CN118284345A - Flavor generating article and smoking system - Google Patents
Flavor generating article and smoking system Download PDFInfo
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- CN118284345A CN118284345A CN202180104369.5A CN202180104369A CN118284345A CN 118284345 A CN118284345 A CN 118284345A CN 202180104369 A CN202180104369 A CN 202180104369A CN 118284345 A CN118284345 A CN 118284345A
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- flavor
- generating article
- heater
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- 239000000796 flavoring agent Substances 0.000 title claims abstract description 190
- 235000019634 flavors Nutrition 0.000 title claims abstract description 182
- 230000000391 smoking effect Effects 0.000 title claims description 19
- 230000005489 elastic deformation Effects 0.000 claims abstract description 87
- 238000010438 heat treatment Methods 0.000 claims abstract description 17
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 93
- 241000208125 Nicotiana Species 0.000 claims description 91
- 239000003205 fragrance Substances 0.000 claims description 43
- 239000000443 aerosol Substances 0.000 claims description 27
- 239000000758 substrate Substances 0.000 claims description 11
- 238000003780 insertion Methods 0.000 claims description 9
- 230000037431 insertion Effects 0.000 claims description 9
- 239000011800 void material Substances 0.000 claims description 7
- 239000012159 carrier gas Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 description 22
- 239000002304 perfume Substances 0.000 description 17
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- CRZQGDNQQAALAY-UHFFFAOYSA-N Methyl benzeneacetate Chemical compound COC(=O)CC1=CC=CC=C1 CRZQGDNQQAALAY-UHFFFAOYSA-N 0.000 description 2
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- 150000002540 isothiocyanates Chemical class 0.000 description 1
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- 150000002596 lactones Chemical class 0.000 description 1
- 238000007561 laser diffraction method Methods 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229940069445 licorice extract Drugs 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229940043353 maltol Drugs 0.000 description 1
- 239000001683 mentha spicata herb oil Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- DILOFCBIBDMHAY-UHFFFAOYSA-N methyl 2-(3,4-dimethoxyphenyl)acetate Chemical compound COC(=O)CC1=CC=C(OC)C(OC)=C1 DILOFCBIBDMHAY-UHFFFAOYSA-N 0.000 description 1
- 229940102398 methyl anthranilate Drugs 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000001627 myristica fragrans houtt. fruit oil Substances 0.000 description 1
- 239000001186 myroxylon pereirae klotzsch oil Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- ZYTMANIQRDEHIO-UHFFFAOYSA-N neo-Isopulegol Natural products CC1CCC(C(C)=C)C(O)C1 ZYTMANIQRDEHIO-UHFFFAOYSA-N 0.000 description 1
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- YYZUSRORWSJGET-UHFFFAOYSA-N octanoic acid ethyl ester Natural products CCCCCCCC(=O)OCC YYZUSRORWSJGET-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- VWMVAQHMFFZQGD-UHFFFAOYSA-N p-Hydroxybenzyl acetone Natural products CC(=O)CC1=CC=C(O)C=C1 VWMVAQHMFFZQGD-UHFFFAOYSA-N 0.000 description 1
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 150000008379 phenol ethers Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940081310 piperonal Drugs 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- NJGBTKGETPDVIK-UHFFFAOYSA-N raspberry ketone Chemical compound CC(=O)CCC1=CC=C(O)C=C1 NJGBTKGETPDVIK-UHFFFAOYSA-N 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229940112950 sage extract Drugs 0.000 description 1
- 235000020752 sage extract Nutrition 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- VQTLGLGPQXZERV-UHFFFAOYSA-M sodium;4-hydroxyundecanoate Chemical compound [Na+].CCCCCCCC(O)CCC([O-])=O VQTLGLGPQXZERV-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- UNYNVICDCJHOPO-UHFFFAOYSA-N sotolone Chemical compound CC1OC(=O)C(O)=C1C UNYNVICDCJHOPO-UHFFFAOYSA-N 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000010676 star anise oil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- PINIEAOMWQJGBW-FYZOBXCZSA-N tenofovir hydrate Chemical compound O.N1=CN=C2N(C[C@@H](C)OCP(O)(O)=O)C=NC2=C1N PINIEAOMWQJGBW-FYZOBXCZSA-N 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 1
- BJIOGJUNALELMI-ONEGZZNKSA-N trans-isoeugenol Chemical compound COC1=CC(\C=C\C)=CC=C1O BJIOGJUNALELMI-ONEGZZNKSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 239000001917 trigonella foenum graecum l. absolute Substances 0.000 description 1
- 235000019583 umami taste Nutrition 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000001846 viola odorata l. leaf absolute Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/20—Devices using solid inhalable precursors
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/12—Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/167—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes in liquid or vaporisable form, e.g. liquid compositions for electronic cigarettes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/40—Constructional details, e.g. connection of cartridges and battery parts
- A24F40/46—Shape or structure of electric heating means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/40—Constructional details, e.g. connection of cartridges and battery parts
- A24F40/48—Fluid transfer means, e.g. pumps
- A24F40/485—Valves; Apertures
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F47/00—Smokers' requisites not otherwise provided for
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The present invention provides a flavor-generating article that generates flavor by heating. The flavor generating article has a through hole into which a heater can be inserted and a tubular elastic deformation piece defining the through hole. The elastically deformable sheet is capable of elastically deforming in a thickness direction thereof.
Description
Technical Field
The present invention relates to flavour generating articles and smoking systems.
Background
Conventionally, a flavor generating article for sucking flavor or the like without burning a material is known (for example, patent document 1 and patent document 2). Such a flavor generating article has a flavor source containing tobacco containing volatile components, and can be heated directly from the interior of the flavor source by inserting a heater or the like into the interior of the flavor source.
Prior art literature
Patent literature
Patent document 1: international publication No. 2020/002165
Patent document 2: international publication No. 2020/007879
Disclosure of Invention
Problems to be solved by the invention
A so-called internal heating type heating device in which a fragrance source is heated from the inside by a heater plate, a heating pin, a heating base, or the like can directly heat the fragrance source to a high temperature. It is required to efficiently heat the fragrance source using such an internal heating type heating apparatus.
An object of the present invention is to provide a flavor generating article and a smoking system that can be efficiently heated.
Means for solving the problems
According to the 1 st aspect, a flavor-generating article that generates flavor by heating can be provided. The flavor generating article has a through hole into which a heater can be inserted and a tubular elastic deformation piece defining the through hole. The elastic deformation sheet is elastically deformable in the thickness direction thereof.
According to the 1 st aspect, when the heater is inserted into the through hole, the elastic deformation piece is elastically deformed in the thickness direction with respect to the heater, and is easily brought into contact with or close to the heater. Therefore, in the case where the elastically deformable sheet contains a fragrance, or in the case where a sheet containing a fragrance is present inside the elastically deformable sheet, the sheet containing a fragrance can be brought into further contact with or close to the heater, and therefore the fragrance-generating article can be efficiently heated.
In the aspect 2, in the aspect 1, the elastically deformable sheet has a volume void ratio of 85% or more and 95% or less.
According to claim 2, the sheet containing the fragrance can be brought into contact with or close to the heater more appropriately. When the volume void ratio of the elastic deformation sheet is less than 85%, the elastic deformation sheet has an excessively strong elastic resilience, and it is difficult to deform the flavor-generating article. In this case, there is a risk that the ventilation resistance of the flavor-generating article excessively increases. When the volume void ratio of the elastic deformation sheet is more than 95%, the elastic deformation sheet has weak resilience, and when the flavor-generating article is deformed, the contact between the inner wall of the flavor-generating article and the heater is weakened, and there is a risk of affecting the conveyance.
The gist of claim 3 is that, in claim 1 or claim 2, the elastically deformable sheet has an air passage resistance of 0mmH 2 O or more and 150mmH 2 O or less.
According to claim 3, a gap is not generated between the heater and the elastically deformable sheet, and ventilation resistance at the time of suction by the user can be made appropriate. If the ventilation resistance of the elastic deformation sheet is more than 150mmH 2 O, the suction resistance becomes too high, and there is a risk that the user feels uncomfortable with suction.
The gist of claim 4 is that, in any of the aspects 1 to 3, the elastically deformable sheet is a non-tobacco sheet having a weight per unit area of 30g/m 2 or more and 100g/m 2 or less.
According to the 4 th aspect, the sheet containing the fragrance can be brought into contact with the heater more appropriately. When the weight per unit area of the elastic deformation sheet is less than 30g/m 2, the following hidden troubles exist: immediately dispersing the fragrance; the elastic deformation sheet becomes too thin and is liable to be broken or the like during the manufacturing process, and the manufacturing adaptability becomes poor; the elastically deformable sheet breaks upon insertion of the heater. When the weight per unit area of the elastic deformation sheet is more than 100g/m 2, it is difficult to bend the elastic deformation sheet and deform the flavor-generating article 10. In this case, the heat capacity increases, and therefore, the temperature of the flavor-generating article 10 increases slowly, which may take a long time until the first smoking can be performed.
The gist of claim 5 is that, in any of claims 1 to 4, the elastically deformable sheet is a non-tobacco sheet carrying an aerosol source or a flavor generating base material.
According to the 5 th aspect, the elastic deformation sheet is brought into contact with or close to the heater, whereby the elastic deformation sheet can be efficiently heated to generate aerosol or flavor.
The gist of claim 6 is that, in any of the aspects 1 to 5, the elastically deformable sheet is a non-tobacco sheet having a wavy cross section as viewed from the longitudinal direction.
According to the 6 th aspect, the elastic deformation sheet can be elastically deformed in the thickness direction thereof by deforming the wavy cross section of the non-tobacco sheet. Further, since the non-tobacco sheet having the wave-shaped cross section has a gap (between waves) along the longitudinal direction thereof, a flow path through which flavor or the like generated by the flavor-generating article passes can be defined.
The gist of claim 7 is that, in any of the aspects 1 to 6, the sheet includes a flavor generating sheet positioned inside the elastic deformation sheet.
According to the 7 th aspect, the elastic deformation sheet is brought into contact with or close to the heater, so that the flavor generating sheet positioned inside the elastic deformation sheet can be brought into contact with or close to the heater, and the flavor generating sheet can be efficiently heated to generate aerosol or flavor.
The gist of claim 8 is that, in claim 7, the flavor-generating sheet comprises a negative carrier gas sol source or a non-tobacco sheet of a flavor-generating base material.
According to the 8 th aspect, the aerosol source or the flavor generating substrate of the non-tobacco sheet can be efficiently heated to generate aerosol, flavor, or the like. In the present specification, the flavor-generating base material to be supported on the non-tobacco sheet may include, for example, a tobacco extract, synthetic nicotine, and other known flavors.
In the case of claim 9, the flavor-generating sheet according to claim 7 includes a tobacco sheet.
According to the 9 th aspect, the tobacco sheet can be efficiently heated to generate aerosol or flavor.
The gist of claim 10 is that, in claim 7, the flavor-generating sheet comprises a tobacco sheet and a non-tobacco sheet carrying an aerosol source or a flavor-generating base material.
According to the 10 th aspect, the non-tobacco sheet and the tobacco sheet can be efficiently heated to generate aerosol or flavor.
The 11 th aspect is the gist of any one of the 1 st to 10 th aspects, wherein the system comprises: the first part (1) is heated to generate a fragrance and includes the elastic deformation sheet, and the second part (2) is adjacent to the first part (1) in the longitudinal direction and passes the fragrance generated by the first part (1).
According to claim 11, the fragrance generated in the 1 st part can be passed through the 2 nd part, and therefore the fragrance can be cooled in the 2 nd part. In the present specification, the longitudinal direction may be the axial direction of the rod-shaped flavor generating article or the insertion direction of the heater into the flavor generating article.
In the 12 th aspect, in the 11 th aspect, the 2 nd portion includes a1 st stopper for preventing the elastic deformation piece from moving from the 1 st portion to the 2 nd portion.
According to claim 12, the elastically deformable sheet can be prevented from moving toward the 2 nd portion when the heater is inserted into the through hole. Therefore, the damage of the flavor generating article at the time of the heater insertion can be suppressed.
The gist of claim 13 is that, in claim 11 or claim 12, there is provided a2 nd stopper for preventing the elastic deformation piece from moving from the 1 st part to the opposite side of the 2 nd part.
According to aspect 13, the movement of the elastic deformation piece to the opposite side of the 2 nd portion when the heater is pulled out from the through hole, that is, the pulling-out of the elastic deformation piece from the 1 st portion together with the heater can be suppressed. Therefore, even if the heater is pulled out from the through hole, the elastic deformation piece can be left in the 1 st part, so that the used flavor-generating article can be easily disposed of.
In the 14 th aspect, in the 13 th aspect, the 2 nd stopper is a sealing sheet covering an end surface of the elastic deformation sheet and the through hole.
According to the 14 th aspect, by inserting the heater into the through hole so as to break the seal piece, the flavor generating article can be heated by the heater while the seal piece is positioned on the end surface of the elastic deformation piece. Therefore, when the heater is pulled out of the through hole after use, the seal piece located on the end face of the elastic deformation piece can suppress the elastic deformation piece from being pulled out of the 1 st part together with the heater.
The 15 th aspect is the object of any one of the 1 st to 14 th aspects, wherein the elastic deformation sheet comprises an outer wrapping sheet surrounding an outer side of the elastic deformation sheet, and the outer wrapping sheet has a weight per unit area of 50g/m 2 to 100g/m 2.
According to the 15 th aspect, the exterior sheet can maintain an appropriate shape with respect to the deformation of the elastic deformation sheet. When the outer cover sheet has a weight per unit area of less than 50g/m 2, the outer cover sheet is more likely to deform than the elastic deformation sheet, and there is a risk that an appropriate shape cannot be maintained. When the outer cover sheet has a weight per unit area of more than 100g/m 2, there is a risk that the elastic deformation sheet surrounded by the outer cover sheet is hardly deformed.
According to the 16 th aspect, a smoking system may be provided. The smoking system includes the flavor generating article according to any one of aspects 1 to 15, and the flavor aspirator including the heater. The diameter of the through hole is smaller than the maximum length of the heater perpendicular to the insertion direction.
According to the 16 th aspect, by inserting the heater into the through hole, the through hole is expanded by the heater. Thus, the elastically deformable sheet of the flavor-generating article is deformed. For example, in the case where the heater is a plate-like heater, the cross-sectional shape of the through hole is deformed to be flat by the heater, and accordingly, the elastically deformable piece may be in contact with or close to the main surface of the plate-like heater. In addition, in the case of a needle-shaped heater, when the heater is inserted into the through hole, the elastic deformation piece is compressed in the thickness direction, and the elastic deformation piece can be brought into contact with or close to the circumferential surface of the heater. Thus, the flavor generating article can be efficiently heated.
According to mode 17, there can be provided a smoking system. The smoking system includes the flavor generating article according to any one of aspects 1 to 15, and the flavor aspirator including the heater. The flavor aspirator has an opening for receiving the flavor generating article. The maximum diameter of the opening is larger than the maximum diameter of the flavor-generating article, and the minimum diameter of the opening is smaller than the minimum diameter of the flavor-generating article.
According to the 17 th aspect, by inserting the flavor generating article into the opening of the flavor aspirator, the flavor generating article can be deformed in accordance with the shape of the opening. Specifically, the flavor-generating article is deformed in accordance with the minimum diameter of the opening, and its cross section is deformed flat. Thus, the elastically deformable sheet of the flavor-generating article contacts or approaches the heater, and the flavor-generating article can be efficiently heated.
In the eighth aspect, in the 16 th or 17 th aspect, the inner circumference of the through hole is equal to or larger than the outer circumference of the heater.
According to the 18 th aspect, even if the flavor-generating article and the through-hole are deformed, a gap can be generated between the heater and the flavor-generating article (the inner surface of the flavor-generating article defining the through-hole), and therefore, an increase in suction resistance can be prevented, and the flavor or aerosol generated by the flavor-generating article can be delivered to the user more reliably through the gap. The outer circumferential length of the heater may be the maximum outer circumferential length of the portion of the heater into which the fragrance generating article is inserted.
In the 19 th aspect, in any one of the 16 th to 18 th aspects, the heater is a plate-shaped heater having a1 st surface and a2 nd surface facing the 1 st surface, and when the plate-shaped heater is inserted into the through hole, the elastic deformation piece is deformed so that a distance between the elastic deformation piece and the 1 st surface or the 2 nd surface is reduced.
According to the 19 th aspect, since the elastic deformation piece is deformed so that the elastic deformation piece contacts or approaches the 1 st or 2 nd surface of the heater, the flavor generating article can be efficiently heated.
The gist of claim 20 is that, in any of the 16 th to 19 th aspects, the through hole is defined by an inner surface of the elastic deformation sheet or the flavor generating sheet.
According to the 20 th aspect, since the inner surface of the elastic deformation sheet or the flavor generating sheet can directly contact the heater when the heater is inserted into the through hole, the elastic deformation sheet or the flavor generating sheet can be efficiently heated.
Drawings
Fig. 1 is a schematic view of a flavor generating article according to the present embodiment.
Fig. 2 is a side view of the flavor generating article of fig. 1, looking at 2-2.
Fig. 3 is a cross-sectional view of the portion 2 of fig. 1, looking at 3-3.
Fig. 4A is a side view of a scent-generating article of other embodiments.
Fig. 4B is a schematic view of the flavor generating article after the heater is inserted.
Fig. 5 is a cross-sectional view showing a main portion of the fragrance aspirator along the width direction of the heater.
Fig. 6 is a sectional view showing a main portion of the fragrance aspirator along a thickness direction of the heater.
Fig. 7 is a sectional view showing a state in which the flavor generating article is accommodated in the flavor aspirator.
Fig. 8 is a cross-sectional view showing a state in which the flavor generating article is accommodated in the flavor aspirator.
Fig. 9 is a cross-sectional view showing a state in which the flavor generating article is accommodated in the flavor aspirator.
Fig. 10 is a side view of a scent-generating article of other embodiments.
Symbol description
10: Fragrance generating article
20: Part 2
21: Outer wrapping sheet
22: No. 1 stop block
30: Part 1
32: Elastic deformation sheet
34: Fragrance generating sheet
34A: non-tobacco sheet
34B: tobacco sheet
36: Through hole
38: Stop block 2
100: Fragrance aspirator
112: An opening
120: Heater
120A: plane 1
120B: 2 nd surface
Detailed Description
Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the drawings described below, the same or corresponding components are denoted by the same reference numerals, and the same repetitive description is omitted.
Fig. 1 is a schematic view of a flavor generating article according to the present embodiment. Fig. 2 is a side view of the flavor generating article of fig. 1, looking at 2-2. In fig. 1, a portion 130 of a flavour generating article 10 is shown in cross-section and a portion 220 is shown in side view. The flavor generating article 10 is a rod-shaped member as a whole, and is configured to generate flavor by heating and to provide flavor to a user who sucks the flavor generating article 10. As shown in fig. 1, the flavor generating article 10 has a 1 st part 30 and a2 nd part 20 adjacent to the 1 st part 30 in the longitudinal direction.
Part 130 is configured to generate a fragrance by heating. As shown in fig. 1 and 2, the 1 st portion 30 includes an elastically deformable sheet 32. The 2 nd part 20 is configured to pass the fragrance generated by the 1 st part 30. Thus, the scent generated by section 130 may be cooled in section 2 20. The flavor generating article 10 has a through hole 36 into which a heater of a flavor aspirator described later can be inserted, and the through hole 36 may be defined at least in part by the tubular elastic deformation sheet 32. As shown in fig. 2, the through hole 36 and the 1 st portion 30 have a substantially circular cross section as viewed in the longitudinal direction. In the present embodiment, the elastic deformation piece 32 is elastically deformable in the thickness direction thereof (i.e., the radial direction of the cylindrical elastic deformation piece 32). Thus, when the heater is inserted into the through hole 36, the elastically deforming piece 32 elastically deforms in the thickness direction with respect to the heater, and is easily brought into contact with or close to the heater. Therefore, in the case where the elastically deforming sheet 32 contains the fragrance, or in the case where the sheet containing the fragrance is present inside the elastically deforming sheet 32, the sheet containing the fragrance can be brought into further contact with or close to the heater, and therefore the fragrance generating article 10 can be efficiently heated.
In the example shown in fig. 1 and 2, the elastically deformable sheet 32 may be a non-tobacco sheet. The non-tobacco sheet refers to a material formed from a non-tobacco material into a sheet, and may contain a tobacco material. Specifically, the elastically deformable sheet 32 may be made of non-tobacco fibers such as pulp fibers or nonwoven fabrics, and may contain an aerosol source. The non-tobacco fibers used in the non-tobacco sheet may comprise non-pulp fibers. Non-pulp fibers refer to fibers other than pulp fibers. Pulp fibers are aggregates of cellulose fibers extracted from plants such as wood, and are generally used as a raw material for paper. As pulp fibers, there may be mentioned: waste pulp, chemical pulp, mechanical pulp, and the like.
The non-tobacco sheet may comprise a binder. The binder is an adhesive for bonding fibers to each other and the like. As the binder, a binder known in the art can be used. The non-tobacco sheet may comprise an emulsifier. The emulsifier can increase the affinity of the lipophilic aerosol-generating substrate for hydrophilic non-pulp fibers. As the emulsifier, a known emulsifier can be used, and examples thereof include emulsifiers having an HLB value of 8 to 18.
An aerosol source refers to a material that generates an aerosol by heating and vaporizing and cooling, or generates an aerosol by atomizing. As the aerosol source, a known material can be used, and as an example thereof, there can be mentioned: polyhydric alcohols such as glycerin and Propylene Glycol (PG), triethyl citrate (TEC), and glyceryl triacetate. The aerosol source may be added to the tobacco sheet 34b described later.
The non-tobacco sheet may comprise a flavour generating substrate. The flavor generating base material is a material imparting a flavor, and is preferably a tobacco material. Specific tobacco materials include: cut materials obtained by cutting dried tobacco leaves, crushed tobacco leaves, or tobacco extracts (extracts obtained by using water, an organic solvent, or a mixed solution thereof), and the like. The tobacco leaf crushed material is particles obtained by crushing tobacco leaves. The average particle diameter of the crushed tobacco leaves may be, for example, 30 to 120. Mu.m. The pulverization may be performed using a known pulverizer, and may be performed by dry pulverization or wet pulverization. Accordingly, the crushed tobacco leaves are also referred to as tobacco particles. In the present embodiment, the average particle diameter can be obtained by a laser diffraction/scattering method, and specifically, can be measured by using a laser diffraction type particle diameter distribution measuring apparatus (for example, LA-950 manufactured by horiba ltd). The type of tobacco is not limited, and a yellow variety, a burley variety, an oriental variety, a local variety, another tobacco (Nicotiana tabacum) line variety, a tobacco (Nicotiana rustica) line variety, and the like can be used. The amount of the flavor-imparting base material in the non-tobacco sheet is not particularly limited, but is preferably 1 to 30% by weight, more preferably 10 to 20% by weight.
The flavour generating substrate may also comprise a perfume. The perfume is a substance that provides a fragrance or flavor. The perfume may be natural perfume or synthetic perfume. As the perfume, 1 kind of perfume may be used, or a mixture of plural kinds of perfumes may be used. As the flavoring, any flavoring commonly used in smoking articles can be used, and specific examples thereof will be described later. The flavoring may be included in the non-tobacco sheet in an amount that the smoking article is capable of providing the preferred flavor, taste, and for example, in an amount of preferably 1 to 30% by weight, more preferably 10 to 20% by weight, in the non-tobacco sheet.
The perfume may be any commonly used perfume such as essential oil, natural perfume, or synthetic perfume, and any perfume may be used. The shape of the material may be any shape, and may be any shape. Preferred flavoring agents (flavoring) include flavoring agents selected from tobacco extracts and tobacco components, sugar and saccharide flavoring agents, licorice (Lycoris), cocoa, chocolate, fruit juice and fruit, flavoring, wine, herbs, vanilla, and flower flavoring agents, or combinations thereof. Specifically, the aromatic hydrocarbon may be a perfume selected from isothiocyanates, indoles and derivatives thereof, ethers, esters, ketones, fatty acids, aliphatic higher alcohols, aliphatic higher aldehydes, aliphatic higher hydrocarbons, thioethers, thiols, terpene hydrocarbons, phenol ethers, phenols, furfurals and derivatives thereof, aromatic alcohols, aromatic aldehydes, lactones, and the like, or a combination thereof.
For example, a wide variety of fragrances described in "known/conventional technology set (fragrance)" (release of patent office at 3/14/2007), "topical reference book (popular version) of latest fragrance" (release at 2/25/2012), barren 1/small Lin Zhangfu/daycare spring/kawasaki general, sho, toward a bookstore), or "Tobacco Flavoring for Smoking Products" (release at 6/1972, r.j.reynolds TOBACCO com) can be used.
From the viewpoint of imparting a good odor, the perfume may be exemplified by, for example: acetoanisole, acetophenone, acetylpyrazine, 2-acetylthiazole, alfalfa extract (alfalfa extract), amyl alcohol, amyl butyrate, trans-anethole, star anise oil, apple juice, peru balsam oil, beeswax absolute, benzaldehyde, benzoin resin, benzyl alcohol, benzyl benzoate, benzyl propionate, 2, 3-butanedione, 2-butanol, butyl butyrate, butyric acid, caramel, cardamom oil, carob absolute, beta-carotene, carrot juice, L-carvone, beta-caryophyllene, cinnamon bark oil, cedar oil, celery seed oil, chamomile oil, cinnamaldehyde, cinnamic acid, cinnamyl alcohol, cinnamyl cinnamate, citronellol, DL-citronellol, sage extract, cocoa, coffee kang brewing gram oil, coriander oil, cumyl aldehyde, artemisia oil, delta-decalactone, gamma-decalactone, capric acid, dill herb oil, 3, 4-dimethyl-1, 2-cyclopentanedione, 4, 5-dimethyl-3-hydroxy-2, 5-dihydrofuran-2-one, 3, 7-dimethyl-6-octenoic acid, 2, 3-dimethylpyrazine, 2, 5-dimethylpyrazine, 2, 6-dimethylpyrazine, ethyl 2-methylbutanoate, ethyl acetate, ethyl butyrate, ethyl caproate, ethyl isovalerate, ethyl lactate, ethyl laurate, ethyl levulinate, ethyl maltol, ethyl caprylate, ethyl oleate, ethyl palmitate, ethyl phenylacetate, ethyl propionate, ethyl stearate, ethyl valerate, ethyl vanillin glucoside, 2-ethyl-3, (5 or 6) -dimethylpyrazine, 5-ethyl-3-hydroxy-4-methyl-2 (5H) -furanone, 2-ethyl-3-methyl pyrazine, eucalyptol, fenugreek absolute, cytisine absolute, gentian liquor, geraniol, geranyl acetate, grape juice, guaiacol, guava extract, gamma-heptanolide, gamma-caprolactone, caproic acid, cis-3-hexen-1-ol, hexyl acetate, hexanol, hexyl phenylacetate, honey, 4-hydroxy-3-pentenoic acid lactone, 4-hydroxy-4- (3-hydroxy-1-butenyl) -3, 5-trimethyl-2-cyclohexen-1-one 4- (p-hydroxyphenyl) -2-butanone, sodium 4-hydroxyundecanoate, permanent flower (immortelle) absolute, beta-ionone, isoamyl acetate, isoamyl butyrate, isoamyl phenylacetate, isobutyl acetate, isobutyl phenylacetate, jasmine absolute, cola tincture, rice oil, terpeneless lemon oil, licorice extract, linalool, linalyl acetate, round leaf angelica root oil, maltol, maple syrup, menthol, menthone, acetic acid-L-room oilEsters, p-methoxybenzaldehyde, methyl-2-pyrrolyl ketone, methyl anthranilate, methyl phenylacetate, methyl salicylate, 4' -methylacetophenone, methylcyclopentenolone, 3-methylpentanoic acid, mimosa absolute, molasses, myristic acid, nerol, nerolidol, gamma-nonolactone, nutmeg oil, delta-octalactone, octanal, caprylic acid, neroli oil, orange oil, iris oil, palmitic acid, omega-pentadecanol, peppermint oil, ilex paraguariensis leaf oil, phenethyl alcohol, phenethyl phenylacetate, phenylacetic acid, piperonal, propenyl guaiacol, propyl acetate, 3-propylidene-1-isobenzofuranone, prune juice, pyruvic acid the extract of Salvia officinalis, oleum Rosae Rugosae, rum, salvia officinalis, oleum Santali albi, spearmint oil, storax absolute, tagetes Erecta oil, tea distillate, alpha-terpineol, terpineyl acetate, 5,6,7, 8-tetrahydroquinoxaline, 1,5,5,9-tetramethyl-13-oxacyclo (8.3.0.0 (4.9)) tridecane, 2,3,5, 6-tetramethylpyrazine, thyme oil, tomato extract, 2-tridecanone, triethyl citrate, 4- (2, 6-trimethyl-1-cyclohexenyl) 2-butene-4-one, 2, 6-trimethyl-2-cyclohexene-1, 4-dione, 4- (2, 6-trimethyl-1, 3-cyclohexadienyl) 2-butene-4-one, 2,3, 5-trimethylpyrazine, gamma-undecalactone, vanilla extract, vanillin, veratraldehyde, violet leaf absolute, citral, sweet orange oil (MANDARINE OIL), 4- (acetoxymethyl) toluene, 2-methyl-1-butanol, ethyl 10-undecenoate, isoamyl caproate, 1-phenylethyl acetate, lauric acid, 8-mercaptomenthone, sweet orange aldehyde, hexyl butyrate and the like, with menthol being particularly preferred. In addition, 1 kind of these perfumes may be used alone, or 2 or more kinds may be used in combination.
The type of the solid perfume is not particularly limited, and examples thereof include, from the viewpoint of imparting a good flavor and taste, the following: flavoring agent selected from cocoa powder, carob powder, coriander powder, licorice powder, orange peel powder, herb powder, flower powder, spice powder, tea powder, etc., or combinations thereof.
In addition, the flavour generating substrate may comprise a cooling agent or flavour. The type of the cooling agent is not particularly limited, and examples thereof include those giving a good flavor and taste: menthol, camphor, isopulegol, eucalyptol, peppermint oil, eucalyptus oil, 2-l-menthoxyethanol (COOLACT (registered trademark) 5), 3-l-menthoxypropyl-1, 2-diol (COOLACT (registered trademark) 10), l-3-Hydroxy-butyrate (COOLACT (registered trademark) 20), p-Alkane-3, 8-diol (COOLACT (registered trademark) 38D), N- (2-hydroxy-2-phenethyl) -2-isopropyl-5, 5-dimethylcyclohexane-1-carboxamide (COOLACT (registered trademark) 370), N- (4- (aminomethyl) phenyl) -2-isopropyl-5, 5-dimethylcyclohexane-carboxamide (COOLACT (registered trademark) 400), N- (3-hydroxy-4-methoxyphenyl) -2-isopropyl-5, 5-dimethylcyclohexane-carboxamide, N-ethyl-p-Alkyl-3-carboxamides (WS-3), ethyl-2- (p-methyl)Alkyl-3-carboxamide acetate (WS-5), N- (4-methoxyphenyl) -p-Alkanecarboxamide (WS-12), 2-isopropyl-N, 2, 3-trimethylbutyramide (WS-23), 3-l-menthoxy-2-methylpropan-1, 2-diol, 2-l-menthoxyethane-1-ol, 3-l-menthoxypropane-1-ol, 4-l-menthoxybutan-1-ol, menthyl lactate (FEMA 3748), menthone glycerol ketal (Frescolat MGA, FEMA3807, FEMA 3808), 2- (2-l) menthoneOxyethyl) ethanol,Glyoxylate, 2-pyrrolidone-5-carboxylic acidEsters, succinic acidEsters (FEMA 3810), N- (2- (pyridin-2-yl) -ethyl) -3-pAlkylcarboxamides (FEMA 4549), N- (ethoxycarbonylmethyl) -p-Alkyl-3-carboxamides, N- (4-cyanomethylphenyl) -p-Alkanecarboxamides and N- (4-aminocarbonylphenyl) -p-An alkane, and the like. The cooling agents may be used alone or in combination of 2 or more.
The type of the flavoring agent is not particularly limited, and examples thereof include those giving a good flavor and taste: sweeteners (sugars (glucose, fructose, isomerized sugar, caramel, etc)), acidulants (organic acids, etc.), other flavoring agents (raw materials exhibiting umami, bitter, salty, etc.), and the like. Further, lipids (wax), wax (u), fatty acids (short chain, medium chain, long chain fatty acids, etc.) may be optionally added.
When the flavor, the cooling agent, and the flavoring agent are contained in the tobacco shred, the total content of these components is not particularly limited, but is usually 10000ppm or more, preferably 20000ppm or more, more preferably 25000ppm or more, and is usually 70000ppm or less, preferably 50000ppm, more preferably 40000ppm or less, more preferably 33000ppm or less, from the viewpoint of imparting a good flavor. In another embodiment, the total amount is preferably 2% by weight or more, more preferably 5% by weight or more, and preferably 20% by weight or less, more preferably 10% by weight or less.
The elastically deformable sheet 32 preferably has a volume void ratio of 85% or more and 95% or less. This enables the sheet (the elastically deformable sheet 32 or the tobacco sheet 34b described later) containing the flavor to be brought into further proper contact with or close to the heater. When the volume void ratio of the elastic deformation sheet 32 is less than 85%, the elastic deformation sheet has an excessively strong elastic resilience, and it is difficult to deform the flavor-generating article. In this case, there is a risk that the ventilation resistance of the flavor-generating article excessively increases. When the volume void ratio of the elastic deformation sheet 32 is larger than 95%, the elastic force of the elastic deformation sheet is weak, and when the flavor-generating article is deformed, the contact between the inner wall of the flavor-generating article and the heater is weakened, and there is a possibility that the conveyance is affected.
The elastically deformable sheet 32 preferably has an air passage resistance of 0mmH 2 O or more and 150mmH 2 O or less. This can generate a gap between the heater and the elastically deformable sheet 32, and can make the ventilation resistance of the user appropriate at the time of suction. If the ventilation resistance of the elastic deformation sheet 32 is greater than 150mmH 2 O, the suction resistance becomes too high, and there is a risk that the user feels uncomfortable with suction. The air flow resistance of the elastic deformation sheet 32 here refers to the air flow resistance in the longitudinal direction of the elastic deformation sheet 32, that is, in the left-right direction (air flow direction) in fig. 1.
The elastically deformable sheet 32 preferably has a given hardness in the thickness direction. By controlling the hardness, the fragrance generating article 10 can be easily deformed, and the fragrance generating article 10 can be closely adhered to the heater, thereby improving the heating efficiency.
The elastically deformable sheet 32 is preferably a non-tobacco sheet having a weight per unit area of 30g/m 2 or more and 100g/m 2 or less. This enables the sheet containing the fragrance to be brought into further proper contact with the heater. When the weight per unit area of the elastic deformation sheet 32 is less than 30g/m 2, there are the following problems: the fragrance is quickly dispersed; the elastic deformation sheet becomes too thin and is liable to be broken or the like during the manufacturing process, and the manufacturing adaptability becomes poor; the elastically deformable sheet breaks upon insertion of the heater. When the weight per unit area of the elastic deformation sheet 32 is greater than 100g/m 2, it is difficult to bend the elastic deformation sheet and deform the flavor-generating article 10. In this case, the heat capacity increases, and therefore, the temperature of the flavor-generating article 10 increases slowly, which may take a long time until the first smoking can be performed.
As described above, the elastically deformable sheet 32 is preferably a non-tobacco sheet carrying an aerosol source or a flavour-generating substrate. Thus, the elastically deformable sheet 32 is brought into contact with or close to the heater, whereby the elastically deformable sheet 32 can be efficiently heated to generate aerosol or flavor.
As shown in fig. 1 and 2, the flavor-generating article 10 preferably has a flavor-generating sheet 34. In the illustrated example, the flavor generating sheet 34 is positioned inside the elastic deformation sheet 32, is formed in a tubular shape, and defines at least a part of the through hole 36 together with the elastic deformation sheet 32. Thus, the elastic deformation piece 32 is deformed to bring the elastic deformation piece 32 into contact with or close to the heater, and the fragrance generating piece 34 located inside the elastic deformation piece 32 can be brought into contact with or close to the heater. As a result, the fragrance generating sheet 34 can be efficiently heated to generate aerosol or fragrance. In the present embodiment, the through-hole 36 may be defined by the inner surface of the elastic deformation sheet 32 or the fragrance generating sheet 34, but is not limited thereto. Thus, when the heater 120 is inserted into the through hole 36, the inner surface of the elastic deformation sheet 32 or the fragrance generating sheet 34 can directly contact the heater 120, and therefore the elastic deformation sheet 32 or the fragrance generating sheet 34 can be efficiently heated.
As shown in fig. 2, the flavour generating sheet 34 may comprise a negative carrier gas sol source or a non-tobacco sheet 34a of a flavour generating substrate. Thus, the aerosol source or the flavor-generating substrate other than the tobacco sheet 34a can be efficiently heated to generate an aerosol, a flavor, or the like. The aerosol source or the flavor generating base material to be supported by the non-tobacco sheet 34a may be the aerosol source or the flavor generating base material that can be supported by the elastically deformable sheet 32.
In addition, as shown in fig. 2, the flavour generating sheet 34 may comprise a tobacco sheet 34b. Thus, the tobacco sheet 34b can be efficiently heated to generate aerosol or flavor. In the example shown in fig. 2, the tobacco sheet 34b is positioned inside the non-tobacco sheet 34a, but the tobacco sheet 34b may be positioned outside the non-tobacco sheet 34 a.
The tobacco sheet 34b may include, for example, tobacco (corresponding to an example of a flavor generating base material) and polyol (corresponding to an example of an aerosol source). The polyol may contain glycerol, propylene glycol, sorbitol, xylitol, and erythritol. These polyols may be used alone or in combination of 2 or more for the tobacco sheet 34b. These polyols may also be added to the elastically deformable sheet 32 described above. The tobacco sheet 34b may be formed into a sheet shape by mixing a binder with powdered tobacco and a polyol. As the binder, for example, guar gum, xanthan gum, CMC (carboxymethyl cellulose), CMC-Na (sodium salt of carboxymethyl cellulose), pullulan, hydroxypropyl cellulose (HPC), methyl cellulose, hydroxymethyl cellulose, and the like can be used. The adhesive may be added to the elastically deformable sheet 32.
In addition, pulp may be added to the tobacco sheet 34 b. The pulp may increase the strength of the tobacco sheet 34 b. On the other hand, pulp may not be added to the tobacco sheet 34 b. If pulp is not used, the proportion of tobacco in the tobacco sheet 34b increases accordingly, and thus an improvement in flavor can be expected.
The weight% of the binder that can be added to the tobacco sheet 34b is, for example, preferably 0% or more and 60% or less, more preferably 0% or more and 10% or less, relative to the weight of the tobacco sheet 34 b. The tobacco sheet 34b may have a blend ratio (weight percentage) of, for example, 5% to 40% of polyol, 50% to 90% of tobacco, 0% to 10% of binder, and 0% to 10% of pulp. Further, an acid such as lactic acid, palmitic acid, or benzoic acid may be added to the tobacco sheet 34 b.
As shown in fig. 2, the flavour generating sheet 34 may comprise a tobacco sheet 34b and a non-tobacco sheet 34a. The flavor-generating sheet 34 may include only any one of the tobacco sheet 34b and the non-tobacco sheet 34a, but is not limited thereto.
Fig. 3 is a cross-sectional view of the portion 220 of fig. 1, looking at 3-3. As shown in fig. 3, the 2 nd portion 20 has a cylindrical exterior sheet 21 and a1 st stopper 22 located inside the exterior sheet 21. In the present embodiment, the weight per unit area of the exterior sheet 21 is preferably 50g/m 2 to 150g/m 2, more preferably 50g/m 2 to 100g/m 2. The outer wrap sheet 21 preferably surrounds the outside of the elastically deforming sheet 32 as shown in fig. 2. Specifically, the overwrap sheet 21 preferably extends from the 2 nd portion 20 to the 1 st portion 30. Thus, the exterior sheet 21 can maintain an appropriate shape with respect to the deformation of the elastic deformation sheet 32. If the outer cover sheet 21 has a weight per unit area of less than 50g/m 2, the outer cover sheet is more likely to be deformed than the elastic deformation sheet 32, and there is a risk that an appropriate shape cannot be maintained. If the outer cover sheet 21 has a weight per unit area of more than 100g/m 2, the elastic deformation sheet 32 surrounded by the outer cover sheet 21 may be difficult to deform.
The 1 st stopper 22 can prevent the elastically deforming piece 32 from moving from the 1 st portion 30 to the 2 nd portion 20. Specifically, in the present embodiment, at least a part of the 1 st stopper 22 of the 2 nd portion 20 is located on the same radius as the elastically deforming piece 32 as viewed in the longitudinal direction. In other words, at least a portion of the 1 st stopper 22 contacts the elastically deforming piece 32 in the longitudinal direction. Thus, even if a force is applied to the elastic deformation piece 32 by the heater in the direction toward the 2 nd portion 20 when the heater is inserted into the through hole 36, the 1 st stopper 22 contacts the elastic deformation piece 32, and movement of the elastic deformation piece 32 can be prevented. Therefore, the damage of the flavor generating article 10 at the time of the heater insertion can be suppressed. In the present embodiment, the 1 st stopper 22 may be a paper having both ends connected to different positions of the inner surface of the tubular exterior sheet 21 and having a length between the ends longer than the diameter of the exterior sheet 21. Without being limited to the above, the 1 st stopper 22 may take any form capable of preventing the elastically deforming sheet 32 from moving from the 1 st part 30 to the 2 nd part 20.
Fig. 4A is a side view of another embodiment of a scent-generating article 10. Fig. 4A shows a side view of the view 2-2 shown in fig. 1. The flavor generating article 10 preferably has a2 nd stopper 38 capable of preventing the elastically deforming sheet 32 from moving from the 1 st part 30 to the opposite side of the 2 nd part 20. In the 2 nd stopper 38, at a position on the opposite side of the 1 st portion 30 from the 2 nd portion 20, at least a part of the 2 nd stopper 38 is located on the same radius as the elastically deforming piece 32 as viewed in the longitudinal direction. In other words, at least a part of the 2 nd stopper 38 is located at a position contacting the elastically deforming piece 32 in the longitudinal direction at a position on the opposite side of the 1 st part 30 from the 2 nd part 20. This can suppress the movement of the elastic deformation piece 32 to the opposite side of the 2 nd portion 20 when the heater is pulled out of the through hole 36, that is, can suppress the elastic deformation piece 32 from being pulled out of the 1 st portion 30 together with the heater. Therefore, even if the heater is pulled out from the through hole 36, the elastic deformation piece 32 can be left in the 1 st portion 30, and therefore, the used flavor-generating article 10 can be easily discarded.
In the example shown in fig. 4A, the 2 nd stopper 38 is a sealing sheet covering the end surface of the elastically deformable sheet 32 and the through hole 36. Specifically, the 2 nd stop 38 may extend in the radial direction of the 1 st portion 30 of the flavour generating article 10 and form a seam 38a at a substantially central portion thereof. Fig. 4B is a schematic view of the flavor generating article 10 after the heater is inserted. In fig. 4B, section 1, 30, is shown in cross-section. As shown in fig. 4B, when the heater is inserted into the through hole 36, the 2 nd stopper 38 is cut by the heater along the joint 38a, for example. By inserting the heater into the through-hole 36 so as to break the 2 nd stopper 38, the flavor generating article 10 can be heated by the heater while the 2 nd stopper 38 is positioned on the end surface of the elastically deforming sheet 32. Therefore, when the heater is pulled out of the through hole 36 after use, the elastic deformation piece 32 can be restrained from being pulled out of the 1 st portion 30 together with the heater by the 2 nd stopper 38 located on the end surface of the elastic deformation piece 32. The 2 nd stop 38 may be any form capable of preventing movement of the elastically deformable sheet 32 from the 1 st section 30 to the opposite side of the 2 nd section 20, such as a center hole filter.
Next, a description will be given of a flavor aspirator for heating the flavor generating article 10. Fig. 5 is a cross-sectional view showing a main portion of the fragrance aspirator 100 in the width direction of the heater 120. Fig. 6 is a cross-sectional view showing a main portion of the fragrance aspirator 100 in a thickness direction of the heater 120. The flavor aspirator 100 may constitute a smoking system with the flavor generating article 10. As shown in fig. 5 and 6, the flavor aspirator 100 includes a housing 110 and a heater 120. The housing 110 has an opening 112 at one end, and accommodates at least a part of the flavor-generating article 10 inserted into the opening 112 through the opening 112. The housing 110 is made of, for example, a resin, and is formed of, in particular, a metal such as PC (polycarbonate), ABS (Acrylonitrile-Butadiene-Styrene), acrylonitrile-Butadiene-Styrene (PEEK), PEEK (polyetheretherketone), a polymer alloy containing a plurality of polymers, or aluminum. Here, the housing 110 is configured such that a cross-sectional area of a cross section orthogonal to the longitudinal direction of the housing 110 is smallest near the opening 112.
In addition, the housing 110 has a swage guide 114 and a hold-down flange 116. The shaping guide 114 is provided in the opening 112, and deforms the cross-sectional shape of the flavor generating article 10 inserted into the housing 110. The pressing flange 116 is provided on the inner circumferential surface of the housing 110, and presses the flavor generating article 10 inserted into the housing 110 against the heater 120, thereby deforming the shape of the flavor generating article 10. The detailed configuration of the shaping guide 114 and the pressing flange 116 and the function of deforming the flavor generating article 10 will be described later.
In the illustrated example, the heater 120 is a flat plate-shaped PTC (positive temperature coefficient ) heater that is inserted into the flavor generating article 10 housed in the housing 110 and heats the flavor generating article 10 from the inside. The heater 120 deforms the shape of the flavor generating article 10 inserted into the housing 110 along the shape of the heater 120. The function of the heater 120 to deform the flavor generating article 10 will be described later. Here, the shaping guide 114, the pressing flange 116, and the heater 120 deform the shape of the flavor-generating article 10 after being accommodated in the housing 110, compared with the shape of the flavor-generating article 10 before being accommodated in the housing 110. The heater 120 may be plate-shaped, and is not limited to the resistance heating type heater 120 as in the present embodiment, and may be, for example, a heater that is used as a heating base and inductively heated by an induction coil.
Next, a relationship between the flavor generating article 10 and the housing 110 and the heater 120 when the flavor generating article 10 is housed in the flavor aspirator 100, that is, when the flavor generating article 10 is inserted from one end side to the other end side of the housing 110 will be described. Fig. 7 to 9 are sectional views showing a state in which the flavor generating article 10 is accommodated in the flavor aspirator 100. In fig. 7 to 9, the elastically deformable sheet 32 and the flavor-generating sheet 34 of the flavor-generating article 10 are shown as 1 annular sheet 33.
Fig. 7 shows a state in which the flavor generating article 10 passes through the shaping guide 114, with respect to a cross section in the width direction of the heater 120 and a cross section orthogonal to the longitudinal direction of the housing 110 at the inlet portion 118 of the shaping guide 114. Fig. 8 shows a state in which the flavor generating article 10 passes through the pressing flange 116, with respect to a cross section in the width direction of the heater 120 and a cross section orthogonal to the longitudinal direction of the housing 110 at the middle portion and the other end portion of the pressing flange 116. Fig. 9 shows a state in which the flavor generating article 10 is accommodated in a predetermined accommodation position of the housing 110, with respect to a cross section in the width direction of the heater 120 and a cross section orthogonal to the longitudinal direction of the housing 110 in the vicinity of the other end side end portion of the heater 120.
As shown in fig. 7, the shaping guide 114 has a tapered portion 117 and an inlet portion 118. The tapered portion 117 is formed so as to expand toward one end of the housing 110, and guides insertion of the flavor generating article 10 into the flavor aspirator 100. Preferably, the largest diameter of the opening 112 of the flavour aspirator 100 is larger than the largest diameter of the flavour generating article 10, and the smallest diameter of the opening 112 is smaller than the smallest diameter of the flavour generating article 10. In this case, by inserting the flavor generating article 10 into the opening 112 of the flavor aspirator 100, the flavor generating article 10 is deformed in accordance with the shape of the opening 112. Specifically, the flavor generating article 10 is deformed in accordance with the minimum diameter of the opening 112, and its cross section is deformed flat. Thus, the elastically deforming sheet 32 of the flavor generating article 10 contacts or approaches the heater 120, and the flavor generating article 10 can be efficiently heated. The opening 112 may be a portion having a smallest cross-sectional area in the opening 112 of the flavor aspirator 100 into which the flavor generating article 10 is inserted. Specifically, in the example shown in fig. 7, the opening 112 herein may be the inlet portion 118. The inlet 118 has an elliptical cross section, and may be configured such that the longer diameter is larger than the diameter of the flavor-generating article 10 after being accommodated in the housing 110, and the shorter diameter is substantially the same length as the diameter of the flavor-generating article 10 before being accommodated in the housing 110. The inlet portion 118 may be formed such that the inner circumference is shorter than the outer circumference of the flavor-generating article 10.
As shown in fig. 8, the heater 120 is configured to have a sharp shape and to have a width that expands toward the other end side. Thus, as the flavour generating article 10 is inserted through the shaping guide 114, the shape of the flavour generating article 10 will be deformed along the shape of the heater 120. Specifically, the heater 120 is a plate-shaped heater having a1 st surface 120a and a2 nd surface 120b opposite to the 1 st surface 120a, and as shown in fig. 8, when the heater 120 is inserted into the through hole 36, the elastically deforming piece 32 is deformed so that the distance between the elastically deforming piece 32 and the 1 st surface 120a or the 2 nd surface 120b is reduced. As a result, the elastic deformation sheet 32 is deformed, and the elastic deformation sheet 32 contacts or approaches the 1 st surface 120a or the 2 nd surface 120b of the heater 120, so that the flavor generating article 10 can be efficiently heated.
The diameter of the through hole 36 of the flavor generating article 10 is preferably smaller than the maximum length of the heater 120 perpendicular to the insertion direction. In this case, as shown in fig. 8, the heater 120 is inserted into the through hole 36, whereby the through hole 36 can be expanded by the heater 120. Thus, the elastically deformable sheet 32 of the flavor generating article 10 can be deformed. As in the illustrated example, when the heater 120 is plate-shaped, the cross-sectional shape of the through-hole 36 is deformed to be flat by the heater 120, and accordingly, the elastic deformation piece 32 can be brought into contact with or close to the main surface of the plate-shaped heater 120. In the case where the heater 120 is needle-shaped, the elastic deformation piece 32 is compressed in the thickness direction when the heater 120 is inserted into the through hole 36, and the elastic deformation piece 32 may contact or come close to the circumferential surface of the heater 120. Thus, the flavor generating article 10 can be efficiently heated. Further, the heater 120 expands the flavor generating article 10, so that the flavor generating article 10 can be prevented from falling off.
The pressing flange 116 is provided on the inner circumferential surface of the housing 110 in the thickness direction of the heater 120, and is formed of a pair of tapered surfaces facing each other (see fig. 6). The pressing flange 116 is disposed so as to overlap with a region in which the width of the heater 120 gradually increases along the longitudinal direction of the housing 110. Here, the pressing flange 116 is configured to gradually extend the distance protruding toward the other end side of the housing 110, and is configured to maximize the protruding distance at the position where the width of the heater 120 is maximized. At this time, the length between the tapered surfaces is smaller than the diameter of the flavor generating article 10. Thus, when the flavor generating article 10 passes through the pressing flange 116, the pressing flange 116 abuts against the flavor generating article 10 expanded in the width direction of the heater 120 in the thickness direction of the heater 120, thereby deforming the flavor generating article 10 into a flat shape. In addition, by pressing the flange 116 against the flavor-generating article 10, the flavor-generating article 10 can be prevented from falling off.
The inner circumference of the through hole 36 of the flavor generating article 10 is preferably equal to or greater than the outer circumference of the heater 120. As a result, as shown in fig. 9, even when the flavor generating article 10 and the through-hole 36 are deformed, a gap can be formed between the heater 120 and the flavor generating article 10 (the inner surface of the flavor generating article 10 defining the through-hole 36), and therefore, an increase in suction resistance can be prevented, and flavor or aerosol generated by the flavor generating article 10 can be more reliably delivered to the user through the gap.
Fig. 10 is a side view of another embodiment of a scent-generating article 10. Fig. 10 shows a side view of the scent-generating article of fig. 1, looking at 2-2. The flavor generating article 10 shown in fig. 10 is different from the flavor generating article 10 shown in fig. 1 and 2 in the structure of the elastic deformation sheet 32. Specifically, the elastically deformable sheet 32 of the flavor-generating article 10 shown in fig. 10 is a non-tobacco sheet having a wavy cross section as viewed in the longitudinal direction. In the illustrated example, the non-tobacco sheet is deformed in the waveform cross section, so that the elastic deformation sheet 32 can be elastically deformed in the thickness direction. The non-tobacco sheet having a wave-shaped cross section has gaps (between waves) along the longitudinal direction thereof, and can define a flow path through which the flavor or the like generated by the flavor-generating article 10 passes. In the example shown in fig. 10, the flavor generating sheet 34 has only the tobacco sheet 34b.
The embodiments of the present application have been described above, but the present application is not limited to the above embodiments, and various modifications are possible within the scope of the technical ideas described in the claims, the specification, and the drawings. Any shape and material not directly described in the specification and drawings are within the technical spirit of the present application as long as they can function and effect of the present application.
Claims (20)
1. A flavor generating article which generates flavor by heating,
The flavor generating article has:
Through-hole capable of being inserted into heater, and
A tubular elastic deformation piece defining the through hole,
The elastically deformable sheet is capable of being elastically deformed in a thickness direction thereof.
2. The flavor generating article according to claim 1, wherein,
The elastically deformable sheet has a volume void ratio of 85% or more and 95% or less.
3. The flavor generating article according to claim 1 or 2, wherein,
The elastically deformable sheet has an air flow resistance of 0mmH 2 O or more and 150mmH 2 O or less.
4. The flavor generating article according to claim 1 to 3, wherein,
The elastically deformable sheet is a non-tobacco sheet having a weight per unit area of 30g/m 2 or more and 100g/m 2 or less.
5. The flavor generating article according to any one of claims 1 to 4, wherein,
The elastically deformable sheet is a non-tobacco sheet carrying an aerosol source or a flavour generating substrate.
6. The flavor generating article according to any one of claims 1 to 5, wherein,
The elastic deformation sheet is a non-tobacco sheet having a wave-shaped cross section as viewed from the longitudinal direction.
7. The flavor-generating article according to any one of claims 1 to 6, comprising a flavor-generating sheet located inside the elastically deformable sheet.
8. The flavor generating article according to claim 7, wherein,
The flavour generating sheet comprises a negative carrier aerosol source or a non-tobacco sheet of a flavour generating substrate.
9. The flavor generating article according to claim 7, wherein,
The flavour generating sheet comprises a tobacco sheet.
10. The flavor generating article according to claim 7, wherein,
The fragrance-generating sheet comprises:
Tobacco sheet
A negative carrier gas sol source or a non-tobacco sheet of a flavour generating substrate.
11. The flavor generating article according to any one of claims 1 to 10, having:
part 1, which generates a fragrance by heating and comprises the elastically deformable sheet, and
And a2 nd portion adjacent to the 1 st portion in a longitudinal direction and passing the fragrance generated by the 1 st portion.
12. The flavor generating article according to claim 11, wherein,
The 2 nd portion has a1 st stopper preventing the elastically deforming piece from moving from the 1 st portion to the 2 nd portion.
13. The flavor generating article according to claim 11 or 12, having a2 nd stopper that prevents the elastically deformable sheet from moving from the 1 st part to an opposite side of the 2 nd part.
14. The flavor generating article according to claim 13, wherein,
The 2 nd stop block is a sealing sheet covering the end face of the elastic deformation sheet and the through hole.
15. The flavor generating article according to any one of claims 1 to 14, which has an outer wrap sheet surrounding an outer side of the elastically deformable sheet,
The outer wrapper sheet has a weight per unit area of 50g/m 2 or more and 100g/m 2 or less.
16. A smoking system, having:
The flavor generating article according to any one of claims 1 to 15, and
A flavor aspirator having the heater,
The diameter of the through hole is smaller than the maximum length of the heater orthogonal to the insertion direction.
17. A smoking system, having:
The flavor generating article according to any one of claims 1 to 15, and
A flavor aspirator having the heater,
The flavour aspirator has an opening to receive the flavour generating article,
The maximum diameter of the opening is larger than the maximum diameter of the flavour generating article,
The smallest diameter of the opening is smaller than the smallest diameter of the flavour generating article.
18. A smoking system according to claim 16 or 17, wherein,
The inner circumference of the through hole is equal to or more than the outer circumference of the heater.
19. A smoking system according to any one of claims 16 to 18, wherein,
The heater is a plate-shaped heater having a 1 st surface and a2 nd surface facing the 1 st surface,
When the plate-like heater is inserted into the through hole, the elastically deforming piece is deformed such that a distance between the elastically deforming piece and the 1 st or 2 nd surface is reduced.
20. A smoking system according to any one of claims 16 to 19, wherein,
The through hole is defined by an inner surface of the elastically deformable sheet or the flavor generating sheet.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2021/042723 WO2023089803A1 (en) | 2021-11-22 | 2021-11-22 | Flavor-generating substance and smoking system |
Publications (1)
Publication Number | Publication Date |
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CN118284345A true CN118284345A (en) | 2024-07-02 |
Family
ID=86396521
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN202180104369.5A Pending CN118284345A (en) | 2021-11-22 | 2021-11-22 | Flavor generating article and smoking system |
Country Status (6)
Country | Link |
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US (1) | US20240277040A1 (en) |
EP (1) | EP4437863A1 (en) |
JP (1) | JPWO2023089803A1 (en) |
KR (1) | KR20240113528A (en) |
CN (1) | CN118284345A (en) |
WO (1) | WO2023089803A1 (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2620491C2 (en) * | 2011-12-30 | 2017-05-25 | Филип Моррис Продактс С.А. | Smoking product with front plug and aerosol-forming substrate and method of its use |
CN112218548B (en) | 2018-06-27 | 2023-04-04 | 菲利普莫里斯生产公司 | Aerosol-generating article and apparatus for forming an aerosol-generating article |
GB201810994D0 (en) | 2018-07-04 | 2018-08-15 | British American Tobacco Investments Ltd | A consumable article for use with an apparatus for heating aersolisable material |
CN113710108A (en) * | 2019-04-18 | 2021-11-26 | 日本烟草产业株式会社 | Heating type cigarette |
-
2021
- 2021-11-22 WO PCT/JP2021/042723 patent/WO2023089803A1/en active Application Filing
- 2021-11-22 KR KR1020247020520A patent/KR20240113528A/en unknown
- 2021-11-22 EP EP21964818.5A patent/EP4437863A1/en active Pending
- 2021-11-22 JP JP2023562077A patent/JPWO2023089803A1/ja active Pending
- 2021-11-22 CN CN202180104369.5A patent/CN118284345A/en active Pending
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2024
- 2024-04-30 US US18/650,187 patent/US20240277040A1/en active Pending
Also Published As
Publication number | Publication date |
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KR20240113528A (en) | 2024-07-22 |
EP4437863A1 (en) | 2024-10-02 |
JPWO2023089803A1 (en) | 2023-05-25 |
US20240277040A1 (en) | 2024-08-22 |
WO2023089803A1 (en) | 2023-05-25 |
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