CN117959872A - Carbon dioxide sealing system in geothermal energy heat supply - Google Patents
Carbon dioxide sealing system in geothermal energy heat supply Download PDFInfo
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- CN117959872A CN117959872A CN202410361790.XA CN202410361790A CN117959872A CN 117959872 A CN117959872 A CN 117959872A CN 202410361790 A CN202410361790 A CN 202410361790A CN 117959872 A CN117959872 A CN 117959872A
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- carbon dioxide
- water
- tank
- geothermal energy
- heating
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 162
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 81
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 81
- 238000007789 sealing Methods 0.000 title abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 88
- 238000010438 heat treatment Methods 0.000 claims abstract description 58
- 238000004519 manufacturing process Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 12
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 239000000284 extract Substances 0.000 claims abstract description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 27
- 238000000926 separation method Methods 0.000 claims description 23
- 238000009413 insulation Methods 0.000 claims description 22
- 238000001914 filtration Methods 0.000 claims description 21
- 239000002808 molecular sieve Substances 0.000 claims description 21
- 238000004140 cleaning Methods 0.000 claims description 20
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 19
- 238000004321 preservation Methods 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 17
- 230000009919 sequestration Effects 0.000 claims description 14
- 238000003860 storage Methods 0.000 claims description 14
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 13
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 13
- 239000002699 waste material Substances 0.000 claims description 13
- 239000007921 spray Substances 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 8
- 238000000746 purification Methods 0.000 claims description 7
- 230000000712 assembly Effects 0.000 claims description 5
- 238000000429 assembly Methods 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 4
- 238000005086 pumping Methods 0.000 claims description 3
- 230000014759 maintenance of location Effects 0.000 claims 3
- 238000010992 reflux Methods 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 37
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 8
- 230000001105 regulatory effect Effects 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000013618 particulate matter Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D50/00—Combinations of methods or devices for separating particles from gases or vapours
- B01D50/60—Combinations of devices covered by groups B01D46/00 and B01D47/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/42—Auxiliary equipment or operation thereof
- B01D46/4263—Means for active heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/66—Regeneration of the filtering material or filter elements inside the filter
- B01D46/79—Regeneration of the filtering material or filter elements inside the filter by liquid process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/90—Devices for taking out of action one or more units of multi-unit filters, e.g. for regeneration or maintenance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/261—Drying gases or vapours by adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
- F24T10/00—Geothermal collectors
- F24T10/20—Geothermal collectors using underground water as working fluid; using working fluid injected directly into the ground, e.g. using injection wells and recovery wells
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
- F24T50/00—Geothermal systems
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Energy (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Sustainable Development (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Hydrology & Water Resources (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses a carbon dioxide sealing and storing system in geothermal energy heat supply, which comprises: the air extractor extracts hot water or steam from the gas production well, and inputs the extracted hot water or steam into a heating system through a heat exchanger, the heating system is input into each unit, and then the water which is not used is returned into the gas production well through a water return system; carbon dioxide generated in the operation process of the air extractor, the heat exchanger, the heating system and the water reflux system is collected through the carbon dioxide collector and is input into the carbon dioxide purifying assembly to remove impurities, and then the carbon dioxide meeting the requirements is sealed in a proper mode.
Description
Technical Field
The invention relates to the technical field of geothermal energy, in particular to a carbon dioxide sealing and storing system in geothermal energy heat supply.
Background
Geothermal energy heating refers to a system that utilizes thermal energy contained within the earth to provide heat to a building or facility. The geothermal energy is used as a renewable clean energy source and has wide application prospect in the heat supply field. Geothermal energy can be classified into high-temperature geothermal energy and shallow geothermal energy according to the difference of temperature and existence form. High temperature geothermal energy exists primarily in the form of steam, often closely related to geographical factors, and is a naturally occurring form of heat. The shallow geothermal energy exists in the form of hot water, warm water or warm water, and is transferred to the crust through the movement of lava and groundwater, so that the thermal energy is stable in temperature and wide in range, a large amount of carbon dioxide can be generated in the heating process, and the sealing mode of the carbon dioxide is divided into three modes, namely ocean sealing, geological sealing and earth surface sealing, in order to prevent the pollution of air.
In the actual utilization process, because the different spatial positions and geological structures are located, the carbon dioxide sealing modes which can be selected by the geothermal energy heating system are different, the existing sealing system is usually only treated by one mode and cannot be adjusted according to actual conditions, meanwhile, the requirements of each sealing mode on the carbon dioxide are different, the mixed use of a single treatment system is extremely easy to cause energy waste, meanwhile, the working efficiency is influenced, and the sealing modes which can be selected by most heating systems are not single.
Accordingly, there is a need to provide a carbon dioxide sequestration system in geothermal energy heat supply to address the above-described problems.
Disclosure of Invention
In order to achieve the above object, the present invention provides a carbon dioxide sequestration system in geothermal energy heat supply, comprising:
The air extractor extracts hot water or steam from the gas production well, and inputs the extracted hot water or steam into a heating system through a heat exchanger, the heating system is input into each unit, and then the water which is not used is returned into the gas production well through a water return system;
Carbon dioxide generated in the operation process of the air extractor, the heat exchanger, the heating system and the water reflux system is collected through the carbon dioxide collector and is input into the carbon dioxide purifying assembly to remove impurities, and then the carbon dioxide meeting the requirements is sealed in a proper mode.
Further, preferably, the carbon dioxide purifying assembly includes:
The cooling spray assembly is characterized in that a double molecular sieve dryer, a physical filter assembly, a high-efficiency particle filter, a sulfide separation assembly, a membrane separator and another group of double molecular sieve dryers are fixedly arranged on the right side of the cooling spray assembly in sequence, and all the assemblies are fixedly connected through a gas flow pipeline.
Further, preferably, a branch pipe is arranged on a gas flowing pipeline between the double molecular sieve dryer and the physical filtering component, a condenser is fixedly arranged at the other end of the branch pipe, a supercritical carbon dioxide manufacturing chamber is fixedly arranged at the other end of the condenser, and a geological sealing gas outlet is connected at the other end of the supercritical carbon dioxide manufacturing chamber.
Further, preferably, one end of the right side of the bi-molecular sieve dryer is directly connected with the marine seal gas output port, the other end is connected with a temperature-rise pressure-regulating component, and the other end of the temperature-rise pressure-regulating component is connected with the geological seal gas output port.
Further, preferably, the physical filter assembly includes:
The filter shell is fixedly placed on the left side between the double molecular sieve dryer and the high-efficiency particle filter, two groups of heating dryers are fixedly embedded on the side wall of the filter shell, two groups of heating wires are fixedly embedded on the inner wall of the filter shell on two sides of the heating dryer, a primary filter screen and a secondary filter screen are horizontally fixedly embedded on the inner wall of the filter shell at the radiation position of the heating dryer, and a water diversion gas collecting plate is coaxially fixed at the upper end, the lower end and the middle of the filter shell.
Further, as preferable, the water diversion and air collection plates at the upper end and the middle part are fixedly provided with filter plate cleaning groups, a plurality of groups of cleaning spray heads are embedded in the filter plate cleaning groups and the corresponding water diversion and air collection plates, a water inlet pipe is arranged between the two groups of filter plate cleaning groups, and the other end of the water inlet pipe is connected to the water delivery device;
and a water outlet is formed in the inner wall of the filter shell on the right side of the water diversion and air collection plate at the middle part and the lower end.
Further, as the preference, the water diversion gas collecting plate, the first-stage filter screen, the second-stage filter screen at the lower end and the water diversion gas collecting plate at the middle part are fixedly provided with air inlet pipes, the air inlet pipes are provided with two groups of air outlet branch pipes, the connection part of the air outlet branch pipes at the lower end and the air outlet pipe, and the air outlet pipes between the two groups of air outlet branch pipes are respectively provided with a regulating valve A and a regulating valve B.
Further, preferably, the sulfide separation assembly includes:
The support frame is fixedly placed between the high-efficiency particle filter and the membrane separator, the sulfide separating tank is fixedly assembled in the middle of the support frame, the copper sulfate solvent storage tank and the waste liquid collecting tank are respectively arranged at two ends of the support frame, the pumping pumps are respectively arranged at one sides of the copper sulfate solvent storage tank and the waste liquid collecting tank, and the other ends of the copper sulfate solvent storage tank and the waste liquid collecting tank are respectively connected to the sulfide separating tank.
Further, preferably, the sulfide separation tank includes:
the heat preservation and heat insulation tank is fixedly assembled in the middle of the support frame, the water bath heating tank is coaxially arranged in the heat preservation and heat insulation tank, a water bath heating layer is arranged between the heat preservation and heat insulation tank and is heated through a thermostat fixedly assembled on the outer wall of the heat preservation and heat insulation tank, and a pressurizing assembly is fixedly assembled on the outer wall of the upper end of the heat preservation and heat insulation tank;
The stirrer is arranged inside the water bath heating tank and fixedly assembled on an output shaft of the driving motor, and the driving motor is fixedly assembled at the upper end of the heat preservation and insulation tank.
Compared with the prior art, the invention provides a carbon dioxide sealing system in geothermal energy heat supply, which has the following beneficial effects:
According to the invention, the carbon dioxide purification device is provided with three sealing paths which correspond to the three sealing modes respectively, can be selected according to the actual geological condition and the position of the heating system, and can be used for sealing the three sets of modes simultaneously according to the actual condition, so that the sealing efficiency is improved, meanwhile, the practicability of the device is improved, and meanwhile, the three sealing paths are overlapped and separated and are not interfered mutually, so that the corresponding paths can meet the corresponding sealing modes, simultaneously, more processes are avoided to the greatest extent, and the cost is saved while the feeding and sealing efficiency is improved.
According to the invention, the physical filter assembly is arranged, through the rotation between the two groups of filter assemblies, the filter assemblies which are rotated down are cleaned, so that a great amount of impurities are prevented from adhering to the filter plates, a certain degree of blockage is caused, the efficiency of the device is further caused to slide down, the device is dried through the heating drier and the heating wire after the cleaning is finished, and then the device is used in a rotation mode, meanwhile, the sulfide separation assembly is arranged, according to the change of the daily actual heating amount, the volume of the copper sulfate solution in the sulfide separation tank is reduced, the reduction of the collision frequency among reactants caused by the excessive volume of the solution is avoided, the reaction rate is reduced, the waste and unnecessary cost are further increased, and even the problems of stability of the solution and safety in operation are possibly caused.
Drawings
FIG. 1 is a schematic diagram of a carbon dioxide sequestration system during geothermal energy heat supply;
FIG. 2 is a schematic diagram of a carbon dioxide purification assembly;
FIG. 3 is a schematic view of the external structure of a physical filter assembly;
FIG. 4 is a schematic view of a partial cross-sectional structure of a physical filter assembly;
FIG. 5 is a schematic view of a sulfide separation assembly;
FIG. 6 is a schematic cross-sectional view of a sulfide separation tank;
FIG. 7 is a process flow diagram of a carbon dioxide purification assembly;
In the figure: 1. an air extractor; 2. a heat exchanger; 3. a heating system; 4. a water reflux system; 5. a carbon dioxide collector; 6. a carbon dioxide purification assembly; 61. the cooling spray assembly; 62. a dual molecular sieve dryer; 63. a condenser; 64. a supercritical carbon dioxide production chamber; 65. a physical filtration assembly; 66. a high efficiency particulate filter; 67. a sulfide separation assembly; 68. a membrane separator; 69. a gas flow conduit; 651. a filter housing; 652. a heating dryer; 653. a heating wire; 654. a first-stage filter screen; 655. a secondary filter screen; 656. a water diversion and air collection plate; 657. a filter plate cleaning group; 658. cleaning the spray head; 659. a water outlet; 6510. a water inlet pipe; 6511. an outlet branch pipe; 6512. a regulating valve A; 6513. a regulating valve B; 671. a support frame; 672. a sulfide separation tank; 673. a copper sulfate solvent storage tank; 674. a waste liquid collection tank; 675. a pump; 6721. a thermal insulation tank; 6722. a water bath heating tank; 6723. a thermostat; 6724. a pressurizing assembly; 6725. a driving motor; 6726. a stirrer.
Detailed Description
Referring to fig. 1 to 7, the present invention provides a carbon dioxide sequestration system in geothermal energy heat supply, comprising:
An air extractor 1 which extracts hot water or steam from a gas production well and inputs the extracted hot water or steam into a heating system 3 through a heat exchanger 2, the heating system 3 is input into each unit, and then the water which is not used is returned into the gas production well through a water return system 4;
Carbon dioxide generated in the operation process of the air extractor 1, the heat exchanger 2, the heating system 3 and the water reflux system 4 is collected through the carbon dioxide collector 5 and is input into the carbon dioxide purifying component 6 for impurity removal, and then the carbon dioxide meeting the requirements is sealed in a proper mode;
In a preferred embodiment, the air extractor 1 extracts hot water or steam from the gas well, and inputs the extracted hot water or steam into the heating system 3 through the heat exchanger 2, the heating system 3 inputs to each unit, and then the water which is lost in use flows back into the gas well through the water backflow system 4, so as to keep sustainable utilization of geothermal resources, a certain amount of carbon dioxide can be generated in the operation process of the air extractor 1, the heat exchanger 2, the heating system 3 and the water backflow system 4, and meanwhile, when the steam in geothermal heat is extracted, the geothermal steam contains carbon dioxide, hydrogen sulfide and other gases which cannot be condensed by conventional cold sources, and part of the geothermal resources is extracted together with the geothermal steam, and the gases can greatly pollute the atmosphere, so that the carbon dioxide is collected and captured through the carbon dioxide collector 5, and some hydrogen sulfide, the water vapor, dust particles, nitrogen and other inert gases can be captured at the same time when the carbon dioxide collector 5 collects carbon dioxide, in order to prevent the sealing and storage of carbon dioxide from being influenced, the carbon dioxide purification assembly 6 is used for removing impurities, and the sealing and sealing efficiency of carbon dioxide can be improved in a mode of the transportation mode (the sealing and the sealing process are not required by the three sealing and sealing modes) are simultaneously carried out.
Further, the carbon dioxide purifying module 6 includes:
The cooling spray assembly 61 is fixedly provided with a double molecular sieve dryer 62, a physical filter assembly 65, a high-efficiency particle filter 66, a sulfide separation assembly 67, a membrane separator 68 and another group of double molecular sieve dryers 62 on the right side in sequence, and all the assemblies are fixedly connected through a gas flow pipeline 69;
As a preferred embodiment, the cooling spray assembly 61 can primarily remove particles from the captured mixed gas, and reduce the overall temperature thereof, the dual molecular sieve dryer 62 is based on the adsorption of molecular sieves on moisture molecules in the gas or liquid, by having specific pore size molecular sieves, and adsorbing molecules with a smaller molecular diameter than the pore size, including water molecules, so as to continuously and efficiently remove moisture in the gas or liquid, and achieve a continuous drying effect, the physical filter assembly 65 is designed to capture and remove larger particles, and has fine pores designed to block the passage of particles, and allow the passage of gas, and the high-efficiency particle filter 66 is designed to capture particles with a size of more than 0.3 μm with extremely high efficiency, so as to ensure that particles in carbon dioxide are effectively removed, and the sulfide separation assembly 67 uses the difference in permeability of different gases on the membrane materials, so as to separate carbon dioxide from nitrogen and inert gases.
Further, a branch pipe is arranged on a gas flowing pipeline 69 between the double molecular sieve dryer 62 and the physical filtering component 65, a condenser 63 is fixedly arranged at the other end of the branch pipe, a supercritical carbon dioxide manufacturing chamber 64 is fixedly arranged at the other end of the condenser 63, and a geological storage gas outlet is connected to the other end of the supercritical carbon dioxide manufacturing chamber 64;
As a preferred embodiment, for geological sequestration, carbon dioxide is usually required to be compressed to a supercritical state, the supercritical state carbon dioxide has characteristics similar to liquids and gases, which makes it easier to store in underground formations, and it does not require higher purity, so that after preliminary spray cooling (shortening condensation time) and drying (removing water vapor, while improving efficiency of the device, preventing condensation of water vapor, causing damage to the device), separation is achieved by low temperature condensation technology using differences in condensation properties of carbon dioxide, sulfide, nitrogen and other inert gases at different temperatures, carbon dioxide is first condensed to liquid or solid during the temperature reduction process, while sulfide, nitrogen and other inert gases remain in a gaseous state, thereby achieving separation, while achieving geological sequestration requirements of carbon dioxide, making it somewhat purified, improving its storage under geology, avoiding unnecessary steps, improving efficiency, and reducing energy consumption.
Further, one end of the right side of the bi-molecular sieve dryer 62 is directly connected with the marine seal gas output port, the other end is connected with a temperature-rise pressure-regulating component, and the other end of the temperature-rise pressure-regulating component is connected with the geological seal gas output port;
as a preferred embodiment, for marine sequestration, the purity of the carbon dioxide is a key factor, and high purity carbon dioxide can reduce the potential impact on the marine ecosystem, and for surface sequestration, particularly sequestration by chemical reaction to convert carbon dioxide into a solid form, it is necessary to ensure that the chemical nature of the carbon dioxide matches that of the reactants to facilitate the reaction; the carbon dioxide needs to be pretreated to meet specific chemical conditions, so that the purity of the carbon dioxide reaches the corresponding sealing requirement through a complete impurity removal step, the moisture attached in the impurity removal process is removed by the double molecular sieve dryer 62 on the right side, and the temperature and pressure raising component pretreats the surface sealing of the carbon dioxide.
Further, the physical filter assembly 65 includes:
The filtering shell 651 is fixedly arranged between the left side of the double molecular sieve dryer 62 and the high-efficiency particle filter 66, two groups of heating dryers 652 are fixedly embedded on the side wall of the filtering shell 651 at the two sides of each group of heating dryers 652, two groups of heating wires 653 are fixedly embedded on the inner wall of the filtering shell 651 at the radiation position of the heating dryer 652, a primary filter screen 654 and a secondary filter screen 655 are horizontally fixedly embedded on the inner wall of the filtering shell 651 at the radiation position of the heating dryer 652, and water diversion and gas gathering plates 656 are coaxially fixed at the upper end, the lower end and the middle part of the filtering shell 651;
in a preferred embodiment, the primary filter screen 654 and the secondary filter screen 655 are made of metal mesh or fiber material, and are designed with fine pores to block the passage of particulate matter and allow the passage of gas, thereby capturing and removing larger particulate matter from the mixed gas, and the pores of the primary filter screen 654 are larger than those of the secondary filter screen 655, thereby removing particulate matter to a greater extent and further improving the efficiency of the high efficiency particulate filtration 66.
Further, a filter plate cleaning group 657 is fixedly assembled on the water diversion and air gathering plate 656 at the upper end and the middle part, a plurality of groups of cleaning spray heads 658 are embedded on the filter plate cleaning group 657 and the corresponding water diversion and air gathering plate 656, a water inlet pipe 6510 is arranged between the two groups of filter plate cleaning groups 657, and the other end of the water inlet pipe 6510 is connected to a water delivery device;
a water outlet 659 is arranged on the inner wall of the filter shell 651 at the right side of the water diversion and air collection plate 656 at the middle part and the lower end;
As a preferred embodiment, the water diversion and air gathering plate 656 at the upper end plays a role of gathering air, guides the filtered air, is discharged by an air outlet pipe, the water diversion and air gathering plate 656 at the lower end plays a role of diversion, guides the water sprayed by the filter plate cleaning group 657 to flow out from the water outlet 659, and the water diversion and air gathering plate 656 at the middle part is divided into two groups of filtering groups at the same time, and is periodically rotated, the rotated filtering groups are cleaned by the filter plate cleaning group 657, a large amount of impurities are prevented from adhering to the filter plates, so that a certain degree of blockage is caused, the efficiency of the device is further reduced, the filter plates are dried by the heating drier 652 and the heating wire 653 after the cleaning is completed, and the filter plates are waited for being rotated for use.
Further, an air inlet pipe is fixedly arranged on the water diversion and air collection plate 656 at the lower end, the primary filter screen 654, the secondary filter screen 655 and the water diversion and air collection plate 656 at the middle part, two groups of air outlet branch pipes 6511 are arranged on the air inlet pipe, the joint of the air outlet branch pipes 6511 at the lower end and the air outlet pipe is respectively provided with a regulating valve A6512 and a regulating valve B6513 on the air outlet pipe between the two groups of air outlet branch pipes 6511;
As a preferred embodiment, the air outlet of the air outlet branch 6511 is downward, so that the air outlet is blocked in the cleaning process due to the fact that cleaning water and attached water can fall into the air outlet, and therefore the efficiency of the device is affected, the adjusting valve A6512 and the adjusting valve B6513 are used for rotating the upper filtering group and the lower filtering group, and at most one group is in an open state at the same time.
Further, the sulfide separation assembly 67 includes:
The support 671 is fixedly arranged between the high-efficiency particle filter 66 and the membrane separator 68, the middle part of the support 671 is fixedly provided with a sulfide separation tank 672, both ends of the support are respectively provided with a copper sulfate solvent storage tank 673 and a waste liquid collection tank 674, one sides of the copper sulfate solvent storage tank 673 and the waste liquid collection tank 674 are respectively provided with a pumping pump 675, and the other ends of the support are connected with the sulfide separation tank 672;
As a preferred embodiment, in the morning, the human body may consume more carbohydrates to supply energy, and in the evening, fat is more easily burned, and this metabolic shift may mean that there is a difference in demand for heating amount for different periods of time, and furthermore, activity level and environmental temperature in one day may affect consumption of heating amount, for example, activity amount of people in the late afternoon and evening may be higher, and thus consumption of heating amount may be correspondingly increased, total amount of mixed gas generated by the copper sulfate solvent storage tank 673 and the collection tank may be reduced while heating amount is changed, quality of sulfide per unit time is reduced, copper sulfate concentration in the sulfide separation tank 672 is unchanged, although more copper ions may increase possibility of reaction, excessive solution volume may cause reduction of reaction rate because collision frequency between reactants is reduced, thereby causing waste and unnecessary increase of cost, and even problems of stability of solution and safety of operation may be caused, and thus the safety of the apparatus for injecting or extracting the copper sulfate solvent storage tank 673 and the collection tank may be subjected to injection or extraction of waste solution, thereby improving efficiency of solution and safety of operation may be caused relative to the apparatus.
Further, the sulfide separation tank 672 includes:
The heat preservation and insulation tank 6721 is fixedly assembled in the middle of the supporting frame 671, a water bath heating tank 6722 is coaxially arranged in the heat preservation and insulation tank 6721, a water bath heating layer is arranged between the heat preservation and insulation tank 6721, the heat preservation and insulation tank is heated through a thermostat 6723 fixedly assembled on the outer wall of the heat preservation and insulation tank 6721, and a pressurizing component 6724 is fixedly assembled on the outer wall of the upper end of the heat preservation and insulation tank 6721;
A stirrer 6726 is arranged in the water bath heating tank 6722, the stirrer 6726 is fixedly assembled on an output shaft of a driving motor 6725, and the driving motor 6725 is fixedly assembled at the upper end of the heat insulation tank 6721;
In a preferred embodiment, the thermostat 6723, the pressurizing assembly 6724 and the agitator 6726 are arranged to increase the separation efficiency of the carbon dioxide and the hydrogen sulfide, thereby separating the sulfide more efficiently and environmentally friendly.
The specific implementation method comprises the following steps: the air extractor 1 extracts hot water or steam from the gas production well, and inputs the extracted hot water or steam into the heating system 3 through the heat exchanger 2, the heating system 3 inputs each unit, and then the water which is lost in use flows back into the gas production well through the water backflow system 4, so as to keep sustainable utilization of geothermal resources, a certain amount of carbon dioxide can be generated in the operation process of the air extractor 1, the heat exchanger 2, the heating system 3 and the water backflow system 4, meanwhile, when the steam in geothermal heat is extracted, the geothermal steam contains carbon dioxide, hydrogen sulfide and other gases which cannot be condensed by a conventional cold source, and part of geothermal resources, and the gases are extracted together with the geothermal steam, so that the gases can greatly pollute the atmosphere, and are collected and captured through the carbon dioxide collector 5, and simultaneously, some hydrogen sulfide, the steam, dust particles, nitrogen and other inert gases can be captured, so as to prevent the impurities from affecting the sealing and storing of carbon dioxide, the carbon dioxide purification assembly 6 is used for removing impurities, and the sealing and storing efficiency can be improved in a mode that the sealing and storing and transportation are not required by the method.
The foregoing description is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical solution of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.
Claims (9)
1. The utility model provides a carbon dioxide seals up system in geothermal energy heat supply which characterized in that: comprising the following steps:
An air extractor (1) which extracts hot water or steam from the gas production well and inputs the extracted hot water or steam into a heating system (3) through a heat exchanger (2), wherein the heating system (3) is input into each unit, and then the water which is not used is returned into the gas production well through a water return system (4);
Carbon dioxide generated in the operation process of the air extractor (1), the heat exchanger (2), the heating system (3) and the water backflow system (4) is collected through the carbon dioxide collector (5), is input into the carbon dioxide purifying component (6) for impurity removal, and then is sealed in a proper mode.
2. A carbon dioxide sequestration system in geothermal energy thermal energy as claimed in claim 1 wherein: the carbon dioxide purification assembly (6) comprises:
the cooling spray assembly (61) is characterized in that a double molecular sieve dryer (62), a physical filtering assembly (65), a high-efficiency particle filter (66), a sulfide separating assembly (67), a membrane separator (68) and another group of double molecular sieve dryers (62) are fixedly arranged on the right side of the cooling spray assembly in sequence, and all the assemblies are fixedly connected through a gas flowing pipeline (69).
3. A carbon dioxide sequestration system in geothermal energy heat supply according to claim 2, wherein: a branch pipe is arranged on a gas flowing pipeline (69) between the double molecular sieve dryer (62) and the physical filtering component (65), the other end of the branch pipe is fixedly provided with a condenser (63), the other end of the condenser (63) is fixedly provided with a supercritical carbon dioxide manufacturing chamber (64), and the other end of the supercritical carbon dioxide manufacturing chamber (64) is connected with a geological seal gas outlet.
4. A carbon dioxide sequestration system in geothermal energy heat supply according to claim 2, wherein: one end of the right side of the double molecular sieve dryer (62) is directly connected with the marine seal gas output port, the other end of the double molecular sieve dryer is connected with the temperature-rise pressure-regulating assembly, and the other end of the temperature-rise pressure-regulating assembly is connected with the geological seal gas output port.
5. A carbon dioxide sequestration system in geothermal energy heat supply according to claim 2, wherein: the physical filter assembly (65) comprises:
The filtering shell (651) is fixedly arranged on the left side between the double molecular sieve dryer (62) and the high-efficiency particle filter (66), two groups of heating dryers (652) are fixedly embedded on the side wall of the filtering shell (651) on the two sides of the heating dryer (652), two groups of heating wires (653) are fixedly embedded on the inner wall of the filtering shell (651), a primary filter screen (654) and a secondary filter screen (655) are horizontally fixedly embedded on the inner wall of the filtering shell (651) at the radiation position of the heating dryer (652), and water diversion and gas gathering plates (656) are coaxially fixed at the upper end, the lower end and the middle of the filtering shell (651).
6. The system for sequestering carbon dioxide in geothermal energy, as defined in claim 5, wherein: a filter plate cleaning group (657) is fixedly assembled on the water diversion and air collection plate (656) at the upper end and the middle part, a plurality of groups of cleaning spray heads (658) are embedded on the filter plate cleaning group (657) and the corresponding water diversion and air collection plate (656), a water inlet pipe (6510) is arranged between the two groups of filter plate cleaning groups (657), and the other end of the water inlet pipe (6510) is connected to a water delivery device;
a water outlet (659) is arranged on the inner wall of the filtering shell (651) at the right side of the water diversion and air gathering plate (656) at the middle part and the lower end.
7. The system for sequestering carbon dioxide in geothermal energy, as defined in claim 6, wherein: the water diversion gas gathering plate (656) of lower extreme, one-level filter screen (654), two-level filter screen (655) and water diversion gas gathering plate (656) at middle part are last fixedly provided with the intake pipe, just the intake pipe is provided with two sets of branch pipes (6511) of giving vent to anger, and lower extreme branch pipe (6511) and outlet duct junction to be provided with governing valve A (6512) and governing valve B (6513) on the outlet duct between two sets of branch pipes (6511) of giving vent to anger respectively.
8. A carbon dioxide sequestration system in geothermal energy heat supply according to claim 2, wherein: the sulfide separation assembly (67) includes:
The support frame (671) is fixedly arranged between the efficient particle filter (66) and the membrane separator (68), the middle part of the support frame is fixedly provided with a sulfide separation tank (672), both ends of the support frame are respectively provided with a copper sulfate solvent storage tank (673) and a waste liquid collection tank (674), one sides of the copper sulfate solvent storage tank (673) and the waste liquid collection tank (674) are respectively provided with a pumping pump (675), and the other ends of the copper sulfate solvent storage tank and the waste liquid collection tank (674) are respectively connected to the sulfide separation tank (672).
9. The system for sequestering carbon dioxide in geothermal energy, as defined in claim 8, wherein: the sulfide separation tank (672) includes:
The heat preservation and heat insulation tank (6721) is fixedly assembled in the middle of the supporting frame (671), a water bath heating tank (6722) is coaxially arranged in the heat preservation and heat insulation tank, a water bath heating layer is arranged between the heat preservation and heat insulation tank and the heat insulation tank, the heat preservation and heat insulation tank is heated through a thermostat (6723) fixedly assembled on the outer wall of the heat preservation and heat insulation tank (6721), and a pressurizing assembly (6724) is fixedly assembled on the outer wall of the upper end of the heat preservation and heat insulation tank (6721);
The stirrer (6726) is arranged in the water bath heating tank (6722), the stirrer (6726) is fixedly assembled on an output shaft of the driving motor (6725), and the driving motor (6725) is fixedly assembled at the upper end of the heat insulation tank (6721).
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