CN117323106B - Sheet heating paste - Google Patents
Sheet heating paste Download PDFInfo
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- CN117323106B CN117323106B CN202311538571.6A CN202311538571A CN117323106B CN 117323106 B CN117323106 B CN 117323106B CN 202311538571 A CN202311538571 A CN 202311538571A CN 117323106 B CN117323106 B CN 117323106B
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- heating
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 279
- 239000000463 material Substances 0.000 claims abstract description 114
- 239000000835 fiber Substances 0.000 claims abstract description 88
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000000843 powder Substances 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 23
- 229920005989 resin Polymers 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910001868 water Inorganic materials 0.000 claims abstract description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002250 absorbent Substances 0.000 claims abstract description 21
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 20
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- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 239000013543 active substance Substances 0.000 claims abstract description 13
- 238000005520 cutting process Methods 0.000 claims abstract description 9
- 230000000694 effects Effects 0.000 claims description 15
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 10
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- 238000007664 blowing Methods 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000003466 welding Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 abstract description 12
- 239000010410 layer Substances 0.000 description 118
- 238000010792 warming Methods 0.000 description 29
- 210000003127 knee Anatomy 0.000 description 8
- 210000000481 breast Anatomy 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
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- 239000000230 xanthan gum Substances 0.000 description 3
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- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
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- 241001391944 Commicarpus scandens Species 0.000 description 1
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- 206010053615 Thermal burn Diseases 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 238000001467 acupuncture Methods 0.000 description 1
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- 230000001070 adhesive effect Effects 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
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- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F7/03—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction
- A61F7/032—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction using oxygen from the air, e.g. pocket-stoves
- A61F7/034—Flameless
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F7/0241—Apparatus for the preparation of hot packs, hot compresses, cooling pads, e.g. heaters or refrigerators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F2007/0244—Compresses or poultices for effecting heating or cooling with layers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F2007/0244—Compresses or poultices for effecting heating or cooling with layers
- A61F2007/026—Compresses or poultices for effecting heating or cooling with layers with a fluid absorbing layer
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F7/03—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction
- A61F7/032—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction using oxygen from the air, e.g. pocket-stoves
- A61F7/034—Flameless
- A61F2007/036—Fuels
- A61F2007/038—Carbon or charcoal, e.g. active
Landscapes
- Health & Medical Sciences (AREA)
- Heart & Thoracic Surgery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
Abstract
The invention relates to the technical field of self-heating products, in particular to a sheet heating paste which comprises a heating material layer, a hydrophilic fiber layer, a breathable film layer and a non-breathable film layer, wherein the heating material layer is prepared from the following components in percentage by weight: reduced iron powder, activated carbon, vermiculite, water, salt, an active agent, superfine fibers and water-absorbent resin, wherein the sum of the percentages of the raw materials is 100%; the heating material layers are evenly spread on the two adjacent hydrophilic fiber layers to form a whole heating sheet, or the heating material layers are evenly distributed on the two adjacent hydrophilic fiber layers at intervals to form a dot-shaped cuttable heating sheet. A plurality of grooves are pressed on the surface of the heating sheet; when the heating sheet is a cutting type heating sheet, the lower surface of the heating sheet is in a state that a plurality of bulges are uniformly distributed. The invention improves the structure and components of the traditional heating paste, the prepared heating paste is more attached to a human body, the structure is more stable, the preparation process is clean and simple, and the application scene is wide.
Description
Technical Field
The invention relates to the technical field of self-heating products, in particular to a sheet heating patch.
Background
The warming plaster, also called as 'warmer', is a tool for warming human body, and the reaction principle is that chemical heat generating agent reacts with oxygen to release heat, so that chemical energy is converted into heat energy. Due to the characteristics of simple manufacture, portability, cold protection, warmth retention and rapid hot compress, the warm patch has wide application in recent years and rapid development of industry, and has become an indispensable popular single product in the market of China. In addition to the warming patches with the warming function, the warming patches with the health-preserving and hot-compressing functions are gradually evolved, and according to the difference of the warming patches attached to the body part, the warming patches can be divided into a uterus warming patch, a foot warming patch, a hand warming patch, a breast patch, a shoulder and neck physiotherapy patch and the like.
The spontaneous heating in the market at present is mainly classified into two types of powder type and flake type.
The powder type heating paste is generally composed of a raw material layer, a gelatin layer and a non-woven fabric bag, wherein the raw material is generally in powder form, when the powder type heating paste is used, an oxygen-isolated plastic outer bag outside the heating paste is removed, and oxygen in air enters the non-woven fabric bag to react with the raw material to emit heat. The outer surface of the bagged powder warming patch is softer, but the raw materials are unevenly distributed, the outer bag is easy to break, and in the use process, (1) the bag is easy to fall down, so that powder is accumulated to cause scalding; (2) the heating temperature and the heating time are uncontrollable, and the reaction is insufficient; (3) The heating device is limited by the existing structure, the capacity of the raw materials cannot be changed, the heating effect is reduced due to the influence of the raw materials, and the raw materials at the center are increased to cause insufficient reaction of the raw materials.
In recent years, the sheet type warming patch has rapid development, the sheet type warming patch is uniform in material and relatively good in temperature control, as disclosed in patent document No. CN 104974720B, and a preparation method and application thereof, but the prepared sheet type warming patch (1) has high hardness, is suitable for different parts of a human body, cannot be well attached to the human body, and affects the warming effect; (2) The preparation process is complex, thickening agents such as xanthan gum, arabic gum and the like are required to be added, the preparation time is long, and the cost is increased.
Disclosure of Invention
The invention provides the sheet heating patch, which solves the problems that the existing sheet heating patch is not attached to a human body and the powder heating patch has poor heating effect, and the prepared heating patch is attached to the human body, so that the preparation process is simple, a proper shape can be cut by a consumer, the attaching performance is strong, and the application is wide.
In order to achieve the above object, the technical scheme of the present invention is as follows:
A sheet heating patch comprising:
The heating material layer is prepared from the following components in percentage by weight: 40% -60% of reduced iron powder, 7% -30% of activated carbon, 1% -10% of vermiculite, 20% -30% of water, 1% -5% of salt, 0.1% -2% of active agent, 0.1% -1% of superfine fiber and 0.5% -5% of water-absorbent resin, and the heat-generating material prepared from raw materials forms a layered structure, wherein the sum of the percentages of the raw materials is 100%; the water-absorbent resin is used for prolonging the heating time.
The hydrophilic fiber layers are positioned on the upper side and the lower side of the heating material layer and wrap the heating material layer; the hydrophilic fiber and the superfine fiber play a role of a framework in the invention, and keep the shape of the heating patch.
And the breathable film layer is positioned on the upper layer of the hydrophilic fiber layer on the upper side. Oxygen in the air enters the heating material layer through the breathable film layer.
And the non-breathable film layer is positioned below the hydrophilic fiber layer on the lower side.
Further, the active agent is any one of alkylphenol ethoxylates, glyceryl monostearate and polysorbate.
Further, the heating material layer is prepared from the following raw materials in percentage by weight: 50% of reduced iron powder, 11.6% of activated carbon, 8% of vermiculite, 27% of water, 2% of salt, 0.3% of polysorbate, 0.1% of superfine fiber and 1% of water-absorbent resin.
Further, the hydrophilic fiber layers are multiple, heating material layers are distributed between every two adjacent hydrophilic fiber layers, the number of layers of different heating materials can be adjusted according to different product requirements, and due to the stable structure of the heating material layers, the heating materials are uniformly distributed between the two adjacent hydrophilic fiber layers, and even if the heating material layers are thick, the raw materials can fully react with oxygen.
Further, the heating material layers are evenly spread on two adjacent hydrophilic fiber layers to form a whole heating sheet, or the heating material layers are formed by a plurality of blocks, and the plurality of heating material layers are evenly distributed on the two adjacent hydrophilic fiber layers at intervals to form dot-shaped cuttable heating sheets. Different heating paste shapes can be trimmed according to the use scene, and the heating paste is more attached to a human body, so that the heating paste is suitable for more warm-keeping scenes.
Further, a plurality of grooves are pressed on the surface of the heating sheet, the grooves are used for bending the heating sheet, and the angle of the heating sheet is adjusted according to the human body curve; when the heating sheet is a cutting type heating sheet, the lower surface of the heating sheet is in a state that a plurality of bulges are uniformly distributed.
Further, the grooves are linear grooves, and the grooves are linear or arc-shaped. Different linear combinations can be pressed according to different warmth retention parts.
Further, the plurality of protrusions are semicircular protrusions or square protrusions; when the massage device is in a semicircular bulge, the massage effect is achieved.
The preparation method of the sheet heating patch is characterized by comprising the following steps of:
step one: the active agent and the salt are mixed and then dissolved in water to prepare a mixed solution.
Step two: and uniformly stirring the reduced iron powder, the vermiculite, the activated carbon, the water-absorbent resin and the superfine fibers, and adding the mixture to form the heating material.
Step three: uniformly spreading the heating material on the hydrophilic fiber layer to form a heating material layer, covering the hydrophilic fiber layer on the upper part of the heating material layer again to enable the hydrophilic fiber layer to fully wrap the heating material layer to form a whole heating sheet, or uniformly distributing the heating material on the hydrophilic fiber layer at intervals to form a plurality of heating material layers on two adjacent hydrophilic fiber layers to form a dot-shaped cuttable heating sheet, wherein the intervals between the plurality of heating material layers are 1cm.
Step four: and applying pressure to the heating sheet, sealing edges of the heating sheet, extruding grooves on the heating sheet, and pressing the heating sheet into a convex state by a plurality of heating material layers when the cutting type heating sheet is pressed, wherein the pressing is performed between adjacent hydrophilic fiber layers, so that the lower surface of the heating sheet is in a convex uniform distribution state.
Step five: the heat generating sheet is placed on the non-breathable film layer, and the breathable film layer is used for covering the heat generating sheet.
Step six: and bonding the heating sheet with the non-breathable film layer and the breathable film layer into a whole in a heat sealing or ultrasonic welding mode to obtain the sheet heating paste.
Because the active agent and the superfine fibers exist in the heating material, the crosslinking effect can be achieved in the heating material, and when the heating sheet with the structure is pressed, the moisture in the heating material is extruded and can be absorbed by the hydrophilic fibers, so that the hydrophilic fibers and the heating material are firmly combined to form a sheet with a stable structure. Therefore, the adhesive can replace the role of gums such as xanthan gum and the like as a thickening agent and a stabilizing agent in the heating paste, has simple process, can not form a high-viscosity material body, and has cleaner and more concise manufacturing process.
In addition, the heating sheet adopts the edge sealing structure, the periphery of the heating material is wrapped by the hydrophilic fiber, the structure is more stable, when die cutting is carried out, the hydrophilic fiber is cut, the cutter does not pass through the heating material, the service life of a die cutting tool is effectively prolonged, the material leakage is avoided in the production process, the manufacturing process is clean and concise, and the waste of materials is avoided.
In the second step, the reduced iron powder, vermiculite, activated carbon and water absorbent resin are mixed, and ultrafine fibers are added in a blowing mode while stirring. With this method, the superfine fiber and the heating material are mixed more uniformly, and spherical particles after adding the mixed liquid are reduced.
Further, the thickness of the heating sheet prepared in the fourth step is between 1mm and 10 mm. The thickness of the heating sheet is related to the layer number of the heating material, and can be positioned and adjusted according to the design of the product.
According to the invention, the grooves are formed in the surface of the heating sheet, the structure of the heating sheet is physically changed, and the grooves with different depths and different shapes are pressed according to the requirements, so that the heating patch can be bent according to the curve radian of a human body when in use, is more tightly attached to the human body, improves the warm-keeping effect when being used for the human body part, is suitable for more scenes, and increases the comfort of the body feeling when in use.
When the heating material layers are distributed in the hydrophilic fiber layers, the heating material layers can be cut according to the shape and the size of the attached parts, so that a better technical effect of being tightly attached to a human body is realized, the heating material layers can be suitable for more parts of the human body, the distance between the heating points is large, point-shaped heating is adopted to replace planar heating, the air permeability is superior to that of a common heating product, and low-temperature scalding can be effectively prevented.
According to the invention, by adjusting the structure and components of the heating paste, the superfine fibers and the water-absorbing resin are added into the heating material, the hydrophilic fibers are used for coating the heating material, the hydrophilic fibers and the heating material are firmly combined, the superfine fibers in the heating material and the active agent generate a crosslinking effect to form a solid sheet with stable structure, the heating material is uniformly distributed, the problem of leakage of the heating material is avoided, and meanwhile, the production stage is simple in process, a high-viscosity material body is not formed, so that the manufacturing process is cleaner and simpler.
The volume of the heating material in the heating paste is increased by adopting a mode of stacking the hydrophilic fiber layer and the heating material layer, and the heating paste has stable structure, uniform distribution of the heating material, good air permeability of the hydrophilic fiber, stable inside of the stacked heating sheets, no influence on the heating material due to different heights, high reaction rate and utilization rate of the heating material, no influence on heating efficiency, and stable heating temperature and heating duration in actual production.
The invention provides a preparation method of a flake heating paste, which comprises the steps of uniformly mixing raw materials such as reduced iron powder and water-absorbing resin, adding superfine fibers in a blowing mode while stirring, and realizing the technical effect of uniform mixing of the superfine fibers in heating materials; the hydrophilic fiber layer and the heating material layer are combined in a pressing mode, so that the use of gum products such as xanthan gum and the like as a thickening agent and a stabilizing agent in the prior art is avoided, and the manufacturing process is clean and concise.
The invention can be widely applied to preparing portable heating thermal insulation devices such as neck warming patches, shoulder warming patches, waist warming patches, knee warming patches, foot warming patches, uterus warming patches, abdomen warming patches, stomach warming patches, prostate warming patches, breast warming patches and the like.
Drawings
FIG. 1 is a schematic illustration of a single layer structure of the present invention;
FIG. 2 is a schematic diagram of a double layer structure of the present invention;
FIG. 3 is a schematic diagram of a groove structure according to the present invention;
FIG. 4 is a schematic view of a heat generating sheet according to the present invention 1;
FIG. 5 is a schematic view of a heat generating sheet according to the present invention;
FIG. 6 is a top view 1 of a recess of a heat-generating plate of the present invention;
FIG. 7 is a top view 2 of the grooves of the heat-generating fin of the present invention;
FIG. 8 is a schematic view 1 of a heat patch of the present invention in use in different scenarios;
FIG. 9 is a schematic view of the heat patch of the present invention in use in different scenarios 2;
The reference numbers in the drawings: 1 is a heating material layer, 2 is a hydrophilic fiber layer, 3 is a breathable film layer, 4 is a non-breathable film layer, and 5 is a groove.
Detailed Description
The invention is further described with reference to the drawings and detailed description which follow:
As shown in fig. 1-9, the sheet heating patch comprises:
The heating material layer 1, wherein the heating material layer 1 is prepared from the following components in percentage by weight: 40% -60% of reduced iron powder, 7% -30% of activated carbon, 1% -10% of vermiculite, 20% -30% of water, 1% -5% of salt, 0.1% -2% of active agent, 0.1% -1% of superfine fiber and 0.5% -5% of water-absorbent resin, and the heat-generating material prepared from raw materials is of a layered structure, wherein the sum of the percentages of the raw materials is 100%. The ultrafine fibers have a fineness of 0.3 and a diameter of 5 μm or less.
The active agent of the invention is any one of nonionic active agents such as alkylphenol ethoxylates, glyceryl monostearate, polysorbate and the like.
As an implementation manner, the heating material layer 1 is made of the following raw materials in percentage by weight: 50% of reduced iron powder, 11.6% of activated carbon, 8% of vermiculite, 27% of water, 2% of salt, 0.3% of polysorbate, 0.1% of superfine fiber and 1% of water-absorbent resin.
As an implementation manner, the heating material layer 1 is made of the following raw materials in percentage by weight: 50% of reduced iron powder, 15% of activated carbon, 2% of vermiculite, 29.6% of water, 2% of salt, 0.3% of alkylphenol ethoxylates, 0.1% of superfine fibers and 1% of water-absorbent resin.
As an implementation manner, the heating material layer 1 is made of the following raw materials in percentage by weight: 47.45% of reduced iron powder, 14.5% of activated carbon, 5% of vermiculite, 29.6% of water, 2% of salt, 0.3% of glyceryl monostearate, 0.15% of superfine fiber and 1% of water-absorbent resin.
The heating material layer 1 can also be used as an implementation mode, and is prepared from the following raw materials in percentage by weight: 60% of reduced iron powder, 7% of activated carbon, 10% of vermiculite, 20% of water, 1% of salt, 1.4% of polysorbate, 0.1% of superfine fiber and 0.5% of water absorbent resin.
The heating material layer 1 can also be used as an implementation mode, and is prepared from the following raw materials in percentage by weight: 40% of reduced iron powder, 26% of activated carbon, 1% of vermiculite, 20% of water, 5% of salt, 2% of glyceryl monostearate, 1% of superfine fibers and 5% of water-absorbent resin.
And the hydrophilic fiber layers 2 are positioned on the upper side and the lower side of the heating material layer 1 and wrap the heating material layer 1. The hydrophilic fiber refers to a fiber with moisture regain more than 4.5% and liquid phase moisture and gas phase moisture absorption property, and comprises natural fibers such as hydrophilic fibers of cotton, hemp and the like and hydrophilic synthetic fibers made of synthetic fibers of terylene, acrylic fibers, cotton and the like, wherein the molecular structure of the fiber is loose, and water molecules easily penetrate into micro gaps on the surface of the fiber.
The hydrophilic fiber layers 2 are multi-layered, and a heating material layer 1 is distributed between every two adjacent hydrophilic fiber layers 2. The heating sheet is formed by the heating material layer 1 and the hydrophilic fiber layer 2, and the heating material layer 1 has stable structure, uniform distribution and good air permeability, and the inside of the heating sheet after stacking is still stable, so that the heating efficiency is not influenced.
And a breathable film layer 3, wherein the breathable film layer 3 is positioned on the upper layer of the hydrophilic fiber layer 2, and a waterproof breathable film is preferred in the invention.
A non-breathable film layer 4, wherein the non-breathable film layer 4 is positioned below the hydrophilic fiber layer 2 at the lower side. The non-breathable film layer 4 is made of pE film, laminated paper or bopp film.
The heating material layers 1 are uniformly paved on two adjacent hydrophilic fiber layers 2 to form a whole heating sheet, or the heating material layers 1 are formed by a plurality of blocks, and the plurality of heating material layers 1 are uniformly distributed on the two adjacent hydrophilic fiber layers 2 at intervals to form punctiform cuttable heating sheets; the heating material layers 1 are spaced 1cm apart from each other.
A plurality of grooves 5 are pressed on the surface of the heating sheet; when the heating sheet is a cuttable heating sheet, the lower surface of the heating sheet is in a state that a plurality of bulges are uniformly distributed, as shown in fig. 5.
The groove 5 is a linear groove 5, and the shape of the groove 5 is a linear type or an arc type.
The plurality of bulges are semicircular bulges or square bulges; when the massage device is in a semicircular bulge shape, the massage effect is achieved, the bulge positions of the plurality of bulges on the lower surface of the heating sheet can be arranged according to the acupuncture points of a human body, when the massage device is used, the bulge parts of the heating sheet have certain pressure on the surface of the skin, so that the massage effect is achieved, meanwhile, the heating sheet is in a punctiform shape, the comfort level of the human body is improved, the body and mind are relaxed, and the massage device can be widely applied to the parts of shoulder, neck, feet, knees and the like.
When preparing large-area heating patches such as a neck warming patch and a uterus warming patch, a whole heating sheet (shown in fig. 1,2 and 3) can be used, namely, the heating material layers 1 are continuously distributed in the hydrophilic fiber layer 2, the grooves 5 are linear or arc-shaped, different grooves 5 conforming to the human body curve can be customized on the surface of the heating sheet according to different body parts, and the technical effect of being more attached to the human body can be achieved.
When preparing small-area heating patches such as a breast patch, a knee warming patch and the like, a cuttable heating sheet (shown in fig. 4 and 5) can be used, namely, the heating material layer 1 is intermittently distributed in the hydrophilic fiber layer 2, and the intermittent distance is more than 1cm. The punctiform can cut the type heating piece and buckle according to the shape of the part that pastes, in order to laminate the part that pastes, cut according to the size of the part that pastes, and, because the area is smaller, can also paste in other positions, avoid the waste of material.
The preparation method of the sheet heating patch is characterized by comprising the following steps of:
Step one: the active agent and the salt are mixed and then dissolved in water to prepare a mixed solution;
Step two: uniformly stirring reduced iron powder, vermiculite, active carbon, water-absorbent resin and superfine fibers, and adding the mixture to form a heating material;
Step three: uniformly spreading the heating material on the hydrophilic fiber layer to form a heating material layer, covering the hydrophilic fiber layer on the upper part of the heating material layer again to enable the hydrophilic fiber layer to fully wrap the heating material layer to form a whole heating sheet, or spreading the heating material on the hydrophilic fiber layer in a punctiform manner to form a plurality of heating material layers, wherein the heating material layers are uniformly distributed on two adjacent hydrophilic fiber layers 2 at intervals to form punctiform cuttable heating sheets, and the plurality of heating material layers 1 are spaced by 1cm;
step four: applying pressure to the heating sheet, sealing edges of the heating sheet, extruding grooves on the heating sheet, and pressing a plurality of heating material layers into a convex state when the cutting type heating sheet is pressed, wherein the heating material layers are pressed between adjacent hydrophilic fiber layers to form a lower surface of the heating sheet into a convex uniform distribution state;
step five: placing the heating sheet on a non-breathable film layer, and covering the heating sheet with the breathable film layer;
Step six: and bonding the heating sheet with the non-breathable film layer and the breathable film layer into a whole in a heat sealing or ultrasonic welding mode to obtain the sheet heating paste.
Preferably, in the second step, the reduced iron powder, vermiculite, activated carbon and water absorbent resin are mixed first, and ultrafine fibers are added in a blowing manner while stirring them.
Preferably, the thickness of the heating sheet prepared in the fourth step is between 1mm and 10 mm.
Selecting heating patches with different thicknesses, and testing heating time and temperature of the heating patches, wherein test samples are as follows: 50mm long by 50mm wide and 2mm, 4mm and 6mm thick respectively.
The test method comprises the following steps: and (3) fixing heating patches with different specifications on the surface of a constant-temperature water bath box with the surface temperature of (35+/-0.5) ℃ under the normal temperature condition of a laboratory, recording heating time and temperature, and observing the heating process.
When the thickness of the heating paste is 2 mm:
the heating material layer 1 is a layer, the heating paste structure is shown in the attached figure 1, the components of the heating material layer 1 are shown in the table 1, and the experimental results are shown in the table 2:
TABLE 1 heating sheet 1 Components and proportions thereof
Component (A) | Reduced iron powder | Activated carbon | Vermiculite | Water and its preparation method | Salt | Alkylphenol polyoxyethylene | Ultrafine fiber | Water-absorbent resin |
Weight percent | 50 | 15 | 2 | 29.6 | 2 | 0.3 | 0.1 | 1 |
TABLE 2 sample heating temperature (unit:. Degree. C.) and heating time (unit: min)
Time of | 0 | 10 | 20 | 30 | 40 | 50 | 60 | 70 | 80 |
Temperature (temperature) | 32 | 45 | 49 | 51 | 51.5 | 51 | 47 | 45 | 40 |
When the thickness of the heating paste is 4 mm:
the heating material layer 1 is a layer, the heating paste structure is shown in the attached figure 1, the components of the heating material layer 1 are shown in the table 3, and the experimental results are shown in the table 4:
TABLE 3 heating sheet 1 Components and proportions thereof
Component (A) | Reduced iron powder | Activated carbon | Vermiculite | Water and its preparation method | Salt | Glyceryl monostearate | Ultrafine fiber | Water-absorbent resin |
Weight percent | 47.45 | 14.5 | 5 | 29.6 | 2 | 0.3 | 0.15 | 1 |
TABLE 4 sample heating temperature (unit:. Degree. C.) and heating time (unit: min)
Time of | 0 | 10 | 30 | 60 | 90 | 20 | 150 | 180 | 210 | 240 | 270 | 300 | 330 | 350 |
Temperature (temperature) | 31 | 51 | 51.2 | 51.5 | 51.5 | 51.3 | 51 | 51 | 50.5 | 50.2 | 49.5 | 47 | 41 | 39 |
When the thickness of the heating paste is 6 mm:
the heating material layer 1 is two layers, the heating paste structure is shown in the attached figure 2, the components of the heating material layer 1 are shown in the table 5, and the experimental results are shown in the table 6:
TABLE 5 heating sheet 1 Components and proportions thereof
Component (A) | Reduced iron powder | Activated carbon | Vermiculite | Water and its preparation method | Salt | Polysorbate esters | Ultrafine fiber | Water-absorbent resin |
Weight percent | 50 | 11.6 | 8 | 27 | 2 | 0.3 | 0.1 | 1 |
TABLE 6 sample heating temperature (unit:. Degree. C.) and heating time (unit: min)
Time of | 0 | 10 | 30 | 60 | 20 | 180 | 240 | 300 | 360 | 420 | 480 | 540 |
Temperature (temperature) | 32.2 | 48.5 | 51 | 52 | 52.1 | 51.8 | 51.5 | 50.8 | 49.9 | 48 | 45 | 40 |
According to the test, as the thickness of the heating paste is increased, the effective heating time of the heating paste is prolonged, the technical effect that the heating time is increased along with the thickness is achieved, the heating paste with the corresponding thickness can be selected according to the required heating time, and the heating time and the temperature are more controllable compared with the traditional heating paste; when the thickness of the heat generating patch exceeds 10mm, the required equipment cost increases greatly although the heat generating time is still prolonged, and in view of the relatively heavy and inconvenient carrying of the heat generating patch of 10mm or more, the heat generating patch of 10mm or less is preferably prepared in the present invention.
When the whole heating piece is used and the surface of the heating piece carries the heating paste of the groove 5, the heating paste can be bent along the trend of the surface groove 5, so that the heating paste is more attached to the surface of a human body, and the depth of the groove 5 and the shape of the groove can be adjusted in the preparation stage so as to be suitable for the heating paste requirements of different parts of the human body. When in use, the warm paste is placed at a place needing to keep warm, oxygen in the air enters the heating material layer 1 to react with the reduced iron powder therein, and heat is released.
When the heating patch prepared from the cutting type heating sheet is used, the heating patch can be cut into a proper shape according to the needs, the heating patch is more attached to a human body, raw materials are not wasted, the air permeability is good, and low-temperature scalds are not easy to generate.
1. When the invention is used as a mammary gland patch:
As shown in figure 8, the heating patch can be cut into a ring shape, and is directly inserted between the breast and the bra when in use, and the heat emitted by the heating patch is used for hot compress on the breast, thereby promoting the blood circulation of the breast and relaxing the mind and body.
2. The invention is used as a knee warming patch:
As shown in fig. 9, the heating patch can be sheared into an X shape, the center corresponds to the top end of the knee, and the periphery of the heating patch surrounds the knee, so that the heating patch can play a role in heat preservation and hot compress on the knee, and meanwhile, the daily activities of the knee are not affected.
The above-mentioned application method of the heat generating patch is merely an example, and does not limit the application of the present invention.
The above-described embodiments are merely preferred embodiments of the present invention and are not intended to limit the scope of the present invention, so that all equivalent changes or modifications of the structure, characteristics and principles described in the claims should be included in the scope of the present invention.
Claims (9)
1. The thin slice subsides that generate heat, its characterized in that includes:
The heating material layer (1), wherein the heating material layer (1) is prepared from the following components in percentage by weight: 40% -60% of reduced iron powder, 7% -30% of activated carbon, 1% -10% of vermiculite, 20% -30% of water, 1% -5% of salt, 0.1% -2% of active agent, 0.1% -1% of superfine fiber and 0.5% -5% of water-absorbent resin, and the heat-generating material prepared from raw materials forms a layered structure, wherein the sum of the percentages of the raw materials is 100%; the superfine fiber is fiber with fineness of 0.3 and diameter of less than 5 micrometers;
the hydrophilic fiber layer (2), the said hydrophilic fiber layer (2) locates at upper and lower both sides of the heating material layer (1), wrap up the said heating material layer (1);
a breathable film layer (3), wherein the breathable film layer (3) is positioned on the upper layer of the hydrophilic fiber layer (2) on the upper side;
A non-breathable film layer (4), wherein the non-breathable film layer (4) is positioned below the hydrophilic fiber layer (2) at the lower side;
The active agent is any one of alkylphenol ethoxylates, glyceryl monostearate and polysorbate.
2. The sheet heating paste according to claim 1, wherein the heating layer (1) is made of the following raw materials in percentage by weight: 50% of reduced iron powder, 11.6% of activated carbon, 8% of vermiculite, 27% of water, 2% of salt, 0.3% of polysorbate, 0.1% of superfine fiber and 1% of water-absorbent resin.
3. The sheet heating patch according to claim 1, wherein the hydrophilic fiber layers (2) are multi-layered, and a heating material layer (1) is distributed between every two adjacent hydrophilic fiber layers (2).
4. The sheet heating patch according to claim 1, wherein the heating material layers (1) are uniformly spread on two adjacent hydrophilic fiber layers (2) to form a whole heating sheet, or the heating material layers (1) are formed by a plurality of blocks, and the plurality of heating material layers (1) are uniformly distributed on the two adjacent hydrophilic fiber layers (2) at intervals to form dot-shaped cuttable heating sheets.
5. The sheet heating patch according to claim 4, wherein a plurality of grooves (5) are pressed on the surface of the heating sheet; when the heating sheet is a cutting type heating sheet, the lower surface of the heating sheet is in a state that a plurality of bulges are uniformly distributed.
6. The sheet heating patch according to claim 5, wherein the groove (5) is a linear groove (5), and the groove (5) is linear or arcuate in shape; the plurality of bulges are semicircular bulges or square bulges; when the massage device is in a semicircular bulge, the massage effect is achieved.
7. A method for producing a sheet heat patch according to any one of claims 5 to 6, comprising the steps of:
Step one: the active agent and the salt are mixed and then dissolved in water to prepare a mixed solution;
Step two: uniformly stirring reduced iron powder, vermiculite, active carbon, water-absorbent resin and superfine fibers, and adding the mixture to form a heating material;
Step three: uniformly spreading the heating material on the hydrophilic fiber layer to form a heating material layer, covering the hydrophilic fiber layer on the upper part of the heating material layer again to enable the hydrophilic fiber layer to fully wrap the heating material layer to form a whole heating sheet, or spreading the heating material on the hydrophilic fiber layer in a punctiform manner to form a plurality of heating material layers which are uniformly distributed on two adjacent hydrophilic fiber layers at intervals to form punctiform cuttable heating sheets, wherein the distance between the plurality of heating material layers is 1cm;
Step four: applying pressure to the heating sheet, sealing edges of the heating sheet, extruding grooves on the heating sheet, and pressing a plurality of heating material layers into a convex state when the cutting type heating sheet is pressed, wherein the heating material layers are pressed between adjacent hydrophilic fiber layers to form a lower surface of the heating sheet into a convex uniform distribution state;
step five: placing the heating sheet on a non-breathable film layer, and covering the heating sheet with the breathable film layer;
Step six: and bonding the heating sheet with the non-breathable film layer and the breathable film layer into a whole in a heat sealing or ultrasonic welding mode to obtain the sheet heating paste.
8. The method for producing a sheet heat generating patch according to claim 7, wherein in the second step, reduced iron powder, vermiculite, activated carbon and water absorbent resin are mixed, and ultrafine fibers are added in a blowing manner while stirring.
9. The method for preparing a sheet heating paste according to claim 7, wherein the thickness of the heating sheet prepared in the fourth step is 1 mm-10 mm.
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JP2001137275A (en) * | 1999-11-11 | 2001-05-22 | Hisamitsu Pharmaceut Co Inc | Skin-applicable exothermic sheet |
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EP1655005A4 (en) * | 2003-07-31 | 2010-12-08 | Kao Corp | Warming tool in a sheet form |
CA2573826A1 (en) * | 2004-07-14 | 2006-01-19 | Mycoal Products Corporation | Heat generating body, heat insulating method using the same and packaging material for die molding heat generation |
CN215131397U (en) * | 2021-03-31 | 2021-12-14 | 舒建龙 | Self-heating strong medicine application |
CN114191416B (en) * | 2021-12-27 | 2023-09-15 | 河南省超亚医药器械有限公司 | Transdermal drug delivery system for nonsteroidal anti-inflammatory drug and preparation process thereof |
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US5425975A (en) * | 1989-11-08 | 1995-06-20 | Japan Pionics Co., Ltd. | Sheet-shaped heat-generating body |
JP2009153948A (en) * | 2007-12-28 | 2009-07-16 | Kao Corp | Sheetlike exothermic element, sheetlike exothermic intermediate, and exothermic sheet |
CN104974720A (en) * | 2014-04-11 | 2015-10-14 | 上海暖友实业有限公司 | Thin-sheet-type self-heating element, preparation method and application thereof |
CN207492860U (en) * | 2017-01-05 | 2018-06-15 | 苏州恒星医用材料有限公司 | Cervical vertebra warm paste |
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