CN1180475A - Composition of expelling mouse agent containing amido saccharide - Google Patents
Composition of expelling mouse agent containing amido saccharide Download PDFInfo
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- CN1180475A CN1180475A CN 97115110 CN97115110A CN1180475A CN 1180475 A CN1180475 A CN 1180475A CN 97115110 CN97115110 CN 97115110 CN 97115110 A CN97115110 A CN 97115110A CN 1180475 A CN1180475 A CN 1180475A
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- rat destruction
- resin
- amido
- saccharide
- rat
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Abstract
A composition containing amido saccharide class of mouse repellent is composed of mouse-repelling plastics, rubber, paint and adhesive and can be made into different shaped products.
Description
The present invention relates to contain a kind of combination preparation and the application in coating, rubber and plastics thereof of amido saccharide expelling mouse agent.Belong to the repellent field in the fine chemistry industry.
Muroid causes huge harm to the mankind for a long time.Because the life habit that the love of muroid bites does a lot of damage to the mankind's diet, trees, electric wire and some daily necessitiess.The mankind take the whole bag of tricks and muroid to struggle always for a long time, comprise that physical method is as the way that adopts armouring, method that medicine kills mouse and the method for medicine repellent.Have as traditional medicine repellant examples of applications many, such as: the method for the benzene thiocarbamide being made the rat destruction cable as the direct blending of expelling mouse agent in plastics has been described among the JP5272818.But, test discovery through us: benzene thiocarbamide poor heat resistance, 160 ℃ with regard to variable color, and 190 ℃ of just boilings are unsuitable for making the rat destruction cable.
As everyone knows, cycloheximide is the very desirable expelling mouse agent of a kind of repellent effect, and still, the cycloheximide warm tolerance is very poor, its direct blending can't be used in plastics.And cycloheximide toxicity is very strong, and humans and animals all is harmful to, so also inconvenience is directly mixed it in coating or the adhesive and used.Proposition is wrapped in cycloheximide and makes the cycloheximide microcapsules in the heat stable resin among the CN86108396A, and the cycloheximide microcapsules are applied in the plastics rat destruction cable as expelling mouse agent, overcome the shortcoming of cycloheximide poor heat resistance, obtained repellent effect preferably.But, be directed at itself owing to the cost of cycloheximide microcapsules itself is too high and possess what commercial value hardly.
And amido saccharide compound warm tolerance is fine, 220 ℃ of nondiscolourings in plastics, do not decompose, and in plastics, also play the effect of heat stabilizer, this be the benzene thiocarbamide with cycloheximide can't compare.And amido saccharide compound cost is lower, and the user can accept, and this is that the cycloheximide microcapsules are not available.On the other hand, the amido saccharide toxicity of compound is very low, can be applied in the field that plastics, rubber, coating and adhesive etc. are pressed close to human daily life safely.Therefore, the amido saccharide compound will have wide practical use.
Yet, the development and application of amido saccharide compound aspect expelling mouse agent but seldom, the potentiality of its rat destruction aspect are far from excavating.For example:
Propose among the EP173410 amido saccharide compound is used as birds repellant, such as: the pigeon repellant.
Schafer, E.W., Jr; Bowles, W.A., Jr, Archivs of Environmental Contaminationand Toxicology.1985,14 (1), measured the toxicity (LD of amido saccharide compound among the 111-29 (Eng.)
50), and assessed the repellent effect of amido saccharide compound, but do not relate to the applicable cases of amido saccharide compound at aspects such as plastics, rubber, coating, adhesives.
Among the WO9310712 amido saccharide compound is mixed with other expelling mouse agent as bitters, be used for the rat destruction of foodstuff seed.But this patent does not relate to the content of relevant rat destruction plastics, rat destruction rubber, rat destruction coating and rat destruction adhesive aspect.
Therefore one of purpose of the present invention is:
(1) the amido saccharide expelling mouse agent is mixed in the plastics, make the rat destruction plastic products, such as: rat destruction cable, cable rat destruction sheath, optical cable rat destruction sheath, rat destruction plastic tunnel film or rat destruction Masterbatch etc.
(2) the amido saccharide expelling mouse agent is mixed in the plastic optical fibre, make rat destruction plastic optical fibre goods, such as: rat destruction Polywoven Bag, rat destruction chemical fabric etc.
(3) the amido saccharide expelling mouse agent is mixed in the rubber, make the rat destruction rubber.
(4) the amido saccharide expelling mouse agent is mixed in the coating, make rat destruction coating.
(5) the amido saccharide expelling mouse agent is mixed in the adhesive, make the rat destruction adhesive.
Another object of the present invention is on calcium carbonate, atlapulgite and the carbon black that the amido saccharide expelling mouse agent is adsorbed on, and makes rat destruction calcium carbonate, rat destruction atlapulgite and rat destruction carbon black.
A further object of the present invention is:
(1) rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black are mixed in the plastics, make the rat destruction plastic products, such as: rat destruction cable, cable rat destruction sheath, optical cable rat destruction sheath, rat destruction plastic tunnel film or rat destruction Masterbatch etc.
(2) rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black are mixed in the plastic optical fibre, make rat destruction plastic optical fibre goods, such as: rat destruction Polywoven Bag, rat destruction chemical fabric etc.
(3) rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black are mixed in the rubber, make the rat destruction rubber.
(4) rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black are mixed in the coating, make rat destruction coating.
(5) rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black are mixed in the adhesive, make the rat destruction adhesive.
These and other objects of the present invention will further specify by following specific descriptions and embody.In the present invention, the amido saccharide expelling mouse agent has following structural formula:
R wherein
1, R
2, R
3, R
4, R
5, R
6, R
7And R
8Be identical or different and each is:
Hydrogen atom; C
1～C
25Alkyl; C
1～C
25Alkoxyl; Hydroxyl; Halogen atom; Alkylsulfonyloxy; Alkanoylamino; Alkyl amino; Benzoyl-amido; Aralkyl, wherein moieties is C
1～C
25And aryl moiety is C
6～C
10And be unsubstituted or have a substituting group (a) (hereinafter definition) at least; The aryl that has a substituting group (b) (hereinafter definition) at least; Aromatic yl alkenyl, wherein aryl moiety is C
6～C
10And alkenyl partly is C
2～C
25Alkenyl; Substituting group (a):
Hydrogen atom; C
1～C
25Alkyl; C
1～C
25Alkoxyl; Hydroxyl; Halogen atom; Alkylsulfonyloxy; Alkanoylamino; Alkyl amino; Benzoyl-amido; Nitro; Cyano group; Trifluoromethyl; Trichloromethyl; Substituting group (b):
Hydrogen atom; C
1～C
25Alkyl; C
1～C
25Alkoxyl; Hydroxyl; Halogen atom; Alkylsulfonyloxy; Alkanoylamino; Alkyl amino; Benzoyl-amido; Nitro; Cyano group; Trifluoromethyl; Trichloromethyl;
In the above-mentioned range of definition, the representative example of amido saccharide expelling mouse agent comprises:
1. eight formyl sucrose
2. octaacetyl sucrose
3. eight propionyl sucrose
4. eight butyryl sucrose
5. eight valeryl sucrose
6. eight hexanoyl sucrose
7. eight oenanthyl sucrose
8. eight decoyl sucrose
9. eight nonanoyl sucrose
10. eight caprinoyl sucrose
Eight 11. (chloracetyl) sucrose
Eight 12. (benzoyl) sucrose
Eight 13. (phenylacetyl) sucrose
Eight 14. (to chlorobenzoyl) sucrose
Eight 15. (adjacent chlorobenzoyl) sucrose
Eight 16. (p-nitrophenyl formyl) sucrose
Eight 17. (to methoxybenzoyl) sucrose
Eight 18. (O-methoxy benzoyl) sucrose
Eight 19. (para hydroxybenzene formyl) sucrose
Eight 20. ((2-hydroxybenzoyl)) sucrose
Eight 21. (2,4 dichloro benzene formyl) sucrose
Eight 22. (2, the 6-dichloro-benzoyl) sucrose
Eight 23. (to toluyl) sucrose
Eight 24. (toluyl) sucrose
Eight 25. (o-methyl-benzene formyl) sucrose
The present inventor has given one's full attention to such fact, has not only considered the crystallization of aforementioned acid amides sugar, also consider acid amides sugar only crystal form application and after deliberation many other methods.As a kind of result, crystallization of the present invention and dissolve each other fully with acid amides sugar or partial miscibility in order to be adsorbed onto the solvent in the micropore on the plastic additive, the preparation that forms with they and plastic additive such as calcium carbonate, atlapulgite, carbon black etc. can be effectively and economically as the rat destruction medicine and used dissolve each other with acid amides sugar or the solvent of partial miscibility or plastic additive and plastics are to be made to the rat destruction that the makes acid amides sugar material that descends of tiring hardly by a kind of.
In the rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black of absorption acid amides sugar expelling mouse agent of the present invention, contain 0.1-50% (weight), be preferably and account for 0.5-40% (weight), the best is the expelling mouse agent of 1.0-30% (weight).
Further found to mix with plastics or join in a kind of resin, a kind of coated substance, a kind of adhesive and the suchlike material, prepared the result and can keep over a long time strong repellent effect when acid amides sugar.And when the multiple use, expelling mouse agent also will keep stablizing.
Therefore, the present invention relates to a kind of rat destruction resin, comprising in the rat destruction resin with the resin component is the amido saccharide expelling mouse agent 0.1-50% (weight) of benchmark, preferentially adopts 0.5-40% (weight), the best 1.0-30% (weight) that adopts.
And, the present invention relates to a kind of rat destruction resin, comprise in the rat destruction resin with the resin component is rat destruction calcium carbonate and/or the rat destruction atlapulgite and/or the rat destruction carbon black 0.1-60% (weight) of the absorption acid amides sugar expelling mouse agent of benchmark, the preferential 0.5-50% (weight) that adopts, the best 1.0-40% (weight) that adopts.
Further, the present invention relates to a kind of acid amides sugar rat destruction coating composition that contains, used acid amides sugar quantity can restrain at 0.01-50/square metre, preferentially adopt the 0.05-40 gram/square metre, best adopt the 0.1-30 gram/square metre.
Further again, the present invention relates to a kind of rat destruction adhesive that contains acid amides sugar, can the restraining of used acid amides sugar at 0.01-50/square metre, preferentially adopt the 0.05-40 gram/square metre, best adopt the 0.1-30 gram/square metre.
Rat destruction calcium carbonate, rat destruction atlapulgite and rat destruction carbon black
The rat destruction calcium carbonate, rat destruction atlapulgite and the rat destruction carbon black that contain the amido saccharide expelling mouse agent can adopt any known production technology to produce.Such as: solution adsorption method, adsorption dry method, fusion absorption method etc.
The adsorption dry method is that the amido saccharide expelling mouse agent is dissolved in wiring solution-forming in the solvent, then this solution and calcium carbonate and/or atlapulgite and/or carbon black are mixed, make calcium carbonate and/or atlapulgite and/or carbon black adsorb this solution, leach calcium carbonate and/or atlapulgite and/or carbon black again, oven dry (can normal pressure or vacuum drying, temperature will be controlled at and be lower than amido saccharide expelling mouse agent fusing point more than 20 ℃), make the rat destruction calcium carbonate and/or rat destruction atlapulgite and/or the rat destruction carbon black that contain the amido saccharide expelling mouse agent.
The solvent of used dissolving amido saccharide expelling mouse agent must be safe in the adsorption dry method, and the amido saccharide expelling mouse agent must be chemically stable in solvent, that is this solvent can not damage the stability of amido saccharide expelling mouse agent.Therefore, available solvent in the present invention should meet this requirement, and has the ability of suitable dissolving amido saccharide expelling mouse agent again.The example of available solvent like that comprises alcohols, such as: methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, the tert-butyl alcohol, ethylene glycol and phenmethylol; Ketone, such as: acetone, butanone and cyclohexanone; Ethers, such as: ether, propyl ether, butyl ether, amyl ether and hexyl ether; Hydro carbons, such as: hexane, heptane, octane, nonane, decane, cyclohexane, benzene,toluene,xylene and isopropylbenzene; Halogenated hydrocarbons, such as: carrene, chloroform, tetrachloromethane, 1,2-dichloroethane, chlorobenzene, bromobenzene, ortho-chlorotolu'ene and parachlorotoluene; The ester class, such as: formic acid esters, acetic acid esters, propionic ester, butyrate, oxalate, salicylate, benzoic ether, phosphate, adipate ester and phthalic acid ester; Mineral oils, such as: gasoline, kerosene, diesel oil, paraffin oil, banana oil and benzinum; Other solvent, such as: formamide, dimethyl formamide, oxolane, acetonitrile and pyridine.
In the adsorption dry method, want and to use after rat destruction calcium carbonate and/or rat destruction atlapulgite and/or the rat destruction carbon black drying, then solvent for use must be a low boiling and volatile, adapt to this requirement, the above-mentioned alcohols of mentioning, ketone, ethers, hydro carbons, halogenated hydrocarbon, ester class, mineral oils or other solvent are a kind of selections preferably, wherein, alcohols is preferentially selected methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, the tert-butyl alcohol; Ketone is preferentially selected acetone, butanone and cyclohexanone; Ethers is preferentially selected ether, propyl ether; Hydro carbons is preferentially selected hexane, heptane, octane, nonane, decane, cyclohexane, benzene,toluene,xylene and isopropylbenzene; Halogenated hydrocarbon is preferentially selected carrene, chloroform, tetrachloromethane, 1,2-dichloroethane and chlorobenzene; The ester class is preferentially selected formic acid esters and acetic acid esters, such as: methyl formate, Ethyl formate, methyl acetate, ethyl acetate; Mineral oils is preferentially selected gasoline, diesel oil, banana oil and benzinum; Other solvent is preferentially selected dimethyl formamide, oxolane, acetonitrile and pyridine.And above-mentioned solvent not only can use separately, can also get two or more solvent as required and use, and this can decide according to actual conditions.
The fusion absorption method is with the fusion of amido saccharide expelling mouse agent, then this liquid and calcium carbonate and/or atlapulgite and/or carbon black are mixed, make calcium carbonate and/or atlapulgite and/or carbon black adsorb this liquid, leach calcium carbonate and/or atlapulgite and/or carbon black again, cooling, grind, make the rat destruction calcium carbonate and/or rat destruction atlapulgite and/or the rat destruction carbon black that contain the amido saccharide expelling mouse agent.Since the fusing point of some amido saccharide expelling mouse agent too high (some even above 300 ℃), and too high temperature makes variable color of amido saccharide expelling mouse agent even decomposition easily, and therefore, it is extensive that the range of application of fusion absorption method is not so good as the adsorption dry method.
Solution adsorption method is that the amido saccharide expelling mouse agent is dissolved in wiring solution-forming in the solvent, then this solution and calcium carbonate and/or atlapulgite and/or carbon black are mixed, make calcium carbonate and/or atlapulgite and/or carbon black adsorb this solution, leach calcium carbonate and/or atlapulgite and/or carbon black again, make the rat destruction calcium carbonate and/or rat destruction atlapulgite and/or the rat destruction carbon black that contain the amido saccharide expelling mouse agent.
The solvent of used dissolving amido saccharide expelling mouse agent must be safe in solution adsorption method, and the amido saccharide expelling mouse agent must be chemically stable in solvent, that is this solvent can not damage the stability of amido saccharide expelling mouse agent.Therefore, available solvent in the present invention should meet this requirement, and has the ability of suitable dissolving amido saccharide expelling mouse agent again.The example of available solvent like that comprises alcohols, such as: methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, the tert-butyl alcohol, ethylene glycol, glycerine and phenmethylol; Ketone, such as: acetone, butanone and cyclohexanone; Ethers, such as: ether, propyl ether, butyl ether, amyl ether and hexyl ether; Hydro carbons, such as: hexane, heptane, octane, nonane, decane, cyclohexane, benzene,toluene,xylene and isopropylbenzene; Halogenated hydrocarbons, such as: carrene, chloroform, tetrachloromethane, 1,2-dichloroethane, chlorobenzene, bromobenzene, ortho-chlorotolu'ene and parachlorotoluene; The ester class, such as: formic acid esters, acetic acid esters, propionic ester, butyrate, oxalate, salicylate, benzoic ether, phosphate, adipate ester and phthalic acid ester; Mineral oils, such as: gasoline, kerosene, diesel oil, atoleine, banana oil and benzinum; Other solvent, such as: formamide, dimethyl formamide, oxolane, acetonitrile and pyridine.
In solution adsorption method, want to make rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black heat-resisting, then solvent for use must be a high boiling point and nonvolatile, adapt to this requirement, the above-mentioned alcohols of mentioning, ester class, mineral oils are a kind of selections preferably, wherein, alcohols is preferentially selected ethylene glycol and glycerine; The ester class is preferentially selected phosphate, adipate ester and phthalic acid ester, such as: triphenyl phosphate, trioctyl phosphate and tricresyl phosphate, dibutyl adipate, dioctyl adipate and diisobutyl adipate, repefral, diethyl phthalate, dipropyl phthalate, dibutyl phthalate, diamyl phthalate, dihexylphthalate, dibutyl phthalate (DHP), dioctyl phthalate, phthalic acid ester in the ninth of the ten Heavenly Stems, didecyl phthalate, dibenzyl phthalate and diisopropyl phthalate; Mineral oils is preferentially selected atoleine (boiling point is more than 300 ℃).And above-mentioned solvent not only can use separately, can also get two or more solvent as required and use, and this can decide according to actual conditions.
Rat destruction resin combination (one)
In rat destruction resin combination of the present invention, available is not the special resin that contains acid amides sugar that limits.
Available resin examples comprises thermoplastic resin, thermosetting resin, synthetic rubber and natural resin.
Specifically, thermoplastic resin comprises the vinyl class, such as: polyvinyl chloride, polyvinyl acetate, Vingon, polyvinyl alcohol; Petroleum resinoid, such as: polyethylene, polypropylene and polybutene; Crylic acid resin, such as: methacrylic resin and acrylonitrile; Styrene resin lipid, such as: polystyrene, ABS resin; And polyamide.
Viewpoint from the application of rat destruction resinous principle, thermoplastic resin is particularly useful, comprise polymer and the copolymer that forms from monomer with vinyl, that is, the polyethylene of polyethylene, polypropylene, polyvinyl chloride, polyvinyl acetate, polyvinyl alcohol, polystyrene, ethylene-vinyl acetate copolymer, interlinkage, polyvinyl chloride, polystyrene and ethylene-acrylic acid copolymer.
The example of thermosetting resin comprises phenolic resins, urea resin, melamine resin, polyesters, polyurethanes and epoxy resin.In addition, elastomeric example, comprise dienes, chain alkene, acrylic compounds, polyurethanes, silicone rubber kinds, fluorine series rubber-like, their object lesson comprises: polybutadiene, SBR, NBR, butyl rubber, chloroprene rubber, Oppanol, methylene rubber, acrylic rubber and silicon rubber.In addition, the example of natural resin comprises rosin.
In these resins, preferential especially example comprises polyvinyl chloride, polyethylene, polypropylene, polystyrene, ABS resin, phenolic resins, epoxy resin and aminoplast.
For the ease of processing and raising stability, in resin, can add plasticizer, stabilizing agent, lubricant, colouring agent, fire retardant, antioxidant and other suitable additive.
Being used in acid amides sugar of the present invention can be by known technology preparation, the content of acid amides sugar is usually in 0.1-50% (weight) in the rat destruction resin, the preferential 0.5-40% (weight) that adopts, the best 1.0-30% (weight) that adopts, this depends on the kind of used place, existing processing step and resin.
The rat destruction resin combination that acid amides sugar and mixed with resin make can be used with solid form, liquid form and form like that.In addition, in the rat destruction paste resin, except adding acid amides sugar, also can add proper additive, such as: plasticizer and dispersant.It can be used with direct mode, is coated on the object of wanting rat destruction by dipping or filling.Further, can consider the kneading of acid amides sugar in the resin of fusing, to be processed into the shape that needs then and to use.
As mentioned above, the rat destruction resin that contains acid amides sugar itself has outstanding repellent effect, thus they can be applicable to various rat destruction fillers and with direct mode as the rat destruction material, with paste or be molded as the shape that needs.Such as: rat destruction inserts, rat destruction powder material and like that.
The example of molded rat destruction resin comprises the wire goods, such as electric wire and hawser, hollow product, and such as pipe, flexible pipe, housing and bag, and stampings, such as: winding, thin slice and be used for the canvas and the film of flexible container.
In these molded rat destruction goods, the content of acid amides sugar is in 0.1-50% (weight).As an example when the rat destruction molded products is electric wire or cable, acid amides sugar is to be combined in the insulating barrier of electric wire or in the shell of cable, so that the content of acid amides sugar in 0.1-50% (weight), is preferably 0.5-40% (weight), the best is 1.0-30% (weight).On the other hand, the rat destruction electric wire and cable is made at electric wire insulation layer or cable outer layer surface formation coating by the rat destruction resin combination, and in the coating of Xing Chenging, the content of acid amides sugar is identical with the content of acid amides sugar in insulating barrier or the shell in this case.Under each situation, electric wire or cable can adopt the usual method that electric wire is covered with paint, lacquer, colour wash, etc. in this field to cover with paint, lacquer, colour wash, etc.
Rat destruction band, sheet and be used for these rat destruction goods of the canvas that contains fiber of flexible containers can be by directly being pressed into the rat destruction resin or providing the rat destruction composition by laminated molding technology.For the molded product of the rat destruction of considering thin slice, the content of acid amides sugar in them is 0.1-50% (weight), is preferably 0.5-40% (weight), and the best is 1.0-30% (weight).
Except the above-mentioned goods of mentioning, rat destruction resinous principle of the present invention can be used in various films (particularly agricultural film) ethene leather, ethene watt and the like.
Rat destruction resin combination (two)
In rat destruction resin combination of the present invention, available is not the special resin that contains rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black that limits.
Available resin examples comprises thermoplastic resin, thermosetting resin, synthetic rubber and natural resin.
Specifically, thermoplastic resin comprises the vinyl class, such as: polyvinyl chloride, polyvinyl acetate, Vingon, polyvinyl alcohol; Petroleum resinoid, such as: polyethylene, polypropylene and polybutene; Crylic acid resin, such as: methacrylic resin and acrylonitrile; Styrene resin lipid, such as: polystyrene, ABS resin; And polyamide.
Viewpoint from the application of rat destruction resinous principle, thermoplastic resin is particularly useful, comprise polymer and the copolymer that forms from monomer with vinyl, that is, the polyethylene of polyethylene, polypropylene, polyvinyl chloride, polyvinyl acetate, polyvinyl alcohol, polystyrene, ethylene-vinyl acetate copolymer, interlinkage, polyvinyl chloride, polystyrene and ethylene-acrylic acid copolymer.
The example of thermosetting resin comprises phenolic resins, urea resin, melamine resin, polyesters, polyurethanes and epoxy resin.In addition, elastomeric example, comprise dienes, chain alkene, acrylic compounds, polyurethanes, silicone rubber kinds, fluorine series rubber-like, their object lesson comprises: polybutadiene, SBR, NBR, butyl rubber, chloroprene rubber, Oppanol, methylene rubber, acrylic rubber and silicon rubber.In addition, the example of natural resin comprises rosin.
In these resins, preferential especially example comprises polyvinyl chloride, polyethylene, polypropylene, polystyrene, ABS resin, phenolic resins, epoxy resin and aminoplast.
For the ease of processing and raising stability, in resin, can add plasticizer, stabilizing agent, lubricant, fire retardant, antioxidant and other suitable additive.
Being used in rat destruction calcium carbonate of the present invention, rat destruction atlapulgite and rat destruction carbon black can be by at present known technology preparation, the content of rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black is usually in 0.1-60% (weight) in resin, the preferential 0.5-50% (weight) that adopts, the best 1.0-40% (weight) that adopts, this depends on the kind of used place, existing processing step and resin.
The rat destruction resin combination of rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black and mixed with resin can be used with solid form and form like that.In addition, in the rat destruction paste resin, except adding rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black, also can add proper additive, such as: plasticizer and dispersant.It can be used with direct mode, can consider rat destruction calcium carbonate and/or rat destruction atlapulgite and/or the kneading of rat destruction carbon black to be processed into the shape that needs then and to use in the resin of fusing.
As mentioned above, the rat destruction resin that contains rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black itself has outstanding repellent effect, so they can be applicable to various rat destruction fillers and with direct mode as the rat destruction material, with paste or be molded as the shape that needs.Such as: rat destruction inserts, rat destruction powder material and like that.
The example of molded rat destruction resin comprises the wire goods, such as electric wire and hawser, hollow product, and such as pipe, flexible pipe, housing and bag, and stampings, such as: winding, thin slice and be used for the canvas and the film of flexible container.
In these molded rat destruction goods, the content of rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black is in 0.1-60% (weight).As an example when the rat destruction molded products is electric wire or cable, rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black are to be combined in the insulating barrier of electric wire or in the shell of cable, so that the content of rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black is in 0.1-60% (weight), be preferably for 0.5-50% (weight), the best is 1.0-40% (weight).On the other hand, the rat destruction electric wire and cable is made at electric wire insulation layer or cable outer layer surface formation coating by the rat destruction resin combination, in this case in the coating of Xing Chenging, the content of rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black is identical in the content of rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black and insulating barrier or the shell.Under each situation, electric wire or cable can adopt the usual method that electric wire is covered with paint, lacquer, colour wash, etc. in this field to cover with paint, lacquer, colour wash, etc.
Rat destruction band, sheet and be used for these rat destruction goods of the canvas that contains fiber of flexible containers can be by directly being pressed into the rat destruction resin or providing the rat destruction composition by laminated molding technology.For the molded product of the rat destruction of considering thin slice, rat destruction calcium carbonate and/or rat destruction atlapulgite and/or the content of rat destruction carbon black in them are 0.1-60% (weight), are preferably 0.5-50% (weight), and the best is 1.0-40% (weight).
Except the above-mentioned goods of mentioning, rat destruction resinous principle of the present invention can be used in various films (particularly agricultural film) ethene leather, ethene watt and the like.
It is emphasized that in the resin combination that contains rat destruction calcium carbonate and/or rat destruction atlapulgite and/or rat destruction carbon black the content of amido saccharide expelling mouse agent is 0.1-50% (weight), optimum content is 1.0-30% (weight).
The rat destruction coating material
Rat destruction coating material of the present invention is the mixture of coating material and acid amides sugar.
According to the kind classification of coating material, the example of coating material comprises: oiliness coating material, alcohol coating material, match sieve Lopa Nationality coating material, synthetic resin coated layer material, water quality coating material, rubber series coating material.Above-mentioned oiliness coating material of promoting to a higher rank comprises: stand oil, paint, oily note on the use water and enamel paint; The alcohol coating material comprises: natural resin note on the use water and synthetic resin note on the use water; Match sieve Lopa Nationality coating material comprises: wax removal gram and lacquer enamel paint; Synthetic resin coated layer material comprises: water quality coating material note on the use water, synthetic enamel and polymer emulsion coating material; The water quality coating material comprises: water quality lacquer, emulsion paint and polymer emulsion coating material; Rubber series coating material comprises: chlorinated rubber coating material, cyclization rubber and synthetic rubber coating material are as SBR and like that.
At first, synthetic resin note on the use water is best, and their example comprises: phenolic resins note on the use water, phthalic resin note on the use water, maleic acid resin note on the use water, vinyl note on the use water, epoxy resin note on the use water, silicones note on the use water, furane resins note on the use water and mylar note on the use water.In these note on the use water, vinyl note on the use water is useful especially, and their example comprises: vinyl acetate resin note on the use water, vinyl chloride-vinyl acetate copolymer note on the use water, polystyrene note on the use water, acrylic resin note on the use water and polyethylene butyraldehyde note on the use water.
In fact the above-mentioned coating material of mentioning can comprise the pigment that plasticizer, desiccant, curing agent, dispersant, decortication inhibitor, thickener, flatting agent, anti-heavy agent, mildewcide, ultraviolet absorber and conduct form second component of coated film.The sugared rat destruction coating composition that mixes or be dispersed in the resin of acid amides can directly be used as the coating material of the electric wire on communication, signal or the electric power, and can be used as the flexible container that the vinyl chloride sheet forms.In addition, the above-mentioned rat destruction coating material of mentioning can be used in that various paper are that do, synthetic resin, on sack cloth or that dry goods is done and wall paper, wallpaper and interior of building ornament materials, be made into rat destruction sack, rat destruction cloth and rat destruction house decorative material thus.
The rat destruction goods that apply with the rat destruction coating material can adopt common coating technology preparation, the example of these coating technologies comprises: brush applied coating, sprayed coating, electrostatic coating, electro-deposition and printing technique such as serigraphy.In this case, can adopt coating machine, available coating machine comprises: scraper applicator, printing applicator and air knife coaters.
In the coating of used rat destruction coating material acid amides sugar account for 0.01-50 gram/square metre, be preferably the 0.05-40 gram/square metre, best for 0.1-30 restrain/square metre.
The rat destruction adhesive
Rat destruction adhesive of the present invention is the mixture of adhesive and acid amides sugar.
Available adhesive comprises: composite adhesives, rubber series adhesive and natural glue.Composite adhesives comprises the resin series adhesive, such as: phenolic resins, urea resin, melamine resin, polyamide, Corvic, polyvinyl acetate resin, acrylic resin, polyvinyl alcohol resin, polyurethane resin and epoxy resin.Rubber series adhesive comprises: chlorobutadiene, acrylonitrile-butadiene rubber, SBR, silicon rubber, natural rubber, butyl rubber, reclaimed rubber and polysulfide rubber; And natural glue comprises: gummed starch.In addition, available adhesive comprises: polyisobutene, polyvinyl ester, chlorinated rubber, match sieve Lopa Nationality and pitch series adhesive.
In fact the above-mentioned adhesive of mentioning can comprise a kind of solvent, plasticizer, resin, thickener, inserts, pigment, preservative and other required additives.
Acid amides sugar mixes or is scattered in the rat destruction adhesive of gained in the adhesive, can directly be applied in rat destruction bag or the container flexible container of doing as wall paper, interior of building ornament materials, paper bag, vinyl chloride sheet bonding.In addition, the rat destruction adhesive can be used as the rat destruction adhesive tape, is coated on the vinyl chloride thin slice in the adhesive that has viscosity usually and with the rat destruction adhesive by the kneading of acid amides sugar.In addition, the sealing medium that disperses or contain acid amides sugar can directly be used in the place that mends a split and be tightly connected.
When rat destruction adhesive of the present invention is used as general jointing material and is used, the key component of adhesive can be at first selected according to the viscosity of object, and acid amides sugar can disperse or be blended in the selected key component in the adhesive preparation process, or acid amides sugar can join in the adhesive in use.
In addition, the rat destruction adhesive is used under the occasion of the band or the adhesive phase of sticking paper, at first the acid amides sugar with needs is blended in the adhesive, be administered on the plastic sheet then, on the paper or suchlike holder, by paint-on technique with the preparation adhesive phase, and the holder that will have adhesive phase cuts into band or sticking paper, is wrapped in them on the object or they are clung on object.By the use of this rat destruction adhesive, rat destruction electric wire, the rubber hose that is used for gas or vinyl chloride water pipe can be easily by twining the rat destruction band or gluing paper at electric wire, flexible pipe or pipe, and these objects are handled without rat destruction.
Further, because rodent infringement fruit tree is coated on the fruit tree and can ideally prevents in the tree or with the rat destruction adhesive by twining the rat destruction band.
Be used as under the sealing medium situation at the rat destruction adhesive, acid amides sugar fully is blended in a kind of liquid-carrier, such as: a kind of oil, polybutene or alkyd resins or a kind of mineral filler, such as: calcium carbonate or asbestos are made main composition, and the rat destruction adhesive of Xing Chenging can be used as encapsulant thus.
In the rat destruction adhesive coating quantity of used acid amides sugar be 0.01-50 gram/square metre, preferentially be adopted as the 0.05-40 gram/square metre, the best be adopted as the 0.1-30 gram/square metre.The content of acid amides sugar should be considered adhesive strength and apply quantity in the adhesive.
In order to further describe and illustrate the present invention, provide following examples.These embodiment that provided are as understanding illustrative purposes, and description herein is not the claim that limits the present invention and state below.
Embodiment one
With 50 gram eight (chloracetyl) sucrose dissolved wiring solution-forming in 100 ml methanol, be heated to 50 ℃, then this solution is mixed with 50 gram carbon blacks (channel process), make carbon black adsorb this solution.Stirred 30 minutes, and leached carbon black more while hot, with the washing of 10 ml methanol, vacuum drying then (20 ℃ of temperature, vacuum 20mmHg) makes the rat destruction carbon black that contains eight (chloracetyl) sucrose, 20.8% (weight).
Embodiment two
With 50 gram eight formyl sucrose dissolved wiring solution-forming in 100 ml methanol, be heated to 60 ℃, then this solution and 100 gram atlapulgites (fineness 200 orders, the place of production, Fushun) are mixed, make atlapulgite adsorb this solution.Stirred 30 minutes, and leached carbon black more while hot, with the washing of 10 ml methanol, vacuum drying then (20 ℃ of temperature, vacuum 20mmHg) makes the rat destruction atlapulgite that contains eight formyl sucrose 17.3% (weight).
Embodiment three
With 50 gram eight (to toluyl) sucrose dissolved wiring solution-forming in 100 ml methanol, be heated to 50 ℃, then this solution is mixed with 80 gram precipitated calcium carbonates, make precipitated calcium carbonate adsorb this solution.Stirred 50 minutes, and leached precipitated calcium carbonate more while hot, with the washing of 10 ml methanol, vacuum drying then (20 ℃ of temperature, vacuum 20mmHg) makes the rat destruction calcium carbonate that contains eight (to toluyl) sucrose, 6.5% (weight).
Embodiment four
The rat destruction carbon black that will contain eight (chloracetyl) sucrose, 20.8% (weight) mixes and makes thickness in the Polyethylene insulated cable protective cover material is 2.0 millimeters cable jacket material compressing tablet, makes a control cable protective cover material compressing tablet (processing of cable jacket material compressing tablet can be adopted synchronous extruding and other technology manufacturing) of not mixing the rat destruction carbon black simultaneously.
The composition weight umber
Low density polyethylene (LDPE) 100
The rat destruction carbon black 11 that contains eight (chloracetyl) sucrose, 20.8% (weight)
With cable jacket material compressing tablet that is mixed with the rat destruction carbon black that obtains in the said method and the control cable protective cover material compressing tablet of not mixing the rat destruction carbon black, cut the sample of making 2 centimetres of 5 cm x respectively.A slice is mixed with the cable cover(ing) material samples of rat destruction carbon black and control cable protective cover material sample that a slice is not mixed the rat destruction carbon black as one group, put into one group in every mouse cage, have three mouse cages, a Cricetulus barabensis is arranged in every mouse cage, feed and drinking-water are provided, allow it place 10 days.Take out cable jacket material every day, observe the situation that is bitten and damage by mouse.(seeing Table 1):
Table 1
Embodiment five
The rat destruction atlapulgite that will contain eight formyl sucrose 17.3% (weight) mixes and makes thickness of insulating layer in the polyvinyl chloride cable material is 1.0 millimeters cable, makes a control cable (processing of cable can be adopted synchronous extruding and other technology manufacturing) of not mixing the rat destruction atlapulgite simultaneously.
The composition weight umber
Polyvinyl chloride 100
Dioctyl phthalate 30
Lead sulfate 8
Lead stearate 1
The rat destruction atlapulgite 25 that contains eight formyl sucrose 17.3% (weight)
With cable that is mixed with the rat destruction atlapulgite that obtains in the said method and the control cable of not mixing the rat destruction atlapulgite, cutting respectively and making length is 10 centimetres sample.With a cable sample that is mixed with the rat destruction atlapulgite and a control cable sample of not mixing the rat destruction atlapulgite as one group, put into one group in every mouse cage, have three mouse cages, a Cricetulus barabensis is arranged in every mouse cage, feed and drinking-water are provided, allow it place 5 days, take out cable every day, observe the situation that is bitten and damage by mouse.(seeing Table 2):
Table 2
Embodiment six
Eight (to chlorobenzoyl) sucrose mixed to make thickness in the Polyethylene insulated cable protective cover material be 2.0 millimeters cable jacket material compressing tablet, make a control cable protective cover material compressing tablet (processing of cable jacket material compressing tablet can be adopted synchronous extruding and other technology manufacturing) of not mixing eight (to chlorobenzoyl) sucrose simultaneously.
The composition weight umber
Polyethylene 92
PEWAX 6
Eight (to chlorobenzoyl) sucrose 2
With cable jacket material compressing tablet that is mixed with eight (to chlorobenzoyl) sucrose that obtains in the said method and the control cable protective cover material compressing tablet of not mixing eight (to chlorobenzoyl) sucrose, cut the sample of making 2 centimetres of 5 cm x respectively.A slice is mixed with the cable cover(ing) material samples of eight (to chlorobenzoyl) sucrose and a control cable protective cover material sample of not mixing eight (to chlorobenzoyl) sucrose as one group, put into one group in every mouse cage, have three mouse cages, a Cricetulus barabensis is arranged in every mouse cage, feed and drinking-water are provided, allow it place 10 days.Take out cable jacket material every day, observe the situation that is bitten and damage by mouse.(seeing Table 3):
Table 3
Embodiment seven
Eight (to methoxybenzoyl) sucrose mixed to make thickness of insulating layer in the polyvinyl chloride cable material be 1.0 millimeters cable, make a control cable (processing of cable can be adopted synchronous extruding and other technology manufacturing) of not mixing eight (to methoxybenzoyl) sucrose simultaneously.
The composition weight umber
Polyvinyl chloride 100
Dioctyl phthalate 30
Lead sulfate 8
Lead stearate 1
Atlapulgite 30
Eight (to methoxybenzoyl) sucrose 5
With cable that is mixed with eight (to methoxybenzoyl) sucrose that obtains in the said method and the control cable of not mixing eight (to methoxybenzoyl) sucrose, cutting respectively and making length is 10 centimetres sample.With a cable sample that is mixed with eight (to methoxybenzoyl) sucrose and a control cable sample of not mixing eight (to methoxybenzoyl) sucrose as one group, put into one group in every mouse cage, have three mouse cages, a Cricetulus barabensis is arranged in every mouse cage, feed and drinking-water are provided, allow it place 5 days, take out cable every day, observe the situation that is bitten and damage by mouse.(seeing Table 4):
Table 4
Embodiment eight
A kind of coating material is according to following formulation.Zhi Bei coating material can be used as the manufacturing of PVC canvas thus.
The composition weight umber
Polyvinyl chloride-acrylic copolymeric resin 30
(20: 80, average degree of polymerization 500)
Toluene 50
Acetone 10
Banana oil 40
Eight (p-nitrophenyl formyl) sucrose 3
Above mentioned PVC canvas is to be base fabric with the polyester material, adopts pressing process polyvinyl chloride composite to be pressed in the canvas of the softness that makes on the base fabric.The prescription of polyvinyl chloride composite is as follows:
The composition parts by weight of polyvinyl chloride composite
Polyvinyl chloride 100
(average degree of polymerization is 1500)
Dioctyl phthalate 30
Lead sulfate 5
Lead stearate 1
Chlorinated paraffin wax 15
Coating material is applied the two sides of canvas respectively, and consumption is 20 gram coating material/square metre canvas.The canvas that coats obtains the rat destruction canvas 60 ℃ of dryings 5 minutes.Do not contain the canvas of the coating material of eight (p-nitrophenyl formyl) sucrose with same technology manufacturing, in contrast.Canvas is cut into the print of 5 centimetres of 10 cm x, makes sack then, two yellow corns of parcel in each sack, the sack edge is sealed with staple.Get three mouse cages, a Cricetulus barabensis is arranged in every mouse cage, mouse heavily is about 90 grams, drinking-water is provided, but does not provide feed.Put into a rat destruction canvas sack and a contrast canvas sack in every mouse cage, allow it place 24 hours, observe the situation that is bitten and damage by mouse.(seeing Table 5):
Table 5
Embodiment nine
Eight (benzoyl) sucrose is blended in the acrylate adhesive, makes the rat destruction adhesive, it is as follows to fill a prescription:
The composition weight umber
Esters of acrylic acid 100
(180-3 type, solid content 40%, the positive chemical plant of Shanghai Songjiang County China)
Eight (benzoyl) sucrose 30
Get the PVC copper core cable of 3.5 millimeters of external diameters, be cut into two sections, wherein one section at the above-mentioned rat destruction adhesive of surface-coated, apply consumption and be 30 gram rat destruction adhesives/square metre, the sealed polyethylene plastic of one deck 0.2 millimeters thick is twined in the outside, 80 ℃ of air dryings 30 minutes, be cut into the section of 10 centimeter length, make the rat destruction cable sample; Another section does not contain the acrylate adhesive of eight (benzoyl) sucrose in surface-coated, apply consumption and also be 30 gram adhesives/square metre, the sealed polyethylene plastic of one deck 0.2 millimeters thick is twined in the outside, 80 ℃ of air dryings 30 minutes, be cut into the section of 10 centimeter length, make the control cable sample.Get three mouse cages, a Cricetulus barabensis is arranged in every mouse cage, mouse heavily is about 80 grams, and feed and drinking-water are provided.Put into a rat destruction cable sample and a control cable sample in every mouse cage, allow it place 5 days, take out cable every day, observe the situation that is bitten and damage by mouse.(seeing Table 6):
Table 6
The present invention includes the rat destruction resin combination, coating material and the adhesive that contain acid amides sugar expelling mouse agent, they have outstanding repellent effect.Therefore, they can directly be used as the rat destruction material widely or be spiked into various objects, can adopt various technologies, as: blending, coating, spary, dipping, lamination, filling, winding or like that.
Those skilled in the art can make multiple variation and change according to content disclosed by the invention, all should understand within the scope of the present invention, limited by the present invention's claim.
Claims (6)
1. the composition of an expelling mouse agent containing amido saccharide is characterized in that the structure of described amido saccharide (I) is as follows:
R wherein
1, R
2, R
3, R
4, R
5, R
6, R
7And R
8Be identical or different and each is:
Hydrogen atom; C
1～C
25Alkyl; C
1～C
25Alkoxyl; Hydroxyl; Alkylsulfonyloxy; Alkanoylamino; Alkyl amino; Benzoyl-amido; Aralkyl, wherein moieties is C
1～C
25And aryl moiety is C
6～C
10And be unsubstituted or have a substituting group (a) (hereinafter definition) at least; The aryl that has a substituting group (b) (hereinafter definition) at least; Aromatic yl alkenyl, wherein aryl moiety is C
6～C
10And alkenyl partly is C
2～C
25Alkenyl; Substituting group (a):
Hydrogen atom; C
1～C
25Alkyl; C
1～C
25Alkoxyl; Hydroxyl; Halogen atom; Alkylsulfonyloxy; Alkanoylamino; Alkyl amino; Benzoyl-amido; Nitro; Cyano group; Trifluoromethyl; Trichloromethyl; Substituting group (b):
Hydrogen atom; C
1～C
25Alkyl; C
1～C
25Alkoxyl; Hydroxyl; Halogen atom; Alkylsulfonyloxy; Alkanoylamino; Alkyl amino; Benzoyl-amido; Nitro; Cyano group; Trifluoromethyl; Trichloromethyl;
Title compound (I) is adsorbed on calcium carbonate, atlapulgite and the carbon black, makes rat destruction calcium carbonate, rat destruction atlapulgite, rat destruction carbon black; In title compound (I) and the rat destruction calcium carbonate of making, rat destruction atlapulgite, the rat destruction carbon black one or more are mixed make rat destruction plastic products, rat destruction resin in plastics or the resin; Mix in the plastic optical fibre, make rat destruction plastic optical fibre goods; Mix in the rubber, make the rat destruction rubber; Mix in the coating, make rat destruction and be coated with material products; Mix in the adhesive, make the rat destruction adhesive article; All goods have added additives such as plasticizer, stabilizing agent, lubricant, curing agent, desiccant, dispersant, fire retardant, antioxidant, mildewcide respectively for the safety in application and stable.
2. amido saccharide expelling mouse agent composition as claimed in claim 1, it is characterized in that containing in the said preparation rat destruction active ingredient amido saccharide expelling mouse agent is 0.1-50% (weight), optimum content is 1.0-30% (weight).
3. in the rat destruction resin combination as claimed in claim 1, its feature is resinous in composition to be 0.1-98% (weight), and optimum content is 1.0-90% (weight).
4. in rat destruction coating as claimed in claim 1 and the rat destruction adhesive coating, the occupancy volume that it is characterized in that amido saccharide expelling mouse agent in the coating be 0.01-50 gram/square metre, best for 0.1-30 restrain/square metre.
5. as claim 1,3 described rat destruction resin combinations, it is characterized in that the resin that is adopted has thermoplastic resin, thermosetting resin, synthetic rubber and natural resin.
6. the amido saccharide expelling mouse agent composition that proposes with the present invention is made a kind of moulded products for rat destruction active ingredient, is used for rat destruction as column, wire, rope form, band shape, belt tubulose, hose-like, winding shape, band shape, sheet or film shape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97115110A CN1067514C (en) | 1997-07-21 | 1997-07-21 | Composition of expelling mouse agent containing amido saccharide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97115110A CN1067514C (en) | 1997-07-21 | 1997-07-21 | Composition of expelling mouse agent containing amido saccharide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1180475A true CN1180475A (en) | 1998-05-06 |
| CN1067514C CN1067514C (en) | 2001-06-27 |
Family
ID=5173129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97115110A Expired - Fee Related CN1067514C (en) | 1997-07-21 | 1997-07-21 | Composition of expelling mouse agent containing amido saccharide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1067514C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8877735B2 (en) * | 2004-08-31 | 2014-11-04 | The Procter & Gamble Company | Alkoxylated sucrose esters composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3592910A (en) * | 1968-10-30 | 1971-07-13 | Arthur R Clark | Compositions and method for controlling release of pesticides using terpene polymers |
| EP0173410A1 (en) * | 1984-05-09 | 1986-03-05 | Michael James Sampson | Repellent for birds and other creatures |
| FR2663815A1 (en) * | 1990-06-27 | 1992-01-03 | Montpellier Ii Universite | Composition and application, as antiappetite agent, of sucrose esters |
-
1997
- 1997-07-21 CN CN97115110A patent/CN1067514C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8877735B2 (en) * | 2004-08-31 | 2014-11-04 | The Procter & Gamble Company | Alkoxylated sucrose esters composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1067514C (en) | 2001-06-27 |
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