CN120136498B - Concrete based on iron ore tailings and preparation method thereof - Google Patents

Concrete based on iron ore tailings and preparation method thereof

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Publication number
CN120136498B
CN120136498B CN202510247304.6A CN202510247304A CN120136498B CN 120136498 B CN120136498 B CN 120136498B CN 202510247304 A CN202510247304 A CN 202510247304A CN 120136498 B CN120136498 B CN 120136498B
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iron ore
ore tailings
stirring
concrete
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CN120136498A (en
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李淳
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Anhui Wanke New Technology Development Co ltd
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Anhui Wanke New Technology Development Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/12Waste materials; Refuse from quarries, mining or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators or shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/066Magnesia; Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2652Nitrogen containing polymers, e.g. polyacrylamides, polyacrylonitriles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/38Polysaccharides or derivatives thereof
    • C04B24/383Cellulose or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mining & Mineral Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The application relates to concrete based on iron ore tailings and a preparation method thereof, and belongs to the technical field of iron ore tailings application, wherein the preparation raw materials of the concrete comprise, by weight, 20-30 parts of polyacrylamide solution, 3-6 parts of magnesia powder, 5-10 parts of resin, 20-25 parts of polypropylene fiber, 10-18 parts of antioxidant and 5-12 parts of cellulose acetate butyrate powder, and the preparation raw materials of the water reducer comprise, by weight, 6-10 parts of montmorillonite powder, 10-15 parts of ferric oxide powder and 3-8 parts of corn starch. The existing iron ore tailings are added into the concrete to reduce the compressive strength and the flexural strength, and the iron ore tailings are mutually cooperated with the polyacrylamide solution, the magnesia powder and the cellulose acetate butyrate powder to reduce the influence of the iron ore tailings on the compressive strength and the flexural strength of the concrete, increase the content of the concrete as the iron ore tailings and increase the consumption of the iron ore tailings.

Description

Concrete based on iron ore tailings and preparation method thereof
Technical Field
The invention belongs to the technical field of iron ore tailings application, and particularly relates to concrete based on iron ore tailings and a preparation method thereof.
Background
The iron ore tailings are waste residues left after ore dressing, contain beneficial components and harmful components in the iron ore, are accumulated more due to ore exploitation, pollute the environment after long-term storage, and are usually used for preparing concrete.
However, when concrete is disposed, the proportion of iron ore tailings added is inversely related to the strength of the concrete, that is, the higher the proportion of iron ore tailings added to the concrete is, the lower the strength of the concrete is, and therefore, in order to increase the strength of the concrete, it is necessary to reduce the addition of iron ore tailings, which makes it difficult to consume a large amount of iron ore tailings.
Disclosure of Invention
The invention aims to solve the problems and provide concrete based on iron ore tailings and a preparation method thereof.
The invention realizes the above purpose through the following technical scheme:
The invention provides concrete based on iron ore tailings, which comprises the iron ore tailings, river sand, silicate cement, tap water, binding liquid and a water reducing agent;
the adhesive liquid is prepared from, by weight, 20-30 parts of polyacrylamide solution, 3-6 parts of magnesia powder, 5-10 parts of resin, 20-25 parts of polypropylene fibers, 10-18 parts of antioxidants and 5-12 parts of cellulose acetate butyrate powder, and the water reducer is prepared from, by weight, 6-10 parts of montmorillonite powder, 10-15 parts of ferric oxide powder and 3-8 parts of corn starch.
According to the preparation method, the concrete is prepared from, by weight, 20-35 parts of iron ore tailings, 10-15 parts of river sand, 35-45 parts of Portland cement, 60-80 parts of tap water, 5-10 parts of binding liquid and 8-15 parts of water reducer.
As a further optimization scheme of the invention, the preparation process of the polyacrylamide solution comprises the steps of placing the polyacrylamide colloid in a container and stirring for 30-45min, adding pure water in the stirring process and mixing with the pure water, and obtaining the polyacrylamide solution after full mixing, wherein the stirring speed is 60rpm.
As a further optimization scheme of the invention, the mass ratio of the polyacrylamide colloid to the pure water is 1:5.
The preparation process of the resin comprises the steps of heating and fusing furfuryl alcohol resin and rosin to obtain the resin, mixing palmitic acid, magnesium stearate and glycerin, adding distilled water, and heating to 80-120 ℃ to obtain the antioxidant.
According to the preparation method, the resin is prepared from, by weight, 30-45 parts of furfuryl alcohol resin and 10-20 parts of rosin, and the antioxidant is prepared from, by weight, 20-35 parts of palmitic acid, 6-10 parts of magnesium stearate, 10-20 parts of glycerol and 50-60 parts of distilled water.
The invention also provides a preparation method of the concrete based on the iron ore tailings, which comprises the following steps:
S1, heating a polyacrylamide solution to 100-120 ℃, stirring after the temperature is reached, wherein the stirring speed is 80rpm, stirring for 45-60min, adding magnesia powder and polypropylene fiber in the 10 th min of stirring, adding resin and cellulose acetate butyrate powder in the 20 th min of stirring, and finally adding an antioxidant in the 30 th min of stirring to obtain a bonding liquid;
S2, mixing montmorillonite powder, ferric oxide powder and corn starch, and grinding to 10-15nm through a grinding process to obtain a water reducer;
s3, adding the adhesive liquid into tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
and S4, putting the iron ore tailings, the river sand and the acid salt cement into the cement mixer with the mixture in the step S3, stirring, adding the water reducer during stirring, and uniformly mixing to obtain the concrete.
As a further optimization scheme of the invention, the stirring time in the step S4 is 20-35min, and the stirring speed is 60rpm.
The application has the beneficial effects that the compressive strength and the flexural strength of the existing iron ore tailings are reduced when the iron ore tailings are added into the concrete, and the iron ore tailings are mutually cooperated with the polyacrylamide solution, the magnesia powder and the cellulose acetate butyrate powder, so that the influence of the iron ore tailings on the compressive strength and the flexural strength of the concrete is reduced, the content of the concrete when the iron ore tailings are increased, and the consumption of the iron ore tailings is increased.
Detailed Description
The following detailed description of the application is provided to illustrate the application and should not be construed as limiting the scope of the application since it is intended that the following detailed description is given for the purpose of illustration only, and that certain non-essential modifications and adaptations of the application may occur to those skilled in the art in light of the foregoing disclosure.
Example 1
The concrete of the embodiment is prepared by the following steps:
placing the polyacrylamide colloid into a container, stirring for 30min, adding pure water in the stirring process, mixing with the pure water, and fully mixing to obtain a polyacrylamide solution, wherein the stirring speed is 60rpm, and the mass ratio of the polyacrylamide colloid to the pure water is 1:5;
Mixing 20 parts of palmitic acid, 6 parts of magnesium stearate and 10 parts of glycerol, adding 50 parts of distilled water, and heating to 80 ℃ to obtain an antioxidant;
heating 20 parts of polyacrylamide solution to 100 ℃, stirring when the temperature reaches, wherein the stirring speed is 80rpm, stirring for 45min, adding 3 parts of magnesia powder and 20 parts of polypropylene fibers in the 10 th min of stirring, adding 5 parts of resin and 5 parts of cellulose acetate butyrate powder in the 20 th min of stirring, and finally adding 10 parts of antioxidant in the 30 th min of stirring to obtain a bonding liquid;
Mixing 6 parts of montmorillonite powder, 10 parts of ferric oxide powder and 3 parts of corn starch, and grinding to 10nm through a grinding process to obtain a water reducer;
Adding 5 parts of binding solution into 60 parts of tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
20 parts of iron ore tailings, 10 parts of river sand and 35 parts of silicate cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 20min, the stirring speed is 60 rpm), 8 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain the concrete.
Example 2
The concrete of the embodiment is prepared by the following steps:
Placing the polyacrylamide colloid into a container, stirring for 35min, adding pure water in the stirring process, mixing with the pure water, and fully mixing to obtain a polyacrylamide solution, wherein the stirring speed is 60rpm, and the mass ratio of the polyacrylamide colloid to the pure water is 1:5;
Mixing 28 parts of palmitic acid, 8 parts of magnesium stearate and 15 parts of glycerol, adding 55 parts of distilled water, and heating to 100 ℃ to obtain an antioxidant;
Heating 25 parts of polyacrylamide solution to 110 ℃, stirring after the temperature reaches, wherein the stirring speed is 80rpm, stirring for 50min, adding 5 parts of magnesia powder and 22 parts of polypropylene fibers in the 10 th min of stirring, adding 8 parts of resin and 8 parts of cellulose acetate butyrate powder in the 20 th min of stirring, and finally adding 14 parts of antioxidant in the 30 th min of stirring to obtain a bonding liquid;
mixing 8 parts of montmorillonite powder, 12 parts of ferric oxide powder and 6 parts of corn starch, and grinding to 13nm through a grinding process to obtain a water reducer;
adding 8 parts of binding solution into 70 parts of tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
30 parts of iron ore tailings, 12 parts of river sand and 40 parts of silicate cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 30min, the stirring speed is 60 rpm), 10 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain concrete.
Example 3
The concrete of the embodiment is prepared by the following steps:
Placing the polyacrylamide colloid into a container, stirring for 45min, adding pure water in the stirring process, mixing with the pure water, and fully mixing to obtain a polyacrylamide solution, wherein the stirring speed is 60rpm, and the mass ratio of the polyacrylamide colloid to the pure water is 1:5;
mixing 35 parts of palmitic acid, 10 parts of magnesium stearate and 20 parts of glycerol, adding 60 parts of distilled water, and heating to 120 ℃ to obtain an antioxidant;
Heating 30 parts of polyacrylamide solution to 120 ℃, stirring when the temperature reaches, wherein the stirring speed is 80rpm, stirring for 60min, adding 6 parts of magnesia powder and 25 parts of polypropylene fibers in the 10 th min of stirring, adding 10 parts of resin and 12 parts of cellulose acetate butyrate powder in the 20 th min of stirring, and finally adding 18 parts of antioxidant in the 30 th min of stirring to obtain a bonding liquid;
Mixing 10 parts of montmorillonite powder, 15 parts of ferric oxide powder and 8 parts of corn starch, and grinding to 15nm through a grinding process to obtain a water reducer;
adding 10 parts of binding solution into 80 parts of tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
35 parts of iron ore tailings, 15 parts of river sand and 45 parts of Portland cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 35min, the stirring speed is 60 rpm), 15 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain the concrete.
Comparative example 1
The concrete of the comparative example is prepared by the following steps:
Placing the epoxy resin colloid into a container, stirring for 35min, adding pure water in the stirring process, mixing with the pure water, and obtaining an epoxy resin solution after full mixing, wherein the stirring speed is 60rpm, and the mass ratio of the epoxy resin colloid to the pure water is 1:5;
Mixing 28 parts of palmitic acid, 8 parts of magnesium stearate and 15 parts of glycerol, adding 55 parts of distilled water, and heating to 100 ℃ to obtain an antioxidant;
Heating 25 parts of epoxy resin solution to 110 ℃, stirring when the temperature reaches, wherein the stirring speed is 80rpm, stirring for 50min, adding 5 parts of magnesia powder and 22 parts of polypropylene fibers in the 10 th min of stirring, adding 8 parts of resin and 8 parts of cellulose acetate butyrate powder in the 20 th min of stirring, and finally adding 14 parts of antioxidant in the 30 th min of stirring to obtain adhesive liquid;
mixing 8 parts of montmorillonite powder, 12 parts of ferric oxide powder and 6 parts of corn starch, and grinding to 13nm through a grinding process to obtain a water reducer;
adding 8 parts of binding solution into 70 parts of tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
30 parts of iron ore tailings, 12 parts of river sand and 40 parts of silicate cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 30min, the stirring speed is 60 rpm), 10 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain concrete.
Comparative example 2
The concrete of the comparative example is prepared by the following steps:
Placing the polyacrylamide colloid into a container, stirring for 35min, adding pure water in the stirring process, mixing with the pure water, and fully mixing to obtain a polyacrylamide solution, wherein the stirring speed is 60rpm, and the mass ratio of the polyacrylamide colloid to the pure water is 1:5;
Mixing 28 parts of palmitic acid, 8 parts of magnesium stearate and 15 parts of glycerol, adding 55 parts of distilled water, and heating to 100 ℃ to obtain an antioxidant;
Heating 26.6 parts of polyacrylamide solution to 110 ℃, stirring after the temperature reaches, wherein the stirring speed is 80rpm, stirring for 50min, adding 24.5 parts of polypropylene fiber in the 10 th min of stirring, adding 8.5 parts of resin and 8.5 parts of cellulose acetate butyrate powder in the 20 th min of stirring, and finally adding 16 parts of antioxidant in the 30 th min of stirring to obtain a bonding liquid;
mixing 8 parts of montmorillonite powder, 12 parts of ferric oxide powder and 6 parts of corn starch, and grinding to 13nm through a grinding process to obtain a water reducer;
adding 8 parts of binding solution into 70 parts of tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
30 parts of iron ore tailings, 12 parts of river sand and 40 parts of silicate cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 30min, the stirring speed is 60 rpm), 10 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain concrete.
Comparative example 3
The concrete of the comparative example is prepared by the following steps:
Placing the polyacrylamide colloid into a container, stirring for 35min, adding pure water in the stirring process, mixing with the pure water, and fully mixing to obtain a polyacrylamide solution, wherein the stirring speed is 60rpm, and the mass ratio of the polyacrylamide colloid to the pure water is 1:5;
Mixing 28 parts of palmitic acid, 8 parts of magnesium stearate and 15 parts of glycerol, adding 55 parts of distilled water, and heating to 100 ℃ to obtain an antioxidant;
Heating 27.6 parts of polyacrylamide solution to 110 ℃, stirring after the temperature reaches, wherein the stirring speed is 80rpm, stirring for 50min, adding 5.6 parts of magnesia powder and 24.3 parts of polypropylene fibers in the 10 th min of stirring, adding 9 parts of resin in the 20 th min of stirring, and finally adding 15.5 parts of antioxidant in the 30 th min of stirring to obtain a bonding liquid;
mixing 8 parts of montmorillonite powder, 12 parts of ferric oxide powder and 6 parts of corn starch, and grinding to 13nm through a grinding process to obtain a water reducer;
adding 8 parts of binding solution into 70 parts of tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
30 parts of iron ore tailings, 12 parts of river sand and 40 parts of silicate cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 30min, the stirring speed is 60 rpm), 10 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain concrete.
Comparative example 4
The concrete of the comparative example is prepared by the following steps:
mixing 8 parts of montmorillonite powder, 12 parts of ferric oxide powder and 6 parts of corn starch, and grinding to 13nm through a grinding process to obtain a water reducer;
adding 8 parts of binding solution into 70 parts of tap water, uniformly mixing to obtain a mixture, and putting the mixture into a cement mixer;
12 parts of river sand and 40 parts of silicate cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 30min, the stirring speed is 60 rpm), 10 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain concrete.
Comparative example 5
The concrete of the comparative example is prepared by the following steps:
mixing 8 parts of montmorillonite powder, 12 parts of ferric oxide powder and 6 parts of corn starch, and grinding to 13nm through a grinding process to obtain a water reducer;
30 parts of iron ore tailings, 12 parts of river sand and 40 parts of silicate cement are put into a cement mixer containing the mixture, the mixture is stirred (the stirring time is 30min, the stirring speed is 60 rpm), 10 parts of water reducer is added during stirring, and the mixture is uniformly mixed to obtain concrete.
Performance test
1.1, Concrete samples prepared in examples 1-3 and comparative examples 1-5 were taken, compressive strength and flexural strength performance were tested according to the concrete strength test evaluation Standard GB/T50107-2010 at the ages of 3d and 28d, portland cement (from Jianghuai building materials science and technology Co., ltd.) for test, river sand (ISO standard sand) and iron ore tailings (extra fine sand meeting GB/T31288-2014 and having a fineness modulus of 1.5-0.7 were selected).
TABLE 1 product Performance test
The test results are shown in Table 1 above, comparing examples 1-3 and finding that the proportioned parts by weight of the concrete used in example 2 is optimal in both compressive strength and flexural strength, comparing comparative example 1 with example 2 and finding that comparative example 1 is not as good as example 2 in compressive strength and flexural strength by changing the polyacrylamide solution to an epoxy solution, and then comparing comparative example 4 with example 2 and finding that comparative example 2 is not as good as example 2 in compressive strength and flexural strength, comparing comparative example 2 with example 2 and finding that no magnesium oxide powder is added to comparative example 2 and making comparative example 2 not as example 2 in compressive strength and flexural strength, comparing comparative example 3 with example 2 and finding that comparative example 3 lacks cellulose acetate butyrate powder and making comparative example 3 not as example 2 in compressive strength and flexural strength, comparing comparative example 4 with example 2 and finding that comparative example 4 is not as good as example 2 in compressive strength, and comparing comparative example 4 with example 2 and finding that comparative example 4 is not as good as example 2 in compressive strength and comparative example 4 is not as compared to example 2 in compressive strength, and comparing example 2 by not as compared to example 28 and comparing example 2 and finding that comparative example 2 is not as good as example 2 and comparing example 2 is not as compressive strength and as compared as example 28d and comparing example 2 and comparing comparative example 2 and comparing example 2 to find that comparative example 2 is not as good as compressive strength and as compared as example 2.
In summary, there are many factors affecting the compressive strength and flexural strength of concrete, in which the addition of polyacrylamide solution, magnesia powder, cellulose acetate butyrate powder, iron oxide powder and antioxidant to concrete has a great influence on the compressive strength and flexural strength of concrete, and the existing addition of iron ore tailings to concrete results in a decrease in compressive strength and flexural strength, whereas iron ore tailings in the present application cooperate with polyacrylamide solution, magnesia powder, cellulose acetate butyrate powder, so that example 2 has no compressive strength and flexural strength of iron ore tailings concrete at 28d because of comparative example 4.
1.2, Concrete samples prepared in examples 1 to 3 and comparative examples 1 to 5 were taken and placed in a container, respectively, and initial setting time and final setting time of the concrete samples prepared in examples 1 to 3 and comparative examples 1 to 4 were measured using a Vicat in an environment of-5 ℃.
TABLE 2 product Performance test
Group of Initial setting time/min Final setting time/min
Example 1 50 155
Example 2 45 150
Example 3 48 150
Comparative example 1 56 240
Comparative example 2 65 245
Comparative example 3 60 240
Comparative example 4 45 160
Comparative example 5 63 180
As shown in table 2 above, it can be seen from comparison that the initial setting time of the concrete prepared by the method of example 2 is the same as that of comparative example 4, but the final setting time is longer than that of example 2, so that it is explained that the initial setting time of the concrete is not affected but the final setting time of the concrete is affected without adding iron ore tailings, and the polyacrylamide solution, magnesia powder, cellulose acetate butyrate powder and iron ore tailings added in example 2 cooperate with each other, so that the final setting time of the concrete can be shortened.
The foregoing examples illustrate only a few embodiments of the invention and are described in detail herein without thereby limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention.

Claims (8)

1.一种基于铁矿尾砂的混凝土,其特征在于,所述混凝土的制备原料包括铁矿尾砂、河沙、硅酸盐水泥、自来水、粘合液和减水剂;1. A type of concrete based on iron ore tailings, characterized in that the raw materials for preparing the concrete include iron ore tailings, river sand, silicate cement, tap water, adhesive liquid and water-reducing agent; 其中,按重量份计,所述粘合液的制备原料为:20-30份聚丙烯酰胺溶液、3-6份氧化镁粉、5-10份树脂、20-25份聚丙烯纤维、10-18份抗氧化剂和5-12份乙酸丁酸纤维素粉;所述减水剂的制备原料为:6-10份蒙脱石粉、10-15份氧化铁粉、3-8份玉米淀粉。The raw materials for preparing the adhesive liquid, by weight, are: 20-30 parts polyacrylamide solution, 3-6 parts magnesium oxide powder, 5-10 parts resin, 20-25 parts polypropylene fiber, 10-18 parts antioxidant and 5-12 parts cellulose acetate butyrate powder; the raw materials for preparing the water-reducing agent are: 6-10 parts montmorillonite powder, 10-15 parts iron oxide powder and 3-8 parts corn starch. 2.根据权利要求1所述的一种基于铁矿尾砂的混凝土,其特征在于,按照重量份计,所述混凝土的制备原料为:20-35份铁矿尾砂、10-15份河沙、35-45份硅酸盐水泥、60-80份自来水、5-10份粘合液和8-15份减水剂。2. The concrete based on iron ore tailings according to claim 1, characterized in that, by weight, the raw materials for preparing the concrete are: 20-35 parts iron ore tailings, 10-15 parts river sand, 35-45 parts silicate cement, 60-80 parts tap water, 5-10 parts adhesive liquid and 8-15 parts water-reducing agent. 3.根据权利要求2所述的一种基于铁矿尾砂的混凝土,其特征在于,所述聚丙烯酰胺溶液的制备过程为:将聚丙烯酰胺胶体放入容器当中搅拌30-45min,在搅拌过程中加入纯水与之混合,充分混合后得到聚丙烯酰胺溶液,所述搅拌速度为60rpm。3. The concrete based on iron ore tailings according to claim 2, characterized in that the preparation process of the polyacrylamide solution is as follows: polyacrylamide colloid is placed in a container and stirred for 30-45 minutes, pure water is added and mixed during the stirring process, and a polyacrylamide solution is obtained after thorough mixing, wherein the stirring speed is 60 rpm. 4.根据权利要求3所述的一种基于铁矿尾砂的混凝土,其特征在于,所述聚丙烯酰胺胶体与纯水的质量比为1:5。4. The concrete based on iron ore tailings according to claim 3, characterized in that the mass ratio of the polyacrylamide colloid to pure water is 1:5. 5.根据权利要求1所述的一种基于铁矿尾砂的混凝土,其特征在于,所述树脂的制备过程为:将糠醇树脂和松香进行加热融合,得到树脂;所述抗氧化剂的制备过程为:将棕榈酸、硬脂酸镁、甘油进行混合,后加入蒸馏水,加热至80-120℃,得到抗氧化剂。5. The concrete based on iron ore tailings according to claim 1, characterized in that the resin is prepared by heating and fusing furfuryl alcohol resin and rosin to obtain resin; the antioxidant is prepared by mixing palmitic acid, magnesium stearate and glycerin, then adding distilled water and heating to 80-120℃ to obtain antioxidant. 6.根据权利要求5所述的一种基于铁矿尾砂的混凝土,其特征在于,按重量份计,所述树脂的制备原料为:30-45份糠醇树脂和10-20份松香;所述抗氧化剂的制备原料为:20-35份棕榈酸、6-10份硬脂酸镁、10-20份甘油和50-60份蒸馏水。6. The concrete based on iron ore tailings according to claim 5, characterized in that, by weight, the raw materials for preparing the resin are: 30-45 parts furfuryl alcohol resin and 10-20 parts rosin; the raw materials for preparing the antioxidant are: 20-35 parts palmitic acid, 6-10 parts magnesium stearate, 10-20 parts glycerol and 50-60 parts distilled water. 7.一种权利要求1-6任一所述的基于铁矿尾砂的混凝土的制备方法,其特征在于,包括以下步骤:7. A method for preparing concrete based on iron ore tailings as described in any one of claims 1-6, characterized in that it comprises the following steps: S1,将聚丙烯酰胺溶液加热至100-120℃,当温度达到后进行搅拌,搅拌速度为80rpm,搅拌45-60min,在搅拌的第10min加入氧化镁粉和聚丙烯纤维,在搅拌的第20min加入树脂和乙酸丁酸纤维素粉,最后在搅拌的第30min加入抗氧化剂,得到粘合液;S1. Heat the polyacrylamide solution to 100-120℃. Once the temperature is reached, stir at 80 rpm for 45-60 minutes. Add magnesium oxide powder and polypropylene fiber at the 10th minute of stirring. Add resin and cellulose acetate butyrate powder at the 20th minute of stirring. Finally, add antioxidant at the 30th minute of stirring to obtain the adhesive liquid. S2,将蒙脱石粉、氧化铁粉和玉米淀粉进行混合,通过研磨工艺研磨至10-15nm,得到减水剂;S2, Montmorillonite powder, iron oxide powder and corn starch are mixed and ground to 10-15nm by a grinding process to obtain a water-reducing agent; S3,将粘合液加入到自来水中,混合均匀后得到混合物,将混合物投入水泥搅拌机当中;S3, add the adhesive liquid to tap water, mix well to obtain a mixture, and put the mixture into a cement mixer; S4,将铁矿尾砂、河沙和酸盐水泥投入步骤S3中的盛有混合物的水泥搅拌机中,进行搅拌,在搅拌期间加入减水剂,混合均匀后得到混凝土。S4. Iron ore tailings, river sand and acid cement are put into the cement mixer containing the mixture in step S3 and stirred. Water-reducing agent is added during stirring. After mixing evenly, concrete is obtained. 8.根据权利要求7所述的一种基于铁矿尾砂的混凝土的制备方法,其特征在于,所述步骤S4中的搅拌时长为20-35min,搅拌速度为60rpm。8. The method for preparing concrete based on iron ore tailings according to claim 7, characterized in that the stirring time in step S4 is 20-35 min and the stirring speed is 60 rpm.
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EP3472117A4 (en) * 2016-06-20 2020-07-29 Integrity Bio-Chemicals, LLC IMPROVED BONDS FOR IRON ORE PELLETIZING AND CEMENT ADHESIVES
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CN110357538A (en) * 2019-08-01 2019-10-22 西安新意达建筑制品有限公司 A kind of regeneration self-compacting concrete and preparation method thereof

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