CN117285868A - Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof - Google Patents

Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof Download PDF

Info

Publication number
CN117285868A
CN117285868A CN202311436893.XA CN202311436893A CN117285868A CN 117285868 A CN117285868 A CN 117285868A CN 202311436893 A CN202311436893 A CN 202311436893A CN 117285868 A CN117285868 A CN 117285868A
Authority
CN
China
Prior art keywords
water
component
based environment
friendly paint
agricultural machinery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311436893.XA
Other languages
Chinese (zh)
Inventor
刘琼
刘福春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Jinghao New Material Co ltd
Original Assignee
Guangzhou Jinghao New Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Jinghao New Material Co ltd filed Critical Guangzhou Jinghao New Material Co ltd
Priority to CN202311436893.XA priority Critical patent/CN117285868A/en
Publication of CN117285868A publication Critical patent/CN117285868A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/002Pretreatement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/16Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to the technical field of water-based environment-friendly paint, and particularly relates to a water-based environment-friendly paint for a bottom surface of an agricultural machine and a preparation method thereof, wherein the water-based environment-friendly paint for the bottom surface of a metal substrate is coated on the surface of the metal substrate; the primer-topcoat water-based environment-friendly paint comprises a component A and a component B, wherein the mass ratio of the component A to the component B is (5-6): 1, a step of; the component A is a water-based epoxy modified acrylic paint, the component B is a hydrophilic aliphatic polyisocyanate curing agent of hexamethylene diisocyanate, and the paint is a primer-topcoat water-based environment-friendly paint which has excellent anti-corrosion performance, good water resistance, excellent adhesive force and easy construction in the field of agricultural machinery.

Description

Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof
Technical Field
The invention belongs to the technical field of water-based environment-friendly paint, and particularly relates to a water-based environment-friendly paint for a bottom surface of an agricultural machine and a preparation method thereof.
Background
With the high development of agricultural mechanization and modernization in China, the technical level of agricultural machinery paint and coating is also continuously improved. The paint for coating is gradually replaced by water paint with low pollution and high performance, high solid paint, powder paint and the like; the traditional coating mode is that the substrate is pretreated by degreasing and dust removal, and then sandblasted; the base coat is epoxy primer, the top coat is polyurethane top coat, the system can not meet the adhesive force requirement of a metal substrate which is not polished, and the salt spray resistance and weather resistance of a coating can not be considered. In order to improve the production efficiency of a part of agricultural equipment, the base materials of the parts of the equipment are steel plates, aluminum plates and cast iron parts, the pretreatment is not polished, a coating manufacturer needs primer-surfacer integrated paint to ensure the consistency of colors, the adhesive force is required to be good, the construction is convenient, the salt spray resistance and weather resistance are good, the appearance is smooth and smooth, the requirements on the paint coating technology are higher, and the primer-surfacer integrated water-based environment-friendly paint is required to be suitable for the coating of various base materials in order to solve the pain points of the industry.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a primer-topcoat water-based environment-friendly paint for agricultural machinery and a preparation method thereof, wherein the paint is the primer-topcoat water-based environment-friendly paint which has excellent anti-corrosion performance, good water resistance, excellent adhesive force and easy construction in the field of agricultural machinery, and the technical scheme of the invention is as follows:
the primer-topcoat water-based environment-friendly paint for agricultural machinery has the specific structure that the primer-topcoat water-based environment-friendly paint is coated on the surface of a metal substrate; the primer-topcoat water-based environment-friendly paint comprises a component A and a component B, wherein the mass ratio of the component A to the component B is (5-6): 1, a step of; the component A is a waterborne epoxy modified acrylic coating, and has quick drying, excellent cohesiveness, flexibility, corrosion resistance and weather resistance; the component B is a hydrophilic aliphatic polyisocyanate curing agent of hexamethylene diisocyanate, has the characteristics of good compatibility, quick drying, hardening and flexibility, good weather resistance and chemical resistance, and the synthetic reaction of the aqueous epoxy modified acrylic acid OH-containing group and isocyanate mainly occurs by the reaction of the active hydride molecular structure in the polyol and the NCO group in the isocyanate.
The component A comprises the following components in percentage by mass: 70-80 parts of aqueous epoxy modified acrylic emulsion, 0.2-0.4 part of defoamer, 0.3-0.5 part of wetting agent, 1-4 parts of cosolvent, 0.1-0.5 part of thixotropic agent, 1-3 parts of aqueous coupling agent, 0.2-0.5 part of flash rust inhibitor and 10-18 parts of deionized water;
the component B is a hydrophilic aliphatic polyisocyanate curing agent of hexamethylene diisocyanate. The component B comprises the following components in percentage by mass: 15-20 parts of aqueous isocyanate curing agent and 3-5 parts of solvent.
Furthermore, the agricultural machinery bottom surface integrated water-based environment-friendly paint comprises a metal substrate, a metal substrate and an iron casting.
Furthermore, in the agricultural machinery bottom surface integrated water-based environment-friendly coating, the water-based coupling agent is gamma-glycidol ether oxypropyl trimethoxy silane, so that the adhesive force, salt fog resistance and water resistance of the water-based epoxy coating to a substrate are enhanced.
Furthermore, the organic alkanolamine salt anti-flash rust agent is added into the component A, so that the anti-flash rust agent has the effects of inhibiting corrosion, passivating and shielding, prevents cathode reaction on the surface of an iron metal substrate, prevents ionization of iron and prevents electrochemical reaction.
Furthermore, in the agricultural machinery bottom surface integrated water-based environment-friendly coating, the component A uses water-based epoxy modified acrylic emulsion, the hydroxyl value of the emulsion is 60-70mgKOH/g, and the emulsion is internally emulsified water-based epoxy modified acrylic emulsion with high Tg and high crosslinking density so as to enhance water resistance, adhesive force and weather resistance.
The preparation method of the agricultural machinery bottom surface integrated water-based environment-friendly paint comprises the following steps:
step 1, pretreatment: ethanol is used for removing oil and impurities on the surface of the metal substrate, and a polishing process is not needed in the process;
step 2, coating: and (3) diluting the primer-topcoat water-based environment-friendly paint with 5-10% purified water to spray viscosity, filtering the paint with 200-mesh nylon filter screen cloth, spraying the sprayed primer-topcoat water-based environment-friendly paint which is one of paint varnish, colored paint, silver paint and pearl paint, baking the paint film with the thickness of 40-60 mu m for 4 hours at the temperature of 60 ℃, and standing for 7 days for performance test.
The beneficial effects of the invention are as follows:
1. the invention improves the coating efficiency, saves the cost and solves the industrial problem;
2. the invention simplifies the coating, and the original epoxy primer and polyurethane finish paint are updated to be the primer-topcoat water-based environment-friendly paint;
3. the invention simplifies pretreatment, removes impurities from the original oil, then sprays sand, updates to remove the impurities only by oil removal, does not need sand spraying, and also meets the adhesive force requirement;
4. the invention improves the appearance effect, and uses the water-based environment-friendly paint with the integrated bottom surface on different metal substrates, thereby achieving consistent appearance color and beautifying the appearance effect.
Drawings
FIG. 1 is a schematic perspective view of a primer-topcoat aqueous environmental-friendly coating for agricultural machinery according to the present invention;
FIG. 2 is a schematic side sectional view of the present invention agricultural machinery floor unification aqueous environmental protection paint;
in the figure, 1-a metal substrate; 2-primer-topcoat aqueous environmental protection paint.
Detailed Description
As shown in fig. 1-2, an agricultural machinery primer-topcoat aqueous environment-friendly coating is specifically configured by coating a primer-topcoat aqueous environment-friendly coating 2 on the surface of a metal substrate 1; the primer-topcoat water-based environment-friendly paint comprises a component A and a component B, wherein the mass ratio of the component A to the component B is 5:1, a step of; the component A is a water-based epoxy modified acrylic paint, and the water-based epoxy modified acrylic emulsion is used, wherein the hydroxyl value of the emulsion is 60-70mgKOH/g, and the emulsion is an internal emulsified high Tg and high crosslinking density water-based epoxy modified acrylic emulsion; the component A is added with a water-based coupling agent which is gamma-glycidyl ether oxypropyl trimethoxy silane and an anti-flash rust agent which are organic-inorganic compound metal organic chelate, and the component B is a hydrophilic aliphatic polyisocyanate curing agent of hexamethylene diisocyanate.
The component A comprises the following components in percentage by mass: 70-80 parts of aqueous epoxy modified acrylic emulsion, 0.2-0.4 part of defoamer, 0.3-0.5 part of wetting agent, 1-4 parts of cosolvent, 0.1-0.5 part of thixotropic agent, 1-3 parts of aqueous coupling agent, 0.2-0.5 part of flash rust inhibitor and 10-18 parts of deionized water;
the component B is a hydrophilic aliphatic polyisocyanate curing agent of hexamethylene diisocyanate. The component B comprises the following components in percentage by mass: 15-20 parts of aqueous isocyanate curing agent and 3-5 parts of solvent.
The preparation method of the agricultural machinery bottom surface integrated water-based environment-friendly paint is characterized by comprising the following steps of:
step 1, pretreatment: ethanol is used for degreasing and impurity removal treatment on the surface of the metal substrate carbon steel plate, and a polishing process is not needed in the process;
step 2, coating: diluting the primer-topcoat water-based environment-friendly paint with 8% purified water to spray viscosity, filtering with 200 mesh nylon filter screen cloth, spraying, baking at 60deg.C for 4 hr with dry film thickness of 50 μm, standing for 7 days, and testing performance as shown in Table 1:
specific embodiments of the present invention will be described in further detail with reference to 1 example and 3 comparative examples, which are illustrative of the present invention but are not intended to limit the scope of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention. The parts indicated in the examples are parts by weight unless otherwise indicated.
Comparative examples 1 to 3 are different from example 1 in the kind of aqueous acrylic emulsion in comparative examples 1 to 2 and the hydroxyl value is the same; comparative example 3 without the addition of an aqueous coupling agent; the preparation process of the paint is kept consistent.
The metal substrates in example 1 and comparative examples 1 to 3 were steel sheets.
The relevant raw materials used in example 1 and comparative examples 1 to 3 were purchased commercially, and the specific sources are shown in table 1:
TABLE 1 sources of raw materials
In example 1 and comparative examples 1 to 3, the components and the contents are as shown in Table 2 in parts by weight:
table 2: component content of example 1 and comparative examples 1 to 3
The agricultural machinery primer-topcoat aqueous environment-friendly paints prepared in this example 1 and comparative examples 1 to 3 were tested with reference to HG/T4757-2014 agricultural machinery paint standards, and the test results are shown in Table 3:
TABLE 3 Performance test results
As can be seen from example 1 and comparative examples 1-3, the agricultural machinery bottom surface integrated water-based environment-friendly paint meets the performance requirements in HG/T4757-2014 agricultural machinery paint standards, wherein the water resistance is 480 hours (standard 168 hours) without abnormality, the salt spray resistance is 500 hours without abnormality, and the artificial climate aging resistance is 1000 hours according with the requirements.
Comparative examples 1 and 2 used aqueous acrylic emulsions, and were unsatisfactory in terms of water resistance and salt spray resistance and resistance to artificial weathering; in the test of adhesion force of different substrates, the test results of not polishing the wiredrawing steel plate, not polishing the iron casting and not polishing the aluminum plate do not meet the requirements.
Summarizing example 1 and comparative examples 1-3, it can be seen that the aqueous epoxy modified acrylic emulsion used in example 1, when applied in combination with a coating formulation, meets standard requirements; the quick-drying performance is achieved, and the construction convenience is improved; the adhesive force of different substrates is good, and the integrated application of different substrates can be solved in the industrial application; and the scheme of integrating the bottom surface improves the construction efficiency and reduces the cost.

Claims (6)

1. The primer-topcoat water-based environment-friendly paint for agricultural machinery is characterized in that the primer-topcoat water-based environment-friendly paint is coated on the surface of a metal substrate; the primer-topcoat water-based environment-friendly paint comprises a component A and a component B, wherein the mass ratio of the component A to the component B is (5-6): 1, a step of;
the component A is a waterborne epoxy modified acrylic coating, and comprises the following components in percentage by mass: 70-80 parts of aqueous epoxy modified acrylic emulsion, 0.2-0.4 part of defoamer, 0.3-0.5 part of wetting agent, 1-4 parts of cosolvent, 0.1-0.5 part of thixotropic agent, 1-3 parts of aqueous coupling agent, 0.2-0.5 part of flash rust inhibitor and 10-18 parts of deionized water;
the component B is a hydrophilic aliphatic polyisocyanate curing agent of hexamethylene diisocyanate, and comprises the following components in percentage by mass: 15-20 parts of aqueous isocyanate curing agent and 3-5 parts of solvent.
2. The agricultural machinery primer-topcoat water-based environmental-friendly paint as claimed in claim 1, wherein the metal substrate comprises steel plate, aluminum plate and iron casting.
3. The agricultural machinery bottom surface unification water-based environment-friendly paint is characterized in that the water-based coupling agent added in the component A is gamma-glycidyl ether oxypropyl trimethoxy silane coupling agent.
4. The agricultural machinery primer-topcoat aqueous environmental protection coating according to claim 1, wherein an organic alkanolamine salt anti-flash rust agent is added to the component a.
5. The agricultural machinery bottom surface unification water-based environment-friendly paint is characterized in that in the component A, water-based epoxy modified acrylic emulsion is used, the hydroxyl value of the emulsion is 60-70mgKOH/g, and the emulsion is an internally emulsified high Tg and high crosslinking density water-based epoxy modified acrylic emulsion.
6. A method for preparing the agricultural machinery bottom surface integrated water-based environment-friendly paint as claimed in any one of claims 1-5, which is characterized by comprising the following steps:
step 1, pretreatment: ethanol is used for removing oil and impurities on the surface of the metal substrate, and a polishing process is not needed in the process;
step 2, coating: and (3) diluting the water-based environment-friendly paint with 5-20% of purified water to the spraying viscosity, filtering by using a 200-mesh nylon filter screen cloth, spraying, baking at the temperature of 60 ℃ for 4 hours, and standing for 7 days to perform performance test.
CN202311436893.XA 2023-11-01 2023-11-01 Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof Pending CN117285868A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311436893.XA CN117285868A (en) 2023-11-01 2023-11-01 Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311436893.XA CN117285868A (en) 2023-11-01 2023-11-01 Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN117285868A true CN117285868A (en) 2023-12-26

Family

ID=89244482

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202311436893.XA Pending CN117285868A (en) 2023-11-01 2023-11-01 Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN117285868A (en)

Similar Documents

Publication Publication Date Title
KR100999328B1 (en) Surface-treated steel sheet
CN107964317A (en) Water soluble acrylic acid amino-stoving varnish and preparation method thereof
CN108977043B (en) Universal single-component water-based metal flashing paint and preparation method thereof
CN102408803A (en) High-performance water-based paint for medium and small mechanical equipment and preparation method thereof
CN108192437B (en) Water-based high-temperature metallic paint capable of being used for wet-on-wet floating-free system and construction process thereof
CN110229602A (en) Fluorocarbon coating and preparation method thereof and coating process
CN111057444A (en) High-solid-content low-viscosity paint, preparation method thereof and paint film coating formed by same
CN111334160A (en) Water-based anticorrosive primer and preparation method thereof
CA1253274A (en) Liquid coating composition, a method of coating a metal substrate and the metal substrate thus obtained
CN109266142B (en) Aqueous solvent-free and high-gloss single-component metallic paint without covering and preparation thereof
CN114133837A (en) Water-based salt spray resistant amino primer and preparation method thereof
CN117285868A (en) Agricultural machinery bottom surface integrated water-based environment-friendly paint and preparation method thereof
CN110791187B (en) Water-based organic hybrid anticorrosive coating and preparation method thereof
CN112680010A (en) Quick-drying bi-component water-based epoxy anticorrosive paint and preparation method thereof
CN112301341A (en) Chromium-free passivation composition capable of being dried at medium and low temperature for galvanized steel and manufacturing and using method thereof
CN115304973B (en) Microcosmic corrosion type nylon glass fiber treating agent and preparation method and application thereof
CN115368805B (en) Water-based double-component matched paint and preparation method and application thereof
CN109836967A (en) Water paint and the general aqueous dual-component epoxy anticorrosion primer of solvent based coating
CN108148494A (en) A kind of urban rail and multiple unit train body double-component aqueous acroleic acid polyurethane selfreparing bloom varnish and preparation method thereof
CN109161316B (en) Coating with good surface adhesion and preparation method and application thereof
CN112409885A (en) Corrosion-resistant water-based epoxy floor paint and preparation method thereof
CN112480793B (en) Zinc-rich coating and preparation method thereof
CN105273616A (en) Conversion coating based on organic metal system
CN116218310B (en) Silica sol modified acrylic acid anticorrosive paint and preparation method thereof
CN113861791B (en) Single-component curing acidic water-based rust conversion coating and preparation and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination