CN1196522C - Hydrogen-storage alloy reactor - Google Patents

Hydrogen-storage alloy reactor Download PDF

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Publication number
CN1196522C
CN1196522C CNB011348860A CN01134886A CN1196522C CN 1196522 C CN1196522 C CN 1196522C CN B011348860 A CNB011348860 A CN B011348860A CN 01134886 A CN01134886 A CN 01134886A CN 1196522 C CN1196522 C CN 1196522C
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China
Prior art keywords
hydrogen
storage alloy
reactor
sintered
conducting strip
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Expired - Fee Related
Application number
CNB011348860A
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Chinese (zh)
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CN1419958A (en
Inventor
姜成熙
车刚旭
成时庆
洪尚义
洪暎昊
金志原
金寅圭
许庆旭
金映秀
金阳昊
具滋亨
朴柄日
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LG Electronics Tianjin Appliances Co Ltd
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LG Electronics Tianjin Appliances Co Ltd
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Publication date
Application filed by LG Electronics Tianjin Appliances Co Ltd filed Critical LG Electronics Tianjin Appliances Co Ltd
Priority to CNB011348860A priority Critical patent/CN1196522C/en
Publication of CN1419958A publication Critical patent/CN1419958A/en
Application granted granted Critical
Publication of CN1196522C publication Critical patent/CN1196522C/en
Anticipated expiration legal-status Critical
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage

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  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

The present invention relates to a hydrogen-storage alloy reactor which is composed of a container and a plurality of sintered forming bodies, wherein the sintered forming bodies are arranged in the container and are formed by sintering hydrogen-storage alloy powder, a communicating hole is arranged in the center of each sintered forming body, and the communicating holes form the hydrogen gas passage of the reactor; a heat conducting piece is arranged between every two of the sintered forming bodies, a communicating hole corresponding to the communicating hole of each sintered forming body is arranged in the center of each heat conducting piece, and porous filter screens are arranged in the communicating holes. The present invention has the advantages of favorable assembling performance, high assembling efficiency and even density of the alloy powder stored in the reactor so as to cause heat productivity to be even and enhance heat efficiency; the shape variation of the heat conducting pieces can enhance the heat conducting performance and the assembling performance of the reactor.

Description

Hydrogen-storage alloy reactor
One, technical field:
The present invention relates to a kind of hydrogen-storage alloy reactor, specifically, relate to a kind of hydrogen-storage alloy reactor the powder sintered moulding of hydrogen-storage alloy.
Two, background technology:
Generally speaking, hydrogen be under high pressure conditions, be stored in high-pressure bottle by or be cooled to extremely low temperature and store with liquid condition.But because the density of hydrogen is very little, thus can be stored in the high-pressure bottle amounts of hydrogen seldom, thereby make the container volume of storage of hydrogen big, weight is also big, the inconvenience that causes transportation and use.Recently, for the storage problem that solves hydrogen has adopted hydrogen-storage alloy, promptly utilize hydrogen-storage alloy to absorb hydrogen and stored.From the weight ratio angle, the capacity of hydrogen-storage alloy storage of hydrogen is still lower, but from volume ratio than compression hydrogen and liquefaction hydrogen height, so by contrast, hydrogen-storage alloy can store more hydrogen.
Hydrogen-storage alloy is a kind of metallic compound that is formed by very strong element of hydrogen affinity and the element a little less than the hydrogen affinity, and as Mg-Ni alloy, Mg-Cu alloy, Ti-Ni alloy and R-Co alloy etc., wherein R represents rare earth metal.Like this, when hydrogen-storage alloy absorbs hydrogen, exothermic reaction will take place; And during release hydrogen, the endothermic reaction will take place from hydrogen-storage alloy.Therefore, utilize hydrogen-storage alloy reactor can constitute heat exchanger.
Fig. 1 and Fig. 2 are the structural representations of existing hydrogen-storage alloy heat exchanger and hydrogen-storage alloy reactor, and in general, the hydrogen-storage alloy heat exchanger all is that two or more assemblings are used, and has only represented one of them hydrogen-storage alloy heat exchanger among Fig. 1.As shown in Figure 1, hydrogen-storage alloy heat exchanger 1 is made of distributing pipe 10, reactor 20 and external heat-exchanging pin 30 three parts.Distributing pipe 10 is provided with a plurality of and hydrogen pipeline and reaction along the 20 hydrogen pipes that are communicated with; The outside of reactor 20 is provided with a plurality of heat exchange pins 30, so that carry out heat exchange easilier between the outside heat conduction medium such as reactor and air.When hydrogen is sent into reactor 20 by distributing pipe 10, be filled in hydrogen-storage alloy and hydrogen generation exothermic reaction in the reactor 20; And when hydrogen when reactor 20 is extracted out, the hydrogen-storage alloy and the hydrogen generation endothermic reaction.
As shown in Figure 2, reactor 20 is made of container 21, conducting strip 24 and screen pack 25.Conducting strip 24 is installed in container 21 inside, and at regular intervals each other; Between each conducting strip 24, screen pack 25 is used to filter the hydrogen-storage alloy powder in container 21 in hydrogen-storage alloy 23 fillings.When making reactor 20, at first in container 21, load the hydrogen-storage alloy powder of certain altitude, and then conducting strip 24 is installed, carry out so repeatedly just producing reactor 20.This is, the reactor of Zhi Zuoing like this, and the differing heights that the density of Zhuan Tian hydrogen-storage alloy powder will be in container and different wherein, therefore, the heat that hydrogen-storage alloy is produced during with hydrogen reaction also will be with the different deviations that produce of density.In order to make the hydrogen-storage alloy powder density in the container even, should rock container behind a certain amount of hydrogen-storage alloy powder of packing into, and should be whenever to adorn a hydrogen-storage alloy powder and just rock once or periodically and rock.
In a word, the assembly production of existing hydrogen-storage alloy reactor is cumbersome, and efficient is lower; And the deviation of the caloric value of bringing owing to the difference of hydrogen-storage alloy powder density will make the thermal efficiency of whole heat exchanger reduce.
Three, summary of the invention:
Purpose of the present invention promptly is the improvement suitable in addition to the structure of hydrogen-storage alloy reactor, so that its assembling is more convenient.
To achieve these goals, a kind of hydrogen-storage alloy reactor of the present invention, it is characterized in that constituting by container and a plurality of sintered moulded bodies that are installed in the container, sintered moulded body forms by hydrogen-storage alloy is powder sintered, its central authorities have intercommunicating pore, be provided with conducting strip between the sintered moulded body, the central authorities of conducting strip have and the corresponding intercommunicating pore of sintered moulded body central authorities' intercommunicating pore.
Aforesaid hydrogen-storage alloy reactor, wherein intercommunicating pore is circle or polygonal.
Aforesaid hydrogen-storage alloy reactor, wherein the conducting strip inboard is formed with outstanding position and works in coordination with sintered moulded body.
Aforesaid hydrogen-storage alloy reactor, wherein the inside and outside both sides of conducting strip all are formed with outstanding position and work in coordination with sintered moulded body.
Aforesaid hydrogen-storage alloy reactor wherein is provided with the porous filtering net in the intercommunicating pore.
The present invention has good assembly performance, the efficiency of assembling height; Hydrogen-storage alloy powder density in the reactor is even, caloric value is even, thermal efficiency height.After between each sintered moulded body conducting strip being installed, can further improving the assembly performance of reactor and improve its heat conductivility.
Be described in further detail below in conjunction with the technical characterictic of specific embodiment hydrogen-storage alloy reactor of the present invention.
Four, description of drawings:
Fig. 1 is the side view of existing hydrogen-storage alloy heat exchanger.
Fig. 2 is the sectional view of existing hydrogen-storage alloy reactor.
Fig. 3 is the decomposition chart of hydrogen-storage alloy reactor of the present invention.
Fig. 4 is that second of hydrogen-storage alloy sintered moulded body and conducting strip implemented illustration.
Fig. 5 is that the 3rd of hydrogen-storage alloy sintered moulded body and conducting strip implemented illustration.
Five, the specific embodiment:
With reference to shown in Figure 3, hydrogen-storage alloy reactor 50 of the present invention mainly is made of container 51 and a plurality of sintered moulded body 53 two large divisions, sintered moulded body 53 be by the powder sintered moulding of hydrogen-storage alloy and be installed in the container 51.For ease of being installed in the container 51, sintered moulded body 53 should be made unified specification, is provided with conducting strip 54 between each sintered moulded body 53, to improve the heat conductivility of reactor.The center of sintered moulded body 53 and conducting strip 54 is provided with intercommunicating pore, so that form the hydrogen passage of reactor.If the relevant position at sintered moulded body 53 and conducting strip 54 forms a plurality of intercommunicating pores, then can in reactor, form a plurality of hydrogen passages.Intercommunicating pore on sintered moulded body 53 and the conducting strip 54 can be circular hole, also can be polygonal holes.
Fig. 4 is second embodiment of sintered moulded body and conducting strip 54, and the inner peripheral of conducting strip 54a is formed with outstanding position and works in coordination with sintered moulded body 53, can improve the assembly performance of reactor.
Fig. 5 is the 3rd embodiment of sintered moulded body and conducting strip, the inside and outside both sides of conducting strip 54b all form outstanding position and work in coordination with sintered moulded body 53, except that the assembly performance that can further improve reactor, also can enlarge the contact area between conducting strip and the container, further improve its heat conductivility.
In addition, porous filtering net 52 is installed in the intercommunicating pore of above-mentioned sintered moulded body 53 and conducting strip 54, hydrogen is filtered; As hydrogen inlet the porous filtering net is installed, hydrogen is filtered once more at container 51.
In sum as can be known, the present invention not only can improve the assembly performance and the efficiency of assembling of reactor with the powder sintered one-tenth sintered moulded body of hydrogen-storage alloy, and can make the interior hydrogen-storage alloy powder density of reactor more even, thereby makes the caloric value of reactor more even; The shape that changes conducting strip then can improve the heat conductivility of reactor.

Claims (5)

1, a kind of hydrogen-storage alloy reactor, it is characterized in that constituting by container and a plurality of sintered moulded bodies that are installed in the container, sintered moulded body forms by hydrogen-storage alloy is powder sintered, its central authorities have intercommunicating pore, be provided with conducting strip between the sintered moulded body, the central authorities of conducting strip have and the corresponding intercommunicating pore of sintered moulded body central authorities' intercommunicating pore.
2, hydrogen-storage alloy reactor according to claim 1 is characterized in that described intercommunicating pore is circle or polygonal.
3, hydrogen-storage alloy reactor according to claim 1 is characterized in that described conducting strip inboard is formed with outstanding position and works in coordination with sintered moulded body.
4, hydrogen-storage alloy reactor according to claim 1 is characterized in that the inside and outside both sides of described conducting strip all are formed with outstanding position and work in coordination with sintered moulded body.
5, hydrogen-storage alloy reactor according to claim 1 is characterized in that being provided with in the described intercommunicating pore porous filtering net.
CNB011348860A 2001-11-19 2001-11-19 Hydrogen-storage alloy reactor Expired - Fee Related CN1196522C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB011348860A CN1196522C (en) 2001-11-19 2001-11-19 Hydrogen-storage alloy reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB011348860A CN1196522C (en) 2001-11-19 2001-11-19 Hydrogen-storage alloy reactor

Publications (2)

Publication Number Publication Date
CN1419958A CN1419958A (en) 2003-05-28
CN1196522C true CN1196522C (en) 2005-04-13

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