CN1200016C - Antiflaming type expansible polystyrene granule and producing method thereof - Google Patents
Antiflaming type expansible polystyrene granule and producing method thereof Download PDFInfo
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- CN1200016C CN1200016C CN 02138594 CN02138594A CN1200016C CN 1200016 C CN1200016 C CN 1200016C CN 02138594 CN02138594 CN 02138594 CN 02138594 A CN02138594 A CN 02138594A CN 1200016 C CN1200016 C CN 1200016C
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- 239000004793 Polystyrene Substances 0.000 title claims abstract description 21
- 229920002223 polystyrene Polymers 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 6
- 239000008187 granular material Substances 0.000 title abstract description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims abstract description 25
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 13
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 12
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 11
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 11
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 9
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000003153 chemical reaction reagent Substances 0.000 claims description 13
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 12
- 235000011010 calcium phosphates Nutrition 0.000 claims description 12
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 12
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 12
- 239000001488 sodium phosphate Substances 0.000 claims description 12
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 12
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 12
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 230000008030 elimination Effects 0.000 claims description 5
- 238000003379 elimination reaction Methods 0.000 claims description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 125000001246 bromo group Chemical class Br* 0.000 claims description 2
- 239000004566 building material Substances 0.000 abstract description 6
- 239000006172 buffering agent Substances 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 229940078499 tricalcium phosphate Drugs 0.000 abstract 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 abstract 1
- 235000019731 tricalcium phosphate Nutrition 0.000 abstract 1
- 229920006248 expandable polystyrene Polymers 0.000 description 7
- 239000003063 flame retardant Substances 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The present invention discloses a fire resisting type expansible polystyrene granules and a producing method thereof. The fire resisting type expansible polystyrene granules can be used for producing building materials and packing materials. The polystyrene granules are formed by the steps that: 90 to 110 portions of styrene, 1.2 to 4.0 portions of tricalcium phosphate, 0.08 to 0.20 portions of buffering agent, 0.04 to 0.10 portions of monostearin, 0.10 to 0.30 portions of tetrasodium pyrophosphate, 0.30 to 0.50 portions of benzoyl peroxide, 0.40 to 0.60 portions of dicumyl peroxide, 5.6 to 7.8 portions of bromine and 6.2 to 8.4 portions of pentane are used as raw materials; the raw materials are mixed, heated, stirred, etc. The fire resisting type expansible polystyrene granules produced by the recipe and the producing method of the present invention have the advantages of high yield and good benefits.
Description
Technical field
The present invention relates to a kind of granules of polystyrene and production method thereof that has flame retardant properties and expandable energy, can be used for producing building materials and wrapping material.
Background technology
Because the flame retardant type Expandable Polystyrene (EPS) has premium properties, is applied to building material industry increasingly extensively.Such as, with the sheet material that the flame retardant type Expandable Polystyrene (EPS) is made, can be used as novel color steel building materials plate, motorway basis place mat and gymnasium building materials etc.And the use density of flame retardant type Expandable Polystyrene (EPS) product aspect building materials is 14～20kg/m
3, correspondingly, be 0.9～1.60mm with regard to the particle diameter that needs its feed particles.
At present, the production of fire-retarding foamable polystyrene grain mostly adopts wilkinite/gelatin as dispersion agent, makes the product produce have only 25～50% to reach effective size of grain, and promptly product percent of pass has only 25～50%, yields poorly, benefit is not high.
Summary of the invention
The object of the present invention is to provide a kind of fire-retarding foamable polystyrene grain.This fire-retarding foamable polystyrene grain, output height, profitable.
Another object of the present invention provides a kind of method of production fire-retarding foamable polystyrene grain.
Above-mentioned purpose of the present invention is realized by following technical solution:
Fire-retarding foamable polystyrene grain of the present invention, make by the raw material of following parts by weight:
90～110 parts of vinylbenzene, 1.2～4.0 parts in calcium phosphate, 0.08～0.20 part of buffer reagent, 0.04～0.10 part of glyceryl monostearate, 0.10～0.30 part of trisodium phosphate, 0.30～0.50 part of benzoyl peroxide, 0.40～0.60 part of dicumyl peroxide, 5.6～7.8 parts of bromines, 6.2～8.4 parts of pentanes.Buffer reagent wherein is sodium hydroxide or calcium hydroxide.
The method of production fire-retarding foamable polystyrene grain may further comprise the steps:
(1) adding weight part in reactor is 100～120 parts de-salted water;
(2) when evenly stirring, adding weight part successively is 1.2～4.0 parts calcium phosphate, 0.08～0.20 part buffer reagent, 0.04～0.10 part glyceryl monostearate and 0.10～0.30 part trisodium phosphate, continues to stir 3～8 minutes;
(3) afterwards, adding weight part successively is 90～110 parts vinylbenzene, 0.30～0.50 part of benzoyl peroxide, 0.40～0.60 part dicumyl peroxide and 5.6～7.8 parts bromine;
(4) afterwards, begin reactor is heated according to 0.8～1.2 ℃/minute heat-up rate; When temperature rose to 85～95 ℃, constant temperature kept 360～420 minutes, made material form the particle with a certain size distribution;
(5) afterwards, adding weight part is 6.2～8.4 parts pentane, and continues reactor is heated; When reacting kettle inner pressure reaches 0.9～1.0Mpa, kept 300～420 minutes; Then, allow it naturally cool to normal temperature;
(6) last, elimination moisture obtains fire-retarding foamable polystyrene grain of the present invention.
Take such scheme, have the following advantages:
Because in the fire-retarding foamable polystyrene grain prescription of the present invention, adopt calcium phosphate, glyceryl monostearate and trisodium phosphate as dispersion agent, carry out compatibility with inorganic salt calcium phosphate and trisodium phosphate and tensio-active agent glyceryl monostearate, make the fire-retarding foamable polystyrene grain qualification rate of producing up to 70～90%, be higher than the product percent of pass that employing wilkinite/gelatin is produced as dispersion agent far away, thereby output and benefit all are greatly improved.
Embodiment
First embodiment:
Choose 90 parts vinylbenzene, 3.8 parts calcium phosphate, 0.15 part buffer reagent, 0.04 part glyceryl monostearate, 0.15 part trisodium phosphate, 0.50 part benzoyl peroxide, 0.40 part dicumyl peroxide, 6.5 parts bromine and 8.3 parts pentane, stand-by.Wherein, each raw material umber of choosing is weight part.
De-salted water with 100 (weight) part adds in the reactor earlier, when evenly stirring, adds calcium phosphate, buffer reagent, glyceryl monostearate and trisodium phosphate successively, continues stirring 5 minutes.
Afterwards, add vinylbenzene, benzoyl peroxide, dicumyl peroxide and bromine more successively.
Afterwards, begin reactor is heated according to 1.2 ℃/minute heat-up rates, when temperature rose to 85 ℃, constant temperature kept 420 minutes under this temperature, made material form the particle with a certain size distribution.
Afterwards, add pentane, and continue reactor is heated.When reacting kettle inner pressure reaches 0.9Mpa, under this pressure, kept 380 minutes.Then, allow it naturally cool to normal temperature.
At last, after filtration, elimination moisture wherein obtains fire-retarding foamable polystyrene grain of the present invention.
Second embodiment:
Choose 100 parts vinylbenzene, 2.0 parts calcium phosphate, 0.20 part buffer reagent, 0.07 part glyceryl monostearate, 0.30 part trisodium phosphate, 0.30 part benzoyl peroxide, 0.50 part dicumyl peroxide, 7.8 parts bromine and 6.2 parts pentane, stand-by.Wherein, each raw material umber of choosing is weight part.
De-salted water with 110 (weight) part adds in the reactor earlier, when evenly stirring, adds calcium phosphate, buffer reagent, glyceryl monostearate and trisodium phosphate successively, continues stirring 8 minutes.
Afterwards, add vinylbenzene, benzoyl peroxide, dicumyl peroxide and bromine more successively.
Afterwards, begin reactor is heated according to 0.8 ℃/minute heat-up rate, when temperature rose to 90 ℃, constant temperature kept 390 minutes under this temperature, made material form the particle with a certain size distribution.
Afterwards, add pentane, and continue reactor is heated.When reacting kettle inner pressure reaches 0.95Mpa, under this pressure, kept 310 minutes.Then, allow it naturally cool to normal temperature.
At last, after filtration, elimination moisture wherein obtains fire-retarding foamable polystyrene grain of the present invention.
The 3rd embodiment:
Choose 110 parts vinylbenzene, 1.2 parts calcium phosphate, 0.08 part buffer reagent, 0.10 part glyceryl monostearate, 0.10 part trisodium phosphate, 0.25 part benzoyl peroxide, 0.60 part dicumyl peroxide, 5.6 parts bromine and 7.5 parts pentane, stand-by.Wherein, each raw material umber of choosing is weight part.
De-salted water with 120 (weight) part adds in the reactor earlier, when evenly stirring, adds calcium phosphate, buffer reagent, glyceryl monostearate and trisodium phosphate successively, continues stirring 3 minutes.
Afterwards, add vinylbenzene, benzoyl peroxide, dicumyl peroxide and bromine more successively.
Afterwards, begin reactor is heated according to 1.0 ℃/minute heat-up rates, when temperature rose to 95 ℃, constant temperature kept 360 minutes under this temperature, made material form the particle with a certain size distribution.
Afterwards, add pentane, and continue reactor is heated.When reacting kettle inner pressure reaches 1.0Mpa, under this pressure, kept 420 minutes.Then, allow it naturally cool to normal temperature.
At last, after filtration, elimination moisture wherein obtains fire-retarding foamable polystyrene grain of the present invention.
Buffer reagent among above-mentioned three embodiment can be a sodium hydroxide, also can be calcium hydroxide.
In the foregoing description, every part of raw material is equal in weight in every part of weight of used de-salted water and the prescription.
Claims (2)
1. fire-retarding foamable polystyrene grain is characterized in that being made by the raw material of following parts by weight:
90～110 parts of vinylbenzene, 1.2～4.0 parts in calcium phosphate, 0.08～0.20 part of buffer reagent, 0.04～0.10 part of glyceryl monostearate, 0.10～0.30 part of trisodium phosphate, 0.30～0.50 part of benzoyl peroxide, 0.40～0.60 part of dicumyl peroxide, 5.6～7.8 parts of bromines, 6.2～8.4 parts of pentanes; Buffer reagent wherein is sodium hydroxide or calcium hydroxide.
2. the method for the described fire-retarding foamable polystyrene grain of production claim 1 is characterized in that may further comprise the steps:
(1) adding weight part in reactor is 100～120 parts de-salted water;
(2) when evenly stirring, adding weight part successively is 1.2～4.0 parts calcium phosphate, 0.08～0.20 part buffer reagent, 0.04～0.10 part glyceryl monostearate and 0.10～0.30 part trisodium phosphate, continues to stir 3～8 minutes;
(3) afterwards, adding weight part successively is 90～110 parts vinylbenzene, 0.30～0.50 part benzoyl peroxide, 0.40～0.60 part dicumyl peroxide and 5.6～7.8 parts bromine;
(4) afterwards, begin reactor is heated according to 0.8～1.2 ℃/minute heat-up rate; When temperature rose to 85～95 ℃, constant temperature kept 360～420 minutes, made material form the particle with a certain size distribution;
(5) afterwards, adding weight part is 6.2～8.4 parts pentane, and continues reactor is heated; When reacting kettle inner pressure reaches 0.9～1.0Mpa, kept 300～420 minutes; Then, allow it naturally cool to normal temperature;
(6) last, elimination moisture obtains fire-retarding foamable polystyrene grain of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02138594 CN1200016C (en) | 2002-11-15 | 2002-11-15 | Antiflaming type expansible polystyrene granule and producing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02138594 CN1200016C (en) | 2002-11-15 | 2002-11-15 | Antiflaming type expansible polystyrene granule and producing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1500815A CN1500815A (en) | 2004-06-02 |
| CN1200016C true CN1200016C (en) | 2005-05-04 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02138594 Expired - Lifetime CN1200016C (en) | 2002-11-15 | 2002-11-15 | Antiflaming type expansible polystyrene granule and producing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1200016C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100443538C (en) * | 2006-07-28 | 2008-12-17 | 许其昌 | Plastic sand |
| CN104610564B (en) * | 2008-01-30 | 2018-05-11 | 积水化成品工业株式会社 | Expandable polystyrene resin beads and its manufacture method and expanded moldings |
| CN101768285B (en) * | 2009-07-16 | 2012-03-21 | 新疆蓝山屯河新材料有限公司 | Expandable polystyrene product and production method thereof |
| CN104059185A (en) * | 2014-06-18 | 2014-09-24 | 安徽圣源橡塑科技有限公司 | Flame-retardant polystyrene composite material and preparation method thereof |
| CN104629204A (en) * | 2015-02-13 | 2015-05-20 | 芜湖市伟华泡塑有限公司 | Preparation method of modified expanded polystyrene |
| CN108164849A (en) * | 2017-12-06 | 2018-06-15 | 黄家月 | A kind of esp foamed damping packing materials and preparation method thereof |
-
2002
- 2002-11-15 CN CN 02138594 patent/CN1200016C/en not_active Expired - Lifetime
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| Publication number | Publication date |
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| CN1500815A (en) | 2004-06-02 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: JIANGSU CHENGDA PETROCHEMICAL INDUSTRY Co.,Ltd. Assignor: Hua Ruozhong Contract fulfillment period: 2009.6.1 to 2014.5.30 Contract record no.: 2009320001067 Denomination of invention: Antiflaming type expansible polystyrene granule and producing method thereof Granted publication date: 20050504 License type: Exclusive license Record date: 20090707 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.6.1 TO 2014.5.30; CHANGE OF CONTRACT Name of requester: JIANGSU CHENGDA PETROCHEMICAL INDUSTRIAL CO., LTD. Effective date: 20090707 |
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Assignee: JIANGSU CHENGDA PETROCHEMICAL INDUSTRY Co.,Ltd. Assignor: Hua Ruozhong Contract record no.: 2009320001067 Date of cancellation: 20120307 |
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Owner name: WUXI XINGDA NEW FOAM PLASTIC MATERIALS CO., LTD. Free format text: FORMER OWNER: HUA RUOZHONG Effective date: 20120515 |
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Free format text: CORRECT: ADDRESS; FROM: 214101 WUXI, JIANGSU PROVINCE TO: 214196 WUXI, JIANGSU PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20120515 Address after: 214196, No. 88 South Harbour Road, Donggang Town, Xishan District, Jiangsu, Wuxi Patentee after: WUXI XINGDA FOAM PLASTIC NEW MATERIALS CO.,LTD. Address before: East Town Xishan District Jiangsu city Wuxi province Xinming road 214101 No. 88 Patentee before: Hua Ruozhong |
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