CN1186598A - Plant protecting adjuvant composition - Google Patents
Plant protecting adjuvant composition Download PDFInfo
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- CN1186598A CN1186598A CN96123986A CN96123986A CN1186598A CN 1186598 A CN1186598 A CN 1186598A CN 96123986 A CN96123986 A CN 96123986A CN 96123986 A CN96123986 A CN 96123986A CN 1186598 A CN1186598 A CN 1186598A
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Abstract
An adjuvant composition including at least one nonionic surfactant and at least one corrosion inhibitor. A method of improving the efficacy of the pesticide formulation by adding the adjuvant composition is also included.
Description
The assistant composition that the present invention relates to use in the pesticidal preparations particularly comprises the assistant composition of at least a corrosion inhibitor and at least a non-ionic surface active agent.
Agricultural chemicals is to be used to alleviate, control or to eliminate material to people or economic prejudicial plant or animal.Agricultural chemicals comprises algicide, disleave desiccant, weed killer herbicide, plant growth regulator, and they are used for regulating the population that competes or parasitize the noxious plant on crop or the observation of plant with crop or ornamental plants.Other agricultural chemicals comprises attractant, bactericide, insecticide, miticide (miticides), miticide (acaricides), invertebrate poison, nematocide, repellant and rodenticide, they are mainly used to reduce parasitism and disease propagation in the domestic animal, the loss of crop, plant, the breaking-up of processed food, textile and wood products and parasitism in the fluid and disease propagation.These destroy normally because the feed behavior of pest.Cognitive " pest " comprises for example bird, mouse, rabbit, mouse, insect, mite, lice, eelworm, slug and snail.
There is the compound more than 800 kinds to be used as agricultural chemicals.Agricultural chemicals can be made up of the inorganic matter that contains sulphur, lead, arsenic or copper, and above-mentioned institute's organic/inorganic substance all has the character of killing livestock.In addition, agricultural chemicals can contain the organic matter that is extracted by plant such as Dalmatian chrysanthemum, tobacco and rotenone.The quantity of organic biocide is in continuous increase.Widely different in the generation of the toxicity of these organic biocides, specificity, persistence and harmful derivative.
Have found that the effectiveness of many agricultural chemicals can be improved by adding auxiliary agent.For example, auxiliary agent can be used in the weed killer herbicide (plant protection composition) processing and/or the stable adminicle as herbicide formulations or spray solution.For chemistry and/or the physical characteristic that improves or improve some agricultural chemicals, can add auxiliary agent and form the spraying mixture.Because spray application is vital to pesticidal properties, therefore add problem such as chemical stability, incompatibility, solvability, suspension, foaming, drift evaporation, volatility, poisoning, surface tension, drop size and the cover degree that auxiliary agent is used with minimizing.Have found that that auxiliary agent can improve is wetting, diffusion, adhesion, emulsification and dispersive property.
One of the main component that is used for pesticide combination is a non-ionic surface active agent.Ionic surfactant pack contains hydrophilic and the oleophylic segment.But non-ionic surface active agent perhaps can not be used alone as complete auxiliary agent.For example, non-ionic surface active agent perhaps can not mix with pesticidal preparations.Therefore need be with non-ionic surface active agent and the combination of other composition, to produce effective auxiliary agent.And, in the life-span for the storage period that prolongs auxiliary agent and pesticidal preparations and pump and spraying apparatus parts, demand is arranged always.
The present invention relates to comprise the assistant composition of at least a non-ionic surface active agent and at least a corrosion inhibitor.
In preferred embodiments, assistant composition comprises following component: about 2% to about 98% at least a non-ionic surface active agent that is selected from oxyalkylated aliphatic alcohol, oxyalkylated polyalcohol, alkylaryl alkoxide, oxyalkylated amine, oxyalkylated acid amides, oxyalkylated fatty acid and block copolymer, about 0.1% to about 5% at least a alkali metal benzoate, alkali metal cinnamate, alkali metal polyphosphates and the alkali metal phenyl carboxylate of being selected from, about 0% to about 30% at least a carbon chain lengths is C
1-Yue C
8Between fatty alcohol or the alcohol of aliphatic glycol and 0% to about 30% at least a fatty acid that is selected from linoleic acid, rosin acid, linolenic acid and oleic acid.The surplus of assistant composition comprises water.
Surprising is that assistant composition of the present invention increases the effectiveness of its a little agricultural chemicals.In addition, this assistant composition that comprises corrosion inhibitor helps to protect pump and spraying apparatus.And the corrosion inhibitor component of assistant composition helps to prolong storage period.
It should be noted that unless otherwise the percentage that provides is meant weight percent in this specification and the appended claims.
With reference to following detailed description of the preferred embodiments, will be better understood above-mentioned and other advantage and characteristics of the present invention.
The present invention relates to comprise the assistant composition of at least a non-ionic surface active agent and at least a corrosion inhibitor.
Being suitable for ionic surfactant pack of the present invention draws together, but be not limited to pure alkoxide, polyalcohol alkoxide, alkylaryl alkoxide, oxyalkylated amine, oxyalkylated acid amides, oxyalkylated fatty acid, block copolymer and composition thereof.Generally speaking, these non-ionic surface active agents can be in the presence of base catalyst such as alkali metal, alkaline hydrated oxide, alkaline alkoxide and amine, and the carbochain that replaces by the oxygen alkoxide prepares.
The pure alkoxide of usefulness and polyalcohol alkoxide contain aliphatic hydrocarbon chain and oxyalkylene chain in the present invention.Hydrocarbon chain can be derived by aliphatic alcohol or aliphatic polyol.Generally including those as the example of the fatty alcohol of non-ionic surface active agent and polyalcohol alkoxide contains carbochain and is about C
6To about C
18And average out to about 1 aliphatic alcohol chain to about 20 moles alkylene oxide.Pure alkoxide and polyalcohol alkoxide as non-ionic surface active agent preferably contain by mainly being ethylene oxide unit(s) (so-called alcohol ethoxylate), the oxyalkylene chain that expoxy propane unit's (so-called pure propoxylate) or its combination (alcohol of so-called propoxylation and ethoxylation) are formed.
Alcohol alkoxylates prepares by carrying out the oxygen alkoxy fatty alcohols with oxyalkylene normally in the presence of base catalyst such as sodium, potassium hydroxide, sodium hydroxide, sodium methoxide or caustic alcohol.The polyalcohol alcoxylates normally in the presence of catalyzer such as sodium hydroxide or sodium methoxide, prepares by oxygen alkoxylated polyol hydroxy aliphatic ester such as aliphatic diol ester.These alcoxylates can be ethoxylate, propoxylate or its combination.Comprise C as the polyalcohol b-oxide of non-ionic surface active agent or aliphatic alcohol ethyl oxide and fatty alcohol propoxide or polyalcohol propoxide
6-C
18Fatty alcohol or polyalcohol, every mole fatty alcohol or polyalcohol have about 1 to about 20 moles oxirane (EO) or expoxy propane (PO).The distribution of oxyethylation and/or propoxylation can be suitable wide.Common aliphatic alcohol ethyl oxide is at " emulsifier and washing agent " (Emulsifiers﹠amp of McCutcheon; Deterqents) in 1992 yearbooks, be listed under the chemical classification hurdle " Ethoxylated Alcohols ".In this this yearbook of McCutcheon, the alcohol of the common pure propoxylate and the pure and mild ethoxylation of third oxidation is listed in chemical classification hurdle " Propoxylated﹠amp; Ethoxylated Fatty Acids, Alcohol orAlkyl Phenols " under.
Alkylaryl alkoxide used in this invention contains aromatic hydrocarbon and oxyalkylene chain.Aromatic hydrocarbon can be derived by for example alkyl phenol or other alkyl aryl compound.The preferred C of oxyalkylene chain chain length of compound
2To about C
15Alkaryl alkoxide as non-ionic surface active agent preferably contains the oxyalkylene chain that has by mainly being ethylene oxide unit(s), expoxy propane unit or combinations thereof.
The alkaryl alkoxide normally in the presence of base catalyst such as sodium, potassium hydroxide, sodium hydroxide, sodium acetate, potash or sodium methoxide, prepares by oxygen alkoxylate aromatic hydrocarbons.The example that is used as the alkaryl alkoxide of non-ionic surface active agent comprises that every moles of phenol or other aryl have 1 phenol or other aryl compound to about 20 moles of ethylene oxide (EO) or expoxy propane (PO) unit.The distribution of ethoxyquin effect and/or propoxylation can be suitable wide.Common alkaryl alkoxide comprises nonyl phenol b-oxide and octyl phenol b-oxide.Other instantiation is in " emulsifier and washing agent " 1992 yearbooks of McCutcheon, be listed among chemical classification hurdle " Ethoxylated Alkyl Phenols " and " Propoxylated and Ethoxylated Fatty Acids, the Glycols or AlkylPhendols ".
Oxyalkylated amine used in this invention contains oxyalkylene chain and fatty amine.The oxyalkylene chain of compound preferably has chain length C
2To about C
18Oxyalkylated amine as non-ionic surface active agent preferably contains by the oxyalkylene chain that mainly is ethylene oxide unit(s), expoxy propane unit or combinations thereof.
Oxyalkylated amine prepares as uncle or secondary alkylamine by oxygen alkoxylated alphatic amine normally in the presence of base catalyst such as potassium hydroxide, sodium hydroxide or sodium methoxide.The example that is used as the oxyalkylated amine of non-ionic surface active agent comprises that every mole amine has about 1 aliphatic amine to about 20 moles of ethylene oxide (EO) or expoxy propane (PO) unit.What distribution can be suitable between oxyethylation and/or propoxylation is wide.Common oxyalkylated amine is listed in the chemical classification hurdle " Ethoxylated Amines and/or Amides " in " emulsifier and washing agent " 1992 yearbooks of McCutcheon.
Be used for alkoxylate acid amides of the present invention and contain oxyalkylene chain and aliphatic acid amides.The oxyalkylene chain of compound preferably has C
2To about C
18Chain length.Oxyalkylated acid amides as non-ionic surface active agent preferably contains by the oxyalkylene chain that mainly is ethylene oxide unit(s), expoxy propane unit or combinations thereof.
Oxyalkylated acid amides is normally in the presence of base catalyst such as sodium hydroxide or triethylamine, and the acid amides by oxygen alkoxylate acid amides or list or dialkoxyization prepares.The example that is used as the oxyalkylated acid amides of non-ionic surface active agent comprises that every mole of acid amides has the about 1 aliphatic acid amides to about 20 moles of ethylene oxide (EO) or expoxy propane (PO) unit.Common alkoxyl acid amides is listed in the chemical classification hurdle " Ethoxylated Aminesand/or Amides " in " emulsifier and washing agent " 1992 yearbooks of McCutcheon.
Fatty acid alkoxide used in this invention contains fatty acid and oxyalkylene chain.Fatty acid component can have about C
6To about C
20Chain length.The oxyalkylene chain of this compound preferably has C
2To about C
18Chain length.Preferably containing as the fatty acid alkoxide of non-ionic surface active agent mainly is oxyalkylene chain by ethylene oxide unit(s), expoxy propane unit or combinations thereof.
Fatty acid in the presence of base catalyst such as alkali metal hydroxide, alkali alcoholate, alkali metal, alkali carbonate and alkali metal carboxylate, prepares by the oxygen alkoxylated fatty acid usually.In addition, the fatty acid alkoxide can be produced with the poly alkylene glycol esterified fatty acid.The example that is used as the fatty acid alkoxide of non-ionic surface active agent comprises that every moles of fatty acids has the about 1 fatty acid alkoxide to about 20 moles of ethylene oxide (EO) or expoxy propane (PO) unit.Common fatty acid alkoxide is listed in chemical classification hurdle " Propoxylated﹠amp in " emulsifier and washing agent " 1992 yearbooks of McCutcheon; Ethoxylated Fatty Acids, Alohol or AlkylPhenols " in.
Block copolymer is by two or the surfactant that makes of more alkoxyl material.Block copolymer can only form by the alkoxyl material or can by two or more on fatty alcohol the different alkoxyl material of polymerization form.Block copolymer is normally at first produced many alkoxides (as b-oxide, propoxide and combination thereof), addition second and different many alkoxides again in the presence of base catalyst such as sodium hydroxide subsequently in the presence of base catalyst such as sodium hydroxide.The another kind of selection is that same method can be made raw material with fatty alcohol, makes two or more alkoxyl addition product then.The polyalkoxylated chain of compound can have the alkoxide (alkoxide) of 10-400 unit.The alcohol block copolymer can have C
2-C
18Carbon chain lengths and being used to produce each alkoxide of the 1-20 mole of this surfactant.Block copolymer as non-ionic surface active agent preferably contains by mainly being many alkoxides that ethylene oxide unit(s), expoxy propane unit or its composition are formed.For example, common block copolymer is the ethoxylation chain of poly-propoxyl group material or the opposite propoxylation chain of polyethoxy material.Common block copolymer is listed in the chemical classification hurdle " Block Polymers " in " emulsifier and washing agent " 1992 yearbooks of McCutcheon.
The corrosion inhibitor component of assistant composition comprises those non-oxide compounds, and this compound is obviously by utilizing the absorption to dissolved oxygen, at nearly neutral pH scope, passivated iron or other metal effectively.The material as corrosion inhibitor that is fit to includes, but not limited to inorganic oxide such as alkali-metal benzoate such as Sodium Benzoate (C
6H
5COONa), alkali metal cinnamate such as sodium cinnamate (C
6H
5CHCHCOONa), alkali-metal polyphosphate such as sodium polyphosphate ((NaPO
3)
n) and the salt such as the sodium phenylacetate of organic inhibitor such as alkali metal phenyl carboxylic acid or phenyl carboxylic acid.Other example that is used for corrosion inhibitor of the present invention comprises the compound of following type:
Nitrite
Hypophosphites
Ortho-aminobenzoic acid
Borate
The amine functional carboxylic acid
Phosphate
Soap
Alkanolamide
The tannin of modification
The oxazoline derivative
Petroleum sulfonate
Polyamines
Salt and the composition thereof of fatty amine imidazoline amino acid and salt amine official energy amphoteric surfactant quaternary ammonium salt fatty ester fatty alcohol sorbitan ester benzotriazole cpd tolytriazole compound fat sarcosinate phosphonic acids and salt lanolin derivative calgon butanedioic acid, its derivative and their salt D2EHDTPA and the oxyalkylated fatty amine fatty amine oxide of salt amine phosphate and derivative silicate (metasilicate salts) alkanolamine mercaptobenzothiazoler silicate (Silicate Salts) aliphatic methyl amimoacetic acid and derivative glyceride boramides amine quaternary compound aliphatic series amidoamines dimerization and three polyglycerol fatty acids
The instantiation of the compound of these types is found in the FunctionalMaterials of McCutcheon, North American Edition, and 1992, be listed in the functional classification column " Corrosion Inhibitors ".
Preferred assistant composition also contains at least a alcohol or glycol and/or at least a fatty acid.The alkoxide component of auxiliary agent preferably is selected from has about 1 to about 8 carbon, more preferably 2 fatty alcohol and aliphatic diols to about 6 carbon.Alkoxide component can contain the combination and/or the glycol of a kind of alcohol or alcohol.More excellent alcohol comprises isopropyl alcohol and n-butanol.Preferred glycol comprises propane diols and hexylene glycol.The fatty acid component of assistant composition includes but not limited to have about 6 to about 20 carbon and about 1 unsaturated carboxylic acid to about 4 degrees of unsaturation.The source that is used for fatty acid of the present invention comprises for example pine tree stake (its fatty acid is ready denier oil acid), plant such as soybean and cotton seed oil, and animal.The example of the fatty acid that is fit to comprises the fatty acid of the plant derivation that ready denier oil acid and major part are made up of linoleic acid, rosin acid, linolenic acid, oleic acid and composition thereof.
Assistant composition of the present invention can contain 2 to about 98% the non-ionic surface active agent of having an appointment, 0 to about 30% fatty acid, 0 to 30% alcohol and about 0.1 to about 5% corrosion inhibitor.The preferred content of non-ionic surface active agent in assistant composition is about 10 to 85%, more preferably from about 20 to about 80%.Though do not wish to be bound by any theory, it is believed that the existence of fatty acid and alkoxide component overcomes the gel phase of non-ionic surface active agent.Therefore, the amount of fatty acid and alcohol depends on the gel characteristic of non-ionic surface active agent.When usually existing greater than about 25% non-ionic surface active agent, can be with about 1 to about 15% fatty acid and/or about 1 to about 20% alcohol.The preferred amounts of corrosion inhibitor is about 0.3 to about 1%.The surplus of assistant composition comprises water.
Assistant composition of the present invention also can contain other composition as long as they do not damage beneficial effect of the present invention.The example of optional member comprises other surfactant such as anion, cation and zwitterionic surfactant, cosolvent, preservative, defoamer, adhesion agent and buffer.
Assistant composition of the present invention can make up with various forms with one or more pesticide composition.For example, assistant composition can mix using the apparatus stage, in this stage pesticidal preparations water or suitable carrier dilution, in the aerosol can of packing into (so-called " bucket mixes ").The form accepted that can be used for the mixed agricultural chemicals of bucket of processing for example comprises aqueous emulsion, fat liquor, the aqueous solution or dry suspending agent.Pesticide composition can be for example bactericide, weed killer herbicide, insecticide, nematocide, miticide and composition thereof.Assistant composition of the present invention can be added in the mixed thing of bucket, its amount be generally the mixed thing of bucket about 0.005 to about 5% (weight).Preferably, agent mixture be the mixed thing of bucket 0.02% to about 2% (weight).In preferred embodiments, assistant composition of the present invention has about 10 to about 15 hydrophilic lipophilic balance (HLB).
Advantage of the present invention and other characteristics can be made best illustration with the following example.
Embodiment 1
The effect of the weed killer herbicide formulation resistance of rainwater washing against of embodiment 1 explanation assistant composition of the present invention.
The sprayable herbicide formulations that the weeding control is estimated with the auxiliary agent of the present invention of the component of listing in the tabulation 1 under the having of containing various amounts carries out.
Table 1
| Auxiliary component | Chemical descriptor | Amount (wt% of assistant composition) |
| Non-ionic surface active agent | The nonyl phenol of ethoxylation | ????76 |
| Corrosion inhibitor | Sodium Benzoate | ????0.5 |
| Alcohol | Butanols | ????12 |
| Fatty acid | Oleic acid-83wt% linoleic acid-14wt% | ????4 |
| Water | Water | ????7.5 |
This spray adjuvantses of various amounts (0,0.1,0.2,0.3 and 5wt%) added to contain per hectare 0.66kg active ingredient (" 0.66kg-ai/ha ") farming and reach
In the mixed thing of bucket of board weed killer herbicide (can buy) by U.S. Missouri Monsanto Company.
Use herbicide formulations with knapsack sprayer with the amount of 187 liters of per hectares (187l/ha).Set up spray fully with sprinkling irrigation and release 1.27cm water/h, simulated rainfall.Behind the herbicide application, reach with farming
Sprayed 15,30,60,120 and 240 minutes with the experimental plot that table 1 auxiliary agent is handled.Rainfall is not carried out in each control plot of handling.The split block experiment design is adopted in experiment.
Each sub-district is of a size of 3.66 * 7.69 meters.Each is handled and repeats four times.Soil types is husky earth (sand 60%, silty sand 24%, a clay 15%, organic 24%).
Through 2 years, gather control of weeds data to broad-leaved arm shape grass (Brachiaria platyphyllaNash.) and Amaranthus retroflexus (Amaranthus retroflexus L.).Below shown in Table II and the data among the III be that the data in the Table IV are to Amaranthus retroflexus (the 1st year) to broad-leaved arm shape grass (the 1st year and the 2nd year).
Table II
In the 1st year, use the farming that mixes with table 1 auxiliary agent to reach
Handle also and be exposed to subsequently
After the artificial rainfall 15 days, to the control of weeds rate of broad-leaved arm shape grass
| Auxiliary agent accounts for the amount (wt% of the mixed thing of bucket) of the mixed thing of bucket | Control of weeds rate (%) (time (handling back the number of minutes) that artificial rainfall is used) | |||||
| ?15 | ?30 | ?60 | ?120 | ?240 | There is not artificial rainfall | |
| ?0 | ?83 | ?75 | ?88 | ?97 | ?96 | ?98 |
| ?0.1 | ?83 | ?90 | ?98 | ?99 | ?99 | ?100 |
| ?0.2 | ?92 | ?92 | ?94 | ?98 | ?99 | ?100 |
| ?0.5 | ?90 | ?97 | ?97 | ?99 | ?98 | ?100 |
| ?0.5 | ?90 | ?95 | ?100 | ?100 | ?98 | ?100 |
In the Table III the 2nd year, use the farming that mixes with table 1 auxiliary agent to reach
Handle and be exposed to after the artificial rainfall 23 days subsequently, to the control of weeds rate of broad-leaved arm shape grass
| Auxiliary agent accounts for the amount (wt% of the mixed thing of bucket) of the mixed thing of bucket | Control of weeds rate (%) (time (handling back the number of minutes) that artificial rainfall is used) | |||||
| ?15 | ?30 | ?60 | ?120 | ?240 | There is not artificial rainfall | |
| ?0.0 | ?30 | ?62 | ?73 | ?88 | ?90 | ?100 |
| ?0.1 | ?57 | ?68 | ?93 | ?92 | ?100 | ?100 |
| ?0.2 | ?63 | ?73 | ?97 | ?100 | ?100 | ?100 |
| ?0.3 | ?60 | ?82 | ?90 | ?98 | ?97 | ?100 |
| ?0.5 | ?67 | ?85 | ?98 | ?100 | ?98 | ?100 |
In the Table IV the 1st year, use the farming that mixes with table 1 auxiliary agent to reach
Processing also is exposed to artificial rainfall subsequently, to the control of weeds rate of broad-leaved arm shape grass
| Auxiliary agent accounts for the amount (wt% of the mixed thing of bucket) of the mixed thing of bucket | Control of weeds rate (%) (time (handling back the number of minutes) that artificial rainfall is used) | |||||
| ?15 | ?30 | ?60 | ?120 | ?240 | There is not artificial rainfall | |
| ?0.0 | ?77 | ?73 | ?87 | ?93 | ?98 | ?95 |
| ?0.1 | ?75 | ?86 | ?93 | ?93 | ?98 | ?100 |
| ?0.2 | ?83 | ?85 | ?92 | ?96 | ?100 | ?100 |
| ?0.3 | ?80 | ?93 | ?91 | ?95 | ?96 | ?100 |
| ?0.5 | ?82 | ?88 | ?97 | ?98 | ?99 | ?100 |
The required no rain of the 90% control of weeds rate that reaches that is calculated by each weeds kind is shown in the Table V period.This time is referred to as T
90, obtain by the small plot experiment data, with the control of weeds rate that obtains 90% no rain time.
Table V obtain 90% control of weeds rate (%) required no rain period (minute) (T90) auxiliary agent account for amount (wt% of the mixed thing of bucket) the broad-leaved arm shape grass Amaranthus retroflexus of the mixed thing weeds kind of bucket
The 1st year the 2nd year the 1st year 0.0 73 240 900.1 30 56 470.2＜15 51 510.3 15 60 260.5 15 42 37
The data in 2 years of broad-leaved arm shape grass show, being added in of assistant composition all obviously increases farming and reach under all test volumes
Resistance of rainwater washing against (Table II and III).Compare T
90Value as seen, the required no rain average out in period of the 90% control of weeds rate that reaches 35.5 minutes, and this moment, adding did not have the farming of table 1 auxiliary agent to reach
The viewed control rate of preparation only is 23%.
The type (Table IV) of Amaranthus retroflexus control is with very approaching with the viewed trend of broad-leaved arm shape grass, and the average out to 40.2 minutes in anhydrous period that the 90% control of weeds rate that reaches is required exists and only do not observe 44% control rate down and there is the auxiliary agent composition.
As shown in Table V, when table 1 auxiliary agent added increase, farming reached
Effect increase with the concentration of auxiliary agent, with the auxiliary agent of 5ml/l amount, provide the 90% control of weeds rate that reaches required the shortest no rain period.Moreover, find that farming reaches
The resistance of rainwater washing against of+agent mixture depends on the weather vegetative period of condition and weeds.Particularly, in the test in 1 year, soil wets, and control of weeds is good especially, and in 1 year, soil is done, and control of weeds is difficulty.
Embodiment 2
Sprayable herbicide formulations with the auxiliary agent of the present invention that contains listed composition in the top table 1 carries out the control of weeds evaluation.This spray adjuvants with the amount of 0.20wt% add contain 9g-ai/ha chlorimuron weed killer herbicide (can be by U.S. E.I.Dupont﹠amp; Co.of Delaware buys) the mixed thing of bucket.
With knapsack sprayer with the amount of 180l/ha water under the atomisation pressure of 32psi, use this weed killer herbicide bucket and mix thing+auxiliary agent preparation.
Soil types is husky earth (sand 60%, flour sand 24%, a clay 15%, organic 24%).A kind of processing is only accepted the weed killer herbicide bucket and is mixed thing, and the mixed thing+spray adjuvants of weed killer herbicide bucket is accepted in second kind of processing.Each is handled and repeats four times.
The control of weeds data are collection in 7,14,20 and 34 days after processing.Be shown in following Table VI and list data pharbitis nilChoisy.Be shown in following Table VII and list data blunt leaf Cassia tora.
Table VI
| Herbicide treatment | Control of weeds percentage (handling the back fate) | |||
| ????7 | ????14 | ????20 | ????34 | |
| Chlorimuron+0.2wt% Table I auxiliary agent | ????83 | ????93 | ????83 | ????80 |
| Chlorimuron | ????63 | ????53 | ????50 | ????67 |
Table VII
| Herbicide treatment | Control of weeds percentage (handling the back fate) | |||
| ?????7 | ????14 | ????20 | ????34 | |
| Chlorimuron+0.2wt% Table I auxiliary agent | ????83 | ????93 | ????73 | ????80 |
| Chlorimuron | ????60 | ????47 | ????10 | ????57 |
The result of Table VI and VII shows that the effect of weed killer herbicide improves by adding the Table I auxiliary agent.
Embodiment 3
With the sprayable preparation of the auxiliary agent of the present invention that contains the assistant composition that is listed in top table 1, on oily orange, carry out the rust mite control and estimate.
This spray adjuvants of two kinds of amounts (0.02 and 0.04wt%) adds and contains 50g-ai/ha Bristol gram
RBoard miticide (active component: in the mixed thing of bucket fenbutatin oxide).The Bristol gram
RCan buy by Dutch shell chemical company.
With knapsack sprayer with the amount of 500l/ha water under the 30psi atomisation pressure, use this miticide bucket and mix thing+auxiliary agent preparation.First kind of processing accepted the miticide bucket separately and mixed thing, and second kind of processing accepted the miticide bucket and mixed thing+0.02wt% auxiliary agent, and the third processing is accepted the miticide bucket and mixed thing+0.04wt% auxiliary agent.Each is handled and repeats four times.
Table VIII contains rust mite and prevents and treats data, collects in 3,7,14 and 21 days after processing.
Table VIII
| Miticide is handled | Citrus rust mite control percentage (handling the back fate) | |||
| ????3 | ????7 | ????14 | ????21 | |
| The Bristol gram | ?35.5 | ??53.4 | ??16.0 | ??17.1 |
| The Bristol gram + 0.02% Table I auxiliary agent | ?56.5 | ??68.8 | ??43.4 | ??25.8 |
| The Bristol gram + 0.04% Table I auxiliary agent | ?74.9 | ??83.1 | ??48.1 | ??50.2 |
The result of Table VIII shows that the effect of this mite-killing preparation is improved by the auxiliary agent of Table I.
Embodiment 4
Estimate with the bacterial leaf-blight control that the sprayable bactericide of the preparation of the present invention that contains the composition of listing in top Table I carries out on rice.
This spray adjuvants of two kinds of amounts (0.02 and 0.04wt%) is added and contains the 7.8kg-ai/ha Jinggangmei
Board bactericide (active component: in the mixed thing of bucket streptomycete).
With knapsack sprayer with the amount of 1500l/ha water under the 30psi atomisation pressure, use this bactericide bucket and mix thing+auxiliary agent preparation.A kind of processing is only accepted the bactericide bucket and is mixed thing, and second kind of processing accepted the bactericide bucket and mixed thing+0.02% auxiliary agent, and the third processing is accepted the bactericide bucket and mixed thing+0.04% auxiliary agent.Each is handled and repeats four times.
Contain 7,14 and 21 days the bacterial leaf-blight in processing back among the Table I X and prevent and treat data.
Table I X
| Bactericide is handled | Bacterial leaf-blight control percentage (handling the back fate) | ||
| ????7 | ????14 | ????21 | |
| Jinggangmycin | ?98.2 | ??71.6 | ??68.6 |
| Jinggangmycin + 0.02wt% Table I auxiliary agent | ?99.2 | ??90.3 | ??74.7 |
| Jinggangmycin + 0.04wt% Table I auxiliary agent | ?100 | ??95.9 | ??93.8 |
Embodiment 5
With the mixed thing of bucket of sprayable formulation of insecticides and auxiliary agent of the present invention, on rice, carry out the grand in vain root eating insect control of beans and estimate with composition listed in the top table 1.
This spray adjuvants adds in the mixed thing of bucket of EPN insecticide of the parathion-methyl insecticide that contains 0.28kg-ai/ha and 0.28kg-ai/ha.
With knapsack sprayer the mixed thing of water yield applying pesticide bucket under the 30psi atomisation pressure+auxiliary agent preparation with 20l/ha.First kind of processing only accepted the insecticide bucket and mixed thing, and second kind of processing accepted the insecticide bucket and mixed thing+0.047% auxiliary agent.Each is handled and repeats four times.
Discovery, the mixed thing of bucket of adding assistant obtains 85.2% the grand in vain root eating insect control rate of beans, and adds the pesticide control effect of the mixed thing acquisition 93.4% of bucket of barrel agent.
Embodiment 6
Sprayable weed killer herbicide with the another kind of auxiliary agent of the present invention who contains the composition of listing in following Table X carries out the control of weeds evaluation on corn.
Table X
| Adjuvant component | Chemical descriptor | Amount (wt%) |
| Non-ionic surface active agent | The nonyl phenol of ethoxylation | ????23.6 |
| Corrosion inhibitor | Sodium Benzoate | ????0.5 |
| Water | Water | ????75.9 |
Then this spray adjuvants is added the Aatrex that contains 1.1kg-ai/ha
RIn the mixed thing of bucket of board weed killer herbicide.(Aatrex
RActive ingredient: atrazine), can buy by U.S. vapour Ba-Jia Ji company.
Use weed killer herbicide+auxiliary agent preparation with knapsack sprayer with the water yield of 200l/ha.Soil types is husky earth (sand 60%, silty sand 24%, a clay 15%, organic 24%).Weed killer herbicide is only accepted in first kind of processing.The Table X auxiliary agent of weed killer herbicide and 0.625wt% is accepted in second kind of processing.Each is handled and repeats four times.
Table X I lists the control of weeds data to Amaranthus retroflexus, pharbitis nilChoisy, Binzhou Siberian cocklebur and lady's-grass.
Table X I
| Herbicide treatment | The control of weeds percentage | |||
| The weeds kind | Amaranthus retroflexus | Pharbitis nilChoisy | Binzhou Siberian cocklebur | Lady's-grass |
| Aatrex4C | ???88 | ????88 | ????83 | ???78 |
| Aatrex R+ 0.0625 wt% Table X auxiliary agent | ???93 | ????95 | ????93 | ???90 |
Except the effect that increases pesticidal preparations, the existence of the corrosion inhibitor of assistant composition of the present invention helps to protect pump and spraying apparatus component not to be subjected to the corrosion infringement.In addition, mix the storage period that corrosion inhibitor helps assistant composition or contains the pesticidal preparations of assistant composition of the present invention.
Claims (12)
1. an assistant composition is characterized in that, described composition comprises:
About by weight 2 to about 98% at least a non-ionic surface active agent;
About by weight 0.1 to about 5% at least a corrosion inhibitor;
About by weight 0 to about 30% at least a alcohol; With
About by weight 0 to about 30% at least aly have about 6 fatty acid to about 20 carbon.
2. method that improves the pesticidal preparations performance, it comprises:
The assistant composition of claim 1 is provided;
The mixed thing of bucket of the pesticidal preparations that comprises effective dose and carrier is provided;
Make up described assistant composition and the mixed thing of described bucket.
3. the method for the composition of claim 1 and/or claim 2, wherein at least a described non-ionic surface active agent is to be selected from pure alkoxide, polyalcohol alkoxide, alkaryl alkoxide, oxyalkylated amine, oxyalkylated acid amides, fatty acid alkoxide block copolymer and combination thereof.
4. the method for the composition of claim 1 and/or claim 2, wherein at least a described corrosion inhibitor is selected from: the alkali metal benzoate, the alkali metal cinnamate, alkali metal polyphosphates, alkali metal phenyl carboxylic acid, nitrite, hypophosphites, ortho-aminobenzoic acid, borate, the amine functional carboxylic acid, phosphate, soap, alkanolamide, the tannin oxazoline derivative of modification, petroleum sulfonate, polyamines, fatty amine, imidazoline, amino acid and salt thereof, amine official energy amphoteric surfactant, quaternary ammonium salt, fatty ester, fatty alcohol, sorbitan ester, benzotriazole cpd, the tolytriazole compound, the fat sarcosinate, phosphonic acids and salt thereof, lanolin derivative, hexametaphosphate, succinic acid and derivative thereof and salt thereof, D2EHDTPA and salt thereof, amine phosphate, oxyalkylated fatty amine, fatty amine oxide and derivative thereof, silicate (metasiliate salts), alkanolamine, mercaptobenzothiazoler, silicate, fat methyl amimoacetic acid and derivative thereof, glyceride, boramides, amine, quaternary compound, the fat amidoamines, dimerization and trimerization soap, and composition.
5. the method for the composition of claim 1 and/or claim 2, wherein at least a described alcohol is selected from has about C
1To about C
8The aliphatic alcohol of carbon chain length and aliphatic polyol.
6. the method for the composition of claim 1 and/or claim 2, wherein at least a described fatty acid is selected from linoleic acid, rosin acid, linolenic acid and oleic acid and combination thereof.
7. the method for the composition of claim 1 and/or claim 2, wherein said non-ionic surface active agent exists with about 25% to about 98% assistant composition amount.
8. the composition of claim 7, wherein said fatty acid exists with about 1% to about 15% amount.
9. the composition of claim 7, wherein said pure and mild glycol exists with about 1% to about 20% amount.
10. each of claim 1-9 or multinomial composition, wherein said corrosion inhibitor are to exist with about 0.3% to about 1% amount.
11. each of claim 2-7 or multinomial method, wherein said assistant composition are amount and the combination of described bucket mixing composition with 0.005% to about 5%.
12. the composition of claim 1 and/or the method for claim 2, wherein said assistant composition have about 10 to about 15 HLB value.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96123986A CN1186598A (en) | 1996-12-30 | 1996-12-30 | Plant protecting adjuvant composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96123986A CN1186598A (en) | 1996-12-30 | 1996-12-30 | Plant protecting adjuvant composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1186598A true CN1186598A (en) | 1998-07-08 |
Family
ID=5127732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96123986A Pending CN1186598A (en) | 1996-12-30 | 1996-12-30 | Plant protecting adjuvant composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1186598A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108347920A (en) * | 2015-08-04 | 2018-07-31 | 罗地亚经营管理公司 | Agriculture adjuvant composition and the method for using such composition |
| CN109287632A (en) * | 2018-09-26 | 2019-02-01 | 广西田园生化股份有限公司 | A kind of oil base pesticidal preparations enhancer composition and its application |
-
1996
- 1996-12-30 CN CN96123986A patent/CN1186598A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108347920A (en) * | 2015-08-04 | 2018-07-31 | 罗地亚经营管理公司 | Agriculture adjuvant composition and the method for using such composition |
| CN108347920B (en) * | 2015-08-04 | 2022-04-26 | 罗地亚经营管理公司 | Agricultural adjuvant compositions and methods of using such compositions |
| CN109287632A (en) * | 2018-09-26 | 2019-02-01 | 广西田园生化股份有限公司 | A kind of oil base pesticidal preparations enhancer composition and its application |
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