CN117794372A - Method for controlling pests on tea trees - Google Patents

Method for controlling pests on tea trees Download PDF

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Publication number
CN117794372A
CN117794372A CN202280053990.8A CN202280053990A CN117794372A CN 117794372 A CN117794372 A CN 117794372A CN 202280053990 A CN202280053990 A CN 202280053990A CN 117794372 A CN117794372 A CN 117794372A
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China
Prior art keywords
methyl
active ingredient
pesticidal composition
per hectare
ethyl
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CN202280053990.8A
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Chinese (zh)
Inventor
船田刚玄
柳田优一
小笠原宏实
森本辉一
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Syngenta Crop Protection AG Switzerland
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Syngenta Crop Protection AG Switzerland
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Publication of CN117794372A publication Critical patent/CN117794372A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/04—Insecticides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof

Abstract

A method of controlling insect pests on tea trees, the method comprising applying to the canopy spray of tea trees a pesticidal composition comprising methylpiperidine ethyl, spirotetramat, spirodiclofen, spiromesifen or dispiro as an insecticidal active ingredient.

Description

Method for controlling pests on tea trees
The present invention relates generally to the use of certain compounds as pesticidally Active Ingredients (AI) in methods of application to camellia species, and in particular to camellia sinensis (Camellia sinensis). Tea is a globally important crop, particularly in many areas of east and south asia, growing many different varieties that may be vulnerable to insect pests, often resulting in significant commercial costs. The compounds used according to the invention belong to IRAC MoA classification 23, referring to inhibitors of acetyl-coa carboxylase (accase) inhibitors, such as methoxypiperidine ethyl, spirotetramat, spiromesifen and spirodiclofen.
Methoxypiperidine ethyl (CAS number: 1229023-00-0) is known to be effective for controlling insect pests, including so-called piercing insect pests such as aphids, whiteflies, scale insects and mites, and is described in particular in WO 2010/066780, WO 2018/114648 and WO 2018/114649. Pesticide formulations comprising methoxypiperidine ethyl are described in WO 2020/208098. Spirotetramat (CAS number 203313-25-1) is described in particular in WO 98/05638 and WO 2004/007472. Spiromesifen (CAS number: 283594-90-1) and spirodiclofen (CAS number: 148477-71-8) are described in particular in EP 0 528 156. Other active ingredient compounds include the dispiro worm (spidoxamat) (CAS number 907187-07-9), which is disclosed in WO 2006/089633, among others.
The spray application of a pesticidal composition to tea trees to achieve total plant coverage is often hindered by thick canopy layers of plant leaves. The canopy acts as a physical barrier limiting the effective application to the stems (trunk) or shoots, which may in fact be the main habitat for insect pests such as scale insects.
In fact, this problem can be at least partially overcome by washing the active ingredient spray composition through the canopy and into the more inaccessible parts below the plant canopy. The disadvantage of this approach is that a large volume (water dilution) of the pesticide composition is typically required to fully cover the plant crop. These volumes can be as much as 10,000 liters per hectare (L/ha) or more and thus lead to undesirably high water demands. Also, in order for spray application to be effective, the spray applicator (e.g., tea house worker) needs to exert more physical effort to reach difficult to access parts of the plant below the leaf cap with the spray equipment.
It has now surprisingly been found that highly effective control of certain pests such as scale insects can be achieved by applying the pesticidal composition only to the canopy (foliar portion) of the tea tree and not specifically to the trunk, branch or stem of the plant. This method (i) allows much less water to be used for effective pest killing spray treatment in the tea house, and (ii) avoids the need for pest killing spray application under the leaf cap for effective control treatment, and is therefore a less labor intensive method.
According to the present invention there is provided a method of controlling insect pests on tea trees, the method comprising applying to the canopy spray of tea trees a pesticidal composition comprising an insecticidal active ingredient selected from the group consisting of ethylparaben, spirotetramat, spirodiclofen, spiromesifen or dispiro.
In the methods of the invention, spray application preferably (substantially) avoids application of the pesticidal composition to non-foliar parts (trunk, shoots, stems, roots) of the tea tree.
The methods of the invention may be used for therapeutic or prophylactic control of insect pests.
Preferably, the active ingredient is methoxypiperidine ethyl or spirotetramat. Most preferably, the active ingredient is methoxypiperidine ethyl ester.
Typically, the active ingredient, such as methylpiperidine ethyl ester, is applied as a liquid composition further comprising one or more agrochemically acceptable diluents or carriers. Preferably, the liquid composition is a dilution of a concentrated active ingredient composition (e.g., a Suspension Concentrate (SC) formulation, such as SC100 or SC 300) in water. The liquid composition may comprise an adjuvant (intramolecular adjuvant or tank mix adjuvant), preferably an adjuvant selected from mineral oil, vegetable oil or trans-esterified vegetable oil.
Examples of classes of adjuvants that may be used according to the invention include mineral oils, vegetable oils, esterified vegetable oils, methylated vegetable oils or alkyl phosphate-based adjuvants. Commercially available adjuvant products that can be tank-mixed with the compositions of the present invention to produce spray formulations include HASTEN TM (Victoria chemical Co., ltd (Victorian Chemical Co. Pty. Ltd.) -blend of esterified vegetable oil and nonionic surfactant),(Syngenta) -alkyl phosphate (EC formulation), LEDNA TM (Polaquimia company-EC formulation comprising methyl soyate), tel>463 (Heda European Co., ltd (CRODA Europe Limited) -60% blend of paraffinic oil and surfactant),B (Bayer AG) -rapeseed oil methyl ester (esterified vegetable oil)), -/->HC (Winfield Solutions Co., ltd. -methylated soybean oil), DYNE-/and a method for producing the same>(blend of HELENA company- (methylated) vegetable oil and organosilicone-based nonionic surfactant), and FS Optique TM (growmak company-canola oil methyl ester).
Preferably, the tea tree is a wild tea tree.
Preferably, the pest is a scale insect. In particular Sang Bai (Sang Baidun mealy bugs (Pseudaulacaspis pentagona)) or mealy bugs (Ceroplastes ceriferus)). Most preferably, the pest is Sang Bai.
The spray application volume of the pesticidal composition per hectare is preferably in the range of 100 to 5000 litres per hectare (L/ha), more preferably in the range of 200 to 4000 litres per hectare (L/ha), and still more preferably in the range of 500 to 1500 litres per hectare (L/ha).
Preferably, the application rate of the active ingredient according to the invention (such as methoxypiperidine ethyl ester) may be a rate of 500 to 2000 grams per hectare, and preferably a rate of 1000 to 1500 grams per hectare.
Preferably, the application is as a single treatment performed before the onset of infestation by the insect pest, for example 7 to 28 Days (DBI) before infestation or more preferably 14 to 21 days before infestation.
Controlling insect pests according to the present invention means in particular killing such insect pests, delaying the growth or reproduction of the insects, reducing the insect population, and/or reducing the damage to the plants caused by the insects.
Preferably, the active ingredient (such as methoxypiperidine ethyl ester) is used according to the invention as the sole pesticidally active ingredient in a pesticidally composition. However, it may also be used in combination with one or more additional pesticidal (insecticidal, acaricidal or nematicidal) active ingredients in the same composition or in separate compositions. This may include pesticidally active ingredient compositions comprising methoxypiperidine ethyl ester (denoted "(I)") and another active ingredient as follows:
The adjuvant-containing composition comprises (I) +a compound selected from the group of substances consisting of petroleum.
A composition comprising a acaricide comprising: (I) +1, 1-bis (4-chlorophenyl) -2-ethoxyethanol, (I) +2, 4-dichlorophenyl benzenesulfonate, (I) +2-fluoro-N-methyl-N-1-naphthaleneacetamide, (I) +4-chlorophenyl phenylsulfone, (I) +avermectin, (I) +methoquinone, (I) +acetylchlorfenapyr, (I) +flumethrin, (I) +aldicarb, (I) +cis-cypermethrin, (I) +racefruit, (I) +sulfamate, (I) +fruit-filling phosphorus, (I) +amine phosphorus, I) +hydrogen oxalate amine phosphorus (I) +amitraz, (I) +acaricide, (I) +arsenic trioxide, (I) +AVI 382, (I) +AZ 60541, (I) +yigossyphos, (I) +bazophos (azinphos-methyl), (I) +azobenzene, (I) +azocyclotin, (I) +azophos (azomethionate), (I) +benomyl, (I) +benno Sha Lin (benoxafos), (I) +benacarid, (I) +benzyl benzoate, (I) +bifenazate, (I) +bifenthrin, (I) +le acaricide, (I) +deltamethrin, (I) +bromenemie, (I) +bromethion, (I) +ethylbromethion, (I) +bromester, (I) +buprofezin, (I) +carbofuran, (I) +butanone sulfone, (I) +butyl pyridaben, (I) +calcium polysulfide, (I) +octachlorocamphene, (I) +chlorfenapyr, (I) +carbaryl, (I) +carbofuran, (I) +trisulfide, (I) +CGA 50'439, (I) +miticide, (I) +miticidal ether, (I) +acetamiprid hydrochloride, (I) +chlorfenapyr chlor (I) +acaricidal alcohol, (I) +acaricidal ester, (I) +dichlormite, (I) +chlorfenphos, (I) +ethyl acaricidal alcohol, (I) +chlormebutform, (I) +chlorpyrifos, (I) +propyl ester acaricidal alcohol, (I) +chlorpyrifos, (I) +methyl chlorpyrifos, (I) +chlorfenuron, (I) +fenprox I, (I) +guathrin II, (I) +guathrin, (I) +tetramite, I) +clofentezine, (I) +coumaphos, (I) +clomiphos, (I) +clomipide, (I) +bazophos, (I) +thiabendazole, (I) +cyflumetofen, (I) +cyhalothrin, (I) +tricyclotin, (I) +cyhalothrin, (I) +DCPM, (I) +DDT, (I) + Tian Le phosphorus, (I) +tebufos-O, (I) +tebufos-S, (I) +varfop-methyl, (I) +varfop-O-methyl, (I) +varfop-S-methyl, (I) +sulfon, (I) +chlorfenuron, (I) +chlorimfos thiotepa (I) +diazinon, (I) +dichlorvos, (I) +dicarphos, (I) +kai Le San, (I) +paratefosine, (I) +descarboline, (I) +meflofos, (I) +dimethoate, (I) +diasporin, (I) +detritol (dinex), (I) +detritol (dinex-dicyclenine), (I) +detriton (dinobuton), (I) +dichlorprop-4, (I) +dichlorprop-6, (I) +adjacent dichlorprop-eliminating, (I) +nitropentyl ester, (I) +nitrooctyl ester, (I) +nitrobutyl ester, (I) +dichlorphos, (I) +sulfodiphenyl, (I) +alcohol-stopping sulfur, (I) +ethiprole, (I) +DNOC, (I) +phenoxypropargite (dofenapyn), (I) +doragliptin, (I) +thiodan, (I) +phoxim, (I) +EPN, (I) +irinotecan, (I) +ethionine, (I) +yithiaphos, (I) +etoxazole, (I) +ethionine, (I) +anti-fenbuconazole, (I) +fenazate, (I) +fenbucin, (I) +phenyltin, (I) +benfuracarb, (I) +fenpropathrin tebufenpyrad (I) +tebufenpyrad (I) +fenpyroximate (fenitrothion) (I) +flunifedipine (fenrifanil) (I) +fenvalerate (I) +fipronil (I) +azoxystrobin (I) +pyrifos (I) +flufenpyrad (I) +flufluflufenuron (I) +flufenvalerate (I) +flufenprox (I) +flufenuron (I) +flufenthrinate (I) +flufenitrothion (I) +FMC 1137), (I) +valicarb (I) +amomum (formothion), (I) +carboximide (formaranate), (I) +gamma-HCH, (I) +valicarb (I) +benzyl fenpiceatin, (I) +heptenophos (heptenophos), (I) +cetyl cyclopropane carboxylate, (I) +hexythiazox, (I) +methyl iodide, (I) +fenpyrad, (I) +isopropyl O- (methoxyaminothiophosphoryl) salicylate, (I) +ivermectin, (I) +jasmine I, (I) +jasmine II) (I) +iodiphos, (I) +lindane, (I) +lufenuron, (I) +malathion, (I) +propargite, (I) +aphphos, (I) +dithiine, (I) +methirofen, (I) +chlorfenphos, (I) +methamidophos, (I) +methidathion, (I) +methomyl, (I) +bromomethane, (I) +fast mevalonate, (I) +from carbofuran, (I) +fenacet fenacet, (I) +milbeoxime, (I) +propylamine fluorine, (I) +penoxsulam, (I) +I) +cyclon, (I) +moxidectin, (I) +dibromophosphorus (naled), (I) +NC-184, (I) +NC-512, (I) +flumetsulam, (I) +nikkomycin, (I) +pentacarb 1:1 zinc chloride complex, (I) +NNI-0101, (I) +NNI-0250, (I) +omethoate, (I) +oxamyl, (I) +phosphorous for the same, (I) +sulfone for the same, (I) +pp' -DDT, (I) +parathion, (I) +permethrin, (I) +petroleum, (I) +fenphos fenphos, (I) +fenphos, fenfenfenphos (I) +dafenphos) (I) +mevalonate, (I) +fuzophos, (I) +thiocyclophos, (I) +iminothiophos, (I) +phosphamide, (I) +phoxim, (I) +pyrimidone-methyl, (I) +turpentine (polychlorotrpenes) chloride, (I) +acaricidal, (I) +prochlorphos, (I) +profenofos, (I) +tick louse, (I) +propargite, (I) +fenpropiphos, (I) +propoxur, (I) +ethionamide, (I) +thiophos, (I) +pyrethrin I, (I) +pyrethrin II, (I) Pyrethrin, (I) +pyridaben, (I) +pyridaphethione, (I) +pyriminostrobin, (I) +quinalphos, (quintiofos), (I) +R-1492, (I) +RA-17, (I) +rotenone, (I) +octamethyl, (I) +clarinone, (I) +selacin, (I) +SI-0009, (I) + Su Liu phosphorus, (I) +spirodiclofen, (I) +spiromesifen, (I) +SSI-121, (I) + Shu Feilun, (I) +flufenacet flufenamid (I) +Titepu, (I) +sulfur, (I) + SZI-121, (I) +tau-fluvalinate, (I) +tepp, (I) +t-carbofuran (terbam), (I) +set Luo Lin, (I) +tetrachlorfon sulfone, (I) +acaricidal effect, (I) +thiafenozide, (I) +anti-carbofuran, (I) +monocarb, (I) +methyl etop, (I) +g acaricide, (I) +threomycin, (I) +weifenphos, (I) +fenbenfurazolidone, I) +triazophos, (I) +trichloraz, (I) +trichlorfon, (I) +triclopyr, (I) +trioxyphos, (I) +triazocine, (I) +aphididol, (I) +tolfenpyr (vaniliprole) and (I) +yi-5302.
A composition comprising an anthelmintic agent comprising: (I) +avermectin, (I) +clathrfos, (I) +doramectin, (I) +emamectin benzoate, (I) +eprinomectin, (I) +ivermectin, (I) +milbexime, (I) +moxidectin, (I) +piperazine, (I) +selamectin, (I) +spinosad, and (I) +thiophanate.
A composition comprising a bird repellent comprising: (I) +chloraldose, (I) +isodieldrin, (I) +phoxim, (I) +pyridin-4-amine, and (I) +strychnine.
The composition comprising a biocontrol agent comprises: (I) +Heterophasus gossypii GV, (I) +Agrobacterium radiobacter, (I) +Amblyseius species, (I) +Apium graveolens NPV, (I) +Oenanthes Javanica Litsea, anagrus praecox, anagrus atomus, and (I) +Aphis brachycus (Aphelinus abdominalis), and (I) +Aphis gossypii parasitic wasp (Aphidius colemani), (I) +Aphis aphis eating, and (Aphidoletes aphidimyza), (I) +Aphis medicinalis NPV, (I) +Bacillus firmus, (I) +Bacillus sphaericus, (I) +Bacillus thuringiensis (Bacillus thuringiensis Berliner), (I) +Bacillus thuringiensis catze subspecies (subsp. Aizawai), and (I) +Bacillus thuringiensis subspecies (subsp. Israens) (I) +Bacillus thuringiensis subspecies (subsp. Japoniensis), (I) +Bacillus thuringiensis subspecies (subsp. Kurstaki), (I) +Bacillus thuringiensis subspecies (subsp. Tenebrionis), (I) +Beauveria bassiana (Beauveria bassiana), (I) +Beauveria bassiana (Beauveria brongniartii), (I) +Phaeopa albosis (Chrysoperla carnea), (I) +Cryptophanus monte (Cryptolaemus montrouzieri), (I) +codling moth GV, (I) +Siberian off-jaw cocoon bee (Dacnna sibirica), (I) +Pisum sativum She Yingji small bees (Diglyphus isaea), (I) +Aphis citrifolia (Encarsia for mosa), (I) +Metarhizium anisopliae (Eretmocerus eremicus), (I) +Metarhizium anisopliae NPV, (I) +Metarhizium anisopliae (Heterorhabditis bacteriophora) and Metarhizium grandis (H.megdis), (I) +Metarhizium maculatum (Hippodamia convergens), (I) +Georgia parasitic bees (Leptomastix dactylopii), (I) +Aphis lygus (Macrolophus caliginosus), (I) +caulis et folium Brassicae Capitate NPV, (I) + Huang Kuobing flea (Metaphycus helvolus), (I) +Metarhizium anisopliae (Metarhizium anisopliae var. Acridum), (I) +Metarhizium anisopliae variant (Metarhizium anisopliae var. Aniopsis e), (I) +European new pine leaf spring (Neodiprion sertifer) NPV and Metarhizium erythropolis (N.lecontei) NPV, (I) +Lepidium species, (I) +Mesoyabean nematode (4635), (I) +Leideas) and (35), (I) + (35) and (I) +Leideas-35) and (I) + (3295) Pbwegiardia sp (I) + s.species (Steinernema spp.), (I) +trichogramma species, (I) +western blind spider mites (Typhlodromus occidentalis), and (I) +verticillium lecanii (Verticillium lecanii).
A composition comprising a soil disinfectant comprising: (I) +methyl iodide and methyl bromide.
A composition comprising a chemosterilant comprising: (I) +azolephosphazene (apholate), (I) +bis (aziridine) methylaminophosphine sulfide (bisazir), (I) +busulfan, (I) +diflubenzuron, (I) +dimetif (dimatif), (I) +altretamine (hemel), (I) +hexamethophos (hempa), (I) +methylaldimine (metapa), (I) +methylthioaldimine (metathia), (I) +methylphosphinazine (methyl), (I) +infertility (morzid), (I) +fluvaluron (penfluron), (I) +aldimine (tepa), (I) +thiohexamethylphosphorus (thiohempa), (I) +thioaldimine, (I) +triazamine and (I) +urethane imine.
A composition comprising an insect pheromone comprising: (I) (E) -dec-5-en-1-yl acetate and (E) -dec-5-en-1-yl acetate, (I) + (E) -tridec-4-en-1-yl acetate, (I) + (E) -6-methylhept-2-en-4-ol, (I) + (E, Z) -tetradec-4, 10-dien-1-yl acetate, (I) + (Z) -dodeca-7-en-1-yl acetate, (I) + (Z) -hexadec-11-enal, (I) + (Z) -hexadec-11-en-1-yl acetate, (I) + (Z) -hexadec-13-en-11-yn-1-yl acetate, (I) + (Z) -eicos-13-en-10-one, (I) + (Z) -tetradec-7-en-1-al, (I) + (Z) -tetradec-9-en-1-ol, (I) + (Z) -tetradec-9-en-1-yl acetate, (I) (7E, 9Z) -dodeca-7, 9-dien-1-yl acetate, (I) + (9Z, 11E) -tetradec-9, 11-dien-1-yl acetate, (I) + (9Z, 12E) -tetradec-9, 12-dien-1-yl acetate, (I) +14-methyl octadeca-1-ene, (I) +4-methyl non-5-ol and 4-methyl non-5-one, (I) +alpha-strin, (I) +Cethon bark beetle congregation pheromone, (I) +dodecadienol (codlemore), (I) +can obtain Mongolin (codlemone) (I) +cyromazine (cure), (I) +epoxynonadecane, (I) +dode-8-en-1-yl acetate, (I) +dode-9-en-1-yl acetate, (I) +dode-8, (I) +10-diene-1-yl acetate, (I) +cyamous attractant (dominure), (I) +4-methyl ethyl octoate, (I) +eugenol, (I) +cyamous collective pheromone (front in), (I) +cyamous hexadecanoate (gospypl), (I) +trapping and killing alkene mixture (granlure), (I) +trap mixture I, (I) +trap mixture II, (I) +trap mixture III, (I) +trap mixture IV, (I) +trap mixture, (hexalure), (I) +dentate dienol, (I) +small enol (ipsenol), (I) +scara sex attractant (japoniure), (I) +trimethyl dioxa tricyclononane (linetin), (I) +noctuid trap (litlure), (I) +powder noctuid trap (loop lure), (I) +trap ester (midlure), (I) + Meng Tuome g acid (megatomic), (I) +methyl eugenol, (I) +octadeca-2, 13-dien-1-yl acetate, (I) +octadeca-3, 13-dien-1-yl acetate), (I) +trimethyl tricyclononane (line), (I) +6-35-sorangin-11-tetralin, and (I) +cyantran acid (8-tetralin-IV) can aggregate with cyanuric acid (I) +methyl eugenol-tetralin (I) +Mediterranean fruit fly attractant (trimedlure), (I) +Mediterranean fruit fly attractant A, (I) +Mediterranean fruit fly attractant B1, (I) +Mediterranean fruit fly attractant B2, (I) +Mediterranean fruit fly attractant C and (I) +Chunco-call.
The insect repellent-containing composition comprises: (I) +2- (octylthio) ethanol, (I) +mosquito-repellent ketone (butyltopyroxyl), (I) +butoxy (polypropylene glycol), (I) +dibutyl adipate, (I) +dibutyl phthalate, (I) +dibutyl succinate, (I) +mosquito-repellent amine, (I) +mosquito repellent (dimethyl carbate), (I) +dimethyl phthalate, (I) +ethylhexyl glycol, (I) +hexaurea (hexamide), (I) +mequindine (methoquin-butyl), (I) +methyl neodecanoamide, (I) +oxamate) and (I) +peparylene.
The composition comprising an insecticide comprises: (I) +1-dichloro-1-nitroethane, (I) +1, 1-dichloro-2, 2-di (4-ethylphenyl) ethane, (I) +1, 2-dichloropropane with 1, 3-dichloropropene, (I) +1-bromo-2-chloroethane, (I) +2, 2-trichloro-1- (3, 4-dichlorophenyl) ethyl acetate, (I) +2, 2-ethylenesulfinylethyl methyl phosphate, (I) +2- (1, 3-dithiolane-2-yl) phenyldimethylcarbamate, (I) +2- (2-butoxyethoxy) ethylthiocyanate, (I) +2- (4, 5-dimethyl-1, 3-dioxolan-2-yl) phenylmethylcarbamate, (I) +2- (4-chloro-3, 5-xylyloxy) ethanol, (I) +2-chlorovinyldiethylphosphate, (I) +2, 2-ethylsulfinylethyl phosphate, (I) +2- (2-butoxyethoxy) phenylthiocyanic acid, (I) +2- (2-propylenemethoxy) phenylthiocyanic acid, (I) +2- (4-chloro-3, 5-xylyloxy) ethanol (I) +3-bromo-1-chloroproprop-1-ene, (I) +3-methyl-1-phenylpyrazol-5-yl dimethylcarbamate, (I) +4-methyl (prop-2-ynyl) amino-3, 5-xylylmethylcarbamate, (I) +5, 5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate, (I) +avermectin, (I) +acephate, (I) +acetamiprid, (I) +acephate, (I) +acetylfipronil, (I) +fipronil, (I) +acrylonitrile, (I) +cotton bollwire, I) +cotton bollwire (I) +aldicarb, (I) +Ainsliaea, (I) +propylene pyrethrin, (I) +alommon, (I) +carbofuran, (I) +cis-cypermethrin, (I) +alpha-ecdysone, (I) +aluminum phosphide, (I) +racing fruit, (I) +methomyl, (I) +amine phosphorus absorber, (I) +hydrogen oxalate amine phosphorus absorber, (I) +amitraz, (I) +anabine, (I) +anabasine, (I) +ethyl methidathion, (I) +AVI 382, (I) +AZ 60541), (I) +azadirachtin, (I) +picoline phosphorus, (I) +yigossyphos, (I) +baoshos, (I) +azophos, (I) +bacillus thuringiensis delta-endotoxin, (I) +barium hexafluorosilicate, (I) +barium polysulfide, (I) +fumigating pyrethrin, (I) +Bayer 22/190, (I) +Bayer 22408, (I) +oxamyl, (I) +benfuracarb, (I) +monosulfo, (I) +beta-cyhalothrin, (I) +bifenthrin, (I) +bioallethrin, alpha-allethrin (I) +biological allyl pyrethroid S-cyclopentenyl isomer, (I) +pencythrin (bioethane method), biological permethrin, (I) +biological permethrin, (I) +bis (2-chloroethyl) ether, (I) +bis (trifluoracer, (I) +borax, (I) +deltamethrin, (I) +bromophenphos, (I) +bromoene, bromine-DDT, (I) +bromophos-ethyl, (I) +carbofuran, (I) +buprofezin, (I) +benflumetcarb, (I) +terfenacet, (I) +terfenamiphos (busulfos), (I) +carbofuran, (I) +butylphosphorus, (I) +carbosulfone, (I) +butylpyridalyl, (I) +thiotepa, (I) +calcium arsenate, (I) +calcium cyanide, (I) +calcium polysulfide, (I) +octachlorocamphene, (I) +chlorcarbofuran, (I) +carbaryl, (I) +carbofuran, (I) +carbon disulfide, (I) +carbon tetrachloride, (I) +trisulfide, (I) +carbosulfan, (I) +bardane hydrochloride, (I) +celebrine, (I) +borneol dane (I) +chlordane, (I) +chlordecachlorone, (I) +chlordimidine, (I) +chlordimeform hydrochloride, (I) +chlorpyrifos, (I) +chlorfenapyr, (I) +chlorpyrifos, (I) +chloroform, (I) +chlorpicrin, (I) +chlornitrile oxime phosphorus, (I) +chlorzophos, (I) +chlorpyrifos-methyl, (I) +chlorfenphos, (I) +chromafenozide, (I) +fenbufenprox I, (I) +guathrin II, (I) +guathrin, chlorfenuron, (I) +cis-bifenthrin (cis-resmethrin), (I) +cis-bifenthrin (cismithrin), (I) +fenvalerate (cloythrin), (I) +desmethylwire (C) (I) +clofentezine, (I) +clothianidin, (I) +copper acetylarsenite, (I) +copper arsenate, (I) +copper oleate, (I) +coumaphos, (I) +clomiphos, (I) +bafivelphos, (I) +cyphos, (I) +cryolite, (I) +CS 708, (I) +benzonitrile phosphorus, (I) +cartap-in (I) +cyromazine, (I) +cyclothrin, (I) +pyrethroid, (I) +cyfluthrin, (I) +cyhalothrin, (I) +cyfenthrin, (I) +cyromazine, (I) +d-limonene, (I) +d-tetramethrin, (I) +DAEP, (I) +dazomet, (I) +DDT, (I) +desmethylcarbofuran, (I) +deltamethrin, (I) + Tian Le phosphorus, (I) +tebufos-O, (I) +tebufos-S, (I) +Neoprene, (I) +Neoprene-methyl, (I) +Neoprene-O-methyl, (I) +Neoprene-S-methyl, (I) +sulfone (dimet-S-methyl-ulfon), (I) +chlorfenuron, (I) +chlorimfos, (I) +Deline (diamidafos), (I) +diazinon, (I) +isochlorophos, (I) +line-removing phosphorus, (I) +dichlorvos, (I) +dicarboxyphosphos, (I) +dicaryos), (I) +dicumyl (dicaryyl) (I) +baizhephosph, (I) +dicycloprid, (I) +Di' S reagent, (I) +diethyl 5-methylpyrazol-3-yl phosphate, (I) +diflubenzuron, (I) +asthma (dilor), (I) +tetrafluoromethyl ether pyrethrin, (I) +meflofos, (I) +dimchip, (I) +dimethoate, (I) +permethrin, (I) +methylparaben, (I) +dichlorvos, (I) +fenpyrad, (I) +dimetol (dinex), (I) +dimetol (dinex-dichlexine), (I) +prochlorpol, (I) +pentanitol, (I) +dinotefuran, (I) +benomyl, (I) +vegetable and fruit phosphorus, (I) +dioxycarb, (I) +dichlorphos, (I) +ethafos, (I) +thiopyran phosphorus, (I) +DNOC, (I) +doratiptin, (I) +DSP, (I) +ecdysterone, (I) +EI 1642, (I) +emamectin benzoate, (I) +EMPC, (I) +dextromethorphan, (I) +thiodan, (I) +dupone, (I) +isophos, (I) +isodir, (I) +EPBP, (I) +EPN the preparation method comprises the following steps of (I) +juvenile ether, (I) +eprinomectin, (I) +fenvalerate, (I) +oxforn county propylthiophos (ethohos), (I) +ethiophencarb, (I) +ethion, (I) +ethiprole, (I) +ethion, (I) +valphos, (I) +ethyl formate, (I) +ethyl-DDD, (I) +dibromoethane, (I) +dichloroethane, (I) +ethylene oxide, (I) +ethofenprox, (I) +ethion, (I) +EXD, (I) +valvaphos, (I) +benfophos (fenamiphos), (I) Fenpyrad, (I) +cyromazine, (I) +ethylbenzene carb, (I) +penflufen, (I) +fenitrothion, (I) +fenobucarb, (I) +oxamidine (fenoxacrim), (I) +fenoxycarb, (I) +cyhalothrin, (I) +fenpropathrin, (I) +tebufenpyrad, (I) +fenphos, (I) +ethyl phoxim, (I) +fenvalerate, (I) +fipronil, (I) +flonicamid, (I) +flubendiamide, (I) +fluclouron (flufururon) (I) +flufenuron, (I) +flufenvalerate, (I) +bifenate, (I) +pyrimethanil, (I) +flufenuron, (I) +trifluralin, (I) +flumethrin, (I) +flufenthrinate, (I) +FMC 1137, (I) +dinotefuran, (I) +valproate hydrochloride, (I) +amomum fruit, (I) +carbofuran (formaranate), (I) +fenbufos (I) +fosaprylate, (I) +fosthiazate, (I) +buthion phoaphos (fosthiazate), (I) +furofilan, (I) The composition comprises (I) fenhexaflumuron, (I) +gamma-cyhalothrin, (I) +gamma-HCH, (I) +biguanide octyl salt (guazatine), (I) +biguanide octyl acetate, (I) +GY-81, (I) +benzyl acarfen, (I) +chlorantraniliprole, (I) +HCH, (I) +HEOD, (I) +heptachlor, (I) +heptylphosphine, (I) +fashion, (I) +hexaflumuron, (I) +HHHDN, (I) +flumetzon, (I) +hydrogen cyanide, (I) +nitenpyram, (I) +quinoline carb, (I) +imidacloprid, (I) +propathrin indoxacarb (I) +methyl iodide (I) +IPSP (I) +chlorzofos (isazofos), (I) +carbochlor (I) +fenpyrad (isocycloseram), (I) +isoalien, (I) +isosalazine, (I) +transplanting agent, (I) +isoprocarb, (I) +O- (methoxyaminothiophosphoryl) isopropyl salicylate, (I) +isoprothiolane, (I) +isozophos, (I) +oxazolphos, (I) +ivermectin, (I) +jasmine I, (I) +jasmine pyrethroid II, (I) +iodiphos, (I) +juvenile hormone I, (I) +juvenile hormone II, (I) +juvenile hormone III, (I) +chlorovaleric acid, (I) +enworm alkyne, (I) +lambda-cyhalothrin, (I) +lead arsenate, (I) +lepidopterin, (I) +bromophenzophos, (I) +lindane, (I) +acetamiprid, (I) +lufenuron, (I) +fosthiazate, (I) +m-isopropylphenyl methyl carbamate, (I) +magnesium phosphide, (I) +malathion I) +propargite, (I) +azidothion, lead arsenical (I) +aphphos, (I) +methyl aphphos, (I) +aphphos, (I) +dithiine, (I) +mercurous chloride, (I) +methyl sulfoxide phosphorus, (I) +metaflumizone, (I) +metam potassium salt, (I) +metam sodium salt, (I) +chlorfenphos, (I) +methamidophos, (I) +methylsulfonyl fluoride, (I) +methidathion, (I) +methoprene, (I) +butamine phosphorus, (I) +methoprene, (I) +mequin, (I) +methoprene, methyl ether pyrethrin, (I) +methoxyl dropwort, (I) +methoxyfenozide, (I) +bromomethane, (I) +methyl isothiocyanate, (I) +methyl chloroform, (I) +methylene dichloride, (I) +methoxyl bifenthrin, (I) +fast carbofuran, (I) +oxadiazon, (I) +fast-speed phos, (I) +autotrophic, I) +fenacet, (I) +milbexime, (I) +propylamine fluoride, (I) +fenamidone, (I) +monocrotophos, (I) +mukutin, (I) +moxidectin, (I) +nepeptid phosphorus, I) +napeptid phosphorus (I) +dibromophosphorus (naled), (I) +naphthalene, (I) +NC-170, (I) +NC-184, (I) +nicotine sulfate, (I) +flumetsulam, (I) +nitenpyram, (I) +pentofarb 1:1 zinc chloride complex, (I) +NNI-0101, (I) +NNI-0250, (I) +original nicotine, (I) +bisphenylfluorourea, (I) +polyfluorourea, (I) +O-5-dichloro-4-iodophenyl O-ethyl thiophosphonate, (I) +O, o-diethyl O-4-methyl-2-oxo-2H-benzopyran-7-yl thiophosphonate, (I) +O, O-diethyl O-6-methyl-2-propylpyrimidine-4-yl thiophosphonate, (I) +O, O, O ', O ' -tetrapropyldithiopyrophosphonate, (I) +oleic acid, (I) +omethoate, (I) +methiocarb, (I) +sulfoxide phosphorus, (I) +thion (I) +isonaphos, (I) +sulfone phosphorus, (I) +p ' -DDT, (I) +p-dichlorobenzene, (I) +parathion p-thiophos, (I) +methyl parathion (I) +fluvaluron (penfluvalon), (I) +pentachlorophenol, (I) +pentachloro lauric acid (I) +benzyl chlorfenphos, I) +petroleum, (I) +PH 60-38, (I) +fenphos fenphos, fenphos (I) +fenphos, triad, (I) +trifloxysulfide, (I) + (I) +methiphos methyl (I) +phophos-methyl) phophos-methyl (I) +phoxim (I) +p-methyl (I) phophos-methyl (I) +p-methyl (I) phosphorothioate (I) +I) (I) Pirimicarb, (I) +pyrimidophosphorus-ethyl, (I) +pyrimidophosphorus-methyl, (I) +polychlorinated dicyclopentadiene isomer, (I) +chlorinated turpentine (polychlorotrepens), (I) +potassium arsenite, (I) +potassium thiocyanate, (I) +propathrin, (I) +precocin I, (I) +precocin II, (I) +precocin III, (I) +amidephosphorus, (I) +profenofos, (I) +profenothrin, (I) +tick carb, (I) +fipronil, (I) +propafenofos, (I) +aminopropyl, I) +propoxur, prallethrin, I) +propoxur the composition comprises (I) +ethionamide, (I) +propylthiophosphorus, (I) +fosfop, (I) +propylfenitrothion (protriffenbute), (I) +pymetrozine, (I) +pyrazophos, (I) +tebufos, (I) +antichlorethamate, (I) +pyrethrin I, (I) +pyrethrin II, (I) +pyrethrin, (I) +pyridaben, (I) +pyridalyl, (I) +pyridaphethione, (I) +pyriminobac, (I) +pyrifos, (I) +pyriminobac pyrifos, (I) +pyrifos (quassia), (I) +quinalphos, pyrifos (quinalphos), (I) +quinalphos-methyl, (I) +tranexamin, (I) +quinalphos (quintiofos), (I) +R-1492, (I) +iodosal, (I) +benfuraline, (I) +rotenone, (I) +RU 15525, (I) +RU 25475, (I) +rynin, (I) +rimidine, (I) +sabadilla, (I) +octamephos, (I) +claritol, (I) +selacin, (I) +SI-0009, (I) +SI-0205, (I) +SI-0404, (I) +SI-0405, (I) +flusilathrin (I) +SN 72129, (I) +sodium arsenite, (I) +sodium cyanide, (I) +sodium fluoride, (I) +sodium hexafluorosilicate, (I) +sodium pentachlorobenzene oxide, (I) +sodium selenate, (I) +sodium thiocyanate, (I) + Su Liu phosphorus, (I) +spinosad, (I) +spiromesifen, (I) +spirotetramat, (I) +sulfometuron (sulcofuron), (I) +sulfometuron sodium salt (sulcofuron-sodium), (I) +fipronil, (I) +thiotepa, (I) +sulfuryl fluoride, (I) +thioprop profos, (I) +tar, (I) +tau-fluvalinate, (I) +thiamethoxam, (I) +TDE, (I) +tebufenozide, (I) +tebufenpyrad, (I) +butyl pyrimidyl phosphorus, (I) +flufenozide, (I) +tefluthrin, (I) +dithiophosphate, (I) +TEPP, (I) +cyclopentenevalinate, (I) +terbucarb, (I) +terbufos, (I) +tetrachloroethane, (I) +insecticidal avermectin, (I) +tebufenprox, (I) +theta-cypermethrin, (I) +thiacloprid, (I) +thiafenox thiamethoxam (I) +thiacloprid (I) +ticlophos (I) +bendiocarb (I) +thiocyclam oxalate (I) +thiodicarb (II) (I) +jiuwei, (I) +methyl ethyl mixed phosphorus, (I) +bendrophos, (I) +monosultap sodium (I) +threomycin, (I) +tolfenpyrad, (I) +tetrabromothrin, (I) +transfluthrin, (I) +permethrin, (I) +metaflumizone, (I) +triazophos, (triazuron), (I) +trichlorfon, (I) +isophthalos-3 (trichlorethamide-3), (I) +chlorpyrifos, (I) +triclopyr, (I) +chlorfluazuron, (I) +methomyl, (I) +methoprene, fenpyr, (I) +veratrine, (I) +XMC, (I) +methoprene, (I) +YI 5302, (I) +zeta-cypermethrin, (I) +methomyl, (I) +zetamethrin, (I) +zinc phosphide, (I) +fenpyr and Z8901, (I) +chlorfenamid, (I) +chlorfenapyr cyamide, (I) +cyazophos cyazoxystrobin, (I) +cyazofen, (I) + (I) +tebufenpyr quine, (I) +ethyl, I) +spirotetramat, (I) +I) +flufenpyr fluflufenpyr, (I) +flufenpyr I (I) +triflumfenpyr (I) +triflumtebufen.
A composition comprising a molluscicide comprising: (I) +di (tributyltin) oxide, (I) +bromoacetamide, (I) +calcium arsenate, (I) +triamcinolone acetoarsenite, (I) +copper sulfate, (I) +triphenyltin, (I) +ferric phosphate, (I) +metaldehyde, (I) +methomyl, (I) +niclosamide-ethanolamine, (I) +pentachlorophenol, (I) +sodium pentachlorobenzene oxide, (I) +thiamethocarb (tazimcarb), (I) +thiodicarb, (I) +tributyltin oxide, (I) +snail (triformrph), (I) +trimethacarb), (I) +triphenyltin acetate and triphenyltin hydroxide, (I) +pyrazolidines.
A composition comprising a nematicide comprising: (I) +AKD-3088, (I) +1, 2-dibromo-3-chloropropane, (I) +1, 2-dichloropropane and 1, 3-dichloropropene, (I) +1, 3-dichloropropene, (I) +3, 4-dichlorotetrahydrothiophene 1, 1-dioxide, (I) +3- (4-chlorophenyl) -5-methyl-rhodanin, (I) +5-methyl-6-thio-1, 3, 5-thiadiazin-3-ylacetic acid, (I) +6-isopentenylaminopurine, (I) +avermectin, (I) +acetylfipronil, (I) +cotton bolcarb, (I) +aldicarb (aldicarb) (I) +aldicarb (aldoxycarb), (I) +AZ 60541, (I) +benzothiadia (benclothiaz), (I) +benomyl, (I) +butylpyridaben (butyl pyridaben), (I) +thiotepa (cadusafos), (I) +carbofuran (carbofuran), (I) +carbon disulfide, (I) +carbosulfan, (I) +chloropicrin, (I) +chlorpyrifos, (I) +desmodromic (cloethocarb), (I) +trifluoropyridinamine (cycloobutrfulam), (I) +cytokinin, (I) +dazomet), (I) +DBCP, (I) +DCIP, (I) +desmethylte (diamidafos), (I) +desmethylphosphate (dichloFenton), (I) +dicyclophosphates (dicyclophos), (I) +doramectin, (I) +emamectin benzoate, (I) +eprinomectin, (I) +desmoprazole, (I) +dibromoethane, (I) +benaphos (fenamifos), (I) +fenpyran (fenpyrad), (I) +fenaphos, (I) +fosthiazophos (fosthiazate), (I) +bushio (fosthiazate) Furfural (I) +GY-81, (I) +fashion, (I) +iodomethane, (I) +isoamidophosphorus (isamidofos), (I) +chlorzophos (isazofos), (I) +ivermectin, (I) +agonist (kinetin), (I) +methyl triazophos (mecaphin), (I) +wei acre potassium salt, (I) +wei sodium salt, (I) +bromomethane, (I) +methyl isothiocyanate, (I) +milbexime, (I) +moxidectin, (I) +verrucaria verrucosa plaque composition, (I) +NC-184, (I) +carbofuran, (I) +methoprene, (I) +phosphamide, (I) +carbofuran (phosphacarb), (I) +claritan (sebufos), (I) +selametin, (I) +spinosad, (I) +terbucarb (terbam), (I) +terbufos), (I) +tetrachlorothiophene, (I) +thiafenox (thiafenox), (I) +carbofuran (thiazuron), (I) +triazophos (triazophos), (I) +triazophos-carbofuran (triazuron), (I) +xylenol, (I) +YI 5302 and zeatin, (I) +fluthiamethosulfone (fluensodium).
The composition comprising a potentiator comprises: (I) +2- (2-butoxyethoxy) ethyl piperonate, (I) +5- (1, 3-benzodioxol-5-yl) -3-hexylcyclohex-2-enone, (I) +farnesol with nerolidol, (I) +mb-599, (I) +mgk 264, (I) +piperonyl butoxide, (I) +synergistic aldehyde (piportal), (I) +propyl isomer, (I) +s421, (I) +synergistic powder (sesamex), (I) +sesamolin (sesamolin) and (I) +sulfoxide.
A composition comprising an animal repellent comprising: (I) Anthraquinone, (I) +chloraldose, (I) +copper naphthenate, (I) +copper king, (I) +diazinon, (I) +dicyclopentadiene, (I) +biguanide octate (guazatine), (I) +biguanide octaacetate, (I) +methomyl, (I) +pyridin-4-amine, (I) +celecoxib, (I) +carbofuran (trimethacarb), (I) +zinc naphthenate and (I) +ziram.
The additional composition comprises: (I) The composition comprises (A) fenflurafricane, (I) +cycloxaprid, (I) +fluxazine, (I) +flumetsula (fluorometoquin) and (I) +fluhexafon, (I) +penflu guanidine, (I) +plutella xylostella granulosis virus, (I) +cyroman virus (Cydia pomonella Granulosis virus), (I) + Kang Zhuangsu (harpin), (I) +imidazocyclophospha (imicyfos) and (I) +smoke bud noctuid nuclear polyhedrosis virus, (I) +Austratoside nuclear polyhedrosis virus, (I) +cotton bollworm nuclear polyhedrosis virus, (I) +flu spodoptera nuclear polyhedrosis virus, (I) +I) +plutella plutella xylostella nuclear polyhedrosis virus, (I) +pseudocerclathraustralis, (I) +p-cymene, (I) +para-flubutyramide (pyflubutyramide), (I) +fluxazophos) and (I) +fluxazophos 460 (I) +fluxafop-cyantran) and (QRza) cyantranilide (R) + -cyantran-type fluazuride (R) amide, and (alpha-fluazurid) fluazuron, and (R) fluazuron (R) amide, and (alpha-fluazuron-cyantranilide) and (R) fluazuron (I) and (I) + ((I) + -2 (, fluoxazolamide (fluxamide), cloth Luo Fani, propiconazole, tebufenpyrad (tyropyrazofluor), fluopyram (flupiride), benzpyrimoxanil (benzpyrimoxanil), etoxazole, flucycloxapride (acynoapyr) and fipronil (fluorometoquinone).
The weight ratio of methylpiperidine ethyl ester to the other pesticidally active ingredient is typically between 1000:1 and 1:100, more preferably between 500:1 and 1:100, for example between 250:1 and 1:66, between 125:1 and 1:33, between 100:1 and 1:25, between 66:1 and 1:10, between 33:1 and 1:5, between 8:1 and 1:3, and between 2:1 and 1:2.
In practice, the pesticidal composition used according to the present invention is applied as a formulation containing other formulation components known or used in the industry.
These formulations may be in different physical forms, for example, in the following forms: dusting powders, gels, wettable powders, water-dispersible granules, water-dispersible tablets, effervescent compressed tablets, emulsifiable concentrates, microemulsifyable concentrates, oil-in-water emulsions, flowable oils, aqueous dispersions, oily dispersions, suspoemulsions, capsule suspensions, emulsifiable granules, soluble liquids, water-soluble concentrates (with water or water-miscible organic solvents as a carrier), impregnated polymeric films or in other forms known, for example, from Manual on Development and Use of FAO and WHO Specifications for Pesticides [ handbook of development and use of FAO and WHO standards for pesticides ], united nations, first edition, second revision (2010). Such formulations are typically diluted prior to use. Dilution may be performed with, for example, water, liquid fertilizer, micronutrients, biological organisms, oil or solvents.
Formulations may be prepared by mixing the active ingredient with formulation adjuvants in order to obtain formulations in the form of finely divided solids, granules, solutions, dispersions or emulsions. The active ingredient may also be formulated with other adjuvants such as finely divided solids, mineral oils, oils of vegetable or animal origin, modified oils of vegetable or animal origin, organic solvents, water, surface-active substances or combinations thereof.
Formulation auxiliaries suitable for preparing formulations according to the invention are known per se. As the liquid carrier, use can be made of: water, toluene, xylene, petroleum ether, vegetable oil, acetone, methyl ethyl ketone, cyclohexanone, anhydride, acetonitrile, acetophenone, amyl acetate, 2-butanone, butylene carbonate, chlorobenzene, cyclohexane, cyclohexanol, alkyl acetate, diacetone alcohol, 1, 2-dichloropropane, diethanolamine, p-diethylbenzene, diethylene glycol rosinate, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N, N-dimethylformamide, dimethyl sulfoxide, 1, 4-dioxane, dipropylene glycol methyl ether, dipropylene glycol dibenzoate, dipropylene glycol, alkylpyrrolidones, ethyl acetate, 2-ethylhexanol, ethylene carbonate, 1-trichloroethane, 2-heptanone, alpha-pinene, d-limonene, ethyl lactate, ethylene glycol butyl ether, ethylene glycol methyl ether, gamma-butyrolactone, glycerol acetate, glycerol diacetate, glycerol triacetate, hexadecane, hexylene glycol, isoamyl acetate, isobornyl acetate, isooctane, isophorone, cumene, isopropyl alcohol isopropyl myristate, lactic acid, laurylamine, mesityl oxide, methoxypropanol, methyl isoamyl ketone, methyl isobutyl ketone, methyl laurate, methyl octanoate, methyl oleate, methylene chloride, m-xylene, N-hexane, N-octylamine, stearic acid, octylamine acetate, oleic acid, oleylamine, o-xylene, phenol, polyethylene glycol, propionic acid, propyl lactate, propylene carbonate, propylene glycol methyl ether, p-xylene, toluene, triethyl phosphate, triethylene glycol, xylene sulfonic acid, paraffin, mineral oil, trichloroethylene, perchloroethylene, ethyl acetate, amyl acetate, butyl acetate, propylene glycol methyl ether, diethylene glycol methyl ether, methanol, ethanol, isopropanol, and higher molecular weight alcohols such as amyl alcohol, tetrahydrofuryl alcohol, hexyl alcohol, octyl alcohol, ethylene glycol, propylene glycol, glycerol, N-methyl-2-pyrrolidone, and the like.
Suitable solid carriers are, for example, talc, titanium dioxide, pyrophyllite clay, silica, attapulgite clay, diatomaceous earth, limestone, calcium carbonate, bentonite, calcium montmorillonite, cotton seed hulls, wheat flour, soybean flour, pumice, wood flour, ground walnut hulls, lignin and the like.
Many surface-active substances can be advantageously used in both solid and liquid formulations, especially those formulations which can be diluted by a carrier before use. The surface-active substances may be anionic, cationic, nonionic or polymeric and they may be used as emulsifiers, wetting agents or suspending agents or for other purposes. Typical surface-active substances include, for example, salts of alkyl sulfates, such as diethanolammonium lauryl sulfate; salts of alkylaryl sulfonates such as calcium dodecylbenzenesulfonate; alkylphenol/alkylene oxide addition products such as ethoxylated nonylphenols; alcohol/alkylene oxide addition products, such as ethoxylated tridecyl alcohol; soaps, such as sodium stearate; salts of alkyl naphthalene sulfonates such as sodium dibutyl naphthalene sulfonate; salts of dialkyl sulfosuccinates, such as sodium di (2-ethylhexyl) sulfosuccinate; sorbitol esters such as sorbitol oleate; quaternary amines such as dodecyltrimethylammonium chloride; polyethylene glycol esters of fatty acids, such as polyethylene glycol stearate; block copolymers of ethylene oxide and propylene oxide; and salts of mono-and di-alkyl phosphates; and also other substances, such as described in: mcCutcheon's Detergents and Emulsifiers Annual [ Mascin cleaner and emulsifier yearbook ], MC Publishing company (MC Publishing Corp.), richwood, N.J. (Ridgewood New Jersey) (1981).
Additional adjuvants that may be used in the pesticide formulation include crystallization inhibitors, viscosity modifiers, suspending agents, dyes, antioxidants, foaming agents, light absorbers, mixing aids, defoamers, complexing agents, substances and buffers that neutralize or alter the pH, corrosion inhibitors, fragrances, wetting agents, absorption enhancers, micronutrients, plasticizers, glidants, lubricants, dispersants, thickeners, anti-freezing agents, microbiocides, and liquid and solid fertilizers.
The formulation/composition used according to the invention may comprise additives comprising oils of vegetable or animal origin, mineral oils, alkyl esters of such oils or mixtures of such oils with oil derivatives. The amount of oil additive in the formulation according to the invention is generally from 0.01% to 10% based on the mixture to be applied. For example, the oil additive may be added to the spray can at the desired concentration after the spray mixture has been prepared. Preferred oil additives include mineral or vegetable-derived oils, such as rapeseed oil, olive oil orSunflower seed oil; emulsified vegetable oil; alkyl esters of oils of vegetable origin, such as methyl derivatives; or oils of animal origin, such as fish oil or tallow. Preferred oil additives include C 8 -C 22 Alkyl esters of fatty acids, especially C 12 -C 18 Methyl derivatives of fatty acids, such as methyl esters of lauric acid, palmitic acid and oleic acid (methyl laurate, methyl palmitate and methyl oleate, respectively). Many oil derivatives are derived from Compendium of Herbicide Adjuvants [ herbicide adjuvant outline ]]Edition 10, university of south illinois, 2010.
Preferred formulations may have the following composition (in weight%):
suspension concentrate:
active ingredients: 5% to 75%, preferably 10% to 50%
Water: 94% to 24%, preferably 88% to 30%
And (2) a surfactant: 1% to 40%, preferably 2% to 30%
Wettable powder：
Active ingredients: 0.5% to 90%, preferably 1% to 80%
And (2) a surfactant: 0.5% to 20%, preferably 1% to 15%
Solid carrier: 5% to 95%, preferably 15% to 90%
The granule comprises the following components:
active ingredients: 0.1% to 30%, preferably 0.1% to 15%
Solid carrier: 99.5% to 70%, preferably 97% to 85%
Synthetic methods for the preparation of methoxypiperidine ethyl ester (3- (4-chloro-2, 6-dimethyl-phenyl) -8-methoxy-1-methyl-2-oxo-1, 8-diazaspiro [4.5] dec-3-en-4-yl ] ethylcarbonate, CAS No. 1229023-00-0) are described in WO 2010/066780, WO 2018/114648 and WO 2018/114649, and references cited therein.
Examples：
Preventive control of Sang Bai (Sang Baidun scale) on tea trees.
The methoxypiperidine ethyl suspension concentrate formulation (SC 300) was diluted in water and adjuncts with paraffin oil463 (0.1% dilution). Test compositions containing a dilution of methoxypiperidine ethyl were sprayed onto the trunk (test composition 1) or canopy (test compositions 2 to 9) of three tea trees (wild tea tree) in the application volumes and ratios defined in the table for test compositions 1 to 9, for a total of 27 plants. Administration was performed on different Days (DBI) prior to Sang Bai infestation. The infection site is on the trunk of the tea tree. Percentage control of Sang Bai was measured 30 Days After Infestation (DAI). For canopy spray application, the trunks of the plants are covered with a preservative film to prevent the methoxypiperidine ethyl active ingredient from contacting the trunks. />
Watch (watch)
g AI/hl = gram active ingredient per hundred litres.
g AI/ha = gram active ingredient per hectare.
The data in table for test composition 1 shows that water and labor intensive application (AI adhesion to plants) of the methoxypiperidine ethyl composition on the trunk of tea trees using a high volume of composition per hectare provides 100% control of Sang Bai 30 days after infestation.
The data in the table also reveals the unexpected effect of test compositions 2 to 9, i.e. for tea tree canopy application, a similar high level of pest control (systemic effect by cross-layer action and phloem transport) was observed when the application volume was reduced by 10 times (1000L/ha) or even 50 times (200L/ha) at an equivalent dose compared to test composition 1. This is not to be expected.

Claims (15)

1. A method of controlling insect pests on tea trees, the method comprising applying to the canopy spray of the tea tree a pesticidal composition comprising an insecticidal active ingredient selected from the group consisting of ethylparaben, spirotetramat, spirodiclofen, spiromesifen, or dispiro.
2. The method of claim 1, wherein the tea tree is camellia sinensis.
3. The method of claim 1 or claim 2, wherein the pest is a scale insect.
4. A method according to claim 3, wherein the pest is Sang Bai (Sang Baidun mealy bugs) or mealy bugs (mealy bugs).
5. The method according to any one of claims 1 to 4, wherein the pesticidal composition further comprises an adjuvant selected from mineral oil, vegetable oil, esterified vegetable oil, methylated vegetable oil or alkyl phosphate-based coagent, and preferably mineral oil.
6. The method of any one of claims 1 to 5, wherein the pesticidal composition is an aqueous dilution of a suspension concentrate formulation of ethylparaben.
7. A method according to any one of claims 1 to 6 wherein the pesticidal composition comprises one or more additional pesticidally active ingredients and/or one or more agrochemically acceptable diluents or carriers.
8. The method of any one of claims 1 to 7, wherein the spray application volume per hectare of the pesticidal composition is in the range of 200 to 4000 liters per hectare (L/ha).
9. A method according to any one of claims 1 to 8, wherein the spray application volume per hectare of the pesticidal composition is in the range 500 to 1500 litres per hectare (L/ha).
10. A method according to any one of claims 1 to 9, wherein the active ingredient is applied at 500 to 2000 grams per hectare.
11. The method of claim 10, wherein the active ingredient is applied at 1000 to 1500 grams per hectare.
12. A method according to any one of claims 1 to 11 wherein the insect pest inhabits on stems or shoots of the tea tree.
13. A method according to any one of claims 1 to 12, wherein the insecticidal active ingredient is methoxypiperidine ethyl or spirotetramat.
14. A method according to any one of claims 1 to 13, wherein the insecticidal active ingredient is methoxypiperidine ethyl ester.
15. A method according to any one of claims 1 to 14 wherein the spray application substantially avoids application of the pesticidal composition to non-foliar portions of the tea tree.
CN202280053990.8A 2021-08-20 2022-08-18 Method for controlling pests on tea trees Pending CN117794372A (en)

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DE4216814A1 (en) 1991-07-16 1993-01-21 Bayer Ag 3-ARYL-4-HYDROXY- (DELTA) (UP ARROW) 3 (UP ARROW) -DIHYDROFURANONE- AND 3-ARYL-4-HYDROXY- (DELTA) (UP ARROW) 3 (UP ARROW) -DIHYDROTHIOPHENONE DERIVATIVES
JP4202423B2 (en) 1996-08-05 2008-12-24 バイエル・アクチエンゲゼルシヤフト 2- and 2,5-substituted phenylketoenols
DE10231333A1 (en) 2002-07-11 2004-01-22 Bayer Cropscience Ag Cis-alkoxy-substituted 1-H-pyrrolidine-2,4-dione spirocyclic derivatives
DE102005008021A1 (en) 2005-02-22 2006-08-24 Bayer Cropscience Ag New spiroketal-substituted cyclic ketoenol compounds used for combating animal parasites, undesired plant growth and/or undesired microorganisms
CA2746394C (en) 2008-12-12 2017-08-29 Syngenta Limited Spiroheterocyclic n-oxypiperidines as pesticides
HUE053779T2 (en) 2016-12-22 2021-07-28 Syngenta Participations Ag Polymorphs
GB201622007D0 (en) 2016-12-22 2017-02-08 And See Cambridge Display Tech Ltd Syngenta Participations Ag Polymorphs
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