CN117963223A - Blister packaging machine for preparing polypropylene blister web and use method thereof - Google Patents
Blister packaging machine for preparing polypropylene blister web and use method thereof Download PDFInfo
- Publication number
- CN117963223A CN117963223A CN202410259074.0A CN202410259074A CN117963223A CN 117963223 A CN117963223 A CN 117963223A CN 202410259074 A CN202410259074 A CN 202410259074A CN 117963223 A CN117963223 A CN 117963223A
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- Prior art keywords
- polypropylene
- heat sealing
- film
- blister
- packaging machine
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 94
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 94
- -1 polypropylene Polymers 0.000 title claims abstract description 83
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000007789 sealing Methods 0.000 claims abstract description 84
- 238000010438 heat treatment Methods 0.000 claims abstract description 26
- 239000010408 film Substances 0.000 claims description 130
- 239000013039 cover film Substances 0.000 claims description 38
- 239000006260 foam Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010030 laminating Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 10
- 238000009776 industrial production Methods 0.000 abstract description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 239000005033 polyvinylidene chloride Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 229940079593 drug Drugs 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B11/00—Wrapping, e.g. partially or wholly enclosing, articles or quantities of material, in strips, sheets or blanks, of flexible material
- B65B11/50—Enclosing articles, or quantities of material, by disposing contents between two sheets, e.g. pocketed sheets, and securing their opposed free margins
- B65B11/52—Enclosing articles, or quantities of material, by disposing contents between two sheets, e.g. pocketed sheets, and securing their opposed free margins one sheet being rendered plastic, e.g. by heating, and forced by fluid pressure, e.g. vacuum, into engagement with the other sheet and contents, e.g. skin-, blister-, or bubble- packaging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B47/00—Apparatus or devices for forming pockets or receptacles in or from sheets, blanks, or webs, comprising essentially a die into which the material is pressed or a folding die through which the material is moved
- B65B47/02—Apparatus or devices for forming pockets or receptacles in or from sheets, blanks, or webs, comprising essentially a die into which the material is pressed or a folding die through which the material is moved with means for heating the material prior to forming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B47/00—Apparatus or devices for forming pockets or receptacles in or from sheets, blanks, or webs, comprising essentially a die into which the material is pressed or a folding die through which the material is moved
- B65B47/04—Apparatus or devices for forming pockets or receptacles in or from sheets, blanks, or webs, comprising essentially a die into which the material is pressed or a folding die through which the material is moved by application of mechanical pressure
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Containers And Plastic Fillers For Packaging (AREA)
Abstract
The invention discloses a blister packaging machine based on a polypropylene blister web and a use method thereof, and the blister packaging machine comprises a frame, wherein a bottom film heating die, a bottom film forming die and a heat sealing device are sequentially arranged at the top end of the frame from left to right, the right side of the bottom film heating die is attached to the left side of the bottom film forming die, a track is arranged between the bottom film forming die and the heat sealing device, and a forming film preheating device is detachably arranged at the top of the track. The device and the application method thereof provided by the invention can meet the temperature requirements of the polypropylene material on forming and heat sealing, improve the forming and heat sealing effects of the polypropylene blister web, and are well applied to the industrial production of the polypropylene blister web.
Description
Technical Field
The invention relates to the technical field of medicine packaging, in particular to a blister packaging machine for preparing a polypropylene blister web and a using method thereof.
Background
The blister packaging machine is a production equipment widely used in the industries of medicine, food and the like, and when in packaging, a transparent plastic film or sheet is used for forming a blister, and products are sealed between the blister and a base plate by heat sealing or bonding and the like, so that capsules or tablet medicines with various specifications are packaged.
In pharmaceutical production, when a blister packaging machine is used for packaging products, common molding base film materials are polyvinyl chloride (Polyvinyl chloride, hereinafter referred to as "PVC") and polyvinylidene chloride (Polyvinylidene chloride, hereinafter referred to as "PVDC"), however, the two materials, namely the PVC and the PVDC, have strong pollution, can cause environmental pollution, and can also cause harm to human bodies. Accordingly, pharmaceutical enterprises are seeking new alternatives. Polypropylene (PP) is a powerful candidate, and PP materials are easy to recycle and do not release toxins when incinerated. In addition, if the sealing cover film is made of PP material, the performance of the sealing cover film is equivalent to that of an aluminum foil sealing layer, and the sealing cover film can be easily uncovered like a common aluminum foil so as to be convenient for a user to take out medicines. However, there are still difficulties in the prior art with respect to the processing of PP materials for use in blister packaging.
The difficulties are mainly focused on the following aspects: (1) The hot expansion and cold contraction of the PP material are obvious, and the molding difficulty is high; (2) The PP material can be molded only in a very narrow temperature range, and has high requirements on temperature control; (3) The molding temperature of the PP material is higher, and the heat is more required; (4) The PP film absorbs heat at a relatively slow rate, and the heat sealing effect is often poor when using a conventional blister machine for heat sealing. Based on the above difficulties, it is difficult to meet the requirements of the formability and heat sealability of PP materials using a common blister machine suitable for PVC/PVDC.
Therefore, there is a need in the art for a blister packaging machine for producing a polypropylene blister web and a method of using the same that can accommodate the temperature requirements of the polypropylene material for forming and heat sealing, promote the forming and heat sealing effects of the polypropylene blister web, and be well applied to the industrial production of the polypropylene blister web.
Disclosure of Invention
In order to solve the technical problems, the invention provides a blister packaging machine for preparing a polypropylene blister web, which comprises a frame, wherein a bottom film heating die, a bottom film forming die and a heat sealing device are sequentially arranged at the top end of the frame from left to right, the right side of the bottom film heating die is attached to the left side of the bottom film forming die, a track is arranged between the bottom film forming die and the heat sealing device, and a forming film preheating device is detachably arranged at the top of the track.
Specifically, the forming film preheating device comprises a cover film preheating plate and a bottom film preheating plate, wherein the bottom film preheating plate is detachably arranged at the top of the track, the cover film preheating plate and the bottom film preheating plate are mutually perpendicular, and the cover film preheating plate is detachably arranged at the left side of the heat sealing device.
Specifically, one side of the base film preheating plate is provided with a handle, the other side of the base film preheating plate is detachably fixed on the track through a screw and a hinge, and the base film preheating plate can turn over along the side of the track by taking the rotating shaft of the hinge as a central shaft.
Specifically, the bottom film preheating plate is arranged on one side of the top of the track, which is close to the heat sealing device.
Specifically, the top of heat sealing device is provided with the heat seal and goes up the mould, the bottom of heat sealing device is provided with the heat seal lower mould, the surface of heat seal goes up mould and heat seal lower mould all is provided with punctiform boss, and the tapering of every punctiform boss is 45 degrees, and the surface size of every punctiform boss is 0.3mm x 0.3mm.
A second aspect of the present invention provides a method of using a blister packaging machine for producing a polypropylene blister web, the method of using a blister packaging machine for producing a polypropylene blister web as described previously for producing a polypropylene blister web, the method of using comprising the steps of:
(1) After starting up, putting a polypropylene base film and a polypropylene cover film, setting technological parameters, and starting blister packaging;
(2) Closing the cooling function of the bottom film forming die, so that the residual temperature of the bottom film heating die is conducted to the bottom film forming die, and the polypropylene bottom film sequentially passes through the bottom film heating die and the bottom film forming die to form a plurality of consistent and full foam holes on the polypropylene bottom film;
(3) The polypropylene base film and the polypropylene cover film enter a forming film preheating device, and a cover film preheating plate and a base film preheating plate of the forming film preheating device respectively preheat the polypropylene base film and the polypropylene cover film, and are sent to a heat sealing device after preheating is finished;
(4) The heat sealing device heat-seals the preheated polypropylene base film and the polypropylene cover film to finish the blister package.
Specifically, the process parameters are as follows:
The heating temperature of the bottom film forming die is 120-130 ℃, the temperature of the cover film preheating plate is 85-100 ℃, the temperature of the bottom film preheating plate is 85-120 ℃, the heat sealing temperature of the heat sealing device is 140-155 ℃, the heat sealing compressed air pressure is 4.5-6.8bar, and the heat sealing residence time is 0.3-0.8s.
Specifically, the process parameters are as follows:
The heating temperature of the bottom film forming die is 120-130 ℃, the temperature of the cover film preheating plate is 90-100 ℃, the temperature of the bottom film preheating plate is 100-110 ℃, the heat sealing temperature of the heat sealing device is 140-148 ℃, the heat sealing compressed air pressure is 6.8bar, and the heat sealing residence time is 0.5s.
Specifically, the thickness of the polypropylene base film is 300-400 mu m, and the thickness of the polypropylene cover film is 90-100 mu m.
Specifically, the thickness of the polypropylene base film was 300 μm, and the thickness of the polypropylene cap film was 90 μm.
The technical scheme provided by the invention at least comprises the following beneficial effects:
1. According to the blister packaging machine for preparing the polypropylene blister web, no interval exists between the base film heating die and the base film forming die, and when the blister packaging machine is heated, the residual temperature of the base film heating die can be conducted to the base film forming die, so that the phenomenon that the polypropylene base film is shrunk cold before forming a blister is avoided.
2. According to the blister packaging machine for preparing the polypropylene blister web, the forming film preheating device is arranged, and before the polypropylene base film and the polypropylene cover film enter the heat sealing device, the polypropylene base film and the polypropylene cover film are preheated, so that the heat sealing effect of the polypropylene blister web is improved.
3. According to the blister packaging machine for preparing the polypropylene blister web, provided by the invention, through the arrangement of the heat-sealing upper film, the sharpness of the dot-shaped boss is improved, the area of the dot-shaped heat-sealing area on the blister web is enlarged, and the heated and melted polymers among the dots are connected, so that a leakage channel can be eliminated, and the heat-sealing effect of the polypropylene blister web is further improved.
4. The using method of the blister packaging machine provided by the invention is simple and convenient to operate, the process is perfect, and on the basis of combining the blister packaging machine provided by the invention, the inventor explores and optimizes the optimal process parameters, so that the feasibility of blister packaging of the polypropylene material is further improved.
Drawings
FIG. 1 is a schematic view showing the overall structure of a blister pack machine for producing a polypropylene blister web according to the present invention
Fig. 2 is a schematic view of the structure of the dot-shaped boss of the heat-seal upper die of the present invention.
Reference numerals illustrate:
1. a frame; 2. heating the die by the bottom film; 3. a bottom film forming die; 4. a forming film preheating device; 5. covering a film preheating plate; 6. a base film preheating plate; 7. a heat sealing device; 8. a track; 9. a dot-shaped boss.
Detailed Description
The following description of the present invention will be made clearly and fully, and it is apparent that the embodiments described are some, but not all, of the embodiments of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention. Materials, instruments, reagents and the like used in the following examples are commercially available unless otherwise specified. The technical means used in the examples, unless otherwise specified, are conventional means well known to those skilled in the art.
The structures, proportions, sizes, etc. shown in the drawings herein are shown in detail, and should not be construed as limiting the scope of the invention, since it is intended that all changes in structure, proportion, or adjustment of size be included in the scope of the invention without affecting the efficiency or achievement thereof, and terms such as "upper", "lower", "left", "right", "middle", and "one" are used for descriptive purposes only and are not intended to limit the scope of the invention.
Example 1
Referring to fig. 1-2, there is shown a blister packaging machine for preparing a polypropylene blister web according to an exemplary embodiment of the present application, which includes a frame 1, a base film heating mold 2, a base film forming mold 3 and a heat sealing device 7 are sequentially disposed at a top end of the frame 1 from left to right, a right side of the base film heating mold 2 is attached to a left side of the base film forming mold 3, a track 8 is disposed between the base film forming mold 3 and the heat sealing device 7, and a forming film preheating device is detachably mounted at a top of the track 8. There is no interval between the bottom film heating mold 2 and the bottom film forming mold 3, and when heating, the residual temperature of the bottom film heating mold 2 is conducted to the bottom film forming mold 3, so that the phenomenon that the polypropylene bottom film is cold shrunk before forming the foam is avoided, and the foam with consistent, uniform and full shape is produced, so that excellent forming effect is realized.
The forming film preheating device 4 comprises a cover film preheating plate 5 and a bottom film preheating plate 6, wherein the bottom film preheating plate 6 is detachably arranged at the top of the track 8, the cover film preheating plate 5 and the bottom film preheating plate 6 are mutually perpendicular, and the cover film preheating plate 5 is detachably arranged at the left side of the heat sealing device 7.
One side of the bottom film preheating plate 6 is provided with a handle, the other side of the bottom film preheating plate 6 is detachably fixed on the track 8 through a screw and a hinge, the bottom film preheating plate 6 can be turned over along the side edge of the track 8 by taking a rotating shaft of the hinge as a central shaft, and the detachable arrangement can be used for manually opening or disassembling the forming film preheating device when the equipment is stopped, so that the influence of the bottom film preheating plate 6 on the bottom film and medicines during long-time stopping is avoided.
The bottom film preheating plate 6 is arranged on one side of the top of the track 8, which is close to the heat sealing device 7, so that the bottom film preheating plate can enter the heat sealing device 7 immediately after being preheated, and the preheating effect can be utilized in the heat sealing process to the maximum extent.
The top of the heat sealing device 7 is provided with a heat sealing upper die, the bottom of the heat sealing device 7 is provided with a heat sealing lower die, the surfaces of the heat sealing upper die and the heat sealing lower die are respectively provided with a corresponding point-shaped boss 9, the taper of each point-shaped boss 9 is 45 degrees by polishing the point-shaped bosses 9, and the surface size of each point-shaped boss 9 is 0.3mm multiplied by 0.3mm. Referring to fig. 2, the upper two rows of the drawing show the connection condition of the polymer in the heat sealing process of the unground heat sealing upper die, and the lower two rows show the connection condition of the polymer in the heat sealing process of the dot-shaped boss 9 provided by the invention, and it can be seen that the dot-shaped boss 9 provided by the invention enlarges the area of the heat sealing area, and in the heat sealing process, the polymer residues between the dots are connected, so that a leakage channel is eliminated, and the heat sealing effect can be ensured and improved through a side leakage experiment.
A second aspect of the present invention provides a method of using a blister packaging machine for producing a polypropylene blister web, the method of using a blister packaging machine for producing a polypropylene blister web as described above, the method of using comprising the steps of:
(1) After starting up, putting a polypropylene base film and a polypropylene cover film, setting technological parameters, and starting blister packaging;
(2) Closing the cooling function of the bottom film forming die 3, so that the residual temperature of the bottom film heating die 2 is conducted to the bottom film forming die 3, and the polypropylene bottom film sequentially passes through the bottom film heating die 2 and the bottom film forming die 3 to form a plurality of consistent and full foam holes on the polypropylene bottom film;
(3) The polypropylene base film and the polypropylene cover film enter a forming film preheating device 4, and a cover film preheating plate 5 and a base film preheating plate 6 of the forming film preheating device 4 respectively preheat the polypropylene base film and the polypropylene cover film, and are sent to a heat sealing device 7 after preheating;
(4) The heat-sealing device 7 heat-seals the preheated polypropylene base film and the polypropylene cover film to complete the blister package.
This example examined the heat sealing effect of a 90 μm PP cap film of Etimex 400 μm in germany in combination with a PP base film of 300 μm in Sumitomo japan, the process parameters were as follows:
The heating temperature of the bottom film forming die 3 is 120-130 ℃, the temperature of the cover film preheating plate 5 is 85-100 ℃, the temperature of the bottom film preheating plate 6 is 85-120 ℃, the heat sealing temperature of the heat sealing device 7 is 140-155 ℃, the heat sealing compressed air pressure is 4.5-6.8bar, and the heat sealing residence time is 0.3-0.8s.
The skilled person, through continuous screening, determined that the better effect was to use a base film of 300 μm in Sumitomo japan and a PP cap film of 90 μm in Etimex germany, the process parameters were as follows:
The heating temperature of the bottom film forming die 3 is 120-130 ℃, the temperature of the cover film preheating plate 5 is 90-100 ℃, the temperature of the bottom film preheating plate 6 is 100-110 ℃, the heat sealing temperature of the heat sealing device 7 is 140-148 ℃, the heat sealing compressed air pressure is 6.8bar, and the heat sealing residence time is 0.5s.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather to enable any modification, equivalent replacement, improvement or the like to be made within the spirit and principles of the invention.
Claims (10)
1. The utility model provides a blister packaging machine for preparing polypropylene bubble cap web, its characterized in that, includes the frame, bottom film heating mould, bottom film forming die and heat sealing device have set gradually from a left side to the right side on the top of frame, the right side of bottom film heating mould and the laminating of bottom film forming die's left side, be provided with the track between bottom film forming die and the heat sealing device, orbital top detachably installs shaping film preheating device.
2. The blister packaging machine for producing polypropylene blister webs according to claim 1, wherein the forming film preheating means comprises a cover film preheating plate and a base film preheating plate, the base film preheating plate being detachably mounted on the top of the rail, the cover film preheating plate being perpendicular to the base film preheating plate, the cover film preheating plate being detachably mounted on the left side of the heat sealing means.
3. The blister packaging machine for preparing polypropylene blister webs according to claim 2, wherein a handle is provided on one side of the base film preheating plate, the other side of the base film preheating plate is detachably fixed to a rail by screws and hinges, and the base film preheating plate can be turned around a rotation axis of the hinges as a center axis along a side of the rail.
4. Blister packaging machine for the preparation of polypropylene blister webs according to claim 2, characterized in that the carrier film preheating plate is arranged on the side of the rail top close to the heat sealing means.
5. The blister packaging machine for preparing polypropylene blister webs according to claim 1, wherein the top of the heat sealing device is provided with an upper heat sealing die, the bottom of the heat sealing device is provided with a lower heat sealing die, the surfaces of the upper heat sealing die and the lower heat sealing die are provided with dot-shaped bosses, the taper of each dot-shaped boss is 45 degrees, and the surface size of each dot-shaped boss is 0.3mm x 0.3mm.
6. A method of use of a blister packaging machine for producing a polypropylene blister web, characterized in that the method of use of a blister packaging machine for producing a polypropylene blister web is based on a blister packaging machine for producing a polypropylene blister web according to any one of claims 1-5, the method of use comprising the steps of:
(1) After starting up, putting a polypropylene base film and a polypropylene cover film, setting technological parameters, and starting blister packaging;
(2) Closing the cooling function of the bottom film forming die, so that the residual temperature of the bottom film heating die is conducted to the bottom film forming die, and the polypropylene bottom film sequentially passes through the bottom film heating die and the bottom film forming die to form a plurality of consistent and full foam holes on the polypropylene bottom film;
(3) The polypropylene base film and the polypropylene cover film enter a forming film preheating device, and a cover film preheating plate and a base film preheating plate of the forming film preheating device respectively preheat the polypropylene base film and the polypropylene cover film, and are sent to a heat sealing device after preheating is finished;
(4) The heat sealing device heat-seals the preheated polypropylene base film and the polypropylene cover film to finish the blister package.
7. The method of using a blister packaging machine for preparing polypropylene blister webs according to claim 6, wherein the process parameters are as follows:
The heating temperature of the bottom film forming die is 120-130 ℃, the temperature of the cover film preheating plate is 85-100 ℃, the temperature of the bottom film preheating plate is 85-120 ℃, the heat sealing temperature of the heat sealing device is 140-155 ℃, the heat sealing compressed air pressure is 4.5-6.8bar, and the heat sealing residence time is 0.3-0.8s.
8. The method of using a blister packaging machine for preparing polypropylene blister webs according to claim 6, wherein the process parameters are as follows:
The heating temperature of the bottom film forming die is 120-130 ℃, the temperature of the cover film preheating plate is 90-100 ℃, the temperature of the bottom film preheating plate is 100-110 ℃, the heat sealing temperature of the heat sealing device is 140-148 ℃, the heat sealing compressed air pressure is 6.8bar, and the heat sealing residence time is 0.5s.
9. The method of using a blister packaging machine for preparing polypropylene blister webs according to claim 6 wherein the polypropylene base film has a thickness of 300-400 μm and the polypropylene cover film has a thickness of 90-100 μm.
10. The method of using a blister packaging machine for preparing polypropylene blister webs according to claim 6 wherein the polypropylene base film has a thickness of 300 μm and the polypropylene cover film has a thickness of 90 μm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202410259074.0A CN117963223A (en) | 2024-03-07 | 2024-03-07 | Blister packaging machine for preparing polypropylene blister web and use method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN202410259074.0A CN117963223A (en) | 2024-03-07 | 2024-03-07 | Blister packaging machine for preparing polypropylene blister web and use method thereof |
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CN117963223A true CN117963223A (en) | 2024-05-03 |
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Application Number | Title | Priority Date | Filing Date |
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CN202410259074.0A Pending CN117963223A (en) | 2024-03-07 | 2024-03-07 | Blister packaging machine for preparing polypropylene blister web and use method thereof |
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CN (1) | CN117963223A (en) |
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- 2024-03-07 CN CN202410259074.0A patent/CN117963223A/en active Pending
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