CN1192809C - Pawpaw liquor capable of emitting light at night - Google Patents
Pawpaw liquor capable of emitting light at night Download PDFInfo
- Publication number
- CN1192809C CN1192809C CNB011104775A CN01110477A CN1192809C CN 1192809 C CN1192809 C CN 1192809C CN B011104775 A CNB011104775 A CN B011104775A CN 01110477 A CN01110477 A CN 01110477A CN 1192809 C CN1192809 C CN 1192809C
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- China
- Prior art keywords
- night vision
- bubble liquid
- liquid
- luminous bubble
- luminous
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- Display Devices Of Pinball Game Machines (AREA)
Abstract
The present invention relates to bubble liquid capable of emitting light at night, which comprises 42 to 89% of water, 8 to 25% of interfacial active agent, 1 to 3% of glycerol, 1 to 30% of fluorescer and 0 to 1.0% of anchoring agent. The present invention has bubble liquid and bubbles blown by the bubble liquid. The bubble liquid sends out fluorescence in dark environments under the light of light sources, such as invisible ultraviolet light, or infrared light and the like, which increases the application range and the interest of the bubble liquid.
Description
Technical field
The present invention relates to the bubble liquid of bubble blowing toy, particularly provide a kind of night vision luminous bubble liquid, its bubble liquid itself and the bubble of producing by boasting, in than dark surrounds, under the irradiation of light sources such as sightless ultraviolet light or infrared light, can send blue visible fluorescence to the purple radiance, the range of application that improves the liquid that blows bubbles is with interesting.The colorant that also further can add special color, make the luminous bubble liquid of night vision with particular color, when making the bubble liquid splendid attire in transparent vessel, in than darkness environment, under the irradiation of light sources such as sightless ultraviolet light or infrared light, can send the fluorescence that has particular color, to improve the fluorescence significant degree, for example with its splendid attire in the container of the luminous bubble liquid of the night vision with particular color, wearing can show more bright-coloured, the more tangible coloured fluorescent effect of color in the front; It is blow molded into bubble, also can present the fluorescent effect with particular color, increases the changeable voltinism of bubble color and the visual experience of multicolor fluorescence.
Background technology
As everyone knows, traditional bubble liquid only for blowing bubble down in daylight or other general light source irradiation, does not possess night vision function.In order to increase applicable space of bubble blowing toy and scope, for example be used in noctilucence dancing party, stage, concert or other is the place of light source irradiation with the ultraviolet light, a kind of bubble liquid with night vision function need be provided.
Summary of the invention
The object of the present invention is to provide the luminous bubble liquid of a kind of night vision, under light sources such as ultraviolet light or infrared light, the bubble that blowing is come out, can absorb ultraviolet ray or infrared ray in the light source, send fluorescent effect, function with particular color fluorescence, variation that more can increasing colour reaches night vision function and the purpose of better interest with the change sense.
The object of the present invention is achieved like this: the bubble liquid that a kind of night vision is luminous is characterized in that: its main component includes: water 42-89%, interfacial agent 8-25%, glycerine 1-3%, fluorescer 1-30% and tackifier 0-1.0%; This fluorescer is the fluorescer brightening agent.This fluorescer is for containing phenyl ring or heterocycle, and has the compound of conjugated double bond.
This water is through water treatment, the qualified water of degerming.The frothed liquid that this interfacial agent is used for general manufacturing bubble, main component is a liquid soap.
The main component of preferred embodiment includes: water 67-89%, interfacial agent 8-25%, glycerine 2%, fluorescent whitening agent 1-6%.This fluorescer brightening agent is two amido stilbene disulfonic acid derivatives.Also comprise and add tackifier 0.2-0.8%.
The main component of preferred embodiment includes: water 50-78%, interfacial agent 12-26%, glycerine 2%, fluorescer 8-22%.Also comprise and add tackifier 0.2-0.8%.This fluorescer comprises the liquid that contains tetrabromofluorescein, fluorescein or merbromin material.
Preferred embodiment comprises the colorant that contains particular color, makes the luminous bubble liquid of the night vision with particular color.This proportioning with luminous bubble liquid of night vision of particular color is: the luminous bubble liquid of night vision is that the colorant of 80-95% and particular color is 5-20%.The colorant of this particular color is liquid dyes or powdered pigment.This luminous bubble liquid of night vision with particular color is for directly using the fluorescer that contains colorant.
The proportioning of the luminous bubble liquid of night vision with particular color of preferred embodiment is: water 42-76%, interfacial agent 12-26%, glycerine 2% and contain the fluorescer 10-30% of colorant.This luminous bubble liquid of night vision with particular color is that fluorescer is deployed in advance, makes the colorant fluorescent liquid agent that contains setpoint color.Also comprise the tackifier that add 0.2-0.8%.
Major advantage of the present invention is: the effect with night vision function and better interest and change sense.
The present invention is further described below in conjunction with preferred embodiment.
The specific embodiment
Embodiment 1
The bubble liquid that night vision provided by the present invention is luminous, its main component includes: water 42-89%, interfacial agent 8-25%, glycerine 1-3%, fluorescer 1-30% and tackifier 0-1.0%.
Above-mentioned water is through water treatment, the qualified water of degerming.
The frothed liquid that above-mentioned interfacial agent is used for general manufacturing bubble, main component is a liquid soap.
Above-mentioned glycerine has humidification, helps the interfacial agent dispersion of nano-particles, and has freeze proof effect, can increase the temperature range of the use of bubble liquid.
Above-mentioned fluorescer is two amido stilbene disulfonic acid derivatives (Diamino-StilbeneDisulphonic Acid Derivatives).Its outward appearance is light brown liquid, and ionic genus anionic property, proportion are 1.1-1.25 in the time of 20 ℃, is 7-9 during 20 ℃ of pH values, and freezing point is about-4 ℃, and boiling point is about 103 ℃, and has good stability, anergy, no incendivity, non-explosive.The fluorescer of its low content by dilution such as water and interfacial agent after, avirulence and do not have skin irritation.
Mentioned component is fully mixed the luminous bubble liquid of made night vision, it is transparent or semitransparent liquid in appearance, in than dark surrounds, under the irradiation of light sources such as sightless ultraviolet light or infrared light, can send blue visible fluorescence to the purple radiance.
Embodiment 2
The bubble liquid that the night vision of present embodiment 2 is luminous, its main component includes: water 67-89%, interfacial agent 8-25%, glycerine 2%, fluorescent whitening agent 1-6%.The effect of its each composition is with embodiment 1, so do not repeat.
Can also add tackifier 0.2-0.8%, its tackifier increase the viscosity of above-mentioned bubble liquid, the success rate when improving the blowing bubble.
When blowing bubble with the luminous bubble liquid of this night vision, its bubble is in than dark surrounds, under the irradiation of light sources such as sightless ultraviolet light or infrared light, can send blue fluorescence to the purple radiance, and the bubble of blowing has bigger surface tension, the fluorescence that is sent can concentrate on the surface, outer ring of bubble, has the bright effect of the preferable ring of light.
Embodiment 3
In the present embodiment 3, the main component of the bubble liquid that night vision is luminous includes:
Water 50-78%, interfacial agent 12-26%, glycerine 2%, fluorescer 8-22%.
Above-mentioned fluorescer is the commercially available liquid that does not add colorant, is the true qualities state, contains fluorescigenic material.Be subjected to the optical excitation of sightless ultraviolet light or infrared light when its fluorescent material after, its electronics promptly is transformed into single lower state from single upper state, and launches non-polarized light simultaneously.This kind fluorescer is to contain phenyl ring or heterocycle mostly, and has the compound of conjugated double bond, for example contains the liquid of materials such as tetrabromofluorescein, fluorescein, merbromin.
Mentioned component is fully mixed the luminous bubble liquid of making of night vision, and it is opaque emulsifying liquid shape in appearance, in than dark surrounds, under the irradiation of light sources such as sightless ultraviolet light or infrared light, can send blue visible fluorescence to the purple radiance.
Wherein, also can add the tackifier of 0.2-0.8%, so that the viscosity of above-mentioned bubble liquid increases the success rate when improving the blowing bubble.
When blowing bubble with the luminous bubble liquid of this night vision, its bubble under the irradiation of light sources such as sightless ultraviolet light or infrared light, can send blue fluorescence to the purple radiance in than dark surrounds;
Because the bubble surface tension that the bubble liquid of two kinds of compositions of the foregoing description 2 and 3 is made varies in size, so the bubble of the bubble liquid of present embodiment blowing, the fluorescence that is sent can be evenly distributed in the body of bubble, presents the effect of the whole vaporific fluorescence of ball; The surface tension of blowing out with the luminous bubble liquid of the night vision of embodiment 2 is big, slightly different than the bubble of the bright effect of the tool outer ring ring of light.
Owing to the luminous bubble liquid of night vision of the foregoing description 2, only use the fluorescent whitening agent of 1%-6% low content, its manufacturing cost is lower.Yet, on the bubble of making, show: the bubble of the bubble liquid blowing that the night vision of embodiment 2 is luminous according to result of the test, its fluorescence approaches the performance of the cast ring of light, and it is vaporific that the bubble of present embodiment, its fluorescence then are whole ball, slightly the outer ring ring of light respectively has different visual effects.
In addition, in the luminous bubble liquid of the night vision of present embodiment, add colorant, and splendid attire is when going in the transparent vessel, its fluorescence reaction is more obvious and bright-coloured, so though the composition of present embodiment uses the higher fluorescer of content ratio because of needs, and it is higher to cause manufacturing cost, but because of its effect difference, has industrial utilization equally.
Embodiment 4
In the present embodiment 4, be in the luminous bubble liquid of night vision that two kinds of compositions of the foregoing description 2,3 are made, add an amount of colorant again, manufacture bubble liquid with particular color, to increase its color change and vividness, generally the luminous bubble liquid of its night vision is that the colorant of 80-95% and particular color is that 5-20% is mixed and made into the luminous bubble liquid of night vision with particular color.
Colorant commonly used is liquid dyes or powdered pigment.
Above-mentioned glycerine with humidification, help its particle to disperse, be mixed and made into the luminous bubble liquid of night vision with particular color, its bubble liquid and blown bubble, in than dark surrounds, with the irradiation of light sources such as sightless ultraviolet light or infrared light down, can send the fluorescence of particular color, to increase the color change effect with interesting.
Embodiment 5
Another kind is made the method for the luminous bubble liquid of night vision with particular color, be directly to use the fluorescer that contains colorant, the main component of the bubble liquid that this kind night vision is luminous is as follows: water 42-76%, interfacial agent 12-26%, glycerine 2% and contain colorant fluorescer 10-30%.
Above-mentioned water is through water treatment, the qualified water of degerming.
The frothed liquid that above-mentioned interfacial agent is used for general manufacturing bubble, main component is a liquid soap.
Above-mentioned glycerine has humidification, helps the interfacial agent dispersion of nano-particles and has freeze proof effect, can increase the temperature range that bubble liquid uses.
Above-mentioned fluorescer is in advance deployed, includes the fluorescent liquid agent of the colorant of setpoint color.It uses effect to have identical effect with the luminous bubble liquid of the night vision with particular color of the foregoing description 4 basically.
In addition, in the present embodiment 5, can add the tackifier of 0.2-0.8% equally, to improve the success rate that bubble is made.
In a word, bubble liquid with the luminous bubble function of night vision of the present invention, not only bubble may be selected to be the effect that presents the whole vaporific fluorescence of ball, or presents the bubble that has the bright effect of the outer ring ring of light, further can give the variation of color, fully possess novelty with creative.
Claims (19)
1, the luminous bubble liquid of a kind of night vision, it is characterized in that: its main component includes: water 42-89%, interfacial agent 8-25%, glycerine 1-3%, fluorescer 1-30% and tackifier 0-1.0%; This fluorescer is for containing phenyl ring or heterocycle, and has the compound of conjugated double bond.
2, the luminous bubble liquid of night vision as claimed in claim 1 is characterized in that: this water is through water treatment, the qualified water of degerming.
3, the luminous bubble liquid of night vision as claimed in claim 1 is characterized in that: the frothed liquid that this interfacial agent is used for general manufacturing bubble, main component is a liquid soap.
4, the luminous bubble liquid of night vision as claimed in claim 1 is characterized in that: this fluorescer is the fluorescer brightening agent.
5, the luminous bubble liquid of night vision as claimed in claim 1, it is characterized in that: it comprises the colorant that contains particular color, makes the luminous bubble liquid of the night vision with particular color.
6, the luminous bubble liquid of night vision as claimed in claim 1, it is characterized in that: its main component includes: water 67-89%, interfacial agent 8-25%, glycerine 2%, fluorescent whitening agent 1-6%.
7, the luminous bubble liquid of night vision as claimed in claim 6 is characterized in that: this fluorescer brightening agent is two amido stilbene disulfonic acid derivatives.
8, the luminous bubble liquid of night vision as claimed in claim 6 is characterized in that: it also comprises adding tackifier 0.2-0.8%.
9, the luminous bubble liquid of night vision as claimed in claim 1, it is characterized in that: its main component includes: water 50-78%, interfacial agent 12-26%, glycerine 2%, fluorescer 8-22%.
10, the luminous bubble liquid of night vision as claimed in claim 9 is characterized in that: it also comprises adding tackifier 0.2-0.8%.
11, the luminous bubble liquid of night vision as claimed in claim 9 is characterized in that: this fluorescer comprises the liquid that contains tetrabromofluorescein, fluorescein or merbromin material.
12, the luminous bubble liquid of night vision as claimed in claim 6, it is characterized in that: it comprises the colorant that contains particular color, makes the luminous bubble liquid of the night vision with particular color.
13, the luminous bubble liquid of night vision as claimed in claim 9, it is characterized in that: it comprises the colorant that contains particular color, makes the luminous bubble liquid of the night vision with particular color.
14, the luminous bubble liquid of night vision as claimed in claim 13 is characterized in that: this proportioning with luminous bubble liquid of night vision of particular color is: the luminous bubble liquid of night vision is that the colorant of 80-95% and particular color is 5-20%.
15, the luminous bubble liquid of night vision as claimed in claim 13 is characterized in that: the colorant of this particular color is liquid dyes or powdered pigment.
16, the luminous bubble liquid of night vision as claimed in claim 13 is characterized in that: this luminous bubble liquid of night vision with particular color is for directly using the fluorescer that contains colorant.
17, the luminous bubble liquid of night vision as claimed in claim 16 is characterized in that: this proportioning with luminous bubble liquid of night vision of particular color is: water 42-76%, interfacial agent 12-26%, glycerine 2% and contain the fluorescer 10-30% of colorant.
18, the luminous bubble liquid of night vision as claimed in claim 13 is characterized in that: this luminous bubble liquid of night vision with particular color is that fluorescer is deployed in advance, makes the colorant fluorescent liquid agent that contains setpoint color.
19, the luminous bubble liquid of night vision as claimed in claim 13 is characterized in that: also comprise the tackifier that add 0.2-0.8%.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011104775A CN1192809C (en) | 2001-04-12 | 2001-04-12 | Pawpaw liquor capable of emitting light at night |
| HK02109432.5A HK1047901B (en) | 2001-04-12 | 2002-12-31 | Liquid bubble solution for producing luminous bubbles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011104775A CN1192809C (en) | 2001-04-12 | 2001-04-12 | Pawpaw liquor capable of emitting light at night |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1380124A CN1380124A (en) | 2002-11-20 |
| CN1192809C true CN1192809C (en) | 2005-03-16 |
Family
ID=4658618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011104775A Expired - Fee Related CN1192809C (en) | 2001-04-12 | 2001-04-12 | Pawpaw liquor capable of emitting light at night |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN1192809C (en) |
| HK (1) | HK1047901B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102527064A (en) * | 2010-12-15 | 2012-07-04 | 郑得耀 | Colored bubble mixture |
| CN104353251B (en) * | 2014-11-07 | 2016-06-01 | 山西大学 | A kind of carbon nano fluorescent bubble liquid |
| CN106178547A (en) * | 2016-07-21 | 2016-12-07 | 鄢海军 | A kind of bubble-water solution of the nontoxic non-stimulated health of child |
-
2001
- 2001-04-12 CN CNB011104775A patent/CN1192809C/en not_active Expired - Fee Related
-
2002
- 2002-12-31 HK HK02109432.5A patent/HK1047901B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| HK1047901B (en) | 2005-07-22 |
| HK1047901A1 (en) | 2003-03-14 |
| CN1380124A (en) | 2002-11-20 |
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