CN117960773A - A method for remediation and loss prevention of heavy metal soil on slopes in karst areas - Google Patents

A method for remediation and loss prevention of heavy metal soil on slopes in karst areas Download PDF

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CN117960773A
CN117960773A CN202410038216.0A CN202410038216A CN117960773A CN 117960773 A CN117960773 A CN 117960773A CN 202410038216 A CN202410038216 A CN 202410038216A CN 117960773 A CN117960773 A CN 117960773A
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soil
heavy metal
slope
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steep slope
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周忠发
李丹丹
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Guizhou Education University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically

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Abstract

The invention discloses a method for restoring and preventing and controlling loss of heavy metal soil on a slope surface of a karst area, which relates to the field of soil management and control restoration and specifically comprises the following steps: s1, cleaning polluted waste residues on a steep slope, and sampling and detecting on-site polluted soil; s2, deep excavation is carried out according to the depth result of the heavy metal soil detection; s3, then throwing the deeply excavated polluted soil into soil restoration equipment; s4, constructing a barrier layer at the bottom of the deep digging area; s5, backfilling, solidifying and repairing the soil above the barrier layer; s6, finally, performing surface soil conservation measures on the backfilled solidified and repaired soil; according to the method for restoring and preventing and controlling the heavy metal soil on the slope of the karst area, soil moisture regulation and control and water and soil conservation can be performed through the measures of soil conservation on the surface layer, so that the excessive water flow speed caused by heavy rain or surface water in the later period can be slowed down, and the excessive speed can be realized; while the surface water flow can be collected and directed.

Description

一种用于岩溶区坡面重金属土壤修复及流失防控方法A method for remediation and loss prevention of heavy metal soil on slopes in karst areas

周忠发,李丹丹Zhou Zhongfa, Li Dandan

贵州师范大学喀斯特研究院Karst Research Institute of Guizhou Normal University

技术领域Technical Field

本发明涉及土壤修复防控技术,具体涉及一种用于岩溶区坡面重金属土壤修复及流失防控方法。The present invention relates to soil restoration and control technology, and in particular to a method for restoration and loss control of heavy metal soil on slopes in karst areas.

背景技术Background technique

岩溶区在碳酸盐岩风化成土过程中重金属元素的次生富集,使得形成的土壤具有显著的重金属高含量特征。且该区域铅锌矿产资源丰富,其开采冶炼过程引起重金属污染,加之重金属高背景特征,致使区域环境重金属地球化学异常。在喀斯特地区特殊的地质背景下,极易在雨水冲刷作用下,重金属元素随着土壤流失迁移扩散,加剧土壤重金属污染。因此,构建土壤重金属修复方法及防控重金属元素随土壤流失迁移变化已成为热点。The secondary enrichment of heavy metal elements in the process of carbonate rock weathering and soil formation in the karst area makes the formed soil have a significant high content of heavy metals. In addition, the region is rich in lead and zinc mineral resources, and its mining and smelting process causes heavy metal pollution. Coupled with the high background characteristics of heavy metals, the regional environmental heavy metal geochemistry is abnormal. Under the special geological background of the karst area, heavy metal elements are easily migrated and diffused with soil loss under the action of rainwater erosion, aggravating soil heavy metal pollution. Therefore, the construction of soil heavy metal remediation methods and the prevention and control of heavy metal elements migration and changes with soil loss have become hot topics.

目前,关于重金属污染土壤修复法分为:物理修复法、化学修复法和生物修复法。物理修复法包括客土、换土、电动修复、热处理法和玻璃化法等;化学修复法包括土壤淋洗法、固化与稳定化等;生物修复法包括微生物修复、植物修复、微生物辅助修复等。单一的土修复方法效果差,重金属元素随着土壤流失迁移扩散,易造成二次污染。因此,物理修复+化学修复+生物修复是固定去除土壤中重金属的必要措施。同时,结合土壤流失耕作及工程防治措施,从而实现重金属土壤修复,且有效防控重金属土壤流失问题。At present, the methods for remediating heavy metal contaminated soil are divided into: physical remediation, chemical remediation and biological remediation. Physical remediation methods include soil import, soil replacement, electric remediation, heat treatment and vitrification; chemical remediation methods include soil leaching, solidification and stabilization; biological remediation methods include microbial remediation, plant remediation, microbial assisted remediation. The effect of a single soil remediation method is poor, and heavy metal elements migrate and diffuse with soil loss, which can easily cause secondary pollution. Therefore, physical remediation + chemical remediation + biological remediation are necessary measures to fix and remove heavy metals in the soil. At the same time, combined with soil loss cultivation and engineering prevention and control measures, heavy metal soil remediation can be achieved, and the problem of heavy metal soil loss can be effectively prevented and controlled.

发明内容Summary of the invention

本发明的目的是提供一种用于岩溶区坡面重金属土壤修复及流失防控方法,以解决现有技术中的上述不足之处。The purpose of the present invention is to provide a method for repairing and preventing heavy metal soil loss on slopes in karst areas to solve the above-mentioned deficiencies in the prior art.

为了实现上述目的,本发明提供如下技术方案:一种用于岩溶区坡面重金属土壤修复及流失防控方法,具体包括以下步骤:In order to achieve the above-mentioned object, the present invention provides the following technical solution: a method for remediation and loss prevention of heavy metal soil on slopes in karst areas, specifically comprising the following steps:

S1、土壤重金属含量测定:首先,开挖前,对岩溶区坡面污染土壤周边环境进行清理,平整场地;其次,对污染土壤进行取样检测;S1. Determination of heavy metal content in soil: First, before excavation, the surrounding environment of the contaminated soil on the slope of the karst area is cleaned and the site is leveled; second, the contaminated soil is sampled and tested;

取样检测完毕后,将石灰粉铺撒在污染土壤上,静置5~10天,以对污染土壤进行中和处理;After sampling and testing, spread lime powder on the contaminated soil and leave it for 5 to 10 days to neutralize the contaminated soil;

S2、深挖土壤:中和处理完毕后,依据检测重金属土壤的深度结果进行深挖土壤;S2. Deep soil excavation: After the neutralization treatment is completed, deep soil excavation is carried out according to the depth results of the heavy metal soil detection;

S3、固化修复重金属土壤:接着将深挖的污染土壤投入土壤修复设备进行剔除石块、粉碎土壤,并对其进行药剂喷淋,已完成对土壤重金属含量的固化处理;S3. Solidification and remediation of heavy metal soil: The excavated contaminated soil is then put into soil remediation equipment to remove stones, crush the soil, and spray it with chemicals to complete the solidification of the heavy metal content in the soil;

S4、构建阻隔层:再在深挖区底部布设10~30cm厚的混合材料构成的阻隔层;S4. Constructing a barrier layer: laying a barrier layer of mixed materials with a thickness of 10 to 30 cm at the bottom of the deep excavation area;

S5、回填土壤:阻隔层填铺完毕后,接着在阻隔层上方回填固化修复后的土壤;S5. Backfill soil: After the barrier layer is filled, the solidified and repaired soil is backfilled on top of the barrier layer;

S6、防控修复表土壤:最后,在回填的土壤表层布设横坡节流沟与纵坡垄沟等保土工程措施;S6. Prevention and control of surface soil restoration: Finally, soil conservation engineering measures such as cross-slope throttling ditches and longitudinal slope ridges are laid on the surface of the backfilled soil;

同时在土壤表层采用横纵协作耕作措施种植修复土壤重金属草本植物与乔木植物,乔木种植间距为大于等于2mx2m;At the same time, horizontal and vertical cooperative farming measures are adopted on the soil surface to plant herbaceous plants and trees to repair soil heavy metals. The spacing between trees is greater than or equal to 2mx2m.

草种采用混播方式,混播量大于等于30g m-2The grass seeds are sown in a mixed manner, with the sowing amount being greater than or equal to 30 g m -2 .

进一步地,所述S1中土壤在10mx10m的样地中选取3~4处,自地表向土下取50cm,每10cm采集一个混合样品,风干后装入塑料自封袋;Furthermore, the soil in S1 was selected from 3 to 4 locations in a 10mx10m plot, and a mixed sample was collected every 10cm from the surface to 50cm below the soil. The mixed sample was air-dried and then put into a plastic ziplock bag;

进一步地,所述S1中石灰粉与污染土壤的质量比例控制在1%到5%之间。Furthermore, the mass ratio of lime powder to contaminated soil in S1 is controlled between 1% and 5%.

进一步地,所述S3中土壤修复设备包括:粉碎系统、搅拌系统和固液混合系统;Furthermore, the soil remediation equipment in S3 includes: a crushing system, a stirring system and a solid-liquid mixing system;

粉碎系统包括可对投入土壤进行筛选的震动筛选板和安装于震动筛选板下方的复合粉碎机;The pulverizing system includes a vibrating screening plate capable of screening the input soil and a compound pulverizer installed below the vibrating screening plate;

固液混合系统包括药剂罐、安装于药剂罐内的混合装置和喷淋洗系统;The solid-liquid mixing system includes a reagent tank, a mixing device installed in the reagent tank, and a spray washing system;

搅拌系统用于对喷淋后的药剂和粉碎后的土壤进行混合搅拌。The mixing system is used to mix the sprayed agent and the crushed soil.

进一步地,所述药剂罐内填充有喷淋药剂和改良药剂;Furthermore, the agent tank is filled with a spray agent and an improvement agent;

喷淋药剂为钝化剂,改良药剂的原料按重量分包括:厩肥3份、植物枯落物1份和苔藓1份。The spraying agent is a passivating agent, and the raw materials of the improved agent include, by weight: 3 parts of manure, 1 part of plant litter and 1 part of moss.

进一步地,所述S3中阻隔层按质量百分比包括:矿物粘土材料65%~70%、水泥21.5%~23.5%和岩粉5%~8%,余量为粘合剂。Furthermore, the barrier layer in S3 comprises, by mass percentage, 65% to 70% of mineral clay material, 21.5% to 23.5% of cement and 5% to 8% of rock powder, with the remainder being adhesive.

进一步地,所述S6中表层土壤流失防控措施采用的是横纵协同耕作措施及工程措施;同时通过在土壤取样检测点设置传感器以监测采集数据,并通过监测采集的数据得出数据模型,完成验证横纵协同耕作措施及工程措施的防控土壤流失效果;Furthermore, the surface soil loss prevention and control measures in S6 adopt horizontal and vertical coordinated farming measures and engineering measures; at the same time, sensors are set at soil sampling and detection points to monitor and collect data, and a data model is obtained through the monitored collected data to complete the verification of the soil loss prevention and control effects of horizontal and vertical coordinated farming measures and engineering measures;

首先定义:First define:

定义一:当土层荷载条件和陡坡土面抗剪参数与陡坡时的实际情况一致时,边坡的理论最小安全系数接近于1而略小于1;Definition 1: When the soil layer load conditions and the shear parameters of the steep slope soil surface are consistent with the actual situation of the steep slope, the theoretical minimum safety factor of the slope is close to 1 and slightly less than 1;

定义二:当土层荷载条件和陡坡土面抗剪参数与陡坡时的实际情况一致时,边坡的理论最小安全系数接近于1而略小于1,对应的最危险陡坡土面,必与陡坡时的实际滑动面一致;Definition 2: When the soil layer load conditions and the shear parameters of the steep slope soil surface are consistent with the actual situation of the steep slope, the theoretical minimum safety factor of the slope is close to 1 and slightly less than 1, and the corresponding most dangerous steep slope soil surface must be consistent with the actual sliding surface of the steep slope;

而当已滑动过的陡坡,在其上一次滑动或近期滑动处,即将要滑动而尚未滑动时,是处于极限平衡状态的;When a steep slope that has slid is about to slide but has not yet slid at the place where it last slid or slid recently, it is in a state of limit equilibrium.

在其上所取的断面,属于极限平衡状态的断面,据此断面建立的推力计算公式中最后一条土条的剩余下滑力等于零,即:The section taken on it belongs to the section of limit equilibrium state. The residual sliding force of the last soil strip in the thrust calculation formula established based on this section is equal to zero, that is:

Bn=Bn一1fn+FsVnsinɑn-Vncosɑntanfn-cnln=0;(1) Bn = Bn -1fn + FsVn sinɑn -Vn cosɑn tanfn -cnln = 0 ; (1)

式中:Fs为滑动安全系数,Vn为第n土条的自重,ɑn为第n土条的滑动面倾角,cn为陡坡体第n土条的凝聚力,fn为陡坡体第n土条的内摩擦角,ln为第n土条的滑动面弧长,fn为传递系数,即:Where: Fs is the sliding safety factor, Vn is the deadweight of the nth soil strip, ɑn is the inclination angle of the sliding surface of the nth soil strip, cn is the cohesion of the nth soil strip of the steep slope, fn is the internal friction angle of the nth soil strip of the steep slope, ln is the arc length of the sliding surface of the nth soil strip, and fn is the transfer coefficient, that is:

fn=cos(ɑn-1n)-tanfnsin(ɑn-1n);f n =cos(ɑ n-1n )-tanf n sin(ɑ n-1n );

令Fs=1,并假设c或f;Let F s = 1, and assume c or f;

并由式(1)可得:And from formula (1) we can get:

Bi-1=Bi-FsVisinɑi+Vicosɑitanf+cli/fi;(i=1,2,…,n)(2)Bi -1 = Bi -Fs Vi sinɑi + Vi cosɑi tanf + cl i / fi ; (i = 1 , 2, ..., n) (2)

令最后一块土条的推力Bn=0,由式(2)逐步递推计算可得:Assuming the thrust of the last soil strip Bn = 0, we can calculate by recursive step by step from formula (2):

B1=B2-FsV2sinɑ2+V2cosɑ2tanf+cl2/f2;(3)B 1 =B 2 -F s V 2 sinɑ 2 +V 2 cosɑ 2 tanf+cl 2 /f 2 ; (3)

同时,由式(1)亦可得:At the same time, from formula (1), we can also get:

B'1=FsV1sinɑ1-V1cosɑ1tanf-cl1+B0f1;(4)B' 1 =F s V 1 sinɑ 1 -V 1 cosɑ 1 tanf-cl 1 +B 0 f 1 ; (4)

其中:B0=0;Where: B 0 = 0;

令G=B1-B'1;(5)Let G = B 1 -B'1; (5)

当陡坡处于极限平衡状态时(即Fs=1.0),任意给定一个c或f值,由式(5)可求得一个相应的f或c值,使G=B1-B'1,等于或近似等于零;When the steep slope is in the limit equilibrium state (i.e., F s = 1.0), given any c or f value, a corresponding f or c value can be obtained from equation (5) so that G = B 1 -B' 1 , which is equal to or approximately equal to zero;

即可分别求解出每个断面在极限平衡状态时的数对c,f值;The values of c and f of each section in the limit equilibrium state can be solved respectively;

将两个不同断面的数对c,f值分别绘制在安全系数Fs=1.0的平面上,可得到两条相交的c-f值曲线,交点处的一组c,f值即为唯一解,也即为符合陡坡滑动时真实状态的抗剪强度指标数值。By plotting the pairs of c and f values of two different sections on the plane with safety factor Fs = 1.0, two intersecting cf value curves can be obtained. The set of c and f values at the intersection is the unique solution, which is also the shear strength index value that conforms to the actual state of steep slope sliding.

与现有技术相比,本发明提供的一种用于岩溶区坡面重金属土壤修复及流失防控方法,通过先对污染土壤进行中和处理后再进行粉碎固化修复,使得受污染的重金属土壤内的有害物质清除效果更明显,清除效率更高,整体安全性、环保性以及实用性较高;Compared with the prior art, the method for remediation and loss prevention of heavy metal soil on karst slopes provided by the present invention first neutralizes the contaminated soil and then crushes and solidifies it for remediation, so that the harmful substances in the contaminated heavy metal soil are more effectively removed, the removal efficiency is higher, and the overall safety, environmental protection and practicality are higher;

通过表层土壤流失防控措施,可以进行土壤水分调控和水土保持,不仅可以减缓后期因大雨或地表水造成的水流速度过大,速度过快;同时可以对地表水流进行收集和导引,还可以调节土壤水分、保护植被、防止土壤侵蚀。Through surface soil loss prevention and control measures, soil moisture control and soil and water conservation can be carried out, which can not only slow down the excessive and fast water flow caused by heavy rain or surface water in the later period; at the same time, surface water flow can be collected and guided, and soil moisture can be adjusted, vegetation can be protected, and soil erosion can be prevented.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明中记载的一些实施例,对于本领域普通技术人员来讲,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings required for use in the embodiments will be briefly introduced below. Obviously, the drawings described below are only some embodiments recorded in the present invention. For ordinary technicians in this field, other drawings can also be obtained based on these drawings.

图1为本发明实施例提供的修复防控方法流程图;FIG1 is a flow chart of a repair and prevention method provided by an embodiment of the present invention;

图2为本发明实施例提供土壤修复设备的结构立体图;FIG2 is a structural perspective view of a soil remediation device provided by an embodiment of the present invention;

图3为本发明实施例提供的横纵协同耕作措施及工程措施结构立体图。FIG3 is a three-dimensional diagram of the structure of the horizontal and vertical coordinated farming measures and engineering measures provided by an embodiment of the present invention.

附图标记说明:Description of reference numerals:

1、边沟;2、横坡截流沟;3、背沟;4、地埂;5、顺坡垄沟;6、震动筛选板;7、复合粉碎机;8、固液混合系统;9、药剂罐;10、混合装置;11、喷淋洗系统;12、搅拌系统。1. Side ditch; 2. Cross slope interception ditch; 3. Back ditch; 4. Ridge; 5. Ridge ditch along the slope; 6. Vibrating screening plate; 7. Compound crusher; 8. Solid-liquid mixing system; 9. Chemical tank; 10. Mixing device; 11. Spray washing system; 12. Stirring system.

具体实施方式Detailed ways

为了使本领域的技术人员更好地理解本发明的技术方案,下面将结合附图对本发明作进一步的详细介绍。In order to enable those skilled in the art to better understand the technical solution of the present invention, the present invention will be further described in detail below with reference to the accompanying drawings.

实施例一:Embodiment 1:

请参阅图1-图3,一种用于岩溶区坡面重金属土壤修复及流失防控方法,具体包括以下步骤:Please refer to Figures 1 to 3, a method for heavy metal soil restoration and loss prevention and control on slope surfaces in karst areas, specifically comprising the following steps:

S1、土壤重金属含量测定:首先,开挖前,清理岩溶铅锌矿区陡坡上的废渣,平整场地;其次,对污染土壤进行取样检测;S1. Determination of heavy metal content in soil: First, before excavation, clean up the waste residue on the steep slope of the karst lead-zinc mining area and level the site; second, take samples of the contaminated soil for testing;

取样检测完毕后,将石灰粉铺撒在污染土壤上,静置5~10天,以对污染土壤进行中和处理;After sampling and testing, spread lime powder on the contaminated soil and leave it for 5 to 10 days to neutralize the contaminated soil;

S2、深挖土壤:中和处理完毕后,依据检测重金属土壤的深度结果进行深挖土壤;S2. Deep soil excavation: After the neutralization treatment is completed, deep soil excavation is carried out according to the depth results of the heavy metal soil detection;

S3、固化修复重金属土壤:接着将深挖的污染土壤投入土壤修复设备进行剔除石块、粉碎土壤,并对其进行药剂喷淋,已完成对土壤重金属含量的固化处理;S3. Solidification and remediation of heavy metal soil: The excavated contaminated soil is then put into soil remediation equipment to remove stones, crush the soil, and spray it with chemicals to complete the solidification of the heavy metal content in the soil;

S4、构建阻隔层:再在深挖区底部布设10~30cm厚的混合材料构成的阻隔层;S4. Constructing a barrier layer: laying a barrier layer of mixed materials with a thickness of 10 to 30 cm at the bottom of the deep excavation area;

S5、回填土壤:阻隔层填铺完毕后,接着在阻隔层上方回填固化修复后的土壤;S5. Backfill soil: After the barrier layer is filled, the solidified and repaired soil is backfilled on top of the barrier layer;

S6、防控修复表土壤:最后,在回填的土壤表层布设横坡节流沟与纵坡垄沟等保土工程措施;S6. Prevention and control of surface soil restoration: Finally, soil conservation engineering measures such as cross-slope throttling ditches and longitudinal slope ridges are laid on the surface of the backfilled soil;

同时在土壤表层采用横纵协作耕作措施种植修复土壤重金属草本植物与乔木植物,乔木种植间距为大于等于2mx2m;At the same time, horizontal and vertical cooperative farming measures are adopted on the soil surface to plant herbaceous plants and trees to repair soil heavy metals. The spacing between trees is greater than or equal to 2mx2m.

草种采用混播方式,混播量大于等于30g m-2The grass seeds are sown in a mixed manner, with the sowing amount being greater than or equal to 30 g m -2 .

S1中土壤在10mx10m的样地中选取3~4处,自地表向土下取50cm,每10cm采集一个混合样品,风干后装入塑料自封袋;In S1, 3 to 4 locations were selected in a 10mx10m plot, and a mixed sample was collected every 10cm from the surface to 50cm below the soil. After air drying, the mixed sample was placed in a plastic ziplock bag;

S1中石灰粉与污染土壤的质量比例控制在1%到5%之间。石灰粉是一种常用的碱性物质,可以提高土壤的pH值,根据土壤分析结果和所需pH值的调节范围。The mass ratio of lime powder to contaminated soil in S1 is controlled between 1% and 5%. Lime powder is a commonly used alkaline substance that can increase the pH value of the soil, according to the soil analysis results and the required pH value adjustment range.

请参阅图2,S3中土壤修复设备包括:粉碎系统、搅拌系统12和固液混合系统8;Please refer to FIG. 2 , the soil remediation equipment in S3 includes: a crushing system, a stirring system 12 and a solid-liquid mixing system 8;

粉碎系统包括可对投入土壤进行筛选的震动筛选板6和安装于震动筛选板6下方的复合粉碎机7,震动筛选板6和复合粉碎机7皆为本领域下的公知常识,其只需具备震动筛选和粉碎土壤的属性即可,在此不作过多赘述;The crushing system includes a vibrating screening plate 6 for screening the input soil and a compound crusher 7 installed below the vibrating screening plate 6. The vibrating screening plate 6 and the compound crusher 7 are both common knowledge in the art. They only need to have the properties of vibrating screening and crushing the soil, and will not be described in detail here.

固液混合系统8包括药剂罐9、安装于药剂罐9内的混合装置10和喷淋洗系统11,使用者将药剂填充于药剂罐9内,并通过混合装置10对填充的多种药剂进行混合,喷淋洗系统11再将混合完毕的药剂抽取并喷洒至粉碎后的土壤内,药剂罐9与喷淋洗系统11之间连接有输液管,并通过抽液泵配合输液管将药剂罐9内的药剂抽出再利用端处的雾化喷头进行喷出;The solid-liquid mixing system 8 includes a reagent tank 9, a mixing device 10 installed in the reagent tank 9, and a spray washing system 11. The user fills the reagent into the reagent tank 9, and mixes the filled multiple reagents through the mixing device 10. The spray washing system 11 then extracts the mixed reagent and sprays it into the crushed soil. An infusion tube is connected between the reagent tank 9 and the spray washing system 11, and the reagent in the reagent tank 9 is extracted by a liquid pump in cooperation with the infusion tube and then sprayed out by the atomizing nozzle at the end.

搅拌系统12用于对喷淋后的药剂和粉碎后的土壤进行混合搅拌。The stirring system 12 is used to mix and stir the sprayed agent and the crushed soil.

搅拌系统12为本领域下的公知常识,其只需具备固液混合搅拌的属性即可,在此不作过多赘述;The stirring system 12 is common knowledge in the art, and it only needs to have the property of mixing solid and liquid, and will not be described in detail here;

药剂罐9内填充有喷淋药剂和改良药剂;The reagent tank 9 is filled with spray reagent and improvement reagent;

喷淋药剂为钝化剂,且钝化剂的最优选择为硅钙型重金属钝化剂,其内含钙23%和硅17%;The spraying agent is a passivator, and the best choice of the passivator is a silicon-calcium heavy metal passivator, which contains 23% calcium and 17% silicon;

改良药剂的原料按重量分包括:厩肥3份、植物枯落物1份和苔藓1份。The raw materials of the improved agent include, by weight: 3 parts of manure, 1 part of plant litter and 1 part of moss.

S3中阻隔层按质量百分比包括:矿物粘土材料65%~70%、水泥21.5%~23.5%和岩粉5%~8%,余量为粘合剂。The barrier layer in S3 includes, by mass percentage, 65% to 70% of mineral clay material, 21.5% to 23.5% of cement and 5% to 8% of rock powder, with the remainder being adhesive.

S6中表层土壤流失防控措施采用的是横纵协同耕作措施及工程措施;请参阅图3,即自陡坡从下往上依次开设垂直于坡向的边沟1、横坡截流沟2和背沟3,同时在边沟1的陡坡下方修筑地埂4,再开设若干平行于坡向的顺坡垄沟5,顺坡垄沟5也分别垂直于边沟1、横坡截流沟2和背沟3,通过这样的方式,即可最大程度的防止土壤流失,边沟1、横坡截流沟2和背沟3可以对自上而下滑动的土壤进行横向拦截,以降低其滚动所带来的裹挟,同时可以进行土壤水分调控和水土保持,不仅可以(一)、减缓水流速度:陡坡上的水流速度较快,容易导致坡面土壤流失。通过开设横沟和纵沟,可以切断水流路径,分散水流能量,从而减缓水流速度,降低水流对坡面的冲刷作用。(二)、收集和导引水流:横沟和纵沟可以收集来自陡坡上的径流水,将其导引到合适的位置进行处理或排放,避免水流在陡坡上形成大面积冲刷和侵蚀。(三)、调节土壤水分:在陡坡上开设横沟和纵沟可以帮助调节土壤的水分分布。它们可以收集和储存降雨水,增加土壤含水量,并在需要时向坡面供水,提供更好的生长条件。还可以:(四)、保护植被:横沟和纵沟的建设可以减少陡坡上的水流速度和冲击力,有利于植被的生长。通过控制水流路径和分散水流能量,可以减少水流对植被的破坏,提供更好的保护环境。(五)、防止土壤流失:通过开设横沟和纵沟,可以有效地控制水流量和速度,减少土壤流失。The surface soil loss prevention and control measures in S6 adopt horizontal and vertical coordinated farming measures and engineering measures; please refer to Figure 3, that is, from the bottom to the top of the steep slope, a side ditch 1, a cross slope interception ditch 2 and a back ditch 3 are opened in sequence perpendicular to the slope direction, and at the same time, a ridge 4 is built under the steep slope of the side ditch 1, and then several slope ridges 5 are opened parallel to the slope direction. The slope ridges 5 are also perpendicular to the side ditch 1, the cross slope interception ditch 2 and the back ditch 3. In this way, soil loss can be prevented to the greatest extent. The side ditch 1, the cross slope interception ditch 2 and the back ditch 3 can intercept the soil sliding from top to bottom laterally to reduce the entrainment caused by its rolling. At the same time, soil moisture regulation and soil and water conservation can be carried out, which can not only (a) slow down the water flow speed: the water flow speed on the steep slope is fast, which is easy to cause soil loss on the slope. By opening horizontal and vertical ditches, the water flow path can be cut off and the water flow energy can be dispersed, thereby slowing down the water flow speed and reducing the scouring effect of the water flow on the slope. (ii) Collect and guide water flow: Horizontal and vertical ditches can collect runoff water from steep slopes and guide it to appropriate locations for treatment or discharge, avoiding large-scale scouring and erosion on steep slopes. (iii) Regulate soil moisture: Opening horizontal and vertical ditches on steep slopes can help regulate soil moisture distribution. They can collect and store rainfall water, increase soil moisture content, and supply water to the slope when needed, providing better growth conditions. Also: (iv) Protect vegetation: The construction of horizontal and vertical ditches can reduce the speed and impact of water flow on steep slopes, which is conducive to the growth of vegetation. By controlling the water flow path and dispersing water flow energy, the damage to vegetation by water flow can be reduced, providing a better protective environment. (v) Prevent soil loss: By opening horizontal and vertical ditches, the water flow and speed can be effectively controlled to reduce soil loss.

同时通过在陡坡的土壤取样检测点设置传感器以监测采集数据,传感器包括但不限于重量传感器、角度测量仪和长度传感器,监测者可将传感器设于边沟1、横坡截流沟2和背沟3处或陡坡土层的断面处,并通过监测采集的数据得出数据模型;陡坡体如有可能沿许多滑面滑动,则失稳时它将沿抵抗力最小的那个滑面破坏;陡坡体的滑面确定时,则滑面上的反力及陡坡体内的内力皆能自行调整,以发挥最大的抗滑能力;At the same time, sensors are set up at the soil sampling and detection points on the steep slope to monitor and collect data. The sensors include but are not limited to weight sensors, angle measuring instruments and length sensors. The monitor can set the sensors at the side ditch 1, the cross slope interception ditch 2 and the back ditch 3 or the cross section of the steep slope soil layer, and obtain a data model through monitoring the collected data; if the steep slope body is likely to slide along many sliding surfaces, it will be destroyed along the sliding surface with the least resistance when it loses stability; when the sliding surface of the steep slope body is determined, the reaction force on the sliding surface and the internal force in the steep slope body can be adjusted automatically to exert the maximum anti-sliding ability;

首先定义:First define:

定义一:当土层荷载条件和陡坡土面抗剪参数与陡坡时的实际情况一致时,边坡的理论最小安全系数接近于1而略小于1;Definition 1: When the soil layer load conditions and the shear parameters of the steep slope soil surface are consistent with the actual situation of the steep slope, the theoretical minimum safety factor of the slope is close to 1 and slightly less than 1;

定义二:当土层荷载条件和陡坡土面抗剪参数与陡坡时的实际情况一致时,边坡的理论最小安全系数接近于1而略小于1,对应的最危险陡坡土面,必与陡坡时的实际滑动面一致;Definition 2: When the soil layer load conditions and the shear parameters of the steep slope soil surface are consistent with the actual situation of the steep slope, the theoretical minimum safety factor of the slope is close to 1 and slightly less than 1, and the corresponding most dangerous steep slope soil surface must be consistent with the actual sliding surface of the steep slope;

它适应于任意形状的滑动面,它假定条间力的合力与上一条土条底面相平行,根据力的平衡条件,逐条向下推求,直至最后一条土条的推力为零;It is suitable for sliding surfaces of any shape. It assumes that the resultant force between strips is parallel to the bottom surface of the previous strip. According to the force balance condition, it is pushed down one by one until the thrust of the last strip is zero.

而当已滑动过的陡坡,在其上一次滑动或近期滑动处,即将要滑动而尚未滑动时,是处于极限平衡状态的;When a steep slope that has slid is about to slide but has not yet slid at the place where it last slid or slid recently, it is in a state of limit equilibrium.

在其上所取的断面,属于极限平衡状态的断面,据此断面建立的推力计算公式中最后一条土条的剩余下滑力等于零,即:The section taken on it belongs to the section of limit equilibrium state. The residual sliding force of the last soil strip in the thrust calculation formula established based on this section is equal to zero, that is:

Bn=Bn一1fn+FsVnsinɑn-Vncosɑntanfn-cnln=0;(1) Bn = Bn -1fn + FsVn sinɑn -Vn cosɑn tanfn -cnln = 0 ; (1)

式中:Fs为滑动安全系数,Vn为第n土条的自重,ɑn为第n土条的滑动面倾角,cn为陡坡体第n土条的凝聚力,fn为陡坡体第n土条的内摩擦角,ln为第n土条的滑动面弧长,fn为传递系数,即:Where: Fs is the sliding safety factor, Vn is the deadweight of the nth soil strip, ɑn is the inclination angle of the sliding surface of the nth soil strip, cn is the cohesion of the nth soil strip of the steep slope, fn is the internal friction angle of the nth soil strip of the steep slope, ln is the arc length of the sliding surface of the nth soil strip, and fn is the transfer coefficient, that is:

fn=cos(ɑn-1n)-tanfnsin(ɑn-1n);f n =cos(ɑ n-1n )-tanf n sin(ɑ n-1n );

令Fs=1,并假设c或f;Let F s = 1, and assume c or f;

而下列方程模型的建立必须满足以下条件之一:The establishment of the following equation model must meet one of the following conditions:

(1)同一陡坡体,主轴两侧距离相等的两断面所建立的对应方程可以联立。(1) For the same steep slope, the corresponding equations established for two sections with equal distances on both sides of the main axis can be combined.

(2)同一陡坡体,若发生两次滑动,其滑动面位置基本不变时,则按两次滑动之主轴断面分别建立的两个方程可以联立;其他断面对应两次滑动所建立的方程可以联立。(2) If two sliding events occur on the same steep slope and the position of the sliding surface remains basically unchanged, the two equations established for the main axis sections of the two sliding events can be combined; the equations established for other sections corresponding to the two sliding events can also be combined.

(3)两个陡坡体,若陡坡土体的性质类似,影响其强度变化的因素也相同时(一般是同一地区很短距离内的两个陡坡体),这两个陡坡体的主轴断面或其它对应的两个断面所建立的方程可以联立。(3) For two steep slopes, if the properties of the steep slope soils are similar and the factors affecting their strength changes are also the same (generally, two steep slopes within a short distance in the same area), the equations established for the main axis sections or other two corresponding sections of the two steep slopes can be combined.

建立方程模型的条件,一般在陡坡的产生和发展过程中比较容易找到,不仅局限于上述几种情况,只要遵循这样一个基本原则即可;但任何两个方程中的未知数c,f,在此两个断面上必须分别相等,也就是说这两个断面中陡坡土体的强度是一样的。The conditions for establishing the equation model are generally easy to find in the process of the formation and development of steep slopes. They are not limited to the above-mentioned situations. It is sufficient to follow this basic principle. However, the unknowns c and f in any two equations must be equal in these two sections, which means that the strength of the steep slope soil in these two sections is the same.

并由式(1)可得:And from formula (1) we can get:

Bi-1=Bi-FsVisinɑi+Vicosɑitanf+cli/fi;(i=1,2,…,n)(2)Bi -1 = Bi -Fs Vi sinɑi + Vi cosɑi tanf + cl i / fi ; (i = 1 , 2, ..., n) (2)

令最后一块土条的推力Bn=0,由式(2)逐步递推计算可得:Assuming the thrust of the last soil strip Bn = 0, we can calculate step by step by step recursion from formula (2):

B1=B2-FsV2sinɑ2+V2cosɑ2tanf+cl2/f2;(3)B 1 =B 2 -F s V 2 sinɑ 2 +V 2 cosɑ 2 tanf+cl 2 /f 2 ; (3)

同时,由式(1)亦可得:At the same time, from formula (1), we can also get:

B'1=FsV1sinɑ1-V1cosɑ1tanf-cl1+B0f1;(4)B' 1 =F s V 1 sinɑ 1 -V 1 cosɑ 1 tanf-cl 1 +B 0 f 1 ; (4)

其中:B0=0;Where: B 0 = 0;

令G=B1-B'1;(5)Let G = B 1 -B'1; (5)

当陡坡处于极限平衡状态时(即Fs=1.0),任意给定一个c或f值,由式(5)可求得一个相应的f或c值,使G=B1-B'1,等于或近似等于零;When the steep slope is in the limit equilibrium state (i.e., F s = 1.0), given any c or f value, a corresponding f or c value can be obtained from equation (5) so that G = B 1 -B' 1 , which is equal to or approximately equal to zero;

即可分别求解出每个断面在极限平衡状态时的数对c,f值;The values of c and f of each section in the limit equilibrium state can be solved respectively;

将两个不同断面的数对c,f值分别绘制在安全系数Fs=1.0的平面上,可得到两条相交的c-f值曲线,交点处的一组c,f值即为唯一解,也即为符合陡坡滑动时真实状态的抗剪强度指标数值;Plotting the pairs of c and f values of two different sections on the plane with safety factor Fs = 1.0, we can get two intersecting cf value curves. The set of c and f values at the intersection is the only solution, which is also the shear strength index value that meets the actual state of steep slope sliding.

监测者可将得到的准确土壤抗剪强度指标数值重现带入式(1)中,以实时监测Fs的数值是否接近于1而略小于1,从而验证表层土壤流失防控措施效果。The monitor can reproduce the accurate soil shear strength index value obtained and put it into formula (1) to monitor in real time whether the value of Fs is close to 1 but slightly less than 1, so as to verify the effectiveness of surface soil loss prevention and control measures.

以上只通过说明的方式描述了本发明的某些示范性实施例,毋庸置疑,对于本领域的普通技术人员,在不偏离本发明的精神和范围的情况下,可以用各种不同的方式对所描述的实施例进行修正。因此,上述附图和描述在本质上是说明性的,不应理解为对本发明权利要求保护范围的限制。The above description is only by way of illustration of certain exemplary embodiments of the present invention. It is undoubted that, for those skilled in the art, the described embodiments can be modified in various ways without departing from the spirit and scope of the present invention. Therefore, the above drawings and descriptions are illustrative in nature and should not be construed as limiting the scope of protection of the claims of the present invention.

Claims (7)

1.一种用于岩溶区坡面重金属土壤修复及流失防控方法,其特征在于:具体包括以下步骤:1. A method for remediation and loss prevention of heavy metal soil on slopes in karst areas, characterized in that it specifically comprises the following steps: S1、土壤重金属含量测定:首先,开挖前,对岩溶区坡面污染土壤周边环境进行清理,平整场地;其次,对污染土壤进行取样检测;S1. Determination of heavy metal content in soil: First, before excavation, the surrounding environment of the contaminated soil on the slope of the karst area is cleaned and the site is leveled; second, the contaminated soil is sampled and tested; 取样检测完毕后,将石灰粉铺撒在污染土壤上,静置5~10天,已完成对污染土壤进行中和处理;After sampling and testing, spread lime powder on the contaminated soil and let it stand for 5 to 10 days to complete the neutralization of the contaminated soil; S2、深挖土壤:中和处理完毕后,依据检测重金属土壤的深度结果进行深挖土壤;S2. Deep soil excavation: After the neutralization treatment is completed, deep soil excavation is carried out according to the depth results of the heavy metal soil detection; S3、固化修复重金属土壤:接着将深挖的污染土壤投入土壤修复设备进行剔除石块、粉碎土壤,并对其进行药剂喷淋,已完成对土壤重金属含量的固化处理;S3. Solidification and remediation of heavy metal soil: The excavated contaminated soil is then put into soil remediation equipment to remove stones, crush the soil, and spray it with chemicals to complete the solidification of the heavy metal content in the soil; S4、构建阻隔层:再在深挖区底部布设10~30cm厚的混合材料构成的阻隔层;S4. Constructing a barrier layer: laying a barrier layer of mixed materials with a thickness of 10 to 30 cm at the bottom of the deep excavation area; S5、回填土壤:阻隔层填铺完毕后,接着在阻隔层上方回填固化修复后的土壤;S5. Backfill soil: After the barrier layer is filled, the solidified and repaired soil is backfilled on top of the barrier layer; S6、修复防控表层土壤重金属:最后,在回填的土壤表层布设横坡节流沟与纵坡垄沟等保土工程措施;S6. Repair and control heavy metals in the surface soil: Finally, lay out soil conservation engineering measures such as cross-slope throttling ditches and longitudinal slope ridge ditches on the surface of the backfilled soil; 同时在土壤表层采用横纵协作耕作措施种植修复土壤重金属草本植物与乔木植物,乔木种植间距为大于等于2mx2m;At the same time, horizontal and vertical cooperative farming measures are adopted on the soil surface to plant herbaceous plants and trees to repair soil heavy metals. The spacing between trees is greater than or equal to 2mx2m. 草种采用混播方式,混播量大于等于30g m-2The grass seeds are sown in a mixed manner, with the sowing amount being greater than or equal to 30 g m -2 . 2.根据权利要求1所述的一种用于岩溶区坡面重金属土壤修复及流失防控方法,其特征在于,所述S1中土壤在10mx10m的样地中选取3~4处,自地表向土下取50cm,每10cm采集一个混合样品,风干后装入塑料自封袋。2. A method for remediation and loss control of heavy metal soil on slopes in karst areas according to claim 1, characterized in that 3 to 4 places of the soil in S1 are selected in a sample plot of 10mx10m, 50cm is taken from the surface to the bottom of the soil, a mixed sample is collected every 10cm, and the mixed sample is air-dried and packed into a plastic ziplock bag. 3.根据权利要求1所述的一种用于岩溶区坡面重金属土壤修复及流失防控方法,其特征在于,所述S1中石灰粉与污染土壤的质量比例控制在1%到5%之间。3. A method for remediation and loss control of heavy metal soil on slopes in karst areas according to claim 1, characterized in that the mass ratio of lime powder to contaminated soil in S1 is controlled between 1% and 5%. 4.根据权利要求1所述的一种用于岩溶区坡面重金属土壤修复及流失防控方法,其特征在于,所述S3中土壤修复设备包括:粉碎系统、搅拌系统和固液混合系统;4. A method for heavy metal soil remediation and loss prevention and control on slope surfaces in karst areas according to claim 1, characterized in that the soil remediation equipment in S3 comprises: a crushing system, a stirring system and a solid-liquid mixing system; 粉碎系统包括对投入土壤进行筛选的震动筛选板和安装于震动筛选板下方的复合粉碎机;The pulverizing system includes a vibrating screening plate for screening the input soil and a compound pulverizer installed below the vibrating screening plate; 固液混合系统包括药剂罐、安装于药剂罐内的混合装置和喷淋洗系统;The solid-liquid mixing system includes a reagent tank, a mixing device installed in the reagent tank, and a spray washing system; 搅拌系统用于对喷淋后的药剂和粉碎后的土壤进行混合搅拌。The mixing system is used to mix the sprayed agent and the crushed soil. 5.根据权利要求4所述的一种用于岩溶区坡面重金属土壤修复及流失防控方法,其特征在于,所述药剂罐内有喷淋药剂和改良药剂;5. A method for heavy metal soil restoration and loss prevention and control on slope surfaces in karst areas according to claim 4, characterized in that the agent tank contains a spraying agent and an improving agent; 喷淋药剂为钝化剂,改良药剂的原料按重量分包括:厩肥3份、植物枯落物1份和苔藓1份。The spraying agent is a passivating agent, and the raw materials of the improved agent include, by weight: 3 parts of manure, 1 part of plant litter and 1 part of moss. 6.根据权利要求1所述的一种用于岩溶区坡面重金属土壤修复及流失防控方法,其特征在于,所述S3中阻隔层按质量百分比包括:矿物粘土材料65%~70%、水泥21.5%~23.5%和岩粉5%~8%,余量为粘合剂。6. A method for remediation and loss control of heavy metal soil on slopes in karst areas according to claim 1, characterized in that the barrier layer in S3 comprises, by mass percentage, 65% to 70% of mineral clay material, 21.5% to 23.5% of cement and 5% to 8% of rock powder, with the remainder being adhesive. 7.根据权利要求1所述的一种用于岩溶区坡面重金属土壤修复及流失防控方法,其特征在于,所述S6中表层土壤重金属流失防控措施采用的是横纵协同耕作措施及工程措施;同时通过在土壤取样检测点设置传感器以监测采集数据,并通过监测采集的数据得出数据模型,完成验证横纵协同耕作措施及工程措施的防控土壤流失效果;7. A method for remediation and loss control of heavy metal soil on slopes in karst areas according to claim 1, characterized in that the surface soil heavy metal loss control measures in S6 adopt horizontal and vertical coordinated farming measures and engineering measures; at the same time, sensors are set at soil sampling and detection points to monitor and collect data, and a data model is obtained through the monitored collected data to complete the verification of the soil loss control effect of horizontal and vertical coordinated farming measures and engineering measures; 首先定义:First define: 定义一:当土层荷载条件和陡坡土面抗剪参数与陡坡时的实际情况一致时,边坡的理论最小安全系数接近于1而略小于1;Definition 1: When the soil layer load conditions and the shear parameters of the steep slope soil surface are consistent with the actual situation of the steep slope, the theoretical minimum safety factor of the slope is close to 1 and slightly less than 1; 定义二:当土层荷载条件和陡坡土面抗剪参数与陡坡时的实际情况一致时,边坡的理论最小安全系数接近于1而略小于1,对应的最危险陡坡土面,必与陡坡时的实际滑动面一致;Definition 2: When the soil layer load conditions and the shear parameters of the steep slope soil surface are consistent with the actual situation of the steep slope, the theoretical minimum safety factor of the slope is close to 1 and slightly less than 1, and the corresponding most dangerous steep slope soil surface must be consistent with the actual sliding surface of the steep slope; 而当已滑动过的陡坡,在其上一次滑动或近期滑动处,即将要滑动而尚未滑动时,是处于极限平衡状态的;When a steep slope that has slid is about to slide but has not yet slid at the place where it last slid or slid recently, it is in a state of limit equilibrium. 在其上所取的断面,属于极限平衡状态的断面,据此断面建立的推力计算公式中最后一条土条的剩余下滑力等于零,即:The section taken on it belongs to the section of limit equilibrium state. The residual sliding force of the last soil strip in the thrust calculation formula established based on this section is equal to zero, that is: Bn=Bn一1fn+FsVnsinɑn-Vncosɑntanfn-cnln=0; (1) Bn = Bn -1fn + FsVn sinɑn -Vn cosɑn tanfn -cnln = 0 ; (1) 式中:Fs为滑动安全系数,Vn为第n土条的自重,ɑn为第n土条的滑动面倾角,cn为陡坡体第n土条的凝聚力,fn为陡坡体第n土条的内摩擦角,ln为第n土条的滑动面弧长,fn为传递系数,即:Where: Fs is the sliding safety factor, Vn is the deadweight of the nth soil strip, ɑn is the inclination angle of the sliding surface of the nth soil strip, cn is the cohesion of the nth soil strip of the steep slope, fn is the internal friction angle of the nth soil strip of the steep slope, ln is the arc length of the sliding surface of the nth soil strip, and fn is the transfer coefficient, that is: fn=cos(ɑn-1n)-tanfnsin(ɑn-1n);f n =cos(ɑ n-1n )-tanf n sin(ɑ n-1n ); 令Fs=1,并假设c或f;Let F s = 1, and assume c or f; 并由式(1)可得:And from formula (1) we can get: Bi-1=Bi-FsVisinɑi+Vicosɑitanf+cli/fi;(i=1,2,…,n) (2)Bi -1 = Bi -Fs Vi sinɑi + Vi cosɑi tanf + cl i / fi ; (i = 1 , 2, ..., n) (2) 令最后一块土条的推力Bn=0,由式(2)逐步递推计算可得:Assuming the thrust of the last soil strip Bn = 0, we can calculate by recursive step by step from formula (2): B1=B2-FsV2sinɑ2+V2cosɑ2tanf+cl2/f2; (3)B 1 =B 2 -F s V 2 sinɑ 2 +V 2 cosɑ 2 tanf+cl 2 /f 2 ; (3) 同时,由式(1)亦可得:At the same time, from formula (1), we can also get: B'1=FsV1sinɑ1-V1cosɑ1tanf-cl1+B0f1; (4)B' 1 =F s V 1 sinɑ 1 -V 1 cosɑ 1 tanf-cl 1 +B 0 f 1 ; (4) 其中:B0=0;Where: B 0 = 0; 令G=B1-B'1; (5)Let G = B 1 -B'1; (5) 当陡坡处于极限平衡状态时(即Fs=1.0),任意给定一个c或f值,由式(5)可求得一个相应的f或c值,使G=B1-B'1,等于或近似等于零;When the steep slope is in the limit equilibrium state (i.e., F s = 1.0), given any c or f value, a corresponding f or c value can be obtained from formula (5) so that G = B 1 -B' 1 , which is equal to or approximately equal to zero; 即可分别求解出每个断面在极限平衡状态时的数对c,f值;The values of c and f of each section in the limit equilibrium state can be solved respectively; 将两个不同断面的数对c,f值分别绘制在安全系数Fs=1.0的平面上,可得到两条相交的c-f值曲线,交点处的一组c,f值即为唯一解,也即为符合陡坡滑动时真实状态的抗剪强度指标数值。By plotting the pairs of c and f values of two different sections on the plane with safety factor Fs = 1.0, two intersecting cf value curves can be obtained. The set of c and f values at the intersection is the unique solution, which is also the shear strength index value that conforms to the actual state of steep slope sliding.
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