CN117977106A - Preparation method of lithium ion battery diaphragm - Google Patents
Preparation method of lithium ion battery diaphragm Download PDFInfo
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- CN117977106A CN117977106A CN202410034094.8A CN202410034094A CN117977106A CN 117977106 A CN117977106 A CN 117977106A CN 202410034094 A CN202410034094 A CN 202410034094A CN 117977106 A CN117977106 A CN 117977106A
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- pvdf
- lithium ion
- dimethylformamide
- diaphragm
- stirring
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 81
- 238000002347 injection Methods 0.000 claims abstract description 50
- 239000007924 injection Substances 0.000 claims abstract description 50
- 239000002033 PVDF binder Substances 0.000 claims abstract description 47
- 239000012528 membrane Substances 0.000 claims abstract description 38
- 238000003756 stirring Methods 0.000 claims abstract description 27
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 25
- 239000000243 solution Substances 0.000 claims abstract description 24
- 239000012046 mixed solvent Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000005096 rolling process Methods 0.000 claims abstract description 8
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims abstract description 7
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000005520 cutting process Methods 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000004080 punching Methods 0.000 claims abstract description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 42
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 36
- 239000000835 fiber Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 238000009827 uniform distribution Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 33
- 239000012621 metal-organic framework Substances 0.000 description 20
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000011056 performance test Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000013110 organic ligand Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QTJOIXXDCCFVFV-UHFFFAOYSA-N [Li].[O] Chemical compound [Li].[O] QTJOIXXDCCFVFV-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000011258 core-shell material Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000012923 MOF film Substances 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012921 cobalt-based metal-organic framework Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000002090 nanochannel Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/426—Fluorocarbon polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
- H01M50/406—Moulding; Embossing; Cutting
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/491—Porosity
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/22—Polymers or copolymers of halogenated mono-olefins
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Cell Separators (AREA)
Abstract
The invention discloses a lithium ion battery diaphragm and a preparation method thereof, the method comprises the steps of adding cobalt nitrate hexahydrate into N, N-dimethylformamide, carrying out ultrasonic stirring, then adding PVDF (polyvinylidene fluoride), stirring at room temperature to prepare a solution with 15.5-20 wt.% and transferring the solution into an electrostatic spinning injection pump for electrostatic spinning, and obtaining a fibrous membrane I on a receiving roller; adding 2-methylimidazole into N, N-dimethylformamide, stirring by ultrasonic, then adding PVDF (polyvinylidene fluoride), stirring at room temperature to prepare a solution of 14.6-18.2 wt.%, then transferring into an injection pump, carrying out electrostatic spinning, and covering a fibrous membrane II on the surface of a fibrous membrane I on a receiving roller; then putting the membrane in a container in a flat way, adding a mixed solvent, standing for 8-12 h, taking out the membrane from the mixed solvent, drying for 3-5 h at 60-70 ℃, pressing and rolling by a roller press, and then cutting the membrane into a membrane with the diameter of 19mm by a punching machine.
Description
Technical Field
The invention belongs to the technical field of lithium ion battery diaphragms, and particularly relates to a preparation method of a lithium ion battery diaphragm.
Background
As a currently dominant energy storage system, high-speed Lithium Ion Batteries (LIBs) are increasingly demanded in high-performance and lightweight electronic products, so people have higher requirements on the performance of lithium ion batteries: high energy density, excellent cycle stability, high safety performance. The key to constructing high performance LIBs is to improve lithium ion conduction between the electrode and the electrons, while efficient transport of lithium ions within the battery separator remains a challenge for high energy density lithium ion batteries.
PVDF (polyvinylidene fluoride) has a large dielectric constant and strong C-F bonds, and becomes a good material for manufacturing a separator, but a simple PVDF separator is easy to crystallize to affect ion conductivity, and many researches are focused on a battery separator based on a MOF material at the present stage, which can promote uniform flux of lithium ions and improve ion conductivity. For example, chinese patent document CN109428036B discloses a method for preparing a lithium-oxygen battery separator. The method comprises the steps of preparing a polymer PMMA film by an evaporation drying film forming method, acidizing the film, and then preparing an MOF film by taking the PMMA film as a substrate; co (NO 3)2·6H2 O) is dissolved in pelargonic acid and ethanol to obtain mixed solution, magnetic stirring is carried out, trimesic acid and triethylamine are added for continuous stirring, the solution is transferred into a polytetrafluoroethylene reaction kettle liner, PMMA film is clamped by tweezers and placed into the polytetrafluoroethylene reaction kettle liner for hydrothermal synthesis, the film obtained after the reaction is taken out and is washed by a large amount of water, methanol is used for repeatedly washing, and drying is carried out at room temperature, so that the lithium-oxygen battery diaphragm is obtained.
Disclosure of Invention
Based on the defect that the membrane pore diameter is difficult to control in the preparation process of the PVDF membrane, the invention aims to provide the lithium ion battery membrane, wherein the MOF@PVDF membrane is provided with a core-shell structure, the shell structure is PVDF, and the core structure is MOF material.
Further, the MOF material in the diaphragm is ZIF-67, the MOF material is uniformly coated in the PVDF, and the aperture of the diaphragm is regulated and controlled by the MOF material, so that the diaphragm with uniform aperture size and uniform distribution of holes is obtained.
The technical scheme adopted by the invention is that firstly, two raw materials of a metal organic framework ZIF-67 are respectively dissolved in an organic solvent together with polymer polyvinylidene fluoride, then two layers of tightly attached fiber membranes are prepared by an electrostatic spinning method, the metal organic framework ZIF-67 can be synthesized in solvent methanol at room temperature, then the metal organic framework ZIF-67 is soaked in a mixed organic solvent mixed with methanol, ZIF-67 is obtained at the tightly attached position of the two layers of fiber membranes, meanwhile, the mixed organic solvent is adopted to ensure that the polyvinylidene fluoride fiber membranes cannot be completely dissolved at room temperature, and finally the MOF@PVDF membrane is obtained by rolling through a roll squeezer.
The invention further aims to provide a preparation method of the lithium ion battery diaphragm, which comprises the following steps:
S1: adding cobalt nitrate hexahydrate into N, N-dimethylformamide, stirring ultrasonically, then adding PVDF (polyvinylidene fluoride), stirring under the water bath heating condition of 750-900 ℃ to prepare a solution with the concentration of 15.5-20 wt.% of polyvinylidene fluoride, transferring the solution into an electrostatic spinning injection pump, carrying out electrostatic spinning at the injection voltage of 12-16 kV, the injection distance of 12-16 cm and the injection rate of 0.25-0.4 mL/min, and obtaining the fiber membrane I on a receiving roller.
S2: adding 2-methylimidazole into N, N-dimethylformamide, stirring ultrasonically, adding PVDF (polyvinylidene fluoride), stirring at room temperature to prepare a solution of 14.6-18.2 wt.% polyvinylidene fluoride, then transferring into an injection pump, carrying out electrostatic spinning at an injection voltage of 15-19 kV, an injection distance of 14-18 cm and an injection rate of 0.3-0.45 mL/min, and covering the surface of a fiber film I on a receiving roller with a fiber film II.
S3: putting the film obtained in the step S2 in a container in a flat way, adding a mixed solvent, standing for 8-12 h, taking out the film from the mixed solvent, washing and drying with deionized water, then carrying out pressure rolling treatment for 3-5 min at the roller temperature of 45-60 ℃ by using a roller press, soaking the treated film in PVDF for 0.5-2 h, fishing out, drying for 3-5 h at the temperature of 60-70 ℃, then carrying out pressure rolling by using the roller press, and then cutting into a diaphragm with the diameter of 19mm by using a sheet punching machine.
In the step S3, the fiber film I and the fiber film II are tightly attached and then soaked in a mixed solvent, metal ions and organic ligands coordinate at the contact position of the fiber film I and the fiber film II to form metal organic frame material particles, and a small amount of fiber in the fiber film of organic solvent N, N-dimethylformamide is dissolved on the outer surfaces of the two sides to form a compact film due to the mixed solvent, and then soaked in PVDF to further form a shell structure, and then pressed and rolled by a roll squeezer to form a membrane with a core-shell structure better.
Preferably, the molar ratio of PVDF to N, N-dimethylformamide in the steps S1 and S2 is 0.12-0.36:1.
Preferably, the mixed solvent is N, N-dimethylformamide and methanol.
As a more preferable mode, the volume ratio of the N, N-dimethylformamide and the methanol in the mixed solvent is (0.55-0.7) (0.8-0.96).
Preferably, the pressure of the roll squeezer is 20-35 MPa.
Compared with the prior art, the invention has the following beneficial effects:
(1) In the invention, metal salt and organic ligand of metal organic framework material are respectively added into N, N-dimethylformamide solution of PDVF, then a double-layer fiber membrane is prepared by adopting an electrostatic spinning method, then the double-layer fiber membrane is placed in a mixed solvent of N, N-dimethylformamide and methanol, the metal salt and the organic ligand in part of the fiber membrane are dissolved and then react to generate metal organic framework, so as to form a fiber membrane of PVDF-coated MOF material, and finally the MOF@PVDF membrane is obtained by pressing through a roll squeezer.
(2) In the invention, the Co-MOF modified PVDF diaphragm has higher enhancement on wettability, simultaneously improves the problem of volume expansion, and has a uniform and rich nano-channel structure, thereby effectively regulating uniform transmission and deposition of lithium ions in the circulation process, effectively reducing the generation of electrode material polarization phenomenon and guaranteeing the high-capacity agent multiplying power performance of the battery; in the invention, the diaphragm obtained by electrostatic spinning and rolling by a roller press has denser holes with high porosity, which is beneficial to the transmission of lithium ions.
(3) In the invention, the aperture of the diaphragm is regulated by adopting a metal organic frame material ZIF-67, the aperture distribution of the fiber membrane prepared by an electrostatic spinning method is uneven, and the MOF material is obtained through soaking reaction. And then rolling the PVDF by a roll squeezer, and wrapping ZIF-67 inside the PVDF to obtain the diaphragm with uniform pore size and uniform pore distribution.
Drawings
FIG. 1 is an SEM image of a MOF@PVDF separator prepared in example 1 of the present invention.
Detailed Description
The following detailed description of the embodiments of the present invention is provided on the premise of the technical solution of the present invention, and the detailed implementation manner and specific operation process are provided, and it should be noted that, for those skilled in the art, several improvements and modifications can be made without departing from the principle of the present invention, and these improvements and modifications should also be considered as the protection scope of the present invention.
Example 1
The preparation method of the lithium ion battery diaphragm specifically comprises the following steps:
S1: cobalt nitrate hexahydrate is added into N, N-dimethylformamide, ultrasonic stirring is carried out, PVDF (polyvinylidene fluoride) is then added, a solution of PVDF of 15.5wt.% is stirred at room temperature, the solution is transferred into an electrostatic spinning injection pump, electrostatic spinning is carried out at an injection voltage of 12kV and an injection distance of 12cm and an injection rate of 0.25mL/min, and a fibrous membrane I is obtained on a receiving roller.
S2: adding 2-methylimidazole into N, N-dimethylformamide, stirring with ultrasound, adding PVDF (polyvinylidene fluoride), stirring at room temperature to obtain a solution with PVDF content of 14.6wt.%, transferring into an injection pump, electrostatic spinning at an injection voltage of 15kV and an injection distance of 14cm and an injection rate of 0.3mL/min, and covering the surface of the fibrous membrane I on a receiving roller with a fibrous membrane II.
S3: the film obtained in the step S2 is flatly laid in a container, then a mixed solvent of N, N-dimethylformamide and methanol with the volume ratio of 0.55:0.8 is added, the film is taken out from the mixed solvent after standing for 8 hours, the film is soaked in PVDF for 0.5 hours, dried for 3 hours at 60 ℃ after being fished out, then the film is pressed and rolled by a roller press, and then a punching machine is used for cutting into a diaphragm with the diameter of 19 mm.
Example 2
The preparation method of the lithium ion battery diaphragm specifically comprises the following steps:
S1: cobalt nitrate hexahydrate is added into N, N-dimethylformamide, ultrasonic stirring is carried out, PVDF (polyvinylidene fluoride) is then added, a solution of 20wt.% PVDF is prepared by stirring at room temperature, the solution is transferred into an electrostatic spinning injection pump, electrostatic spinning is carried out at an injection voltage of 16kV and an injection distance of 16cm and an injection rate of 0.4mL/min, and a fibrous membrane I is obtained on a receiving roller.
S2: adding 2-methylimidazole into N, N-dimethylformamide, stirring with ultrasound, adding PVDF (polyvinylidene fluoride), stirring at room temperature to obtain a solution with PVDF content of 18.2wt.%, transferring into an injection pump, electrostatic spinning at an injection voltage of 19kV and an injection distance of 18cm and an injection rate of 0.45mL/min, and covering the surface of the fibrous membrane I on a receiving roller with a fibrous membrane II.
S3: the film obtained in the step S2 is flatly laid in a container, then a mixed solvent of N, N-dimethylformamide and methanol with the volume ratio of 0.7:0.96 is added, the film is taken out from the mixed solvent after standing for 12 hours, the film is soaked in PVDF for 2 hours, dried for 5 hours at 70 ℃ after being fished out, then the film is pressed and rolled by a roller press, and then a punching machine is used for cutting into a diaphragm with the diameter of 19 mm.
Example 3
The preparation method of the lithium ion battery diaphragm specifically comprises the following steps:
s1: cobalt nitrate hexahydrate is added into N, N-dimethylformamide, ultrasonic stirring is carried out, PVDF (polyvinylidene fluoride) is then added, a solution of which PVDF is 16wt.% is stirred at room temperature, the solution is transferred into an electrostatic spinning injection pump, electrostatic spinning is carried out at an injection voltage of 13kV and an injection distance of 14cm and an injection rate of 0.3mL/min, and a fibrous membrane I is obtained on a receiving roller.
S2: adding 2-methylimidazole into N, N-dimethylformamide, stirring with ultrasound, adding PVDF (polyvinylidene fluoride), stirring at room temperature to obtain a solution with PVDF content of 15.4wt.%, transferring into an injection pump, electrostatic spinning at an injection voltage of 17kV and an injection distance of 15cm and an injection rate of 0.35mL/min, and covering the surface of the fibrous membrane I on a receiving roller with a fibrous membrane II.
S3: the film obtained in the step S2 is flatly laid in a container, then a mixed solvent of N, N-dimethylformamide and methanol with the volume ratio of 0.6:0.86 is added, the film is taken out from the mixed solvent after standing for 10 hours, the film is soaked in PVDF for 1 hour, dried for 4 hours at 65 ℃ after being fished out, then the film is pressed and rolled by a roller press, and then a punching machine is used for cutting into a diaphragm with the diameter of 19 mm.
Example 4
The preparation method of the lithium ion battery diaphragm specifically comprises the following steps:
s1: cobalt nitrate hexahydrate is added into N, N-dimethylformamide, ultrasonic stirring is carried out, PVDF (polyvinylidene fluoride) is then added, a solution of 18wt.% PVDF is prepared by stirring at room temperature, the solution is transferred into an electrostatic spinning injection pump, electrostatic spinning is carried out at an injection voltage of 15kV and an injection distance of 15.5cm and an injection rate of 0.35mL/min, and a fibrous membrane I is obtained on a receiving roller.
S2: adding 2-methylimidazole into N, N-dimethylformamide, stirring with ultrasound, adding PVDF (polyvinylidene fluoride), stirring at room temperature to obtain a solution with PVDF content of 16.8wt.%, transferring into an injection pump, electrostatic spinning at an injection voltage of 18kV and an injection distance of 17cm and an injection rate of 0.4mL/min, and covering the surface of the fibrous membrane I on a receiving roller with a fibrous membrane II.
S3: the film obtained in the step S2 is flatly laid in a container, then a mixed solvent of N, N-dimethylformamide and methanol with the volume ratio of 0.64:0.92 is added, the film is taken out from the mixed solvent after standing for 11 hours, the film is soaked in PVDF for 1.5 hours, dried for 4 hours at 70 ℃ after being fished out, then the film is pressed and rolled by a roller press, and then a punching machine is used for cutting into a diaphragm with the diameter of 19 mm.
Experimental example: the separator materials prepared in examples 1 to 4 were each subjected to the following performance test.
Performance test: the thermal stability performance test adopts a thermal weightlessness method, and the thermal shrinkage rate of the diaphragm is tested at a heating rate of 5 ℃/min in a nitrogen atmosphere;
The mechanical properties are tested by a tensile testing machine, and the tensile is carried out at a strain rate of 1 mm/min; the liquid absorption test uses a diaphragm placed in an electrolyte (1M LiPF 6 dissolved in EC/DMC/emc=1:1:1), the mass of the diaphragm is weighed after absorption saturation, and the liquid absorption is calculated by the following formula:
Wherein EU is the liquid absorption, W 0 and W are the weights of the separator before and after soaking in the electrolyte;
Conductivity was measured using an electrochemical workstation with a frequency range of 100mHz to 100kHz, calculated by the following equation:
wherein σ is ion conductivity, d is thickness of the separator, R is bulk resistance, and A is electrode area;
Porosity was measured using a surface area tester, and the porosity was measured by immersing n-butanol therein, calculated using the following formula:
Where ρ is the n-butanol density, W 2 is the membrane mass after absorption of n-butanol, W 1 is the dry membrane mass, all of the above test results are reported in Table 1,
Table 1. Results of performance test:
as can be seen from Table 1, the MOF@PVDF diaphragms prepared in examples 1 to 4 of the invention have the advantages of thermal stability at about 180 ℃, mechanical strength at about 32MPa, liquid absorption rate as high as 301wt.%, porosity as high as 80%, and conductivity at 1.22mS/cm, which indicates that the MOF@PVDF diaphragm of the invention has better thermal stability and mechanical strength and higher conductive property.
In order to evaluate the electrochemical performance of the mof@pvdf separator, the mof@pvdf separator assembled batteries prepared in examples 1 to 4 were evaluated for electrochemical performance, in which lithium iron phosphate was used as a positive electrode and a lithium sheet was used as a negative electrode, and an electrolyte known in the art was used as an electrolyte, a current density of 5C was measured, a specific capacity thereof was measured, and the results are shown in table 2,
Table 2. Electrochemical performance test results:
As can be seen from Table 2, the MOF@PVDF separators prepared in examples 1 to 4 have a specific discharge capacity of 118.1mAh/g or more at a current density of 5C for the first time, and after 400 cycles, the specific discharge capacities are still about 110.1mAh/g, which indicates that the MOF@PVDF separator provided by the invention has excellent cycle stability.
Claims (6)
1. A lithium ion battery diaphragm is characterized in that a MOF material in the diaphragm is ZIF-67, the MOF material is uniformly coated inside PVDF, and the aperture of the diaphragm is regulated and controlled by the MOF material to obtain the diaphragm with uniform aperture size and uniform distribution of holes.
2. The preparation method of the lithium ion battery diaphragm as claimed in claim 1, which is characterized by comprising the following steps:
S1: adding cobalt nitrate hexahydrate into N, N-dimethylformamide, stirring ultrasonically, then adding PVDF (polyvinylidene fluoride), stirring under the water bath heating condition of 750-900 ℃ to prepare a solution with the concentration of 15.5-20 wt.% of polyvinylidene fluoride, transferring the solution into an electrostatic spinning injection pump, carrying out electrostatic spinning at the injection voltage of 12-16 kV, the injection distance of 12-16 cm and the injection rate of 0.25-0.4 mL/min, and obtaining a fibrous membrane I on a receiving roller;
S2: adding 2-methylimidazole into N, N-dimethylformamide, stirring ultrasonically, then adding PVDF (polyvinylidene fluoride), stirring at room temperature to prepare a solution of 14.6-18.2 wt.% polyvinylidene fluoride, then moving into an injection pump, carrying out electrostatic spinning at an injection voltage of 15-19 kV, an injection distance of 14-18 cm and an injection rate of 0.3-0.45 mL/min, and covering a fiber film II on the surface of a fiber film I on a receiving roller;
S3: putting the film obtained in the step S2 in a container in a flat way, adding a mixed solvent, standing for 8-12 h, taking out the film from the mixed solvent, washing and drying with deionized water, then carrying out pressure rolling treatment for 3-5 min at the roller temperature of 45-60 ℃ by using a roller press, soaking the treated film in PVDF for 0.5-2 h, fishing out, drying for 3-5 h at the temperature of 60-70 ℃, then carrying out pressure rolling by using the roller press, and then cutting into a diaphragm with the diameter of 19mm by using a sheet punching machine.
3. The method for preparing a lithium ion battery separator according to claim 2, wherein in the steps S1 and S2, the molar ratio of PVDF to N, N-dimethylformamide is 0.12-0.36:1.
4. The method for preparing a lithium ion battery separator according to claim 3, wherein the mixed solvent is N, N-dimethylformamide and methanol.
5. The method for preparing the lithium ion battery diaphragm according to claim 5, wherein the volume ratio of N, N-dimethylformamide to methanol in the mixed solvent is (0.55-0.7) (0.8-0.96).
6. The method for preparing the lithium ion battery diaphragm according to claim 3, wherein the pressure of the roll squeezer is 20-35 MPa.
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| CN113991244A (en) * | 2021-10-25 | 2022-01-28 | 上海高昇新材料有限公司 | Preparation method of polyvinylidene fluoride membrane material with uniform pore diameter |
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| CN113991244A (en) * | 2021-10-25 | 2022-01-28 | 上海高昇新材料有限公司 | Preparation method of polyvinylidene fluoride membrane material with uniform pore diameter |
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