CN1204252A - Compositions and methods for improving performance of long-wearing cosmetic products - Google Patents
Compositions and methods for improving performance of long-wearing cosmetic products Download PDFInfo
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- CN1204252A CN1204252A CN96199088.0A CN96199088A CN1204252A CN 1204252 A CN1204252 A CN 1204252A CN 96199088 A CN96199088 A CN 96199088A CN 1204252 A CN1204252 A CN 1204252A
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Abstract
The invention is for compositions and method for using said compositions to improve the performance of long-wearing cosmetic products. These compositions and methods of use of such compositions enable the user to significantly enhance the attributes of long-wearing cosmetic products without compromising their primary advantages.
Description
Technical field
The present invention relates to compositions and improve the method for long-wearing comsetic products performance with described compositions.This based composition and use the method for this based composition can make user obviously strengthen the performance of long-wearing comsetic products and can not damage its major advantage.
Cross reference
The application requires priority according to United States code 119 (e) rTitle35, and its basis is provisional application serial number 60/006,273 (application on November 7 nineteen ninety-five) and 60/008553 (application on the 13rd of nineteen ninety-five December).
Background technology
The compositions that is used to improve cosmetics is known in the art.This based composition comprise those be applied to as on the compositions of lipstick to offer the compositions of its compositions of using with gloss, slickness and metastasis etc.These improve product and have adopted multiple polymers fluid and film technique.For example, introduce the acrylic acid series film former of lipstick finishing coat, carry in volatile vehicle alcohol as " the Sealed With a Kiss " of CSI company, it is applied to the lipstick surface.
Above-mentioned another side coating product is the flat 5[1993 of Japanese publication] the middle those disclosed of-221829 (applications on August 31st, 1993).Described finishing coat is considered to embody persistent dressing effect, can controls the color and luster transfer and has the improved property used.Described finishing coat comprises the PFPE of the following formula of 0.2 to 25% Cab-O-sil and/or calcined bauxite in powder and 75% to 99.8%.
R wherein
1To R
5Be independently fluorine atom, perfluoroalkyl or oxygen perfluoroalkyl; The value of p, q and r is at least zero; Wherein the PFPE molecular weight is about 500 to about 10,000, and wherein p, q and r can equate, but non-vanishing.Preferred PFPE disclosed herein is commercially available prod Fomblin HC-04, HC-25 and HC-R, available from the Montefluosu company of Milan, ITA.
Although this based composition can produce certain benefit, they use the major advantage of the cosmetics on it to have found their common interference.For example, in order to improve the endurance quality that produces by the compositions that imposes on the cosmetics, can lose the gloss and the sensory property of cosmetic product.In addition, for gloss or the sensory property that is provided by this based composition is provided, the endurance quality of cosmetics can be suffered a loss.
Summary of the invention
The present invention relates to replenish with compositions with described compositions and solubility parameter and be less than or equal to 8.5 (block/centimetre
3)
1/2The method used together of cosmetics, to improve the overall performance relevant with cosmetics.These supplement compositions comprise C log P value more than or equal to 13 oil.
In addition, the present invention relates to improve the method for the pliability film-forming cosmetic of metastasis, described method comprises:
A. use the pliability film-forming cosmetic of metastasis, the solubility parameter of wherein said cosmetics be less than or equal to 8.5 (card/centimetre
3)
1/2
B. allow described cosmetics drying; With
C. use supplement composition on described cosmetics, the C log P value of wherein said compositions is more than or equal to 13.
Background of invention
Best is that when augmenting the advantage of cosmetics with supplement composition, the major advantage of cosmetics should not suffered a loss.In the dependency relation of film-forming cosmetic, supplement composition should be enough incompatible with the cosmetics film, uses Shi Buhui when supplement composition and destroy this cosmetics film." incompatible " is meant that supplement composition comprises specific components, and this component can not destroyed the film that forms after the cosmetic application.
A. the pliability film-forming cosmetic of metastasis
Supplement composition of the present invention can use with all types of cosmetics, so that other required performance to be provided.For the lip product, these performances comprise gloss, light and lubricity.
Cosmetic lip is well known in the art, comprises that the different prescription of many kinds is to provide skin beauty and nursing efficacy.Consumer an advantage of normal searching especially in cosmetic lip be increase or " secular " durability.
Some think that long-wearing comsetic products is the cosmetics that the sort of opposing is defiled to another object that is in contact with it; For example, prevent that lip compositions is to tableware such as cup and napkin transfer.But, find that on the prediction durability very crucial other factors is the pliability of cosmetics and opposing thereof to putting on the ability that solvent on the skin such as edible oil shift.This cosmetics are the themes among common unexamined patent application USSN__ and the USSN__, and this patent title is " a metastasis cosmetic composition ", and people such as Drechsler apply in October, 1996, are incorporated herein to be reference.This compositions comprises 1170-002, liquid diorganosiloxane polymer and volatile vehicle, and wherein the film that becomes after the cosmetic application is metastasis basically, and be flexible, and wherein cosmetics have the durability that has shockingly improved.Disclosed herein is with cosmetics are enough inconsistent supplement compositions that are used for these class cosmetics." enough visitor " mutually is meant that here using of supplement composition can not destroy the film that these class cosmetics become.
That the solubility parameter of the cosmetics that use with supplement composition of the present invention is less than or equal to is about 8.5 (card/centimetre
3)
1/2(pressing the Hildebrand scale).Usually, solubility parameter is the function of the cohesive energy of material or the cosmetics that comprise described material.Briefly cohesive energy is a kind of captivation, and it depends on the electronegativity of the atom that constitutes molecule, and as the basis of some performances such as viscosity, adhesion, miscibility even boiling point.Some materials have high cohesive energy as glassware for drinking water, and some materials such as oil have low cohesive energy.The high cohesion composition is " polar ", and low cohesion is oiliness or " nonpolar ".Hildeband has developed the method that a kind of boiling point with material, molecular weight and proportion are inferred solubility parameter; See J.H.Hidebrand, the Regularand Related Solutions of J.M.Prausnitz and R.L.Scott, New York; Van Nostrand Reinholdt (1950) introduces reference here.The Hildebrand solubility parameter of many cosmetics and medical substance is existing publishes, see Cosmetic Bench Reference, Carol Stream lL, Alluted Publishing publishes (1992), Handbook of Solubility Parameters and OtherCohesion Parameters with A.F.Barton, the 2nd edition, Boca Raton; CRC publishing house (1992); Two documents are introduced as reference.
B. supplement composition
Supplement composition of the present invention comprises oil, and can be solid-state to liquid various forms.Do not consider form, the C log P value of supplement composition of the present invention is equal to or greater than 13, is preferably greater than or equals 17, most preferably more than or equal to 20.
The C log P value of compositions has determined whether supplement composition is enough incompatible with cosmetics, to improve the performance of cosmetics.The P value is the octanol/water partition coefficient that constitutes the oil of supplement composition.This coefficient is the ratio of the composition equilibrated concentration in hot alcohol and water.Because the value height of octanol/water partition coefficient therefore for more convenient, takes 10 to be the form of the log value of the truth of a matter, i.e. logP.
Above-mentioned logp value adopts " C log P " program of Daylight CIS company to calculate.The logP of this calculating is based on the sheet phase method of Hansch and Leo (referring to the ComprehensiveMedicinal Chemistry of A.leo, the 4th volume, C.Hansch, P.G.Sammens, J.B.Taylor and C.A.Ransden edit, the 295th page, Pergamon publishing house, nineteen ninety); Be introduced as reference.The sheet phase method is based on the chemical constitution of every kind of oil ingredient, and considers number and type, atomic conductivity and the chemical bonding of atom.C log P value is the method for these physicochemical properties of assessment of the most reliable and extensive employing.
The oil ingredient of supplement composition is a main component in the compositions.Generally, the oil content of supplement composition is about 55%, preferred about 65% and most preferably from about 75% of compositions at least.Like this, the whole C log P value of all non-solid molecular entities of formation supplement composition is almost equal with the C log P value of independent oil ingredient.Supplement composition of the present invention comprises oil ingredient, and this oil ingredient is selected from many polyol fatty acids polyester, triglyceride, liquid synthetic polymer and composition thereof.
Many polyol fatty acids polyester
Many polyol fatty acids polyester is that these many alcohol have at least 4 free hydroxyl derived from the fatty acid poleysters of the many alcohol of any aliphatic series or aromatics, and at least 80% carries out esterification with one or more fatty acids with 8 22 carbon atoms in these hydroxyls.
The many alcohol that derive many polyol fatty acids polyester are preferably from sugar alcohol how, comprise list, two and polysaccharide.The how pure preferred examples of monosaccharide sugar has: how pure pentose is, as D-ribose, D-arabinose, D-xylose, D-lyxose, D-ribulose and D-xylulose; How pure sugar is, as D-allose, D-altrose, D-glucose, D-mannose, D-gulose, D-idose, D-galactose, D-talose, D-fructose, D-sorbose and D-Tagatose; How pure heptose is, as D-mannoheptulose and D-sedoheptulose;
The many alcohol that derive many polyol fatty acids polyester also can be selected from disaccharide, as maltose, lactose, cellobiose, sucrose, trehalose, gentiobiose, 6-(.alpha.-D-galactosido)-D-glucose. and 6-(.beta.-D-xylosido)-D-glucose..
The many alcohol that derive many polyol fatty acids polyester also can be selected from trisaccharide, as gentianose and melitriose.
The many alcohol that derive many polyol fatty acids polyester also can be selected from sugar alcohol, as D-mannitol, D-Sorbitol, D-ribitol, D-erithritol, D-lactose and D-xylitol.
Derive the also optional methyl glucoside freely of many alcohol of many polyol fatty acids polyester and the sugar of inositol.Preferred sugared many alcohol are sucrose.Many alcohol fatty acid esters of sucrose or SPEs are disclosed in the priority document of quoting in the description, and derived from sucrose and vegetable oil.This has been disclosed in the patent documentation of relevant nondigestible oil widely, for example include but not limited to the US3600186 that on August 17th, 1971 authorized, 4005195 of mandate on January 25th, 1977, awarded on January 25th, 1977 4005196, these patents have been transferred the possession of in P﹠G and have been incorporated herein and have been reference.
The fatty acid that is used to form many polyol fatty acids polyester here can be one C8-C24, the free fatty acid of preferred C16-C22.These fatty acids can be saturated or unsaturated, is line style or branched chain type.
Fatty and oily
Be used for fat of the present invention and oil and be triacylglycerol ester or triglyceride that the esterification by fatty acid and glycerol and glycerol forms.Although the difference between fat and the oil is uncertain, it at room temperature is solid-state or mouldable that fat generally is considered to, and oil is liquid under the same conditions.The fatty acid that esterification subsequently forms fat of triglyceride or oil the most normally derives from marine organisms, animal and plant source.About the further details of triglyceride oil, its source and processing, can be referring to " iundustrial oil and the fat products " of the Bailey that is introduced as reference, Interscience Publications publishes.
At least 90% ester substituent group has at least 12 carbon chain length on the triglyceride skeleton.Usually oil is hydrogenated to a certain degree to suppress abnormal flavour.This quasi-glycerol three-ester comprises the oil of plant source, as soybean oil, Oleum Ricini, olive oil, Oleum helianthi, almond oil, Oleum Arachidis hypogaeae semen, canola oil (canola oil), Semen Maydis oil, other similar plants oil and composition thereof.
Synthetic polymer oil
Synthetic polymer oil is useful in the present invention.Described synthetic polymer oil at room temperature is liquid, and comprises glycerol/diethylene glycol/adipic acid ester cross linked polymer (crosspolymer), and it is the Lexorez 100 available from Inolex chemical company.
Selectable components
There are many other compositions that can be used in the cosmetics can be used for the present composition.These compositions are to allow in those cosmetics to adopt, and can find in handbook, as " CTFA cosmetic composition handbook, the 2nd edition, cosmetics, public washing article and fragrance association, Inc, 1998,1992.Described material can adopt, as long as their adding obvious destroying compositions not, forms in case said composition is used and to approach.Described composition comprises wax, spice, flavoring oil, skin care ingredient, as sunscreen, emulsifying agent etc.The present composition also can be made into the hypoallergenic compositions, and wherein said compositions does not conform to spice, flavoring oil, lanoline, sunscreen, PABA especially, or other sensitizing agent and stimulus object.Other component that adds should not be reduced to the C Log P value of composition in its entirety and be lower than 13.The nonexcludability group of this other component of class below is discussed:
Although replenish normally transparently, comprise pigment and also can add, with the required effect of enhancing cosmetic product as the colorant of Talcum and micaceous particulate matter with compositions.Here the colorant of Shi Yonging is inorganic and organic toner/pigment that all are applicable to lip compositions.These have aluminum, barium or calcium salt or color lake.Color lake or fill or the colorant of dilution with solid-state diluent, or be deposited in the organic toner that absorbent surfaces prepares above by water-soluble dye, this is the hydrate of aluminum normally.Also can be from the precipitation of the insoluble salt of acidity or basic stain and produces in the color lake, also can use calcium and barium color lake here.
The preferred color lake of the present invention is red 3 aluminum color lakes, red 21 aluminum color lakes, red 27 aluminum color lakes, red 28 aluminum color lakes, red 33 aluminum color lakes, yellow 5 aluminum color lakes, yellow 6 aluminum color lakes, yellow 10 aluminum color lakes, orange 5 aluminum color lakes and blue 1 aluminum color lake, red 6 barium color lakes, red 7 calcium color lakes.
Other colorant and pigment also can be included in the lip compositions, as dyestuff and iridescent, titanium dioxide, red 6, red 21, blue 1, orange 5 and green 5 dyestuffs, Chalk, Talcum, iron oxides and metatitanic acid Muscovitum.
The wax that also can adopt q.s among the present invention is to provide the more solid-state composition of traditional form.Wax is defined as high-molecular weight low melting point organic mixture or complex, at room temperature is solid-state, and composition and fat and oil phase are that they do not contain glyceride seemingly usually.Some are hydrocarbon, and other is the ester of fatty acid and alcohol.Be used for wax of the present invention and be selected from animal wax, vegetable wax, mineral wax, the various fractions of native paraffin, synthetic wax, petrolatum wax, polyvinyls, hydro carbons, as Fischer-Tropsch wax, silicone waxes and composition thereof, wherein the fusing point of wax is 30 ℃ to 100 ℃.Be used for specific wax of the present invention and be selected from synthetic wax, ceresine, simmondsia ester, " Unilins ", " Ganex " alkylation polyvinyl pyrroles of ISP company of Petrolite company, aliphatic alcohol of C22 to C50 and composition thereof.Synthetic wax is included in wax chemistry and the technology of Warth, part 2, Reinhold publishing company publishes, in 1956 disclosed those, be introduced as reference.Here the fusing point of the most suitable wax is about 30 ℃ extremely about 115 ℃ and is selected from C8 to C50 chloroflo.These waxes comprise the long-chain polymer that oxirane combines with dihydroxylic alcohols, i.e. polyoxyethylene glycol.This class wax comprises the carbowat of carbide and C.-Chem AG.Other synthetic wax comprises the long-chain polymer that ethylene and OH or other form at the end capped group of chain end.This class wax comprises Fischer-Tropsch wax, as in above-mentioned article 465-469 page or leaf disclosed those and comprise Rosswox available from Ross company, and available from the PT-0602 of AstorWax company.Other synthetic wax comprises alkylation polyvinyl pyrrolidone class or PVP, and this comprises tricontanyl PVP (available from the Gannex WP-660 of ISP company) and PVP/ eicosylene copolymer (available from ISP company).
Emulsifying agent can be used as coupling agent, and it has affinity mutually with the hydrophilic and hydrophobic of lip compositions of the present invention.Emulsifying agent also can be used for introducing polar fluid, as water, propylene glycol, certain oil or its mixture.This class emulsifying agent comprises and is usually used in the cosmetics those, and can find in CTFA.Polar fluid for example water, glycerol, propylene glycol and composition thereof also can add and not need emulsifying agent, and this is when amphiprotic substance such as polyol fatty acid polyesters are used for compositions.
Not only can add in the lip compositions with water-soluble form but also with the skin care activity composition of water-insoluble form.Described composition can comprise fatsoluble vitamin, sunscreen and medicament active composition.These skin care activity compositions comprise glycerol, zinc oxide; Chamomile oil; Ginko biloba extract; Pyroglutamic acid, salt or ester; Hyaluronate sodium; The 2-Hydroxycaprylic acid; Sulfur; Salicylic acid; Carbocisteine; Water, propylene glycol and composition thereof.
Embodiment example 1: composition weight (%) SPE Cottonate 89.75SPE docosane acid esters 5.05 silk Muscovitum
15.05 propyl parabene 0.10 brassylic acid second diester 0.05
1Silk Muscovitum available from U.S.Cosmetics Corp.
At a container mixing all components and be heated to 90 ℃, constantly stir with paddle mixer simultaneously.After SPE docosane acid esters melted fully, mixture became uniformly, removed heating and was cooled to room temperature.In cooling procedure, should constantly stir the mixture.The liquid of gained is transferred in the individual packaging.Example 2: composition weight (%) SPE Cottonate 88.30SPE docosane acid esters 4.70 Muscovitums
14.65 propyl parabene 0.15 nipagin 0.15 brassylic acid second diester 0.05
1Silk Muscovitum available from U.S.Cosmetics Corp.
At a container mixing all components and be heated to 90 ℃, constantly stir with paddle mixer simultaneously.After SPE docosane acid esters melted fully, mixture became uniformly, removed heating and was cooled to room temperature.In cooling procedure, should constantly stir the mixture.The liquid of gained is transferred in the individual packaging.Example 3: composition weight (%) Oleum Ricini 89.75 glycerol/diethylene glycol/own diester cross linked polymer
15.00 ceresine 5.00 propyl parabenes 0.10 nipagin 0.10 brassylic acid second diester 0.05
1Lexorez 100 available from Inolex chemical company
At a container mixing all components and be heated to 90 ℃, constantly stir with arm mixer simultaneously.After ceresine melted fully, mixture became uniformly, removed heating and was cooled to room temperature.In cooling procedure, should constantly stir the mixture.The liquid of gained is transferred in the individual packaging.Example 4: composition weight (%) SPE Cottonate 85.85SPE docosane acid esters 14.00 propyl parabenes 0.10 brassylic acid second diester 0.05
At a container mixing all components and be heated to 90 ℃, constantly stir with paddle mixer simultaneously.After SPE docosane acid esters melted fully, mixture became uniformly, removed heating and poured in the lipstick mould, it was cooled to before the demoulding approximately-5 ℃, then it was put in the suitable packing.Example 5: composition weight (%) A group: SEFA Cottonate 84.58SEFA docosane acid esters 14.36Ganex Wax WP-660
10.86 propyl parabene 0.10BHT 0.05B group: brassylic acid second diester 0.05
1Ganex Wax available from ISP Technologies Inc.
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Adding B organizes component and mixed 5 minutes with arm mixer.Control temperature is no more than 90 ℃.When the mixture of A group component and B group component be mixed spare after, melt substance is poured in exsiccant (seasoned) lipstick mould.On about 20 minutes of the mould of 5 ℃ of cooling fillings.Move to mould in the environmental condition and demoulding outlet Toona sureni.This rod is packed in the lipstic case.Example 6: composition weight (%) A group: SEFA Cottonate 70.67SEFA docosane acid esters 14.13 Talcums 15.00 propyl parabene 0.10BHT 0.05B group: brassylic acid second diester 0.05
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Adding B organizes component and mixed 5 minutes with paddle mixer.Control temperature is no more than 90 ℃.When the mixture of A group component and B group component be mixed spare after, melt substance is poured in the exsiccant lipstick mould.On about 20 minutes of the mould of 5 ℃ of cooling fillings.Move to mould in the environmental condition and demoulding outlet Toona sureni.This rod is packed in the lipstic case.Example 7: composition weight (%) A group: SEFA Cottonate 83.17SEFA docosane acid esters 16.63 propyl parabene 0.10BHT 0.05B group: brassylic acid second diester 0.05
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Add the B component and mixed 5 minutes with arm mixer.Control temperature is no more than 90 ℃.When the mixture of A group component and B group component be mixed spare after, melt substance is poured in the exsiccant lipstick mould.On about 20 minutes of the mould of 5 ℃ of cooling fillings.Move to mould in the environmental condition and demoulding outlet Toona sureni.This rod is packed in the lipstic case.Example 8: composition weight (%) A group: SEFA Cottonate 75.02SEFA docosane acid esters 13.58 Talcum 7.50Ganex Wax WP-660
10.50 propyl parabene 0.15BHT 0.05B group: glycerol 3.00 nipagin 0.15C group: brassylic acid second diester 0.05
1Ganex Wax available from ISP Technologies Inc.
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Mix B group component and use the spatula mixing.Heating B group mixture is to about 90 ℃.Mix A group and B group component, under 5000rpm, homogenized 5 minutes.Adding C organizes component and mixed 5 minutes with paddle mixer.When mixture be mixed even after, melt substance is poured in the exsiccant lipstick mould.On about 20 minutes of the mould of 5 ℃ of cooling fillings.Move to mould in the environmental condition and demoulding outlet Toona sureni.This rod is packed in the lipstic case.Example 9: composition weight (%) A group: SEFA Cottonate 59.55SEFA docosane acid esters 12.50 Talcums 7.50 propyl parabenes 0.15 linoleic acid ester of vitamin e 0.10B group: water 10.00 propylene glycol 5.00 glycerol 5.00 nipagin 0.15C group: brassylic acid second diester 0.05
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Mix B group component and use the spatula mixing.Heating B group mixture is to about 90 ℃.Mix A group and B group component, under 5000rpm, homogenized 2 minutes.Adding C organizes component and mixed 5 minutes with paddle mixer.When mixture be mixed even after, melt substance is poured in the exsiccant lipstick mould.On about 20 minutes of the mould of 5 ℃ of cooling fillings.Move to mould in the environmental condition and demoulding outlet Toona sureni.This rod is packed in the lipstic case.Example 10: composition weight (%) A group: SEFA Cottonate 85.85SEFA docosane acid esters 14.00 propyl parabene 0.10B group: brassylic acid second diester 0.05
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Add the B component and mixed 5 minutes with paddle mixer.Control temperature is no more than 90 ℃.When the mixture of A group component and B group component be mixed spare after, melt substance is poured in the exsiccant lipstick mould.On about 20 minutes of the mould of 5 ℃ of cooling fillings.Move to mould in the environmental condition and demoulding outlet Toona sureni.This rod is packed in the lipstic case.Example 11: composition weight (%) A group: SEFA Cottonate 85.21SEFA docosane acid esters 14.09Ganex Wax WP-6601 0.50 propyl parabene 0.10BHT 0.05B group: brassylic acid second diester 0.05
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Add the B component and mixed 5 minutes with paddle mixer.Control temperature is no more than 90 ℃.When the mixture of A group component and B group component be mixed spare after, melt substance is poured in the exsiccant lipstick mould.On about 20 minutes of the mould of 5 ℃ of cooling fillings.Move to mould in the environmental condition and demoulding outlet Toona sureni.This rod is packed in the lipstic case.Example 12: composition weight (%) A group: SEFA Cottonate 89.75SEFA docosane acid esters 5.05 Muscovitums 5.05 propyl parabene 0.10B group: brassylic acid second diester 0.05
Mix A group component, and use the spatula mix homogeneously.Heating A group mixture is stirred between the period of heating once in a while until all solids fusing (about 90%).Add the B component and mixed 5 minutes with arm mixer.Control temperature is no more than 90 ℃.When the mixture of A group component and B group component be mixed spare after, melt substance is poured in the single container.Make it to be cooled to environmental condition.
The all embodiment that below do not comprise the cosmetics that can use with the above-mentioned supplement composition of the present invention.Embodiment 1: lip compositions composition weight (%) A group: siloxanes gum stock
112.60 Fancol ID
212.60B group: Fancol ID
243.38 bentonite
41.00 propylene carbonate 0.32 red #6 calcium color lake 1.00 red #7 barium color lakes, 3.00 titanium dioxide, 1.50 Muscovitums, 2.20 1170-002
322.401. dimethicone gum stock (2 available from the SE63 by name of General Electric Co. Limited, 500,000cSt) 2. available from the Permethyl 99A3. of Permethyl Corp. available from the MQ resin of the 1170-002 by name of General Electric Co. Limited (M: Q=0.7: 1) 4. available from the bentonite 38 of Rheox company
In beaker, the A component is mixed, and stir evenly with arm mixer.B group component that will be except that propylene carbonate is incorporated into and manually mixes roughly dry powder is incorporated into.Fully disperse until colorant with the RossME100LC homogenizer whole prescription that under 7500rpm, homogenizes.Then, when continuing the process of homogenizing, add propylene carbonate lentamente until the mixture retrogradation.In beaker, A group and the combination of B group mixture are also used the arm mixer mixing.Gained liquid is moved in the individual packaging.Embodiment 2: liquid foundation make-up composition weight (%) A group: 1170-002
14.48 SILIBIONE OIL 70047 V20 DC-21330 DC21330
211.11 silicone polyether emulsifying agent
310.00B group: the iron black 0.06C group that iron oxide red 0.15 polysiloxanes that iron oxide yellow 0.28 polysiloxanes that titanium dioxide 6.50 polysiloxanes that polysiloxanes is handled are handled is handled is handled: 2,500,000 cSt silicone gums
42.52 SILIBIONE OIL 70047 V20 DC-21330 DC21330
24.89D group: water 49.50 glycerol 10.00 nipagin 0.202-phenyl phenol 0.301. available from the MQ resin 2. of the 1170-002 by name of General Electric Co. Limited available from the SILIBIONE OIL 70047 V20 DC-21330 DC21330 3. of the 245Fluid by name of Dow Corning Corporation available from the silicone polyether emulsifying agent 4. of the DC3225C by name of Dow Corning Corporation dimethicone gum stock (2 available from the SE63 by name of Dow Corning Corporation, 500,000 cSt)
A group and B group component are mixed, and homogenizing 15 minutes under 9500rpm.Adding C group component also homogenized under 2000rpm 2 minutes.The D component mixed in another container and mix to the clear solution shape with arm mixer.Lentamente D is organized in the mixture that solution is added to A, B, C group, under 2000rpm, homogenize simultaneously.After all D group solution had all added, whole mixture 10 minutes again homogenized under 2000rpm.At last, under 5000rpm, homogenize whole mixture 5 minutes.Gained liquid is moved in the individual packaging.Embodiment 3: eyelash cosmetics composition weight (%) A group: 1170-002
19.60 SILIBIONE OIL 70047 V20 DC-21330 DC21330
28.82 silicone polyether emulsifying agent
310.00B group: the iron black 5.00C group that polysiloxanes is handled: 2,500,000 cSt silicone gum
45.40 SILIBIONE OIL 70047 V20 DC-21330 DC21330
216.19D group: water 43.50 sodium chloride 1.00 nipagin 0.202-phenyl phenol 0.301. available from the MQ resin 2. of the 1170-002 by name of General Electric Co. Limited available from the SILIBIONE OIL 70047 V20 DC-21330 DC21330 3. of 245 Fluid by name of Dow Corning Corporation available from the silicone polyether emulsifying agent 4. of the DC3225C by name of Dow Corning Corporation dimethicone gum stock (2 available from the SE63 by name of General Electric Co. Limited, 500,000 cSt)
A group and B group component are mixed, and homogenizing 15 minutes under 9500rpm.Adding C group component also homogenized under 2000rpm 2 minutes.The D component mixed in another container and mix to the clear solution shape with paddle mixer.Lentamente D is organized in the mixture that solution is added to A, B, C group, under 2000rpm, homogenize simultaneously.After all D group solution had all added, whole mixture 10 minutes again homogenized under 2000rpm.At last, under 5000rpm, homogenize whole mixture 5 minutes.Gained liquid is moved in the individual packaging.Embodiment 4: shear lipstick shading composition (Shear Lip Tint Composition) composition weight (%) A group: silicone gum
111.88 Fancol ID
254.45B group: 1170-002
320.78 red #6 calcium color lake 0.50 red #7 barium color lake 0.50Gemtone Sunstone
50.50Timiron MP-115 iridescent
60.50 Bentonite gel
410.891. dimethicone gum stock (2 available from the SE63 by name of General Electric Co. Limited, 500,000cSt) 2. available from the Permethyl 99A3. of Permethyl Corp. available from the MQ resin of the 1170-002 by name of General Electric Co. Limited (M: Q=0.7: 1) 4. available from the VS-5PC5. of Rheox available from the Gemtone Sunstone6. of Mear company Timiron MP-115 iridescent available from Mear company
In beaker, the A component is mixed, and use the arm mixer mix homogeneously.In A group component mixture, add B group component and manual stirring roughly dry powder is incorporated into.The whole ingredients that homogenizes is fully disperseed until all colorants.The gained fluid is moved in the individual packaging.Embodiment 5: liquid informer's components of cosmetics weight (%) A group: 1170-002
18.90 Fancol ID
214.90B group: iron black 20.00 propyl p-hydroxybenzoate 0.10C group: the polyorganosiloxane fluid of 100,000 cSt
311.10 Fancol ID
233.00D group: Fancol ID
210.00 trihydroxy tristerin 2.001. is available from the MQ resin of the 1170-002 by name of General Electric Co. Limited (M: Q=0.7: 1) 2. available from the Permethyl 99A3. of the Permethyl Corp. dimethicone liquid available from General Electric Co. Limited
The A component is mixed and be mixed even with paddle mixer.Adding B group component also homogenizes until the abundant mark of colorant.In another container with arm mixer with the premixing of C component until evenly, be incorporated into the mixture of A group and B group component then.Premixing D component and be heated to about 57-60 ℃ about 3 minutes.Remove heating and homogenized about 5 minutes or occur until gel.At last, D is organized component mixture be added in remaining material and heat whole mixture to 57-60 ℃ of about 7-10 minute, paddle mixer mixes simultaneously.Remove heating and be cooled to room temperature, mix with arm mixer simultaneously.Gained liquid is moved in the individual packaging.Embodiment 6: eye shadow components of cosmetics weight (%) A group: 1170-002
122.40 Fancol ID
214.90B group: Flamenco Gold Pearl 0.60Flamenco Superpearl 0.84 titanium dioxide 0.94Gemtone Copper 0.41Gemtone Sunstone 1.21 propyl p-hydroxybenzoate 0.10C group: the polyorganosiloxane fluid of 1,000 cSt
313.86 Fancol ID
233.00D group: Fancol ID
210.00 trihydroxy tristerin 2.001. is available from the MQ resin of the 1170-002 by name of General Electric Co. Limited (M: Q=0.7: 1) 2. available from the Permethyl 99A3. of the Permethyl Corp. dimethicone liquid available from General Electric Co. Limited
The A component is mixed and be mixed even with arm mixer.Adding B group component also homogenizes until the abundant mark of colorant.In another container with paddle mixer with the premixing of C component until evenly, be incorporated into the mixture of A group and B group component then.Premixing D component and be heated to about 57-60 ℃ about 3 minutes.Remove heating and homogenized about 5 minutes or occur until gel.At last, D is organized component mixture be added in remaining material and heat whole mixture to 57-60 ℃ of about 7-10 minute, paddle mixer mixes simultaneously.Remove heating and be cooled to room temperature, mix with arm mixer simultaneously.Gained liquid is moved in the individual packaging.
Improve the method for cosmetics
In addition, the present invention relates to improve the method for the pliability film-forming cosmetic of metastasis, described method comprises:
A. to the pliability film-forming cosmetic of dermal administration metastasis, the solubility parameter of wherein said cosmetics be less than or equal to 8.5 (card/centimetre
3)
1/2
B. allow described cosmetics drying; With
C. use supplement composition on described cosmetics, the C log P value of wherein said compositions is more than or equal to 13.
User is applied in cosmetics of the present invention and the supplement composition in the suitable liquid make-up applicator.A kind of this class applicator that is used for fluid product is British patent 21198037 a disclosed form of a stroke or a combination of strokes liquid package, and this patent is authorized in 5/09/90, and transfers the possession of in a Mitsubishi system company limited.
Another kind of this class cosmetic product applicators is that the folk prescription that increases of dosage is to the screw type applicator, be disclosed in people's such as Horstman the USSN_ patent application of common pending trial, the applying date, to transfer the possession of and P﹠G, its title is " the simple folk prescription that dosage increases is to the screw type applicator ".This screw type applicator can comprise a hollow sheath body, and it has determined a cell, and the piston holding and be positioned at cell of using of an opening is arranged on this chamber, and it is restricted to straight line and moves in cell.This piston preferably has the threaded rod that stretches out from it, and this bar links to each other with tapping hole in actuator, makes when actuator rotates, and the propelling of piston to applicator occur.The rotation of actuator produces product from using using of end.Applicator preferably is connected in using on the end of sheath body, and this end links to each other with cell and carries out the liquid conveying, and the product in the cell is used by applicator.Applicator can comprise coupling and use part that wherein coupling is connected to the end of using of sheath body, has at least one opening and use in the part.The applicator of several forms can adopt, the application surface that this comprises brosse for example or felt pan is arranged.Felt pan is meant that the flexible fiber of thin weak point is basically perpendicular to the cushion block of application surface.The hair of brosse preferably taper and make by flexible material.In addition, supplement composition can form solid-state and can adopt more traditional applicator known in the art or instrument.
Claims (6)
1. improve the compositions of performance metastasis, the pliability film-forming cosmetic, described cosmetics have and be less than or equal to 8.5 (card/centimetre
3)
1/2Solubility parameter, wherein to comprise C Log P value be 13 or higher oil to compositions.
2. the compositions of claim 2, wherein compositions comprises at least 55% oil, this grease separation is from polyol fatty acid polyesters, triglyceride, synthetic polymer oil and composition thereof, preferred at least 65% polyol fatty acid polyesters, wherein polyol fatty acid polyesters comprises fatty acid poleysters, it is preferably derived from aliphatic series with at least 4 free hydroxyl or aromatic polyol, and at least 80% free hydroxyl is had one or more fatty acid esterifications of 8 to 22 carbon atoms in this alcohol.
3. the compositions of claim 3, wherein polyhydric alcohol is a sugar polyol, is selected from list, two and polysaccharide, preferably sucrose, more preferably at least 85% sucrose polyhydric alcohol.
4. the compositions of claim 2, its medium oil is a triglyceride, the oil in preferred plant source.
5. the compositions of claim 9, wherein the grease separation of plant source is from for example soybean oil, Oleum Ricini, olive oil, Oleum helianthi, almond oil, Oleum Arachidis hypogaeae semen, canola oil, Semen Maydis oil, other similar relevant vegetable oil and composition thereof.
6. method of improving the long-wearing comsetic products performance, this method may further comprise the steps:
A. use the pliability film-forming cosmetic of metastasis, the solubility parameter of wherein said cosmetics be less than or equal to 8.5 (card/centimetre
3)
1/2
B. allow described cosmetics drying; With
C. use a kind of compositions on described cosmetics, wherein said compositions comprises C Log P value and is not less than 13 oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96199088A CN1098064C (en) | 1995-11-07 | 1996-10-25 | Compositions and methods for improving performance of long-wearing cosmetic products |
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US627395P | 1995-11-07 | 1995-11-07 | |
| US60/006,273 | 1995-11-07 | ||
| US855295P | 1995-12-13 | 1995-12-13 | |
| US60/008,552 | 1995-12-13 | ||
| CN96199088A CN1098064C (en) | 1995-11-07 | 1996-10-25 | Compositions and methods for improving performance of long-wearing cosmetic products |
| PCT/US1996/017145 WO1997017057A1 (en) | 1995-11-07 | 1996-10-25 | Compositions and methods for improving the performance of long-wearing cosmetic products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1204252A true CN1204252A (en) | 1999-01-06 |
| CN1098064C CN1098064C (en) | 2003-01-08 |
Family
ID=27429992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96199088A Expired - Lifetime CN1098064C (en) | 1995-11-07 | 1996-10-25 | Compositions and methods for improving performance of long-wearing cosmetic products |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1098064C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100413488C (en) * | 2000-12-12 | 2008-08-27 | 欧莱雅股份有限公司 | Cosemetic compositions containing at least one hetero polymer and at least one film-forming silicone resin and methods of using |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9113484D0 (en) * | 1991-06-21 | 1991-08-07 | Unilever Plc | Cosmetic composition |
-
1996
- 1996-10-25 CN CN96199088A patent/CN1098064C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100413488C (en) * | 2000-12-12 | 2008-08-27 | 欧莱雅股份有限公司 | Cosemetic compositions containing at least one hetero polymer and at least one film-forming silicone resin and methods of using |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1098064C (en) | 2003-01-08 |
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