CN117572700A - Electrochromic device, electrochromic device and electrochromic product - Google Patents

Electrochromic device, electrochromic device and electrochromic product Download PDF

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Publication number
CN117572700A
CN117572700A CN202311851223.4A CN202311851223A CN117572700A CN 117572700 A CN117572700 A CN 117572700A CN 202311851223 A CN202311851223 A CN 202311851223A CN 117572700 A CN117572700 A CN 117572700A
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China
Prior art keywords
conductive
layer
connecting piece
electrochromic
base layer
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Pending
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CN202311851223.4A
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Chinese (zh)
Inventor
谢树发
鹿存洁
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Guangyi Intelligent Technology Suzhou Co ltd
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Guangyi Intelligent Technology Suzhou Co ltd
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Priority to CN202311851223.4A priority Critical patent/CN117572700A/en
Publication of CN117572700A publication Critical patent/CN117572700A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153Constructional details
    • G02F1/161Gaskets; Spacers; Sealing of cells; Filling or closing of cells
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153Constructional details
    • G02F1/1533Constructional details structural features not otherwise provided for
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153Constructional details
    • G02F1/155Electrodes

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Abstract

The application relates to the technical field of electrochromic devices and provides an electrochromic device, an electrochromic device and an electrochromic product, wherein the electrochromic device comprises a conductive component, a first conductive substrate layer, an electrochromic layer and a second conductive substrate layer which are arranged in a lamination manner; the conductive component is arranged on the peripheral edge of at least one of the first conductive substrate layer and the second conductive substrate layer; the conductive assembly comprises a first conductive connecting piece, wherein the first conductive connecting piece comprises a conductive layer and an adhesive layer which are stacked; the bonding layer comprises an insulating part and a conductive part; the conductive layer is electrically connected with the first conductive basal layer through the conductive part, and is insulated with the second conductive basal layer through the insulating part; and/or the conductive layer is electrically connected with the second conductive basal layer through the conductive part, and the conductive layer is insulated with the first conductive basal layer through the insulating part; the conductive component has the dual functions of forming an electrode and sealing the side surface of the device, and simplifies the manufacturing procedure of the electrochromic device.

Description

Electrochromic device, electrochromic device and electrochromic product
Technical Field
The application relates to the technical field of electrochromic, and particularly provides an electrochromic device, an electrochromic device and an electrochromic product.
Background
Electrochromic phenomenon refers to reversible color change of materials under the action of an external electric field; electrochromic is essentially a phenomenon that a material undergoes oxidation-reduction reaction under the action of an external electric field and current, so that the structure of the material is changed, and further, the absorption spectrum and optical properties (such as absorptivity, transmissivity and reflectivity) are changed, and the material is expressed as reversible changes in color and transparency in appearance. In recent years, electrochromic devices are widely applied to the fields of energy-saving windows, automobile rearview mirrors, display devices, mobile terminals and the like, and have good market application prospects.
Electrochromic materials are extremely sensitive and therefore require a tight seal. In the prior art, a sealing colloid is generally arranged at the peripheral edge of the electrochromic device to prevent water vapor or other substances in the external environment from entering the inside of the electrochromic device from the side, so that the electrochromic material is damaged and the device fails. However, this requires an additional sealant, which increases the device manufacturing process and reduces the production efficiency.
Disclosure of Invention
The embodiment of the application aims to provide an electrochromic device and aims to solve the problems of more production procedures and low generation efficiency of the conventional electrochromic device.
In order to achieve the above purpose, the technical scheme adopted in the application is that,
in a first aspect, the present application provides an electrochromic device comprising: the conductive assembly comprises a first conductive substrate layer, an electrochromic layer and a second conductive substrate layer which are sequentially stacked; the conductive component is arranged on the peripheral edge of at least one of the first conductive substrate layer and the second conductive substrate layer; the conductive assembly comprises a first conductive connecting piece, wherein the first conductive connecting piece comprises a conductive layer and an adhesive layer which are stacked; the bonding layer comprises an insulating part and a conductive part; the conductive layer is electrically connected with the first conductive substrate layer through the conductive part, and is insulated with the second conductive substrate layer through the insulating part; and/or, the conductive layer is electrically connected with the second conductive substrate layer through the conductive part, and the conductive layer is insulated with the first conductive substrate layer through the insulating part.
In some embodiments, a peripheral edge of the electrochromic device is provided with a groove extending through the first conductive substrate layer and the electrochromic layer in the lamination direction, and/or the groove extends through the second conductive substrate layer and the electrochromic layer in the lamination direction of the first conductive substrate layer, the electrochromic layer, and the second conductive substrate layer; the conductive component is at least partially positioned in the groove, and two ends of the conductive component in the first direction are respectively connected with the first conductive substrate layer and the second conductive substrate layer; the first direction is perpendicular to a lamination direction of the first conductive base layer, the electrochromic layer, and the second conductive base layer.
In some embodiments, the first conductive connection member is connected to the first conductive base layer and the second conductive base layer at both ends thereof in a first direction, respectively; wherein the conductive part at least partially passes through the groove and is connected to the peripheral edge of the second conductive substrate layer, which is close to the electrochromic layer, so that the conductive layer and the second conductive substrate layer are electrically connected; and/or the conductive part passes through the groove at least partially and is connected to the peripheral edge of the first conductive substrate layer, which is close to the electrochromic layer, so that the conductive layer and the first conductive substrate layer are electrically connected.
In some embodiments, in the groove, one end of the insulating portion of the first conductive connector is connected to a peripheral edge of the first conductive base layer away from the electrochromic layer, and the other end of the insulating portion of the first conductive connector is connected to a peripheral edge of the second conductive base layer near the electrochromic layer; and/or, in the groove, one end of the insulating part of the first conductive connecting piece is connected to the peripheral edge of the second conductive basal layer far away from the electrochromic layer, and the other end of the insulating part of the first conductive connecting piece is connected to the peripheral edge of the first conductive basal layer close to the electrochromic layer.
In some embodiments, the adhesive layer of the first conductive connector includes a first conductive portion, a second conductive portion, and the insulating portion connected between the first conductive portion and the second conductive portion, which are sequentially arranged; the conductive layer is electrically connected with the second conductive substrate layer through the second conductive part, and two ends of the first conductive part in the first direction are arranged on the first conductive substrate layer; and/or the conductive layer is electrically connected with the first conductive substrate layer through the second conductive part, and two ends of the first conductive part in the first direction are arranged on the second conductive substrate layer.
In some embodiments, the conductive assembly further includes at least one second conductive connector, the first conductive connector and the second conductive connector are sequentially arranged on the peripheral edge of the first conductive substrate layer along the first direction, and the second conductive connector is electrically connected with the first conductive substrate layer; and/or the first conductive connecting piece and the second conductive connecting piece are sequentially arranged on the peripheral edge of the second conductive basal layer, and the second conductive connecting piece is electrically connected with the second conductive basal layer.
In some embodiments, the conductive assembly includes the first conductive connector and the second conductive connector at least partially stacked, and an electrical connection is formed between the first conductive connector and the second conductive connector; one end of the first conductive connecting piece far away from the second conductive connecting piece is connected to the peripheral edge of one side of the first conductive basal layer far away from the electrochromic layer along the first direction, and one end of the second conductive connecting piece far away from the first conductive connecting piece is arranged on the peripheral edge of one side of the second conductive basal layer near the electrochromic layer; and/or, along the first direction, one end of the first conductive connecting piece far away from the second conductive connecting piece is connected to the peripheral edge of one side of the second conductive basal layer far away from the electrochromic layer, and one end of the second conductive connecting piece far away from the first conductive connecting piece is arranged on the peripheral edge of one side of the first conductive basal layer near the electrochromic layer.
In some embodiments, the first conductive connection member and the second conductive connection member are spaced apart from each other, the first conductive connection member is insulated from the first conductive base layer by the insulating portion, and the second conductive connection member is electrically connected to the second conductive base layer; and/or, the first conductive connecting piece is insulated from the second conductive base layer through the insulating part, and the second conductive connecting piece is electrically connected with the first conductive base layer.
In some embodiments, the conductive assembly further comprises a sealant disposed between adjacent two of the first and second conductive connectors; and/or the conductive component comprises two or more second conductive connecting pieces, two adjacent second conductive connecting pieces are spaced, and the sealant is arranged between the two adjacent second conductive connecting pieces.
In some embodiments, in the recess, a maximum thickness of the conductive component is less than or equal to a lamination thickness of the first conductive base layer and the electrochromic layer in a lamination direction; and/or, in the groove, the maximum thickness of the conductive component is smaller than or equal to the lamination thickness of the second conductive substrate layer and the electrochromic layer in the lamination direction.
In some embodiments, outside the groove, both ends of the conductive component along the first direction are disposed on the first conductive base layer, and/or both ends of the conductive component along the first direction are disposed on the second conductive base layer.
In some embodiments, the device further comprises an extraction electrode electrically connected to the second conductive base layer through the first conductive connection and/or the second conductive connection; and/or the extraction electrode is electrically connected with the first conductive basal layer through the first conductive connecting piece and/or the second conductive connecting piece.
In some embodiments, the extraction electrode is disposed on a side of the conductive layer of the first conductive connection piece away from the adhesive layer, and the extraction electrode is electrically connected to the first conductive base layer through the conductive portion of the first conductive connection piece; and/or the extraction electrode is arranged on one side, far away from the bonding layer, of the conductive layer of the first conductive connecting piece, and the extraction electrode is electrically connected with the second conductive basal layer through the conductive part of the first conductive connecting piece.
In some embodiments, the extraction electrode is disposed on at least one side of the second conductive connection in the lamination direction, the extraction electrode being electrically connected to the first conductive base layer through the second conductive connection; and/or the extraction electrode is electrically connected with the second conductive basal layer through the second conductive connecting piece.
In a second aspect, an embodiment of the present application provides an electrochromic device, including a substrate and the electrochromic device, where the substrate is disposed on a side of the first conductive base layer facing away from the electrochromic layer; and/or the substrate is arranged on one side of the second conductive base layer, which faces away from the electrochromic layer.
In a third aspect, an embodiment of the present application provides an electrochromic product, including the electrochromic device or the electrochromic device, where the electrochromic product includes any one of a rearview mirror, a curtain wall, a sunroof, a side window of an automobile, a windshield of an automobile, a housing of an electronic product, glasses, a vehicle, and a display panel.
The beneficial effects of this application are: the first conductive connecting piece is formed by arranging a conductive layer and an adhesive layer in a laminated way, and is adhered to the peripheral edge of any side of the electrochromic device in the lamination direction through the adhesive layer, so that the arrangement is convenient and quick; the conductive layer of the first conductive connecting piece at any side can be electrically connected with the conductive base layer of the first conductive base layer or the conductive base layer of the second conductive base layer under the action of the conductive part and the insulating part; the conductive layer can form an electrode by itself or is provided with an extraction electrode thereon, so that the electrochromic device is convenient to be connected with an external power supply.
In addition, the insulating part covers the first conductive basal layer and the second conductive basal layer along the first direction at the same time, so that the first conductive connecting piece can also play a role in sealing the side surface of the electrochromic layer, water vapor or other substances in the external environment can be prevented from entering the electrochromic device from the side surface, and the reliability of the product is improved; namely, the conductive component can simultaneously play a double role of forming a device electrode and sealing the side surface of the device, so that the peripheral edge of the electrochromic device is not required to be additionally provided with a sealing colloid, the structural design is ingenious, the manufacturing procedures of the device are reduced, and the production efficiency is improved.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present application, the following description will briefly introduce the drawings that are needed in the embodiments or the description of the prior art, it is obvious that the drawings in the following description are only some embodiments of the present application, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a schematic top view of an electrochromic device according to one embodiment of the present disclosure;
FIG. 2 is a cross-sectional view of B-B of FIG. 1;
FIG. 3 is a cross-sectional view of A-A of FIG. 1;
fig. 4 is a schematic perspective view of a stacked arrangement of a first conductive base layer, an electrochromic layer and a second conductive base layer of an electrochromic device according to an embodiment of the present disclosure;
fig. 5 is a schematic perspective view of a first conductive connecting member provided in an embodiment of the present application disposed in a first groove; the bonding layer of the first conductive connecting piece comprises a first conductive part, an insulating part and a second conductive part;
fig. 6 is a schematic perspective view of a first conductive connection member of an electrochromic device according to an embodiment of the present disclosure, which is located in a groove and outside the groove;
fig. 7 is a schematic perspective view of a conductive assembly according to an embodiment of the present application, including a first conductive connecting member and a second conductive connecting member;
fig. 8 is a schematic perspective view of another arrangement of a conductive assembly according to an embodiment of the present disclosure, including a first conductive connecting member and a second conductive connecting member;
fig. 9 is a schematic perspective view of a first conductive connecting member and a second conductive connecting member according to an embodiment of the present disclosure;
fig. 10 is a schematic perspective view of a first conductive connector and a second conductive connector provided in an embodiment of the present application, where a sealant is disposed at a distance;
Fig. 11 is a schematic perspective view of a conductive assembly according to an embodiment of the present application, including 2 second conductive connectors;
FIG. 12 is a schematic view of an electrochromic device according to an embodiment of the present disclosure at another angle;
fig. 13 is a schematic structural diagram of an electrochromic device according to an embodiment of the present application.
Wherein, each reference numeral in the figures,
1000. an electrochromic device;
1. a conductive assembly;
2. a first conductive base layer; 21. a first substrate layer; 22. a first conductive base layer; 3. an electrochromic layer;
4. a second conductive base layer; 41. a second substrate layer; 42. a second conductive base layer;
5. a first conductive connection; 501 a conductive layer; 502. an adhesive layer;
5021. an insulating part; 5022. a conductive portion; 5023. a first conductive portion; 5024. a second conductive portion;
6. a groove; 601. a first groove; 602. a second groove;
7. a second conductive connection; 701. a second conductive layer; 702. a second adhesive layer;
8. an extraction electrode; 9. a seal;
2000. an electrochromic device;
2001. a substrate; 2002. a substrate adhesive layer;
x, a first direction; y; lamination direction.
Detailed Description
Embodiments of the present application are described in detail below, examples of which are illustrated in the accompanying drawings, wherein the same or similar reference numerals refer to the same or similar elements or elements having the same or similar functions throughout. The embodiments described below by referring to the drawings are exemplary and intended for the purpose of explaining the present application and are not to be construed as limiting the present application.
In the description of the present application, it should be understood that the terms "length," "width," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like indicate orientations or positional relationships based on the orientation or positional relationships shown in the drawings, merely to facilitate description of the present application and simplify the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and therefore should not be construed as limiting the present application.
Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more such feature. In the description of the present application, the meaning of "a plurality" is two or more, unless explicitly defined otherwise.
In this application, unless specifically stated and limited otherwise, the terms "mounted," "connected," "secured," and the like are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communicated with the inside of two elements or the interaction relationship of the two elements. The specific meaning of the terms in this application will be understood by those of ordinary skill in the art as the case may be.
The terms "one embodiment," "some embodiments," "examples," "specific examples," or "some examples," etc., in this application, mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present application. In this specification, schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, the different embodiments or examples described in this specification and the features of the different embodiments or examples may be combined and combined by those skilled in the art without contradiction.
Currently, electrochromic devices are widely applied to the fields of energy-saving windows, automobile rearview mirrors, display devices, mobile terminals and the like, and have good market application prospects. Electrochromic is essentially a phenomenon that a material undergoes oxidation-reduction reaction under the action of an external electric field and current, so that the structure of the material is changed, and further, the absorption spectrum and optical properties (such as absorptivity, transmissivity and reflectivity) are changed, and the material is expressed as reversible changes in color and transparency in appearance.
Electrochromic materials are extremely sensitive and therefore require a tight seal. In the prior art, a sealing colloid is generally arranged at the peripheral edge of the electrochromic device so as to prevent water vapor or other substances in the external environment from entering the inside of the electrochromic device from the side, thereby damaging the electrochromic material and disabling the device. However, this requires an additional sealant, which increases the device manufacturing process and reduces the production efficiency.
Based on the above, in order to solve the above problems, the present application designs an electrochromic device, in which a first conductive connecting member is adhered to the peripheral edge of the electrochromic device on either side in the stacking direction through an adhesive layer, and the layout is convenient and quick; the conducting layer of the first conducting connecting piece at any side can be electrically connected with the first conducting base layer of the first conducting base layer or the second conducting base layer of the second conducting base layer only under the action of the insulating part and the conducting part, so that the conducting layer can form an electrode, and the electrochromic device is convenient to be connected with an external power supply. Meanwhile, the insulating part covers the first conductive basal layer and the second conductive basal layer along the first direction, so that the first conductive connecting piece can also play a role in sealing the side face of the electrochromic layer, water vapor or other substances in the external environment can be prevented from entering the electrochromic device from the side face, and the reliability of the product is improved; namely, the conductive component can simultaneously play a double role of forming a device electrode and sealing the side surface of the device, and then sealing colloid is not required to be additionally arranged on the peripheral edge of the electrochromic device, so that the structural design is ingenious, the manufacturing procedures of the device are reduced, and the production efficiency is improved.
Referring to fig. 1, 2 and 3, an electrochromic device 1000 according to a first aspect of the present embodiment includes a conductive component 1, and a first conductive base layer 2, an electrochromic layer 3 and a second conductive base layer 4 that are sequentially stacked; the conductive component 1 is arranged on the peripheral edge of at least one of the first conductive base layer 2 and the second conductive base layer 4; the conductive assembly 1 includes a first conductive connector 5, and the first conductive connector 5 includes a conductive layer 501 and an adhesive layer 502 which are stacked; the adhesive layer 502 includes an insulating portion 5021 and a conductive portion 5022, the conductive layer 501 is electrically connected with the first conductive base layer 2 through the conductive portion 5022, and the conductive layer 501 is insulated from the second conductive base layer 4 through the insulating portion 5021; and/or, the conductive layer 501 is electrically connected to the second conductive base layer 4 through the conductive portion 5022, and the conductive layer 501 is insulated from the first conductive base layer 2 through the insulating portion 5021.
As can be appreciated, fig. 1 is a top view of an electrochromic device 1000 according to an embodiment of the present application, in a stacking direction Y of the first conductive base layer 2, the electrochromic layer 3, and the second conductive base layer 4, an overlapping area of the first conductive base layer 2 and the second conductive base layer 4 is covered on the electrochromic layer 3, so that the electrochromic layer 3 is not exposed outside the electrochromic device 1000, and effective protection is formed on the electrochromic layer 3.
The electrochromic layer 3 is made of electrochromic materials, and can generate stable and reversible color change under the action of an external electric field. The Electrochromic layer 3 is a sheet of one or more layers of material in gel or solid state, such as a polymer dispersed liquid crystal (Polymer Dispersed Liquid Crystal, PDLC) layer, suspended particle layer (SuspendedParticle Device, SPD) and Electrochromic (EC) types. For Electrochromic (EC) type Electrochromic layer 3, it may comprise a layer of Electrochromic material, an electrolyte layer and an ion storage layer, which are stacked in sequence. The materials of the color-changing material layer, the electrolyte layer and the ion storage layer may be materials in the prior art, which are not particularly limited in this application.
In some embodiments, referring to fig. 4, the first conductive base layer 2 includes a first base layer 21 stacked and a first conductive base layer 22 provided on a surface of the first base layer 21; the second conductive base layers 4 include second base layers 41 stacked and arranged, respectively, and second conductive base layers 42 provided on the surfaces of the second base layers 41; the first substrate layer 21 of the first conductive substrate layer 2 is arranged on one side of the first conductive substrate layer 22 away from the electrochromic layer 3; or the second base layer 41 of the second conductive base layer 4 is arranged on the side of the second conductive base layer 42 remote from the electrochromic layer 3.
Preferably, the first substrate layer 21 and the second conductive substrate layer 4 are transparent flexible substrates, which have light transmittance, such as polyethylene terephthalate (polyethylene glycol terephthalate, PET), polycarbonate (polycarbonate, PC), and the like, and may be provided as glass substrates; the first conductive base layer 22 and the second conductive base layer 42 are formed of indium-tin oxide (ITO), zinc-aluminum oxide (aluminum zinc oxide, AZO), fluorine doped tin oxide (fluorine doped tinoxide, FTO), and the first conductive base layer 22 and the second conductive base layer 42 are preferably formed of ITO; the first conductive base layer 2 and the second conductive base layer 4 have good conductivity and light transmission performance.
Referring to fig. 2 and 3, at the peripheral edge of the electrochromic device 1000, a portion that does not overlap in the lamination direction Y is formed between the first conductive base layer 2 and the second conductive base layer 4; the conductive element 1 can be provided on the first conductive base layer 22 of the first conductive base layer 2 to enable an electrical connection with the first conductive base layer 2 and/or the conductive element 1 can be provided on the second conductive base layer 42 of the second conductive base layer 4 to enable an electrical connection with the second conductive base layer 4.
Specifically, fig. 2 is a cross-sectional view of the electrochromic device 1000 in fig. 1 in the B-B direction, the conductive assembly 1 includes a first conductive connector 5, the first conductive connector 5 includes a conductive layer 501 and an adhesive layer 502 that are stacked, the conductive layer 501 has conductivity, and the conductive layer 501 is made of, but not limited to, a conductive material such as copper foil, silver wire, conductive resin, etc.; the bonding layer 502 has adhesiveness, and the conductive layer 501 and the bonding layer 502 are laminated and connected to form an integrated structure; the conductive layer 501 and the adhesive layer 502 are both composite layers with good ductility, and the specific layer number structure is not limited herein; the first conductive connecting piece 5 can be quickly adhered and arranged on the first conductive substrate layer 2 or the second conductive substrate layer 4 through the adhesive layer 502, so that the first conductive connecting piece 5 is conveniently and quickly arranged.
The adhesive layer 502 further includes an insulating portion 5021 and a conductive portion 5022 that are arranged along a first direction X, which is a direction X shown in the drawing, and which is perpendicular to the stacking direction Y. The insulating portion 5021 has adhesion and insulation, and the material of the insulating portion 5021 includes a colloid which is conventional in the art and has an insulating and water-oxygen isolating effect. The conductive portion 5022 has conductivity, and the conductive portion 5022 is formed using conductive paste or conductive resin, preferably conductive paste, and the conductive portion 5022 is stacked and connected with the conductive layer 501 to form conduction therebetween.
Fig. 3 is a cross-sectional view of the electrochromic device 1000 of fig. 1 in the A-A direction, in some embodiments, the electrochromic device 1000 is provided with first conductive connectors 5 on both sides in the stacking direction Y, wherein the first conductive connectors 5 on one side are provided on the peripheral edge of the first conductive base layer 2 and form an electrical connection with the second conductive base layer 4 so as to be able to serve as the positive electrode or the negative electrode of the electrochromic device 1000; the first conductive connecting piece 5 on the other side is arranged at the peripheral edge of the second conductive basal layer 4 and is electrically connected with the first conductive basal layer 2 so as to be used as a negative electrode or a positive electrode of the electrochromic device 1000, and the two electrodes are used for being electrically connected with an external power supply, so that voltage or current is provided for the electrochromic layer. The electrochromic device 1000 can then be used to introduce a current or a voltage to the first conductive base layer 22 of the first conductive base layer 2 and the second conductive base layer 42 of the second conductive base layer 4 by respectively communicating the conductive assemblies 1 on both sides in the stacking direction Y with an external power source, that is, to form an electric field on both sides of the electrochromic layer 3, so as to drive the electrochromic layer 3 to generate a coloring or fading phenomenon, so that the electrochromic device 1000 shows a change in transmittance in appearance, and an effect of adjusting the transmittance of a scene to which the electrochromic device 1000 is applied is realized.
Specifically, referring to fig. 2, the conductive layer 501 can form an electrical connection with the first conductive base layer 22 of the first conductive base layer 2 through the conductive portion 5022, and the conductive layer 501 is simultaneously insulated from the second conductive base layer 42 of the second conductive base layer 4 through the insulating portion 5021. The conductive layer 501 can also be electrically connected to the second conductive base layer 42 of the second conductive base layer 4 by the conductive portion 5022, and the conductive layer 501 is insulated from the first conductive base layer 22 of the first conductive base layer 2 by the insulating portion 5021. Namely, the insulation part 5021 is used for isolating the conductive layer 501 from the first conductive base layer 22 of the first conductive base layer 2 or the second conductive base layer 42 of the second conductive base layer 4, so that the conductive layer 501 of the single first conductive connector 5 is prevented from being electrically connected with the first conductive base layer 2 and the second conductive base layer 4 at the same time, a short circuit phenomenon is caused, and the stability of the electrochromic device 1000 is ensured.
As can be appreciated, referring to fig. 2, in order to achieve a good insulating effect, the insulating portion 5021 covers both the first and second conductive base layers 2 and 4 in the first direction; the insulating part 5021 can also form effective sealing to the side of the electrochromic layer 3 in the first direction X, so that water vapor of the external environment can be prevented from entering the electrochromic device 1000 from the side, damage to electrochromic materials and device failure are avoided, and product reliability is improved. Therefore, the conductive component 1 can not only play a role of connecting the electrochromic device 1000 with an external power supply, but also play a dual role of forming a good sealing effect on the side surface of the electrochromic device 1000; and thus there is no need to additionally provide a sealing compound at the peripheral edge of the electrochromic device 1000.
According to the electrochromic device, the first conductive connecting piece 5 is formed by laminating the conductive layer 501 and the bonding layer 502, the first conductive connecting piece 5 is bonded on the peripheral edge of any side of the electrochromic device 1000 in the lamination direction through the bonding layer 502, and the arrangement is convenient and quick; the conductive layer 501 of the first conductive connection piece 5 at any side can be electrically connected with only the first conductive base layer 22 of the first conductive base layer 2 or the second conductive base layer 42 of the second conductive base layer 4 under the action of the conductive portion 5022 and the insulating portion 5021; enabling the conductive layer 501 to form an electrode itself or to provide an extraction electrode 8 thereon facilitates the connection of the electrochromic device 1000 to an external power source.
In addition, the insulating part 5021 simultaneously covers the first conductive basal layer 2 and the second conductive basal layer 4 along the first direction, so that the first conductive connecting piece 5 can also play a role in sealing the side surface of the electrochromic layer 3, water vapor of the external environment can be prevented from entering the electrochromic device 1000 from the side surface, and the reliability of a product is improved; namely, the conductive component 1 can simultaneously play a double role of forming a device electrode and sealing the side surface of the device, so that the peripheral edge of the electrochromic device 1000 does not need to be additionally provided with a sealing colloid, the structural design is ingenious, the manufacturing procedures of the device are reduced, and the production efficiency is improved.
Referring to fig. 1-4, in some embodiments, the peripheral edge of electrochromic device 1000 is provided with a groove 6, groove 6 extending through first conductive base layer 2 and electrochromic layer 3 in lamination direction Y, and/or groove 6 extending through second conductive base layer 4 and electrochromic layer 3 in lamination direction Y; the conductive element 1 is at least partially located in the recess 6, and both ends of the conductive element 1 in the first direction X are connected to the first conductive base layer 2 and the second conductive base layer 4, respectively.
Specifically, referring to fig. 1, 3, and 4, a plurality of grooves 6 are alternately provided at intervals at the peripheral edge of the electrochromic device 1000, and the grooves 6 include first grooves 601 penetrating the first conductive base layer 2 and the electrochromic layer 3 in the lamination direction Y; and a second groove 602 penetrating the second conductive base layer 4 and the electrochromic layer 3 in the lamination direction Y. The number of the first grooves 601 and the number of the second grooves 602 are plural, and may be any number greater than two, and may be specifically set according to practical situations.
The electrochromic device 1000 is provided with conductive elements 1 on both sides in the stacking direction Y, wherein the conductive elements 1 on one side are at least partially connected electrically with the second conductive base layer 42 in the second conductive base layer 4 through a plurality of first grooves 601; the conductive member 1 on the other side is at least partially electrically connected to the first conductive base layer 22 in the first conductive base layer 2 through the plurality of second grooves 602, thereby enabling to alternately form a multi-electrode structure at the peripheral edge of the electrochromic device 1000, and accelerating the color change speed of the electrochromic device 1000.
Here, the number and arrangement positions of the first grooves 601 and the second grooves 602 are not limited.
For example, referring to fig. 1, 2, both ends of the electrochromic device 1000 in the first direction X can be formed with grooves 6 in the cross-sectional view of fig. 2. Alternatively, referring to fig. 5, the electrochromic device 1000 may be formed with a groove 6 at only one end in the first direction X in the cross-sectional view of fig. 5.
Specifically, two ends of the conductive component 1 in the first direction X are respectively connected with the first conductive base layer 2 and the second conductive base layer 4, where two ends of the conductive component 1 are two ends of the conductive component 1 as a whole, so as to ensure that the conductive component 1 can form a seal with the electrochromic layer 3.
For example, referring to fig. 2, the conductive assembly 1 may include only the first conductive connection member 5, and both ends of the conductive assembly 1 are both ends of the first conductive connection member 5, and both ends of the first conductive connection member 5 are connected with the first conductive base layer 2 and the second conductive base layer 4, respectively, such that the first conductive connection member 5 can form an effective seal against the side surface of the electrochromic layer 3.
Alternatively, referring to fig. 7, 8 and 11, the conductive assembly 1 may further include one or more second conductive connectors 7 arranged in sequence along the first direction X in addition to the first conductive connector 5. When the conductive component 1 comprises a first conductive connecting piece 5 and a second conductive connecting piece 7, one end of the whole conductive component 1 is one end of the first conductive connecting piece 5, which is close to the electrochromic layer 3, and the other end of the conductive component 1 is one end of the second conductive connecting piece 7, which is far away from the electrochromic layer 3; the conductive assembly 1 as a whole is able to form an effective seal against the sides of the electrochromic layer 3.
In some embodiments, referring to fig. 2 and 5, the first conductive connection member 5 is connected to the first conductive base layer 2 and the second conductive base layer 4 at both ends thereof in the first direction X, respectively; wherein,
the conductive portion 5022 of the first conductive connector 5 in the first groove 601 passes through the first groove 601 and is connected to the peripheral edge of the second conductive base layer 4 near the electrochromic layer 3, so that the conductive layer 501 and the second conductive base layer 4 are electrically connected; and/or the number of the groups of groups,
the conductive portion 5022 of the first conductive connector 5 in the second groove 602 passes through the second groove 602 and is connected to the first conductive base layer 2 near the peripheral edge of the electrochromic layer 3, so that the conductive layer 501 is electrically connected with the first conductive base layer 2.
Specifically, when the first conductive connection member 5 is disposed, the conductive portion 5022 needs to be connected to the first conductive base layer 22 of the first conductive base layer 2 or the second conductive base layer 42 of the second conductive base layer 4 to ensure that the conductive layer 501 is electrically connected to the first conductive base layer 2 or the second conductive base layer 4 through the conductive portion 5022.
Here, the number of the conductive portions 5022 is not limited, and the adhesive layer 502 may have only one conductive portion 5022, or the adhesive layer 502 may have a plurality of conductive portions 5022; so that the conductive layer 501 can be electrically connected to the first conductive base layer 2 or the second conductive base layer 4 through one or more conductive portions 5022.
In some embodiments, referring to fig. 2, 7, and 8, in the first groove 601, one end of the insulating portion 5021 of the first conductive connector 5 is connected to the peripheral edge of the first conductive base layer 2 away from the electrochromic layer 3, and the other end of the insulating portion 5021 of the first conductive connector 5 is connected to the peripheral edge of the second conductive base layer 4 near the electrochromic layer 3; and/or the number of the groups of groups,
in the second groove 602, one end of the insulating portion 5021 of the first conductive connecting piece 5 is connected to the peripheral edge of the second conductive base layer 4 away from the electrochromic layer 3, and the other end of the insulating portion 5021 of the first conductive connecting piece 5 is connected to the peripheral edge of the first conductive base layer 2 near the electrochromic layer 3.
As can be appreciated, in the first groove 601, the insulating portion 5021 can isolate the conductive layer 501 from the first conductive base layer 22 of the first conductive base layer 2, so that the conductive layer 501 is electrically connected only to the second conductive base layer 42 of the second conductive base layer 4. In the second groove 602, the insulating portion 5021 can isolate the conductive layer 501 from the second conductive base layer 42 of the second conductive base layer 4, so that the conductive layer 501 is electrically connected only to the first conductive base layer 22 of the first conductive base layer 2; the first conductive base layer 22 and the second conductive base layer 42 are prevented from being in contact with each other to generate a short circuit, so that the stability of the electrochromic device 1000 is ensured.
The insulating portion 5021 covers the first conductive substrate layer 2 and the second conductive substrate layer 4 in the first groove 601 and the second groove 602 at the same time, that is, the insulating portion 5021 can form a seal on the side surface of the electrochromic layer 3 in the first direction X, so that water vapor of external environment is prevented from entering the electrochromic device 1000 from the side surface, and the service life of a product is prolonged.
Referring to fig. 5, in some embodiments, the adhesive layer 502 of the first conductive connector 5 includes a first conductive portion 5023, a second conductive portion 5024, and an insulating portion 5021 connected between the first conductive portion 5023 and the second conductive portion 5024, which are sequentially arranged; wherein,
the conductive layer 501 is electrically connected with the second conductive base layer 4 through the second conductive portion 5024, and two ends of the first conductive portion 5023 in the first direction X are disposed on the first conductive base layer 2; and/or the number of the groups of groups,
the conductive layer 501 is electrically connected to the first conductive base layer 2 through the second conductive portion 5024, and both ends of the first conductive portion 5023 in the first direction X are disposed on the second conductive base layer 4.
Specifically, in some embodiments, in the first groove 601, both ends of the second conductive portion 5024 are connected to the peripheral edge of the side of the second conductive base layer 4 near the electrochromic layer 3, and both ends of the first conductive portion 5023 are connected to the peripheral edge of the side of the first conductive base layer 2 far from the electrochromic layer 3; namely, the conductive layer 501 is electrically connected to the second conductive base layer 4 only through the second conductive portion 5024; at this time, the first conductive portion 5023 does not serve as an electrical connection and only serves as an adhesive.
In other embodiments, in the second groove 602, both ends of the second conductive portion 5024 are connected to the peripheral edge of the side of the first conductive substrate layer 2 near the electrochromic layer 3, and both ends of the first conductive portion 5023 are connected to the peripheral edge of the side of the second conductive substrate layer 4 far from the electrochromic layer 3; namely, the conductive layer 501 is electrically connected with the first conductive base layer 2 only through the second conductive portion 5024; at this time, the first conductive portion 5023 does not serve as an electrical connection and only serves as an adhesive.
In some embodiments, referring to fig. 2, in the first groove 601, the first conductive connection 5 partially covers the first conductive base layer 2, and the width of the portion of the first conductive connection 5 covering the first conductive base layer 2 ranges from 0 to 1 mm. The width of the portion of the first conductive connecting member 5 covering the first conductive base layer 2 is the length of the first conductive connecting member 5 in the first direction X. By providing the first conductive connection 5 to partially cover the edge of the first conductive base layer 2, the first conductive connection 5 has good connectivity with the first conductive base layer 2, so as to avoid that the first conductive connection 5 is separated or even separated from the surface of the first conductive base layer 2 due to larger stress on the portion of the first conductive connection 5 covered on the first conductive base layer 2 when the electrochromic device 1000 is pressed, because the thickness of the peripheral edge of the first conductive base layer 2 is larger.
In other embodiments, in the second groove 602, the first conductive connection member 5 partially covers the second conductive base layer 4, and the width of the portion of the first conductive connection member 5 covering the second conductive base layer 4 ranges from 0 to 1 mm. The width of the portion of the first conductive connecting member 5 covering the second conductive base layer 4 is the length of the first conductive connecting member 5 in the first direction X. By providing the first conductive connection 5 to partially cover the edge of the second conductive base layer 4, the first conductive connection 5 has good connectivity with the second conductive base layer 4, so as to avoid that the first conductive connection 5 is separated or even separated from the surface of the second conductive base layer 4 due to the larger stress on the portion of the first conductive connection 5 covering the second conductive base layer 4 due to the larger thickness at the peripheral edge of the second conductive base layer 4 when the electrochromic device 1000 is pressed.
In some embodiments, the first conductive connecting piece 5 is formed by stacking the conductive layer 501 and the adhesive layer 502, the adhesive layer 502 is formed by pre-forming conductive glue, and then the insulating part 5021 is formed by disposing partial conductive glue and filling insulating glue, so that the manufacturing is more convenient;
In other embodiments, the first conductive connecting piece 5 is formed by laminating the conductive layer 501 and the adhesive layer 502, and the adhesive layer 502 is formed by pre-forming conductive adhesive, and then an insulating adhesive is further disposed on a part of the conductive adhesive to form the insulating portion 5021.
Therefore, the first conductive portion 5023 and the second conductive portion 5024 are correspondingly formed on two sides of the insulating portion 5021, and do not affect the conduction and sealing effect of the first conductive connector 5.
Referring to fig. 8-11, in some embodiments, the conductive assembly 1 further includes at least one second conductive connecting member 7, wherein the first conductive connecting member 5 and the second conductive connecting member 7 are sequentially arranged on the peripheral edge of the first conductive base layer 2 along the first direction X, and the second conductive connecting member 7 is electrically connected to the first conductive base layer 2; and/or the number of the groups of groups,
in other embodiments, the first conductive connecting piece 5 and the second conductive connecting piece 7 are sequentially arranged on the peripheral edge of the second conductive base layer 4, and the second conductive connecting piece 7 is electrically connected with the second conductive base layer 4.
As can be understood, referring to fig. 12, the peripheral edge of the electrochromic device 1000 has an irregular structure, and at the irregular edge, the first conductive base layer 2, the electrochromic layer 3 and the second conductive base layer 4 all have irregular shapes, so when the conductive component 1 is disposed at the structure, if only one first conductive connecting piece 5 is used for bonding, the width of the first conductive connecting piece 5 needs to be designed to be wider, and the phenomenon that the conductive component 1 generates wrinkles during attachment easily occurs, resulting in local uneven product. Therefore, in the case where the width of the portion to be bonded of the peripheral edge of the electrochromic device 1000 is the same, by providing the first conductive connecting member 5 in combination with one or more second conductive connecting members 7, the widths of the first conductive connecting member 5 and the second conductive connecting member 7 are necessarily both smaller than the width when only one first conductive connecting member 5 is provided, and the width of the first conductive connecting member 5 is the length of the first conductive connecting member 5 in the first direction X; the first conductive connecting piece 5 and the second conductive connecting piece 7 are easy to attach, the operation difficulty is reduced, and the peripheral edge of the electrochromic device 1000 is smoother. Here, the width of the first conductive connection 5 and the width of the second conductive connection 7 are the lengths of the first conductive connection 5 in the first direction X.
In some embodiments, referring to fig. 7 and 8, in the first groove 601, the length of the portion of the second conductive base layer 4 that extends outward beyond the electrochromic layer 3 in the first direction X ranges from 2 to 10 millimeters. By arranging the first conductive connecting piece 5 and the second conductive connecting piece 7 to cover the peripheral edge of the second conductive basal layer 4, the first conductive connecting piece 5 and the second conductive connecting piece 7 are easy to attach, wrinkling of the first conductive connecting piece 5 or the second conductive connecting piece 7 is avoided, and the peripheral edge of the electrochromic device 1000 is smoother.
In the second groove 602, the length of the portion of the first conductive base layer 2 that extends outward in the first direction X beyond the electrochromic layer 3 ranges from 2 to 10 millimeters. By arranging the first conductive connecting piece 5 and the second conductive connecting piece 7 to cover the peripheral edge of the first conductive basal layer 2, the first conductive connecting piece 5 and the second conductive connecting piece 7 can be easily attached, the first conductive connecting piece 5 or the second conductive connecting piece 7 is prevented from wrinkling, and the peripheral edge of the first electrochromic device 1000 is smoother.
Specifically, the second conductive connection member 7 has a double-layer structure, and the second conductive connection member 7 includes a second conductive layer 701 and a second adhesive layer 702 that are stacked; and here, the second adhesive layer 702 may have conductivity as a whole; alternatively, the second adhesive layer 702 may be partially insulating and partially conductive, so that the second conductive connection member 7 can be electrically connected to the first conductive base layer 2 or the second conductive base layer 4.
Referring to fig. 7 and 8, in some embodiments, the conductive assembly 1 includes a first conductive connector 5 and a second conductive connector 7 that are at least partially stacked, with an electrical connection being formed between the first conductive connector 5 and the second conductive connector 7; wherein,
along the first direction X, one end of the first conductive connecting piece 5, which is far away from the second conductive connecting piece 7, is connected to the peripheral edge of the first conductive base layer 2, which is far away from the electrochromic layer 3, and one end of the second conductive connecting piece 7, which is far away from the first conductive connecting piece 5, is arranged on the peripheral edge of the second conductive base layer 4, which is near to the electrochromic layer 3; and/or the number of the groups of groups,
along the first direction X, an end of the first conductive connecting piece 5 away from the second conductive connecting piece 7 is connected to a peripheral edge of the second conductive base layer 4 on a side away from the electrochromic layer 3, and an end of the second conductive connecting piece 7 away from the first conductive connecting piece 5 is disposed on a peripheral edge of the first conductive base layer 2 on a side close to the electrochromic layer 3.
In some embodiments, the second adhesive layer 702 of the second conductive connecting member 7 is made of conductive adhesive, and referring to fig. 7 and 8, adjacent first conductive connecting members 5 and second conductive connecting members 7 are stacked and connected, so that the first conductive connecting members 5 and the second conductive connecting members 7 form electrical conduction, and it is more convenient to arrange the extraction electrode 8 on any one of the first conductive connecting members 5 and the second conductive connecting members 7. The first conductive connecting piece 5 and the second conductive connecting piece 7 are connected in a laminated mode, and the bonding stability of the first conductive connecting piece 5 and the second conductive connecting piece 7 can be improved.
The specific lamination arrangement manner of the first conductive connection member 5 and the second conductive connection member 7 is not limited, and referring to fig. 7, for example, the first conductive connection member 5 may be first arranged, and then one end of the second conductive connection member 7 is laminated and bonded on the conductive layer 501 of the first conductive connection member 5; alternatively, referring to fig. 8, the second conductive connector 7 may be provided first, and then one end of the first conductive connector 5 may be laminated and bonded to the second conductive connector 7.
Referring to fig. 11, in some embodiments, the conductive assembly 1 may further include 2 or more sequentially disposed second conductive connectors 7, the first conductive connector 5 and the plurality of second conductive connectors 7 are sequentially disposed along the first direction X at the peripheral edge of the electrochromic device 1000, and the first conductive connector 5 and the plurality of second conductive connectors 7 are sequentially stacked and connected.
As can be appreciated, the conductive component 1 is provided with the plurality of second conductive connectors 7, so that the length of the conductive component 1 in the first direction X can be longer to be laid, the conductive area formed is larger, and the color changing speed of the electrochromic device 1000 can be accelerated.
Referring to fig. 9, 10, in some embodiments, adjacent first conductive connection 5 and second conductive connection 7 are spaced apart,
In the first groove 601, the first conductive connection piece 5 forms insulation with the first conductive base layer 2 through the insulation part 5021, and the second conductive connection piece 7 forms electrical connection with the second conductive base layer 4; and/or the number of the groups of groups,
in the second groove 602, the first conductive connection member 5 is insulated from the second conductive base layer 4 by the insulation portion 5021, and the second conductive connection member 7 is electrically connected to the first conductive base layer 2.
Specifically, in some embodiments, the first conductive connecting element 5 may be spaced from the second conductive connecting element 7, and the second conductive connecting element 7 alone forms an electrical connection with the first conductive base layer 2 or the second conductive base layer 4, so that the first conductive connecting element 5 and the second conductive connecting element 7 do not interfere with each other when they are connected to the electrochromic device 1000, and the conductive assembly 1 is more convenient to be arranged. Referring to fig. 11, in some embodiments, the conductive assembly 1 further includes a sealing member 9, and the sealing member 9 is disposed between two adjacent first conductive connecting members 5 and the second conductive connecting member 7. And/or the number of the groups of groups,
the conductive component 1 comprises two or more second conductive connecting pieces 7, wherein two adjacent second conductive connecting pieces 7 are spaced, and a sealing piece 9 is arranged between the two adjacent second conductive connecting pieces 7.
It can be understood that, when the adjacent first conductive connecting piece 5 and the adjacent second conductive connecting pieces 7 are spaced apart from each other, in order to improve the connection stability and the tightness of the conductive assembly 1, the sealing member 9 is disposed at the spacing between the adjacent first conductive connecting piece 5 and the adjacent second conductive connecting piece 7, and at the spacing between the adjacent two second conductive connecting pieces 7, so as to ensure that the bonding structure of the conductive assembly 1 is stable.
Referring to fig. 7-11, in some embodiments, in the first groove 601, the maximum thickness of the conductive assembly 1 is less than or equal to the lamination thickness of the first conductive base layer 2 and the electrochromic layer 3 in the lamination direction Y; and/or the number of the groups of groups,
in the second groove 602, the maximum thickness of the conductive member 1 is smaller than or equal to the lamination thickness of the second conductive base layer 4 and the electrochromic layer 3 in the lamination direction Y.
Specifically, the thickness of the conductive component 1 is the maximum thickness of the whole conductive component 1, and may be only the thickness of the first conductive connecting member 5; it may be the maximum lamination thickness of the two first conductive connectors 5 and the second conductive connectors 7 laminated; or, the maximum lamination thickness of the two laminated second conductive connectors 7; the maximum thickness is not limited herein.
Since the electrochromic device 1000 subsequently needs to perform a lamination operation on the product, in the first groove 601, the conductive assembly 1 as a whole is not higher than the first conductive base layer 2 in the lamination direction Y; in the second groove 602, the conductive member 1 as a whole is not higher than the second conductive base layer 4 in the lamination direction Y; the stress to which the conductive member 1 in the first recess 601 or the second recess 602 is subjected can be not excessively high, and structural stability can be improved.
Referring to fig. 3 and 6, in some embodiments, both ends of the conductive member 1 in the first direction X are disposed on the first conductive base layer 2 outside the first groove 601, and/or both ends of the conductive member 1 in the first direction X are disposed on the second conductive base layer 4 outside the first groove 601.
As can be appreciated, the peripheral edges of the electrochromic device 1000 on both sides in the stacking direction Y are respectively surrounded with the conductive assemblies 1, wherein the conductive assemblies 1 on one side are partially located in the first groove 601 and partially located outside the first groove 601; the two ends of the conductive component 1 positioned in the first groove 601 simultaneously cover the first conductive substrate layer 2 and the second conductive substrate layer 4, and the two ends of the conductive component 1 positioned outside the first groove 601 are both arranged at the peripheral edge of one side of the first conductive substrate layer 2 away from the electrochromic layer 3; here, the two ends of the conductive component 1 are two ends of the conductive component 1 in the first direction X.
The other side of the conductive component 1 is partially positioned in the second groove 602 and partially positioned outside the second groove 602; the two ends of the conductive component 1 positioned in the second groove 602 simultaneously cover the first conductive substrate layer 2 and the second conductive substrate layer 4, and the two ends of the conductive component 1 positioned outside the second groove 602 are both arranged at the peripheral edge of one side of the second conductive substrate layer 4 away from the electrochromic layer 3; here, the two ends of the conductive component 1 are two ends of the conductive component 1 in the first direction X.
Referring to fig. 7-11, in some embodiments, the device further comprises an extraction electrode 8, the extraction electrode 8 being electrically connected to the second conductive base layer 4 by the first conductive connection 5 and/or the second conductive connection 7; and/or the number of the groups of groups,
the extraction electrode 8 is electrically connected to the first conductive base layer 2 via the first conductive connection 5 and/or the second conductive connection 7.
It will be appreciated that by providing the extraction electrode 8 on the first conductive connection 5 and/or the second conductive connection 7, the electrochromic device 1000 can be conveniently connected to an external power source.
In some embodiments, referring to fig. 6 and 8, the extraction electrode 8 may be disposed only on the conductive layer 501 of the first conductive connection 5, the extraction electrode 8 being electrically connected to the first conductive base layer 2 through the first conductive connection 5, or the extraction electrode 8 being electrically connected to the second conductive base layer 4 through the first conductive connection 5.
In other embodiments, referring to fig. 7, 8 and 10, the extraction electrode 8 may be disposed only on the second conductive layer 701 of the second conductive connection member 7, where the extraction electrode 8 is electrically connected to the first conductive base layer 2 through the second conductive connection member 7, or where the extraction electrode 8 is electrically connected to the second conductive base layer 4 through the second conductive connection member 7.
In other embodiments, referring to fig. 11, the extraction electrode 8 may be disposed only under the second adhesive layer 702 of the second conductive connecting member 7, so as to avoid the extraction electrode 8 from falling off from the first conductive base layer 2 or the second conductive base layer 4, and further improve the connection stability of the extraction electrode 8.
In still other embodiments, referring to fig. 9, the extraction electrode 8 may also cover both the first conductive connection 5 and the second conductive connection 7.
As can be appreciated, the extraction electrode 8 is provided on the conductive member 1 on the side of the electrochromic device 1000 in the lamination direction Y to form an electrical connection with the second conductive base layer 4;
in other embodiments, an extraction electrode 8 is provided on the conductive assembly 1 on the other side of the electrochromic device 1000 in the lamination direction Y to form an electrical connection with the first conductive base layer 2;
in the above embodiment, the extraction electrodes 8 located at both sides of the stacking direction Y of the electrochromic device are respectively used as the positive electrode or the negative electrode of the electrochromic device 1000, and are electrically connected to an external power source through the extraction electrodes 8 at both sides, thereby realizing the voltage supply to the electrochromic layer. And the extraction electrodes 8 on two sides are always spaced in the stacking direction Y, so that the phenomenon that the electrochromic device 1000 is short-circuited due to the contact of the extraction electrodes 8 on two sides is avoided, and the stability of the electrochromic device 1000 is improved.
In some embodiments, when the extraction electrode 8 is disposed on the first conductive connection member 5, the extraction electrode 8 is disposed on a side of the conductive layer 501 of the first conductive connection member 5 away from the adhesive layer 502, and the extraction electrode 8 is electrically connected to the first conductive base layer 2 through the conductive portion 5022 of the first conductive connection member 5; and/or the number of the groups of groups,
the extraction electrode 8 is disposed on a side of the conductive layer 501 of the first conductive connection member 5 away from the adhesive layer 502, and the extraction electrode 8 is electrically connected to the second conductive base layer 4 through the conductive portion 5022 of the first conductive connection member 5.
It will be appreciated that the extraction electrode 8 needs to be disposed on the side of the conductive layer 501 away from the adhesive layer 502, and cannot be disposed on the side of the conductive layer 501 close to the adhesive layer 502, so as to avoid affecting the connection stability between the first conductive connecting piece 5 and the first conductive base layer 2 or the second conductive base layer 4, and ensure that the first conductive connecting piece 5 can form an effective seal against the side surface of the electrochromic layer 3.
In some embodiments, referring to fig. 7, the extraction electrode 8 is disposed on at least one side of the second conductive connection 7 in the lamination direction Y; the extraction electrode 8 is electrically connected with the first conductive basal layer 2 through the second conductive connecting piece 7; and/or the extraction electrode 8 is electrically connected with the second conductive base layer 4 through the second conductive connection 7.
In some embodiments, referring to fig. 10, in the first groove 601, the extraction electrode 8 may be disposed at a side of the second conductive connection 7 remote from the second conductive base layer 4; and/or, referring to fig. 11, the extraction electrode 8 may be disposed at a side of the second conductive connection 7 near the first conductive base layer 2.
In other embodiments, in the second recess 602, the extraction electrode 8 may be disposed on a side of the second conductive connection 7 remote from the first conductive base layer 2; and/or the extraction electrode 8 may be provided at a side of the second conductive connection 7 close to the first conductive base layer 2.
As can be understood, referring to fig. 10 and 11, when the extraction electrode 8 is provided on the second conductive connection member 7 alone, since both the second conductive layer 701 and the second adhesive layer 702 of the second conductive connection member 7 have conductivity, the extraction electrode 8 can be provided on either side of the second conductive connection member 7 in the lamination direction Y, and the electrochromic device 1000 can be supplied with power through the extraction electrode 8; since the second adhesive layer 702 is conductive as a whole, the extraction electrode 8 is provided on the second connector 7, and the conductivity is higher.
By adopting the above technical scheme, the second bonding layer 702 of the second conductive connecting piece 7 only has a conductive portion, so that when only has a conductive portion, the larger the area of the conductive portion is, when the extraction electrode passes through the second connecting piece 7, the more the area of the conductive portion is, the smaller the resistance value is, and the higher the conductive efficiency is.
Referring to fig. 13, a second aspect of the embodiments of the present application provides an electrochromic device 2000 comprising a substrate 2001, the substrate 2001 being arranged on a side of the first conductive base layer 2 facing away from the electrochromic layer 3; and/or the substrate 2001 is arranged on the side of the second conductive base layer 4 facing away from the electrochromic layer 3.
Specifically, the substrate 2001 is provided on both sides of the electrochromic device 1000 in the lamination direction Y, and the substrate 2001 is bonded to both sides of the electrochromic device 1000 in the lamination direction Y through the substrate bonding layer 2002; the substrate 2001 has light transmittance, and is preferably glass.
A third aspect of the embodiments provides an electrochromic product comprising the electrochromic device 1000 or electrochromic apparatus 2000 described above.
The electrochromic product comprises any one of rearview mirrors, curtain walls, automobile skylights, automobile side windows, automobile windshields, shells of electronic products, glasses, vehicles and display panels.

Claims (16)

1. An electrochromic device comprising:
the first conductive substrate layer, the electrochromic layer and the second conductive substrate layer are sequentially stacked;
a conductive component disposed at a peripheral edge of at least one of the first and second conductive base layers;
The conductive assembly comprises a first conductive connecting piece, wherein the first conductive connecting piece comprises a conductive layer and an adhesive layer which are stacked; the bonding layer comprises an insulating part and a conductive part; the conductive layer is electrically connected with the first conductive substrate layer through the conductive part, and is insulated with the second conductive substrate layer through the insulating part; and/or the number of the groups of groups,
the conductive layer is electrically connected with the second conductive base layer through the conductive part, and the conductive layer is insulated with the first conductive base layer through the insulating part.
2. An electrochromic device according to claim 1, characterized in that: a groove is formed in the peripheral edge of the electrochromic device, and penetrates through the first conductive substrate layer and the electrochromic layer along the lamination direction of the first conductive substrate layer, the electrochromic layer and the second conductive substrate layer, and/or penetrates through the second conductive substrate layer and the electrochromic layer along the lamination direction of the first conductive substrate layer, the electrochromic layer and the second conductive substrate layer;
the conductive component is at least partially positioned in the groove, and two ends of the conductive component in the first direction are respectively connected with the first conductive substrate layer and the second conductive substrate layer; the first direction is perpendicular to a lamination direction of the first conductive base layer, the electrochromic layer, and the second conductive base layer.
3. An electrochromic device according to claim 2, characterized in that: the two ends of the first conductive connecting piece in the first direction are respectively connected with the first conductive basal layer and the second conductive basal layer; wherein,
the conductive part at least partially passes through the groove and is connected with the peripheral edge of the second conductive basal layer close to the electrochromic layer so as to enable the conductive layer to be electrically connected with the second conductive basal layer; and/or the number of the groups of groups,
the conductive part at least partially passes through the groove and is connected with the peripheral edge of the first conductive basal layer, which is close to the electrochromic layer, so that the conductive layer and the first conductive basal layer form electrical connection.
4. An electrochromic device according to claim 3, characterized in that: in the groove, one end of the insulating part of the first conductive connecting piece is connected to the peripheral edge of the first conductive basal layer far away from the electrochromic layer, and the other end of the insulating part of the first conductive connecting piece is connected to the peripheral edge of the second conductive basal layer near the electrochromic layer; and/or the number of the groups of groups,
in the groove, one end of the insulating part of the first conductive connecting piece is connected with the peripheral edge of the second conductive basal layer far away from the electrochromic layer, and the other end of the insulating part of the first conductive connecting piece is connected with the peripheral edge of the first conductive basal layer close to the electrochromic layer.
5. The electrochromic device of claim 4, wherein: the bonding layer of the first conductive connecting piece comprises a first conductive part, a second conductive part and an insulating part, wherein the first conductive part, the second conductive part and the insulating part are sequentially arranged and connected between the first conductive part and the second conductive part; wherein,
the conductive layer is electrically connected with the second conductive substrate layer through the second conductive part, and two ends of the first conductive part in the first direction are arranged on the first conductive substrate layer; and/or the number of the groups of groups,
the conductive layer is electrically connected with the first conductive substrate layer through the second conductive part, and two ends of the first conductive part in the first direction are arranged on the second conductive substrate layer.
6. An electrochromic device according to claim 2, characterized in that: the conductive assembly further comprises at least one second conductive connecting piece, the first conductive connecting piece and the second conductive connecting piece are sequentially arranged on the peripheral edge of the first conductive basal layer along the first direction, and the second conductive connecting piece is electrically connected with the first conductive basal layer; and/or the number of the groups of groups,
The first conductive connecting pieces and the second conductive connecting pieces are sequentially arranged on the peripheral edge of the second conductive basal layer, and the second conductive connecting pieces are electrically connected with the second conductive basal layer.
7. The electrochromic device of claim 6, wherein: the conductive assembly comprises a first conductive connecting piece and a second conductive connecting piece which are at least partially overlapped, and the first conductive connecting piece and the second conductive connecting piece are electrically connected; wherein,
along the first direction, one end of the first conductive connecting piece far away from the second conductive connecting piece is connected to the peripheral edge of one side of the first conductive basal layer far away from the electrochromic layer, and one end of the second conductive connecting piece far away from the first conductive connecting piece is arranged on the peripheral edge of one side of the second conductive basal layer near the electrochromic layer; and/or the number of the groups of groups,
along the first direction, one end of the first conductive connecting piece far away from the second conductive connecting piece is connected to the peripheral edge of one side of the second conductive basal layer far away from the electrochromic layer, and one end of the second conductive connecting piece far away from the first conductive connecting piece is arranged on the peripheral edge of one side of the first conductive basal layer near the electrochromic layer.
8. The electrochromic device of claim 6, wherein: the adjacent first conductive connecting piece and the adjacent second conductive connecting piece are separated,
the first conductive connecting piece is insulated from the first conductive basal layer through the insulating part, and the second conductive connecting piece is electrically connected with the second conductive basal layer; and/or the number of the groups of groups,
the first conductive connecting piece is insulated from the second conductive basal layer through the insulating part, and the second conductive connecting piece is electrically connected with the first conductive basal layer.
9. The electrochromic device according to claim 8, wherein: the conductive assembly further comprises a sealing element, wherein the sealing element is arranged between two adjacent first conductive connecting elements and second conductive connecting elements; and/or the number of the groups of groups,
the conductive component comprises two or more second conductive connecting pieces, two adjacent second conductive connecting pieces are spaced, and the sealing piece is arranged between the two adjacent second conductive connecting pieces.
10. An electrochromic device according to any one of claims 6-9, characterized in that: in the groove, a maximum thickness of the conductive member is less than or equal to a lamination thickness of the first conductive base layer and the electrochromic layer in a lamination direction; and/or the number of the groups of groups,
In the groove, a maximum thickness of the conductive member is less than or equal to a lamination thickness of the second conductive base layer and the electrochromic layer in a lamination direction.
11. An electrochromic device according to claim 3 or 6, characterized in that: outside the groove, two ends of the conductive component along the first direction are arranged on the first conductive substrate layer, and/or two ends of the conductive component along the first direction are arranged on the second conductive substrate layer.
12. The electrochromic device of claim 6, wherein: the extraction electrode is electrically connected with the second conductive basal layer through the first conductive connecting piece and/or the second conductive connecting piece; and/or the number of the groups of groups,
the extraction electrode is electrically connected with the first conductive basal layer through the first conductive connecting piece and/or the second conductive connecting piece.
13. The electrochromic device according to claim 12, wherein: the extraction electrode is arranged on one side, far away from the bonding layer, of the conductive layer of the first conductive connecting piece, and is electrically connected with the first conductive basal layer through the conductive part of the first conductive connecting piece; and/or the number of the groups of groups,
The extraction electrode is arranged on one side, far away from the bonding layer, of the conductive layer of the first conductive connecting piece, and the extraction electrode is electrically connected with the second conductive basal layer through the conductive part of the first conductive connecting piece.
14. The electrochromic device according to claim 12, wherein the extraction electrode is provided on at least one side of the second conductive connection member in the lamination direction, the extraction electrode being electrically connected with the first conductive base layer through the second conductive connection member; and/or the extraction electrode is electrically connected with the second conductive basal layer through the second conductive connecting piece.
15. An electrochromic device according to any one of claims 1 to 14, comprising a substrate and an electrochromic device according to any one of claims 1 to 14, said substrate being arranged on a side of said first conductive base layer facing away from said electrochromic layer; and/or the substrate is arranged on one side of the second conductive base layer, which faces away from the electrochromic layer.
16. An electrochromic product comprising an electrochromic device according to any one of claims 1-14 or an electrochromic device according to claim 15, wherein the electrochromic product comprises any one of a rear view mirror, a curtain wall, a sunroof, a side window of an automobile, a windscreen of an automobile, a housing of an electronic product, eyeglasses, a vehicle and a display panel.
CN202311851223.4A 2023-12-29 2023-12-29 Electrochromic device, electrochromic device and electrochromic product Pending CN117572700A (en)

Priority Applications (1)

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CN202311851223.4A CN117572700A (en) 2023-12-29 2023-12-29 Electrochromic device, electrochromic device and electrochromic product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311851223.4A CN117572700A (en) 2023-12-29 2023-12-29 Electrochromic device, electrochromic device and electrochromic product

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CN117572700A true CN117572700A (en) 2024-02-20

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