CN118320360A - Easily-decomposed high-performance fire extinguishing coolant for aerosol fire extinguishing agent - Google Patents

Easily-decomposed high-performance fire extinguishing coolant for aerosol fire extinguishing agent Download PDF

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Publication number
CN118320360A
CN118320360A CN202410237095.2A CN202410237095A CN118320360A CN 118320360 A CN118320360 A CN 118320360A CN 202410237095 A CN202410237095 A CN 202410237095A CN 118320360 A CN118320360 A CN 118320360A
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China
Prior art keywords
coolant
potassium
fire extinguishing
extinguishing
aerosol
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Pending
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CN202410237095.2A
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Chinese (zh)
Inventor
黄瑞
卢发贵
刘心宇
邹蓓蓓
付巧宇
王祺
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Hubei Jiandun Fire Technology Co Ltd
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Hubei Jiandun Fire Technology Co Ltd
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Priority to CN202410237095.2A priority Critical patent/CN118320360A/en
Publication of CN118320360A publication Critical patent/CN118320360A/en
Pending legal-status Critical Current

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Abstract

The invention develops a novel coolant by taking the organic acid potassium salt and the forming auxiliary agent as raw materials, and compared with the traditional chemical coolant and physical coolant, the novel coolant has obviously improved fire extinguishing capability and electrical insulation property when being used in combination with aerosol, the fire extinguishing capability is increased from 65g/M 3-100 g/m3 to 35g/M 3-47 g/m3, and the electrical insulation property is increased from 0MΩ -20M Ω to 200MΩ -2200M Ω.

Description

Easily-decomposed high-performance fire extinguishing coolant for aerosol fire extinguishing agent
Technical Field
The invention belongs to the technical field of fire extinguishment, and particularly relates to an easily-decomposable high-performance fire extinguishing coolant for an aerosol fire extinguishing agent.
Background
When the aerosol fire extinguishing agent is sprayed, intense high-temperature impact flame is generated, in order to ensure the safe use of the aerosol fire extinguishing device or the fire extinguisher, the cooling is realized by adopting a mode of externally adding a cooling agent, and when the aerosol fire extinguishing agent is sprayed, the flame-extinguishing cooling is mainly realized by adopting a physical flame-extinguishing cooling or chemical flame-extinguishing cooling method. When the physical cooling agent such as ceramic balls is adopted, although the flame-extinguishing cooling effect is better, the ceramic balls have very high adsorption effect on the sprayed aerosol, so that the fire extinguishing capability of the aerosol is greatly weakened, while the chemical cooling agent used at present has the main effect of flame-extinguishing cooling, although the influence on the weakening of the fire extinguishing capability of the aerosol is smaller than that of the physical cooling agent such as the ceramic balls, the fire extinguishing capability of the aerosol is weakened as a whole, the main reason is that the cooling agent is firstly melted at high temperature and then decomposed under the continuous effect of high temperature, a large amount of residues are generated, and the melted residues have a blocking effect on the released aerosol fire extinguishing agent, so that the fire extinguishing capability is reduced. In addition, the current coolant plays a role in flame-out cooling or improving electrical insulation, and two parameters cannot be simultaneously considered.
According to the invention, the potassium salt of the organic acid is adopted as the coolant of the aerosol fire extinguishing agent, so that the decomposition efficiency of the coolant is greatly improved compared with an inorganic salt formula, the heat released by spraying the aerosol fire extinguishing agent is fully absorbed, the spraying temperature of a product is effectively reduced, fire extinguishing particles are fully released, the fire extinguishing capability of the product is greatly improved, and the organic particles generated by decomposition have the characteristic of weak hygroscopicity, so that the electrical insulation of sprayed objects is effectively improved.
Disclosure of Invention
The invention provides an easily-decomposable high-performance fire extinguishing coolant for an aerosol fire extinguishing agent, which comprises the following components in parts by mass: 90-100 parts of organic acid potassium salt and 1-10 parts of forming auxiliary agent.
The organic acid potassium salt is two or more of potassium hydrogen tartrate, potassium formate, potassium cinnamate, potassium benzoate, potassium methylmalonate, potassium ethyloxalate, potassium lactate, potassium ethylmalonate and potassium hydroxycitrate.
The forming auxiliary agent is any one of hydroxypropyl methyl cellulose, ethyl cellulose, polyvinyl alcohol, phenolic resin, urea-formaldehyde resin, melamine formaldehyde resin, polyurethane, epoxy resin and carboxymethyl cellulose.
The invention also relates to a preparation method of the easily-decomposable high-performance fire extinguishing coolant for the aerosol fire extinguishing agent, which comprises the following steps of:
S1, uniformly mixing organic acid potassium salt and a forming auxiliary agent;
s2, adding a solvent into the S1 and uniformly mixing;
S3, granulating, drying and tabletting the material obtained in the step S2 to obtain the coolant tablet with the thickness of 6mm multiplied by 6 mm.
And S1, mixing time is 5 min-20 min.
S2, the solvent is one or more of water or ethanol; the mass of the solvent added is 5% -30% of the material obtained in the step S1.
And S2, mixing time is 2 min-10 min.
And S3, the granulating size is 10-30 meshes.
And S3, the drying temperature is 40-70 ℃ and the drying time is 6-48 h.
The invention has the following beneficial effects:
(1) By introducing organic potassium salt containing fire-extinguishing elements, the coolant is decomposed under the action of aerosol generating agent to generate K-fire-extinguishing free radicals, so that the fire-extinguishing capability of the fire-extinguishing device or fire extinguisher is further improved.
(2) The heat released by the combustion of the aerosol generating agent is absorbed when the coolant is decomposed, so that the temperature of the aerosol extinguishing agent during spraying is effectively reduced.
(3) According to the invention, the full organic component is selected, and after the cooling agent is decomposed and settled, the cooling agent still exists in the form of small molecular organic salt, so that the hygroscopicity of aerosol products potassium bicarbonate, potassium carbonate and potassium hydroxide is reduced, the electrical insulation of the settled matters is effectively improved, and the application scene is widened.
Detailed Description
Embodiments of the present invention will be described in detail below with reference to examples, but it will be understood by those skilled in the art that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention.
The organic acid potassium salt is two or more of potassium hydrogen tartrate, potassium formate, potassium cinnamate, potassium benzoate, potassium methylmalonate, potassium ethyloxalate, potassium lactate, potassium ethylmalonate and potassium hydroxycitrate.
The forming auxiliary agent is any one of hydroxypropyl methyl cellulose, ethyl cellulose, polyvinyl alcohol, phenolic resin, urea-formaldehyde resin, melamine formaldehyde resin, polyurethane, epoxy resin and carboxymethyl cellulose.
Example 1
70 Parts of potassium cinnamate, 20 parts of potassium methylmalonate, 10 parts of potassium ethylmalonate and 5 parts of polyvinyl alcohol.
Weighing the components according to the proportion, mixing for 15min in a mixer, then adding water accounting for 10% of the total mass of the materials as a solvent, mixing for 5min, granulating into 20-mesh granules by a granulator after the mixing, drying for 6-48 h in a drying room at 40-70 ℃, and then tabletting to form the coolant tablet with the mass of 6mm multiplied by 6 mm.
70G of coolant and 35g K type aerosol grain are assembled in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Example 2
60 Parts of potassium hydroxycitrate, 30 parts of potassium cinnamate, 10 parts of potassium methylmalonate and 5 parts of phenolic resin.
Weighing the components according to the proportion, mixing for 20-30 min in a mixer, then adding ethanol as a solvent, continuously mixing for 4-7 min, granulating into 20-mesh granules by a granulator after the mixing, drying for 48-72 h in a drying room at 40-60 ℃, and then tabletting to form 6X 6mm tablets.
70G of coolant and 43g K type aerosol grain are assembled in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Example 3
50 Parts of potassium ethyl malonate, 40 parts of potassium ethyl oxalate, 10 parts of potassium methyl malonate and 5 parts of hydroxypropyl methyl cellulose.
Weighing the components according to the proportion, mixing for 20-30 min in a mixer, then adding water as a solvent, continuously mixing for 4-7 min, granulating into 20-mesh granules by a granulator after the mixing, drying for 48-72 h in a drying room at 40-60 ℃, and then tabletting to form tablets with the size of 6 multiplied by 6 mm.
70G of coolant and 45g K type aerosol grain are assembled in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Example 4
50 Parts of potassium methylmalonate, 40 parts of potassium hydroxycitrate, 10 parts of potassium ethyloxalate and 5 parts of hydroxypropyl methyl cellulose.
Weighing the components according to the proportion, mixing for 20-30 min in a mixer, then adding water as a solvent, continuously mixing for 4-7 min, granulating into 20-mesh granules by a granulator after the mixing, drying for 48-72 h in a drying room at 40-60 ℃, and then tabletting to form tablets with the size of 6 multiplied by 6 mm.
70G of coolant and 43g K type aerosol grain are assembled in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Example 5
50 Parts of potassium cinnamate, 40 parts of potassium formate, 10 parts of potassium methylmalonate and 5 parts of hydroxypropyl methyl cellulose.
Weighing the components according to the proportion, mixing for 20-30 min in a mixer, then adding water as a solvent, continuously mixing for 4-7 min, granulating into 20-mesh granules by a granulator after the mixing, drying for 48-72 h in a drying room at 40-60 ℃, and then tabletting to form tablets with the size of 6 multiplied by 6 mm.
70G of coolant and 47g K type aerosol grain are assembled in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Example 6
50 Parts of potassium lactate, 40 parts of potassium ethyloxalate, 10 parts of potassium methylmalonate and 5 parts of hydroxypropyl methyl cellulose.
Weighing the components according to the proportion, mixing for 20-30 min in a mixer, then adding water as a solvent, continuously mixing for 4-7 min, granulating into 20-mesh granules by a granulator after the mixing, drying for 48-72 h in a drying room at 40-60 ℃, and then tabletting to form tablets with the size of 6 multiplied by 6 mm.
70G of coolant and 42g K type aerosol grain are assembled in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Comparative example 1
70G of aluminosilicate ceramic balls with the diameter of 6mm are assembled, and 100g K type aerosol grains are arranged in a fire extinguishing device, and fire extinguishing test and sediment electrical insulation test are carried out according to XF499.1-2010 standard.
Comparative example 2
70G of the existing L2 coolant with the thickness of 6mm multiplied by 6mm is assembled, and a 65g K type aerosol grain is arranged in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Comparative example 3
60 Parts of potassium benzoate, 20 parts of monopotassium phosphate, 20 parts of potassium bicarbonate and 5 parts of polyvinyl alcohol.
Weighing the components according to the proportion, mixing for 20-30 min in a mixer, then adding water as a solvent, continuously mixing for 4-7 min, granulating into 20-mesh granules by a granulator after the mixing, drying for 48-72 h in a drying room at 40-60 ℃, and then tabletting to form tablets with the size of 6 multiplied by 6 mm.
70G of coolant and 70g K type aerosol grain are assembled in a fire extinguishing device, and fire extinguishing test and sediment electric insulation test are carried out according to XF499.1-2010 standard.
Characterization data and effect data for the products obtained in the above examples and comparative examples are shown in table 1 below.
TABLE 1 characterization data for fire extinguishing Performance of different formulations of coolants
When the novel coolant prepared by the invention is used in combination with aerosol, compared with the traditional chemical coolant and physical coolant, the fire extinguishing capability and the electrical insulation property are obviously improved, the fire extinguishing capability is increased from 65-100g/M 3 to 35-47g/M 3, and the electrical insulation property is increased from 0-20MΩ to 200-2200MΩ.

Claims (9)

1. The easily-decomposable high-performance fire extinguishing coolant for the aerosol fire extinguishing agent is characterized by comprising the following components in parts by mass:
90-100 parts of organic acid potassium salt and 1-10 parts of forming auxiliary agent.
2. The easily decomposable high-performance fire extinguishing coolant for aerosol fire extinguishing agent according to claim 1, wherein the organic acid potassium salt is two or more of potassium hydrogen tartrate, potassium formate, potassium cinnamate, potassium benzoate, potassium methylmalonate, potassium ethyloxalate, potassium lactate, potassium ethylmalonate, and potassium hydroxycitrate.
3. The easily decomposable high-performance fire-extinguishing coolant for aerosol fire-extinguishing agent according to claim 1, wherein the forming aid is any one of hydroxypropyl methyl cellulose, ethyl cellulose, polyvinyl alcohol, phenolic resin, urea-formaldehyde resin, melamine formaldehyde resin, polyurethane, epoxy resin and carboxymethyl cellulose.
4. The preparation method of the easily-decomposable high-performance fire extinguishing coolant for the aerosol fire extinguishing agent is characterized by comprising the following steps of:
S1, uniformly mixing organic acid potassium salt and a forming auxiliary agent;
s2, adding a solvent into the S1 and uniformly mixing;
s3, granulating, drying, tabletting and forming the material obtained in the step S2 to obtain the coolant tablet.
5. The method for preparing the easily-decomposable high-performance fire-extinguishing coolant for the aerosol fire-extinguishing agent according to claim 4, wherein the mixing time of S1 is 5-20 min.
6. The method for preparing the easily decomposable high-performance fire extinguishing coolant for aerosol fire extinguishing agents according to claim 4, wherein the solvent in S2 is one or more of water or ethanol; the mass of the solvent added is 5% -30% of the material obtained in the step S1.
7. The method for preparing the easily-decomposable high-performance fire-extinguishing coolant for the aerosol fire-extinguishing agent according to claim 4, wherein the mixing time of S2 is 2 min-10 min.
8. The method for preparing the easily-decomposable high-performance fire-extinguishing coolant for aerosol fire extinguishing agent according to claim 4, wherein,
And S3, the granulating size is 10-30 meshes.
9. The method for preparing the easily-decomposable high-performance fire-extinguishing coolant for the aerosol fire-extinguishing agent according to claim 4, wherein the drying temperature is 40-70 ℃ and the drying time is 6-48 h.
CN202410237095.2A 2024-03-01 2024-03-01 Easily-decomposed high-performance fire extinguishing coolant for aerosol fire extinguishing agent Pending CN118320360A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202410237095.2A CN118320360A (en) 2024-03-01 2024-03-01 Easily-decomposed high-performance fire extinguishing coolant for aerosol fire extinguishing agent

Publications (1)

Publication Number Publication Date
CN118320360A true CN118320360A (en) 2024-07-12

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