CN118084228A - Electrolytic reduction water and electrolytic oxidation water processing method and electrolytic device thereof - Google Patents

Electrolytic reduction water and electrolytic oxidation water processing method and electrolytic device thereof Download PDF

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CN118084228A
CN118084228A CN202311574384.3A CN202311574384A CN118084228A CN 118084228 A CN118084228 A CN 118084228A CN 202311574384 A CN202311574384 A CN 202311574384A CN 118084228 A CN118084228 A CN 118084228A
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water
electrolytic
outer sleeve
electrolysis
electrode plate
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吴�琳
宋新安
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Henan Fuhydrokang Health Technology Co ltd
CATAS Environment and Plant Protection Institute
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Henan Fuhydrokang Health Technology Co ltd
CATAS Environment and Plant Protection Institute
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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Abstract

The invention discloses a processing method of electrolytic reduction water and electrolytic oxidation water and an electrolytic device thereof, belonging to the technical field of electrolytic tanks and solving the problems that the prior water resource is wasted, and in the process of preparing hydrogen-rich water, water which mostly contains impurities and minerals beneficial to human bodies is discharged as waste water, only hydrogen is emphasized, the effect of the minerals on the human bodies is ignored, and moreover, the hydrogen is insoluble in water; the method comprises the following steps: filtering tap water through a pre-filter; magnetizing the filtered water while passing through the pipeline and then entering the inside of the electrolysis device; the water entering the interior is subjected to synchronous ultrasonic vibration and electrolysis through an electrolysis device; the continuous circulation electrolysis high-flow separation can be realized, the ingenious application of high magnetization and ultrasonic technology is realized, the problems of small water flow, low hydrogen concentration and easy scaling of the existing electrolytic tank are solved, the electrolysis effect is better, the water flow can be large or small, the hydrogen concentration is improved, and scaling is not easy to occur.

Description

Electrolytic reduction water and electrolytic oxidation water processing method and electrolytic device thereof
Technical Field
The invention belongs to the technical field of electrolytic tanks, and particularly relates to the technical field of high-magnetization ultrasonic continuous circulation electrolysis high-flow electrolytic tanks.
Background
A great deal of research is carried out on the electrolytic water at home and abroad, and after more than 90 years of development, the electrolytic water is closely related to the production and life of people: the electrolyzed water has good effects on drinking by people and livestock, medical care, agricultural application and the like. The water electrolysis machine originates from japan and is widely accepted, but the problems of different degrees appear from japan machines to china or europe and america, and the following problems mainly exist:
1. the water yield is small, and the large water works, farms and agricultural applications cannot be satisfied;
2. the electrolytic tank is easy to scale, the electrolytic effect is affected, and the electric energy consumption is increased;
3. The hydrogen concentration of the water electrolysis machine is lower, and the hydrogen demand of people cannot be met.
The electrolytic tank is a heart of the water electrolysis machine, is a core component of the water electrolysis machine, and is mostly 3-plate 2-tank or 5-plate 4-tank in the market at present. On the premise of the same material, the more the number of the electrode plates is, the better the electrolysis effect is, and the smaller the load born by each electrode plate is, so the longer the service life is. The life of an electrolyzer is mainly dependent on the life of the electrolyzer, which in turn is dependent on the life of the electrode plates. In other words, it means how long the electrode plate can be electrolyzed in total, and the life of the electrode plate depends on the material and manufacturing process, and the scale prevention and removal technology of the electrolytic tank and the electrolytic power.
The electrode plate cleaning technology comprises the following steps: the water electrolysis machine is most prone to the problem of scaling of the electrode plate on the cathode side of the electrolytic cell, which is unavoidable during the electrolysis process, similar to the electroplating principle. In the electrolysis process, mineral ions such as calcium, magnesium, sodium, potassium and the like with positive charges in water at the anode side, including ultra-trace metal particles released from the anode plate, move to the cathode side, so that weakly alkaline reduced water is generated; at the same time, negatively charged chloride ions, sulfide ions and the like in the water at the cathode side move to the anode to generate weakly acidic oxidized water commonly called acid water. In the process, mineral components are continuously adsorbed on the cathode plate in a bit manner, a layer of mineral crystals (commonly called scale) is formed over time to cover the surface of the cathode plate, and if the mineral crystals are left alone, the electrolysis effect is greatly reduced until the whole electrolytic tank stops working due to the blockage of the scale.
In summary, most of the electrolytic tanks of the water electrolysers in the market at present are flat plate type electrolytic tanks, in order to increase the water flow, the area of the flat plate needs to be increased, and the water flow is unevenly distributed along with the pressure change. In order to increase the hydrogen content, electrolytic cells or stacked electrode plates are required to be connected in series, so that the water flow resistance is increased, the flow speed is reduced, scaling is easy, and the water yield is small. The prior solution on the market is that the pure water physical hydrogen dissolution technology is generally adopted, namely, the pure water is used for preparing hydrogen through electrolysis, then the hydrogen is blended into the pure water without mineral substances through physical means, and the method has the advantages of large water yield, high hydrogen content, no scaling and the like, but still has the problems: 1. waste water resources, and in the process of preparing purified water, most of water containing impurities and minerals beneficial to human bodies is discharged as waste water, and oxidation-reduction potential and the like are the same as tap water and are positive. 2. Only hydrogen is emphasized, but the effect of minerals on the human body is neglected, and moreover, hydrogen is insoluble in water; 3. the oxidized acidic water for sterilization and disinfection cannot be produced. The purified water physical hydrogen dissolving technology can not meet the requirements in the aspects of drinking by people and livestock, medical care and agricultural application.
Disclosure of Invention
The invention aims at: the method for processing the electrolytic reduction water and the electrolytic oxidation water and the electrolytic device thereof are provided to solve the problems that firstly, water resources are wasted, most of water containing impurities and minerals beneficial to human bodies is discharged as waste water in the process of preparing hydrogen-rich water, and secondly, only hydrogen is emphasized, the effect of the minerals on the human bodies is ignored, and moreover, hydrogen is insoluble in water; furthermore, the problem of sterilizing and disinfecting oxidized acidic water cannot be generated.
The technical scheme adopted by the invention is as follows:
An electrolytic reduction water and electrolytic oxidation water processing method comprises the following steps:
and (3) a step of: filtering tap water through a pre-filter;
And II: magnetizing the filtered water while passing through the pipeline and then entering the inside of the electrolysis device;
Thirdly,: the water entering the interior is subjected to synchronous ultrasonic vibration and electrolysis through an electrolysis device;
fourth, the method comprises the following steps: magnetizing the processed water through a pipeline and discharging alkaline water and weak acid water;
the pre-filter consists of a customized thickened deep sea diatom ooze ceramic filter element and two sintered active carbon filter elements.
The utility model provides an electrolytic reduction water and electrolytic oxidation water electrolysis device, includes outer sleeve pipe, outer sleeve pipe's one end dismantlement formula is connected with outlet pipe A, outer sleeve pipe's the other end dismantlement formula is connected with and is used for carrying out the vibrating structure that shakes to the inside water of outer sleeve pipe, outer sleeve pipe's inside is provided with the processing structure that can improve inside aquatic hydrogen concentration, outer sleeve pipe's side distributes has inlet tube and outlet pipe B, magnet is all installed to inlet tube, outlet pipe B and outlet pipe A's side.
Further, the treatment structure comprises an outer negative electrode plate, an outer bracket of the electrolytic cell, an outer screen plate, an ionic membrane, an inner screen plate, an inner bracket of the electrolytic cell and an inner positive electrode plate which are sequentially distributed in the outer sleeve from outside to inside, and the outer negative electrode plate is tightly attached to the inner wall of the outer sleeve.
Furthermore, a water outlet plug is arranged between the outer sleeve and the water outlet pipe A, and the outer wall of the water outlet plug extending into the outer sleeve is tangent to the inner wall of the inner positive electrode plate.
Furthermore, the water outlet of the water inlet pipe is arranged between the outer negative electrode plate and the outer sleeve, the water inlet of the water outlet pipe B is also arranged between the outer negative electrode plate and the outer bracket of the electrolytic tank, and the inner cavities of the water inlet pipe and the inner positive electrode plate are communicated with the water outlet pipe A through the ion membrane.
Further, the vibration structure comprises a protective sleeve arranged on the outer sleeve, an ultrasonic generator is arranged in the protective sleeve, an ultrasonic generating end of the ultrasonic generator is arranged at the bottom of the outer sleeve, and a water inlet pipe is arranged at a position close to the ultrasonic generator.
Furthermore, sealing gaskets are arranged between the outer sleeve and the protective sleeve and between the outer sleeve and the water outlet plug, and the sealing gaskets are made of silica gel.
Further, the outer negative electrode plate and the inner positive electrode plate are both made of platinum titanium plates.
In summary, due to the adoption of the technical scheme, the beneficial effects of the invention are as follows:
The electrolytic tank has the advantages of small occupied area, large electrolytic area, no dead angle in water flow, rapid separation and full electrolysis, can realize continuous circulation electrolysis and large-flow separation, and the ingenious application of high magnetization and ultrasonic technology, solves the problem that the electrolytic tank is easy to scale, has better electrolytic effect, improves the hydrogen concentration, and completely meets the requirements for detecting various data.
The tap water is filtered by the preposed filter when the device is used, then the filtered tap water is treated by the device and enters the high-magnetization device, the properties of the water such as surface tension, dissolving power, pH value and density osmotic power are changed under the action of a strong magnetic field, and the fine changes such as the rising of the dissolving power, activity and osmotic power can influence the solubility and crystallization process of magnesium, calcium salt and metal ion compounds, so that dense mineral calcite crystals are converted into soft and fine crystals, the dense mineral calcite crystals are more favorable for being washed away by water flow, the scale prevention and removal effects are achieved, the scale formation of an electrolytic tank is prevented, the ionization effect of the electrolytic tank is enhanced, the concentration of dissolved hydrogen and ionized mineral substances is improved, and meanwhile, the service life of an electrode plate is also greatly prolonged.
The ultrasonic generator is arranged, because positive-valence mineral components contained in raw water are gathered on the surface of the cathode plate and negative-valence mineral components are gathered on the surface of the anode plate when hard water is electrolyzed, rapid electroplating reaction can be generated, overload current leads to increase of power consumption, mineral substances electroplated on the electrode plate are rapidly separated by using ultrasonic high-frequency vibration in the electrolysis process, meanwhile, atomic hydrogen, active hydrogen and hydrogen separated out of the cathode tank rapidly leave the vicinity of the cathode plate, oxygen generated by the anode tank rapidly leaves the vicinity of the anode plate, conductivity is enhanced, power consumption is reduced, atomic hydrogen, active hydrogen and hydrogen in the cathode tank are well fused into water, the atomic hydrogen and active hydrogen are adsorbed or depended on the ionized mineral substances, the concentration of dissolved hydrogen is also greatly improved along with water flow in the ultrasonic high-frequency vibration process, the purposes of scale prevention and removal and hydrogen concentration improvement are achieved, and meanwhile, the service life of the electrode plate is also greatly prolonged.
Baishi Longhun, hecun Zong Dian, page 74, health Start Water: "water passes rapidly in a strong magnetic field, generating an electric current and producing active hydrogen. The water is subjected to ultrasonic treatment to generate high pressure and high voltage, and thus is decomposed. The mineral dissolves and brings electrons to the hydrogen ion, and active hydrogen is generated. The high magnetizing device and the ultrasonic technology are applied to the electrolytic tank, so that not only is the scale prevention and removal carried out, but also the electrolysis efficiency is enhanced, and the concentration of dissolved hydrogen is improved.
Drawings
FIG. 1 is a water treatment flow chart of the present invention;
FIG. 2 is a schematic plan view of an electrolytic device according to the present invention;
FIG. 3 is a schematic cross-sectional view of an electrolytic device according to the present invention;
FIG. 4 is a schematic view showing the internal structure of the electrolytic device of the present invention;
FIG. 5 is a schematic view of the principle of the electrolytic reaction of water according to the present invention;
FIG. 6 is a schematic representation of the stable presence of active hydrogen adsorption on minerals according to the present invention;
FIG. 7 is a schematic view of H+e- →H-of the present invention;
FIG. 8 is a schematic view of the electrolytic principle of the present invention;
1-an outer sleeve; 2-an ultrasonic generator; 3-an inner layer circular tube sealing cover; 4-magnet; 5-a water inlet pipe; 6-a water outlet pipe B; 7-a water outlet pipe A; 8-protecting sleeve; 9-a gasket; 10-a water outlet plug; 11-an outer negative electrode plate; 12-an outer screen; 13-ion membrane; 14-an inner screen; 15-an inner positive electrode plate; 16-an outer bracket of the electrolytic cell; 17-an inner bracket of the electrolytic tank.
Detailed Description
The present invention will be described in further detail with reference to the drawings and examples, in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
Examples
As shown in figures 1 to 8 of the drawings,
An electrolytic reduction water and electrolytic oxidation water processing method comprises the following steps:
and (3) a step of: filtering tap water through a pre-filter;
And II: magnetizing the filtered water while passing through the pipeline and then entering the inside of the electrolysis device; tap water enters a high magnetization device after being filtered, the surface tension, the dissolution force, the pH value, the density permeability and other properties of the water are changed under the action of a strong magnetic field, and the slight changes, such as the rising of the dissolution force, the activity and the permeability, influence the solubility and the crystallization process of magnesium, calcium salt and metal ion compounds, so that compact mineral calcite crystals are converted into soft and fine crystals, the dense mineral calcite crystals are more favorable for being washed away by water, the anti-scaling and descaling effects are achieved, the scaling of an electrolytic tank is prevented, the ionization effect of the electrolytic tank is enhanced, the concentration of dissolved hydrogen and the concentration of ionized mineral substances are improved, and meanwhile, the service life of an electrode plate is also greatly prolonged.
Thirdly,: the water entering the interior is subjected to synchronous ultrasonic vibration and electrolysis through an electrolysis device;
fourth, the method comprises the following steps: magnetizing the processed water through a pipeline and discharging alkaline water and weak acid water;
The front filter consists of a customized thickened deep sea diatom ooze ceramic filter core and two sintered active carbon filter cores, the thickened ceramic diatom ooze filter core can well remove impurities such as sediment, rust, organic matters and bacteria, and can be repeatedly cleaned and used, the sintered active carbon filter core can remove peculiar smell and improve taste, the set of filter system not only removes harmful substances to human bodies, but also well retains mineral matters and trace elements, and the filter system also has a good protection effect on an ion membrane of an electrolytic tank.
Because positive-valence mineral components contained in raw water gather on the surface of a cathode plate and negative-valence mineral components gather on the surface of an anode plate when hard water is electrolyzed, rapid electroplating reaction can be generated, overload current leads to increase of power consumption, mineral substances electroplated on the electrode plate are rapidly separated by using ultrasonic high-frequency vibration in the electrolysis process, meanwhile, atomic hydrogen, active hydrogen and hydrogen separated out of a cathode tank rapidly leave the vicinity of the cathode plate, oxygen generated by the anode tank rapidly leaves the vicinity of the anode plate, conductivity is enhanced, power consumption is reduced, the atomic hydrogen, the active hydrogen and the hydrogen in the cathode tank are well fused into water, the atomic hydrogen and the active hydrogen are adsorbed or depended on ionized mineral substances, and are smoothly discharged along with water flow in the ultrasonic high-frequency vibration process, so that the purposes of scale prevention and removal and hydrogen concentration improvement are achieved, and meanwhile, the service life of the electrode plate is also greatly prolonged.
Water passes through the magnetic field rapidly, so that current is generated and active hydrogen is generated. The water is subjected to ultrasonic treatment to generate high pressure and high voltage, and thus is decomposed. The mineral dissolves and brings electrons to the hydrogen ion, and active hydrogen is generated. The high magnetizing device and the ultrasonic technology are applied to the electrolytic tank, so that not only is the scale prevention and removal carried out, but also the electrolysis efficiency is enhanced, and the concentration of dissolved hydrogen is improved.
The cylindrical continuous circulation electrolysis high-flow electrolytic tank can be long or short according to the requirements for electrolyzed water, the diameter of the cylindrical electrolytic tank can be large or small, the electrolysis strength can be adjusted on a control circuit board according to the requirements, and the indexes such as PH value, dissolved hydrogen concentration, available chlorine and the like can be adjusted according to the requirements. Municipal tap water is filtered by a primary water supply pre-filter, a secondary electrolytic tank water inlet high magnetization device, a tertiary electrolytic tank bottom ultrasonic device, and enters a four-stage cylindrical continuous circulation electrolysis high-flow electrolytic tank for strong electrolytic separation, and chemical reaction is generated, wherein the steps are as follows:
Fig. 5: water electrolysis reaction;
fig. 6: the active hydrogen is adsorbed on mineral substances and stably exists
As shown in fig. 5 and 6:
Professor Baishi, university of ninety, university of japan, synergetic hospital, long river village Zong Dian, beginning with water for health: since water has the characteristic of "always decomposing into hydrogen ions and hydroxide ions", it is sensitive to electric current, and it is immediately decomposed by passing a small amount of electric current, and active hydrogen is generated first, followed by hydrogen gas. How does the active hydrogen stabilize in water? It is well known that active hydrogen, i.e., a hydrogen atom, is the smallest atom that can be adsorbed and stored on almost all metals. We have established the hypothesis that "active hydrogen in electrolytically reduced water is adsorbed and stored on minerals to be stably present". However, the mineral is neither an ion in the traditional sense nor a large metal which is deposited in water, and the size of the mineral is only about 1 nanometer (one billion molecules) and is a very fine mineral called a "metal nano colloid" or a "nano beam". Such fine metal nano-colloids, as if dissolved in water, are uniformly distributed in water and can exist stably for a long period of time. The smaller the volume of the metal nano-colloid, the more easily it is absorbed by cells like water and rapidly spreads throughout the whole body.
Incidentally, the size of the hydrogen atom is 0.1 nm, and the size of the water molecule is 0.3 nm. As is known, the cells have a "water channel" of 0.3 to 1.3 nanometers in diameter to allow water to pass through rapidly. It is better if the metal nano-gels in the electrolytically reduced water can pass through the "water channel" like water.
It was found that when the electrolytic treatment is performed on ultrapure water containing only sodium hydroxide, a part of platinum is deposited on the platinum electrode, and the platinum content in the electrolytic reduced water has a close relationship with the "free radical elimination energy" thereof. In fact, we have found that by allowing active hydrogen to adsorb onto pure platinum, it is possible to carry "free radical scavenging energy", and that the synthetic platinum colloid also has the same characteristics as electrolytically reduced water. In fact, it was confirmed by observation with an electron microscope that the electrolytic reduced water contained platinum colloid, the average diameter of which was about 1 nm. At the same time, observation using the "dynamic light scattering method" shows that there is likely to be some colloid with a diameter less than 1 nm in water beyond our measurement limit.
It has been demonstrated that metal nanocolloids that act as "carriers" or "hosts" for active hydrogen are not limited to platinum alone, but other metals can also act as "hosts" for active hydrogen. The group of professor Tian Yishang, university of ninety, university of japan, university of academy of sciences, et al claims: active hydrogen is stable in aqueous solution for more than one year after being placed in the silicic acid compound.
Baishi, hecun Zong Dian, p 72, J.H. from Water: active hydrogen is extremely unstable and highly reactive, and is likely to react with surrounding materials immediately to change its properties. It is believed that after the active hydrogen is adsorbed and stored on the metal colloid, its reducing activity is reduced to such an extent that it reacts only with the free radicals. This characteristic is pleasing, and means that even in an environment where various substances are mixed with each other such as living bodies, the activity is not easily lost, and the living bodies can exist stably for a long period of time (fig. 6).
The water flow enters the water outlet high magnetization device after circulating electrolysis, and under the action of a strong magnetic field, water molecules are fully clustered into small molecules, so that the concentration of dissolved hydrogen is more favorably enhanced.
Cathode water (reduced water) properties:
pH value: is alkaline and has pH of 8.5-9.5
Dissolving hydrogen: contains abundant atomic hydrogen, active hydrogen (negative hydrogen ion), and hydrogen gas
Has reducibility
The oxidation-reduction potential is "negative", (ORP: -250-750 mV)
Small molecular group: strong dissolving power and penetrating power
The cation is increased, and the plasmas of calcium, magnesium, potassium and sodium are improved by 15 to 20 percent
H2O → H++OH-
2H2O+2e- → H2 + 2OH-
2H+ + 2e- → H2
H+ + e- → H
H + e- → H-
Fig. 7: h+e- & gtH-
It is well known that hydrogen is the smallest atom in the universe and, for electrolysis reasons, becomes a "negative hydrogen ion" when it gets an electron at the cathode, in fact a negatively charged hydrogen atom.
Atomic hydrogen originally carries only one electron, but becomes a "negative hydrogen ion" when it has one more electron. Negative hydrogen ions work in reverse with free radicals. The free radical is "rob the electron of the person, make oneself reduce, make the other side oxidize", and the negative hydrogen ion is "offer the electron, help the other side reduce, inhibit its oxidation". That is, it has a reducing effect, i.e. "antioxidant ability".
When the free radical is to rob electrons from other cells or tissues, the negative hydrogen ions can timely release electrons to the cells or tissues, so that the free radical is neutralized, and the oxidative damage and destruction of the cells or tissues caused by the free radical are avoided. This is the principle of antioxidation of negative hydrogen ions. Although vitamin, multi-fifene and coenzyme Q10 nutritional supplements have the same effect, the absorption effect is affected by the gastrointestinal environment, the dosage is limited, and meanwhile, the part of the body which is not absorbed completely becomes waste residues to wait for being excreted. The negative hydrogen ion is most characterized in that it does not generate any waste residue of physical burden, because it becomes water after neutralization with free radicals. Water is safe, has no side effects, is a substance essential to the body, and is either absorbed by the body or excreted.
Effect of reducing water by electrolysis to remove free radical: the university of ninety, university of white and white professor koku, using cultured cells, conducted comparative experiments on several reducing effect water and antioxidants for scavenging free radicals, the results are shown below:
1. Day Tian Tian inland waters (japan), radical scavenging rate was 20%;
2. nordena natural water (germany), radical scavenging rate 24%;
3. toract natural water (mexico) with radical scavenging of 22%;
4. reducing water by electrolysis, wherein the free radical clearance rate is 25%;
5. vitamin C with a free radical scavenging rate of 22%;
6. Mineral water is sold in the market, and the inside of cells is oxidized by 10%;
7. tap water, the inside of the cell was oxidized by 25%.
Wherein Japanese day Tian Tian inland waters, germany's Nodina natural water and Mexico's Torax natural water are all world-known odd-numbered water, and the electrolytic reduction water is water rich in dissolved hydrogen generated from the cathode side of an electrolytic tank built in the electrolytic reduction water machine.
The best radical scavenging effect is electrolytic reduction of water.
The concentration of calcium and magnesium ions in the electrolyzed reduced water is about 15 to 20 percent higher than that of the raw water before electrolysis on average, and the electrolyzed reduced water is easier to be absorbed by the body, so the electrolyzed reduced water is beneficial to supplementing mineral substances and microelements to the body and strengthening bones.
Is rich in dissolved hydrogen: as described above, in the electrolysis of tap water containing an electrolyte, a large amount of hydrogen gas is generated at the cathode side, and most of the hydrogen gas exists in the water in the form of hydrogen bubbles, and atomic hydrogen is adsorbed on the mineral nano-ions as a host, which also includes ultra-trace platinum nano-ions precipitated from the platinum coating of the electrode plate. They are dissolved in the electrolytic reduced water and are therefore called "dissolved hydrogen", which is also a source of excellent "antioxidation, radical scavenging" characteristics for the electrolytic reduced water.
Anode water (oxidation water) characteristics:
pH value: acidic and with pH 4.5-5.5
Containing oxygen
Has oxidizing property (oxidant)
Oxidation-reduction potential is "positive," ORP: +750- +1100
Anion increase: chloride, sulfate, nitrate … …
2H2O-4e- → 4H++O2
2Cl- - 2 e- → Cl2
Cl2+H2O → HCl+HClO
The electrolysis principle is as shown in fig. 8: according to the principle of positive and negative absorption, anionic substances such as chloride ions, sulfate radicals, nitrate ions and the like in the water at the cathode side can pass through the ionic membrane to move to the anode side, so that the hydrogen ions are increased, the oxygen content is increased, while cations such as calcium, magnesium, potassium, sodium ions and the like in the water at the anode side reversely move to the cathode side, the hydroxyl ions are increased, and the hydrogen content is increased. Therefore, the water generated at the cathode side contains rich active hydrogen, hydroxyl ions and ionic minerals, has antioxidation property, can remove free radicals, is slightly alkaline, is called as electrolytic reduction water or alkaline ion water, is mainly used for daily drinking and pickling vegetables and fruits, removing peculiar smell of food materials, brewing tea or coffee, cooking and the like, and the water generated at the anode side contains rich acid radical ions and oxygen, has oxidation property and is acidic, is called electrolytic oxidation water or acidic water, and is mainly suitable for external use, such as beauty care, cleaning and disinfection and the like.
The electrolytic reduction water has seven characteristics: 1. the tap water does not contain impurities, bacteria, viruses, residual chlorine and other harmful substances in tap water; 2. the product is rich in dissolved hydrogen, exists in the form of atomic hydrogen and hydrogen bubbles, has strong antioxidation, and can inhibit oxidative damage of free radicals to the body. Meanwhile, the buffer has the effect of neutralizing body acid, is beneficial to relieving the acidification trend of the body and lightens the burden of a buffer system; 3. small molecular groups have strong dissolving power and penetrating power and are easy to be absorbed. The water-soluble gel has a dissolving power which is about 2 times that of common water, and is beneficial to body water supplementing and metabolic waste discharging in the body; 4. contains rich ionic calcium, magnesium, sodium and potassium minerals, and is easier to absorb than compound minerals; the PH value is 8.5-10.0, and the product is alkalescent. However, too high a pH is not necessary in practice; 6. the oxidation-reduction potential ORP as a reference indicator is negative, known as "negative potential", and sometimes even below-250 mV. While the ORP of normal water is substantially positive. The higher the positive value, the more oxidizing and the greater the risk of oxidative damage to the body. 7. The antioxidant activity of the electrolytic reduced water is difficult to maintain for a long time, and boiling, shaking or shaking and sunlight irradiation affect the activity, so that the electrolytic reduced water is preferably prepared as a drink. The mineral water bottle or glass container with cover is easy to use when stored, and for safety, the use up is recommended within 2 days.
When the electrolytic reduction water is used for cooking, the main functions are as follows: can remove harmful residues on food materials such as pesticides, fertilizers and the like, and indirectly eliminate sources for generating a large amount of free radicals in vivo; removing fishy smell and bitter taste of food materials; the chlorine (bleaching powder) in the tap water is prevented from damaging vitamins in the food materials, and the release of nutrition of the food materials is promoted, so that the food materials can be better absorbed by the body, the waste of the food materials and the consumption of seasonings are reduced, and the rice and the dish are more fragrant and nutritional. Meanwhile, the electrolytic reduction water contains rich ionic minerals, has excellent heat conductivity, can enable rice and dishes to be cooked quickly and soft, and particularly shortens the stewing time greatly when stewing, saves gas and electric power, and is beneficial to the ecological environment protection of the earth.
The electrolytic reduction water and electrolytic oxidation water electrolysis device comprises an outer sleeve 1, wherein one end of the outer sleeve 1 is detachably connected with a water outlet pipe A7, the other end of the outer sleeve 1 is detachably connected with a vibrating structure for vibrating water in the outer sleeve 1, a treatment structure capable of improving the hydrogen concentration in the water in the outer sleeve 1 is arranged in the outer sleeve 1, a water inlet pipe 5 and a water outlet pipe B6 are distributed on the side surface of the outer sleeve 1, magnets 4 are arranged on the side surfaces of the water inlet pipe 5, the water outlet pipe B6 and the water outlet pipe A7, tap water passes through a magnetic field formed by the magnets 4 outside the water inlet pipe 5 after being filtered, and the properties of the water such as surface tension, dissolving force, pH value and density osmotic force change under the action of a strong magnetic field, these fine changes, such as the rising of the dissolution force, activity and permeability, affect the solubility and crystallization process of magnesium, calcium salt and metal ion compounds, so that dense mineral calcite crystals are converted into soft and fine crystals, thereby being more beneficial to being washed away by water flow, achieving the effects of scale prevention and removal, preventing the scaling of the electrolytic tank, enhancing the ionization effect of the electrolytic tank, improving the concentration of dissolved hydrogen and ionized mineral, greatly prolonging the service life of an electrode plate, entering the water outlet pipe A7 after the treatment of a treatment structure, passing through a magnetic field formed by a magnet 4, and enabling water molecules to be fully and small molecules to be clustered under the action of a strong magnetic field, thereby being more beneficial to enhancing the concentration of dissolved hydrogen.
The treatment structure comprises an outer negative electrode plate 11, an electrolytic tank outer support 16, an outer net plate 12, an ionic membrane 13, an inner net plate 14, an electrolytic tank inner support 17 and an inner positive electrode plate 15 which are sequentially distributed in the outer sleeve 1 from outside to inside, wherein the outer negative electrode plate 11 is tightly attached to the inner wall of the outer sleeve 1, positive-valence mineral components contained in raw water are gathered on the surface of the negative electrode plate 11 when hard water is electrolyzed, negative-valence mineral components are gathered on the surface of the inner positive electrode plate 15, rapid electroplating reaction can be generated, overload current leads to increased power consumption, ultrasonic high-frequency vibration is generated by using an ultrasonic generator 2 in the electrolysis process, so that mineral substances electroplated on the electrode plates are rapidly separated, atomic hydrogen, active hydrogen and hydrogen precipitated at the position of the outer negative electrode plate 11 are rapidly separated from the vicinity of the negative electrode plate, oxygen generated at the position of the inner positive electrode plate 15 is rapidly separated from the vicinity of the inner positive electrode plate 15, the conductivity is enhanced, the power consumption is reduced, the atomic hydrogen, the active hydrogen and the hydrogen well depend on the ionized mineral substances are adsorbed on the surface of the negative electrode plate 15, the ultrasonic high-frequency vibration is generated, the concentration of the ultrasonic high-frequency vibration is greatly prolonged, the scale-preventing concentration is greatly prolonged, and the scale-preventing concentration is greatly prolonged.
A water outlet plug 10 is arranged between the outer sleeve 1 and the water outlet pipe A7, and the outer wall of the water outlet plug 10 extending into the outer sleeve 1 is tangential to the inner wall of the inner positive electrode plate 15, so that the treatment device can be positioned through the water outlet plug 10.
The water outlet of the water inlet pipe 5 is arranged between the outer negative electrode plate 11 and the outer bracket 16 of the electrolytic cell, so that when water enters the outer sleeve 1 and reaches the inner positive electrode plate 15, the water needs to pass through the inside of the treatment device, the water inlet of the water outlet pipe B6 is also arranged between the outer negative electrode plate 11 and the outer bracket 16 of the electrolytic cell, the inner cavities of the water inlet pipe 5 and the inner positive electrode plate 15 are communicated with the water outlet pipe A7 through the ionic membrane 13, and alkaline water and weak acid water can be discharged from the positions of the water outlet pipe B6 and the water outlet pipe A7 respectively.
The vibration structure includes the protective sheath 8 of installing on outer sleeve pipe 1, and the internally mounted of protective sheath 8 has ultrasonic generator 2, and the ultrasonic generating end of ultrasonic generator 2 sets up in the bottom of outer sleeve pipe 1, and the position department that inlet tube 5 is close to ultrasonic generator 2 sets up, has guaranteed from this that water can be vibrated by the ultrasonic wave high frequency that ultrasonic generator 2 produced when entering the inside of outer sleeve pipe 1.
And sealing gaskets 9 are arranged between the outer sleeve 1 and the protective sleeve 8 and between the outer sleeve 1 and the water outlet plug 10, and the sealing gaskets 9 are made of silica gel, so that the sealing effect between the connecting parts is ensured.
The outer negative electrode plate 11 and the inner positive electrode plate 15 are both made of platinum titanium plates, and the platinum titanium plates have the advantages of high electrolysis efficiency and stable electrolysis.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the invention.

Claims (9)

1. An electrolytic reduction water and electrolytic oxidation water processing method is characterized in that: the method comprises the following steps:
and (3) a step of: filtering tap water through a pre-filter;
And II: magnetizing the filtered water while passing through the pipeline and then entering the inside of the electrolysis device;
Thirdly,: the water entering the interior is subjected to synchronous ultrasonic vibration and electrolysis through an electrolysis device;
Fourth, the method comprises the following steps: after being processed by an electrolysis device, the water passes through a pipeline and is magnetized, and then alkaline water and weak acid water are discharged.
2. The electrolytic reduced water and electrolytic oxidized water processing method according to claim 1, characterized in that: the pre-filter consists of a customized thickened deep sea diatom ooze ceramic filter element and two sintered active carbon filter elements.
3. An electrolytic device for electrolytically reducing water and electrolytically oxidizing water, which is characterized in that: the novel water heater comprises an outer sleeve (1), wherein a water outlet pipe A (7) is detachably connected to one end of the outer sleeve (1), a vibrating structure used for vibrating water inside the outer sleeve (1) is detachably connected to the other end of the outer sleeve (1), a processing structure capable of improving the hydrogen concentration in water inside the outer sleeve (1) is arranged inside the outer sleeve (1), a water inlet pipe (5) and a water outlet pipe B (6) are distributed on the side face of the outer sleeve (1), and magnets (4) are arranged on the side faces of the water inlet pipe (5), the water outlet pipe B (6) and the water outlet pipe A (7).
4. The electrolytic reduced water and electrolytic oxidized water electrolysis apparatus according to claim 3, wherein: the treatment structure comprises an outer negative electrode plate (11), an outer support (16), an outer net plate (12), an ion membrane (13), an inner net plate (14), an inner support (17) and an inner positive electrode plate (15) which are sequentially distributed from outside to inside in the outer sleeve (1), wherein the outer negative electrode plate (11) is tightly attached to the inner wall of the outer sleeve (1).
5. The electrolytic reduced water and electrolytic oxidized water electrolysis apparatus according to claim 4, wherein: a water outlet plug (10) is arranged between the outer sleeve (1) and the water outlet pipe A (7), and the outer wall of the water outlet plug (10) extending into the outer sleeve (1) is tangential to the inner wall of the inner positive electrode plate (15).
6. The electrolytic reduced water and electrolytic oxidized water electrolysis apparatus according to claim 4, wherein: the water outlet of the water inlet pipe (5) is arranged between the outer negative electrode plate (11) and the outer bracket (16) of the electrolytic tank, the water inlet of the water outlet pipe B (6) is also arranged between the outer negative electrode plate (11) and the outer bracket (16) of the electrolytic tank, and the inner cavities of the water inlet pipe (5) and the inner positive electrode plate (15) are communicated with the water outlet pipe A (7) through an ion membrane.
7. The electrolytic reduced water and electrolytic oxidized water electrolysis apparatus according to claim 3, wherein: the vibration structure comprises a protective sleeve (8) arranged on the outer sleeve (1), an ultrasonic generator (2) is arranged in the protective sleeve (8), an ultrasonic generating end of the ultrasonic generator (2) is arranged at the bottom of the outer sleeve (1), and a water inlet pipe (5) is arranged at a position close to the ultrasonic generator (2).
8. The electrolytic reduced water and electrolytic oxidized water electrolysis apparatus according to claim 7, wherein: sealing gaskets (9) are arranged between the outer sleeve (1) and the protective sleeve (8) and between the outer sleeve (1) and the water outlet plug (10), and the sealing gaskets (9) are made of silica gel.
9. The electrolytic reduced water and electrolytic oxidized water electrolysis apparatus according to claim 4, wherein: the outer negative electrode plate (11) and the inner positive electrode plate (15) are both made of platinum titanium plates.
CN202311574384.3A 2023-11-23 2023-11-23 Electrolytic reduction water and electrolytic oxidation water processing method and electrolytic device thereof Pending CN118084228A (en)

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CN202311574384.3A CN118084228A (en) 2023-11-23 2023-11-23 Electrolytic reduction water and electrolytic oxidation water processing method and electrolytic device thereof

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