CN117509996A - Wastewater treatment device and wastewater treatment method for perovskite flotation - Google Patents

Wastewater treatment device and wastewater treatment method for perovskite flotation Download PDF

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Publication number
CN117509996A
CN117509996A CN202410013942.7A CN202410013942A CN117509996A CN 117509996 A CN117509996 A CN 117509996A CN 202410013942 A CN202410013942 A CN 202410013942A CN 117509996 A CN117509996 A CN 117509996A
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CN
China
Prior art keywords
tank
wastewater
coagulation
wastewater treatment
filter
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Pending
Application number
CN202410013942.7A
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Chinese (zh)
Inventor
周奎
张波
王松源
刘俊良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Yuxiao Zirconium &titanium Co ltd
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Shandong Yuxiao Zirconium &titanium Co ltd
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Application filed by Shandong Yuxiao Zirconium &titanium Co ltd filed Critical Shandong Yuxiao Zirconium &titanium Co ltd
Priority to CN202410013942.7A priority Critical patent/CN117509996A/en
Publication of CN117509996A publication Critical patent/CN117509996A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/008Control or steering systems not provided for elsewhere in subclass C02F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5209Regulation methods for flocculation or precipitation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention mainly relates to the field of wastewater treatment, in particular to a wastewater treatment device and a wastewater treatment method for perovskite flotation. The wastewater treatment device comprises an adjusting tank, wherein a screen is arranged in the adjusting tank and is used for pretreating large-particle substances and impurities in wastewater; a coagulation tank is connected behind the regulating tank and is used for carrying out coagulation reaction; a sedimentation tank is connected behind the coagulation tank, and a filter and a PH adjusting device are connected behind the sedimentation tank; a membrane separation device, a biological filter and a chemical oxidation device are sequentially connected between the filter and the PH adjusting device; electric regulating valves are arranged on the pipelines among the regulating tank, the coagulation tank and the sedimentation tank, and are connected with a control system. Through setting up equalizing basin, coagulating basin, sedimentation tank, filter, PH adjusting device, membrane separation device, biological filter and chemical oxidation device processing unit, can get rid of all kinds of pollutants in the waste water, improve out water quality, reach environmental protection emission or reuse's standard.

Description

Wastewater treatment device and wastewater treatment method for perovskite flotation
Technical Field
The invention mainly relates to the field of wastewater treatment, in particular to a wastewater treatment device and a wastewater treatment method for perovskite flotation.
Background
In the field of wastewater treatment, particularly for wastewater treatment for perovskite flotation, a number of challenges are often faced. These waste waters often contain a large amount of contaminants such as metal ions, organics, suspended matter, etc., which have serious environmental and human health effects. Therefore, it is important to develop an efficient and stable wastewater treatment device and treatment method.
The existing wastewater treatment device and treatment method often have the problems of low treatment efficiency, unstable treatment effect, complex operation and maintenance and the like.
Disclosure of Invention
In order to solve the problems, the invention adopts the following technical scheme.
The wastewater treatment device for the zirconium titanium ore flotation comprises an adjusting tank, wherein a screen is arranged in the adjusting tank and is used for pretreating large-particle substances and impurities in wastewater; a coagulation tank is connected behind the regulating tank and is used for carrying out coagulation reaction; a sedimentation tank is connected behind the coagulation tank, and a filter and a PH adjusting device are connected behind the sedimentation tank;
a membrane separation device, a biological filter and a chemical oxidation device are sequentially connected between the filter and the PH adjusting device;
electric regulating valves are arranged on pipelines among the regulating tank, the coagulation tank and the sedimentation tank, and are connected with a control system.
Further, the control system comprises a liquid level meter and a processor which are arranged in the regulating tank, the coagulation tank and the sedimentation tank.
Further, the coagulation tank comprises a mixing area and a reaction area, wherein stirring paddles are arranged in the mixing area; and a guide wall and a baffle are arranged in the reaction zone.
Further, the sedimentation tank is connected with a sludge processor.
Further, an aeration device is arranged in the coagulation tank.
Further, microorganisms capable of leaching nickel ions are arranged in the biological pond.
By utilizing the device, the invention also discloses a method for treating the wastewater generated by the perovskite flotation, which comprises the following steps:
s1, wastewater enters an adjusting tank, water quality, water quantity and pH value are adjusted, and simultaneously coagulant is added for coagulation reaction;
s2, in a coagulation tank, colloidal substances and micro suspended matters in the wastewater react with a coagulant to form larger floccules;
s3, the wastewater enters a sedimentation tank, flocculating constituents are settled down through gravity sedimentation, and supernatant fluid enters the next step of treatment;
s4, further removing micro suspended matters and colloid substances in the wastewater by using a filter medium through a filter;
s5, the wastewater sequentially passes through a membrane separation device, a biological filter and a chemical oxidation device to further remove pollutants in the wastewater;
s6, adding an acid-base regulator into the effluent through a pH regulator according to the requirement to adjust the pH value of the effluent to reach the emission standard or the recycling standard;
s7, contacting with microorganisms to convert metal ions in the wastewater into soluble ions;
s8, discharging or recycling the treated wastewater.
The invention has the beneficial effects that: through setting up equalizing basin, coagulating basin, sedimentation tank, filter, PH adjusting device, membrane separation device, biological filter and chemical oxidation device processing unit, can get rid of all kinds of pollutants in the waste water effectively, improve out water quality, reach environmental protection emission or reuse's standard. Meanwhile, the electric regulating valve is arranged on the pipeline among the regulating tank, the coagulation tank and the sedimentation tank and is connected with the control system, so that the accurate control of the treatment process can be realized, the treatment efficiency is improved, and the treatment effect is enhanced. In addition, through setting up mixing zone and reaction zone and stirring rake, guide wall and baffle structure, can optimize coagulation reaction and sedimentation effect, improve waste water treatment's efficiency and stability. In a word, the invention has the advantages of reasonable structure, good treatment effect and accurate control, and is suitable for the treatment of wastewater for the zirconium titanium ore flotation.
Detailed Description
The present invention will be described in further detail below.
The wastewater treatment device for the zirconium titanium ore flotation comprises an adjusting tank, wherein a screen is arranged in the adjusting tank and is used for pretreating large-particle substances and impurities in wastewater; a coagulation tank is connected behind the regulating tank and is used for carrying out coagulation reaction; a sedimentation tank is connected behind the coagulation tank, and a filter and a PH adjusting device are connected behind the sedimentation tank;
a membrane separation device, a biological filter and a chemical oxidation device are sequentially connected between the filter and the PH adjusting device;
electric regulating valves are arranged on pipelines among the regulating tank, the coagulation tank and the sedimentation tank, and are connected with a control system.
The control system comprises a liquid level meter and a processor which are arranged in the regulating tank, the coagulation tank and the sedimentation tank. The control system is an important component of the whole wastewater treatment device, and realizes accurate control of the treatment process by monitoring and processing various sensor data. The control system comprises a liquid level meter and a processor which are arranged in the regulating tank, the coagulation tank and the sedimentation tank. The liquid level meter is used for monitoring the liquid level of each pool, and the processor controls the opening degree and the running time of the electric regulating valve according to the liquid level and other sensor data, so that the flow and the liquid level of each pool are regulated, and the stable running of the treatment process is ensured. The design of the coagulation basin has an important influence on the effect of the coagulation reaction. The coagulation pool comprises a mixing area and a reaction area, wherein a stirring paddle is arranged in the mixing area, and the coagulant and the wastewater are fully mixed by rotating and stirring the stirring paddle, so that good conditions are provided for coagulation reaction. The reaction zone is internally provided with a guide wall and a baffle, and the facilities can control the water flow state and prolong the residence time of the wastewater in the reaction zone, thereby improving the coagulation reaction effect.
The sedimentation tank is used for settling the floccule formed by the coagulation reaction through gravity sedimentation, and the supernatant fluid enters the next treatment. In order to maintain a good sedimentation environment of the sedimentation tank, it is necessary to periodically discharge the sedimented sludge. Therefore, the sedimentation tank is connected with a sludge processor, and the sludge processor can stabilize, reduce and harmlessly treat deposited sludge, so that secondary pollution is avoided. The biological pool is internally provided with microorganisms capable of leaching nickel ions.
An aeration device is arranged in the coagulation tank. The aeration device has the functions of enhancing the oxidation capability of the wastewater and improving the speed and effect of coagulation reaction by introducing air or oxygen into the wastewater. Meanwhile, the aeration device can play a role in stirring and mixing, and further promote the coagulation reaction.
By utilizing the device, the invention also discloses a method for treating the wastewater generated by the perovskite flotation, which comprises the following steps:
s1, the wastewater enters an adjusting tank, the water quality, the water quantity and the pH value are adjusted, and simultaneously, a coagulant is added for coagulation reaction.
S2, in the coagulation tank, colloidal substances and micro suspended matters in the wastewater react with a coagulant to form larger floccules.
S3, the wastewater enters a sedimentation tank, flocculating constituents are settled down through gravity sedimentation, and supernatant fluid enters the next step of treatment.
S4, further removing micro suspended matters and colloid substances in the wastewater by using a filter medium through a filter.
S5, the wastewater sequentially passes through a membrane separation device, a biological filter and a chemical oxidation device, so that pollutants in the wastewater are further removed.
S6, adding an acid-base regulator into the effluent through a pH regulator according to the pH value which is finally required to be reached, so that the effluent reaches the emission standard or the recycling standard.
S7, contacting with microorganisms to convert metal ions in the wastewater into soluble ions;
s8, discharging or recycling the treated wastewater.
The present invention can be easily implemented by those skilled in the art through the above specific embodiments. It should be understood that the invention is not limited to the particular embodiments described above. Based on the disclosed embodiments, a person skilled in the art may combine different technical features at will, so as to implement different technical solutions.

Claims (7)

1. A wastewater treatment device for zirconium titanium ore floatation is characterized in that: the wastewater treatment device comprises an adjusting tank, wherein a screen is arranged in the adjusting tank and is used for preprocessing large-particle substances and impurities in wastewater; a coagulation tank is connected behind the regulating tank and is used for carrying out coagulation reaction; a sedimentation tank is connected behind the coagulation tank, and a filter and a PH adjusting device are connected behind the sedimentation tank; the rear part of the sedimentation tank is communicated with a biological tank;
a membrane separation device, a biological filter and a chemical oxidation device are sequentially connected between the filter and the PH adjusting device;
electric regulating valves are arranged on pipelines among the regulating tank, the coagulation tank and the sedimentation tank, and are connected with a control system.
2. A wastewater treatment apparatus for the flotation of a perovskite according to claim 1, wherein: the control system comprises a liquid level meter and a processor which are arranged in the regulating tank, the coagulation tank and the sedimentation tank.
3. A wastewater treatment apparatus for the flotation of a perovskite according to claim 1, wherein: the coagulation pool comprises a mixing area and a reaction area, wherein stirring paddles are arranged in the mixing area; and a guide wall and a baffle are arranged in the reaction zone.
4. A wastewater treatment apparatus for the flotation of a perovskite according to claim 1, wherein: the sedimentation tank is connected with a sludge processor.
5. A wastewater treatment apparatus for the flotation of a perovskite according to claim 1, wherein: an aeration device is arranged in the coagulation tank.
6. A wastewater treatment apparatus for the flotation of a perovskite according to claim 1, wherein: the biological pool is internally provided with microorganisms capable of leaching nickel ions.
7. A method for treating wastewater from the flotation of a perovskite, comprising:
s1, wastewater enters an adjusting tank, water quality, water quantity and pH value are adjusted, and simultaneously coagulant is added for coagulation reaction;
s2, in a coagulation tank, colloidal substances and micro suspended matters in the wastewater react with a coagulant to form larger floccules;
s3, the wastewater enters a sedimentation tank, flocculating constituents are settled down through gravity sedimentation, and supernatant fluid enters the next step of treatment;
s4, further removing micro suspended matters and colloid substances in the wastewater by using a filter medium through a filter;
s5, the wastewater sequentially passes through a membrane separation device, a biological filter and a chemical oxidation device to further remove pollutants in the wastewater;
s6, adding an acid-base regulator into the effluent through a pH regulator according to the requirement to adjust the pH value of the effluent to reach the emission standard or the recycling standard;
s7, contacting with microorganisms to convert metal ions in the wastewater into soluble ions;
s8, discharging or recycling the treated wastewater.
CN202410013942.7A 2024-01-05 2024-01-05 Wastewater treatment device and wastewater treatment method for perovskite flotation Pending CN117509996A (en)

Priority Applications (1)

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CN202410013942.7A CN117509996A (en) 2024-01-05 2024-01-05 Wastewater treatment device and wastewater treatment method for perovskite flotation

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Application Number Priority Date Filing Date Title
CN202410013942.7A CN117509996A (en) 2024-01-05 2024-01-05 Wastewater treatment device and wastewater treatment method for perovskite flotation

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CN117509996A true CN117509996A (en) 2024-02-06

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020009956A (en) * 2000-07-28 2002-02-02 김화지 Apparatus and method for waste water processing contain heavy metal and a pollutant non decomposition
CN101786734A (en) * 2009-09-08 2010-07-28 刘春喜 Process for treating acid waste water containing copper, nickel and the like by membrane method
US20100193436A1 (en) * 2007-08-20 2010-08-05 Earth Renaissance Technologies, Llc Pre-treatment reverse osmosis water recovery method for brine retentate metals removal
CN102153220A (en) * 2011-02-21 2011-08-17 中国科学院生态环境研究中心 Method for treating and recycling polishing waste water of plated part in electroplating industry
CN102674626A (en) * 2012-04-28 2012-09-19 东莞市科达环保工程有限公司 System and method for treatment and recovery of electronic electroplating wastewater
CN209161571U (en) * 2018-08-15 2019-07-26 江苏如意环境工程有限公司 Potassium permanganate composites
CN211688726U (en) * 2020-01-18 2020-10-16 杭州传一科技有限公司 Electroplating wastewater treatment device for treating metal-chelating agent complex
CN117023834A (en) * 2023-05-05 2023-11-10 山东域潇锆钛矿业股份有限公司 High-hardness water purification treatment recycling process

Patent Citations (8)

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US20100193436A1 (en) * 2007-08-20 2010-08-05 Earth Renaissance Technologies, Llc Pre-treatment reverse osmosis water recovery method for brine retentate metals removal
CN101786734A (en) * 2009-09-08 2010-07-28 刘春喜 Process for treating acid waste water containing copper, nickel and the like by membrane method
CN102153220A (en) * 2011-02-21 2011-08-17 中国科学院生态环境研究中心 Method for treating and recycling polishing waste water of plated part in electroplating industry
CN102674626A (en) * 2012-04-28 2012-09-19 东莞市科达环保工程有限公司 System and method for treatment and recovery of electronic electroplating wastewater
CN209161571U (en) * 2018-08-15 2019-07-26 江苏如意环境工程有限公司 Potassium permanganate composites
CN211688726U (en) * 2020-01-18 2020-10-16 杭州传一科技有限公司 Electroplating wastewater treatment device for treating metal-chelating agent complex
CN117023834A (en) * 2023-05-05 2023-11-10 山东域潇锆钛矿业股份有限公司 High-hardness water purification treatment recycling process

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