CN117906147A - Sulfur-containing waste liquid regeneration acid production device and method and burner for same - Google Patents

Sulfur-containing waste liquid regeneration acid production device and method and burner for same Download PDF

Info

Publication number
CN117906147A
CN117906147A CN202211267417.5A CN202211267417A CN117906147A CN 117906147 A CN117906147 A CN 117906147A CN 202211267417 A CN202211267417 A CN 202211267417A CN 117906147 A CN117906147 A CN 117906147A
Authority
CN
China
Prior art keywords
waste liquid
burner
sulfur
containing waste
fuel gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202211267417.5A
Other languages
Chinese (zh)
Inventor
陈英斌
徐晓燕
王雪雯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Research Institute of Sinopec Nanjing Chemical Industry Co Ltd
Original Assignee
China Petroleum and Chemical Corp
Research Institute of Sinopec Nanjing Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp, Research Institute of Sinopec Nanjing Chemical Industry Co Ltd filed Critical China Petroleum and Chemical Corp
Priority to CN202211267417.5A priority Critical patent/CN117906147A/en
Publication of CN117906147A publication Critical patent/CN117906147A/en
Pending legal-status Critical Current

Links

Abstract

The invention relates to the field of chemical environment-friendly equipment, and discloses a sulfur-containing waste liquid regeneration acid making device, a sulfur-containing waste liquid regeneration acid making method and a burner used for the same, wherein the burner comprises a burner cylinder body (1) and a central tube assembly (2), the central tube assembly (2) comprises an inner tube (21), a middle tube (22) and an outer tube (23) which are coaxially arranged from inside to outside so as to limit a sulfur-containing waste liquid channel, an atomized air channel and a fuel gas channel, the inner tube (21) is provided with a waste liquid nozzle (211), and fuel gas conveyed by the fuel gas channel can be combusted at the position of the waste liquid nozzle (211) for spraying the sulfur-containing waste liquid to generate combustion flame. The burner can absorb heat by utilizing the decomposition process of the sulfur-containing waste liquid, so that the local temperature of the flame center is prevented from being too high, meanwhile, a low-pressure area is formed near the waste liquid nozzle by the spraying action of atomized wind and the sulfur-containing waste liquid, and part of smoke is sucked and mixed to a combustion position, so that the oxygen content of the combustion area is reduced, and the generation of NO x is effectively inhibited.

Description

Sulfur-containing waste liquid regeneration acid production device and method and burner for same
Technical Field
The invention relates to chemical environment-friendly equipment, in particular to a combustor for a sulfur-containing waste liquid regeneration acid making device. On the basis, the invention also relates to a device and a method for regenerating and preparing acid by using the sulfur-containing waste liquid.
Background
With the progress of industrial production technology, while the production efficiency is increasing, mankind is also facing serious challenges in the aspect of atmospheric environmental protection. One of the main major causes of atmospheric pollution is oxynitride, and the treatment of nitrogen oxides is not slow. For various sulfur-containing waste liquid generated in industrial production, sulfur resources in the waste liquid can be recycled through a regeneration acid preparation mode, however, for example, in an industrial device for preparing acid through cracking and regeneration of alkylated waste acid and burning the acrylonitrile sulfur-containing waste liquid, the problem that NO x in discharged tail gas cannot reach the standard often exists.
The related research data show that NO x generated by combustion is mainly divided into thermal NO x, rapid NO x and fuel NO x, and the influencing factors mainly comprise nitrogen element in fuel, local high temperature, flue gas residence time, oxygen-enriched combustion and the like. Therefore, in the regeneration acid production technology, the generation of NO x in the combustion process can be reduced by controlling the fuel type, the combustion temperature, the combustion time and the like.
At present, two main measures are taken in the industry: one is to add denitration facilities to a cracking or converting unit of the acid making device, but the technology is still immature, and after NH 3 is sprayed, the stable operation of the acid making device is adversely affected; another is to use a low nitrogen burner with internal flue gas recirculation to reduce the formation of NO x by reducing the oxygen concentration in the flame zone, which is also not satisfactory.
Disclosure of Invention
The invention aims to solve the problem that a large amount of NO x is easy to generate in the regeneration acid making process of sulfur-containing waste liquid in the prior art, and provides a burner for a regeneration acid making device of the sulfur-containing waste liquid, which can effectively inhibit the generation of NO x in the regeneration acid making process.
In order to achieve the above object, an aspect of the present invention provides a burner for a sour plant for regenerating a sulfur-containing waste liquid, comprising: a burner cylinder having opposite first and second ends and provided with a combustion air inlet communicating to the second end through an inner cavity of the burner cylinder and an ignition device arranged at the second end; a center tube assembly extending from the first end to the second end along a centerline of the burner cylinder and including an inner tube, a middle tube and an outer tube coaxially disposed from inside to outside to define a sulfur-containing waste liquid passage therein, an atomized air passage between the inner tube and the middle tube, and a fuel gas passage between the middle tube and the outer tube, a waste liquid nozzle being provided at a free end of the inner tube at the second end, and fuel gas conveyed by the fuel gas passage being capable of burning to produce a combustion flame at a location where the waste liquid nozzle ejects sulfur-containing waste liquid.
Preferably, a swirl plate for guiding the combustion air to flow spirally towards the second end is arranged in the space between the central tube assembly and the burner cylinder.
Preferably, a flame stabilizing cap disposed around the center tube assembly is attached to the second end of the burner cylinder.
Preferably, one end of the fuel gas channel near the waste liquid nozzle is provided with a plurality of fuel gas burners arranged around the waste liquid nozzle.
Preferably, the first end of the burner cylinder is provided with an operation panel, through which the inner tube, the intermediate tube and the outer tube extend, and a sulfur-containing waste liquid inlet, an atomized air inlet and a fuel gas inlet are respectively provided at portions extending outside the burner cylinder.
Preferably, the combustion air inlet is arranged on the side wall of the burner cylinder.
Preferably, the operation panel is provided with a flame detector and/or a fire observation hole.
A second aspect of the present invention provides a sour apparatus for regenerating sour liquid from a sour liquid comprising a combustion furnace and a burner as described above connected to the combustion furnace and connected such that the second end is directed towards or within the furnace of the combustion furnace.
A third aspect of the present invention provides a method for regenerating a sulfur-containing waste liquid, wherein the sulfur-containing waste liquid is transported through the sulfur-containing waste liquid channel, and the sulfur-containing waste liquid contains at least one of sulfuric acid, sulfurous acid, ammonium sulfate, ammonium bisulfate, sodium sulfate, potassium sulfate, and ammonium sulfite.
Preferably, the atomized air pressure output by the atomized air channel is not less than 0.3MPa.
According to the technical scheme, the waste liquid spray gun is integrated in the combustor, so that the installation space for the waste liquid spray gun on the combustion furnace of the sulfur-containing waste liquid regeneration acid making device is saved, the combustion flame generated by combustion of fuel gas is positioned at the ejection position of the sulfur-containing waste liquid, and heat is absorbed by utilizing the decomposition process of the sulfur-containing waste liquid, so that the local temperature of the flame center is prevented from being too high, meanwhile, the spraying effect of atomized wind and the sulfur-containing waste liquid forms a low-pressure area near the waste liquid nozzle, and part of flue gas can be sucked and mixed to the combustion position, so that the oxygen content of the combustion area is reduced, and the generation of NO x is effectively inhibited in the regeneration acid making process.
Drawings
FIG. 1 is a schematic cross-sectional structure of a burner for a sour plant for regenerating a sulfur-containing waste liquid according to a preferred embodiment of the present invention.
Description of the reference numerals
1-A burner cylinder; 11-combustion-supporting air inlet; 12-ignition device; 12 a-igniter; 12 b-changming lamp; 13-an operation panel; 14-a flame detector; 15-fire observation holes; 16-combustion-supporting air channels; 2-a central tube assembly; 21-an inner tube; 211-waste liquid nozzle; 212-sulfur-containing waste liquid inlet; 22-an intermediate tube; 221-an atomized air inlet; 23-an outer tube; 231-fuel gas burner; 232-fuel gas inlet; 3-a cyclone plate; 4-flame stabilizing cover.
Detailed Description
The following describes specific embodiments of the present invention in detail with reference to the drawings. It should be understood that the detailed description and specific examples, while indicating and illustrating the invention, are not intended to limit the invention.
In the present invention, unless otherwise specified, terms such as "upper, lower, left, and right" and "upper, lower, left, and right" are used generically to refer to the upper, lower, left, and right illustrated in the drawings; "inner and outer" means inner and outer relative to the contour of the respective parts themselves.
Referring to fig. 1, a burner for a sour plant for regenerating sulfur-containing waste liquid according to a preferred embodiment of the present invention includes a burner cylinder 1 and a center tube assembly 2 extending through a center line of the burner cylinder 1. Wherein the burner cylinder 1 may be formed in a substantially cylindrical shape and have opposite first and second ends. The burner cylinder 1 is provided with a combustion air inlet 11 for the introduction of a combustion air, such as pressurized air, through which combustion air inlet 11 the combustion air introduced can be conveyed to the second end via the inner chamber of the burner cylinder 1, i.e. the combustion air channel 16 formed by the radial space between the burner cylinder 1 and the central tube assembly 2, for combustion reaction with the fuel air introduced by the fuel air channel of the central tube assembly 2 as described later. The burner cylinder 1 is furthermore provided with an ignition device 12 arranged at its second end. In a preferred embodiment, the ignition device 12 may be mounted on the operating panel 13 at the first end of the burner cylinder 1 and extend to the position of the second end in order to perform ignition maneuvers. Further, the ignition device 12 may include an igniter 12a and a pilot burner 12b provided near the free end of the second end of the center tube assembly 2 for the ignition and stable operation of the combustion process of the fuel gas burner 231 described later, respectively.
In the burner, the center tube assembly 2 extends at least from a first end to a second end of the burner cylinder 1 so that fuel gas or the like is introduced into the center tube assembly 2 at the first end and burned at the second end. Specifically, the center tube assembly 2 includes an inner tube 21, an intermediate tube 22, and an outer tube 23 coaxially disposed with each other from the inside to the outside, whereby three sets of passages are defined in the center tube assembly 2: the free end of the inner tube 21, which is positioned at the second end, is provided with a waste liquid nozzle 211, so that the burner can be utilized and the sulfur-containing waste liquid can be directly introduced into the hearth of the combustion furnace through the sulfur-containing waste liquid channel thereof without separately arranging an installation space for a waste liquid spray gun; the atomizing air channel can spray pressure air flow (such as pressurized air with relatively high pressure) to the waste liquid nozzle 211, so that the sulfur-containing waste liquid sprayed by the waste liquid nozzle 211 is atomized and sprayed into the hearth; the fuel gas channel can be used to deliver fuel gas, such as natural gas, methane, etc., which can be combusted at the point where the waste liquid nozzle 211 ejects the sulfur-containing waste liquid to produce a combustion flame.
Thus, the burner of the present invention is integrated with the waste liquid spray gun, so that it is unnecessary to provide a separate installation space for the waste liquid spray gun on the burner of the sulfur-containing waste liquid regeneration acid making apparatus. More importantly, by locating the combustion flame generated by the combustion of the fuel gas at the location of the ejection of the sulfur-containing effluent, the combustion heat can be absorbed by the sulfur-containing effluent decomposition process, thereby avoiding excessive local temperature at the flame center. At the same time, the spraying action of the atomized wind and the sulfur-containing waste liquid forms a low pressure area near the waste liquid nozzle 211, which can entrain part of the flue gas generated by combustion in the hearth to mix towards the combustion position, thereby reducing the oxygen content of the combustion area and effectively inhibiting the generation of NO x in the regeneration acid making process.
On the basis, the invention also provides a sulfur-containing waste liquid regeneration acid making device which is different from the prior art that a burner and a waste liquid spray gun are independently arranged on a combustion furnace, and the sulfur-containing waste liquid regeneration acid making device is provided with the burner, so that the sulfur-containing waste liquid can be directly sprayed into a hearth of the combustion furnace by using the burner, the spraying position of the sulfur-containing waste liquid is positioned in the combustion flame center of fuel gas, and the heat generated by combustion can be absorbed by using the decomposition process of the sulfur-containing waste liquid, so that the generation of NO x caused by the overhigh local temperature of the flame center can be avoided. At the same time, the spraying action of the atomized wind and the sulfur-containing waste liquid forms a low pressure area near the waste liquid nozzle, which draws a part of flue gas in the hearth to the combustion position, thereby further inhibiting the generation of NO x in the regeneration acid making process by reducing the oxygen content of the combustion area.
The device for regenerating and preparing the acid by using the sulfur-containing waste liquid can be used in regeneration and acid preparation processes based on various sulfur-containing waste liquids, and therefore, the invention also provides a method for regenerating and preparing the acid by using the sulfur-containing waste liquid of the device for regenerating and preparing the acid by using the sulfur-containing waste liquid, wherein the sulfur-containing waste liquid which is introduced into a sulfur-containing waste liquid channel of a combustor and used for regenerating and preparing the acid can contain at least one of sulfuric acid, sulfurous acid, ammonium sulfate, ammonium bisulfate, sodium sulfate, potassium sulfate and ammonium sulfite. In order to promote the atomization of the sulfur-containing waste liquid by utilizing the air flow introduced into the atomization air channel, the pressure of the atomization air should be set relatively high, for example, the pressure of the atomization air output by the atomization air channel can be not less than 0.3MPa.
With continued reference to fig. 1, the space between the center tube assembly 2 and the burner cylinder 1 is formed as a combustion air channel 16 for the flow of combustion-supporting gas, which combustion air channel 16 may be provided with a swirl plate 3 at a position near the second end, which swirl plate 3 is arranged to be able to direct the flow of combustion-supporting air introduced by the combustion-supporting air inlet 11 in a spiral manner in the direction of the second end. With this arrangement, the combustion air passage 16 forms a swirl flow of the combustion air discharged into the furnace through the second end of the burner cylinder 1, which can sufficiently burn the fuel gas and ensure the stability of the combustion flame generated by the combustion.
In a preferred embodiment, a flame stabilizing cap 4 arranged around the central tube assembly 2 may also be attached to the second end of the burner cylinder 1, which also helps to maintain the stability of the combustion flame.
In the above-described burner, the center tube assembly 2 may be mainly formed by nesting three concentric circular tubes to form a sulfur-containing waste liquid passage, an atomizing wind passage, and a fuel gas passage in different radial spaces. In order to absorb the heat generated by the combustion of the fuel gas by the decomposition process of the sulfur-containing waste liquid, the combustion flame generated by the combustion of the fuel gas needs to cover the sulfur-containing waste liquid ejected from the waste liquid nozzle 211 as much as possible. For this purpose, sulfur-containing waste liquid may be caused to be ejected from an annular region surrounding the waste liquid nozzle 211. Generally, in order to facilitate the ejection of sulfur-containing waste liquid, the waste liquid nozzle 211 has a relatively large radial dimension compared to the main body portion of the inner tube 21 so as to atomize the waste liquid nozzle 211 ejected therefrom by mechanical means or compressed gas means. In this regard, one end of the fuel gas channel near the waste liquid nozzle 211 may be provided with a plurality of fuel gas burners 231 arranged around the waste liquid nozzle 211, such as four, six or eight fuel gas burners 231 uniformly arranged in the circumferential direction around the waste liquid nozzle 211.
In order to isolate the high temperatures generated by combustion and to facilitate the operation of the operator, the first end of the burner cylinder 1 may be provided with an operating panel 13. As described above, the igniter 12a, the pilot lamp 12b, and the like may be fixed to the operation panel 13 and extended to the position of the second end. Furthermore, the center tube assembly 2 may be arranged to extend through the operation panel 13 at the first end, and is provided with a sulfur-containing waste liquid inlet 212 at a portion of the inner tube 21 extending out of the burner cylinder 1, an atomizing wind inlet 221 at a portion of the intermediate tube 22 extending out of the burner cylinder 1, and a fuel gas inlet 232 at a portion of the outer tube 23 extending out of the burner cylinder 1, respectively. In this case, the combustion air inlet 11 may be provided on the side wall of the burner cylinder 1, thereby facilitating the rational arrangement of the parts.
Further, the operation panel 13 is mounted with a flame detector 14 and/or a flame viewing hole 15 so as to directly monitor the combustion condition at the fuel gas burner 231 by a sensor or a person. Wherein the number of flame detectors 14 is not less than two, such as three.
In the above-mentioned burner, the waste liquid nozzle 211 may be made of silicon carbide, alloy 20 (Alloy 20) or 904L; the fuel gas burner 231 may be made of stainless steel such as 310S, 304 or 316; the material of the burner cylinder 1 is preferably carbon steel or stainless steel, preferably 304 stainless steel. The inner tube 21 of the central tube assembly 2 may be made of corrosion-resistant alloy steel, and the intermediate tube 22 and the outer tube 23 may be made of alloy steel.
The burner and the sulfur-containing waste liquid regeneration acid making device are in a special structural form, and the waste liquid nozzle is arranged at the center of the fuel gas burner, so that the waste liquid is atomized and then is sprayed into the hearth at a high speed, the generation of NO x is greatly reduced, and the burner and the sulfur-containing waste liquid regeneration acid making device are suitable for various waste sulfuric acid and sulfur-containing waste liquid high-temperature incineration acid making devices produced in industries such as chemical industry, petrochemical industry and the like.
The preferred embodiments of the present invention have been described in detail above with reference to the accompanying drawings, but the present invention is not limited thereto. Within the scope of the technical idea of the invention, a number of simple variants of the technical solution of the invention are possible, including combinations of individual specific technical features in any suitable way. The various possible combinations of the invention are not described in detail in order to avoid unnecessary repetition. Such simple variations and combinations are likewise to be regarded as being within the scope of the present disclosure.

Claims (10)

1. A burner for a sulfur-containing waste liquid regeneration acid making device, comprising:
A burner cylinder (1), the burner cylinder (1) having a first end and a second end opposite to each other, and being provided with a combustion air inlet (11) communicating to the second end through an inner cavity of the burner cylinder (1) and an ignition device (12) arranged at the second end;
A central tube assembly (2), the central tube assembly (2) extending from the first end to the second end along the central line of the burner cylinder (1) and comprising an inner tube (21), a middle tube (22) and an outer tube (23) coaxially arranged from inside to outside, so as to define a sulfur-containing waste liquid channel in the inner tube (21), an atomized wind channel between the inner tube (21) and the middle tube (22) and a fuel gas channel between the middle tube (22) and the outer tube (23), a waste liquid nozzle (211) being arranged at the free end of the inner tube (21) at the second end, and the fuel gas conveyed by the fuel gas channel being capable of burning at the position where the waste liquid nozzle (211) ejects sulfur-containing waste liquid to generate a combustion flame.
2. Burner for a sour device for regeneration of sulphur-containing waste liquid according to claim 1, characterized in that a swirl plate (3) for guiding the flow of combustion air in a spiral towards the second end is arranged in the space between the centre tube assembly (2) and the burner cylinder (1).
3. Burner for a sour plant for regeneration of sulphur-containing waste liquids according to claim 1, characterized in that the second end of the burner cylinder (1) is connected with a flame stabilizing cap (4) arranged around the central tube assembly (2).
4. The burner for a sulfur-containing waste liquid regenerating acid generator of claim 1, wherein an end of the fuel gas channel near the waste liquid nozzle (211) is provided with a plurality of fuel gas burners (231) arranged around the waste liquid nozzle (211).
5. Burner for a sour device for regeneration of waste sulphur liquid according to claim 1, characterized in that the first end of the burner cylinder (1) is provided with an operating panel (13), through which operating panel (13) the inner tube (21), intermediate tube (22) and outer tube (23) extend and are provided with a waste sulphur liquid inlet (212), an atomized wind inlet (221) and a fuel gas inlet (232) respectively in the portion extending outside the burner cylinder (1).
6. The burner for a sulfur-containing waste liquid regeneration acid generator according to claim 5, wherein the combustion air inlet (11) is provided on a side wall of the burner cylinder (1).
7. The burner for a sulfur-containing waste liquid regenerating acid generator as set forth in claim 5, wherein a flame detector (14) and/or a flame viewing hole (15) are mounted on the operation panel (13).
8. A sour apparatus for regenerating sour liquid from a sour liquid comprising a combustion furnace and a burner according to any one of claims 1 to 7, the burner being connected to the combustion furnace and being connected such that the second end is directed towards or within the furnace chamber of the combustion furnace.
9. A method for regenerating a sulfuric waste liquid to prepare an acid, characterized by using the apparatus for regenerating a sulfuric waste liquid to prepare an acid according to claim 8, wherein the sulfuric waste liquid is transported through the sulfur waste liquid channel, and the sulfuric waste liquid contains at least one of sulfuric acid, sulfurous acid, ammonium sulfate, ammonium bisulfate, sodium sulfate, potassium sulfate, and ammonium sulfite.
10. The method for regenerating an acid from a sulfur-containing waste liquid according to claim 9, wherein the pressure of the atomized wind outputted from the atomized wind channel is not less than 0.3MPa.
CN202211267417.5A 2022-10-17 2022-10-17 Sulfur-containing waste liquid regeneration acid production device and method and burner for same Pending CN117906147A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202211267417.5A CN117906147A (en) 2022-10-17 2022-10-17 Sulfur-containing waste liquid regeneration acid production device and method and burner for same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211267417.5A CN117906147A (en) 2022-10-17 2022-10-17 Sulfur-containing waste liquid regeneration acid production device and method and burner for same

Publications (1)

Publication Number Publication Date
CN117906147A true CN117906147A (en) 2024-04-19

Family

ID=90680817

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202211267417.5A Pending CN117906147A (en) 2022-10-17 2022-10-17 Sulfur-containing waste liquid regeneration acid production device and method and burner for same

Country Status (1)

Country Link
CN (1) CN117906147A (en)

Similar Documents

Publication Publication Date Title
EP0388886B1 (en) Method of burning a premixed gas and a combustor for practicing the method
US4035137A (en) Burner unit
US7062917B2 (en) Combustion chamber with flameless oxidation
CN104633655A (en) Ultra-low nitrogen oxide combustion apparatus using internal recirculation of combustion gas and method therefor
CN107514644B (en) Dinitrogen tetroxide/Hydrazine propellant waste gas and liquids treatment burner and control method
CN1878987A (en) Combustor for gas turbine
CN218993423U (en) Incineration device and incineration system
US6893255B2 (en) Spray burner for the thermal decomposition of sulphur-containing residues
US7521035B1 (en) Method for regenerating a residual substance that contains sulfur and an atomizing burner suited for carrying out said method
CN101644434A (en) Burner of tail gas burning furnace of sulfur recovery device
CN117906147A (en) Sulfur-containing waste liquid regeneration acid production device and method and burner for same
CN205174397U (en) A incineration disposal system for HPF waste liquid
CN114110618B (en) Combustion device for treating acrylonitrile wastewater
CN215951445U (en) Waste liquid incinerator system
CN213513915U (en) High-efficient sulphur waste liquid that contains burns burning furnace
CN212362015U (en) Composite combustion system with acid gas and fuel gas spray gun
KR100231975B1 (en) Two stage nozzle for reducing nox
JPH0336409A (en) Low nox burner
CN220379691U (en) Nitrile chemical industry high nitrogen organic waste gas waste liquid burns burning furnace
CN215982605U (en) Low-nitrogen incomplete regeneration flue gas incineration system
CN219713386U (en) Rotational flow mixed type waste gas incinerator
CN211575912U (en) Equipment for reducing emission of nitrogen oxides in rotary kiln
CN219713352U (en) Combustor for ammonia-containing tail gas incinerator for sulfur recovery device
CN220471634U (en) Combined incineration device for acrylonitrile waste gas and waste liquid
CN217785134U (en) Stable combustion spray gun for side wall burner of cracking furnace

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination