CN117945715A - Ceramic tile adhesive and preparation method thereof - Google Patents

Ceramic tile adhesive and preparation method thereof Download PDF

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Publication number
CN117945715A
CN117945715A CN202410100511.4A CN202410100511A CN117945715A CN 117945715 A CN117945715 A CN 117945715A CN 202410100511 A CN202410100511 A CN 202410100511A CN 117945715 A CN117945715 A CN 117945715A
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China
Prior art keywords
parts
vinyl acetate
tile glue
glue according
wetting agent
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Pending
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CN202410100511.4A
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Chinese (zh)
Inventor
王劭勃
林震
邰志国
阮家铭
陈顺腾
陈炜
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Guangdong Fute New Materials Technology Co ltd
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Guangdong Fute New Materials Technology Co ltd
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Priority to CN202410100511.4A priority Critical patent/CN117945715A/en
Publication of CN117945715A publication Critical patent/CN117945715A/en
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Abstract

The invention discloses a tile adhesive, which comprises the following raw materials: silicate cement, sintered sand, gray calcium powder, tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, silicon dioxide, magnesium lithium silicate, alkali swelling thickener, anionic wetting agent, cationic surfactant and water. The tile adhesive has excellent adhesive property, and can effectively improve the firmness of paving the flexible tile patches.

Description

Ceramic tile adhesive and preparation method thereof
Technical Field
The invention belongs to the technical field of building materials, and particularly relates to a tile adhesive and a preparation method thereof.
Background
The ceramic tile glue products are special mortar products which are widely applied and have very large market usage amount. The most common application of the existing tile glue products is concentrated in hard tiles, ceramic tiles, vitrified tiles, rock plates, stones, culture stones and other products. At present, a flexible tile patch product is newly introduced in the market in recent years and is called as a soft porcelain or soft porcelain imitation tile product, and the self weight of the product is only one fifth of the weight of a traditional tile under the same volume, so that the product is widely paid attention to and favored by the market. Compared with the traditional hard ceramic tile, the back of the flexible ceramic tile patch is smoother, so that the flexible ceramic tile patch is attached by adopting the existing cement-based ceramic tile adhesive, and the problem of infirm attachment easily occurs, therefore, the existing ceramic tile adhesive needs to be improved to meet the paving requirement of the flexible ceramic tile patch.
Disclosure of Invention
The present invention aims to solve at least one of the technical problems existing in the prior art. Therefore, the invention provides the tile adhesive and the preparation method thereof, and the tile adhesive has excellent adhesive property and can effectively improve the firmness of paving the flexible tile patches.
The technical aim of the invention is realized by the following technical scheme:
The tile adhesive comprises the following raw materials: silicate cement, sintered sand, gray calcium powder, tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, silicon dioxide, magnesium lithium silicate, alkali swelling thickener, anionic wetting agent, cationic surfactant and water.
Preferably, the tile adhesive comprises the following raw materials in parts by weight: 20-25 parts of silicate cement, 65-75 parts of sintered sand, 5-10 parts of gray calcium powder, 4-6 parts of tertiary vinyl acetate-acrylic ternary polymerization emulsion, 1-2 parts of liquid flexible resin, 0.05-0.1 part of silicon dioxide, 0.2-0.3 part of magnesium lithium silicate, 0.4-0.6 part of alkali swelling thickener, 0.01-0.03 part of anionic wetting agent, 0.01-0.02 part of cationic surfactant and 20-50 parts of water.
Preferably, the Portland cement is one of P.II 42.5 and P.O 42.5.
Preferably, the granularity of the sintering sand is 50-100 meshes, the density of the sintering sand is less than or equal to 3.0g/cm 3, and the specific sintering sand has the characteristic of light weight and hollowness, and the adhesive property of the ceramic tile adhesive can be further ensured when the ceramic tile adhesive is used in the ceramic tile adhesive.
Preferably, the particle size of the dust calcium powder is 300-500 mesh.
Preferably, the tertiary vinyl acetate-acrylic ternary polymerization emulsion is a tertiary vinyl acetate-acrylic emulsion with the model of SZS-111.
Preferably, the method comprises: the liquid flexible resin is at least one of epoxy resin LS-835, epoxy resin LS-832 and epoxy resin LS-828.
Preferably, the silica is fumed silica having a particle size of less than 1mm.
Preferably, the particle size of the lithium magnesium silicate is 600-1000 mesh.
Preferably, the alkali-swellable thickener is a polycarboxylic acid.
Preferably, the anionic wetting agent is at least one of sodium methylenedinaphthyl sulfonate and sodium dodecyl sulfonate.
Preferably, the cationic surfactant is polyethylenimine.
The preparation method of the tile adhesive comprises the following steps:
(1) Mixing silicate cement, sintered sand, gray calcium powder, silicon dioxide and magnesium lithium silicate into a solid material;
(2) Mixing tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, alkali swelling thickener, anionic wetting agent, cationic surfactant and water to obtain a liquid material;
(3) Mixing the solid material prepared in the step (1) with the liquid material prepared in the step (2).
The beneficial effects of the invention are as follows:
(1) The gray calcium powder in the ceramic tile adhesive is an air hardening material, so that the reduction of the surface flexibility caused by higher early hardening rigidity of the ceramic tile adhesive can be avoided, and the later strength increase can be ensured by matching with the silicate cement material, so that the product flexibility can be improved;
(2) The specific tertiary vinyl acetate-acrylic ternary polymerization emulsion in the tile adhesive can effectively improve the weather resistance of the tile adhesive, and can be matched with specific liquid flexible resin and cationic surfactant to effectively improve the later interface strength and cohesiveness, and the problem of paving firmness caused by insufficient early wettability can be avoided to the greatest extent by adding the specific anionic wetting agent.
Detailed Description
The invention will be further illustrated with reference to specific examples.
Example 1:
The tile adhesive comprises the following raw materials in parts by weight: 20 parts of silicate cement, 65 parts of sintered sand, 5 parts of gray calcium powder, 4 parts of tertiary vinyl acetate-acrylic ternary polymerization emulsion, 1 part of liquid flexible resin, 0.05 part of fumed silica, 0.2 part of magnesium lithium silicate, 0.4 part of alkali swelling thickener, 0.01 part of anionic wetting agent, 0.01 part of cationic surfactant and 20 parts of water, wherein the silicate cement is P.II 42.5, the granularity of the sintered sand is 80 meshes, the density of the sintered sand is 2.13g/cm 3, the granularity of the gray calcium powder is 300 meshes, the tertiary vinyl acetate-acrylic ternary polymerization emulsion is tertiary vinyl acetate-acrylic emulsion sold by Wuhan super age electric company, the liquid flexible resin is epoxy resin LS-835, the granularity of the fumed silica is less than 100nm, the granularity of the magnesium lithium silicate is 600 meshes, the alkali swelling thickener is polycarboxylic acid sold by the company of Arkesu Nobel (Shanghai) with the name T-615, the anionic wetting agent is sodium methylene dinaphthyl sulfonate, and the cationic surfactant is polyethylene imine.
The preparation method of the tile adhesive comprises the following steps:
(1) Mixing silicate cement, sintered sand, gray calcium powder, fumed silica and lithium magnesium silicate, and stirring at 1300rpm for 10 minutes to obtain a solid material;
(2) Mixing tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, alkali swelling thickener, anionic wetting agent, cationic surfactant and water, stirring at 1800rpm for 15 minutes, and preparing a liquid material;
(3) Slowly adding the solid material prepared in the step (1) into the liquid material prepared in the step (2) under the stirring state of 2000rpm, and uniformly mixing to obtain the composite material.
Example 2:
The tile adhesive comprises the following raw materials in parts by weight: 25 parts of Portland cement, 75 parts of sintered sand, 10 parts of ash calcium powder, 6 parts of tertiary vinyl acetate-acrylic ternary polymerization emulsion, 2 parts of liquid flexible resin, 0.1 part of fumed silica, 0.3 part of magnesium lithium silicate, 0.6 part of alkali swelling thickener, 0.03 part of anionic wetting agent, 0.02 part of cationic surfactant and 50 parts of water, wherein the Portland cement is PO42.5, the granularity of the sintered sand is 80 meshes, the density of the sintered sand is 2.13g/cm 3, the granularity of the ash calcium powder is 500 meshes, the tertiary vinyl acetate-acrylic ternary polymerization emulsion is tertiary vinyl acetate-acrylic emulsion sold by Wuhan super electric company Limited and having the model number SZS-111, the liquid flexible resin is epoxy resin LS-832, the granularity of the fumed silica is less than 100nm, the granularity of the magnesium lithium silicate is 1000 meshes, the alkali swelling thickener is polycarboxylic acid sold by the company of Arctosubel chemical (Shanghai) and the brand name T-615, the anionic wetting agent is sodium dodecyl sulfonate, and the cationic surfactant is polyethylenimine.
The preparation method of the tile adhesive comprises the following steps:
(1) Mixing silicate cement, sintered sand, gray calcium powder, fumed silica and lithium magnesium silicate, and stirring at 1300rpm for 10 minutes to obtain a solid material;
(2) Mixing tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, alkali swelling thickener, anionic wetting agent, cationic surfactant and water, stirring at 1800rpm for 15 minutes, and preparing a liquid material;
(3) Slowly adding the solid material prepared in the step (1) into the liquid material prepared in the step (2) under the stirring state of 2000rpm, and uniformly mixing to obtain the composite material.
Example 3:
The tile adhesive comprises the following raw materials in parts by weight: 23 parts of Portland cement, 70 parts of sintered sand, 8 parts of gray calcium powder, 5 parts of tertiary vinyl acetate-acrylic ternary polymerization emulsion, 1.5 parts of liquid flexible resin, 0.08 part of fumed silica, 0.25 part of magnesium lithium silicate, 0.5 part of alkali swelling thickener, 0.02 part of anionic wetting agent, 0.01 part of cationic surfactant and 30 parts of water, wherein the Portland cement is P.II 42.5, the granularity of the sintered sand is 80 meshes, the density of the sintered sand is 2.13g/cm 3, the granularity of the gray calcium powder is 300 meshes, the tertiary vinyl acetate-acrylic ternary polymerization emulsion is tertiary vinyl acetate-acrylic emulsion sold by Wuhan super-age electric company, the liquid flexible resin is epoxy resin LS-835, the granularity of the fumed silica is less than 100nm, the granularity of the magnesium lithium silicate is 600 meshes, the alkali swelling thickener is polycarboxylic acid sold by Arkesu Barbel (Shanghai) with the name T-615, the anionic wetting agent is sodium methylene dinaphtalate, and the cationic surfactant is polyethylene imine.
The preparation method of the tile adhesive comprises the following steps:
(1) Mixing silicate cement, sintered sand, gray calcium powder, fumed silica and lithium magnesium silicate, and stirring at 1300rpm for 10 minutes to obtain a solid material;
(2) Mixing tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, alkali swelling thickener, anionic wetting agent, cationic surfactant and water, stirring at 1800rpm for 15 minutes, and preparing a liquid material;
(3) Slowly adding the solid material prepared in the step (1) into the liquid material prepared in the step (2) under the stirring state of 2000rpm, and uniformly mixing to obtain the composite material.
Example 4:
The tile adhesive comprises the following raw materials in parts by weight: 22 parts of Portland cement, 66 parts of sintered sand, 9 parts of gray calcium powder, 5 parts of tertiary vinyl acetate-acrylic ternary polymerization emulsion, 1.3 parts of liquid flexible resin, 0.05 part of fumed silica, 0.2 part of magnesium lithium silicate, 0.45 part of alkali swelling thickener, 0.015 part of anionic wetting agent, 0.015 part of cationic surfactant and 35 parts of water, wherein the Portland cement is P.II 42.5, the granularity of the sintered sand is 80 meshes, the density of the sintered sand is 2.13g/cm 3, the granularity of the gray calcium powder is 300 meshes, the tertiary vinyl acetate-acrylic ternary polymerization emulsion is tertiary vinyl acetate-acrylic emulsion sold by Wuhan super-age electric company, the liquid flexible resin is epoxy resin LS-835, the granularity of the fumed silica is less than 100nm, the granularity of the magnesium lithium silicate is 600 meshes, the alkali swelling thickener is polycarboxylic acid sold by Arkesu Barbel (Shanghai) with the name T-615, the anionic wetting agent is sodium methylene dinaphthyl sulfonate, and the cationic surfactant is polyethylene imine.
The preparation method of the tile adhesive comprises the following steps:
(1) Mixing silicate cement, sintered sand, gray calcium powder, fumed silica and lithium magnesium silicate, and stirring at 1300rpm for 10 minutes to obtain a solid material;
(2) Mixing tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, alkali swelling thickener, anionic wetting agent, cationic surfactant and water, stirring at 1800rpm for 15 minutes, and preparing a liquid material;
(3) Slowly adding the solid material prepared in the step (1) into the liquid material prepared in the step (2) under the stirring state of 2000rpm, and uniformly mixing to obtain the composite material.
Example 5:
The tile adhesive comprises the following raw materials in parts by weight: 24 parts of Portland cement, 73 parts of sintered sand, 6 parts of gray calcium powder, 5 parts of tertiary vinyl acetate-acrylic ternary polymerization emulsion, 1.8 parts of liquid flexible resin, 0.08 part of fumed silica, 0.28 part of magnesium lithium silicate, 0.56 part of alkali swelling thickener, 0.02 part of anionic wetting agent, 0.018 part of cationic surfactant and 40 parts of water, wherein the Portland cement is P.II 42.5, the granularity of the sintered sand is 80 meshes, the density of the sintered sand is 2.13g/cm 3, the granularity of the gray calcium powder is 300 meshes, the tertiary vinyl acetate-acrylic ternary polymerization emulsion is tertiary vinyl acetate-acrylic emulsion sold by Wuhan super-age electric company, the liquid flexible resin is epoxy resin LS-835, the granularity of the fumed silica is less than 100nm, the granularity of the magnesium lithium silicate is 600 meshes, the alkali swelling thickener is polycarboxylic acid sold by Arkesinobell chemical (Shanghai) and the brand name T-615, the anionic wetting agent is sodium methylene dinaphtalate, and the cationic surfactant is polyethyleneimine.
The preparation method of the tile adhesive comprises the following steps:
(1) Mixing silicate cement, sintered sand, gray calcium powder, fumed silica and lithium magnesium silicate, and stirring at 1300rpm for 10 minutes to obtain a solid material;
(2) Mixing tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, alkali swelling thickener, anionic wetting agent, cationic surfactant and water, stirring at 1800rpm for 15 minutes, and preparing a liquid material;
(3) Slowly adding the solid material prepared in the step (1) into the liquid material prepared in the step (2) under the stirring state of 2000rpm, and uniformly mixing to obtain the composite material.
Comparative example 1:
a tile adhesive differing from example 3 only in that it does not contain gray calcium powder.
Comparative example 2:
A tile adhesive differs from example 3 only in that it does not contain a tertiary vinyl acetate-acrylic terpolymer emulsion.
Comparative example 3:
A tile adhesive differs from example 3 only in that it does not contain a liquid flexible resin.
Comparative example 4:
A tile glue differs from example 3 only in that it does not contain a cationic surfactant.
Comparative example 5:
a tile glue differs from example 3 only in that it does not contain an anionic wetting agent.
Test example:
the tile adhesives of examples 1-5 and comparative examples 1-5 were tested for performance with reference to the JC/T547-2017 standard, and the test results are shown in Table 1 below:
table 1: results of Performance test
As shown in Table 1, the original tensile bond strength of the tile adhesive can reach more than 2.73MPa, the tensile bond strength after soaking in water can reach more than 2.21MPa, the tensile bond strength after heat aging can reach more than 2.03MPa, the tensile bond strength after 3 times of freeze thawing can reach more than 1.95MPa, the tensile bond strength after 20min of ultraviolet irradiation can reach more than 2.05MPa, and the tile adhesive has excellent adhesive property and weather resistance, and can effectively improve the firmness of paving a flexible tile patch.
Meanwhile, as is clear from comparative examples 3 and comparative examples 1 to 5, when other conditions are not changed, the adhesive property and weather resistance of the tile are reduced when one of the gray calcium powder, the tertiary vinyl acetate-acrylic ternary polymerization emulsion, the liquid flexible resin, the cationic surfactant and the anionic wetting agent is absent from the tile adhesive.
The above examples are preferred embodiments of the present invention, but the embodiments of the present invention are not limited to the above examples, and any other changes, modifications, substitutions, combinations, and simplifications that do not depart from the spirit and principle of the present invention should be made in the equivalent manner, and the embodiments are included in the protection scope of the present invention.

Claims (10)

1. The utility model provides a ceramic tile glue which characterized in that: the preparation method comprises the following raw materials:
Silicate cement, sintered sand, gray calcium powder, tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, silicon dioxide, magnesium lithium silicate, alkali swelling thickener, anionic wetting agent, cationic surfactant and water.
2. A tile glue according to claim 1, wherein: the material comprises the following raw materials in parts by weight: 20-25 parts of silicate cement, 65-75 parts of sintered sand, 5-10 parts of gray calcium powder, 4-6 parts of tertiary vinyl acetate-acrylic ternary polymerization emulsion, 1-2 parts of liquid flexible resin, 0.05-0.1 part of silicon dioxide, 0.2-0.3 part of magnesium lithium silicate, 0.4-0.6 part of alkali swelling thickener, 0.01-0.03 part of anionic wetting agent, 0.01-0.02 part of cationic surfactant and 20-50 parts of water.
3. A tile glue according to claim 1, wherein: the tertiary vinyl acetate-acrylic ternary polymerization emulsion is a tertiary vinyl acetate-acrylic emulsion with the model of SZS-111.
4. A tile glue according to claim 1, wherein: the liquid flexible resin is at least one of epoxy resin LS-835, epoxy resin LS-832 and epoxy resin LS-828.
5. A tile glue according to claim 1, wherein: the silicon dioxide is fumed silica, and the particle size of the silicon dioxide is smaller than 100nm.
6. A tile glue according to claim 1, wherein: the granularity of the magnesium lithium silicate is 600-1000 meshes.
7. A tile glue according to claim 1, wherein: the alkali swelling thickener is polycarboxylic acid.
8. A tile glue according to claim 1, wherein: the anionic wetting agent is at least one of sodium methylene dinaphthyl sulfonate and sodium dodecyl sulfonate.
9. A tile glue according to claim 1, wherein: the cationic surfactant is polyethyleneimine.
10. A method of preparing a tile glue according to any one of claims 1 to 9, wherein: the method comprises the following steps:
(1) Mixing silicate cement, sintered sand, gray calcium powder, silicon dioxide and magnesium lithium silicate into a solid material;
(2) Mixing tertiary vinyl acetate-acrylic ternary polymerization emulsion, liquid flexible resin, alkali swelling thickener, anionic wetting agent, cationic surfactant and water to obtain a liquid material;
(3) Mixing the solid material prepared in the step (1) with the liquid material prepared in the step (2).
CN202410100511.4A 2024-01-24 2024-01-24 Ceramic tile adhesive and preparation method thereof Pending CN117945715A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202410100511.4A CN117945715A (en) 2024-01-24 2024-01-24 Ceramic tile adhesive and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202410100511.4A CN117945715A (en) 2024-01-24 2024-01-24 Ceramic tile adhesive and preparation method thereof

Publications (1)

Publication Number Publication Date
CN117945715A true CN117945715A (en) 2024-04-30

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Application Number Title Priority Date Filing Date
CN202410100511.4A Pending CN117945715A (en) 2024-01-24 2024-01-24 Ceramic tile adhesive and preparation method thereof

Country Status (1)

Country Link
CN (1) CN117945715A (en)

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