CN118063130A - Preparation method of artificial stone slurry - Google Patents

Preparation method of artificial stone slurry Download PDF

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Publication number
CN118063130A
CN118063130A CN202410127308.6A CN202410127308A CN118063130A CN 118063130 A CN118063130 A CN 118063130A CN 202410127308 A CN202410127308 A CN 202410127308A CN 118063130 A CN118063130 A CN 118063130A
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China
Prior art keywords
artificial stone
granite
preparing
aggregate
slurry
Prior art date
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Pending
Application number
CN202410127308.6A
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Chinese (zh)
Inventor
袭祥栋
李源
刘祥
景元凯
刘良
李旭
袭祥煜
袭鹏飞
袭利
李磊
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Jinan Tmmt Stone Co ltd China
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Jinan Tmmt Stone Co ltd China
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Priority to CN202410127308.6A priority Critical patent/CN118063130A/en
Publication of CN118063130A publication Critical patent/CN118063130A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to the technical field of artificial stone, and discloses a preparation method of artificial stone slurry, which comprises the following steps: s1, preparing aggregate: crushing granite waste, screening, respectively selecting coarse aggregates and fine aggregates of crushed stone granules, mixing and stirring to obtain granite graded aggregates for later use; s2, preparing an additive: mixing and stirring the binder, the toughening agent, the diluent and the curing agent in proportion to obtain an additive for later use; s3, preparing slurry: and uniformly stirring granite graded aggregate, additives, fillers and reinforcing materials to obtain the artificial stone slurry. The artificial stone produced by the artificial stone slurry has low water absorption rate in water and oil, compact texture, small porosity, difficult corrosion and good durability; the anti-vibration damping material has the advantages of high compressive strength, high tensile strength and bending strength, high elastic modulus, large anti-vibration amplitude, high frequency, quick attenuation and excellent damping effect.

Description

Preparation method of artificial stone slurry
Technical Field
The invention relates to the technical field of artificial stone, in particular to a preparation method of artificial stone slurry.
Background
The natural granite has the characteristics of high compressive strength, good stability, good freezing resistance, high hardness, high barren rate, good wear resistance, good durability, long service life and the like; however, a great deal of waste materials are generated in the process of mining and processing natural granite; thus, artificial granite has been developed; because the high-end equipment base materials such as ultra-precise machine tools, precise measuring instruments and the like are required to meet the requirements of high precision, high rigidity, long service life, high damping and high thermal stability, the artificial granite has the advantages of good damping characteristics, dynamic and static characteristics, thermal stability, high integration, acid and alkali resistance, greenness, no pollution and the like, and is considered to be an ideal material for manufacturing the high-end equipment base materials such as ultra-precise machine tools, precise measuring instruments and the like.
The Chinese patent discloses a manufacturing method of artificial granite (bulletin No. CN 108911582A), and the artificial granite prepared by the method has good fire resistance, natural and uniform color patterns, compact structure, strong wear resistance, high compressive strength and low water absorption; the invention also adds the fire-resistant lightweight filler prepared from sepiolite powder, quartz sand, talcum powder, heavy calcium, glass fiber, asbestos and hollow ceramic microspheres, thereby effectively improving the fire resistance of the artificial granite, simultaneously being lighter than the natural granite, making up the defects of heavy weight, poor fire resistance and high water absorption rate of the natural granite stone, having wide market prospect, but poor strength performance and poor shock resistance effect.
Disclosure of Invention
The invention aims to provide a preparation method of artificial stone slurry, which aims to solve the problems in the background technology.
In order to achieve the above purpose, the present invention provides the following technical solutions:
A method for preparing artificial stone slurry, comprising the following steps:
s1, preparing aggregate: crushing granite waste, screening, and respectively selecting coarse aggregates and fine aggregates of crushed stone granules; cleaning and drying respectively, and then mixing the crushed stone granules, coarse aggregate and fine aggregate according to the following proportion of 3:1:1, mixing and stirring the materials according to the mass ratio to obtain granite grading aggregate for later use;
S2, preparing an additive: mixing and stirring a binder, a toughening agent, a diluent and a curing agent according to the mass ratio of 10:2:1:6 to obtain an additive for standby;
S3, preparing slurry: taking 80-100 parts by mass of granite graded aggregate, 12-16 parts by mass of additive, 8-10 parts by mass of filler and 3-5 parts by mass of reinforcing material, and uniformly stirring to obtain artificial stone slurry; pouring the artificial stone slurry into a mould, vibrating, compacting, exhausting bubbles, solidifying at room temperature, demoulding, and baking at 40-45 ℃ for 24-28 h to form the artificial granite.
As still further aspects of the invention: in the step S1, the particle size of the crushed stone granules is 5-10 mm, the particle size of the coarse aggregate is 2.5-5 mm, and the particle size of the fine aggregate is 1.25-2.5 mm.
As still further aspects of the invention: in the step S2, the binder is bisphenol A epoxy resin, the toughening agent is dibutyl phthalate, and the curing agent is ethylenediamine.
As still further aspects of the invention: in the step S2, the diluent is one or more of acetone, toluene, xylene and diglyceride.
As still further aspects of the invention: in the step S3, the filler consists of graphite powder, nano silicon dioxide powder, calcium carbonate powder and talcum powder, and the mass ratio of the graphite powder to the nano silicon dioxide powder is (1-2): (2-3): (3-5): (3-5), and the particle sizes of the graphite powder, the nano silicon dioxide powder, the calcium carbonate powder and the talcum powder are all 200-250 um.
As still further aspects of the invention: in the step S3, the reinforcing material consists of polypropylene fibers, steel fibers and carbon fibers, and the mass ratio of the reinforcing material is (2-3): (8-10): (2-3).
Compared with the prior art, the invention has the beneficial effects that:
Firstly, screening out broken stone granules, coarse aggregate and fine aggregate from granite waste; adding binder, toughening agent, diluent, curing agent, filler and reinforcing material, and mixing to obtain artificial stone slurry; the artificial stone produced by the artificial stone slurry has low water absorption rate in water and oil, compact texture, small porosity, difficult corrosion and good durability; the high-strength high-damping material has the advantages of high compressive strength, high tensile strength and bending strength, high elastic modulus, large shock resistance, high frequency, high damping and excellent damping effect, and can be used as an excellent material of high-end equipment base parts of ultra-precise machine tools, precise measuring instruments and the like.
Detailed Description
Example 1
In the embodiment of the invention, the preparation method of the artificial stone slurry comprises the following steps:
S1, preparing aggregate: crushing granite waste, screening, and respectively selecting crushed stone granules with the particle size of 5-10 mm, coarse aggregate with the particle size of 2.5-5 mm and fine aggregate with the particle size of 1.25-2.5 mm; cleaning and drying respectively, and then mixing the crushed stone granules, coarse aggregate and fine aggregate according to the following proportion of 3:1:1, mixing and stirring the materials according to the mass ratio to obtain granite grading aggregate for later use;
S2, preparing an additive: mixing bisphenol A epoxy resin, dibutyl phthalate, acetone and ethylenediamine according to a mass ratio of 10:2:1:6, and stirring to obtain an additive for later use;
S3, preparing slurry: according to the mass portion, 80 portions of granite graded aggregate, 12 portions of additive, 1.2 portions of graphite powder with the grain diameter of 200-250 um, 1.6 portions of nano silicon dioxide powder with the grain diameter of 200-250 um, 2.6 portions of calcium carbonate powder with the grain diameter of 200-250 um, 2.6 portions of talcum powder with the grain diameter of 200-250 um, 0.5 portion of polypropylene fiber, 2 portions of steel fiber and 0.5 portion of carbon fiber are taken, and evenly stirred, thus obtaining the artificial stone slurry.
Example two
In the embodiment of the invention, the preparation method of the artificial stone slurry comprises the following steps:
S1, preparing aggregate: crushing granite waste, screening, and respectively selecting crushed stone granules with the particle size of 5-10 mm, coarse aggregate with the particle size of 2.5-5 mm and fine aggregate with the particle size of 1.25-2.5 mm; cleaning and drying respectively, and then mixing the crushed stone granules, coarse aggregate and fine aggregate according to the following proportion of 3:1:1, mixing and stirring the materials according to the mass ratio to obtain granite grading aggregate for later use;
S2, preparing an additive: mixing bisphenol A epoxy resin, dibutyl phthalate, dimethylbenzene and ethylenediamine according to a mass ratio of 10:2:1:6, and stirring to obtain an additive for later use;
S3, preparing slurry: 90 parts of granite graded aggregate, 14 parts of additive, 1.35 parts of graphite powder with the grain diameter of 200-250 um, 1.75 parts of nano silicon dioxide powder with the grain diameter of 200-250 um, 3 parts of calcium carbonate powder with the grain diameter of 200-250 um, 3 parts of talcum powder with the grain diameter of 200-250 um, 0.8 part of polypropylene fiber, 2.5 parts of steel fiber and 0.8 part of carbon fiber are taken according to the parts by mass, and the artificial stone slurry is obtained after uniform stirring.
Example III
In the embodiment of the invention, the preparation method of the artificial stone slurry comprises the following steps:
S1, preparing aggregate: crushing granite waste, screening, and respectively selecting crushed stone granules with the particle size of 5-10 mm, coarse aggregate with the particle size of 2.5-5 mm and fine aggregate with the particle size of 1.25-2.5 mm; cleaning and drying respectively, and then mixing the crushed stone granules, coarse aggregate and fine aggregate according to the following proportion of 3:1:1, mixing and stirring the materials according to the mass ratio to obtain granite grading aggregate for later use;
S2, preparing an additive: mixing bisphenol A epoxy resin, dibutyl phthalate, diglycerol ether and ethylenediamine according to the mass ratio of 10:2:1:6, and stirring to obtain an additive for later use;
S3, preparing slurry: 100 parts of granite graded aggregate, 16 parts of additive, 1.5 parts of graphite powder with the grain diameter of 200-250 um, 1.9 parts of nano silicon dioxide powder with the grain diameter of 200-250 um, 3.3 parts of calcium carbonate powder with the grain diameter of 200-250 um, 3.3 parts of talcum powder with the grain diameter of 200-250 um, 1 part of polypropylene fiber, 3 parts of steel fiber and 1 part of carbon fiber are taken according to the parts by mass, and evenly stirred, thus obtaining the artificial stone slurry.
In order to better illustrate the technical effects of the invention, it is illustrated by the following tests:
An example of a method of manufacturing artificial granite disclosed in the patent net (publication No. 2019-08-30, publication No. CN 106830794B) was adopted as a first comparative example, and an example of 1 of a method of manufacturing artificial granite disclosed in the patent net (publication No. 2018-11-30, publication No. CN108911582 a) was adopted as a second comparative example.
In the first, second, third and comparative examples, the granite aggregate comprises the following ::42.1%SiO2、16.2%Al2O3、8.3%Fe2O3、7.1%MgO、1.7%Na2O、21.9%CaSO4、2.7% other components in mass ratio. The artificial granite slurry obtained in the first, second and third embodiments is poured into a mold, vibrated, compacted, and foamed, cured at room temperature, demolded, and baked at 40-45 ℃ for 24-28 hours to form the artificial granite.
After curing for 28d, the artificial granite prepared in example one, example two, example three, comparative example one and comparative example two were taken, respectively, and samples having dimensions of 150mm×30mm were taken.
1. Drying the sample to constant weight, weighing the sample, respectively soaking the sample in water and lubricating oil for 48 hours, sucking surface liquid by using a paper towel, and weighing the sample again; the water absorption and oil absorption were calculated and recorded in table 1 below;
TABLE 1 moisture absorption Performance analysis Table for Artificial granite
From table 1 above, it can be derived that: the water absorption and oil absorption of the artificial granite prepared in the first embodiment, the second embodiment and the third embodiment are obviously lower than those of the artificial granite prepared in the first and the second comparative examples; and then can be derived: the artificial stone produced by the slurry prepared by the invention has low water absorption rate in water and oil, compact texture, small porosity, difficult corrosion and good durability.
2. The compressive strength (unit: MPa), tensile strength (unit: MPa), flexural strength (unit: MPa), elastic modulus (unit: GPa) and vibration frequency (unit: hz) at which maximum amplitude was generated at the time of forced vibration were each measured, and recorded in Table 2 below.
TABLE 2 analysis of Artificial granite Strength and damping Properties
From table 2 above, it can be derived that: the compressive strength, tensile strength and bending strength of the artificial granite prepared in the first, second and third examples are all obviously higher than those of the artificial granite prepared in the first and second comparative examples; and the elastic modulus of the artificial granite prepared in the first embodiment, the second embodiment and the third embodiment is obviously higher than the vibration frequency of the artificial granite prepared in the first and the second comparative examples when the artificial granite generates maximum amplitude under forced vibration, so that the following can be obtained: the artificial stone produced by the slurry has high compressive strength, tensile strength and bending strength, large elastic modulus, large shock resistance amplitude, high frequency, quick attenuation and excellent damping effect.
The foregoing description is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical solution of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.

Claims (6)

1. A method for preparing artificial stone slurry, which is characterized by comprising the following steps:
s1, preparing aggregate: crushing granite waste, screening, and respectively selecting coarse aggregates and fine aggregates of crushed stone granules; cleaning and drying respectively, and then mixing the crushed stone granules, coarse aggregate and fine aggregate according to the following proportion of 3:1:1, mixing and stirring the materials according to the mass ratio to obtain granite grading aggregate for later use;
S2, preparing an additive: mixing and stirring a binder, a toughening agent, a diluent and a curing agent according to the mass ratio of 10:2:1:6 to obtain an additive for standby;
S3, preparing slurry: taking 80-100 parts by mass of granite graded aggregate, 12-16 parts by mass of additive, 8-10 parts by mass of filler and 3-5 parts by mass of reinforcing material, and uniformly stirring to obtain artificial stone slurry; pouring the artificial stone slurry into a mould, vibrating, compacting, exhausting bubbles, solidifying at room temperature, demoulding, and baking at 40-45 ℃ for 24-28 h to form the artificial granite.
2. The method for producing an artificial stone slurry according to claim 1, wherein in the step S1, the particle size of the crushed stone particles is 5 to 10mm, the particle size of the coarse aggregate is 2.5 to 5mm, and the particle size of the fine aggregate is 1.25 to 2.5mm.
3. The method of claim 1, wherein in the step S2, the binder is bisphenol a epoxy resin, the toughening agent is dibutyl phthalate, and the curing agent is ethylenediamine.
4. A method for preparing artificial stone slurry according to claim 1, wherein in the step S2, the diluent is one or more of acetone, toluene, xylene, and diglycerol ether.
5. The method for preparing artificial stone slurry according to claim 1, wherein in the step S3, the filler is composed of graphite powder, nano silica powder, calcium carbonate powder and talcum powder in a mass ratio of (1-2): (2-3): (3-5): (3-5), and the particle sizes of the graphite powder, the nano silicon dioxide powder, the calcium carbonate powder and the talcum powder are all 200-250 um.
6. The method of producing an artificial stone slurry according to claim 1, wherein in the step S3, the reinforcing material is composed of polypropylene fibers, steel fibers and carbon fibers in a mass ratio of (2 to 3): (8-10): (2-3).
CN202410127308.6A 2024-01-30 2024-01-30 Preparation method of artificial stone slurry Pending CN118063130A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202410127308.6A CN118063130A (en) 2024-01-30 2024-01-30 Preparation method of artificial stone slurry

Publications (1)

Publication Number Publication Date
CN118063130A true CN118063130A (en) 2024-05-24

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Country Status (1)

Country Link
CN (1) CN118063130A (en)

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