CN1176859C - Coagulating and dewatering treatment method for waste drilling fluid - Google Patents
Coagulating and dewatering treatment method for waste drilling fluidInfo
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- CN1176859C CN1176859C CNB021173257A CN02117325A CN1176859C CN 1176859 C CN1176859 C CN 1176859C CN B021173257 A CNB021173257 A CN B021173257A CN 02117325 A CN02117325 A CN 02117325A CN 1176859 C CN1176859 C CN 1176859C
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- acrylamide
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Abstract
The present invention provides a coagulating and dewatering treatment method of waste drilling fluid, which particularly comprises the following steps: an inorganic aluminum salt flocculating agent and organic cation polyelectrolyte flocculating agent solution are added into the waste drilling fluid, and mixed solution is statically coagulated for 10 to 15 minutes after the mixed solution is uniformly stirred; after the waste drilling fluid is completely chemically stably dewatered, lump flocculates and part of flocculated water are centrifugally dewatered. The inorganic aluminum salt flocculating agent is preferably aluminum trichloride, and the use level of the aluminum trichloride is from 2000 to 3500 mg/L; an organic cation polyelectrolyte flocculating agent is organic cation polyelectrolyte with a quaternary ammonium salt cation functional group, suspended fine particles are prompted to coagulate the bulk flocculates under the synergy of the coagulation and the flocculation of the inorganic aluminum salt flocculating agent and the organic cation polyelectrolyte flocculating agent, and then the purpose of the solid-liquid separation of the waste drilling fluid is achieved after a centrifugally dewatering process.
Description
Technical field:
The present invention relates to the dehydration treatment method of a kind of treatment process of oil-gas field rejected well drilling liquid, particularly rejected well drilling liquid.
Background technology:
Drilling fluid leaks, changes drilling fluid, cleaning rig floor, removing drilling cuttings and gas blowout accident etc. and all can produce a large amount of rejected well drilling liquids and sewage in the oilfield drilling process.Refuse amount according to rig size and its generation of the drilling well depth does not wait, and the rejected well drilling liquid that general every mouthful of well produces is about 200~300 sides.Therefore, the processing of rejected well drilling liquid has been become an important research content of environment protection.Chinese patent " drilling completion mud reclamation treatment unit " (88218926.3) is introduced with heat drying and cure system and is handled waste mud, and this device exists energy consumption to reach the slow shortcoming of processing speed greatly, is not suitable for being used for the mass disposal rejected well drilling liquid.Patent " slurry solid-liquid separating method and equipment " (98104310) propose to rely on natural sedimentation and employing moveable filter to separate to allow contained solid matter in the slurry, but be not suitable for the good drilling mud of colloidal stability, the static placement several months of mud can be not settlement separate yet.Patent " handling the method for slime water " (90101597.0) proposes to add alkaline earth metal oxide or oxyhydroxide and negatively charged ion polymer condensing agent in slime water, add sulfuric acid and negatively charged ion polymer condensing agent subsequently again, and the throw out of generation bulk, handle the resulting throw out poor stability of rejected well drilling liquid with this method, can return glue again after the long-time immersion of chance water and become mud, have the potential secondary pollution.Patent " treatment process of waste drilling fluid and storage configuration " (92108103.0) and patent " composite and highly efficient agent for waste water treatment of drilling mud " (91102191) all propose in waste drilling fluid to add organic floculants such as inorganic flocculating agent such as Tai-Ace S 150 and hydro-polyacrylamide, extract supernatant liquid behind the flocculating settling out, on concentrated flocculate precipitate, add the lid layer fibre object, cover with the sealing of concrete such as cement again.Because hydro-polyacrylamide is the polymeric flocculant of anionic, flocculation to the mud clay particle forms by the bridge formation adsorption, the throw out poor stability of handling rejected well drilling liquid in this way and being produced, the long-time immersion just returned glue automatically and formed mud in the water.Though the concrete coating of throw out end face is isolated with itself and air, return the clay slurry can be around heatable adobe sleeping platform and bottom spread seepage in the soil towards periphery, continue to cause environmental pollution.
Summary of the invention:
Purpose of the present invention is the deficiency that has treatment process now in order to overcome, and provides a kind of power consumption low, and processing speed is fast, the dehydration treatment method of throw out good stability, environmentally friendly rejected well drilling liquid.
Treatment process of the present invention by cohesion and flocculation, chemistry take off steady dehydration, several parts of solid-liquid separation are formed, concrete grammar is: add inorganic flocculant and organic-flocculation agent solution in rejected well drilling liquid, the static coagulation in back 10~15 minutes stirs.After treating that the complete chemistry of rejected well drilling liquid takes off steady dehydration, the water outlet centrifuge dehydration of again agglomerate throw out and part being wadded a quilt with cotton, centrifuge speed can be chosen in 2000~5000 rev/mins.
The invention provides novel inorganic aluminate flocculation agent and organic cation polyelectrolyte flocculant;
Wherein one or more form above-mentioned inorganic aluminate flocculation agent by Tai-Ace S 150, aluminum chloride, 12 hydrazine aluminum sulfate potassium, polymerize aluminum chloride, polyaluminium sulfate, copolymerized iron-aluminium thing etc.;
Preferred inorganic aluminate flocculation agent is an aluminum chloride, and its usage quantity is 2000~3500mg/L.
Above-mentioned organic cation polyelectrolyte flocculant is the organic cation polyelectrolyte that has quaternary ammonium salt cationic functional group, as diallyldimethylammonium chloride-acrylamide copolymer, acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer, acrylamide-Jia Jibingxisuanyizhi base trimethyl ammonium chloride multipolymer, acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium methyl sulfate multipolymer, acrylamide-Jia Jibingxisuanyizhi base trimethyl ammonium methyl sulfate multipolymer etc. one or more.
The described polyelectrolyte that contains the quaternary ammonium salt cationic group is characterized in that molecular weight is 1 * 10
6~10 * 10
6, cationic degree is 5%~80%, wherein the molecular weight of the best cationic flocculant acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer that uses with flocculation agent aluminum chloride synergism is 3 * 10
6, cationic degree is 15%.
The inorganic aluminate flocculation agent and the organic cation polyelectrolyte flocculant of best synergism are aluminum chloride and acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer, the rejected well drilling liquid chemistry that can effectively flocculate takes off the solid phase particles in the system of steady back, and latter's usage quantity is 200~300mg/L.
Under the synergy of novel inorganic aluminium salt flocculation agent of the present invention and cohesion of organic cation polyelectrolyte flocculant and flocculation, the surface is electronegative clay particle and thoroughly destroys its colloidal dispersion by static neutralizing effect and macromolecular bridge formation adsorption in the mud, impel the fine particle of suspension to gather into the bulk throw out, through centrifuge dehydration, the body refuse of guaranteeing to flocculate has good anti-water logging bubble ability, isolated water is capable of circulation to be used again, as prepare drilling fluid etc., the dehydration body refuse can directly be imbedded underground safely, finally reaches the purpose of rejected well drilling liquid solid-liquid separation.
Description of drawings:
Fig. 1 is the process flow sheet of rejected well drilling liquid coagulation processed.
Embodiment:
According to shown in Figure 1, at first rejected well drilling liquid is pumped in mud tank or other container with pump, again inorganic flocculant and positively charged ion organic-flocculation agent solution are added in the container that rejected well drilling liquid is housed successively, starting stirrer slowly stirs, static coagulation 10~15 minutes, after treating that the complete chemistry of rejected well drilling liquid takes off steady dehydration, the water outlet of again agglomerate throw out and part being wadded a quilt with cotton pumps in the whizzer with pump, through the water drilling operation that is used further to capable of circulation that centrifugation goes out, dehydration body refuse directly safety is imbedded underground.
The dissimilar rejected well drilling liquid coagulations dehydrations that produce with China's four oil fields four-hole wells such as husky 7 wells of Central Plains Pu 5123 wells, Xinjiang Bao101Jing, Jiangsu and true 138 wells in Jiangsu be treated to example, see the following form.
Table 1
Embodiment | The rejected well drilling liquid source | Flocculation agent | Flocculation agent |
1 | Central Plains Pu 5123 wells | The 3500mg/L aluminum chloride | 300mg/L acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer |
2 | Xinjiang Bao101Jing | The 3000mg/L aluminum chloride | 240mg/L acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer |
3 | Husky 7 wells in Jiangsu | The 2700mg/L aluminum chloride | 200mg/L acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer |
4 | True 138 wells in Jiangsu | The 2000mg/L aluminum chloride | 210mg/L acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer |
After taking off surely, above-mentioned four kinds of rejected well drilling liquid chemistry all produce strong flocculation, the obvious coalescent increase of solid phase particles, and the grain diameter average increases to 126.3~283 μ m by 10.3 preceding μ m of flocculation; Median particle size increases to 106.9~246.1 μ m by 4.1 μ m, particle diameter reduces to 5.3% less than the granule number below the 20 μ m by 85.5% before flocculating, and but natural separation goes out a part of water, further use the whizzer can be with free water residual in the flocculation cluster porosity from totally, the turbidity that separates water outlet is low to decolour thereby make, guarantee the quality of rejected well drilling liquid solid-liquid separation, the results are shown in Table 2, table 3.Through after 4000 rev/mins of centrifuge dehydrations, final rejected well drilling liquid centrifuge dehydration rate reaches 59% again.
Table 2
Useless slurry source Central Plains Pu 5132 well embodiment 1 | Sampling depth density viscosity pH value oleaginousness water content solid load | ||
Time m g/cm 3 s %v %v %v g/L | |||
1995.3 2760 1.29 50 9.0 5.0 75.0 20.0 440 | |||
Rheological parameter | Main treatment agent | Remarks | |
Φ 600 Φ 300 Φ 200 Φ 100 Φ 6 Φ 3 | HPAN, HPAM, FCLS, LV-CMC, HV-CMC, crude oil | Color: dark brown smell: oil flavor | |
178 142 129 113 84 81 | |||
The precious 101 well embodiment 2 in Xinjiang | Sampling depth density viscosity pH value oleaginousness water content solid load | ||
Time m g/cm 3 s %v %v %v g/L | |||
1995.5 2500 1.20 54 8.0 2.5 86.5 11.0 400 | |||
Rheological parameter | Main treatment agent | Remarks | |
Φ 600 Φ 300 Φ 200 Φ 100 Φ 6 Φ 3 | FA-367,XY-27,SMP SPNH,PAC-142, | Color: dark brown smell: oil flavor | |
146 100 80 55 24 20 | |||
The husky 7 well embodiment 3 in Jiangsu | Sampling and deep degree viscosity pH value oleaginousness water content solid load | ||
Time m g/cm 3 s %v %v %v g/L | |||
1994.10 2100 1.20 40 9.5 6.0 82.5 11.5 290 | |||
Rheological parameter | Main treatment agent | Remarks | |
Φ 600 Φ 300 Φ 200 Φ 100 Φ 6 Φ 3 | HPAN, HPAM, XY-27 ABSN, modifying asphalt, crude oil | Color: dark brown smell: oil flavor | |
153 102 81 55 15 13 | |||
The true 138 well embodiment 4 in Jiangsu | Sampling depth density viscosity pH value oleaginousness water content solid load | ||
Time m g/cm 3 s %v %v %v g/L | |||
1994.10 2573 1.14 44 10.0 7.0 85.0 8.0 265 | |||
Rheological parameter | Main treatment agent | Remarks | |
Φ 600 Φ 300 Φ 100 Φ 100 Φ 6 Φ 3 | HPAN, HPAM, XY27, FA367, emulsifying agent, crude oil | Color: dark brown smell: oil flavor | |
151 105 75 54 17 12 |
Annotate: 1. useless slurry viscosity probe temperature is about 25 ℃;
2. the used main treatment agent HPAN of drilling fluid, HPAM, FCLS, CMC, FA367, XY27, SMP, SPNH, PAC142, ABSN etc. are the code names with macromolecular compound of different action functions.
Wherein:
HPAN: hydrolysis polyacrylonitrile.
HPAM: hydro-polyacrylamide.
FCLS: feero-chromo-lignosulfonate.
CMC: sodium carboxymethyl-cellulose.
FA367: compound ion type high molecular polymer fluid loss agent.
XY-27: contain the amphoteric ion polymer of negatively charged ion and cation group, belong to the vinyl monomer multiple copolymer.
SMP: sulfonated-pheno-formoldehyde resin.
SPNH: with brown coal, eyeball synthetic fibre waste silk is main raw material, the multipolymer that the ternary of a kind of hydroxyl, carbonyl, methylene radical, sulfonic group, phenyl ring, carboxyl and eyeball base that employing graft copolymerization and sulfonation method make is above.
PAC142: the multiple copolymer of vinylformic acid, acrylic amine, acrylonitrile, sodium allylsulfonate.
ABSN: Sodium dodecylbenzene sulfonate.
Table 3
Useless slurry | Before the flocculation | After the flocculation |
<20 μ m grain diameter average median particle sizes (%) (μ m) (μ m) | <20 μ m grain diameter average median particle sizes (%) (μ m) (μ m) | |
Embodiment 1 embodiment 2 embodiment 3 embodiment 4 | 85.5 10.3 4.1 85.5 10.7 6.0 85.3 10.8 6.0 42.4 54.2 28.5 | 5.3 126.3 106.9 1.2 177.6 161.8 1.7 283.0 246.1 3.3 134.1 118.6 |
Claims (5)
1. coagulating and dewatering treatment method for waste drilling fluid, it is characterized in that by cohesion and flocculation, chemistry take off steady dehydration, several parts of solid-liquid separation are formed; Concrete grammar is: add inorganic aluminate flocculation agent and organic cation polyelectrolyte flocculant solution in rejected well drilling liquid, static coagulation is 10~15 minutes after stirring; After treating that the complete chemistry of rejected well drilling liquid takes off steady dehydration, the water outlet centrifuge dehydration of again agglomerate throw out and part being wadded a quilt with cotton, centrifuge speed is 2000~5000 rev/mins; Described organic cation polyelectrolyte flocculant is the organic cation polyelectrolyte that has quaternary ammonium salt cationic functional group, comprises in diallyldimethylammonium chloride-acrylamide copolymer, acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer, acrylamide-Jia Jibingxisuanyizhi base trimethyl ammonium chloride multipolymer, acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium methyl sulfate multipolymer, the acrylamide-Jia Jibingxisuanyizhi base trimethyl ammonium methyl sulfate multipolymer one or more.
2. the described coagulating and dewatering treatment method for waste drilling fluid of claim 1, it is characterized in that described inorganic aluminate flocculation agent by Tai-Ace S 150, aluminum chloride, 12 hydrazine aluminum sulfate potassium, polymerize aluminum chloride, polyaluminium sulfate, wherein one or more form the copolymerized iron-aluminium thing.
3. the described coagulating and dewatering treatment method for waste drilling fluid of claim 2 is characterized in that described inorganic aluminate flocculation agent is an aluminum chloride, and its usage quantity is 2000~3500mg/L.
4. the described coagulating and dewatering treatment method for waste drilling fluid of claim 1 is characterized in that described organic cation polyelectrolyte flocculant contains the polyelectrolyte of quaternary ammonium salt cationic group, and its molecular weight is 1 * 10
6~10 * 10
6, cationic degree is 5%~80%.
5. the described coagulating and dewatering treatment method for waste drilling fluid of claim 1, it is characterized in that described inorganic aluminate flocculation agent and organic cation polyelectrolyte flocculant are aluminum chloride and acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer, acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer usage quantity is 200~300mg/L, and wherein the molecular weight of the cationic flocculant acrylamide-acrylicacid ethoxycarbonyl trimethyl ammonium chloride multipolymer that uses with flocculation agent aluminum chloride synergism is 3 * 10
6, cationic degree is 15%.
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