CN117547099A - Liquid cosmetic container - Google Patents
Liquid cosmetic container Download PDFInfo
- Publication number
- CN117547099A CN117547099A CN202210937977.0A CN202210937977A CN117547099A CN 117547099 A CN117547099 A CN 117547099A CN 202210937977 A CN202210937977 A CN 202210937977A CN 117547099 A CN117547099 A CN 117547099A
- Authority
- CN
- China
- Prior art keywords
- liquid cosmetic
- stretchable
- cosmetic container
- container
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 114
- 239000007788 liquid Substances 0.000 title claims abstract description 101
- 238000003860 storage Methods 0.000 claims abstract description 15
- -1 polyethylene terephthalate Polymers 0.000 claims description 42
- 239000000835 fiber Substances 0.000 claims description 27
- 239000005871 repellent Substances 0.000 claims description 16
- 229920002313 fluoropolymer Polymers 0.000 claims description 14
- 150000002222 fluorine compounds Chemical class 0.000 claims description 12
- 229920002994 synthetic fiber Polymers 0.000 claims description 10
- 239000012209 synthetic fiber Substances 0.000 claims description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 8
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 8
- 238000004381 surface treatment Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 26
- 229920001296 polysiloxane Polymers 0.000 description 35
- 229910052731 fluorine Inorganic materials 0.000 description 30
- 125000001153 fluoro group Chemical group F* 0.000 description 29
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 13
- 230000002940 repellent Effects 0.000 description 13
- 239000002131 composite material Substances 0.000 description 11
- 239000000178 monomer Substances 0.000 description 10
- 125000000524 functional group Chemical group 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 125000001033 ether group Chemical group 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 238000003825 pressing Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 229920005992 thermoplastic resin Polymers 0.000 description 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 239000005056 polyisocyanate Substances 0.000 description 4
- 229920001228 polyisocyanate Polymers 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- 238000004078 waterproofing Methods 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 150000002009 diols Chemical group 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000001589 sorbitan tristearate Substances 0.000 description 2
- 235000011078 sorbitan tristearate Nutrition 0.000 description 2
- 229960004129 sorbitan tristearate Drugs 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 239000013008 thixotropic agent Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- PZQBWGFCGIRLBB-NJYHNNHUSA-N [(2r)-2-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1O PZQBWGFCGIRLBB-NJYHNNHUSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004069 aziridinyl group Chemical group 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000005001 laminate film Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical compound C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 description 1
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 229920006136 organohydrogenpolysiloxane Polymers 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920011301 perfluoro alkoxyl alkane Polymers 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920006294 polydialkylsiloxane Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- UKBHVNMEMHTWQO-UHFFFAOYSA-N trioctadecyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCCCCCCCC)CC(=O)OCCCCCCCCCCCCCCCCCC UKBHVNMEMHTWQO-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D2034/002—Accessories
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/05—Details of containers
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/10—Details of applicators
- A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
- A45D2200/1036—Applicators comprising a pad, tissue, sponge, or the like containing a cosmetic substance, e.g. impregnated with liquid or containing a soluble solid substance
Landscapes
- Cosmetics (AREA)
Abstract
The invention provides a liquid cosmetic container, which can not leak out of the mesh of a stretchable net regardless of the orientation of the container. A liquid cosmetic container is provided with: a container body having an opening and a storage portion, and a stretchable net covering the opening, wherein the storage portion stores a liquid cosmetic containing water, and the stretchable net is subjected to a waterproof treatment.
Description
Technical Field
The present invention relates to a container for containing liquid cosmetics.
Background
Conventionally, various cosmetic containers exist. For example, when a cosmetic product stored in a bottomed container body having an opening in the top surface is attached to an applicator such as a puff for use, a container using a stretchable net is described in japanese unexamined patent application publication No. 63-177406, japanese unexamined patent application publication No. 3-72808, and the like as a cosmetic product container capable of adjusting the attachment amount of the cosmetic product.
The above-mentioned cosmetic container has the following advantages: by pressing an applicator such as a puff against the cosmetic from above the stretchable net and wiping the same, the cosmetic can be attached to the applicator in an amount corresponding to the pressing force.
Prior art literature
Patent literature
Patent document 1: japanese unexamined patent publication No. 63-177406;
patent document 2: japanese patent application laid-open No. 3-72808.
Disclosure of Invention
Problems to be solved by the invention
When the cosmetic contained in the cosmetic container is in a liquid state, the liquid cosmetic may leak out from the mesh of the stretchable net depending on the orientation of the container. For example, if the cosmetic container is in a state of being tilted during transportation or the like, the liquid cosmetic may come into contact with the stretchable net and may leak out of the mesh of the stretchable net.
The invention aims to provide that: regardless of the orientation of the container, the liquid cosmetic does not leak from the mesh of the stretchable net.
Means for solving the problems
As a result of intensive studies, the present inventors found that: the above object can be achieved by a liquid cosmetic container comprising:
a container body having an opening and a receiving portion; and
a stretchable net covering the opening,
the storage part stores the aqueous liquid cosmetic,
the stretchable web is subjected to a waterproof treatment.
The water repellent treatment is preferably a surface treatment with a fluorine compound.
Preferably, the fluorine compound is a fluorinated polymer.
Preferably, the stretchable web is made of synthetic fibers.
Preferably, the synthetic fibers are bicomponent fibers.
Preferably, the bicomponent fibers are comprised of polyethylene terephthalate and polypropylene terephthalate.
The synthetic fibers constituting the stretchable web are preferably water-repellent treated.
Preferably, the liquid cosmetic container of the present invention further comprises a cap,
the cover may cover the stretchable web.
Preferably, the liquid cosmetic container of the present invention further comprises an applicator,
the applicator is present between the cover and the stretchable web.
Preferably, the liquid cosmetic is a foundation.
Effects of the invention
The liquid cosmetic container of the present invention does not leak out of the mesh of the stretchable net regardless of the orientation of the container. Therefore, for example, even when the cosmetic container is in a state of being tilted during transportation or the like, the liquid cosmetic does not leak out of the mesh of the stretchable net.
Drawings
FIG. 1 is an exploded perspective view (perspective view) showing one example of the cosmetic container of the present invention.
Detailed Description
The liquid cosmetic container of the present invention is characterized by comprising:
a container body having an opening and a receiving portion; and
a stretchable net covering the opening,
the storage part stores the aqueous liquid cosmetic,
the stretchable web is subjected to a waterproof treatment.
The present invention will be described below.
The container body constituting the liquid cosmetic container of the present invention includes an opening portion and a receiving portion, and the receiving portion receives the aqueous liquid cosmetic. The receiving portion preferably has 1 bottom.
The material of the container body is arbitrary, and may be: inorganic materials such as metals and ceramics; organic materials such as paper and resin; or a composite thereof.
The opening of the container body is covered with a stretchable net, and the aqueous liquid cosmetic contained in the container body is passed through the stretchable net when in use.
The stretchable net is generally planar but deformable, and when the aqueous liquid cosmetic is used, it is deformed by pressing with a finger or the like, and can be stretched from the opening of the container body into the storage portion (particularly, into the bottom direction in the storage portion). On the other hand, when the aqueous liquid cosmetic is not used, the stretchable net is not deformed and is flat, and does not extend into the storage portion of the container body.
The stretchable web is preferably stretchable vertically downward by 0.5cm or more, more preferably 1cm or more, and still more preferably 1.5cm or more when the horizontally placed stretchable web is pressed downward. The stretchable web particularly preferably reaches the bottom surface of the storage portion when stretched.
When the aqueous liquid cosmetic is used, the elastic net is deformed by pressing the aqueous liquid cosmetic in the storage portion of the container body, so that at least a part of the aqueous liquid cosmetic passes through the mesh of the elastic net. The liquid cosmetic containing water and passing through the mesh of the stretchable net can be applied by being attached to an applicator such as a puff or a cosmetic pencil.
The storage portion of the container body may include a porous member such as a porous sponge or foam, in addition to the stretchable net. In the case where the housing portion of the container body includes a porous member, at least a part of the aqueous liquid cosmetic may permeate into the porous member. However, in the case where the container body housing portion includes a porous member, the stretchable net is not easily deformed into the container body housing portion, and therefore the container body housing portion preferably does not include a porous member.
The material of the stretchable web is not particularly limited, and any material such as an inorganic material such as a metal, an organic material such as a synthetic resin, or a composite thereof can be used. The material of the stretchable web is preferably a synthetic resin, more preferably a thermoplastic resin.
The stretchable web is preferably in the form of a woven fabric or knit fabric made of fibers, more preferably the fibers are made of a synthetic resin, and even more preferably a thermoplastic resin.
Examples of the thermoplastic resin include: polyolefin resins such AS polyethylene, polypropylene, and mixtures thereof, polyester resins such AS polystyrene resins, polylactic acid resins, AS resins (acrylonitrile-styrene copolymers), ABS resins (acrylonitrile-butadiene-styrene copolymers), polyamide resins, PTT (polytrimethylene terephthalate), PBT (polybutylene terephthalate), and PET (polyethylene terephthalate). These resins may be used after being mixed or compounded. As the thermoplastic resin, a polyester resin is more preferable. As the polyester resin, an aromatic polyester resin is more preferable, and PTT, PET, or a composite thereof is still more preferable.
The synthetic resin is preferably not polytetrafluoroethylene or a fluorinated polymer described later.
As the above fiber, a composite fiber can also be used. Examples of the composite fiber include: core-sheath type composite fibers, bicomponent (side-by-side) composite fibers, and segmented composite fibers. More preferably bicomponent (side-by-side) composite fibers. The bicomponent (side-by-side) composite fiber is a structure in which 2 kinds of polymers are combined to form 1 fiber, and 2 fibers composed of different polymers are integrated in the longitudinal direction. Examples of the bicomponent (side-by-side) composite fiber include: toray oceloniex Lycra T400 (registered trademark) as bicomponent fiber of PTT and PET, and the like.
The fibers are preferably composed of synthetic fibers, preferably fibers made of thermoplastic resin, and more preferably bicomponent fibers. The bicomponent fibers described above are preferably composed of polyethylene terephthalate and polypropylene terephthalate. The weight ratio of polyethylene terephthalate and polypropylene terephthalate in the bicomponent fiber is not particularly limited, and may be, for example, 10 to 90:90: 10. preferably 20 to 80:80: 20. more preferably 30 to 70:70 to 30, more preferably 30 to 50: 70-50.
The fiber width of the fibers is not particularly limited, and may be, for example, in the range of 0.01mm to 2mm, preferably 0.05mm to 1.5mm, and more preferably 0.1mm to 1 mm.
The weight per unit area of the stretchable web is not particularly limited as long as the web exhibits stretchability, and may be, for example, 50g/m 2 ~200g/m 2 May preferably be 75g/m 2 ~175g/m 2 More preferably 100g/m 2 ~150g/m 2 。
The thickness of the stretchable web is not particularly limited as long as the web exhibits stretchability, and may be, for example, in the range of 0.01mm to 3mm, preferably 0.05mm to 2mm, and more preferably 0.1mm to 1 mm.
The maximum length of the mesh of the stretchable web is not particularly limited, and may be, for example, in the range of 0.01mm to 0.9mm, preferably 0.05mm to 0.8mm, and more preferably 0.1mm to 0.7 mm.
The maximum opening area of the mesh of the stretchable web may be, for example, 0.01mm 2 ~0.9mm 2 Is preferably 0.05mm 2 ~0.7mm 2 More preferably 0.1mm 2 ~0.5mm 2 Is not limited in terms of the range of (a).
In general, when a cosmetic is used, the mesh of the stretchable net is enlarged by the stretching of the stretchable net, and the cosmetic is easily passed through the stretchable net, but when the cosmetic is not used, the stretchable net is contracted, and the mesh of the stretchable net is reduced, so that the cosmetic is not easily passed through the stretchable net.
However, since the fluidity of the liquid cosmetic is high, even small meshes of the stretchable net are likely to pass when not in use, and for example, if the container is tilted sideways during transportation, the liquid cosmetic may leak from the meshes of the stretchable net.
Therefore, in the present invention, the stretchable web is subjected to a waterproof treatment. Thus, in the present invention, the cosmetic passes through the mesh of the stretchable net when the aqueous liquid cosmetic is used, and on the other hand, the cosmetic does not pass through the mesh of the stretchable net when the aqueous liquid cosmetic is not used. While not being bound by theory, it is believed that the surface of the stretchable web that has been subjected to the water repellent treatment is hydrophobic, thereby impeding passage of the aqueous liquid cosmetic through the small mesh when the stretchable web is not in use.
By sufficiently reducing the mesh size when the stretchable net is stretched, the mesh size of the stretchable net is completely closed when the liquid cosmetic is not used (when the stretchable net is contracted), and the mesh size of the stretchable net can be opened by the stretching of the stretchable net when the liquid cosmetic is used.
The type of the water repellent treatment is not particularly limited, and examples thereof include: surface treatment with an arbitrary water repellent agent containing fluorine compound, silicone (polysiloxane), non-fluorinated hydrocarbon, and the like. Can be used in combination with various waterproofing agents. In terms of water repellency, surface treatment with a water repellent agent containing a fluorine compound is preferable.
The fluorine compound is a compound containing at least 1, preferably a plurality of fluorine atoms.
As the fluorine compound, an organic compound having a fluorine atom-containing group containing at least 1, preferably a plurality of fluorine atoms is preferable. The fluorine-containing group may be either a linear or branched group.
Examples of the fluorine atom-containing group include: perfluoroalkyl, semi-fluoroalkyl, perfluoroalkyl ether, semi-fluoroalkyl ether, and the like.
C for perfluoroalkyl group n F 2n+1 - (n represents a positive number of 1 or more). The perfluoroalkyl group may be either a straight chain or a branched chain, but is preferably a straight chain.
The semi-fluoroalkyl group has a chemical structure in which a part of fluorine atoms of the perfluoroalkyl group is substituted with hydrogen atoms. The semi-fluoroalkyl group may be either a straight chain or a branched chain, but is preferably a straight chain.
C for perfluoroalkyl Ether group n F 2n+1 -O- (n represents a positive number of 1 or more). The perfluoroalkyl ether group may be either linear or branched, but is preferably linear.
The semi-fluoroalkyl ether group has a chemical structure in which a part of fluorine atoms of the perfluoroalkyl ether group is substituted with hydrogen atoms. The semi-fluoroalkyl ether group may be either linear or branched, but is preferably linear.
The number of carbon atoms contained in the fluorine-containing atom group is not particularly limited, but is preferably 12 or less, more preferably 10 or less, still more preferably 8 or less, and particularly preferably 6 or less.
The fluorine atom-containing group may contain at least 1 halogen atom other than fluorine, for example, a chlorine atom.
As the fluorine compound, a low molecular fluoride as a low molecular compound, a fluorinated polymer as a high molecular compound, or a mixture thereof can be used.
Examples of the low-molecular fluoride include: fluorinated carbon, fluorinated hydrocarbon, and the like. More specifically, it is possible to list: alkanes, alcohols, ethers, esters, urethanes, and the like having fluorine atom-containing groups.
Examples of the fluorinated polymer include: polymers or oligomers having at least 1, preferably a plurality of fluorine-containing groups in the main chain and/or side chains.
As the fluorinated polymer, for example, an olefin-based or non-olefin-based fluorinated polymer can be used.
The olefinic fluorinated polymer is a polymer of a monomer having an ethylenic double bond. Examples of the olefin-based fluorinated polymer include: polytetrafluoroethylene, tetrafluoroethylene/hexafluoropropylene copolymers, tetrafluoroethylene/perfluoroalkyl vinyl ether copolymers (perfluoroalkoxyalkanes), tetrafluoroethylene/ethylene copolymers, polyvinylidene fluoride, chlorotrifluoroethylene/ethylene copolymers, polyvinyl fluoride, and mixtures thereof.
The fluorine atom-containing group may have a hydrogen atom. For example, as described above, the fluorine atom-containing group may be a semiperfluoroalkyl group, a semiperfluoroalkyl ether group, or the like.
The olefinic fluorinated polymer may be: a fluorine atom-containing (meth) acrylic polymer or oligomer having at least 1 fluorine atom-containing group in the side chain, or a fluorine atom-containing (meth) acrylic copolymer.
The fluorine atom-containing (meth) acrylic polymer is preferably a polymer or copolymer of a fluorine atom-containing (meth) acrylate having at least 1 fluorine atom-containing group in a side chain, and as such a fluorine atom-containing (meth) acrylate, for example, it can be represented by the following formula 1:
CH 2 =c (R) COO-Q-Rf seed, seed (formula 1)
(wherein R represents a hydrogen atom or a methyl group, Q represents a 2-valent organic group, and Rf represents a fluorine-containing atom group).
Q in formula 1 is preferably an alkylene group, or a 2-valent organic group derived therefrom, more preferably an alkylene group. Examples of Q include: -CH 2 CH 2 -、-CH(CH 3 )CH 2 -、-CH 2 CH 2 N(CH 3 )CO-、-CH 2 CH 2 N(CH 3 )SO 2 -、-CH(CH 2 Cl)CH 2 OCH 2 CH 2 N(CH 3 )SO 2 -and the like.
As the fluorine atom-containing (meth) acrylate represented by formula 1, for example, the following compounds (R represents a hydrogen atom or a methyl group, R f Represents a fluorine-containing group):
CH 2 =CRCOOCH 2 CH 2 R f 、
CH 2 =CRCOOCH(CH 3 )CH 2 R f 、
CH 2 =CRCOOCH 2 CH 2 N(CH 3 )COR f 、
CH 2 =CRCOOCH 2 CH 2 N(C 2 H 5 )COR f 、
CH 2 =CRCOOCH 2 CH 2 N(C 3 H 7 )COR f 、
CH 2 =CRCOOCH 2 CH 2 N(CH 3 )SO 2 R f 、
CH 2 =CRCOOCH 2 CH 2 N(C 2 H 5 )SO 2 R f 、
CH 2 =CRCOOCH 2 CH 2 N(C 3 H 7 )SO 2 R f 、
CH 2 =CRCOOCH(CH 2 Cl)CH 2 OCH 2 CH 2 N(CH 3 )SO 2 R f 。
the fluorine atom-containing (meth) acrylic acid ester may be used alone or in combination of two or more.
The copolymer of the fluorine atom-containing (meth) acrylate may contain polymerized units based on monomers other than the fluorine atom-containing (meth) acrylate. As the other monomer, a monomer having a radical polymerizable unsaturated bond is preferable.
As other monomers, there may be mentioned: vinyl chloride, stearyl (meth) acrylate, ethylene, vinyl acetate, vinyl fluoride, halovinylstyrene, alpha-methylstyrene, p-methylstyrene, (meth) acrylic acid, alkyl (meth) acrylate, polyoxyalkylene (meth) acrylate, (meth) acrylamide, diacetone (meth) acrylamide, N-methylol (meth) acrylamide, vinyl alkyl ether, haloalkylvinyl ether, vinyl alkyl ketone, butadiene, isoprene, chloroprene, glycidyl (meth) acrylate, aziridinyl (meth) acrylate, benzyl (meth) acrylate, 2-isocyanatoethyl (meth) acrylate, cyclohexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, maleic anhydride, polysiloxane-bearing (meth) acrylate, N-vinylcarbazole, and the like, with vinyl chloride, stearyl (meth) acrylate being particularly preferred.
The amount of the fluorine atom-containing (meth) acrylate in the monomer constituting the copolymer of fluorine atom-containing (meth) acrylate is preferably 25 mass% or more, more preferably 50 mass% or more, and still more preferably 75 mass% or more, based on the total mass of the monomer.
The method for producing the olefin-based fluorinated polymer is not particularly limited, and for example, a known production method (polymerization method), reaction conditions, and the like can be arbitrarily selected. Examples of the polymerization method include: bulk polymerization, suspension polymerization, emulsion polymerization, solution polymerization, and the like. The mechanism of the polymerization reaction may be, for example, radical polymerization, radiation polymerization, photopolymerization, or the like, and particularly, emulsion polymerization using radical polymerization is preferable.
In the case of emulsion polymerization, a method of emulsifying, stirring and polymerizing a monomer, a surfactant or the like in the presence of water is preferable. Further, a method of emulsifying the monomer, the surfactant, water, etc. in advance using an emulsifying machine such as a homogenizer, and then polymerizing the same with stirring is also preferable.
As the polymerization initiator, various polymerization initiators such as organic acid peroxides, azo compounds, persulfates, and the like are preferable. As the surfactant, various surfactants of anionic, cationic, amphoteric or nonionic nature can be used.
On the other hand, the non-olefinic fluorinated polymer is a polymer other than a polymer of a monomer having an ethylenic double bond. As the non-olefin fluorinated polymer, for example, polyurethane may be cited, and for example, a reaction product of a low-molecular fluoride containing a functional group reactive with an isocyanate group and a polyisocyanate may be used.
As the low-molecular fluoride containing a functional group reactive with an isocyanate group, a compound having a fluorine atom-containing group and a hydroxyl group, a compound having a fluorine atom-containing group and an amino group, or a compound having a fluorine atom-containing group and a carboxyl group is preferable.
The polyisocyanate compound is preferably a polyisocyanate compound having 2 or more isocyanate groups, and examples thereof include: toluene Diisocyanate (TDI), diphenylmethane diisocyanate (MDI), naphthalene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, xylylene diisocyanate, hydrogenated MDI, lysine diisocyanate, triphenylmethane triisocyanate, and polymers, nurate modifications, biuret modifications, and the like thereof.
The polyurethane may be: a compound obtained by further reacting a compound containing a functional group reactive with an isocyanate group and containing no fluorine atom-containing group with a polyisocyanate compound, in addition to a low-molecular fluoride containing a functional group reactive with an isocyanate. Examples of the compound containing a functional group reactive with isocyanate and containing no fluorine atom-containing group include: alcohols, amines, carboxylic acids, and the like.
Examples of the polyurethane include: JP-A59-157166 discloses a polyurethane.
In order that the aqueous liquid cosmetic does not pass through the stretchable web when not in use, but on the other hand that the aqueous liquid cosmetic passes through the stretchable web more reliably when in use, fluorinated polymers are preferably used.
As the water repellent containing a fluorine compound, commercially available ones can be used, and examples thereof include: asahiGuard SERIES (manufactured by Asahi Kabushiki Kaisha), unidyne Series (manufactured by Daikin industries, inc.), etc., but are not limited thereto. In addition, the waterproofing agent containing fluorine compounds may be used alone, and a plurality of waterproofing agents each containing a different kind of fluorine compound may also be used in combination.
The silicone is not particularly limited, and polydialkylsiloxanes such as polydimethylsiloxane, polyalkylarylsiloxanes such as polymethylphenylsiloxane, organohydrogen polysiloxanes such as methylhydrogen polysiloxanes, and the like can be used, but silicones having functional groups capable of reacting with functional groups of the material constituting the stretchable web are preferable, and silicones having amino groups, hydroxyl groups, carboxyl groups, mercapto groups, epoxy groups, and the like are preferable. More preferred are amino-modified silicone, methanol-modified silicone, glycol-modified silicone, phenol-modified silicone, and carboxyl-modified silicone.
As the amino group-modified silicone, any of a silicone having an amino group introduced into a side chain of a siloxane structure, a silicone having an amino group introduced into a terminal of a siloxane structure, and a mixture thereof can be used, and as the amino group, a monoamine, a diamine, or an amino group a part of which is blocked can be used. Among the amino-modified silicones, from the viewpoint of water repellency, a silicone having an amine equivalent of about 300 to 20000g/mol is preferably used, and 1000 to 7000g/mol is more preferable. Such amino-modified silicone may be commercially available. For example, WACKER FINISH WR, WR1100, WR1200, WR1300 and WR1600 manufactured by Wacker Silicone Inc. of Asahi Kabushiki Kaisha, and KF-867, KF-869 and KF-8004 manufactured by Xinyue chemical industry Co., ltd.
As the methanol-modified silicone, any one of a silicone having a hydroxyl group introduced into a side chain of a siloxane structure, a silicone having a hydroxyl group introduced into a terminal of a siloxane structure, and a mixture thereof can be used. Such a methanol-modified silicone may be commercially available. For example, X-22-4039, X-22-4015, X-22-170BX, X-22-170DX, KF-6000, KF-6001, KF-6002, KF-6003 and the like manufactured by Xinyue chemical industries, inc. can be used.
As the diol-modified silicone, any one of a silicone having a diol group introduced into a side chain of a siloxane structure, a silicone having a diol group introduced into a terminal of a siloxane structure, and a mixture thereof can be used. Such glycol-modified silicone may be commercially available. For example, X-22-176DX, X-22-176F, X-22-176GX-A, etc. manufactured by Xinyue chemical industry Co., ltd.
As the phenol-modified silicone, any one of a silicone having a phenolic hydroxyl group introduced into a side chain of a siloxane structure, a silicone having a phenolic hydroxyl group introduced into a terminal of a siloxane structure, and a mixture thereof can be used. Such phenol-modified silicones are commercially available. For example, KF-2201, manufactured by Xinyue chemical industry Co., ltd, or the like, can be used.
As the carboxyl group-modified silicone, any one of a silicone having a carboxyl group introduced into a side chain of a siloxane structure, a silicone having a carboxyl group introduced into a terminal of a siloxane structure, and a mixture thereof can be used. As such a carboxyl group-modified silicone, commercially available ones can be selected. For example, X-22-3701E, X-22-162C manufactured by Xinyue chemical industry Co., ltd.
The non-fluorinated hydrocarbon is preferably a non-fluorinated hydrocarbon having a long chain alkyl group, and preferably a non-fluorinated hydrocarbon having a functional group reactive with a functional group of a material constituting the stretchable net. As examples, there may be mentioned: the fatty acid esters, sorbitan fatty acid esters, and the like, and specifically, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan distearate, sorbitan tristearate, sorbitan monooleate, sorbitan trioleate, and the like, and fatty acid esters such as various sorbitan derivatives, alkyl citrate, pentaerythritol derivatives, and the like disclosed in WO2014/190905 can be used. Among them, sorbitan tristearate and tristearyl citrate are preferably used from the viewpoint of water repellency.
The type of the water repellent treatment is not particularly limited, and may be carried out by, for example, the following method: a method of immersing the elastic net in a solution of a water repellent and then drying the same, a method of coating a solution of a water repellent on the elastic net and then drying the same, a method of spraying a solution of a water repellent on the elastic net and then drying the same, and the like.
The solvent of the water repellent solution is not particularly limited as long as it is a solvent capable of dissolving the water repellent, but an organic solvent is preferable, and a hydrophobic organic solvent is preferable. As the hydrophobic organic solvent, for example, an organic compound having a linear or cyclic hydrocarbon chain can be used. Particularly, from the industrial point of view, the hydrophobic organic solvent is preferably a petroleum hydrocarbon solvent, more preferably a petroleum hydrocarbon solvent having a low boiling point of 130 ℃ or less. The hydrophobic organic solvent may contain various substituents within a range that does not significantly reduce the hydrophobicity of the hydrocarbon structure, for example, a part of the hydrocarbon chain may be substituted with fluorine atoms, silicon atoms, or the like, or may contain a small amount of ether oxygen atoms.
When the stretchable web is made of fibers, it is preferable to waterproof each of the fibers constituting the stretchable web. For example, when the stretchable web is made of synthetic fibers, it is preferable to manufacture the stretchable web using the synthetic fibers after the waterproof treatment is applied to each of the synthetic fibers constituting the stretchable web.
The amount of the water repellent on the elastic net is not particularly limited, and is, for example, 1.1g/m 2 ~6.0g/m 2 Preferably 1.2g/m 2 ~5.0g/m 2 More preferably 1.3g/m 2 ~4.5g/m 2 。
The liquid cosmetic contained in the liquid cosmetic container of the present invention is an aqueous liquid cosmetic containing at least water. The aqueous liquid cosmetic is liquid at room temperature (25 ℃ C.).
The amount of water contained in the aqueous liquid cosmetic is preferably 20% by mass or more, more preferably 30% by mass or more, still more preferably 40% by mass or more, based on the total mass of the aqueous liquid cosmetic. The amount of water contained in the aqueous liquid cosmetic is preferably 80% by mass or less, more preferably 70% by mass or less, still more preferably 60% by mass or less, based on the total mass of the aqueous liquid cosmetic. The amount of water contained in the aqueous liquid cosmetic is preferably 20 to 80% by mass, more preferably 30 to 70% by mass, still more preferably 40 to 60% by mass, based on the total mass of the aqueous liquid cosmetic.
The aqueous liquid cosmetic may further comprise: c such as ethanol and isopropanol 1-4 Monohydric alcohols; diols such as ethylene glycol, propylene glycol, and butylene glycol; hydrophilic components such as polyhydric alcohols such as glycerin.
The aqueous liquid cosmetic may further comprise various oils, surfactants, thickeners, ultraviolet screening agents, colorants, and the like. Examples of the coloring agent include: inorganic pigments such as titanium dioxide, and organic dyes such as red 227.
The form of the aqueous liquid cosmetic is not particularly limited, and may be any form such as a solution, a dispersion, or an emulsion. The emulsion may be either an oil-in-water type or a water-in-oil type, but is preferably in the form of an oil-in-water emulsion.
The aqueous liquid cosmetic may be of low viscosity. For example, the viscosity of the aqueous liquid cosmetic may be in the range of 1000 to 20000 cps (1 to 20pa·s), preferably 1000 to 10000 cps (1 to 10pa·s), more preferably 1000 to 7000 cps (1 to 7pa·s), still more preferably 1000 to 3000 cps (1 to 3pa·s). The viscosity can be determined by measuring at 30rpm for 1 minute at room temperature (25 ℃), for example using a Brookfield viscometer using spindle No. 4.
The aqueous liquid cosmetic may or may not contain a thixotropic agent. Examples of thixotropic agents include: nonionic block copolymers comprising at least 1 hydrophilic moiety and at least 1 hydrophobic moiety. Complex elastic modulus G of aqueous liquid cosmetic * (Pa) is preferably less than 300Pa, more preferably less than 200 Pa, and still more preferably less than 100Pa.
The aqueous liquid cosmetic is not particularly limited as long as it is a liquid aqueous cosmetic, and examples thereof include: liquid foundations, liquid blushes, and the like. Preferably a liquid foundation.
The liquid cosmetic container of the present invention may be provided with a lid, and the lid preferably covers the stretchable net. Thus, leakage of the aqueous liquid cosmetic from the container body can be more reliably avoided.
The liquid cosmetic container of the present invention may include an applicator such as a puff and a cosmetic pencil between the cover and the stretchable net. Thereby, the application operation can be easily performed when the aqueous liquid cosmetic is used.
Fig. 1 is an exploded perspective view showing an example of the liquid cosmetic container according to the present invention, and the liquid cosmetic container a shown in fig. 1 includes: a container body 1, a lid 2, a middle frame 3, a liquid cosmetic 4 containing water, a stretchable net 5, an applicator 6, and a sealing member 7.
In the example shown in fig. 1, the container body 1 is a substantially cylindrical dish-shaped member having one end closed to form a bottom and the other end opened, and has a storage portion for storing the aqueous liquid cosmetic 4 and an opening portion opening in the direction of the center 3.
The middle frame 3 is a substantially cylindrical member having an upper end opening and a lower end opening, and is accommodated in an accommodating portion of the container body 1 through the opening of the container body 1. Specifically, the outer diameter of the center 3 is equal to or smaller than the inner diameter of the container portion of the container body 1, a flange is formed to protrude from the upper end edge of the center 3 so as to be overlapped with the upper end edge of the opening of the container body 1, the center 3 is inserted into the container portion from the opening of the container body 1 until the lower surface of the flange abuts against the upper end edge of the opening of the container body 1, the flange is overlapped with the upper end edge, and the center 3 is fixed at a predetermined depth position in the container portion of the container body 1, and the aqueous liquid cosmetic 4 is stored in the lower portion of the center 3 in the container portion of the container body 1. Accordingly, in the example shown in fig. 1, the aqueous liquid cosmetic 4 and the center 3 are simultaneously stored in the storage portion of the container body 1. The upper end opening of the center 3 corresponds to the opening of the container body 1, and the aqueous liquid cosmetic 4 can be taken out from the outside.
An elastic net 5 is provided at any position between the upper end opening portion and the lower end opening portion of the middle frame 3. A stretchable net 5 may be provided at the lower end opening of the middle frame 3. The stretchable net 5 covers the opening of the middle frame 3 and also covers the opening of the container body 1.
The stretchable web 5 may be made of the above-described material, and may be subjected to the above-described waterproofing treatment.
The stretchable net 5 is deformable at least to the lower side (bottom direction) of the storage portion of the container body 1. By forming the stretchable web 5 from a material having high flexibility, the deformability of the stretchable web 5 can be improved.
The upper end opening of the center 3 is sealed by a sealing member 7. Thereby, the stretchable web 5 is isolated from the outside. The sealing member 7 is not particularly limited as long as it can seal the upper end opening of the middle frame 3, and for example, a metal laminate film having a releasable adhesive layer can be used.
The applicator 6 is accommodated in a space between the sealing member 7 and the lid 2. The form of the applicator 6 is not particularly limited, and for example, a puff or the like may be used.
The lid body 2 is also a substantially cylindrical member, and can be engaged with the container body 1 in a state where the applicator 6 is accommodated. Further, by engaging the lid 2 with the container body 1, the lid 2 can cover the stretchable net 5. Further, by engaging the lid 2 with the container body 1, the opening of the container body 1 can be closed.
In this way, the liquid cosmetic container a can hold and retain the aqueous liquid cosmetic 4.
When the aqueous liquid cosmetic 4 is used, the lid 2 is removed from the container body 1, the sealing member 7 is peeled off and removed to expose the stretchable net 5 to the outside, and then the applicator 6 is pressed against the stretchable net 5 by a finger or the like, so that the stretchable net 5 is deformed downward (in the bottom direction) of the storage portion of the container body 1, and only an appropriate amount of the aqueous liquid cosmetic 4 can be caused to float out of the mesh of the stretchable net 5. The aqueous liquid cosmetic 4 that emerges onto the surface of the stretchable web 5 is attached to the applicator 6.
Therefore, by pressing the applicator 6 against the stretchable web 5, the aqueous liquid cosmetic 4 can be attached to the applicator 6, and can be taken out from the container body 1 for use in cosmetic treatment of skin or the like. By the action of the stretchable web 5, an appropriate amount of the aqueous liquid cosmetic 4 adheres to the applicator 6, and thus it is possible to prevent the application of the aqueous liquid cosmetic 4 more than necessary to the skin.
Industrial applicability
The liquid cosmetic container of the present invention does not leak out of the mesh of the stretchable net regardless of the orientation of the container. Therefore, the liquid cosmetic container of the present invention is easy to handle, store, and the like.
The liquid cosmetic container of the present invention is suitable for use as a container for liquid cosmetic, and as a container for liquid foundation, liquid blush, etc. In particular, the liquid cosmetic container of the present invention may be more suitably used as a container for liquid foundations.
Symbol description
1: a container body;
2: a cover body;
3: a middle frame;
4: an aqueous liquid cosmetic;
5: a stretchable web;
6: a painting tool;
7: and a sealing member.
Claims (10)
1. A liquid cosmetic container is provided with:
a container body having an opening and a receiving portion; and
a stretchable net covering the opening,
the storage part stores the aqueous liquid cosmetic,
the stretchable web is subjected to a waterproof treatment.
2. The liquid cosmetic container according to claim 1, wherein the water-repellent treatment is a surface treatment with a fluorine compound.
3. The liquid cosmetic container of claim 2, wherein said fluorine compound is a fluorinated polymer.
4. A liquid cosmetic container according to any one of claims 1 to 3, wherein the stretchable web is made of synthetic fibers.
5. The liquid cosmetic container of claim 4, wherein said synthetic fibers are bicomponent fibers.
6. The liquid cosmetic container of claim 5, wherein said bicomponent fibers are comprised of polyethylene terephthalate and polypropylene terephthalate.
7. The liquid cosmetic container according to any one of claims 4 to 6, wherein each synthetic fiber constituting the stretchable web is water-repellent treated.
8. The liquid cosmetic container according to any one of claim 1 to 7, further comprising a lid,
the cover may cover the stretchable web.
9. The liquid cosmetic container according to claim 8, further comprising an applicator,
the applicator is present between the cover and the stretchable web.
10. The liquid cosmetic container according to any one of claims 1 to 9, wherein the aqueous liquid cosmetic is a foundation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210937977.0A CN117547099A (en) | 2022-08-05 | 2022-08-05 | Liquid cosmetic container |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210937977.0A CN117547099A (en) | 2022-08-05 | 2022-08-05 | Liquid cosmetic container |
Publications (1)
Publication Number | Publication Date |
---|---|
CN117547099A true CN117547099A (en) | 2024-02-13 |
Family
ID=89809781
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210937977.0A Pending CN117547099A (en) | 2022-08-05 | 2022-08-05 | Liquid cosmetic container |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN117547099A (en) |
-
2022
- 2022-08-05 CN CN202210937977.0A patent/CN117547099A/en active Pending
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