CN1180684A - Compound long-lasting urea fertilizer and preparing method thereof - Google Patents

Compound long-lasting urea fertilizer and preparing method thereof Download PDF

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Publication number
CN1180684A
CN1180684A CN 96119494 CN96119494A CN1180684A CN 1180684 A CN1180684 A CN 1180684A CN 96119494 CN96119494 CN 96119494 CN 96119494 A CN96119494 A CN 96119494A CN 1180684 A CN1180684 A CN 1180684A
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China
Prior art keywords
urea
fertilizer
inhibitor
lasting
add
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CN 96119494
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CN1073975C (en
Inventor
李荣华
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Institute of Applied Ecology of CAS
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Institute of Applied Ecology of CAS
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Publication of CN1073975C publication Critical patent/CN1073975C/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • C05C9/005Post-treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

A long-acting compound urea fertilizer containing urease and nitrating inhibitors and used as base fertilizer features that after syntehsizing urea, hydroquinone as urease inhibitor and dicyandiamide as nitrating inhibitor are added, and serves to decrease the loss of urea N from soil.

Description

Compound long-lasting urea fertilizer and preparation method thereof
The present invention relates to urea fertilizer, specifically a kind of compound long-lasting urea fertilizer and manufacturing process thereof that contains urease inhibitor and nitrification inhibitor.
Urea fertilizer is to use maximum a kind of solid chemical fertilizer in the present world agriculture, though it has the nitrogen content height, use conveniently, more stable advantage, but because the common urase of enzymolysis urea and the nitrate reductase that its enzymolysis product is carried out of existing in the soil, make urea be manured into soil the back under their serial action, change into ammonia-state nitrogen and nitric nitrogen soon, and can not all be utilized by plant absorbing immediately, often cause the murder by poisoning of plant seedlings and more gaseous loss and leaching loss, cause the utilization ratio of urea fertilizer many,, reduce the loss of blood urea nitrogen in being manured into soil in order to improve the nitrogen utilization efficiency of urea below 40%, in recent ten years, people attempt to take number of ways to study controlled availability fertilizer, realize that urea is unlikely hydrolysis rapidly in soil in a short time, but its effect are undesirable.
The objective of the invention is shortcoming at above-mentioned existence, provide a kind of long-acting carbamide with simple technology, this urea can reduce the accumulation and the loss of nitrate effectively, make the ammonia in the urea in soil, obtain the maintenance more and longer time, guarantee that crop is for fertile needs, prolong the fertilizer efficiency of urea again, improve its utilization ratio.
The object of the present invention is achieved like this: after selecting for use urease inhibitor and nitrification inhibitor to add the urea production synthesis procedure to, before the granulating working procedure, the urease inhibitor and the nitrification inhibitor that add to after the urea synthesis operation are respectively quinhydrones and Dyhard RU 100, and its proportioning is to add 1~3 ‰ and 1~10 ‰ of urea (weight) respectively.Add to and make compound manure in the urea and can suppress the decomposition rate of urea and nitrated effectively.Experiment shows: add certain amount of H Q and DCD in urea, the utilization ratio of its nitrogen improves 10% than common urea; Crop yield increases more than 10%.
Processing method provided by the invention is easy to combine with the existing urea technique of producing, and in conjunction with urea synthesis technology and the condition used at present, needs equipment few, and processing method is simple, is easy to apply in chemical fertilizer industry is produced.After using this fertilizer to apply, can reduce the loss of blood urea nitrogen in the soil, adapt to various farm crop and use, but as the base manure applied once, the saving of labor, joint is fertile, remarkable in economical benefits.
Compound New-type long-acting urea of the present invention also can be used as other in a large number and the carriers of micronutrient element, add P, and K and various trace element be as boron, zinc, and iron, manganese etc. can be made into the compound long-acting compound manure that contains various nutrient elements.
The manufacturing process of compound long-acting urea of the present invention is in the preceding operation of the urea moulding (granulation) of the urea production process that adopts at present, a pipeline is set HQ and DCD are joined concentrated urine according to a certain ratio or dissolves in the urea, make it fully to puddle and evenly make finished product.In this manufacturing process,,, just can utilize original equipment to produce compound long-acting urea so need to increase the inhibitor adding set and puddle device owing to be based on former urea synthesis production technique.
Utilize example and accompanying drawing that the present invention is described further below.
Existing urea technological process of production synoptic diagram shown in the figure, wherein: 1) NH 3With CO 2Mixing tank; 2) synthetic tower; 3) give separator; 4) press in and decompose pressurizer; 5) press separator decomposition in; 6) low pressure decomposition heater; 7) low-pressure distillation tower; The low pressure separator decomposition; 9) urine flash drum; 10) general vaporizer; 11) general vapor seperator; 12) two-section evaporating heater; 13) dual circulation separator; 17) be pressed into prilling tower; 18) carry out granulation and get compound New-type long-acting urea; Technology of the present invention is: increase by 14) HO and DCD puddle device; 15) HQ+DCD mixed solution metering sample feeding pump; 16) puddle device (HQ+DCD mixed solution and concentrated urine formula fusing urea are puddled evenly at this).
Except that above-mentioned manufacturing process, processing method of the present invention also is applicable to other processing method of present production urea, for example: hot gas cycle method, gas delivery circulation method, slurries circulation method; Production technique such as gas formulation and connection pump method just add in these technologies and add HQ, DCD and puddle two procedures.

Claims (2)

1. compound long-lasting urea fertilizer, in the urea operation, add inhibitor, the urease inhibitor and the nitrification inhibitor that it is characterized in that adding to after the urea synthesis operation are respectively quinhydrones and Dyhard RU 100, and its proportioning is to add 1~3 ‰ and 1~10 ‰ of urea (weight) respectively.
2. a method for preparing the described long-acting urea fertilizer of claim 1 is characterized in that behind the urea production synthesis procedure, before the granulating working procedure, adds quinhydrones and Dyhard RU 100; Increased HO and DCD and puddled device (14), HQ and DCD mixed solution metering sample feeding pump (15) are puddled device (16).
CN96119494A 1996-10-18 1996-10-18 Compound long-lasting urea fertilizer and preparing method thereof Expired - Fee Related CN1073975C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN96119494A CN1073975C (en) 1996-10-18 1996-10-18 Compound long-lasting urea fertilizer and preparing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN96119494A CN1073975C (en) 1996-10-18 1996-10-18 Compound long-lasting urea fertilizer and preparing method thereof

Publications (2)

Publication Number Publication Date
CN1180684A true CN1180684A (en) 1998-05-06
CN1073975C CN1073975C (en) 2001-10-31

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CN96119494A Expired - Fee Related CN1073975C (en) 1996-10-18 1996-10-18 Compound long-lasting urea fertilizer and preparing method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100337992C (en) * 2005-02-22 2007-09-19 徐州市五谷丰化肥有限公司 46% sulfur based urea
CN104926570A (en) * 2015-02-10 2015-09-23 四川美丰化工股份有限公司 Method of producing urea with high stability

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2964960A1 (en) 2014-10-31 2016-05-06 Koch Agronomic Services, Llc Nitrification inhibitor compositions and methods of making thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109580B (en) * 1985-12-30 1988-05-04 中国科学院林业土壤研究所 Production of lang life urea fertilizers containing para-dihydroxyl-benzene
DE3714729A1 (en) * 1987-05-02 1988-11-10 Sueddeutsche Kalkstickstoff NITRIFICATION AGENT
CN1065651A (en) * 1992-04-03 1992-10-28 内蒙古自治区大兴安岭农场管理局扎赉河肥料厂 Synergist and nitrogen protective agent for urea

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100337992C (en) * 2005-02-22 2007-09-19 徐州市五谷丰化肥有限公司 46% sulfur based urea
CN104926570A (en) * 2015-02-10 2015-09-23 四川美丰化工股份有限公司 Method of producing urea with high stability
CN104926570B (en) * 2015-02-10 2018-03-16 四川美丰化工股份有限公司 A kind of method of production stability urea

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