CN118602958A - A method for measuring film thickness online - Google Patents
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Abstract
本发明公开了一种薄膜厚度在线测量方法,包括以下步骤:对薄膜厚度测量装置进行校准;对待测样品的基底和样品的材料种类进行选择;将待测样品的基底放在样品放置台上,检测基底的反射亮光场光谱和反射暗光场光谱;将附着有待测薄膜的基底放置在样品放置台上,将检测到的反射光谱减去基底的反射亮光场光谱和基底的反射暗光场光谱之差,得到薄膜的反射光谱;完成薄膜的反射光谱的采集后,微型计算机自动对薄膜的反射光谱进行分析,输出薄膜厚度的测量结果;改变样品放置台的位置,实现对薄膜厚度的多点测量。本发明的方法,采用光谱仪采集薄膜反射光谱,通过薄膜厚度测量网络模型可实现薄膜厚度的在线测量,测量速度快、结果准确、成本低。
The invention discloses an online film thickness measurement method, comprising the following steps: calibrating a film thickness measurement device; selecting the substrate of a sample to be measured and the material type of the sample; placing the substrate of the sample to be measured on a sample placement table, detecting the reflected bright light field spectrum and the reflected dark light field spectrum of the substrate; placing the substrate with the film to be measured attached on the sample placement table, subtracting the difference between the reflected bright light field spectrum of the substrate and the reflected dark light field spectrum of the substrate from the detected reflected spectrum, and obtaining the reflection spectrum of the film; after completing the acquisition of the reflection spectrum of the film, a microcomputer automatically analyzes the reflection spectrum of the film and outputs the measurement result of the film thickness; changing the position of the sample placement table to realize multi-point measurement of the film thickness. The method of the invention uses a spectrometer to collect the film reflection spectrum, and can realize the online measurement of the film thickness through a film thickness measurement network model, with fast measurement speed, accurate results and low cost.
Description
技术领域Technical Field
本发明涉及薄膜厚度的测量技术领域,特别涉及一种薄膜厚度在线测量方法。The invention relates to the technical field of film thickness measurement, and in particular to an online film thickness measurement method.
背景技术Background Art
光电器件一般由薄膜组成,在其制作过程中,薄膜厚度是影响光电器件的关键因素,因此需要在制备薄膜时准确检测其厚度。Optoelectronic devices are generally composed of thin films. During their manufacturing process, the thickness of the film is a key factor affecting the optoelectronic devices. Therefore, it is necessary to accurately detect the thickness of the film when preparing the film.
目前薄膜厚度测量技术主要分为机械扫描法和光学测量法。以台阶仪为例的机械扫描法虽具有较高的精度以及测量范围,但由于测量速度低、只能测量单点膜厚和须破坏薄膜等因素,在实际生产中受到很多限制。目前光学测量法已成为薄膜厚度测量主流方法,根据实验原理可分为椭偏仪、结构照明显微镜等。At present, the thin film thickness measurement technology is mainly divided into mechanical scanning method and optical measurement method. The mechanical scanning method, such as the step meter, has high accuracy and measurement range, but it is subject to many limitations in actual production due to factors such as low measurement speed, only single-point film thickness measurement and the need to destroy the film. At present, the optical measurement method has become the mainstream method for thin film thickness measurement, and can be divided into ellipsometer, structured illumination microscope, etc. according to the experimental principle.
椭偏仪测量膜厚是基于一定偏振态的入射光在样品表面反射时,其反射光的s波和p波振幅衰减比与相位差发生变化,最终导致反射光偏振态变化,然后通过琼斯矩阵对入射光矢量逐一点乘,从而获得s波和p波的电磁场矢量并计算出对应的反射系数。根据菲涅尔公式可知,两反射系数比值可以反解出s波和p波振幅衰减系数相位差的理论表达式,其中变量为薄膜厚度和折射率。因此,可在已知折射率情况下计算出厚度,或是在已知厚度情况下计算出薄膜折射率。The ellipsometer measures film thickness based on the fact that when incident light of a certain polarization state is reflected on the sample surface, the amplitude attenuation ratio and phase difference of the s-wave and p-wave of the reflected light change, which eventually causes the polarization state of the reflected light to change. Then, the incident light vector is multiplied point by point through the Jones matrix to obtain the electromagnetic field vectors of the s-wave and p-wave and calculate the corresponding reflection coefficient. According to the Fresnel formula, the ratio of the two reflection coefficients can be used to inversely solve the theoretical expression of the phase difference of the s-wave and p-wave amplitude attenuation coefficients, where the variables are the film thickness and refractive index. Therefore, the thickness can be calculated when the refractive index is known, or the film refractive index can be calculated when the thickness is known.
使用结构光照明显微镜(MSIM)测量膜厚,可以获得薄膜一定范围厚度轮廓。该方法将数字微镜器件生成的正弦条纹图案投射到薄膜上,用CCD获取薄膜基底和表面反射图像,再移动样品至Z方向位置,根据干涉条纹对比率变化判断焦点位置,并在该位置上对比以薄膜光学厚度为变量的理论光强分布,可实现薄膜厚度测量。Using structured light illumination microscopy (MSIM) to measure film thickness, the thickness profile of a certain range of the film can be obtained. This method projects the sinusoidal fringe pattern generated by the digital micromirror device onto the film, uses CCD to obtain the film substrate and surface reflection image, and then moves the sample to the Z direction position, determines the focus position according to the change in the contrast ratio of the interference fringes, and compares the theoretical light intensity distribution with the film optical thickness as a variable at this position, so as to achieve film thickness measurement.
但是,上述光学测量方法和机械扫描方法都具有测量速度慢、测量点少、成本昂贵等缺点。难以贴近实际的生产需要。However, the above optical measurement method and mechanical scanning method have the disadvantages of slow measurement speed, few measurement points, high cost, etc., which are difficult to meet the actual production needs.
发明内容Summary of the invention
为了克服现有技术的上述缺点与不足,本发明的目的在于提供一种薄膜厚度在线测量方法,采用光谱仪采集薄膜反射光谱,通过薄膜厚度测量网络模型可实现薄膜厚度的在线测量,测量速度快、结果准确、成本低。In order to overcome the above-mentioned shortcomings and deficiencies of the prior art, the purpose of the present invention is to provide a method for online measurement of thin film thickness, which adopts a spectrometer to collect the thin film reflection spectrum, and can realize online measurement of thin film thickness through a thin film thickness measurement network model, with fast measurement speed, accurate results and low cost.
本发明的另一目的在于提供一种薄膜厚度测量网络模型的生成方法,训练过程中迭代收敛速度快,测量准确率高。Another object of the present invention is to provide a method for generating a film thickness measurement network model, which has fast iterative convergence speed and high measurement accuracy during training.
本发明的再一目的在于提供上述薄膜厚度测量网络模型的生成装置。Another object of the present invention is to provide a device for generating the above-mentioned film thickness measurement network model.
本发明的目的通过以下技术方案实现:The purpose of the present invention is achieved through the following technical solutions:
本发明的其中一个实施例提供了一种薄膜厚度在线测量方法,所述薄膜厚度在线测量方法基于薄膜厚度测量装置;所述薄膜厚度测量装置包括样品单元,光路单元和数据处理单元;One embodiment of the present invention provides a method for online measurement of film thickness, wherein the method is based on a film thickness measurement device; the film thickness measurement device includes a sample unit, an optical path unit and a data processing unit;
所述样品单元包括样品放置台和平台移动电机;所述平台移动电机用于驱动样品放置台在二维平面上移动;The sample unit comprises a sample placement platform and a platform moving motor; the platform moving motor is used to drive the sample placement platform to move on a two-dimensional plane;
所述光路单元包括卤钨灯光源、光纤探头、光谱仪、第一光纤和第二光纤;所述卤钨灯光源通过第一光纤与光纤探头连接,所述光纤探头通过第二光纤与光谱仪连接;所述光纤探头位于所述样品放置台的上方;The optical path unit comprises a tungsten halogen lamp light source, an optical fiber probe, a spectrometer, a first optical fiber and a second optical fiber; the tungsten halogen lamp light source is connected to the optical fiber probe via the first optical fiber, and the optical fiber probe is connected to the spectrometer via the second optical fiber; the optical fiber probe is located above the sample placement table;
在对薄膜进行测量时,所述卤钨灯光源的出射光经第一光纤输出到光纤探头,入射到薄膜内并在薄膜的上下界面发生多光束干涉,携带薄膜厚度信息的反射光被光纤探头接收,并经第二光纤传输到光谱仪,光谱仪采集反射光谱数据,经数据处理单元分析处理后,输出薄膜厚度的测量结果;When measuring a thin film, the emitted light of the halogen tungsten lamp light source is output to the optical fiber probe through the first optical fiber, incident into the thin film and causing multi-beam interference at the upper and lower interfaces of the thin film. The reflected light carrying the film thickness information is received by the optical fiber probe and transmitted to the spectrometer through the second optical fiber. The spectrometer collects the reflected spectrum data, and after being analyzed and processed by the data processing unit, the measurement result of the film thickness is output;
所述数据处理单元内置有薄膜厚度测量网络模型;The data processing unit is equipped with a film thickness measurement network model;
所述薄膜厚度测量网络模型由以下方法得到:The film thickness measurement network model is obtained by the following method:
S11数据集生成:S11 dataset generation:
S111根据薄膜和基底的材料的折射率,通过数学分析软件的多项式非线性拟合获取薄膜和基底折射率随波长变化的反射率拟合函数;S111 obtains the reflectivity fitting function of the refractive index of the film and the substrate as it changes with the wavelength through polynomial nonlinear fitting of mathematical analysis software according to the refractive index of the film and the substrate;
S112选取消光系数接近零的波段,根据该波段的薄膜和基底折射率的随波长变化的反射率拟合函数,及设置的薄膜厚度训练步长,生成厚度位于500nm-10μm之间的薄膜理论反射率光谱;S112 selects a wavelength band with a light coefficient close to zero, and generates a theoretical reflectivity spectrum of a thin film with a thickness between 500 nm and 10 μm according to a reflectivity fitting function of the refractive index of the thin film and substrate in the wavelength band and a set film thickness training step;
S113采用Python内置函数,在薄膜理论反射率光谱中引入正态分布噪声,生成多个样本,将多个样本划分为训练集和验证集;S113 uses Python built-in functions to introduce normal distribution noise into the theoretical reflectance spectrum of thin films, generate multiple samples, and divide the multiple samples into training sets and validation sets;
S114改变薄膜和基底的材料,重复步骤S111~S114,得到不同材料的薄膜和基底的数据集;S114 changes the materials of the film and the substrate, repeats steps S111 to S114, and obtains data sets of films and substrates of different materials;
S12卷积神经网络模型搭建:S12 convolutional neural network model construction:
所述卷积神经网络模型包括依次连接的第一卷积激活层、第一池化层、第二卷积激活层、第二池化层、展开层和全连接层;所述第一卷积激活层包括一维卷积运算模块和非线性激活函数模块;所述第一卷积激活层包括第一一维卷积运算模块和第一非线性激活函数模块;所述第二卷积激活层包括第二一维卷积运算模块和第二非线性激活函数模块;所述卷积神经网络模型以薄膜的反射率光谱作为输入,薄膜的厚度作为输出;The convolutional neural network model includes a first convolutional activation layer, a first pooling layer, a second convolutional activation layer, a second pooling layer, an expansion layer and a fully connected layer connected in sequence; the first convolutional activation layer includes a one-dimensional convolution operation module and a nonlinear activation function module; the first convolutional activation layer includes a first one-dimensional convolution operation module and a first nonlinear activation function module; the second convolutional activation layer includes a second one-dimensional convolution operation module and a second nonlinear activation function module; the convolutional neural network model takes the reflectance spectrum of the film as input and the thickness of the film as output;
S13卷积神经网络模型训练;S13 convolutional neural network model training;
S14卷积神经网络模型验证;S14 Convolutional neural network model verification;
所述薄膜厚度在线测量方法包括以下步骤:The film thickness online measurement method comprises the following steps:
S1使用标准样品对所述薄膜厚度测量装置进行校准;S1 calibrates the film thickness measuring device using a standard sample;
S2对待测样品的基底和样品的材料种类进行选择;S2 selects the substrate of the sample to be tested and the material type of the sample;
S3将待测样品的基底放在样品放置台上,并通过控制平台移动电机使其位于在光纤探头正下方,检测基底的反射亮光场光谱和反射暗光场光谱;S3 places the substrate of the sample to be tested on the sample placement table, and controls the platform to move the motor so that it is located directly below the optical fiber probe, and detects the reflected bright light field spectrum and reflected dark light field spectrum of the substrate;
S4将附着有待测薄膜的基底放置在样品放置台上,并通过控制平台移动电机使其位于在光纤探头正下方,将检测到的反射光谱减去基底的反射亮光场光谱和基底的反射暗光场光谱之差,得到薄膜的反射光谱;S4 places the substrate with the film to be tested on the sample placement table, and controls the platform moving motor to make it directly below the optical fiber probe, and subtracts the difference between the reflected bright light field spectrum of the substrate and the reflected dark light field spectrum of the substrate from the detected reflection spectrum to obtain the reflection spectrum of the film;
S5完成薄膜的反射光谱的采集后,数据处理单元自动对薄膜的反射光谱进行分析,输出薄膜厚度的测量结果;After S5 completes the acquisition of the reflection spectrum of the film, the data processing unit automatically analyzes the reflection spectrum of the film and outputs the measurement result of the film thickness;
S6控制平台移动电机,改变样品放置台的位置,实现对薄膜厚度的多点测量。S6 controls the platform movement motor to change the position of the sample placement table to achieve multi-point measurement of film thickness.
在本发明的一个实施例中,步骤S13所述卷积神经网络模型训练,具体采用以下方式:In one embodiment of the present invention, the convolutional neural network model training in step S13 is specifically carried out in the following manner:
采用Adam优化方式,以0.005为学习率,以交叉熵作为损失函数,若在多个迭代周期内,损失值下降则学习率下降10%。The Adam optimization method is used, with a learning rate of 0.005 and cross entropy as the loss function. If the loss value decreases within multiple iterations, the learning rate decreases by 10%.
在本发明的一个实施例中,步骤S12所述卷积神经网络模型搭建步骤中,输入设置为50个200×1的矩阵,第一一维卷积运算模块设置64个卷积核,第二一维卷积运算模块设置128个卷积核,完成卷积运算后进行展平,获得一个6400×1的矩阵,最后全连接至膜厚标签。In one embodiment of the present invention, in the convolutional neural network model building step described in step S12, the input is set to 50 200×1 matrices, the first one-dimensional convolution operation module is set to 64 convolution kernels, and the second one-dimensional convolution operation module is set to 128 convolution kernels. After the convolution operation is completed, it is flattened to obtain a 6400×1 matrix, and finally all connected to the film thickness label.
在其中一个实施例中,所述卷积核设为3×1,步幅设为1,边缘零填充设为1;第一池化层和第二池化层中的池化核设为3×1,步幅设为2。In one of the embodiments, the convolution kernel is set to 3×1, the stride is set to 1, and the edge zero padding is set to 1; the pooling kernel in the first pooling layer and the second pooling layer is set to 3×1, and the stride is set to 2.
在其中一个实施例中,所述薄膜厚度训练步长为50nm。In one embodiment, the film thickness training step size is 50 nm.
在其中一个实施例中,所述薄膜厚度测量装置还包括显示与控制单元;所述显示与控制单元包括显示屏与控制按钮;所述显示屏用于显示样品的反射光谱及薄膜厚度的测量结果;所述控制单元用于设置样品参数与测量参数。In one embodiment, the film thickness measuring device also includes a display and control unit; the display and control unit includes a display screen and control buttons; the display screen is used to display the reflection spectrum of the sample and the measurement results of the film thickness; the control unit is used to set sample parameters and measurement parameters.
在其中一个实施例中,所述样品放置台还设置有调节旋钮,用于调节样品放置台与水平面的角度,使调节样品放置台水平放置;所述卤钨灯光源还与光源调节旋钮连接;所述光源调节旋钮用于调节卤钨灯光源的光强大小。In one of the embodiments, the sample placement table is also provided with an adjustment knob for adjusting the angle between the sample placement table and the horizontal plane so that the sample placement table can be placed horizontally; the halogen tungsten lamp light source is also connected to the light source adjustment knob; the light source adjustment knob is used to adjust the light intensity of the halogen tungsten lamp light source.
在其中一个实施例中,所述数据处理单元为微型计算机;所述薄膜厚度测量网络模型由Python编写,训练、验证完成后导入到微型计算机中。In one embodiment, the data processing unit is a microcomputer; the film thickness measurement network model is written in Python and is imported into the microcomputer after training and verification.
本发明的其中一个实施例还提供了一种薄膜厚度测量网络模型的生成方法,包括以下步骤:S11数据集生成:One of the embodiments of the present invention further provides a method for generating a film thickness measurement network model, comprising the following steps: S11: generating a data set:
S111根据薄膜和基底的材料的折射率,通过数学分析软件的多项式非线性拟合获取薄膜和基底折射率随波长变化的反射率拟合函数;S111 obtains the reflectivity fitting function of the refractive index of the film and the substrate as it changes with the wavelength through polynomial nonlinear fitting of mathematical analysis software according to the refractive index of the film and the substrate;
S112选取消光系数接近零的波段,根据该波段的薄膜和基底折射率的随波长变化的反射率拟合函数,及设置的薄膜厚度训练步长,生成厚度位于500nm-10μm之间的薄膜理论反射率光谱;S112 selects a wavelength band with a light coefficient close to zero, and generates a theoretical reflectivity spectrum of a thin film with a thickness between 500 nm and 10 μm according to a reflectivity fitting function of the refractive index of the thin film and substrate in the wavelength band and a set film thickness training step;
S113采用Python内置函数,在薄膜理论反射率光谱中引入正态分布噪声,生成多个样本,将样本划分为训练集和验证集;S113 uses Python built-in functions to introduce normally distributed noise into the theoretical reflectance spectrum of thin films, generate multiple samples, and divide the samples into training sets and validation sets;
S114改变薄膜和基底的材料,重复步骤S111~S113,得到不同材料的薄膜和基底的数据集;S114 changes the materials of the film and the substrate, repeats steps S111 to S113, and obtains data sets of films and substrates of different materials;
S12卷积神经网络模型搭建:S12 convolutional neural network model construction:
所述卷积神经网络模型包括依次连接的第一卷积激活层、第一池化层、第二卷积激活层、第二池化层、全连接层和展开成;所述第一卷积激活层包括第一一维卷积运算模块和第一非线性激活函数模块;所述第二卷积激活层包括第二一维卷积运算模块和第二非线性激活函数模块;所述卷积神经网络模型以薄膜的反射率光谱作为输入,薄膜的厚度作为输出;The convolutional neural network model includes a first convolutional activation layer, a first pooling layer, a second convolutional activation layer, a second pooling layer, a fully connected layer and an unfolding layer connected in sequence; the first convolutional activation layer includes a first one-dimensional convolution operation module and a first nonlinear activation function module; the second convolutional activation layer includes a second one-dimensional convolution operation module and a second nonlinear activation function module; the convolutional neural network model takes the reflectance spectrum of the film as input and the thickness of the film as output;
S13卷积神经网络模型训练:采用Adam优化方式,以0.005为学习率,以交叉熵作为损失函数,若在多个迭代周期内,损失值下降则学习率下降10%;S13 Convolutional Neural Network Model Training: Adopt Adam optimization method, set learning rate as 0.005, and use cross entropy as loss function. If the loss value decreases within multiple iterations, the learning rate decreases by 10%.
S14卷积神经网络模型验证。S14 Convolutional neural network model verification.
本发明的其中一个实施例还提供了一种薄膜厚度测量网络模型的生成装置,包括存储器、处理器及存储在所述存储器上并可在所述处理器上运行的计算机程序,所述处理器被配置为所述方法的步骤。One of the embodiments of the present invention further provides a device for generating a film thickness measurement network model, comprising a memory, a processor, and a computer program stored in the memory and executable on the processor, wherein the processor is configured to perform the steps of the method.
与现有技术相比,本发明具有以下优点和有益效果:Compared with the prior art, the present invention has the following advantages and beneficial effects:
(1)本发明的薄膜厚度在线测量方法,采用光谱仪采集薄膜反射光谱,生成以薄膜的反射光谱为输入的薄膜厚度测量网络模型,可实现薄膜厚度的在线测量,测量速度快、结果准确、成本低。(1) The thin film thickness online measurement method of the present invention uses a spectrometer to collect the thin film reflection spectrum and generates a thin film thickness measurement network model with the thin film reflection spectrum as input, which can realize the online measurement of the thin film thickness with fast measurement speed, accurate results and low cost.
(2)本发明的薄膜厚度测量网络模型生成方法,在数据集生成步骤中,首先生成厚度位于500nm-10μm之间的薄膜理论反射率光谱,在薄膜理论反射率光谱中引入正态分布噪声,生成多个样本,提高了数据的多样性从而防止过拟合现象发生,同时确保同一膜厚下可生成大量训练样本,保证了测量网络模型的精度。(2) In the method for generating a network model for measuring film thickness of the present invention, in the step of generating a data set, a theoretical reflectance spectrum of a film with a thickness between 500nm and 10μm is first generated, and normally distributed noise is introduced into the theoretical reflectance spectrum of the film to generate multiple samples, thereby improving the diversity of the data and preventing overfitting. At the same time, it ensures that a large number of training samples can be generated under the same film thickness, thereby ensuring the accuracy of the measurement network model.
(3)本发明的薄膜厚度测量网络模型生成方法,搭建了由两层卷积激活层、两层池化层、一层展平层和一层全连接层构成的神经网络,通过对神经网络的参数优化、训练优化,进行20次迭代后,神经网络的分类正确率即可达到99%。(3) The thin film thickness measurement network model generation method of the present invention builds a neural network consisting of two convolution activation layers, two pooling layers, one flattening layer and one fully connected layer. By optimizing the parameters and training of the neural network, after 20 iterations, the classification accuracy of the neural network can reach 99%.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明的实施例的薄膜厚度测量装置的组成示意图。FIG. 1 is a schematic diagram showing the composition of a thin film thickness measuring device according to an embodiment of the present invention.
图2为本发明的实施例的薄膜厚度测量装置的控制柜的剖面示意图。FIG. 2 is a schematic cross-sectional view of a control cabinet of a film thickness measuring device according to an embodiment of the present invention.
图3为本发明的实施例的薄膜厚度测量网络模型的流程图。FIG. 3 is a flow chart of a network model for measuring film thickness according to an embodiment of the present invention.
图4为本发明的实施例的光谱生成过程的原理图。FIG. 4 is a schematic diagram of a spectrum generation process according to an embodiment of the present invention.
图5为本发明的实施例获取得到的薄膜和基底折射率随波长变化的反射率拟合函数。FIG. 5 is a reflectivity fitting function of the refractive index of the film and substrate obtained according to an embodiment of the present invention as a function of wavelength.
图6为本发明的实施例中,引入噪声前后的理论反射率光谱。FIG. 6 is a theoretical reflectivity spectrum before and after the introduction of noise in an embodiment of the present invention.
图7为本发明的实施例的卷积神经网络模型的示意图。FIG7 is a schematic diagram of a convolutional neural network model according to an embodiment of the present invention.
图8为本发明的实施例中,训练集和测试集的损失值变化。FIG8 shows the change in loss values of the training set and the test set in an embodiment of the present invention.
图9为本发明的实施例的薄膜厚度测量方法的流程图。FIG. 9 is a flow chart of a method for measuring film thickness according to an embodiment of the present invention.
图10为本发明的实施例中,实际光谱与预测光谱的对比图。FIG. 10 is a comparison diagram of an actual spectrum and a predicted spectrum in an embodiment of the present invention.
具体实施方式DETAILED DESCRIPTION
下面结合实施例,对本发明作进一步地详细说明,但本发明的实施方式不限于此。The present invention will be further described in detail below in conjunction with the examples, but the embodiments of the present invention are not limited thereto.
实施例Example
请参见图1和图2,本发明的其中一个实施例提供了一种薄膜厚度测量装置,包括数据处理单元、光路单元和样品单元。Please refer to FIG. 1 and FIG. 2 , one embodiment of the present invention provides a thin film thickness measuring device, including a data processing unit, an optical path unit and a sample unit.
所述数据处理单元包括微型计算机2;所述样品单元包括样品放置台3、平台移动电机4和调节旋钮5,所述平台移动电机4用于驱动样品放置台3在二维平面上移动;调节旋钮5用于调节样品放置台3与水平面的角度,使调节样品放置台3水平放置。所述光路单元包括卤钨灯光源6、光纤探头7、第一光纤8、光谱仪1和第二光纤9;所述卤钨灯光源6通过第一光纤8与光纤探头7连接,所述光纤探头7通过第二光纤9与光谱仪1连接;所述光纤探头7位于所述样品放置台3的上方。其中,卤钨灯光源6、光谱仪1和微型计算机2位于控制柜10内。控制柜10设有与微型计算机2连接的显示屏和控制按钮。卤钨灯光源6设有用于调节卤钨灯光源的光强大小的光源调节旋钮。The data processing unit includes a microcomputer 2; the sample unit includes a sample placement table 3, a platform moving motor 4 and an adjustment knob 5, wherein the platform moving motor 4 is used to drive the sample placement table 3 to move on a two-dimensional plane; the adjustment knob 5 is used to adjust the angle between the sample placement table 3 and the horizontal plane, so that the sample placement table 3 is adjusted to be placed horizontally. The optical path unit includes a halogen tungsten lamp light source 6, an optical fiber probe 7, a first optical fiber 8, a spectrometer 1 and a second optical fiber 9; the halogen tungsten lamp light source 6 is connected to the optical fiber probe 7 through the first optical fiber 8, and the optical fiber probe 7 is connected to the spectrometer 1 through the second optical fiber 9; the optical fiber probe 7 is located above the sample placement table 3. The halogen tungsten lamp light source 6, the spectrometer 1 and the microcomputer 2 are located in a control cabinet 10. The control cabinet 10 is provided with a display screen and control buttons connected to the microcomputer 2. The halogen tungsten lamp light source 6 is provided with a light source adjustment knob for adjusting the light intensity of the halogen tungsten lamp light source.
上述实施例中,薄膜厚度测量装置在对薄膜进行测量时,所述卤钨灯光源的出射光经第一光纤输出到光纤探头,入射到薄膜内并在薄膜的上下界面发生多光束干涉,携带薄膜厚度信息的反射光被光纤探头接收,并经第二光纤传输到光谱仪,光谱仪采集反射光谱数据,经数据处理单元分析处理后,输出薄膜厚度的测量结果。In the above embodiment, when the film thickness measuring device measures the film, the outgoing light of the halogen tungsten lamp light source is output to the fiber optic probe via the first optical fiber, incident on the film and causing multi-beam interference at the upper and lower interfaces of the film, and the reflected light carrying the film thickness information is received by the fiber optic probe and transmitted to the spectrometer via the second optical fiber. The spectrometer collects the reflected spectrum data, and after being analyzed and processed by the data processing unit, outputs the measurement result of the film thickness.
在本发明的一个实施例中,微型计算机中内置有薄膜厚度测量网络模型,薄膜厚度测量网络模型由Python编写,训练、验证完成后导入到微型计算机中。In one embodiment of the present invention, a film thickness measurement network model is built into a microcomputer. The film thickness measurement network model is written in Python and is imported into the microcomputer after training and verification.
请参见图3,在本发明的一个实施例中,薄膜厚度测量网络模型生成方法如下:Referring to FIG. 3 , in one embodiment of the present invention, a method for generating a film thickness measurement network model is as follows:
S11数据集生成:S11 dataset generation:
S111根据薄膜和基底的材料的折射率,通过数学分析软件的多项式非线性拟合获取薄膜和基底折射率随波长变化的反射率拟合函数;S111 obtains the reflectivity fitting function of the refractive index of the film and the substrate as it changes with the wavelength through polynomial nonlinear fitting of mathematical analysis software according to the refractive index of the film and the substrate;
S112选取消光系数接近零的波段,根据该波段的薄膜和基底折射率的随波长变化的反射率拟合函数,及设置的薄膜厚度训练步长,采用光谱生成模块生成厚度位于500nm-10μm之间的薄膜理论反射率光谱;S112 selects a wavelength band with a light coefficient close to zero, and uses a spectrum generation module to generate a theoretical reflectivity spectrum of a film with a thickness between 500 nm and 10 μm according to a reflectivity fitting function of the film and substrate refractive index in the wavelength band and a set film thickness training step;
S113采用Python内置函数,在薄膜理论反射率光谱中引入正态分布噪声,生成多个样本,将多个样本划分为训练集和验证集;S113 uses Python built-in functions to introduce normal distribution noise into the theoretical reflectance spectrum of thin films, generate multiple samples, and divide the multiple samples into training sets and validation sets;
S114改变薄膜和基底的材料,重复步骤S111~S113,得到不同材料的薄膜和基底的数据集;S114 changes the materials of the film and the substrate, repeats steps S111 to S113, and obtains data sets of films and substrates of different materials;
S12卷积神经网络模型搭建:S12 convolutional neural network model construction:
在其中一个实施例中,所述卷积神经网络模型包括依次连接的第一卷积激活层、第一池化层、第二卷积激活层、第二池化层、展开层和全连接层;所述第一卷积激活层包括第一一维卷积运算模块和第一非线性激活函数模块;所述第二卷积激活层包括第二一维卷积运算模块和第二非线性激活函数模块;所述卷积神经网络模型以薄膜的反射率光谱作为输入,薄膜的厚度作为输出;In one embodiment, the convolutional neural network model includes a first convolutional activation layer, a first pooling layer, a second convolutional activation layer, a second pooling layer, an expansion layer and a fully connected layer connected in sequence; the first convolutional activation layer includes a first one-dimensional convolution operation module and a first nonlinear activation function module; the second convolutional activation layer includes a second one-dimensional convolution operation module and a second nonlinear activation function module; the convolutional neural network model uses the reflectance spectrum of the film as input and the thickness of the film as output;
S13卷积神经网络模型训练;S13 convolutional neural network model training;
S14卷积神经网络模型验证。S14 Convolutional neural network model verification.
上述实施例中,光谱生成模块的原理如下:In the above embodiment, the principle of the spectrum generation module is as follows:
如图4所示,在平板内光的入射角为θ0,此时相继两束光的光程差为D=2n1dcosθ0。若在正入射的情况下θ0=0,则对应的位相差其中n1d是薄膜的光学厚度,λ为光在真空中的波长。此时据菲涅尔公式可知在薄膜上下表面上的反射系数分别是:As shown in FIG4 , the incident angle of the light in the plate is θ 0 , and the optical path difference between the two consecutive light beams is D = 2n 1 dcosθ 0 . If θ 0 = 0 in the case of normal incidence, the corresponding phase difference is Where n 1 d is the optical thickness of the film, and λ is the wavelength of light in a vacuum. According to the Fresnel formula, the reflection coefficients on the upper and lower surfaces of the film are:
第一级反射光束和其它级次反射光束可分别描述为:The first order reflected beam and other order reflected beams can be described as:
由此可得反射光的合强度为:The total intensity of the reflected light can be obtained as follows:
故可将薄膜反射率表达为:Therefore, the film reflectivity can be expressed as:
可见,在此反射率生成模型中有两个未知量,分别是光的波长和膜的厚度。It can be seen that there are two unknown quantities in this reflectivity generation model, namely the wavelength of light and the thickness of the film.
在本发明的一个实施例中,以硅基底与Pi膜为例,薄膜厚度测量网络模型生成过程中具体设置如下:In one embodiment of the present invention, taking a silicon substrate and a Pi film as an example, the specific settings in the process of generating a film thickness measurement network model are as follows:
数据集生成:在获取薄膜和基底折射率随波长变化的反射率拟合函数后(如图5所示),选择消光系数接近为零(如小于0.05)的部分,即600-800nm波段,生成厚度在500nm-10μm之间、间隔为50nm薄膜理论反射率光谱,在据Python内置函数引入正态分布噪声后作为模型训练集,引入噪声前后的理论反射率光谱分别如图6中的(a)和(b)所示。共计190个膜厚标签,每个标签下有30个训练样本,20个测试样本,训练集和测试集共计有9500个样本导入模型进行训练和验证。Dataset generation: After obtaining the reflectivity fitting function of the refractive index of the film and substrate with wavelength (as shown in Figure 5), select the part with extinction coefficient close to zero (such as less than 0.05), that is, the 600-800nm band, and generate the theoretical reflectivity spectrum of the film with thickness between 500nm-10μm and interval of 50nm. After introducing normal distribution noise according to Python built-in function, it is used as the model training set. The theoretical reflectivity spectra before and after the introduction of noise are shown in (a) and (b) in Figure 6 respectively. There are a total of 190 film thickness labels, each label has 30 training samples and 20 test samples. A total of 9500 samples in the training set and test set are imported into the model for training and verification.
卷积神经网络模型搭建:图7中示出其卷积神经网络模型构成及设置,卷积神经网络模型由两层卷积激活层(Conv and ReLU)、两层池化层(Pooling)、一层展平层(Reshaping)和一层全连接层(FC)构成,输入设置为50个200×1的矩阵,第一次卷积运算设置64个卷积核,第二次卷积运算设置128个卷积核,完成卷积运算后进行展平,获得一个6400×1的矩阵,最后全连接至190个膜厚标签。据多次实践证明,卷积核设为3×1,步幅设为1,padding设为1,池化核设为3×1,步幅设为2,能在最小的迭代次数中获取最好的分类效果。Convolutional neural network model construction: Figure 7 shows the composition and settings of the convolutional neural network model. The convolutional neural network model consists of two layers of convolution activation layers (Conv and ReLU), two layers of pooling layers (Pooling), one flattening layer (Reshaping) and one fully connected layer (FC). The input is set to 50 200×1 matrices. The first convolution operation sets 64 convolution kernels, and the second convolution operation sets 128 convolution kernels. After the convolution operation is completed, it is flattened to obtain a 6400×1 matrix, and finally fully connected to 190 film thickness labels. According to many practices, the convolution kernel is set to 3×1, the stride is set to 1, the padding is set to 1, the pooling kernel is set to 3×1, and the stride is set to 2, which can obtain the best classification effect with the minimum number of iterations.
卷积神经网络模型训练:采用Adam优化方式,以0.005为学习率。若在多个迭代周期内,损失值下降则学习率下降10%,确保模型高效迫近于最优解。以交叉熵作为损失函数,将模型进行20次迭代后,训练集和测试集的损失值均得到了显著的下降(如图8所示)。分类理论光谱数据的正确率达到了99%,充分证明了模型对不同膜厚光谱数据的分类能力。Convolutional neural network model training: Adopt Adam optimization method, with a learning rate of 0.005. If the loss value decreases within multiple iterations, the learning rate decreases by 10% to ensure that the model is efficient and close to the optimal solution. Using cross entropy as the loss function, after 20 iterations of the model, the loss values of both the training set and the test set have been significantly reduced (as shown in Figure 8). The accuracy of the classification of theoretical spectral data reached 99%, which fully demonstrated the model's ability to classify spectral data of different film thicknesses.
在训练好薄膜厚度测量网络模型后,进行薄膜厚度测量,具体步骤如下(如图9所示):After training the film thickness measurement network model, the film thickness measurement is performed. The specific steps are as follows (as shown in Figure 9):
S1使用标准样品对所述薄膜厚度测量装置进行校准;S1 calibrates the film thickness measuring device using a standard sample;
S2对待测样品的基底和样品的材料种类进行选择;S2 selects the substrate of the sample to be tested and the material type of the sample;
S3将待测样品的基底放在样品放置台上,并通过控制平台移动电机使其位于在光纤探头正下方,检测基底的反射亮光场光谱和反射暗光场光谱;S3 places the substrate of the sample to be tested on the sample placement table, and controls the platform to move the motor so that it is located directly below the optical fiber probe, and detects the reflected bright light field spectrum and reflected dark light field spectrum of the substrate;
S4将附着有待测薄膜的基底放置在样品放置台上,并通过控制平台移动电机使其位于在光纤探头正下方,将检测到的反射光谱减去基底的反射亮光场光谱和基底的反射暗光场光谱之差,得到薄膜的反射光谱;S4 places the substrate with the film to be tested on the sample placement table, and controls the platform moving motor to make it directly below the optical fiber probe, and subtracts the difference between the reflected bright light field spectrum of the substrate and the reflected dark light field spectrum of the substrate from the detected reflection spectrum to obtain the reflection spectrum of the film;
S5完成薄膜的反射光谱的采集后,微型计算机自动对薄膜的反射光谱进行分析,输出薄膜厚度的测量结果;After S5 completes the acquisition of the reflection spectrum of the film, the microcomputer automatically analyzes the reflection spectrum of the film and outputs the measurement result of the film thickness;
S6控制平台移动电机,改变样品放置台的位置,实现对薄膜厚度的多点测量。S6 controls the platform movement motor to change the position of the sample placement table to achieve multi-point measurement of film thickness.
本发明的实施例还进行以下验证:一是将预测理论光谱数据值和实际光谱数据对比;二是利用台阶仪测量实际膜厚并与本发明的预测值进行比较。The embodiments of the present invention also carry out the following verifications: first, the predicted theoretical spectrum data value is compared with the actual spectrum data; second, the actual film thickness is measured using a step profiler and compared with the predicted value of the present invention.
验证一:Verification 1:
对薄膜样品(以硅基底与Pi膜为例),通过上述的步骤S1~S4进行测量,测量过程中采样点为四个,得到实际光谱数据;将实际光谱与理论光谱(通过S111~S112步骤生成)进行比较,结果如图10中(a)~(d)所示。由图10可知,在600-800nm范围,实际光谱与预测光谱基本吻合。在折射率不变的情况下,其膜的厚度取决于反射率光谱峰间距大小。The thin film sample (taking silicon substrate and Pi film as examples) is measured through the above steps S1 to S4, with four sampling points in the measurement process, and the actual spectrum data is obtained; the actual spectrum is compared with the theoretical spectrum (generated by steps S111 to S112), and the results are shown in (a) to (d) in Figure 10. As shown in Figure 10, in the range of 600-800nm, the actual spectrum is basically consistent with the predicted spectrum. When the refractive index remains unchanged, the thickness of the film depends on the size of the peak spacing of the reflectivity spectrum.
验证二:Verification 2:
使用美国Ambios科技公司XP-200台阶仪作为膜厚验证仪器,该台阶仪参数如下:载片台直径尺寸:6英寸;扫描长度:50μm到55mm;垂直测量范围:524μm;三维扫描功能模块:含测量软件、彩色可变焦摄像头、精密隔振平台和微米标准校准模块。The XP-200 step profiler from Ambios Technology Company of the United States was used as the film thickness verification instrument. The parameters of the step profiler are as follows: stage diameter: 6 inches; scanning length: 50μm to 55mm; vertical measurement range: 524μm; 3D scanning function module: including measurement software, color zoom camera, precision vibration isolation platform and micron standard calibration module.
首先采用本实施例的薄膜厚度测量网络模型预测薄膜样品(以硅基底与Pi膜为例)上四个采样点的厚度,然后在采样点的位置采用台阶仪测量法分别测量三次薄膜表面与基底表面的垂直距离,取平均数,计算四点膜厚,验证本发明的测量结果的准确度,结果如表1所示。First, the film thickness measurement network model of this embodiment is used to predict the thickness of four sampling points on the film sample (taking silicon substrate and Pi film as examples). Then, the vertical distance between the film surface and the substrate surface is measured three times at the sampling point using the step meter measurement method. The average is taken to calculate the film thickness at the four points to verify the accuracy of the measurement results of the present invention. The results are shown in Table 1.
表1数据显示,误差1.1~3.6%之间,证明本发明具备良好的膜厚测量水平,有很高的可靠性和重复性。The data in Table 1 show that the error is between 1.1% and 3.6%, which proves that the present invention has a good film thickness measurement level and has high reliability and repeatability.
表1样品数据统计Table 1 Sample data statistics
上述实施例为本发明较佳的实施方式,但本发明的实施方式并不受所述实施例的限制,其他的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化,均应为等效的置换方式,都包含在本发明的保护范围之内。The above embodiments are preferred implementation modes of the present invention, but the implementation modes of the present invention are not limited to the embodiments. Any other changes, modifications, substitutions, combinations, and simplifications made without departing from the spirit and principles of the present invention shall be equivalent replacement modes and shall be included in the protection scope of the present invention.
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CN120008492A (en) * | 2025-04-21 | 2025-05-16 | 中国测试技术研究院 | A fast demodulation system and method for thin film reflection signal based on neural network |
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CN119085508A (en) * | 2024-11-07 | 2024-12-06 | 中国计量大学 | Thickness measurement and composition identification method of co-extruded composite films based on infrared spectroscopy |
CN120008492A (en) * | 2025-04-21 | 2025-05-16 | 中国测试技术研究院 | A fast demodulation system and method for thin film reflection signal based on neural network |
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