CN1205985A - Treatment process of naphthenic acid effluents in oil refinery - Google Patents
Treatment process of naphthenic acid effluents in oil refinery Download PDFInfo
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- CN1205985A CN1205985A CN 97112550 CN97112550A CN1205985A CN 1205985 A CN1205985 A CN 1205985A CN 97112550 CN97112550 CN 97112550 CN 97112550 A CN97112550 A CN 97112550A CN 1205985 A CN1205985 A CN 1205985A
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Abstract
By using the mixed liquid of tertiary amine and diesel oil as extractant and sodium hydroxide solution as counter extractant, acid naphthenic acid effluent is counter-current extracted in two stage extracting, mixing and clarifying tank. Waste extractant is regenerated in one stage counter extracting, mixing and clarifying tank for reuse. Unlike the available centrifugal extraction process, which has scale in the drum of centrifugal extracting machine and thus the nuisance of eliminating scale, the said process has no scale and thus low labour strength, high production efficiency and low production cost.
Description
The present invention relates to a kind of waste water extraction treatment method, especially relate to a kind of refinery naphthenic acid waste water extraction treatment method.
Refinery naphthenic acid waste water is mainly produced naphthenic acid technology from the sulfuric acid neutralisation of oil purification alkaline residue, it contains naphthenic acid, phenol and the vitriol of high density, about 8000~the 25000mg/l of CODcr, the pH value is less than 5, intractability is big, both made through neutralizing treatment, its biochemical degradation performance is still relatively poor, impacts the aeration tank, sewage-farm easily.To the processing of this water, " petrochemical complex environment protection " second phase in 1989 proposed the Centrifugical extraction pretreatment process.This method is an extraction agent with the mixed solution of tertiary amine and diesel oil, is reverse-extraction agent with the sodium hydroxide lye, adopts the main equipment of centrifugal extractor for extraction, back extraction; Because the two-phase separating power of centrifugal extractor does not reach the waste water treatment process requirement, so, de-oiling jar, utility appliance such as useless extraction agent deposition dehydrating jar, waste lye sedimentation de-oiling jar and extraction agent sedimentation dealkalize jar fall in the depositing in water that extracts that disposed the residence time and be 8~14 hours, have guaranteed not have in water that each slurry tank discharges, the organic phase to fold zoning; Naphthenic acid waste water extracts through two-stage countercurrent, discharger after the slurry tank de-oiling, and the CODcr clearance reaches 85%~95%; Useless extraction agent is reused through one-level back extraction regeneration back.
There is centrifugal extractor and centrifugal back extraction machine rotary drum incrustation gradually in this technology, makes the problem of the amount of carrying secretly increase mutually.Generally, must remove once dirt, just can keep normally carrying out of extraction, back extraction process every 3~5 days.And take out rotary drum from tearing machine open, and manual scale removal finishes to installation, needs three professionals to work approximately 4 hours, and labour intensity is big, and device had 3%~5% time to be in shut down condition approximately, and easily caused the parts damage in the disassembly-and-assembly machine process.
Another problem of this technology is only to have about 10 seconds two phase materials residence time in centrifugal extractor and centrifugal back extraction machine, mix very violent, even through after the centrifugation, one still exists many tiny disperse phase at another in mutually, therefore, the residence time of each slurry tank reaches 8~14 hours, and the slurry tank volume is big, and investment is high.
The extraction treatment method that the purpose of this invention is to provide a kind of naphthenic acid waste water is avoided incrustation in the device, reduces labour intensity, and holding device moves continuously, enhances productivity; Simultaneously, shorten the residence time of two phase materials in device, reduce equipment volume, reduce investment cost.
The present invention can be summarized as: the mixed liquid with tertiary amine and diesel oil is extraction agent, is reverse-extraction agent with the sodium hydroxide lye; Tart naphthenic acid waste water is through two-stage extraction mixer-settler counter-current extraction discharger; Useless extraction agent is reused through one-level back extraction mixer-settler back extraction regeneration back; The waste lye that the back extraction process produces, adjust pH reclaims sour oil, comes along extraction treatment after new sour water that produces and naphthenic acid waste water are mixed; Floss on two-stage extraction clarifying tank and the one-level back extraction clarifying tank two-phase interface adopts whizzer to handle, and isolated solid precipitation is disposed, and liquid returns clarifying tank.Because the present invention adopts mixer-settler formula extraction (back extraction) technology, so, the rotary drum incrustation problem that does not have centrifugal extractor formula extraction (back extraction) technology, thereby, just avoided also that labour intensity is big, device idle time is long and has easily caused the manual scaling operation of parts damage, reached reduction labour intensity, holding device moves continuously, the purpose of enhancing productivity; Simultaneously, also the reason owing to following two aspects has reduced investment cost, and the one, cancelled expensive titanium material Centrifugical extraction (back extraction) machine, the 2nd, by shortening the residence time of two phase materials in device, reduced equipment volume, reduced investment cost.
1 detailed process of the present invention is described in conjunction with the accompanying drawings:
The incoming stock tank of former water (1) (2) adds sulfuric acid (3) in case of necessity, and the interior sulfuric acid concentration of control flume (2) is 0.05~0.10mol/l, and the sour oil of emersion (4) regularly reclaims in the water; The naphthenic acid waste water of extracting out from raw material tank (2) (5) enters first step extraction tempering tank (6), press water/agent volume ratio 3~6 hybrid extractions with the organic phase (15) that extracts clarifying tank (13) from the second stage, it is settlement separate that two-phase mixed solution (7) enters first step extraction clarifying tank (8), and wherein the organic phase residence time is that 3~6 hours, water are 2~4 hours; Remove second stage extraction tempering tank (11) from the isolated water of groove (8) (10), with 3~6 mix by volume from the extraction agent (fresh extraction agent) of pipeline (21), continue extraction, it is settlement separate that two-phase mixed solution (12) enters second stage extraction clarifying tank (13), wherein the organic phase residence time is that 2~4 hours, water are 4~7 hours, isolated water (14) discharge system, isolated organic phase (15) go first step extraction tempering tank (6) to continue to use; Remove back extraction tempering tank (16) from the organic phase (9) that groove (8) is told, with 0.2~0.4 mix by volume from the 8w%~12w% sodium hydroxide solution (18) of alkali lye storage tank (17), strip, it is settlement separate that two-phase mixed solution (19) enters back extraction clarifying tank (20), wherein organic phase, the water residence time are 5~8 hours, isolated organic phase (i.e. extraction agent after the regeneration) goes second stage extraction tempering tank (11) to continue to use through pipeline (21), and isolated waste lye (22) enters waste lye neutralization tank (23); In jar (23), add sulfuric acid (24) the pH value is transferred to 3~4, reclaim the sour oil (25) of emersion, the sour water of generation (26) goes raw material tank (2) to handle after naphthenic acid waste water is mixed; In addition, make the material of Centrifugical extraction (back extraction) machine rotary drum incrustation, can show as the floss on the clarifying tank two-phase interface, must in time remove, to guarantee the normal running of clarifying tank, therefore, the floss that will regularly the first step be extracted on the clarifying tank (8) and second stage extraction clarifying tank (13) two-phase interface is extracted out, handle through pipeline (27) input whizzer (28), isolated liquid phase (29) is returned first step extraction clarifying tank (8), and solid precipitation (30) is directly removed; Want regularly the floss on the back extraction clarifying tank two-phase interface to be extracted out through pipeline (31) input whizzer (32) to handle, isolated liquid phase (33) is returned back extraction clarifying tank (20), and solid precipitation (34) is directly removed; When loss of extractant acquires a certain degree, in pipeline (21), replenish the extraction agent of new preparation through pipeline (35), extraction agent is by C
8~C
10Tertiary amine and 200 ℃~350 ℃ boiling range diesel oil are formed, wherein tertiary amine concentration 10v%~30v%.
In above-mentioned technology, service temperature is 20 ℃~40 ℃ in extraction tempering tank, the clarifying tank, and service temperature is 30 ℃~45 ℃ in back extraction tempering tank, the clarifying tank.Control two-stage extraction tempering tank, one-level back extraction tempering tank residence time of material 5~10 minutes, medium tenacity stirs.
The present invention adopts mixer-settler formula extraction (back extraction) technology, replaced existing centrifugal extractor formula extraction (back extraction) technology, thereby, there is not rotary drum incrustation problem, just avoided also that labour intensity is big, device idle time is long and has easily caused the manual scaling operation of parts damage, realized reduction labour intensity, holding device moves continuously, the purpose of enhancing productivity; In addition, adopt mixer-settler formula extraction (back extraction) technology, also reduced investment cost from following two aspects, the one, cancelled expensive Centrifugical extraction (back extraction) machine, the 2nd, by extraction (back extraction) tempering tank of selecting 5~10 minutes residence time, medium tenacity to stir, both finished extraction process, do not produce too tiny disperse phase again, make the extraction process water residence time by present 8~14 hours, shortening to the first step extraction clarifying tank and the second stage extraction clarifying tank accumulative total residence time is 6~11 hours; Make the extraction process organic phase residence time by present 8~14 hours, shortening to the first step extraction clarifying tank and the second stage extraction clarifying tank accumulative total residence time is 5~10 hours; Make back extraction process water, the organic phase residence time by present 8~14 hours, shorten to 5~8 hours; Reduce equipment volume, reduced investment cost.
Fig. 1 is the inventive method schema; Embodiment 1 extraction and back extraction tempering tank adopt the enamel lining stirring tank, and extraction and back extraction clarifying tank adopt grouan pond body.Naphthenic acid waste water secondary counter-current extraction, useless extraction agent is regenerated with the one-level back extraction.
Naphthenic acid waste water: CODcr8000~10000mg/l, sulfuric acid concentration 0.05~0.07mol/l, flow 3m
3/ h;
Extraction agent: C
8~C
10Tertiary amine and 200 ℃~350 ℃ mixed liquid of boiling range diesel oil, tertiary amine concentration 10v%, flow 1m
3/ h;
Useless extraction agent: finish naphthenic acid waste water secondary counter-current extraction extraction agent afterwards, claim useless extraction agent, must after back extraction regeneration, just can reuse; Because extraction agent volumetric expansion after extraction naphthenic acid, phenol, so, keep material balance between extraction process and the back extraction process, will make the extraction agent flow of the useless extraction agent flow of back extraction process, present embodiment, useless extraction agent flow 1.1m greater than extraction process
3/ h;
Back extraction alkali lye: the 12w% sodium hydroxide solution, about base excess concentration 2w%, this moment, flux of alkaline liquor was about 0.2m after the control back extraction
3/ h;
Service temperature: interior 20 ℃ of extraction tempering tank, clarifying tank, interior 30 ℃ of back extraction tempering tank, clarifying tank:
Tempering tank: control two-stage extraction tempering tank, 5~10 minutes one-level back extraction tempering tank residence time, medium tenacity stirs;
Clarifying tank: the first step 4 hours clarifying tank water residence time of extraction, 6 hours organic phase residence time; The second stage 7 hours clarifying tank water residence time of extraction, 4 hours organic phase residence time; Back extraction clarifying tank water, the organic phase residence time are 8 hours;
Clarifying tank two-phase interface suspended substance: removed once each clarifying tank suspended substance with whizzer every 7~10 days.
Effect: through 6 months operation, equipment was normal, did not have in the water that each clarifying tank is discharged, the organic phase to fold zoning, waste water COD cr clearance 90%~95%.Embodiment 2 extractions and back extraction steel basin adopt plastic material, and extraction and back extraction clarifying tank adopt plastics pot.Naphthenic acid waste water secondary counter-current extraction, useless extraction agent is regenerated with the one-level back extraction.
Naphthenic acid waste water: flow 6m
3/ h, other parameter is with embodiment 1;
Extraction agent: tertiary amine concentration 30v%, other parameter is with embodiment 1;
Useless extraction agent: with embodiment 1;
Back extraction alkali lye: flux of alkaline liquor is about 0.4m
3/ h, other parameter is with embodiment 1;
Service temperature: interior 40 ℃ of extraction tempering tank, clarifying tank, interior 45 ℃ of back extraction tempering tank, clarifying tank;
Tempering tank: with embodiment 1;
Clarifying tank: the first step 2 hours clarifying tank water residence time of extraction, 3 hours organic phase residence time; The second stage 4 hours clarifying tank water residence time of extraction, 2 hours organic phase residence time; Back extraction clarifying tank water, the organic phase residence time are 5 hours;
Clarifying tank two-phase interface suspended substance: treatment measures are with embodiment 1;
Effect: waste water COD cr clearance 88%~93%, other situation is with embodiment 1.Embodiment 3 extractions and back extraction tempering tank adopt the enamel lining stirring tank, and extraction and back extraction clarifying tank adopt grouan pond body.Naphthenic acid waste water secondary counter-current extraction, useless extraction agent is regenerated with the one-level back extraction.Naphthenic acid waste water: CODcr22000~25000mg/l, sulfuric acid concentration 0.08~0.10mol/l, flow 4m
3/ h;
Extraction agent: tertiary amine concentration 20% (body), other parameter is with embodiment 1;
Useless extraction agent: with embodiment 1;
Back extraction alkali lye: the 8w% sodium hydroxide solution, about base excess concentration 2w%, this moment, flux of alkaline liquor was about 0.3m after the control back extraction
3/ h;
Service temperature: with embodiment 2;
Tempering tank: with embodiment 1;
Clarifying tank: with embodiment 2;
Clarifying tank two-phase interface suspended substance: treatment measures are with embodiment 1;
Effect: waste water COD cr clearance 86%~91%, other situation is with embodiment 1.Embodiment 4 extractions and back extraction tempering tank adopt the enamel lining stirring tank, and extraction and back extraction clarifying tank adopt grouan pond body.Naphthenic acid waste water secondary counter-current extraction, useless extraction agent is regenerated with the one-level back extraction.
Naphthenic acid waste water: flow 3m
3/ h, other parameter is with embodiment 3;
Extraction agent: tertiary amine concentration 15% (body), other parameter is with embodiment 1;
Useless extraction agent: with embodiment 1;
Back extraction alkali lye: the 8w% sodium hydroxide solution, about base excess concentration 2w%, this moment, flux of alkaline liquor was about 0.25m after the control back extraction
3/ h;
Service temperature: with embodiment 1;
Tempering tank: with embodiment 1;
Clarifying tank: with embodiment 1;
Clarifying tank two-phase interface suspended substance: treatment measures are with embodiment 1;
Effect: waste water COD cr clearance 85%~90%, other situation is with embodiment 1.Embodiment 5 extractions and back extraction tempering tank adopt the enamel lining stirring tank, and extraction and back extraction clarifying tank adopt grouan pond body.Naphthenic acid waste water secondary counter-current extraction, useless extraction agent is regenerated with the one-level back extraction.
Naphthenic acid waste water: flow 5m
3/ h, other parameter is with embodiment 3;
Extraction agent: tertiary amine concentration 30v%, other parameter is with embodiment 1;
Useless extraction agent: with embodiment 1;
Back extraction alkali lye: the 10w% sodium hydroxide solution, about base excess concentration 2w%, this moment, flux of alkaline liquor was about 0.4m after the control back extraction
3/ h;
Service temperature: with embodiment 2;
Tempering tank: with embodiment 1;
Clarifying tank: with embodiment 2;
Clarifying tank two-phase interface suspended substance: treatment measures are with embodiment 1;
Effect: waste water COD cr clearance 85%~90%, other situation is with embodiment 1.
Claims (7)
1. waste water extraction treatment method, especially a kind of naphthenic acid waste water extraction treatment method, mixed liquid with tertiary amine and diesel oil is extraction agent, with the sodium hydroxide lye is reverse-extraction agent, it is characterized in that, tart naphthenic acid waste water is in proper order through first step extraction tempering tank (6), first step extraction clarifying tank (8), second stage extraction tempering tank (11), second stage extraction clarifying tank (13), extracted tempering tank (11) along the second stage, second stage extraction clarifying tank (13), first step extraction tempering tank (6), first step extraction clarifying tank (8) direction mobile extraction agent counter-current extraction is then through pipeline (14) discharger; The useless extraction agent of telling from first step extraction clarifying tank (8) (9) removes back extraction tempering tank (16), mix reextraction with sodium hydroxide lye, it is settlement separate that two-phase mixed solution (19) enters back extraction clarifying tank (20) then, and isolated extraction agent returns second stage extraction tempering tank (11) through pipeline (21) and reuses; The isolated waste lye of back extraction clarifying tank (20) (22) removes waste lye neutralization tank (23) adjust pH 3~4, and the sour oil of emersion (25) reclaims, and the sour water of generation (26) comes along extraction treatment after mixing with naphthenic acid waste water; Floss on first step extraction clarifying tank (8), second stage extraction clarifying tank (13) and back extraction clarifying tank (20) two-phase interface, the employing whizzer is handled, isolated solid precipitation is directly gone up in whizzer (28), (32) and is removed, and liquid returns clarifying tank (8), (20).
2. according to the method for claim 1, it is characterized in that selecting for use C
8~C
10Tertiary amine and 200 ℃~350 ℃ mixed liquid of boiling range diesel oil are extraction agent, wherein tertiary amine concentration 10v%~30v%.
3. according to the method for claim 1, it is characterized in that extracting 20 ℃~40 ℃ of tempering tank, the interior service temperatures of clarifying tank, service temperature is 30 ℃~45 ℃ in back extraction tempering tank, the clarifying tank.
4. according to the method for claim 1, the volume ratio that it is characterized in that naphthenic acid waste water and extraction agent is 3~6, and the volume ratio of back extraction alkali lye and useless extraction agent is 0.2~0.4.
5. according to the method for claim 1, the naphthenic acid waste water sulfuric acid concentration that it is characterized in that entering first step extraction tempering tank is 0.05~0.10mol/l.
6. according to the method for claim 1, the concentration that it is characterized in that the reverse-extraction agent sodium hydroxide solution is 8w%~12w%.
7. according to the method for claim 1, it is characterized in that the organic phase residence time in the first step extraction clarifying tank is 3~6 hours, water is 2~4 hours; The organic phase residence time is 2~4 hours in the second stage extraction clarifying tank, and water is 4~7 hours; The organic phase residence time is 5~8 hours in the back extraction clarifying tank, and water is 5~8 hours.
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CN 97112550 CN1078567C (en) | 1997-07-22 | 1997-07-22 | Treatment process of naphthenic acid effluents in oil refinery |
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CN 97112550 CN1078567C (en) | 1997-07-22 | 1997-07-22 | Treatment process of naphthenic acid effluents in oil refinery |
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CN1205985A true CN1205985A (en) | 1999-01-27 |
CN1078567C CN1078567C (en) | 2002-01-30 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100348512C (en) * | 2005-12-06 | 2007-11-14 | 河北工业大学 | Technique for reclaiming ethylene alkali-washing waste liquid |
CN102276007A (en) * | 2010-06-12 | 2011-12-14 | 中国石油化工集团公司 | Method for treating sewage produced during cyclohexanone production by adopting extraction method |
CN102313658A (en) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | Method for preparing naphthenic acid sample in wastewater |
CN102313659A (en) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | Method for separating low-concentration naphthenic acid in wastewater and preparing naphthenic acid sample |
CN102442748A (en) * | 2010-10-12 | 2012-05-09 | 中国石油化工股份有限公司 | Deep treatment method of naphthenic acid wastewater |
CN105848758A (en) * | 2014-01-07 | 2016-08-10 | 陶氏环球技术有限责任公司 | Separation of hydrocarbons from aqueous mixture using fouling resistant reverse osmosis membrane |
-
1997
- 1997-07-22 CN CN 97112550 patent/CN1078567C/en not_active Expired - Fee Related
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100348512C (en) * | 2005-12-06 | 2007-11-14 | 河北工业大学 | Technique for reclaiming ethylene alkali-washing waste liquid |
CN102276007A (en) * | 2010-06-12 | 2011-12-14 | 中国石油化工集团公司 | Method for treating sewage produced during cyclohexanone production by adopting extraction method |
CN102276007B (en) * | 2010-06-12 | 2013-04-03 | 中国石油化工集团公司 | Method for treating sewage produced during cyclohexanone production by adopting extraction method |
CN102313658A (en) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | Method for preparing naphthenic acid sample in wastewater |
CN102313659A (en) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | Method for separating low-concentration naphthenic acid in wastewater and preparing naphthenic acid sample |
CN102313659B (en) * | 2010-07-07 | 2013-10-09 | 中国石油化工股份有限公司 | Method for separating low-concentration naphthenic acid in wastewater and preparing naphthenic acid sample |
CN102313658B (en) * | 2010-07-07 | 2014-04-16 | 中国石油化工股份有限公司 | Method for preparing naphthenic acid sample in wastewater |
CN102442748A (en) * | 2010-10-12 | 2012-05-09 | 中国石油化工股份有限公司 | Deep treatment method of naphthenic acid wastewater |
CN102442748B (en) * | 2010-10-12 | 2013-11-20 | 中国石油化工股份有限公司 | Deep treatment method of naphthenic acid wastewater |
CN105848758A (en) * | 2014-01-07 | 2016-08-10 | 陶氏环球技术有限责任公司 | Separation of hydrocarbons from aqueous mixture using fouling resistant reverse osmosis membrane |
CN105848758B (en) * | 2014-01-07 | 2020-01-17 | 陶氏环球技术有限责任公司 | Separation of hydrocarbons from aqueous mixtures using fouling resistant reverse osmosis membranes |
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