CN1180742A - Technology of yellow, tailing water quick esterification extraction balsam liquid and special equipment thereof - Google Patents
Technology of yellow, tailing water quick esterification extraction balsam liquid and special equipment thereof Download PDFInfo
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- CN1180742A CN1180742A CN 96114703 CN96114703A CN1180742A CN 1180742 A CN1180742 A CN 1180742A CN 96114703 CN96114703 CN 96114703 CN 96114703 A CN96114703 A CN 96114703A CN 1180742 A CN1180742 A CN 1180742A
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Abstract
The yellow water and tail water generated in production of strong fragrant hard liquor go through esterification and layered cooling to obtain fragrant ester liquid, which is a fine material for blending strong fragrant hard liquor. For said purpose, yellow water tank, esterifying tank, layered cooling tank and alcohol feeder are specially designed. Its advantages are reducing environmental pollution, less investment and quick taking its effect.
Description
The present invention belongs to now producing the yellow water that produces in the aroma daqu liquor process and the utilization of tail water, is to belong to yellow water and tail water are carried out the fat processing and extract face cream liquid more specifically, and for this purpose and specialized designs one cover specific equipment.
Yellow water is the xanchromatic water at the bottom of aroma daqu liquor production fermentation the time accumulates in the pond, organic acid in the unit weight wherein, and the content of organic ester and polyvalent alcohol also contains the alcohol of 2%-3% simultaneously all than the content height in the common wine; Past Yin Qise is heavy, and evil assorted flavor is big, does not have the good treatment method again, thus for a long time brewery to the utilization of yellow water seldom, most of yellow water all is dropped.The factory that now has adopts distillating method to handle, and when speed was fast, the evil assorted flavor of product was equally also very heavy, and product is very little when slow, and its product is based on organic acid, and is of poor quality, and comprehensive production cost is big, can not form scale production.
Tail water also is that aroma daqu liquor production produces in still-process, wherein organic acid content be in the common wine 3-5 doubly, high boiling organic ester and high first alcohol are all than content height in the common wine, and it is all heavier with the same its evil assorted flavor of yellow water and sub-slightly flavor, it is how sharp little that fraud is blent in the preparation that is used for former yeast wine, have only small portion to be used for the preparation of low-grade wine and blend, the brewery that now has concentrates tail water to handle with general distillation way, resultant product is equally bitter highly seasoned, the H of brewery that has
2SO
4Balsam liquid is extracted in redistillation after the esterification, but because of its extraction means are existing general distillation way, its extracted amount is little, and the production cycle is long, and treatment capacity is also little, and facility investment is also very big.
Purpose of the present invention, be yellow water and tail water for producing in the Daqu brewery production process now, find technology and its specific equipment of utilization, big to reach treatment capacity, the product recovery rate height, the purpose that quality is good, its comprehensive production cost is low has also reduced because of abandoning the pollution to environment that yellow water causes simultaneously.
The treatment process of yellow water and tail water is that 5 parts of yellow waters are added in the yellow water jar, and makes it reach 73% of yellow water jar useful volume, uses 1.8-2.2Kg/cm
2Steam preheating yellow water, and yellow water was seethed with excitement in 30-60 minute, the back of waiting to seethe with excitement transfers to 0.5-0.6kg/cm to the vapour pressure that feeds
2,, advance device the alcohol of 0.25 part (by weight) was injected the yellow water jar in 90-120 minute with alcohol is little when temperature in the yellow water jar during at 99-100 ℃; With 2 parts of (by weight) tail water and 0.22% part of (by weight) H
2SO
4Mix the back and add the esterification jar, make the yellow water vapour that from the yellow water jar, produces feed the esterification jar, and make the liquid in the esterification jar keep boiling 60-90 minute, behind the liquid boiling that the esterification jar is gone into, the vapour pressure of going into of yellow water jar will be transferred to 0.4-0.5Kg/cm
2Adding to the yellow water jar in the process of alcohol,, then using 0.2-0.3kg/cm as the temperature in the yellow water jar 〉=100 ℃
2Steam feed steam for the esterification jar, stop simultaneously in the yellow water jar, feeding steam; Use 10-20 minute time that the alcohol of 0.02 part (by weight) is added in the esterification jar subsequently, when the face cream steam of esterification jar enters chamber under the layer cooling tank, portion gas becomes liquid to stay down the chamber through naturally cooling, chamber and last chamber during most of gas enters, become partially liq through naturally cooling again, the gas that is not cooled enters general water cooler, gets liquid product 1 after cooling; During at 100 ℃, the liquid of last chamber and middle chamber is put into general water cooler respectively at the temperature-stable of following chamber, must product 2 and product 3 after the cooling; After product 3 reclaimed, yellow water jar and esterification jar all stopped air feed; The liquid of chamber under the layer cooling tank behind naturally cooling, is removed SO through anion exchange process again
4 -2Get product 4.
Elution time to product 1 was controlled at 4.5-5.5 hour, and Peak Flow Rate was controlled at 2.5kg/ minute.
By regulating the thermal insulation layer steam flow of layer cooling tank, to entering the fat oxidizing gases of layer cooling tank from the esterification jar at first hour, the temperature of chamber is controlled at 80-90 ℃ under the layer cooling tank, be controlled at 90-95 ℃ in second hour, be controlled at 93 °-96 ° on the 3rd hour, be controlled at 95-98 ℃ on the 4th hour, and be controlled at 98-100 ℃ after four hours.
After gas entered layer cooling tank in the esterification jar, chamber first three hour temperature was controlled at 80-90 ℃ in the layer cooling tank; Be controlled at 90-95 ℃ after three hours and be controlled at 95-98 ℃ after four hours.
Enter five hour of layer cooling tank at the esterification gas that the esterification jar produces after, the temperature of chamber normally is stabilized in 100 ° under the layer cooling tank, and the liquid of chamber on the layer cooling tank is put into general water cooler, after the cooling product 2; Again the liquid of chamber in the layer cooling tank is put into general water cooler, get product 3 after the cooling.
Product 1 be meant gained be top grade balsam liquid product wherein organic ester content greater than organic acid content; Product 2 is meant one-level balsam liquid product, and wherein organic ester and organic acid content remain basically stable; Product 3 is meant secondary balsam liquid product, and wherein organic acid is main, and organic ester and polyvalent alcohol are auxilliary, this three all can be described as balsam liquid, and be to produce gained byproduct in the face cream liquid to product 4, wherein based on organic acid content, and wherein polyvalent alcohol content is also abundanter.
For realizing above-mentioned technological process, specialized designs yellow water jar (accompanying drawing 1), esterification jar (accompanying drawing 5), alcohol is little to advance device (accompanying drawing 6), four devices of layer cooling tank (accompanying drawing 8, accompanying drawing 9).
The yellow water jar is by garden cylindrical shell (16) jar end (12), conical lid (21), yellow water adds funnel (3), yellow water jar hand-hole (4), yellow water jar loam cake visor (5), yellow water jar garden cylindrical shell top visor (6), thermometer (18), tensimeter (19) and yellow water raffinate vent pipe (13) have the annular of yellow water jar to go into steam pipe (11) to enter pipe (14) with steam and communicate in garden cylindrical shell (16) bottom, between tensimeter (15) is arranged, the yellow water jar alcohol that is entered by cover adds pipe (17) and passes balancing plate (8) and go into steam pipe (11) with annular and be connected; It is preceding along extending to balancing plate (8) near the garden barrel that yellow water jar voltage stabilizing buffer tube (7) passes conical lid (21), and leave fluid port (9), its externally ported voltage stabilizing buffer tube return-air mouth (1) and unnecessary liquid vent pipe of voltage stabilizing buffer tube (2) of being equipped with; Yellow water jar yellow water steam fairlead (22) is drawn from awl lid (21) top, and it moves towards angle ∠ b=90-100. And a=25 °-40 of the horizontal sextant angle ∠ of awl lid (21).
It moves towards preferably preferably 28 °-30 ° of the horizontal sextant angle ∠ 3 of 91 °-92 ° and awl lid of angle ∠ b the yellow water steam fairlead (22) of yellow water jar.
The yellow water steam fairlead (22) of yellow water jar is equipped with the little muffler of yellow water jar (20) before its outlet valve.
The fat jar is by garden cylindrical shell (54), tapered bottom (49), conical lid (56), it has thermal insulation layer garden cylindrical shell (50) in the outside down, tail water adds funnel (55), esterification jar hand-hole (35) conical lid window (36), tensimeter (37), thermometer (38), esterification jar garden cylindrical shell top visor (43), esterification pot bottom raffinate relief outlet (48) is equipped with balancing plate backing ring (52) and holds up balancing plate (53) in inside on it, it descends inside that esterification jar annular is housed and goes into steam pipe (46), go into steam pipe (46) with annular after esterification jar alcohol inlet pipe (41) and yellow water jar yellow water steam fairlead (26), esterification jar steam-gas inlet pipe (45) are connected and be connected, and on steam-gas inlet pipe (45), tensimeter (44) is housed; Enter the voltage stabilizing buffer tube (58) of esterification jar by the awl lid, and extend to the bottom of fat jar by balancing plate (53) always; Fat gasification fairlead (57) after esterification jar awl covers the center esterification is arranged, it moves towards d=91 °-100 ° of angle ∠; The little muffler of esterification jar (39) is housed on esterification jar conical lid (56), and a grade gas plate (40) is housed in conical lid evolution place near little muffler (39); C=25 °-40 ° of the horizontal sextant angle ∠ of conical lid (56), the heating steam tail vapour that is equipped with from the layer cooling tank thermal insulation layer by the bottom at esterification jar thermal insulation layer garden cylindrical shell (50) enters pipe (51) and the cold doubtful water out of this thermal insulation layer (47)
The fat steam fairlead (57) of esterification jar, it moves towards preferably 91 °-92 ° of angle ∠ d.
Preferably 28 °-30 ° of the horizontal sextant angles of the conical lid of esterification jar (56), ∠ C.
The balancing plate of yellow water jar or esterification jar (8) or (53) are made of preceding side plate (23), back side plate (26) and intermediate plate (24), preceding side plate (23) is just the same with back side plate (24) size shape, and the three just in time is a garden shape altogether, its diameter is the internal diameter of yellow water jar garden cylindrical shell (16), or the internal diameter of esterification jar garden cylindrical shell (54), on three blocks of plates, equally distributed bar hole is arranged all, long 10-30mm, wide 1-3mm, institute's foraminous total area accounts for the 5%-15% of the balancing plate total area; At the preceding side plate (23) of balancing plate, be equipped with symmetric anchoring filament hole (25) respectively on back side plate (26) and the intermediate plate (24).
Balancing plate backing ring (10) or (52) of yellow water jar or esterification jar are the rings of a garden shape, its ring outside diameter size equals yellow water jar garden cylindrical shell (16) internal diameter, or equal the internal diameter of esterification jar garden cylindrical shell (54), the silk hole (29) of symmetric eight stable equilibrium plates is arranged on backing ring.
The annular of yellow water jar or esterification jar goes into steam pipe (11) or (46) its annular diameter size will adapt with the internal diameter of yellow water jar garden cylindrical shell (16), or to adapt with the internal diameter of esterification jar garden cylindrical shell (54), the equally distributed vapour eye of opening downwards (30) is arranged on its pipe, loopful has 8-12 eyelet, eyelet diameter=6-7mm.
Alcohol is little to advance device by garden cylindrical shell (65), at the bottom of the flat garden (64), flat garden lid (66), littlely advance device tensimeter (61), littlely advance actuator temperature meter (62), alcohol adds funnel (60) and yellow water jar alcohol adds pipe (24), and esterification jar alcohol adds pipe (41) and advances the steam forcing pipe (63) that (64) enter at the bottom of the flat garden of device and constitute by little.
Layer cooling tank is by with flat garden cylindrical shell (97), taper benefit (71) and be equipped with flat thermal insulation layer garden cylindrical shell (83) in garden cylindrical shell (97) lower, outer perimeter, and the condensed water discharge pipe (84) that the thermal insulation layer steam is gone into pipe (85) and thermal insulation layer is housed, between connect by the heat transfer curved tube, by dividing plate (74), dividing plate (78) is divided into chamber (73) with layer cooling tank inside in garden cylindrical shell (97), middle chamber (77), following chamber (81); Esterification air shooter (72) is housed respectively in last chamber (73) and middle chamber (77), (76) vertical component inlet connects mutually with the hole, garden that open at dividing plate (74) and (78) center respectively, chamber under layer cooling tank (81) are equipped with annular by the bottom and are gone into tracheae (87) and esterification steam and go into to manage (79) and interlink; And chamber raffinate outlet pipe (86) down is being housed near the cylindrical shell place; Dividing plate (78) in middle chamber (77) is equipped with face cream liquid outlet pipe (91) by the cylindrical shell place; Dividing plate (74) in last chamber (73) is equipped with face cream liquid outlet pipe (96) by the cylindrical shell place; Top center at layer cooling tank conical lid (71) has esterification gas fairlead (70) to constitute.
The last chamber (73) of layer cooling tank is equipped with thermometer (99), (95) respectively, (90) and visor (100), (94), (89) on the garden cylindrical shell of middle chamber (77), following chamber (81).
The annular of layer cooling tank is gone into tracheae (98), and (92), (87) all have the equally distributed core of opening downwards on its pipe, and loopful has 8-12 eyelet, and the eyelet diameter is 6-7mm.
Adopt this technology and its support equipment in general fragrant yeast brewery can being produced yellow water and tail water can be in addition processing and utilizing completely, and be easy to realize, gained face cream liquid product 1, product 2, product 3, all be convert to high quality liquor rare auxiliary, product 4 also can be used as the seasonings of blending low-grade assembled alcoholic drinks, and effect is fine, and the productive rate of the said products 1+ product 2 is about 10% of former yellow water+tail water weight; Product 3 is about the 4-5% of yellow water+tail water weight, and product 4 is about the 3-4% of yellow water+tail water weight; To 6000 tons of bent breweries of general annual output only the yellow water that abandons of this utilization and the tail water economic benefit of producing face cream liquid can reach 5,000,000 yuan, and reduced of the pollution of discharging yellow water to environment.
Accompanying drawing 1: yellow water jar front view
Accompanying drawing 2: the vertical view of yellow water jar balancing plate 8
Accompanying drawing 3: backing ring 10 vertical views of yellow water jar balancing plate 8
Accompanying drawing 4: yellow water jar annular is gone into the upward view of steam pipe 11
Accompanying drawing 5: esterification jar front view
Accompanying drawing 6: the shared alcohol of yellow water jar, esterification jar is little to advance the device front view
Accompanying drawing 7: the little vertical view that advances device of the alcohol of yellow water jar, esterification jar
Accompanying drawing 8: the front view of layer cooling tank
Accompanying drawing 9: the positive longitudinal diagram of layer cooling tank
Accompanying drawing 10: the process flow sheet of yellow water, tailing water quick esterification extraction balsam liquid
The implementation procedure of the above-mentioned technology of accompanying drawings: five tons of yellow waters are added the yellow water jar, 2 tons of tail water and 2.2kgH
2SO
4Mix the back and add the esterification jar, after use 1.8-2.2kg/cm
2The steam preheating yellow water seethed with excitement yellow water in 30-60 minute, the boiling back transfers to 0.5-0.6kg/cm to vapour pressure
2When temperature in the yellow water jar during at 99-100 ℃, advance device the alcohol of 250kg was injected the yellow water jar in 90-120 minute by alcohol is little, the steam that the yellow water jar produces enters the fat jar by yellow water jar steam fairlead 26, and, make tail water and H in the esterification jar with time of 60-90 minute
2SO
4The mixed solution boiling; Vapour pressure with the yellow water jar when waiting to seethe with excitement transfers to 0.4-0.5kg/cm
2Use 10-20 minute time that the alcohol of 20kg is added in the esterification jar subsequently, the face cream steam enters chamber 81 under the layer cooling tank by face cream steam fairlead 58 in the fat jar, become liquid through natural condensation portion and stay chamber under the layer cooling tank, chamber 77 and last chamber 73 during most of gas enters, again through naturally cooling, a part becomes liquid and stays middle chamber and last chamber, the gas that is not cooled enters general chemical industry water cooler, get product 1 450kg after the cooling, to descend chambers temp to be stabilized in 100 ℃, in liquid in chamber and the last chamber put into general chemical industry water cooler successively, get product 3315kg and product 2250kg after the cooling, the SO that removes trace is handled with liquid wherein in the following chamber for the treatment of layer cooling tank through resin anion(R.A) behind naturally cooling
4 -2After product 4245Kg.
Claims (18)
1, the treatment process of yellow water and tail water is characterized in that 5 parts of yellow waters are added in the yellow water jar, and makes 73% of its useful volume that reaches the yellow water jar, uses 1.8-2.2Kg/cm
2Steam preheating yellow water, and yellow water was seethed with excitement in 30-60 minute, the back of waiting to seethe with excitement transfers to 0.5-0.6kg/cm to the vapour pressure that feeds
2, when temperature in the yellow water jar during, advance device the alcohol of 0.25 part (by weight) was injected the yellow water jar in 90-120 minute, in addition with the H of 2 parts of (by weight) tail water and 0.22% part (by weight) with alcohol is little at 99-100 ℃
2SO
4Mix the back and add the esterification jar, after make the yellow water steam that from the yellow water jar, produces feed the esterification jar, and make the liquid in the esterification jar keep boiling 60-90 minute, the vapour pressure of going into of yellow water jar to be transferred to 0.4-0.5kg/cm behind the liquid boiling in the esterification jar
2, adding to the yellow water jar in the process of alcohol, as the temperature in the yellow water jar 〉=100 ℃, then use 0.2-0.3kg/cm
2Steam feed steam for the esterification jar, stop simultaneously in the yellow water jar, feeding steam, use 10-20 minute time that the alcohol of 0.02 part (by weight) is added in the esterification jar subsequently; When the fat steam of esterification jar by fat steam fairlead (57), enter chamber under the layer cooling tank (81), partial esterification gas becomes liquid to stay down chamber (81) through naturally cooling, most fat oxidizing gases enters chamber (73) on chamber in the layer cooling tank (77) and the layer cooling tank, become partially liq through naturally cooling again, the fat oxidizing gases that is not cooled enters general water cooler by layer cooling tank gas fairlead (70), gets liquid product 1 after cooling; In the temperature maintenance of following chamber (81) during at 100 ℃, the liquid of last chamber (73) and middle chamber (77) put into respectively general water cooler cool off product 2 and product 3; Yellow water jar and fat jar all stop steam supply after product 3 reclaims, and the liquid of chamber under the layer cooling tank (81) are set through anionresin again refer to handle to get product 4 behind naturally cooling.
2, yellow water according to claim 1 and tail water treatment process, its feature also will should be controlled in the elution time to product 1 4.5-5.5 hour, and Peak Flow Rate was controlled at 2.5Kg/ minute.
3, yellow water according to claim 1 and tail water treatment process, its feature also is to enter the esterification gas of layer cooling tank at first hour from the esterification jar, the temperature of chamber under layer cooling tank (81) should be controlled at 80-90 ℃, be controlled at 90-95 ℃ at second hour, be controlled at 93-96 ℃ at the 3rd hour, be controlled at 95-98 ℃ on the 4th hour, and be controlled at 98-100 ℃ after four hours.
4, yellow water according to claim 1 and tail water treatment process, after its feature is that also the fat oxidizing gases enters layer cooling tank from the esterification jar, chamber in the layer cooling tank (77) first three hour temperature is controlled at 80-90 ℃, is controlled at 90-95 ℃ after the 3rd hour, be controlled at 95-98 ℃ after four hours.
5, yellow water according to claim 1 and tail water treatment process, its feature is that also the esterification gas that produces enters five hour of layer cooling tank in the esterification jar after, the temperature of chamber under the layer cooling tank (81) normally is stabilized in 100 ℃, the liquid of chamber on the layer cooling tank (73) put into general water cooler cool off product 2, again the liquid of chamber in the layer cooling tank (77) put into after the cooling of general water cooler product 3.
6, according to the specific equipment yellow water jar of described yellow water of claim 1 and tail water treatment process by garden cylindrical shell (6), the jar end (12), conical lid (21), yellow water adds funnel (3), yellow water jar hand-hole (4), yellow water jar loam cake visor (5), yellow water jar garden cylindrical shell top visor (6), thermometer (18), tensimeter (19) and yellow water raffinate vent pipe (13) constitute, it is characterized in that having balancing plate backing ring (10) to hold up balancing plate (8) on garden cylindrical shell (16) top, garden cylindrical shell (16) bottom has the annular of yellow water jar to go into steam pipe (11) to enter pipe (14) with steam and communicate, between tensimeter (15) is arranged, the yellow water jar alcohol that is entered by cover adds pipe (17) and passes balancing plate (8) and go into steam pipe (11) with annular and be connected; It is preceding along extending to balancing plate (8) near the garden barrel that yellow water jar voltage stabilizing buffer tube (7) passes conical lid (21), and leave fluid port (9), its externally ported voltage stabilizing buffer tube return-air mouth (1) and unnecessary liquid vent pipe of voltage stabilizing buffer tube (2) of being equipped with; Yellow water jar yellow water steam fairlead (22) is drawn from awl lid (21) top, and it moves towards d=90 °-100 ° of angle ∠; And a=25 °-40 ° of the horizontal sextant angle ∠ of awl lid (21).
7, according to the specific equipment yellow water jar of described yellow water of claim 6 and tail water treatment process, its feature also is yellow water steam fairlead (22), and it moves towards preferably preferably 28 °-30 ° of the horizontal sextant angle ∠ a of 91 °-92 ° and awl lid of angle ∠ d.
8, according to the specific equipment yellow water jar of described yellow water of claim 6 and tail water treatment process, its feature is that also yellow water steam fairlead (22) is equipped with the little muffler of yellow water jar (20) before its outlet valve.
9, according to the specific equipment fat jar of described yellow water of claim 1 and tail water treatment process by garden cylindrical shell (54), tapered bottom (49), conical lid (56), it has thermal insulation layer garden cylindrical shell (50) in the outside down, tail water adds funnel (55), esterification jar hand-hole (35) conical lid window (36), tensimeter (37), thermometer (38), esterification jar garden cylindrical shell top visor (43), esterification pot bottom raffinate relief outlet (48) constitutes, it is characterized in that balancing plate backing ring (52) picking-up balancing plate (53) is equipped with in inside on it, it descends inside that esterification jar annular is housed and goes into steam pipe (46), esterification jar alcohol inlet pipe (41) and yellow water jar yellow water steam fairlead (26), go into steam pipe (46) with annular after esterification jar steam-gas inlet pipe (45) is connected and be connected, and on steam-gas inlet pipe (45), tensimeter (44) is housed; Enter the voltage stabilizing buffer tube (58) of esterification jar by the awl lid, and extend to the bottom of fat jar by balancing plate (53) always; Fat gasification fairlead (57) after esterification jar awl covers the center esterification is arranged, it moves towards d=91 °-100 ° of angle ∠; The little muffler of esterification jar (39) is housed on ester jar conical lid (56), and a grade gas plate (40) is housed in conical lid ingress near little muffler (39); C=25 °-40 ° of the horizontal sextant angle ∠ of conical lid (56); The heating steam tail vapour that is equipped with from the layer cooling tank thermal insulation layer by the bottom at esterification jar thermal insulation layer garden cylindrical shell (50) enters pipe (51) and the cold doubtful water out of this thermal insulation layer (47).
10, its feature of specific equipment esterification jar of yellow water according to claim 9 and tail water treatment process also is fat steam fairlead (57), and it moves towards preferably 91 °-92 ° of angle ∠ d.
11, its feature of specific equipment esterification jar of yellow water according to claim 9 and tail water treatment process also is the horizontal sextant angle of conical lid (56), preferably 28 °-30 ° of ∠ C.
12, specific equipment yellow water jar or its feature of esterification jar according to claim 6 or 9 described yellow waters and tail water treatment process are that also balancing plate (8) or (53) are by preceding side plate (23), back side plate (26) and intermediate plate (24) constitute, preceding side plate (23) is just the same with back side plate (24) size shape, and the three just in time is a garden shape altogether, its diameter is the internal diameter of yellow water jar garden cylindrical shell (16), or the internal diameter of esterification jar garden cylindrical shell (54), on three blocks of plates, equally distributed bar hole is arranged all, long 10-30mm, wide 1-3mm, institute's foraminous total area accounts for the 5%-15% of the balancing plate total area; At the preceding side plate (23) of balancing plate, be equipped with symmetric anchoring filament hole (25) respectively on back side plate (26) and the intermediate plate (24).
13, be also that according to the specific equipment yellow water jar of claim 6 or 9 described yellow waters and tail water treatment process or the feature of esterification jar the balancing plate backing ring (10) of yellow water jar or esterification jar or (52) are the rings of a garden shape, its ring outside diameter size equals the internal diameter of yellow water jar garden cylindrical shell (16), or equal the internal diameter of esterification jar garden cylindrical shell (54), the silk hole (29) of symmetric eight stable equilibrium plates is arranged on backing ring.
14, be also that according to the specific equipment yellow water jar of claim 6 or 9 described yellow waters and tail water treatment process or the feature of esterification jar the annular of yellow water jar or esterification jar is gone into steam pipe (11) or (46) its annular diameter size will adapt with the internal diameter of yellow water jar garden cylindrical shell (16), or to adapt with the internal diameter of esterification jar garden cylindrical shell (54), the equally distributed vapour eye (30) that downward shape is arranged on its pipe, loopful has 8-12 eyelet, eyelet diameter=6-7mm.
15, the specific equipment alcohol of yellow water according to claim 1 and tail water treatment process is little advances device by garden cylindrical shell (65), at the bottom of the flat garden (64), flat garden lid (66), littlely advance device tensimeter (61), littlely advance actuator temperature meter (62), alcohol adds funnel (60) and yellow water jar alcohol adds pipe (24), fat jar alcohol adds pipe (41) and constitutes, and it is characterized in that having by little advancing the steam pressurized pipe (63) that (64) center enters at the bottom of the flat garden of device.
16, the specific equipment layer cooling tank of yellow water according to claim 1 and tail water treatment process is by with flat garden cylindrical shell (97), conical lid (71) and be equipped with flat thermal insulation layer garden cylindrical shell (83) in garden cylindrical shell (97) lower, outer perimeter, and the condensed water discharge pipe (84) that the thermal insulation layer steam is gone into pipe (85) and thermal insulation layer is housed, between connect by the heat transfer curved tube and to constitute, it is characterized in that in garden cylindrical shell (97) by dividing plate (74), dividing plate (78), layer cooling tank inside is divided into chamber (73), middle chamber (77), following chamber (81); Esterification air shooter (72) and (76) and annular are housed respectively in last chamber (73) and middle chamber (77) go into the fat gasification riser of tracheae (98) and (92) composition, esterification air shooter (72), (76) vertical component inlet is connected mutually with the hole, garden that open at dividing plate (74) and (78) center respectively, and chamber under layer cooling tank (81) are equipped with annular by the bottom and are gone into tracheae (87) and esterification steam and go into to manage (79) and interlink; And chamber raffinate outlet pipe (86) down is being housed near the cylindrical shell place; Dividing plate (78) in middle chamber (77) is equipped with face cream liquid outlet pipe (91) by the cylindrical shell place; Dividing plate (74) in last chamber (73) is equipped with face cream liquid outlet pipe (96) by the cylindrical shell place; Top center at layer cooling tank conical lid (71) has esterification gas fairlead (70).
17, its feature of specific equipment layer cooling tank of yellow water according to claim 16 and tail water treatment process also is chamber (73), middle chamber (77) is equipped with thermometer (99), (95), (90) and visor (100), (94), (89) respectively on the garden cylindrical shell of following chamber (81).
18, its feature of specific equipment layer cooling tank of yellow water according to claim 16 and tail water treatment process is that also its annular goes into tracheae (98), (92), (87) the equally distributed core of opening is all arranged downwards on its pipe, loopful has 8-12 eyelet, and the eyelet diameter is 6-7mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96114703 CN1180742A (en) | 1996-10-24 | 1996-10-24 | Technology of yellow, tailing water quick esterification extraction balsam liquid and special equipment thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96114703 CN1180742A (en) | 1996-10-24 | 1996-10-24 | Technology of yellow, tailing water quick esterification extraction balsam liquid and special equipment thereof |
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| CN1180742A true CN1180742A (en) | 1998-05-06 |
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| CN 96114703 Pending CN1180742A (en) | 1996-10-24 | 1996-10-24 | Technology of yellow, tailing water quick esterification extraction balsam liquid and special equipment thereof |
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Cited By (5)
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| CN102516057A (en) * | 2011-10-13 | 2012-06-27 | 贵州大学 | Method for extracting organic acid from yellow water |
| CN101748036B (en) * | 2008-12-17 | 2012-10-31 | 四川省宜宾市叙府酒业股份有限公司 | Method for extracting aroma and flavor-producing substances from yellow solution |
| CN102787063A (en) * | 2012-09-04 | 2012-11-21 | 山东中德设备有限公司 | Distilling method for foreshots and feints of solid-fermentation white spirit and special system for implementing distilling method |
| CN104845735A (en) * | 2015-04-29 | 2015-08-19 | 四川银帆生物科技有限公司 | Two-time esterification technology in process of preparing fragrant liquid from liquor-making byproduct percolated yellow fermenting liquor |
| CN114015530A (en) * | 2021-09-01 | 2022-02-08 | 河南科技大学 | Comprehensive utilization method of white spirit fermentation by-product yellow water |
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1996
- 1996-10-24 CN CN 96114703 patent/CN1180742A/en active Pending
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| CN101748036B (en) * | 2008-12-17 | 2012-10-31 | 四川省宜宾市叙府酒业股份有限公司 | Method for extracting aroma and flavor-producing substances from yellow solution |
| CN102516057A (en) * | 2011-10-13 | 2012-06-27 | 贵州大学 | Method for extracting organic acid from yellow water |
| CN102516057B (en) * | 2011-10-13 | 2015-03-25 | 贵州大学 | Method for extracting organic acid from yellow water |
| CN102787063A (en) * | 2012-09-04 | 2012-11-21 | 山东中德设备有限公司 | Distilling method for foreshots and feints of solid-fermentation white spirit and special system for implementing distilling method |
| CN102787063B (en) * | 2012-09-04 | 2013-12-04 | 山东中德设备有限公司 | Distilling method for foreshots and feints of solid-fermentation white spirit and special system for implementing distilling method |
| CN104845735A (en) * | 2015-04-29 | 2015-08-19 | 四川银帆生物科技有限公司 | Two-time esterification technology in process of preparing fragrant liquid from liquor-making byproduct percolated yellow fermenting liquor |
| CN114015530A (en) * | 2021-09-01 | 2022-02-08 | 河南科技大学 | Comprehensive utilization method of white spirit fermentation by-product yellow water |
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