CN117652750A - High-strength plate for sole and preparation method thereof - Google Patents

High-strength plate for sole and preparation method thereof Download PDF

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Publication number
CN117652750A
CN117652750A CN202410026407.5A CN202410026407A CN117652750A CN 117652750 A CN117652750 A CN 117652750A CN 202410026407 A CN202410026407 A CN 202410026407A CN 117652750 A CN117652750 A CN 117652750A
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China
Prior art keywords
strength
resin
sole
electro
hollowed
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202410026407.5A
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Chinese (zh)
Inventor
程得意
董斌
李柳燕
李云
焦提成
吴敏辉
刘许正
曾全寿
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Anta China Co Ltd
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Anta China Co Ltd
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Publication date
Application filed by Anta China Co Ltd filed Critical Anta China Co Ltd
Priority to CN202410026407.5A priority Critical patent/CN117652750A/en
Publication of CN117652750A publication Critical patent/CN117652750A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/026Composites, e.g. carbon fibre or aramid fibre; the sole, one or more sole layers or sole part being made of a composite
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/14Soles; Sole-and-heel integral units characterised by the constructive form
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/37Sole and heel units
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/12Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
    • B29D35/122Soles
    • DTEXTILES; PAPER
    • D05SEWING; EMBROIDERING; TUFTING
    • D05CEMBROIDERING; TUFTING
    • D05C17/00Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The invention belongs to the technical field of footwear products, and provides a high-strength plate for soles and a preparation method thereof, wherein the high-strength plate is provided with a sole full-sole or half-sole structure and comprises a hollowed-out high-strength fiber resin electroembroidered sheet layer, and the hollowed-out area is less than or equal to 60% of the total surface area of the high-strength plate. The high-strength plate for the sole is formed by adopting the procedures of hollowed-out electroembroidery and the like through the high-strength fibers and the resin, can be precisely arranged, realize the functional distinction of different parts and ensure the integral rigidity strength. The mechanical and electric embroidery machine replaces the traditional manual operation flow, simplifies the process, improves the working efficiency and reduces the production cost. The invention can realize different visual appearance effects through different high-strength fiber yarns, thereby further meeting various demands of consumers.

Description

High-strength plate for sole and preparation method thereof
Technical Field
The invention belongs to the technical field of footwear products, and particularly relates to a high-strength plate for soles and a preparation method thereof.
Background
The carbon plate is a carbon fiber composite material, is usually formed by bonding resin and carbon fiber yarns through heat treatment, can play a supporting role when applied to the bottom of a shoe due to the excellent mechanical property, and can prevent torsion to protect the foot. For carbon plates used for soles, they can be classified into thermosetting carbon plates and thermoplastic carbon plates according to performance and manufacturing process. The manufacturing process of the thermosetting carbon plate mainly comprises the following steps: resin batching and carbon fiber loading; arranging fiber yarns; drawing, folding and pressing yarns; shaping; weighing and loading on a frame. The yarn folding process comprises operations of weighting, yarn folding, cutting, transferring, reinforcing and the like. The molding is generally heating and molding, and the operations of deburring, sand blasting, cleaning and the like are also carried out after demolding. The thermoplastic carbon plate is usually formed by spreading carbon fiber filament windings, then impregnating the carbon fiber filament windings with thermoplastic resin to form unidirectional tapes, unreeling and laying the unidirectional tapes in multiple layers at different angles, and hot-pressing/cold-pressing the unidirectional tapes to form the plate.
The thermoset carbon sheet can be fabricated into a relatively three-dimensional and complex structure relative to the thermoplastic carbon sheet. In the traditional process, the preparation of the multi-hardness hollow carbon plate can be realized by utilizing parameterization design, and through mechanical arm presetting, mould pressing and the like. The hollowed-out carbon plate manufactured in the market at present is light and still has certain limitation, such as partial parts on two sides of the front palm are difficult to realize different hardness, namely the arrangement of the functional areas of the traditional carbon plate is not accurate enough; and is expensive in unit price.
Disclosure of Invention
In view of the above, the invention provides a high-strength plate for soles and a preparation method thereof, and the high-strength plate provided by the invention has a hollowed-out structure, ensures the overall strength, can accurately realize the functionality, and has higher cost performance.
The invention provides a high-strength plate for soles, which has a sole full-palm or half-palm structure, and comprises a hollowed high-strength fiber resin electroembroidered sheet layer, wherein the hollowed area is less than or equal to 60% of the total surface area of the high-strength plate.
In the embodiment of the invention, the high-strength fiber resin electro-embroidered sheet is a carbon fiber resin electro-embroidered sheet, a glass fiber resin electro-embroidered sheet or a carbon fiber/glass fiber resin electro-embroidered sheet.
In an embodiment of the present invention, the high-strength fiber resin electro-embroidered sheet layer includes high-strength fibers and a resin component, wherein the high-strength fibers are carbon fibers having a specification of 3K to 24K.
In the embodiment of the invention, the resin component of the high-strength fiber resin electrotransport sheet layer is epoxy resin.
In an embodiment of the present invention, the high-strength fiber resin electro-embroidered sheet layer has different colors and/or different textures at the main sole portion.
In the embodiment of the invention, the high-strength fiber resin electro-embroidered sheet layer is also provided with a base cloth layer.
The invention provides a preparation method of a high-strength plate for soles, which comprises the following steps:
according to the full sole or half sole structure of the sole, performing hollowed-out design electro-embroidery on the surface of the base cloth by using high-strength fiber yarns to form an electro-embroidery layer; the hollowed-out area is less than or equal to 60% of the total surface area of the embroidery layer;
and (3) carrying out composite compression molding on the electro-embroidering layer and the resin, or removing the base cloth in the electro-embroidering layer, carrying out composite compression molding on the base cloth and the resin, and demolding to obtain the high-strength plate for the sole.
In an embodiment of the present invention, the high-strength fiber yarn is one or both of a carbon fiber yarn and a glass fiber yarn; the resin is epoxy resin.
In the embodiment of the invention, the temperature of the die for composite compression molding is 120-180 ℃. In some embodiments, the mold temperature is 170-180 ℃ and the holding time is 2-5 minutes; in other embodiments, the mold temperature is 120-150 ℃.
In an embodiment of the invention, the half sole average rigidity of the high-strength plate for the sole is 240-560N; other embodiments have a stiffness outside of this range.
Compared with the prior art, the high-strength plate for the sole provided by the invention comprises the following components: the high-strength fiber resin electro-embroidered sheet with hollowed-out structure can comprise an electro-embroidered base fabric or can be free of the base fabric; the hollowed-out area is less than or equal to 60% of the total surface area of the high-strength plate. The high-strength plate for the sole is formed by adopting the procedures of hollowed-out electroembroidery and the like through the high-strength fibers and the resin, can be precisely arranged, realize the functional distinction of different parts and ensure the integral rigidity strength. The mechanical and electric embroidery machine replaces the traditional manual operation flow, simplifies the process, improves the working efficiency and reduces the production cost. The invention can realize different visual appearance effects through different high-strength fiber yarns, thereby further meeting various demands of consumers.
Drawings
FIG. 1 is a schematic view of the structure of a high strength panel in some embodiments of the invention;
FIG. 2 is a schematic view of a high strength panel in accordance with further embodiments of the present invention;
FIG. 3 is a simplified flow diagram of an apparatus for electro-embroidering and embossing in accordance with some embodiments of the present invention;
fig. 4 is a diagram showing the comparison of the hollow structures of the carbon plate sample tested in example 1 of the present invention.
Detailed Description
In order that those skilled in the art will better understand the technical solution of the present invention, the following detailed description of the present invention with reference to specific embodiments thereof is provided by way of example and explanation only, and should not be construed as limiting the scope of the present invention in any way.
The invention provides a high-strength plate for soles, which has a sole full-palm or half-palm structure and comprises a high-strength fiber resin electroembroidered sheet layer with hollowed-out parts, wherein the hollowed-out area is less than or equal to 60% of the total surface area of the high-strength plate.
The high-strength plate provided by the invention has a hollowed-out structure, ensures the overall strength, can accurately realize the functionality, and has higher cost performance.
Referring to fig. 1 and 2, fig. 1 and 2 are schematic structural views of a high strength plate according to an embodiment of the present invention; 1 is a carbon plate, a certain hollowed-out part corresponding to the arch part is formed, and broken lines in the figure are the outer contour of the sole.
The high-strength board 1 for soles provided by the embodiment of the invention has a full-sole structure, and can also be a front half sole or a rear half sole structure of the sole. The high-strength plate 1 comprises a hollowed high-strength fiber resin electro-embroidered sheet layer, and is formed by adopting high-strength fibers and resin through procedures such as hollowed electro-embroidering.
The hollowed-out electric embroidery provided by the embodiment of the invention is to design a hollowed-out sole structure by using computer programming, and embroidering is performed on base cloth by using yarns through an electric embroidery machine, and comprises the procedures of plate making, wiring and the like; the traditional embroidery is commonly called as embroidery, and is a technology for performing puncture on the processed fabric by needle leads according to design requirements and organizing embroidery threads into various patterns and colors by needle transportation.
The high-strength fiber resin electro-embroidered sheet layer of the embodiment of the invention comprises: high strength fiber and resin components; the yarn of the electro-embroidery is mainly carbon fiber yarn, but is not limited to carbon fiber, and pure spinning and blending yarns of glass fiber and other high-strength fibers can be adopted according to requirements. Preferably, the high-strength fiber resin electro-embroidered sheet is a carbon fiber resin electro-embroidered sheet, a glass fiber resin electro-embroidered sheet or a carbon fiber/glass fiber resin electro-embroidered sheet, and more preferably a carbon fiber resin electro-embroidered sheet.
The carbon fiber can be divided into Polyacrylonitrile (PAN) based carbon fiber, asphalt based carbon fiber and the like according to raw material sources, and the embodiment of the invention mainly adopts PAN based carbon fiber, and can be of general type and high strength type, for example, the strength of the carbon fiber is 1000 MPa-2000 MPa, and the modulus is 100 GPa-250 GPa. The types of the carbon fibers are more, in the embodiment of the invention, the high-strength fibers are preferably carbon fibers with the specification of 3K-24K, such as carbon fiber yarn (carbon yarn) products sold in the markets of 3K, 12K and 24K, and if the carbon fibers are too fine, the overall strength and the production and processing quality are difficult to ensure.
The resin component of the high-strength fiber resin electrotransport sheet layer is preferably epoxy resin; the epoxy resin and the curing system thereof have excellent performance. The epoxy resins commonly used are bisphenol a type epoxy resins, bisphenol F type epoxy resins, bisphenol E type epoxy resins, and the like; commonly used curing agents include amine curing agents, anhydride curing agents and the like, and different curing agents have different influences on the curing speed, hardness, heat resistance and other performances of the epoxy resin. The resins used in some embodiments of the present invention are epoxy resins YPH1150, WP-R560023K (Hui Bai, available from New Material technology Co., ltd.), but are not limited thereto and can be adjusted according to the type of product. Wherein the viscosity of the WP-R560023K epoxy resin is 16500-22500mPa.s@70 ℃.
The high-strength fiber resin electro-embroidered sheet layer provided by the embodiment of the invention has a hollowed-out structure, wherein the hollowed-out area is less than or equal to 60% of the total surface area of the surface of the high-strength plate 1, such as about 50%, so that the light weight, the supporting function and the like of the high-strength plate are ensured. The hollowed-out parts are distributed and the outer contour shape has various designs, and the hardness and the rigidity of different parts can be adjusted as required, so that the functionality is accurately realized; the whole palm can be hollowed out, and the half palm can be hollowed out. As shown in fig. 1 and 2, corresponding to the arch part, there are different shapes of hollows, and multiple hollows with symmetrical distribution of the whole palm can be formed. In some embodiments, the high strength panel for a sole has a half sole average stiffness of 240 to 560N.
In the embodiment of the invention, the main sole part of the high-strength fiber resin electro-embroidered sheet layer is provided with different electro-embroidered lines. The electric embroidery lines are various and comprise one or more of one-needle thread rope embroidery, tape embroidery, flat embroidery and three-dimensional embroidery, and the invention is not particularly limited to the above, and rope embroidery (also called strand embroidery) and tape embroidery can be adopted. The flat embroidery is an embroidery method which uses needle methods such as needle alignment, needle swinging, needle sleeving and the like on a planar backing material and consists of straight lines, and the embroidery surface has fine lines. The tape embroidery has the stitch such as winding embroidery, tape embroidery, thousand bird embroidery and the like, and the three-dimensional effect of the embroidery surface is stronger.
The high-strength fiber resin electro-embroidered sheet layer provided by the embodiment of the invention is also provided with a base cloth layer; namely, the hollowed-out electro-embroidered base cloth can be removed and can be reserved in the high-strength plate. The components of the base cloth are not limited, and the performance is selected according to specific strength requirements; the base cloth can be made of cloth with different structures, and the color can also be selected. And for the removal of the base cloth, the subsequent cutting or the embroidering and the cutting can be carried out, and the water-soluble base cloth can be removed in a water-soluble way. In addition, the surface (non-hollowed-out position) of the high-strength fiber resin electrotransport sheet layer can be further electrotransport carved and modified.
The high-strength plate for the sole can be of half palm, full palm and other structures, is light in weight, has the average thickness of 0.8-2.0mm, has the functionality of accurate design of different parts, and meets the requirement on the integral rigidity strength; the fabric can contain different base fabric layers, can have various appearance forms such as different colors, different lines (lines can not be displayed), and the like, has high cost performance and is beneficial to application.
The invention provides a preparation method of a high-strength plate for soles, which comprises the following steps:
according to the full sole or half sole structure of the sole, performing hollowed-out design electro-embroidery on the surface of the base cloth by using high-strength fiber yarns to form an electro-embroidery layer; the hollowed-out area is less than or equal to 60% of the total surface area of the embroidery layer;
and (3) carrying out composite compression molding on the electro-embroidering layer and the resin, or removing the base cloth in the electro-embroidering layer, carrying out composite compression molding on the base cloth and the resin, and demolding to obtain the high-strength plate for the sole.
Firstly, preparing raw materials, wherein removable base cloth is adopted; in the embodiment of the invention, the high-strength fiber yarn is one or two of carbon fiber yarn and glass fiber yarn, preferably carbon yarn with the specification of 3K-24K. The resin adopted by the embodiment of the invention is epoxy resin, such as epoxy resin products of the model YPH1150 and the model WP-R560023K. The resin amount can be adjusted in different ranges according to the design and the processing method, for example, the resin is directly added on the carbon fiber, and the currently tried addition amount is 20-50% (relative to the mass of the carbon fiber), which is different from the added resin amount after embroidery.
In addition, the embodiment of the invention carries out hollowed-out electric embroidery design of the sole pattern according to TOP topology calculation, and then adopts an electric embroidery machine shown in figure 3 to embroider high-strength fiber yarns to form an electric embroidery layer; different textures can be formed through various electro-embroidering processes, such as one or more of one-needle and one-line embroidery, tape embroidery, plain embroidery and three-dimensional embroidery, and the invention is not particularly limited thereto, and the content of the specific hollowed-out structure is as described above.
After the electro-embroidery layer is formed, some embodiments of the invention perform composite compression molding with resin injected into a mold, and other embodiments perform composite compression molding with the resin after the base cloth in the electro-embroidery layer is removed. As shown in fig. 3, the obtained electro-embroidering layer is placed in a mould, the mould is closed, pressed and preshaped, then resin material is injected into the mould, mould pressing and shaping are carried out, and finally cooling and demoulding are carried out. Different embroidered sheet textures and designs, later tooling trim (e.g., resin trim) and different stiffness requirements can affect product thickness and weight.
In an embodiment of the present invention, the mold temperature for the composite compression molding is preferably 120 ℃ to 180 ℃. In some thermoplastic processes, the temperature of the die is 170-180 ℃, and the heat preservation and pressure maintaining time can be 2-5 minutes; heating by infrared heating plate at 350-400deg.C for about 3-4 min; meanwhile, the temperature of the die is set to 170-180 ℃, and the surface temperature of the embroidering layer is 180-200 ℃ before heating and forming. Then removing the heating plate, closing the mold, and adding vacuum to mold, wherein the mold can be divided into two stages, namely a heat preservation and pressure maintaining stage lasts for 3 minutes, and then cooling to a demolding stage, wherein the time is 2 minutes; the temperature of the die is 90-100 ℃ during demoulding, and the temperature of the product is 120-125 ℃. In other thermosetting processes, the mold temperature is set at 150 ℃ for 25 minutes (small machine + vacuum pumping); 120 ℃ for 2 hours (large machine + vacuuming). After the composite compression molding, the mold is opened, the product is taken out, and the appearance and other aspects of the product which is taken out of the mold are finished, such as trimming treatment; the surface (non-hollowed-out position) of the high-strength fiber resin electrotransport sheet layer can be further electrotransport carved and modified.
The embodiment of the invention adopts high-strength fibers and resin to form the high-strength plate for the sole mainly through hollowed-out electro-embroidery and composite compression molding procedures, can be accurately arranged, realize functional distinction of different parts, and ensure the integral rigidity strength, and the average front sole rigidity of the high-strength plate obtained by some embodiments is 240-560N. The mechanical and electric embroidery machine replaces the traditional manual operation flow, simplifies the process, improves the working efficiency and reduces the production cost. The invention can realize different visual appearance effects through different high-strength fiber yarns, thereby further meeting various demands of consumers.
The present invention will be described in further detail with reference to the following examples and drawings, the examples described herein only assist in understanding the present invention, and the embodiments of the present invention are not limited thereto. Wherein, the raw materials of the embodiment of the invention are commercially available.
Example 1
According to the sole full-palm structure, performing hollowed-out design electro-embroidery on the surface of the removable base cloth by using 3K carbon fiber yarns, forming an electro-embroidery layer through rope embroidery and tape embroidery, and subsequently cutting the base cloth; the hollowed-out area accounts for 50% of the total surface area of the embroidery layer, and the specific hollowed-out structure is shown as a test sample V2 in FIG. 4.
And (3) carrying out composite compression molding on the formed embroidery layer and injection-molded epoxy resin (epoxy resin WP-R560023K) in a mold. Heating by an infrared heating plate at 350-400 deg.C for about 3-4 min; meanwhile, the temperature of the die is set to 170-180 ℃, and the surface temperature of the embroidering layer is 180-200 ℃ before heating and forming. Removing the heating plate, closing the mold, adding vacuum for molding, firstly keeping the temperature and the pressure for 3 minutes, and then cooling to a demolding stage for 2 minutes; the temperature of the die is 90-100 ℃ during demoulding, and the temperature of the product is 120-125 ℃. And opening the die, taking out the product, and trimming to obtain the carbon plate for the sole, wherein the thickness of the carbon plate is 0.8-2.0mm.
The prepared carbon plate samples were subjected to comparative tests (test 3-point bending test, a commonly used sole stiffness test method) and the results are as follows. Wherein, the comparative sample A and the comparative sample B are carbon plates manufactured by a conventional method. Fig. 4 shows a hollow structure of a test carbon plate in example 1 of the present invention.
Table 1 comparison of carbon sheet properties of example 1
In addition, other embodiments of the invention can cut out the base cloth and carry out the electric carving process at the same time of electric embroidery; and the hollow structures with different areas can be controlled, so that the carbon plate with the electric embroidery layers with different rigidity and strength can be obtained.
According to the embodiment, the high-strength fiber and the resin are adopted to form the high-strength sheet plate for the sole through the procedures of hollowed-out electro-embroidery and the like, so that the high-strength sheet plate can be accurately arranged, the functional distinction of different parts is realized, and the integral rigidity strength is ensured. The mechanical and electric embroidery machine replaces the traditional manual operation flow, simplifies the process, improves the working efficiency and reduces the production cost. The invention can realize different visual appearance effects through different high-strength fiber yarns, thereby further meeting various demands of consumers.
Finally, it should be noted that the specific embodiments described herein are merely illustrative of the spirit of the invention and are not limiting of the invention. Other modifications and additions to the described embodiments and similar alternatives to the described embodiments will be apparent to those skilled in the art, and it is not necessary nor necessary to fully implement the invention. While these obvious variations and modifications, which come within the spirit of the invention, are within the scope of the invention, they are to be construed as being without departing from the spirit of the invention.

Claims (10)

1. The high-strength plate for the sole is provided with a full-sole or half-sole structure of the sole, and is characterized by comprising a high-strength fiber resin electroembroidered sheet layer with hollowed-out parts, wherein the hollowed-out area is less than or equal to 60% of the total surface area of the high-strength plate.
2. The high-strength plate for shoe soles according to claim 1, characterized in that the high-strength fiber-resin electro-embroidered sheet is a carbon fiber-resin electro-embroidered sheet, a glass fiber-resin electro-embroidered sheet or a carbon fiber/glass fiber-resin electro-embroidered sheet.
3. The high-strength plate for shoe soles according to claim 1, characterized in that the high-strength fiber resin electro-embroidered sheet layer contains high-strength fibers and a resin component, the high-strength fibers being carbon fibers of 3K to 24K in specification.
4. A high strength plate for shoe soles according to claim 3, characterized in that the resin component of said high strength fiber resin electro-embroidered sheet is epoxy resin.
5. The high-strength plate for shoe soles according to claim 1, characterized in that the high-strength fiber-resin electro-embroidered sheet has different colors and/or different textures at the main sole portion.
6. The high-strength plate for shoe soles according to any one of claims 1 to 5, characterized in that said high-strength fiber-resin electro-embroidered sheet layer further has a base cloth layer therein.
7. A method of making a high strength panel for a shoe sole, comprising the steps of:
according to the full sole or half sole structure of the sole, performing hollowed-out design electro-embroidery on the surface of the base cloth by using high-strength fiber yarns to form an electro-embroidery layer; the hollowed-out area is less than or equal to 60% of the total surface area of the embroidery layer;
and (3) carrying out composite compression molding on the electro-embroidering layer and the resin, or removing the base cloth in the electro-embroidering layer, carrying out composite compression molding on the base cloth and the resin, and demolding to obtain the high-strength plate for the sole.
8. The method of claim 7, wherein the high strength fiber yarn is one or both of a carbon fiber yarn and a glass fiber yarn; the resin is epoxy resin.
9. The method according to claim 7, wherein the mold temperature for the composite compression molding is 170-180 ℃ and the holding time is 2-5 minutes.
10. The method of claim 7, wherein the mold temperature for the composite compression molding is 120-150 ℃.
CN202410026407.5A 2024-01-08 2024-01-08 High-strength plate for sole and preparation method thereof Pending CN117652750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202410026407.5A CN117652750A (en) 2024-01-08 2024-01-08 High-strength plate for sole and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202410026407.5A CN117652750A (en) 2024-01-08 2024-01-08 High-strength plate for sole and preparation method thereof

Publications (1)

Publication Number Publication Date
CN117652750A true CN117652750A (en) 2024-03-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202410026407.5A Pending CN117652750A (en) 2024-01-08 2024-01-08 High-strength plate for sole and preparation method thereof

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