CN118291081A - Anti-counterfeiting glue and anti-counterfeiting detection method thereof - Google Patents
Anti-counterfeiting glue and anti-counterfeiting detection method thereof Download PDFInfo
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- CN118291081A CN118291081A CN202311725229.7A CN202311725229A CN118291081A CN 118291081 A CN118291081 A CN 118291081A CN 202311725229 A CN202311725229 A CN 202311725229A CN 118291081 A CN118291081 A CN 118291081A
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- glue
- counterfeiting
- fluorescent
- magnetic
- curing
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- 239000003292 glue Substances 0.000 title claims abstract description 158
- 238000001514 detection method Methods 0.000 title claims abstract description 14
- 239000002245 particle Substances 0.000 claims abstract description 62
- 230000005291 magnetic effect Effects 0.000 claims abstract description 43
- 230000005389 magnetism Effects 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 90
- 238000001723 curing Methods 0.000 claims description 68
- 239000000696 magnetic material Substances 0.000 claims description 31
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229920001109 fluorescent polymer Polymers 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims description 7
- 150000004706 metal oxides Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 239000002096 quantum dot Substances 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052735 hafnium Inorganic materials 0.000 claims description 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 4
- 238000000016 photochemical curing Methods 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910002518 CoFe2O4 Inorganic materials 0.000 claims description 3
- 229910017163 MnFe2O4 Inorganic materials 0.000 claims description 3
- 229910003264 NiFe2O4 Inorganic materials 0.000 claims description 3
- QJVKUMXDEUEQLH-UHFFFAOYSA-N [B].[Fe].[Nd] Chemical compound [B].[Fe].[Nd] QJVKUMXDEUEQLH-UHFFFAOYSA-N 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- KPLQYGBQNPPQGA-UHFFFAOYSA-N cobalt samarium Chemical compound [Co].[Sm] KPLQYGBQNPPQGA-UHFFFAOYSA-N 0.000 claims description 3
- 230000005294 ferromagnetic effect Effects 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 239000002064 nanoplatelet Substances 0.000 claims description 3
- 239000002073 nanorod Substances 0.000 claims description 3
- 229910001172 neodymium magnet Inorganic materials 0.000 claims description 3
- NQNBVCBUOCNRFZ-UHFFFAOYSA-N nickel ferrite Chemical compound [Ni]=O.O=[Fe]O[Fe]=O NQNBVCBUOCNRFZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000005298 paramagnetic effect Effects 0.000 claims description 3
- 229910000938 samarium–cobalt magnet Inorganic materials 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000178 monomer Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- -1 perylenetetracarboxylic imides Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000003848 UV Light-Curing Methods 0.000 description 3
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical class C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 description 3
- NJDNXYGOVLYJHP-UHFFFAOYSA-L disodium;2-(3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=CC(=O)C=C2OC2=CC([O-])=CC=C21 NJDNXYGOVLYJHP-UHFFFAOYSA-L 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 150000001629 stilbenes Chemical class 0.000 description 3
- 235000021286 stilbenes Nutrition 0.000 description 3
- 150000000183 1,3-benzoxazoles Chemical class 0.000 description 2
- YOPDNLMMBBVYOX-UHFFFAOYSA-N 2-carbamoylthiophene-3-carboxylic acid Chemical class NC(=O)C=1SC=CC=1C(O)=O YOPDNLMMBBVYOX-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 235000001671 coumarin Nutrition 0.000 description 2
- 150000004775 coumarins Chemical class 0.000 description 2
- 229940044631 ferric chloride hexahydrate Drugs 0.000 description 2
- 150000002219 fluoranthenes Chemical class 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 2
- 239000002159 nanocrystal Substances 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003557 thiazoles Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 150000003732 xanthenes Chemical class 0.000 description 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- FWBHETKCLVMNFS-UHFFFAOYSA-N 4',6-Diamino-2-phenylindol Chemical compound C1=CC(C(=N)N)=CC=C1C1=CC2=CC=C(C(N)=N)C=C2N1 FWBHETKCLVMNFS-UHFFFAOYSA-N 0.000 description 1
- PCGISRHGYLRXSR-UHFFFAOYSA-N 4-hydroxy-7-[(5-hydroxy-7-sulfonaphthalen-2-yl)carbamoylamino]naphthalene-2-sulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(NC(=O)NC=3C=C4C=C(C=C(C4=CC=3)O)S(O)(=O)=O)=CC=C21 PCGISRHGYLRXSR-UHFFFAOYSA-N 0.000 description 1
- 229910017115 AlSb Inorganic materials 0.000 description 1
- 229910004613 CdTe Inorganic materials 0.000 description 1
- 229910004611 CdZnTe Inorganic materials 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229910005542 GaSb Inorganic materials 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 229910004262 HgTe Inorganic materials 0.000 description 1
- 229910000673 Indium arsenide Inorganic materials 0.000 description 1
- 241000764773 Inna Species 0.000 description 1
- 229910000661 Mercury cadmium telluride Inorganic materials 0.000 description 1
- 229910007709 ZnTe Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001263 acyl chlorides Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- VYXSBFYARXAAKO-WTKGSRSZSA-N chembl402140 Chemical compound Cl.C1=2C=C(C)C(NCC)=CC=2OC2=C\C(=N/CC)C(C)=CC2=C1C1=CC=CC=C1C(=O)OCC VYXSBFYARXAAKO-WTKGSRSZSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- DIRCCMJPRSFUPX-UHFFFAOYSA-N copper 2,11,20,29,38,40-hexaza-37,39-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(36),2,4(9),5,7,10(40),11,13,15,17,19,21(38),22(27),23,25,28,30,32,34-nonadecaene-6,25-disulfonic acid Chemical compound [Cu++].OS(=O)(=O)c1ccc2c3nc(nc4[n-]c(nc5nc(nc6[n-]c(n3)c3ccccc63)c3ccc(cc53)S(O)(=O)=O)c3ccccc43)c2c1 DIRCCMJPRSFUPX-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- FWQHNLCNFPYBCA-UHFFFAOYSA-N fluoran Chemical compound C12=CC=CC=C2OC2=CC=CC=C2C11OC(=O)C2=CC=CC=C21 FWQHNLCNFPYBCA-UHFFFAOYSA-N 0.000 description 1
- MHMNJMPURVTYEJ-UHFFFAOYSA-N fluorescein-5-isothiocyanate Chemical compound O1C(=O)C2=CC(N=C=S)=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 MHMNJMPURVTYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000003278 haem Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WPYVAWXEWQSOGY-UHFFFAOYSA-N indium antimonide Chemical compound [Sb]#[In] WPYVAWXEWQSOGY-UHFFFAOYSA-N 0.000 description 1
- RPQDHPTXJYYUPQ-UHFFFAOYSA-N indium arsenide Chemical compound [In]#[As] RPQDHPTXJYYUPQ-UHFFFAOYSA-N 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- ZBKFYXZXZJPWNQ-UHFFFAOYSA-N isothiocyanate group Chemical group [N-]=C=S ZBKFYXZXZJPWNQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- MUSLHCJRTRQOSP-UHFFFAOYSA-N rhodamine 101 Chemical compound [O-]C(=O)C1=CC=CC=C1C(C1=CC=2CCCN3CCCC(C=23)=C1O1)=C2C1=C(CCC1)C3=[N+]1CCCC3=C2 MUSLHCJRTRQOSP-UHFFFAOYSA-N 0.000 description 1
- TUFFYSFVSYUHPA-UHFFFAOYSA-M rhodamine 123 Chemical compound [Cl-].COC(=O)C1=CC=CC=C1C1=C(C=CC(N)=C2)C2=[O+]C2=C1C=CC(N)=C2 TUFFYSFVSYUHPA-UHFFFAOYSA-M 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- IKEIGECHKXPQKT-UHFFFAOYSA-N silicon phthalocyanine dihydroxide Chemical compound N1=C(C2=CC=CC=C2C2=NC=3C4=CC=CC=C4C(=N4)N=3)N2[Si](O)(O)N2C4=C(C=CC=C3)C3=C2N=C2C3=CC=CC=C3C1=N2 IKEIGECHKXPQKT-UHFFFAOYSA-N 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical group ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Landscapes
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
Abstract
The invention relates to the technical field of glue detection and discloses anti-counterfeiting glue and an anti-counterfeiting detection method thereof. The anti-counterfeiting detection method of the glue comprises the process of detecting whether fluorescence and/or magnetism exists in the glue. When the glue contains anti-counterfeiting particles with fluorescence performance, only light irradiation is needed, fluorescence can be emitted from the glue, and therefore the glue with the same appearance is distinguished; similarly, when the glue contains magnetic anti-counterfeiting particles, only a magnetic field is needed to be applied to the glue to see whether the glue contains enriched particles, so that the glue with the same appearance can be distinguished; when the anti-counterfeiting particles in the glue have both fluorescence and magnetism, the glue with the same appearance can be distinguished by using the fluorescence effect and the magnetism enrichment effect.
Description
Technical Field
The invention belongs to the technical field of glue detection, and particularly relates to anti-counterfeiting glue and an anti-counterfeiting detection method thereof.
Background
Glue is an intermediate for connecting two materials, and is mostly available in water, belonging to the class of fine chemical industry and various types. According to the main component classification, there are mainly acrylic type, epoxy type, polysulfide type, polyurethane type, silica gel type, UV curing type, and the like glues.
At present, no matter what type of glue is on the market, the sources of the glue with the same color system (such as transparent glue) cannot be distinguished from the appearance, the authenticity cannot be distinguished, and the phenomena of stretching the articles of plum and confusing the market are easy to occur.
In view of this, the anti-counterfeiting glue and the anti-counterfeiting detection method thereof enable the public to easily distinguish glue with the same appearance, and avoid counterfeiting.
Disclosure of Invention
The invention aims to provide anti-counterfeiting glue and an anti-counterfeiting detection method thereof, so that the public can easily distinguish glue with the same appearance, and counterfeiting is avoided.
According to a first aspect of the invention, an anti-counterfeiting glue is provided, which is characterized by comprising a glue body and anti-counterfeiting particles dispersed in the glue body, wherein the anti-counterfeiting particles have fluorescence and/or magnetism. When the glue contains anti-counterfeiting particles with fluorescence performance, only light irradiation is needed, fluorescence can be emitted from the glue, and therefore the glue with the same appearance is distinguished; similarly, when the glue contains the anti-counterfeiting particles with magnetism, only a magnetic field is applied to the glue to see whether the glue contains enriched particles, so that the glue with the same appearance can be distinguished. When the anti-counterfeiting particles in the glue have fluorescence performance and magnetic performance, the glue with the same appearance can be distinguished by utilizing the fluorescence effect and the magnetic enrichment effect, and after the anti-counterfeiting particles have magnetism, the anti-counterfeiting particles can be enriched, so that the enriched anti-counterfeiting particles are convenient to remove from the glue, and the normal use of the glue is not affected completely. In order to be able to remove the security particles from the glue, the security particles preferably have a size of 100nm to 500nm.
As a preferable scheme of the anti-counterfeiting glue, the anti-counterfeiting particles comprise a fluorescent layer and/or a magnetic layer, and the fluorescent layer comprises a fluorescent material coated in a curing material; the magnetic layer comprises a magnetic material coated in a solidified material. The fluorescent material and/or the magnetic material are/is wrapped by the curing material, so that the failure caused by the influence of components in the glue on the fluorescent material or the magnetic material is avoided.
As a preferable scheme of the anti-counterfeiting glue, the anti-counterfeiting particles comprise a fluorescent layer, a magnetic layer and a fluorescent layer which are sequentially arranged. Namely, the anti-counterfeiting particles are of a sandwich structure, so that fluorescence can be generated when illumination is conducted on the glue from all angles.
As a preferable scheme of the anti-counterfeiting glue, the magnetic material is wrapped with an inorganic layer;
Preferably, the inorganic layer is selected from at least one of a silicon-containing oxide, an aluminum-containing oxide, a zirconium-containing oxide, a titanium-containing oxide, a hafnium-containing oxide, or an yttrium-containing oxide. The magnetic material carried by the inorganic layer can be stably dispersed in the solidified material, so that the magnetic material is prevented from leaking.
As a preferable scheme of the anti-counterfeiting glue, the fluorescent material comprises at least one of fluorescent nanoparticles, fluorescein, fluorescent polymer and organic fluorescent molecules;
preferably, the fluorescent nanoparticle comprises at least one of a carbon dot, a quantum dot, a nanorod, or a nanoplatelet.
As a preferable scheme of the anti-counterfeiting glue, the magnetic material comprises metal and metal oxide with superparamagnetism, paramagnetic or ferromagnetic properties;
Preferably, the magnetic material is selected from Fe3O4、Fe2O3、CoFe2O4、MnFe2O4、NiFe2O4、 compounds neodymium iron boron, samarium cobalt, metal Fe, co, ni and one of metal oxides of alloy Fe 2Co、Ni2 Fe.
As a preferable scheme of the anti-counterfeiting glue, the preparation method of the anti-counterfeiting particles comprises the following steps:
s1, mixing a fluorescent material with a curing material, and curing to form a fluorescent curing material; and/or
S2, mixing the magnetic material with a curing material, and curing to form a magnetic curing material;
s3, granulating the fluorescent curing material and/or the magnetic curing material;
Preferably, the curing material is a photo-curing glue or a thermosetting glue.
Photo-curable glues such as ultraviolet curing UV glue; heat curable glue such as heat curable epoxy.
As a preferable scheme of the anti-counterfeiting glue, a mixture of a magnetic material and a curing material is coated on the fluorescent curing material for curing;
preferably, after the magnetic curing material is formed on the fluorescent curing material, a mixture of the fluorescent material and the curing material is coated on the magnetic curing material and cured.
As a preferable scheme of the anti-counterfeiting glue, in the fluorescent curing material, the mass ratio of the fluorescent material to the curing material is (1-4): 5, a step of; in the magnetic curing material, the mass ratio of the magnetic material to the curing material is (1-3): 5. the inventor discovers that the glue has better fluorescence and/or magnetism effect through the design of the proportion.
The second aspect of the invention provides a glue anti-counterfeiting detection method, which is characterized in that: including a process of detecting the presence of fluorescence and/or magnetism in the glue.
Compared with the prior art, the invention has at least the following advantages:
1. When the glue contains anti-counterfeiting particles with fluorescence performance, only light irradiation is needed, fluorescence can be emitted from the glue, and therefore the glue with the same appearance is distinguished; similarly, when the glue contains magnetic anti-counterfeiting particles, only a magnetic field is needed to be applied to the glue to see whether the glue contains enriched particles, so that the glue with the same appearance can be distinguished; when the anti-counterfeiting particles in the glue have fluorescence performance and magnetic performance, the glue with the same appearance can be distinguished by utilizing the fluorescence effect and the magnetic enrichment effect, and after the anti-counterfeiting particles have magnetism, the anti-counterfeiting particles can be enriched, so that the enriched anti-counterfeiting particles are convenient to remove from the glue, and the normal use of the glue is not affected completely.
2. Aiming at the application environment of glue, the anti-counterfeiting particles are preferably in a sandwich structure, and the magnetic layer is wrapped between the two fluorescent layers, so that the influence of the glue on magnetism is avoided, and the enrichment of the anti-counterfeiting particles is not easy.
3. The fluorescent material is fixedly sealed in the photo-curing glue or the thermosetting glue, the nature of the curing material is the glue, and the glue to be anti-counterfeiting cannot be influenced as the environment property of the applied glue is similar.
4. The glue detection method is simple, and the authenticity and the source of the glue can be judged by judging whether anti-counterfeiting particles exist in the glue through fluorescence and/or magnetism.
Drawings
The foregoing and other features of the present disclosure will be more fully described when considered in conjunction with the following drawings. It is appreciated that these drawings depict only several embodiments of the present disclosure and are therefore not to be considered limiting of its scope. The present disclosure will be described more specifically and in detail by using the accompanying drawings.
FIG. 1 is an effect diagram of illumination of glue;
FIG. 2 is a graph showing the effect of applying a magnetic field to glue;
fig. 3 is a graph showing the effect of both illuminating the glue and applying a magnetic field to the glue.
Detailed Description
The following examples are described to aid in the understanding of the invention and are not, nor should they be construed in any way to limit the scope of the invention.
At least one of the "when preceding or following a list of elements" as for example "is described herein modifies the entire list of elements without modifying individual elements of the list. Unless otherwise defined, all terms (including technical and scientific terms) in the specification can be defined as commonly understood by one of ordinary skill in the art. Terms defined in commonly used dictionaries should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present disclosure and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein. Furthermore, unless expressly stated to the contrary, the words "comprise" and the words "comprising" when used in this specification mean the presence of stated features, regions, integers, steps, operations, elements, and/or components, but does not preclude the presence or addition of one or more other features, regions, integers, steps, operations, elements, components, and/or groups thereof. Accordingly, the above phraseology is to be understood as meaning to include the stated elements, but not to exclude any other elements.
As mentioned in the background art, no matter what type of glue is currently available in the market, the source of the glue with the same color system (such as transparent glue) cannot be distinguished from the appearance, and the authenticity cannot be distinguished, so that the situation that the market is confused due to the fact that the person wears the transparent glue is easy to occur.
In a first aspect of the present invention, an anti-counterfeiting glue is provided, which comprises a glue body and anti-counterfeiting particles dispersed in the glue body, wherein the anti-counterfeiting particles have fluorescence and/or magnetism. When the glue contains anti-counterfeiting particles with fluorescence performance, only light irradiation is needed, fluorescence can be emitted from the glue, and therefore the glue with the same appearance is distinguished; similarly, when the glue contains the anti-counterfeiting particles with magnetism, only a magnetic field is applied to the glue to see whether the glue contains enriched particles, so that the glue with the same appearance can be distinguished. When the anti-counterfeiting particles in the glue have fluorescence performance and magnetic performance, the glue with the same appearance can be distinguished by utilizing the fluorescence effect and the magnetic enrichment effect, and after the anti-counterfeiting particles have magnetism, the anti-counterfeiting particles can be enriched, so that the enriched anti-counterfeiting particles are convenient to remove from the glue, and the normal use of the glue is not affected completely. In order to be able to remove the security particles from the glue, the security particles preferably have a size of 100nm to 500nm.
In some embodiments, the security particles comprise a fluorescent layer comprising a fluorescent material encapsulated in a cured material and/or a magnetic layer; the magnetic layer comprises a magnetic material coated in a solidified material. The fluorescent material and/or the magnetic material are/is wrapped by the curing material, so that the failure caused by the influence of components in the glue on the fluorescent material or the magnetic material is avoided.
As a preferable scheme of the anti-counterfeiting glue, the anti-counterfeiting particles comprise a fluorescent layer, a magnetic layer and a fluorescent layer which are sequentially arranged. Namely, the anti-counterfeiting particles are of a sandwich structure, so that fluorescence can be generated when illumination is conducted on the glue from all angles.
As a preferable scheme of the anti-counterfeiting glue, the magnetic material is wrapped with an inorganic layer;
Preferably, the inorganic layer is selected from at least one of a silicon-containing oxide, an aluminum-containing oxide, a zirconium-containing oxide, a titanium-containing oxide, a hafnium-containing oxide, or an yttrium-containing oxide. The magnetic material carried by the inorganic layer can be stably dispersed in the solidified material, so that the magnetic material is prevented from leaking. The inorganic material has good water and oxygen blocking performance, and the effect of the inorganic material is to protect the magnetic material and reduce damage to the magnetic material by the external environment, and the inorganic material comprises, but is not limited to, silicon-containing oxide, aluminum-containing oxide, zirconium-containing oxide, titanium-containing oxide, hafnium-containing oxide or yttrium-containing oxide, and the like, and particularly silicon dioxide, titanium dioxide and the like.
As a preferable scheme of the anti-counterfeiting glue, the fluorescent material comprises at least one of fluorescent nanoparticles, fluorescein, fluorescent polymer and organic fluorescent molecules;
preferably, the fluorescent nanoparticle comprises at least one of a carbon dot, a quantum dot, a nanorod, or a nanoplatelet. The quantum dot comprises at least one of group IIB-VIA, group IIIA-VA, group IVA-VIA, group IVA, group IB-IIIA-VIA, group VIII-VIA, perovskite material and carbon quantum dot. For example, the group II-VI compound can include ：CdSe、CdTe、ZnS、ZnSe、ZnTe、ZnO、HgS、HgSe、HgTe、MgSe、MgS、CdSeS、CdSeTe、CdSTe、ZnSeS、ZnSeTe、ZnSTe、HgSeS、HgSeTe、HgSTe、CdZnS、CdZnSe、CdZnTe、CdHgS、CdHgSe、CdHgTe、HgZnS、HgZnSe、HgZnTe、MgZnSe、MgZnS、HgZnTeS、CdZnSeS、CdZnSeTe、CdZnSTe、CdHgSeS、CdHgSeTe、CdHgSTe、HgZnSeS、HgZnSeTe、HgZnSTe or a combination thereof. The III-V compounds may include ：GaN、GaP、GaAs、GaSb、AlN、AlP、AlAs、AlSb、InN、InP、InAs、InSb、GaNP、GaNAs、GaNSb、GaPAs、GaPSb、AlNP、AlNAs、AlNSb、AlPAs、AlPSb、InNP、InNAs、InNSb、InPAs、InPSb、InZnP、GaAlNP、GaAlNAs、GaAlNSb、GaAlPAs、GaAlPSb、GaInNP、GaInNAs、GaInNSb、GaInPAs、GaInPSb、InAlNP、InAlNAs、InAlNSb、InAlPAs、InAlPSb or combinations thereof. Quantum dots include nanocrystals having a homogeneous or substantially homogeneous composition, e.g., a core, as well as heterogeneous nanocrystals, such as core/shell quantum dots comprising a core and one or more shells surrounding the core. A shell is defined as a material surrounding a core and may include one or more shell layers. The metal oxide includes: zn, cr, co, dy, er, eu, fe, gd, gd, pr, nd, ni, in, pr, sm, tb, tm, and combinations thereof. The fluorescent polymer has a functional group (such as fluorescein) capable of emitting fluorescence and monomers capable of polymerizing, and the monomers are polymerized or polymerized with other monomers which do not contain fluorescence, so that the fluorescent polymer is prepared. Fluorescein includes, but is not limited to, stilbenes, coumarins, fluorans (xanthenes), benzoxazoles (including imidazoles, thiazoles), naphthalimides, thiophenedicarboxylamides, polycyclic aromatic hydrocarbons (fluoranthenes), perylenetetracarboxylic imides, phycoerythrins, polymethylchlorophyll proteins, and the like; the fluorescent polymer has a fluorescent functional group in its structure, and common fluorescent groups include, but are not limited to, stilbenes, coumarins, fluorans (xanthenes), benzoxazoles (including imidazoles, thiazoles), naphthalimides, thiophenedicarboxylic amides, polycyclic aromatic hydrocarbons (fluoranthenes), perylenetetracarboxylic imides, and the like, and monomers for synthesizing a fluorescent polymer include: fluorescent polymers are prepared from fluorescein isothiocyanate, tetramethyl isothiocyanamine, heme, rhodamine B, 5 (6) -carboxyl tetramethyl rhodamine, rhodamine 6G, rhodamine 123, rhodamine 101, fluorescein, herste fluorescent dye, 4', 6-diamidino-2-phenylindole, copper phthalocyanine disulfonic acid, dihydroxysilicon phthalocyanine, scarlet acid and the like which have reactive groups such as amino groups, hydroxyl groups, mercapto groups, carboxyl groups, sulfonic acid groups, isothiocyanate groups, acyl chloride groups, sulfonyl chloride groups, epoxy groups and the like, and are polymerized or polymerized with other monomers which do not contain fluorescence. The organic fluorescent dye includes: fluorescein (stilbenes, coumarin, fluoran, benzoxazole, naphthalimide, thiophene dicarboxylic acid amide, polycyclic aromatic hydrocarbon, perylene tetracarboxylic imide, etc.), aromatic condensed ring compounds, intramolecular charge transfer compounds, metal complex fluorescent materials, enzymes, rare earth metal chelates.
In some embodiments, the magnetic material comprises a metal and a metal oxide having superparamagnetic, paramagnetic, or ferromagnetic properties;
Preferably, the magnetic material is selected from Fe3O4、Fe2O3、CoFe2O4、MnFe2O4、NiFe2O4、 compounds neodymium iron boron, samarium cobalt, metal Fe, co, ni and one of metal oxides of alloy Fe 2Co、Ni2 Fe.
In some embodiments, the method of making the security particle comprises the steps of:
s1, mixing a fluorescent material with a curing material, and curing to form a fluorescent curing material; and/or
S2, mixing the magnetic material with a curing material, and curing to form a magnetic curing material;
s3, granulating the fluorescent curing material and/or the magnetic curing material;
Preferably, the curing material is a photo-curing glue or a thermosetting glue.
Photo-curable glues such as ultraviolet curing UV glue; heat curable glue such as heat curable epoxy.
As a preferable scheme of the anti-counterfeiting glue, a mixture of a magnetic material and a curing material is coated on the fluorescent curing material for curing;
preferably, after the magnetic curing material is formed on the fluorescent curing material, a mixture of the fluorescent material and the curing material is coated on the magnetic curing material and cured.
In some embodiments, the mass ratio of the fluorescent material to the cured material in the fluorescent cured material is (1-4): 5, a step of; in the magnetic curing material, the mass ratio of the magnetic material to the curing material is (1-3): 5. the inventor discovers that the glue has better fluorescence and/or magnetism effect through the design of the proportion.
In a second aspect of the present invention, a method for anti-counterfeit detection of glue is provided, which comprises a process of detecting whether fluorescence and/or magnetism exists in the glue. When fluorescence is detected in the glue, the glue can be magnetically attracted to the anti-counterfeiting particles, or fluorescence is detected at the same time, and the anti-counterfeiting particles can be magnetically attracted, so that anti-counterfeiting identification can be performed on the glue.
The present invention will be described in further detail with reference to specific examples and comparative examples, but the present invention is not limited to the following examples, and the implementation conditions adopted in the examples may be further adjusted according to different requirements of specific use, and the conditions not specified are conventional conditions in the industry.
Example 1:
Taking 2 parts of ferric chloride hexahydrate, 1 part of sodium acetate, 1 part of sodium citrate and 150 parts of ethylene glycol according to the mass amount, reacting in a stainless steel reaction kettle at 200 ℃ for 12 hours, taking out after the reaction is finished, and washing with deionized water and ethanol for a plurality of times to obtain the ferroferric oxide. According to the magnitude of substances, 1 part of ferroferric oxide, 2 parts of ammonia water, 100 parts of ethanol and 100 parts of deionized water are taken in a glass reaction kettle, a stirrer is started, the rotating speed is set at 300rpm, then 10 parts of tetraethyl silicate is slowly poured in, after the reaction is finished for 3 hours, the solvent is poured out, and the ferroferric oxide after silicon coating is obtained after the solvent is washed with ethanol and deionized water for several times.
200Mg of sodium fluorescein and 500mg of ultraviolet UV glue (the main components are polyurethane acrylate prepolymer, acrylate monomer, initiator and the like) are taken and uniformly mixed, and UV is cured to form a fluorescent layer. Mixing 150mg of the silicon-coated ferroferric oxide and 500mg of Ultraviolet (UV) glue uniformly, coating on a fluorescent layer, carrying out UV curing, forming a magnetic layer on the fluorescent layer to form a double-layer structure curing material, and crushing the curing material into particles to prepare anti-counterfeiting particles.
The anti-counterfeiting particles are dispersed into glue (any commercially available glue) to form the anti-counterfeiting glue.
Example 2
Taking 2 parts of ferric chloride hexahydrate, 1 part of sodium acetate, 1 part of sodium citrate and 150 parts of ethylene glycol according to the mass amount, reacting in a stainless steel reaction kettle at 200 ℃ for 12 hours, taking out after the reaction is finished, and washing with deionized water and ethanol for a plurality of times to obtain the ferroferric oxide. According to the magnitude of substances, 1 part of ferroferric oxide, 2 parts of ammonia water, 100 parts of ethanol and 100 parts of deionized water are taken in a glass reaction kettle, a stirrer is started, the rotating speed is set at 300rpm, then 10 parts of tetraethyl silicate is slowly poured in, after the reaction is finished for 3 hours, the solvent is poured out, and the ferroferric oxide after silicon coating is obtained after the solvent is washed with ethanol and deionized water for several times.
200Mg of sodium fluorescein and 500mg of ultraviolet UV glue (the main components are polyurethane acrylate prepolymer, acrylate monomer, initiator and the like) are taken and uniformly mixed, and UV is cured to form a fluorescent layer. Mixing 150mg of the silicon-coated ferroferric oxide and 500mg of ultraviolet/UV glue uniformly, coating on a fluorescent layer, and performing UV curing to form a magnetic layer on the fluorescent layer. Mixing 200mg of sodium fluorescein and 500mg of Ultraviolet (UV) glue uniformly, curing by UV to form a three-layer structure curing material, and crushing the curing material into particles to prepare anti-counterfeiting particles.
The anti-counterfeiting particles are dispersed into glue (any commercially available glue) to form the anti-counterfeiting glue.
When judging whether the glue with no difference in appearance is anti-counterfeiting glue or not, only irradiating with light, and emitting fluorescence in the glue, as shown in fig. 1, namely the anti-counterfeiting glue; or applying a magnetic field to the glue, and observing that the glue has enriched particles, as shown in figure 2, namely the anti-counterfeiting glue. Of course, the glue can be illuminated and magnetic field is applied at the same time, and fluorescent light and enriched particles are observed in the glue, as shown in fig. 3, so that the anti-counterfeiting glue is obtained. The anti-counterfeiting particles of the embodiment 1 are added into the glue shown in fig. 1-3, and the anti-counterfeiting particles of the embodiment 2 are added into the glue, so that the detection method is the same.
While the invention has been disclosed in terms of various aspects and embodiments, other aspects and embodiments will be apparent to those skilled in the art in view of this disclosure, and many changes and modifications can be made without departing from the spirit of the invention. The various aspects and embodiments of the present invention are disclosed for illustrative purposes only and are not intended to limit the invention, the true scope of which is set forth in the following claims.
Claims (10)
1. The anti-counterfeiting glue is characterized by comprising a glue body and anti-counterfeiting particles dispersed in the glue body, wherein the anti-counterfeiting particles have fluorescence and/or magnetism;
Preferably, the size of the anti-counterfeiting particles is 100nm-500nm.
2. The anti-counterfeiting glue according to claim 1, wherein the anti-counterfeiting particles comprise a fluorescent layer and/or a magnetic layer, the fluorescent layer comprising a fluorescent material coated in a cured material; the magnetic layer comprises a magnetic material coated in a solidified material.
3. The anti-counterfeiting glue according to claim 2, wherein the anti-counterfeiting particles comprise a fluorescent layer, a magnetic layer and a fluorescent layer which are sequentially arranged.
4. A tamper-evident glue as claimed in claim 2 or 3, wherein the magnetic material is coated with an inorganic layer;
preferably, the inorganic layer is selected from at least one of a silicon-containing oxide, an aluminum-containing oxide, a zirconium-containing oxide, a titanium-containing oxide, a hafnium-containing oxide, or an yttrium-containing oxide.
5. The anti-counterfeiting glue according to claim 2 or 3, wherein the fluorescent material comprises at least one of fluorescent nanoparticles, fluorescein, fluorescent polymers, and organic fluorescent molecules;
preferably, the fluorescent nanoparticle comprises at least one of a carbon dot, a quantum dot, a nanorod, or a nanoplatelet.
6. A tamper-evident glue according to claim 2 or 3, wherein the magnetic material comprises a metal and metal oxide having superparamagnetic, paramagnetic or ferromagnetic properties;
Preferably, the magnetic material is selected from Fe3O4、Fe2O3、CoFe2O4、MnFe2O4、NiFe2O4、 compounds neodymium iron boron, samarium cobalt, metal Fe, co, ni and one of metal oxides of alloy Fe 2Co、Ni2 Fe.
7. A tamper-evident glue as claimed in claim 2 or 3, wherein the method of preparing the tamper-evident particles comprises the steps of:
s1, mixing a fluorescent material with a curing material, and curing to form a fluorescent curing material; and/or
S2, mixing the magnetic material with a curing material, and curing to form a magnetic curing material;
s3, granulating the fluorescent curing material and/or the magnetic curing material;
Preferably, the curing material is a photo-curing glue or a thermosetting glue.
8. The anti-counterfeiting glue according to claim 7, wherein a mixture of a magnetic material and a curing material is coated on the fluorescent curing material and cured;
preferably, after the magnetic curing material is formed on the fluorescent curing material, a mixture of the fluorescent material and the curing material is coated on the magnetic curing material and cured.
9. The anti-counterfeiting glue according to claim 7, wherein in the fluorescent curing material, the mass ratio of the fluorescent material to the curing material is (1-4): 5, a step of; in the magnetic curing material, the mass ratio of the magnetic material to the curing material is (1-3): 5.
10. A glue anti-counterfeiting detection method is characterized by comprising the following steps of: including a process of detecting the presence of fluorescence and/or magnetism in the glue.
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