CN117624794A - All-weather semi-hot-melt tire formula and process - Google Patents

All-weather semi-hot-melt tire formula and process Download PDF

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Publication number
CN117624794A
CN117624794A CN202311507596.XA CN202311507596A CN117624794A CN 117624794 A CN117624794 A CN 117624794A CN 202311507596 A CN202311507596 A CN 202311507596A CN 117624794 A CN117624794 A CN 117624794A
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tire
parts
weather
semi
mold
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陈伟
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Shaowu Zhengxing Wuyi Tyre Co ltd
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Shaowu Zhengxing Wuyi Tyre Co ltd
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Priority to CN202311507596.XA priority Critical patent/CN117624794A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/80Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
    • Y02T10/86Optimisation of rolling resistance, e.g. weight reduction 

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Abstract

The invention provides an all-weather semi-hot-melt tire formula and a process, and relates to the field of tire formulas. The formula and the process based on the all-weather semi-hot-melt tire comprise the following steps of: 76 parts of filler: 19-20 parts of plasticizer: 2-3 parts of sulfur: 1.5 parts of accelerator: 0.5 part of TBBS and an aging agent: 2 parts of sulfur vulcanizing agent: 0.5 parts of an accelerator: 0.5 part. The content of the aging agent in the tire is increased to improve the oxidation resistance and ozone resistance of the tire, the durability and the crack resistance of the tire can be improved by using higher-quality raw materials and precisely adjusting the proportion of each component in the formula, and the crack resistance of the tire can be improved by adopting a low-temperature vulcanization process.

Description

All-weather semi-hot-melt tire formula and process
Technical Field
The invention relates to the field of tire formulas, in particular to an all-weather semi-hot-melt tire formula and a process.
Background
The full-hot-melting high-performance tire refers to a tire which is melted into a gel state after the temperature of the tread is increased, and the tire enhances the adhesion with the ground, thereby improving the over-bending limit of the vehicle. However, all-hot-melt tires are generally green tires, are used more on racing vehicles, are very poor in grip before they are free of hot tires because of the relatively smooth tread, are unsuitable for long-term driving, and are relatively expensive. The semi-hot-melt high-performance tire is characterized in that chemical materials such as Kevlar fiber (low in density, high in strength, good in toughness, high-temperature resistant and non-conductive) are added when the tire is manufactured, and on the basis of certain hot-melt characteristics, the tire has stronger grip through design of patterns and drainage grooves, and also has excellent drainage performance, compared with a full-hot-melt high-performance tire, the cost performance is very high, but the problem of cracking can occur under the condition of long-time placement of the existing tire, and the running safety can be influenced by cracks even though the tire is less in abrasion.
Disclosure of Invention
(one) solving the technical problems
Aiming at the defects of the prior art, the invention provides an all-weather semi-hot melt tire formula and a process, and solves the problem of cracking.
(II) technical scheme
In order to achieve the above purpose, the invention is realized by the following technical scheme: an all-weather semi-hot melt tire formulation comprising:
rubber: 76 parts of filler: 19-20 parts of plasticizer: 2-3 parts of sulfur: 1.5 parts of accelerator: 0.5 part of TBBS and an aging agent: 2 parts of vulcanizing agent: 0.5 parts of an accelerator: 0.5 part.
Preferably, the rubber is divided into synthetic rubber and natural rubber, the synthetic rubber is butyl rubber, the ratio of the butyl rubber to the natural rubber is 8:2, the filler is 15% of carbon black and 5% of silica, the plasticizer is 6PPD and TMQ, and the plasticizer is 2-mercaptobenzothiazole, the aging agent is 6PPD, the vulcanizing agent is sulfur, the accelerator is zinc sulfate, and the chemical structure of TMQ is that:
2,2,4-Trimethyl-1,2-dihydroquinoline
the chemical structure of the 6 PPD:
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine。
3. an all-weather semi-hot melt tire process as in claim 1, wherein:
s1, preparing raw materials of the tire, and mixing the raw materials according to corresponding proportions by using a mixer to manufacture a rubber mixture;
s2, preheating the mixed rubber to about 60 ℃, setting the roller gap, speed and temperature of a rolling mill to be the required thickness, cutting by using a template to ensure the accurate size and shape of each piece, and coating an adhesive between the steel wire band layer and the textile ply;
s3, strictly controlling the temperature and the humidity of a tire building area to ensure that the rubber component is not vulcanized or aged prematurely, and ensuring the accurate alignment of all parts by using laser lamp irradiation;
s4, vulcanizing the tire, preheating a vulcanization mold to 150 ℃, and keeping the temperature to 140-160 ℃ and the pressure to 1500-3500 kPa;
s5, checking the size, appearance and uniformity of the tire by using a magnifying glass, a measuring ruler and other tools, and checking whether the gravity center of the tire is consistent with the geometric center by using a laser indicator and a sensor;
s6, checking by using X-ray equipment.
Preferably, the temperature of the mixing in S1 is between 100 ℃ and 160 ℃, and the mixing time is 5min-20min.
Preferably, the temperature in S3 is 20 ℃ to 25 ℃ and the humidity is 40% to 60%.
Preferably, the specific steps of vulcanization in S4 are:
A. putting the unvulcanized tire after the tire building into a vulcanizing mold, wherein the internal shape of the mold is matched with the shape of the final tire;
B. the mold is heated using steam or other heating medium to heat the green tire and initiate the curing reaction.
C. During vulcanization, the mold interior applies pressure to the green tire, typically between 10MPa and 20MPa, to ensure that the tire is in close fit with the mold interior and to form the desired shape and texture.
D. After the vulcanization is completed, the mold is cooled and the tire is cooled.
E. After cooling, the tire is removed from the mold.
Preferably, the maintaining time of the applied pressure in the step C is 10min-1h.
Preferably, the cooling in step D is cooling with cooling water.
(III) beneficial effects
The invention provides an all-weather semi-hot-melt tire formula and a process. The beneficial effects are as follows:
the content of the aging agent in the tire is increased to improve the oxidation resistance and ozone resistance of the tire, the durability and the crack resistance of the tire can be improved by using higher-quality raw materials and precisely adjusting the proportion of each component in the formula, and the crack resistance of the tire can be improved by adopting a low-temperature vulcanization process.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described, and it is obvious that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Embodiment one:
the embodiment of the invention provides an all-weather semi-hot-melt tire formula, which comprises rubber: 76 parts of filler: 19 parts of plasticizer: 3 parts of sulfur: 1.5 parts of accelerator: 0.5 part of TBBS and an aging agent: 2 parts of vulcanizing agent: 0.5 parts of an accelerator: 0.5 part of rubber which is divided into synthetic rubber and natural rubber, wherein butyl rubber is used as the synthetic rubber, the ratio of the butyl rubber to the natural rubber is 8:2, 15% of carbon black and 5% of silica are used as fillers, 6PPD and TMQ are used as plasticizers, one part of each of the fillers is 2-mercaptobenzothiazole, 6PPD is used as an aging agent, sulfur is used as a vulcanizing agent, zinc sulfate is used as an accelerating agent, and the chemical structure of TMQ is as follows:
2,2,4-Trimethyl-1,2-dihydroquinoline
chemical structure of 6 PPD:
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine。
an all-weather semi-hot-melt tire process comprises the following steps:
s1, preparing raw materials of the tire, and mixing the raw materials according to corresponding proportions by using a mixer to manufacture a rubber mixture, wherein the mixing temperature in S1 is 100-160 ℃, and the mixing time is 5-20 min.
S2, preheating the mixed rubber to about 60 ℃, setting the roller gap, speed and temperature of a rolling mill to be the required thickness, cutting by using a template to ensure the accurate size and shape of each piece, and coating an adhesive between the steel wire band layer and the textile ply.
S3, strictly controlling the temperature and the humidity of the tire building area to ensure that the rubber component is not vulcanized or aged prematurely, and ensuring the accurate alignment of all parts by using laser lamp irradiation.
S4, vulcanizing the tire, preheating a vulcanizing mold to 150 ℃, keeping the temperature to 140-160 ℃ and the pressure to 1500-3500 kPa, wherein the vulcanizing mold in S4 comprises the specific steps that A, the unvulcanized tire with the built tire is placed into the vulcanizing mold, the internal shape of the mold is matched with the shape of the final tire, B, steam or other heating media are used for heating the mold, thereby heating the green tire and starting the vulcanizing reaction, C, in the vulcanizing process, the pressure is applied to the green tire inside the mold, usually between 10MPa and 20MPa, so as to ensure that the tire is tightly attached to the inside of the mold and forms the required shape and texture, the maintaining time of the applied pressure is 10min-1h, D, after the vulcanizing is finished, the mold is cooled, the tire is cooled, the cooling process adopts cooling water cooling, the shape of the tire is fixed, the structural stability of the tire is improved, and E, and the tire is taken out of the mold after the cooling is finished.
S5, checking the size, appearance and uniformity of the tire by using a magnifying glass, a measuring ruler and other tools, checking whether the center of gravity of the tire is consistent with the geometric center by using a laser indicator and a sensor, wherein the temperature is 20-25 ℃ and the humidity is 40-60%, the rubber component is possibly too dry due to the too low humidity, the adhesion problem is caused, and the too high humidity can introduce excessive moisture between the components, which can cause problems in the subsequent vulcanization process.
S6, checking by using X-ray equipment.
Embodiment two:
the embodiment of the invention provides an all-weather semi-hot-melt tire formula, which comprises rubber: 76 parts of filler: 20 parts of plasticizer: 2 parts of sulfur: 1.5 parts of accelerator: 0.5 part of TBBS and an aging agent: 2 parts of vulcanizing agent: 0.5 parts of an accelerator: 0.5 part of rubber which is divided into synthetic rubber and natural rubber, wherein butyl rubber is used as the synthetic rubber, the ratio of the butyl rubber to the natural rubber is 8:2, 15% of carbon black and 5% of silica are used as fillers, 6PPD and TMQ are used as plasticizers, one part of each of the fillers is 2-mercaptobenzothiazole, 6PPD is used as an aging agent, sulfur is used as a vulcanizing agent, zinc sulfate is used as an accelerating agent, and the chemical structure of TMQ is as follows:
2,2,4-Trimethyl-1,2-dihydroquinoline
chemical structure of 6 PPD:
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine。
an all-weather semi-hot-melt tire process comprises the following steps:
s1, preparing raw materials of the tire, and mixing the raw materials according to corresponding proportions by using a mixer to manufacture a rubber mixture, wherein the mixing temperature in S1 is 100-160 ℃, and the mixing time is 5-20 min.
S2, preheating the mixed rubber to about 60 ℃, setting the roller gap, speed and temperature of a rolling mill to be the required thickness, cutting by using a template to ensure the accurate size and shape of each piece, and coating an adhesive between the steel wire band layer and the textile ply.
S3, strictly controlling the temperature and the humidity of the tire building area to ensure that the rubber component is not vulcanized or aged prematurely, and ensuring the accurate alignment of all parts by using laser lamp irradiation.
S4, vulcanizing the tire, preheating a vulcanizing mold to 150 ℃, keeping the temperature to 140-160 ℃ and the pressure to 1500-3500 kPa, wherein the vulcanizing mold in S4 comprises the specific steps that A, the unvulcanized tire with the built tire is placed into the vulcanizing mold, the internal shape of the mold is matched with the shape of the final tire, B, steam or other heating media are used for heating the mold, thereby heating the green tire and starting the vulcanizing reaction, C, in the vulcanizing process, the pressure is applied to the green tire inside the mold, usually between 10MPa and 20MPa, so as to ensure that the tire is tightly attached to the inside of the mold and forms the required shape and texture, the maintaining time of the applied pressure is 10min-1h, D, after the vulcanizing is finished, the mold is cooled, the tire is cooled, the cooling process adopts cooling water cooling, the shape of the tire is fixed, the structural stability of the tire is improved, and E, and the tire is taken out of the mold after the cooling is finished.
S5, checking the size, appearance and uniformity of the tire by using a magnifying glass, a measuring ruler and other tools, checking whether the center of gravity of the tire is consistent with the geometric center by using a laser indicator and a sensor, wherein the temperature is 20-25 ℃ and the humidity is 40-60%, the rubber component is possibly too dry due to the too low humidity, the adhesion problem is caused, and the too high humidity can introduce excessive moisture between the components, which can cause problems in the subsequent vulcanization process.
S6, checking by using X-ray equipment.
Embodiment III:
the embodiment of the invention provides an all-weather semi-hot-melt tire formula, which comprises rubber: 76 parts of filler: 19.5 parts of plasticizer: 2.5 parts of sulfur: 1.5 parts of accelerator: 0.5 part of TBBS and an aging agent: 2 parts of vulcanizing agent: 0.5 parts of an accelerator: 0.5 part of rubber which is divided into synthetic rubber and natural rubber, wherein butyl rubber is used as the synthetic rubber, the ratio of the butyl rubber to the natural rubber is 8:2, 15% of carbon black and 5% of silica are used as fillers, 6PPD and TMQ are used as plasticizers, one part of each of the fillers is 2-mercaptobenzothiazole, 6PPD is used as an aging agent, sulfur is used as a vulcanizing agent, zinc sulfate is used as an accelerating agent, and the chemical structure of TMQ is as follows:
2,2,4-Trimethyl-1,2-dihydroquinoline
chemical structure of 6 PPD:
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine。
an all-weather semi-hot-melt tire process comprises the following steps:
s1, preparing raw materials of the tire, and mixing the raw materials according to corresponding proportions by using a mixer to manufacture a rubber mixture, wherein the mixing temperature in S1 is 100-160 ℃, and the mixing time is 5-20 min.
S2, preheating the mixed rubber to about 60 ℃, setting the roller gap, speed and temperature of a rolling mill to be the required thickness, cutting by using a template to ensure the accurate size and shape of each piece, and coating an adhesive between the steel wire band layer and the textile ply.
S3, strictly controlling the temperature and the humidity of the tire building area to ensure that the rubber component is not vulcanized or aged prematurely, and ensuring the accurate alignment of all parts by using laser lamp irradiation.
S4, vulcanizing the tire, preheating a vulcanizing mold to 150 ℃, keeping the temperature to 140-160 ℃ and the pressure to 1500-3500 kPa, wherein the vulcanizing mold in S4 comprises the specific steps that A, the unvulcanized tire with the built tire is placed into the vulcanizing mold, the internal shape of the mold is matched with the shape of the final tire, B, steam or other heating media are used for heating the mold, thereby heating the green tire and starting the vulcanizing reaction, C, in the vulcanizing process, the pressure is applied to the green tire inside the mold, usually between 10MPa and 20MPa, so as to ensure that the tire is tightly attached to the inside of the mold and forms the required shape and texture, the maintaining time of the applied pressure is 10min-1h, D, after the vulcanizing is finished, the mold is cooled, the tire is cooled, the cooling process adopts cooling water cooling, the shape of the tire is fixed, the structural stability of the tire is improved, and E, and the tire is taken out of the mold after the cooling is finished.
S5, checking the size, appearance and uniformity of the tire by using a magnifying glass, a measuring ruler and other tools, checking whether the center of gravity of the tire is consistent with the geometric center by using a laser indicator and a sensor, wherein the temperature is 20-25 ℃ and the humidity is 40-60%, the rubber component is possibly too dry due to the too low humidity, the adhesion problem is caused, and the too high humidity can introduce excessive moisture between the components, which can cause problems in the subsequent vulcanization process.
S6, checking by using X-ray equipment.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. An all-weather semi-hot melt tire formulation comprising: rubber: 76 parts of filler: 19-20 parts of plasticizer: 2-3 parts of sulfur: 1.5 parts of accelerator: 0.5 part of TBBS and an aging agent: 2 parts of vulcanizing agent: 0.5 parts of an accelerator: 0.5 part.
2. An all-weather semi-hot melt tire formulation as in claim 1, wherein: the rubber is divided into synthetic rubber and natural rubber, the synthetic rubber is butyl rubber, the ratio of the butyl rubber to the natural rubber is 8:2, the filler is 15% of carbon black to 5% of silica, the plasticizer is 6PPD and TMQ, and the plasticizer is 2-mercaptobenzothiazole, the aging agent is 6PPD, the vulcanizing agent is sulfur, the accelerator is zinc sulfate, and the chemical structure of TMQ is that:
2,2,4-Trimethyl-1,2-dihydroquinoline
the chemical structure of the 6 PPD:
N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine。
3. an all-weather semi-hot melt tire process as in claim 1, wherein:
s1, preparing raw materials of the tire, and mixing the raw materials according to corresponding proportions by using a mixer to manufacture a rubber mixture;
s2, preheating the mixed rubber to about 60 ℃, setting the roller gap, speed and temperature of a rolling mill to be the required thickness, cutting by using a template to ensure the accurate size and shape of each piece, and coating an adhesive between the steel wire band layer and the textile ply;
s3, strictly controlling the temperature and the humidity of the tire building area, and ensuring the accurate alignment of all parts by using laser lamp irradiation;
s4, vulcanizing the tire, preheating a vulcanization mold to 150 ℃, and keeping the temperature to 140-160 ℃ and the pressure to 1500-3500 kPa;
s5, checking the size, appearance and uniformity of the tire by using a magnifying glass, a measuring ruler and other tools, and checking whether the gravity center of the tire is consistent with the geometric center by using a laser indicator and a sensor;
s6, checking by using X-ray equipment.
4. An all-weather semi-hot melt tire process as in claim 3, wherein: the temperature of the mixing in the step S1 is between 100 ℃ and 160 ℃, and the mixing time is 5min-20min.
5. An all-weather semi-hot melt tire process as in claim 3, wherein: the temperature in S3 is 20 ℃ to 25 ℃ and the humidity is 40% to 60%.
6. An all-weather semi-hot melt tire process as in claim 3, wherein: the specific steps of vulcanization in S4 are as follows:
A. putting the unvulcanized tire after the tire building into a vulcanizing mold, wherein the internal shape of the mold is matched with the shape of the final tire;
B. heating the mold with steam or other heating medium to heat the green tire and initiate the vulcanization reaction;
C. during the vulcanization process, the inside of the mold applies a pressure to the green tyre, typically between 10MPa and 20MPa, to ensure a tight fit of the tyre to the inside of the mold and to form the desired shape and texture;
D. after vulcanization is finished, the mold is cooled, and the tire is cooled;
E. after cooling, the tire is removed from the mold.
7. The all-weather semi-hot melt tire process of claim 6, wherein: the maintaining time of the applied pressure in the step C is 10min-1h.
8. An all-weather semi-hot melt tire process as in claim 3, wherein: the cooling in the step D adopts cooling water for cooling.
CN202311507596.XA 2023-11-14 2023-11-14 All-weather semi-hot-melt tire formula and process Pending CN117624794A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311507596.XA CN117624794A (en) 2023-11-14 2023-11-14 All-weather semi-hot-melt tire formula and process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311507596.XA CN117624794A (en) 2023-11-14 2023-11-14 All-weather semi-hot-melt tire formula and process

Publications (1)

Publication Number Publication Date
CN117624794A true CN117624794A (en) 2024-03-01

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202311507596.XA Pending CN117624794A (en) 2023-11-14 2023-11-14 All-weather semi-hot-melt tire formula and process

Country Status (1)

Country Link
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