coal big country, nearly more than 40 ten thousand boilers, annual 300000000 tons in the coal that consumes, more than 11 ten thousand of Industrial Stoves, year is consumed more than 200,000,000 ton in coal, and more than 200,000,000 ton in civilian coal is because equipment and technology is outmoded, boiler efficiency is low, energy consumption is big, and exhaust gas emission exceeds standard, and air environmental pollution is serious, at present, for energy consumption that reduces coal firing boiler and the influence that reduces the coal firing boiler environmental pollution, need transform coal firing boiler, change and use coal-fired be use fuel oil or combustion gas, but need to drop into huge fund, and also need the working cost of great number after transforming, in the prior art, in order to improve coal-fired efficiency of combustion, usually use ignition dope, described ignition dope comprises potassium permanganate, sodium salt, ferric oxide and Manganse Dioxide.
Summary of the invention:
Technical problem to be solved by this invention is: in the prior art, in order to improve coal-fired efficiency of combustion, usually use ignition dope, described ignition dope comprises potassium permanganate, sodium salt, ferric oxide, Manganse Dioxide, but potassium permanganate is a kind of strong oxidizer, and security is not high, cost is big, and contain a large amount of sodium salts, and the easy coking of the ignition dope of ferric oxide and Manganse Dioxide, combustion-supporting effect is not good, can cause secondary pollution simultaneously, the present invention provides a kind of smoke elimination for the technical scheme that above-mentioned technical problem adopted that solves in the prior art, dedusting, the manufacture method of combustion energy-saving combustion adjuvant, wherein, the manufacture method of described ignition dope comprises the steps:
A) with 4.0-6.0 weight part Repone K, 3.0-4.0 weight part magnesium chloride, 4.5-5.5 weight part Fe 2O 3After fragmentation, the fine grinding, mix, be placed in the reactor, add certain water, stirring reaction 8-12 hour;
B) 6.0-8.0 weight part ammonium nitrate is pulverized, be placed in another reactor, add entry, stirring reaction 8-12 hour, a) last reactant is added mixing then, stirring reaction;
C) with after the pulverizing of 25-30 weight part water-ground limestone, be placed in the reactor, add 0.5-1.0 weight part nitric acid and add entry, stir, mixing is after the dehydration, generate nitrocalcite, then with b) the reactant stirring and evenly mixing that obtains of step, after the reaction, oven dry, add the quartzy barite carbonate of 24-30 weight part rare earth then, after the reaction, add 27-30 weight part kaolin ore mixing again, reaction can obtain industrial operable ignition dope.In the manufacture method of ignition dope of the present invention, the quartzy barite carbonate of described rare earth contains lanthanum sesquioxide and cerium dioxide, and described kaolin ore contains aluminium sesquioxide, ferric oxide and silicon-dioxide.
In resulting ignition dope by the present invention, owing to added kaolin ore therein, ventilation property when making coal burning is better, coal can fully burn, simultaneously owing to adopted the quartzy barite carbonate of rare earth, ammonium nitrate, Repone K, magnesium chloride, brown iron oxide, nitric acid and water-ground limestone, make in the combustion processes of coal, a series of reaction takes place, play the effect of catalysis and heat release, in the raw material that the present invention adopts, the aluminium vanadine has the prevention coking, and the nitrate of water-ground limestone and magnesium has the combustion position of improvement, and the oxide compound that its pyrolytic decomposition generates has absorption SO 2Deng acidic oxide, make the ignition dope that obtains by the present invention have certain solid sulphur effect again, can alleviate pollution to environment.
Embodiment:
The manufacture method of a kind of smoke elimination of the present invention, dedusting, combustion energy-saving combustion adjuvant, wherein, the manufacture method of described ignition dope comprises the steps:
A) with 4.0-6.0 weight part Repone K, 3.0-4.0 weight part magnesium chloride, 4.5-5.5 weight part Fe 2O 3After fragmentation, the fine grinding, mix, be placed in the reactor, add certain water, stirring reaction 10 hours;
B) 6.0-8.0 weight part ammonium nitrate is pulverized, be placed in another reactor, add entry, stirring reaction 10 hours adds a) last reactant, mixing then, stirring reaction;
C) with after the pulverizing of 25-30 weight part water-ground limestone, be placed in the reactor, add 0.5-1.0 weight part nitric acid and add entry, stir, mixing is after the dehydration, generate nitrocalcite, then with b) the reactant stirring and evenly mixing that obtains of step, after the reaction, oven dry, add the quartzy barite carbonate of 24-30 weight part rare earth then, after the reaction, add 27-30 weight part kaolin ore mixing again, reaction can obtain industrial operable ignition dope.In the manufacture method of ignition dope of the present invention, the quartzy barite carbonate of described rare earth contains lanthanum sesquioxide La 2O 334.85%, cerium dioxide CeO 25%, described kaolin ore contains aluminium sesquioxide Al 2O 325.2%, ferric oxide Fe 2O 38.3%, silicon-dioxide SiO 253.26%.

Claims (3)

1, the manufacture method of a kind of smoke elimination, dedusting, combustion energy-saving combustion adjuvant is characterized in that: the manufacture method of described ignition dope comprises the steps:
A) with 4.0-6.0 weight part Repone K, 3.0-4.0 weight part magnesium chloride, 4.5-5.5 weight part Fe 2O 3After fragmentation, the fine grinding, mix, be placed in the reactor, add certain water, stirring reaction 8-12 hour,
B) 6.0-8.0 weight part ammonium nitrate is pulverized, be placed in another reactor, add entry, stirring reaction 8-12 hour, a) last reactant is added, mixing then, stirring reaction,
C) with 25-30 weight part water-ground limestone CaCO 3After the pulverizing, be placed in the reactor, add 0.5-1.0 weight part nitric acid and add entry, stir, mixing is after the dehydration, generate nitrocalcite, then with b) the reactant stirring and evenly mixing that obtains of step, after the reaction, oven dry, add the quartzy barite carbonate of 24-30 weight part rare earth then, after the reaction, add 27-30 weight part kaolin ore mixing again, reaction.
2, the manufacture method of a kind of smoke elimination as claimed in claim 1, dedusting, combustion energy-saving combustion adjuvant is characterized in that: the quartzy barite carbonate of described rare earth contains lanthanum sesquioxide and cerium dioxide.
3, the manufacture method of a kind of smoke elimination as claimed in claim 1, dedusting, combustion energy-saving combustion adjuvant is characterized in that: described kaolin ore contains and comprises aluminium sesquioxide, ferric oxide and silicon-dioxide.
CN 02136449 2002-08-09 2002-08-09 Method for producing smoke-prevention, dust-contorl and energy saving combustion improver Expired - Fee Related CN1208438C (en)

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CN 02136449 CN1208438C (en) 2002-08-09 2002-08-09 Method for producing smoke-prevention, dust-contorl and energy saving combustion improver

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CN 02136449 CN1208438C (en) 2002-08-09 2002-08-09 Method for producing smoke-prevention, dust-contorl and energy saving combustion improver

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CN1208438C true CN1208438C (en) 2005-06-29

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108048154A (en) * 2017-11-15 2018-05-18 绵阳双甘科技有限公司 A kind of manufacturing method of combustion adjuvant

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Publication number Priority date Publication date Assignee Title
US8574324B2 (en) 2004-06-28 2013-11-05 Nox Ii, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
AU2011202863B2 (en) * 2004-06-28 2012-04-05 Douglas C. Comrie Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
RU2494793C2 (en) 2005-03-17 2013-10-10 НОКС II ИНТЕНЭШНЛ, эЛТиДи. Method of combusting mercury-bearing fuel (versions), method of reducing mercury emission, method of combusting coal with reduced emission of harmful elements and method of decreasing mercury content in flue gas
CA2601325C (en) 2005-03-17 2014-06-17 Douglas C. Comrie Reducing mercury emissions from the burning of coal
CN101434884B (en) * 2007-11-16 2013-08-21 范伟光 Energy-saving coal combustion adjuvant and preparation thereof
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US8845986B2 (en) 2011-05-13 2014-09-30 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US9957454B2 (en) 2012-08-10 2018-05-01 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108048154A (en) * 2017-11-15 2018-05-18 绵阳双甘科技有限公司 A kind of manufacturing method of combustion adjuvant

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