CN117264323A - Vacuum glass bead/glass fiber mixed reinforced polypropylene material and preparation method thereof - Google Patents
Vacuum glass bead/glass fiber mixed reinforced polypropylene material and preparation method thereof Download PDFInfo
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- CN117264323A CN117264323A CN202311337564.XA CN202311337564A CN117264323A CN 117264323 A CN117264323 A CN 117264323A CN 202311337564 A CN202311337564 A CN 202311337564A CN 117264323 A CN117264323 A CN 117264323A
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- parts
- deodorant
- vacuum glass
- polypropylene
- glass fiber
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- -1 polypropylene Polymers 0.000 title claims abstract description 116
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 109
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 108
- 239000011521 glass Substances 0.000 title claims abstract description 85
- 239000003365 glass fiber Substances 0.000 title claims abstract description 73
- 239000011324 bead Substances 0.000 title claims abstract description 67
- 239000000463 material Substances 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 57
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 56
- 239000002781 deodorant agent Substances 0.000 claims abstract description 56
- 239000012855 volatile organic compound Substances 0.000 claims abstract description 49
- 239000011347 resin Substances 0.000 claims abstract description 39
- 229920005989 resin Polymers 0.000 claims abstract description 39
- 239000000314 lubricant Substances 0.000 claims abstract description 24
- 239000002667 nucleating agent Substances 0.000 claims abstract description 24
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 22
- 239000004005 microsphere Substances 0.000 claims abstract description 17
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 229920001577 copolymer Polymers 0.000 claims abstract description 15
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 9
- 229920005629 polypropylene homopolymer Polymers 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 13
- 239000012745 toughening agent Substances 0.000 claims description 13
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 claims description 4
- 229920002943 EPDM rubber Polymers 0.000 claims description 4
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 229940087101 dibenzylidene sorbitol Drugs 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 4
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 4
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 4
- 229940103091 potassium benzoate Drugs 0.000 claims description 4
- 235000010235 potassium benzoate Nutrition 0.000 claims description 4
- 239000004300 potassium benzoate Substances 0.000 claims description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims description 4
- 239000004299 sodium benzoate Substances 0.000 claims description 4
- MPTISGUJJWJZRR-UHFFFAOYSA-N 1,1-bis[2,4-bis(2-phenylpropan-2-yl)phenyl]-2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound C(C)(C)(C1=CC=CC=C1)C1=C(C=CC(=C1)C(C)(C)C1=CC=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C1=CC=CC=C1)C(C)(C)C1=CC=CC=C1 MPTISGUJJWJZRR-UHFFFAOYSA-N 0.000 claims description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- PIFGUSXPWRBLQD-UHFFFAOYSA-N bis[2,4-bis(2-phenylpropan-2-yl)phenyl] dihydroxyphosphanyl phosphite Chemical compound CC(C)(C1=CC=CC=C1)C2=CC(=C(C=C2)OP(OC3=C(C=C(C=C3)C(C)(C)C4=CC=CC=C4)C(C)(C)C5=CC=CC=C5)OP(O)O)C(C)(C)C6=CC=CC=C6 PIFGUSXPWRBLQD-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000007142 ring opening reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 230000004075 alteration Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- DMHHYBUEZRZGDK-UHFFFAOYSA-N 2-(3,5-ditert-butyl-4-hydroxyphenyl)propanamide Chemical compound NC(=O)C(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 DMHHYBUEZRZGDK-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2451/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
Abstract
The invention provides a vacuum glass bead/glass fiber mixed reinforced polypropylene material and a preparation method thereof, wherein the vacuum glass bead/glass fiber mixed reinforced polypropylene material comprises the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent; the polypropylene resin comprises at least one of high-impact copolymer polypropylene and high-strength homo-polypropylene; the vacuum glass microspheres are hollow glass microspheres with smooth surfaces and are treated by a coupling agent; the deodorant A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matters composites with porous structures; the deodorant B is solid or liquid epoxy resin. The polypropylene material prepared by the invention has lower density and smell, and can be applied to the field of new energy automobiles.
Description
Technical Field
The invention belongs to the technical field of high polymer materials, and particularly relates to a vacuum glass bead/glass fiber mixed reinforced polypropylene material and a preparation method thereof.
Background
The polypropylene material has the advantages of light weight, good chemical resistance, high-frequency insulating property, small specific gravity, easy processing and forming, low price and the like, and is widely applied to the fields of automobile industry, electronic and electric industry, household appliances, textile and the like. Compared with the traditional automobile, the electric motor is a great trend of development of the automobile industry. For new energy automobiles, the weight of the power battery can reach hundreds of kilograms. Only by light weight, the weight of the expensive battery can be reduced, the cost of the vehicle can be reduced, and the market demand can be met. Related researches show that the endurance mileage can be increased by 10% -11% when the new energy automobile is reduced by 100 kg. It can also reduce battery cost by 20% and daily wear cost by 20%. Therefore, new energy automobiles are being developed toward weight reduction of the entire vehicle.
At present, glass fibers are generally used for filling reinforced polypropylene materials, so that the polypropylene materials are easy to generate a phenomenon of floating fibers, the appearance is influenced, and the mechanical properties are also reduced; in addition, the density of the glass fiber is high, so that the specific gravity of the filled and reinforced polypropylene material is high, and the development requirement of automobile weight reduction is not met.
Therefore, how to provide a vacuum glass bead/glass fiber mixed reinforced polypropylene material and a preparation method thereof so as to reduce the specific gravity of the polypropylene material is a technical problem which needs to be solved by the person skilled in the art.
Disclosure of Invention
The invention aims to provide a vacuum glass bead/glass fiber mixed reinforced polypropylene material and a preparation method thereof, which are used for at least solving one technical problem.
In order to achieve the above purpose, the first aspect of the invention provides a vacuum glass bead/glass fiber mixed reinforced polypropylene material, which comprises the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent; the polypropylene resin comprises at least one of high-impact copolymer polypropylene and high-strength homo-polypropylene; the vacuum glass microspheres are hollow glass microspheres with smooth surfaces and treated by a coupling agent; the deodorant A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matters composites with porous structures; the deodorant B is solid or liquid epoxy resin.
In a first aspect, the primary antioxidant is 0.2 parts, the secondary antioxidant is 0.3 parts, the low VOC compatibilizer is 4.0 parts, the odor eliminator a is 0.5 parts, the odor eliminator B is 1.5 parts, the nucleating agent is 0.2 parts, the lubricant is 0.5 parts, and the black aid is 1.0 parts.
In a first aspect, the vacuum glass microspheresThe average particle diameter of (2) is 22-27 mu m; the density of the vacuum glass beads is 0.40-0.45g/cm 3 The method comprises the steps of carrying out a first treatment on the surface of the The glass fiber is chopped glass fiber which is soaked by a coupling agent, and the density of the glass fiber is 2.4-2.7g/cm 3 。
In a first aspect, the primary antioxidant comprises at least one of pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], N' -bis- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl) hexanediamine, and stearyl β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate; the secondary antioxidant comprises at least one of tris [2, 4-di-tert-butylphenyl ] phosphite, bis (2, 4-dicumylphenyl) pentaerythritol di (phosphorous) acid ester or bis (2, 4-dicumylphenyl) -diphosphite.
In a first aspect, the toughening agent comprises at least one of a linear low density polyethylene, an ethylene-octene copolymer, and an ethylene propylene diene monomer.
In a first aspect, the low VOC compatibilizer comprises at least one of a low VOC maleic anhydride grafted polypropylene, a maleic anhydride grafted polyethylene, a maleic anhydride grafted ethylene-octene copolymer.
In a first aspect, the nucleating agent comprises at least one of sodium benzoate, potassium benzoate, ultra-fine talc and dibenzylidene sorbitol and derivatives thereof.
In a first aspect, the lubricant comprises maleic anhydride grafted polypropylene wax; the black auxiliary agent comprises a medium-high pigment superfine carbon black masterbatch taking polypropylene or polyethylene as a carrier.
The second aspect of the invention provides a preparation method of the vacuum glass bead/glass fiber mixed reinforced polypropylene material according to the first aspect, which comprises the following steps:
weighing the components, wherein the components comprise the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent;
drying the polypropylene resin;
uniformly mixing the dried polypropylene resin, the weighed main antioxidant, the weighed auxiliary antioxidant, the weighed toughening agent, the weighed low VOC compatilizer, the weighed deodorant A, the weighed deodorant B, the weighed nucleating agent, the weighed lubricant and the weighed black auxiliary agent in a high-speed mixer to obtain a premix;
setting technological parameters of a double-screw extruder, wherein the processing temperature of the double-screw extruder is 220-245 ℃, and the screw rotating speed of the double-screw extruder is 200-450r/min;
the premix is added into a screw cavity of the double-screw extruder from a main feeding port of the double-screw extruder; the vacuum glass beads are added into the screw cavity from one side feeding port of the double-screw extruder; the glass fiber is added into the screw cavity from the other side feeding port of the double-screw extruder;
and extruding and granulating by the double-screw extruder to obtain the vacuum glass bead/glass fiber mixed reinforced polypropylene material.
In a second aspect, the polypropylene resin comprises at least one of high impact copolymer polypropylene and high strength homo-polypropylene; the vacuum glass microspheres are hollow glass microspheres with smooth surfaces and treated by a coupling agent; the deodorant A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matters composites with porous structures; the deodorant B is solid or liquid epoxy resin;
0.2 parts of main antioxidant, 0.3 parts of auxiliary antioxidant, 4.0 parts of low VOC (volatile organic compound) compatilizer, 0.5 parts of deodorant A, 1.5 parts of deodorant B, 0.2 parts of nucleating agent, 0.5 parts of lubricant and 1.0 part of black auxiliary agent.
The beneficial effects are that:
the invention provides a vacuum glass bead/glass fiber mixed reinforced polypropylene material which comprises the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent; the polypropylene resin comprises at least one of high-impact copolymerized polypropylene and high-strength homopolymerized polypropylene, and the mechanical properties of the polypropylene material are changed by adjusting the proportion between the polypropylene resins; the vacuum glass beads are hollow glass beads with smooth surfaces, which are treated by the coupling agent, and the vacuum glass beads are mixed with glass fibers to be filled with reinforced polypropylene materials by utilizing the low density and spherical all-direction consistency of the vacuum glass beads, so that the stress and defects are reduced, and the dimensional stability of the polypropylene materials is maintained; the low VOC compatilizer has lower odor, the odor removing agent A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matter composites with porous structures, the odor, the organic matters and small molecular matters are adsorbed, the odor is further reduced, the odor removing agent B is solid or liquid epoxy resin, and the active epoxy groups can act with the low VOC compatilizer after ring opening, so that the odor is further reduced. The vacuum glass beads and the glass fibers are mixed and filled to strengthen the polypropylene material, so that the density of the polypropylene material is reduced, and the low VOC compatilizer, the deodorant A and the deodorant B are compounded, so that the smell of the polypropylene material is reduced, and the vacuum glass beads and the glass fibers can be applied to the field of new energy automobiles.
Drawings
In order to more clearly illustrate the embodiments of the present description or the technical solutions in the prior art, the drawings that are needed in the embodiments will be briefly described below, it being obvious that the drawings in the following description are only some embodiments of the present invention, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
Fig. 1 is a flow chart of a method for preparing a vacuum glass bead/glass fiber mixed reinforced polypropylene material.
Detailed Description
The advantages and various effects of the present invention will be more clearly apparent from the following detailed description and examples. It will be understood by those skilled in the art that these specific embodiments and examples are intended to illustrate the invention, not to limit the invention.
Throughout the specification, unless specifically indicated otherwise, the terms used herein should be understood as meaning as commonly used in the art. Accordingly, unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification will control.
Unless specifically indicated otherwise, the various raw materials, reagents, instruments, equipment, etc., used in the present invention are commercially available or may be obtained by existing methods.
The application provides a vacuum glass bead/glass fiber mixed reinforced polypropylene material, which comprises the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent; the polypropylene resin comprises at least one of high-impact copolymer polypropylene and high-strength homo-polypropylene; the vacuum glass microspheres are hollow glass microspheres with smooth surfaces and treated by a coupling agent; the deodorant A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matters composites with porous structures; the deodorant B is solid or liquid epoxy resin.
The invention provides a vacuum glass bead/glass fiber mixed reinforced polypropylene material which comprises the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent; the polypropylene resin comprises at least one of high-impact copolymerized polypropylene and high-strength homopolymerized polypropylene, and the mechanical properties of the polypropylene material are changed by adjusting the proportion between the polypropylene resins; the vacuum glass beads are hollow glass beads with smooth surfaces, which are treated by the coupling agent, and the vacuum glass beads are mixed with glass fibers to be filled with reinforced polypropylene materials by utilizing the low density and spherical all-direction consistency of the vacuum glass beads, so that the stress and defects are reduced, and the dimensional stability of the polypropylene materials is maintained; the low VOC compatilizer has lower odor, the odor removing agent A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matter composites with porous structures, the odor, the organic matters and small molecular matters are adsorbed, the odor is further reduced, the odor removing agent B is solid or liquid epoxy resin, and the active epoxy groups can act with the low VOC compatilizer after ring opening, so that the odor is further reduced. The vacuum glass beads and the glass fibers are mixed and filled to strengthen the polypropylene material, so that the density of the polypropylene material is reduced, and the low VOC compatilizer, the deodorant A and the deodorant B are compounded, so that the smell of the polypropylene material is reduced, and the vacuum glass beads and the glass fibers can be applied to the field of new energy automobiles.
In some possible embodiments, the primary antioxidant is 0.2 parts, the secondary antioxidant is 0.3 parts, the low VOC compatibilizer is 4.0 parts, the odor eliminator a is 0.5 parts, the odor eliminator B is 1.5 parts, the nucleating agent is 0.2 parts, the lubricant is 0.5 parts, and the black aid is 1.0 parts.
In some possible embodiments, the vacuum glass microspheres have an average particle size of 22-27 μm; the density of the vacuum glass beads is 0.40-0.45g/cm 3 The method comprises the steps of carrying out a first treatment on the surface of the The glass fiber is chopped glass fiber which is soaked by a coupling agent, and the density of the glass fiber is 2.4-2.7g/cm 3 。
The vacuum glass microsphere is a micron-sized hollow glass microsphere with smooth surface treated by a special coupling agent, and has good compatibility with resin; the vacuum glass beads have very highThe high compression strength density ratio and the obvious weight reducing effect; the spherical consistency reduces stress and defects, and maintains the dimensional stability of the product; the glass fiber is glass fiber which is soaked by special coupling agent, the binding force between resin and glass fiber is improved, and the density of the vacuum glass beads is 0.40-0.45g/cm 3 The density of the glass fiber is 2.4-2.7g/cm 3 The vacuum glass beads and glass fibers are adopted to mix and reinforce the polypropylene material, so that the density of the polypropylene material can be reduced, and meanwhile, the mechanical property of the polypropylene material is kept within the application range of the automobile field.
In some possible embodiments, the primary antioxidant comprises at least one of pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], N' -bis- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl) hexanediamine, and stearyl β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate; the secondary antioxidant comprises at least one of tris [2, 4-di-tert-butylphenyl ] phosphite, bis (2, 4-dicumylphenyl) pentaerythritol di (phosphorous) acid ester or bis (2, 4-dicumylphenyl) -diphosphite.
The antioxidant consists of a main antioxidant and an auxiliary antioxidant, wherein the main antioxidant comprises phenolic antioxidants such as N, N' -1, 6-hexamethylene-bis- (3, 5-di-tert-butyl-4-hydroxy-phenyl-propionamide), the auxiliary antioxidant comprises phosphite antioxidants such as phenyl tri- (2, 4-di-tert-butylphenyl) phosphite, active hydrogen atoms exist in the molecule of the main antioxidant, and the H atom ratio of the H atoms of the high molecular chain is active and can be combined with a decomposed macromolecular chain free radical R or ROO, so that the chain growth is destroyed, and the antioxidant function is realized; the auxiliary antioxidant acts with the hydroperoxide generated by the decomposition of the organic matters to prevent the generation of free radicals, further prevent more free radicals from continuously generating, and achieve the purposes of maintaining the thermal stability of the organic matters and prolonging the service life of the organic matters; the influence of light, heat and oxygen exists in the front and rear stages of processing, and the synergistic effect of the main antioxidant and the auxiliary antioxidant can delay the thermal oxidation rate of the organic matters in the processing and using processes.
In some possible embodiments, the toughening agent includes at least one of a linear low density polyethylene, an ethylene-octene copolymer, and an ethylene propylene diene monomer.
The toughening agent comprises at least one of linear low-density polyethylene, ethylene-octene copolymer and ethylene propylene diene monomer, so that the impact resistance and low temperature resistance of the polypropylene resin are improved.
In some possible embodiments, the low VOC compatibilizer comprises at least one of a low VOC maleic anhydride grafted polypropylene, a maleic anhydride grafted polyethylene, a maleic anhydride grafted ethylene-octene copolymer.
The low VOC compatilizer comprises at least one of low VOC maleic anhydride grafted polypropylene, maleic anhydride grafted polyethylene and maleic anhydride grafted ethylene-octene copolymer, improves the compatibility of the resin and glass fiber, and enhances the binding force of the resin and the glass fiber.
In some possible embodiments, the nucleating agent comprises at least one of sodium benzoate, potassium benzoate, ultra-fine talc and dibenzylidene sorbitol and derivatives thereof.
The nucleating agent comprises at least one of sodium benzoate, potassium benzoate, superfine talcum powder, dibenzylidene sorbitol and derivatives thereof, and can reduce the molding cycle of polypropylene.
In some possible embodiments, the lubricant comprises maleic anhydride grafted polypropylene wax; the black auxiliary agent comprises a medium-high pigment superfine carbon black masterbatch taking polypropylene or polyethylene as a carrier.
The lubricant comprises maleic anhydride grafted polypropylene wax, has good compatibility with polypropylene resin and can be well dispersed in the polypropylene resin; the black auxiliary agent comprises a medium-high pigment superfine carbon black masterbatch taking polypropylene or polyethylene as a carrier, and the polypropylene resin has good compatibility and can be well dispersed in the polypropylene resin.
Based on one general inventive concept, the present application also provides a preparation method of the vacuum glass bead/glass fiber mixed reinforced polypropylene material, which comprises the following steps:
s1: weighing the components, wherein the components comprise the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent;
s2: drying the polypropylene resin;
s3: uniformly mixing the dried polypropylene resin, the weighed main antioxidant, the weighed auxiliary antioxidant, the weighed toughening agent, the weighed low VOC compatilizer, the weighed deodorant A, the weighed deodorant B, the weighed nucleating agent, the weighed lubricant and the weighed black auxiliary agent in a high-speed mixer to obtain a premix;
s4: setting technological parameters of a double-screw extruder, wherein the processing temperature of the double-screw extruder is 220-245 ℃, and the screw rotating speed of the double-screw extruder is 200-450r/min;
s5: the premix is added into a screw cavity of the double-screw extruder from a main feeding port of the double-screw extruder; the vacuum glass beads are added into the screw cavity from one side feeding port of the double-screw extruder; the glass fiber is added into the screw cavity from the other side feeding port of the double-screw extruder;
s6: and extruding and granulating by the double-screw extruder to obtain the vacuum glass bead/glass fiber mixed reinforced polypropylene material.
With reference to the second aspect of the present application, the polypropylene resin includes at least one of high impact copolymer polypropylene and high strength homo-polypropylene; the vacuum glass microspheres are hollow glass microspheres with smooth surfaces and treated by a coupling agent; the deodorant A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matters composites with porous structures; the deodorant B is solid or liquid epoxy resin;
0.2 parts of main antioxidant, 0.3 parts of auxiliary antioxidant, 4.0 parts of low VOC (volatile organic compound) compatilizer, 0.5 parts of deodorant A, 1.5 parts of deodorant B, 0.2 parts of nucleating agent, 0.5 parts of lubricant and 1.0 part of black auxiliary agent.
The present application is further illustrated below in conjunction with specific examples. It should be understood that these examples are illustrative only of the present application and are not intended to limit the scope of the present application. The experimental procedures, which are not specified in the following examples, are generally determined according to national standards. If the corresponding national standard does not exist, the method is carried out according to the general international standard, the conventional condition or the condition recommended by the manufacturer.
The polypropylene materials of examples 1-4 and comparative example 1 are shown in the following Table 1 in parts by weight:
TABLE 1 raw materials components weight portions
| Component (A) | Example 1 | Example 2 | Example 3 | Example 4 | Comparative example |
| Polypropylene resin A | 36.8 | 33.8 | 33.8 | 28.8 | 36.8 |
| Polypropylene resin B | 15 | 15 | 15 | 15 | 15 |
| Vacuum glass bead | 10 | 10 | 15 | 20 | - |
| Glass fiber | 30 | 30 | 25 | 20 | 40 |
| Main antioxidant | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Auxiliary antioxidant | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
| Toughening agent | 0 | 3.0 | 3.0 | 3.0 | 0 |
| Low VOC compatibilizers | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 |
| Deodorant A | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Deodorant B | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| Nucleating agent | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Lubricant | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Black auxiliary agent | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 |
The components are obtained according to the weight parts of the raw materials in table 1, and the polypropylene composite material is prepared according to the following steps:
(1) Drying the weighed polypropylene resin;
(2) Uniformly mixing the dried polypropylene resin with the weighed main antioxidant, auxiliary antioxidant, toughening agent, low VOC compatilizer, deodorant A, deodorant B, nucleating agent, lubricant and black auxiliary agent in a high-speed mixer to obtain a premix;
(3) Setting technological parameters of a double-screw extruder, wherein the processing temperature of the double-screw extruder is 220-245 ℃, and the screw rotating speed of the double-screw extruder is 200-450r/min;
(4) Adding the premix of step (2) from the main feeding port into the screw cavity of the twin-screw extruder; vacuum glass beads are added into the screw cavity from one side feeding port of the double-screw extruder; glass fibers are added into the screw cavity from the other side feeding port of the double-screw extruder;
(5) Extruding and granulating by a double-screw extruder to obtain the vacuum glass bead/glass fiber mixed reinforced polypropylene material.
The polypropylene composite material prepared above was made into sample strips for testing, and the test results are shown in table 2 below:
table 2 test results
From the above table, it can be seen that: compared with the comparative example, the vacuum glass bead/glass fiber mixed reinforced polypropylene material prepared by the embodiment of the invention has lower density, can be applied to the field of new energy automobiles, and meets the development requirement of light weight of the whole automobile.
The examples and the comparative examples have lower odor because the low VOC compatilizer, the deodorant A and the deodorant B are compounded, and the low VOC compatilizer has lower odor; the deodorant A has a porous structure, has strong physical adsorption capacity on smell and organic matters, adsorbs small molecular substances, and can further reduce smell; the deodorant B contains active epoxy groups, can be grafted to maleic anhydride in the low VOC compatilizer after ring opening, and further reduces odor.
In the embodiment 1, 10% of vacuum glass beads are used for replacing 10% of glass fibers, the true density of the selected vacuum glass beads is 0.4296g/cm < 3 >, and the true density of the glass fibers is 2.4-2.7g/cm < 3 >, so that compared with the 40% glass fiber reinforced polypropylene composite material of the comparative example, the density of the 10% vacuum glass beads/30% glass fiber mixed reinforced polypropylene composite material is reduced, but the mechanical property is reduced more.
In example 2, on the basis of the examples, a small amount of toughening agent is added, and the toughening effect is achieved after the content of the compatilizer exceeds a certain amount, so that the toughening efficiency is improved by using a toughening agent/compatilizer composite toughening method, the flexural modulus is partially lost because the rigidity of the material is reduced by adding the toughening agent, the other mechanical properties are obviously improved, the density is further reduced, the damage of external force to the vacuum glass beads in the extrusion and injection molding processes is reduced after adding a small amount of toughening agent, and the buffering effect is achieved, so that the tensile strength and the flexural strength of the material are improved. Examples 3 and 4, after increasing the proportion of vacuum glass beads based on example 2, the density of the material was further reduced, the flexural modulus was increased, the rigidity of the material was increased, resulting in a decrease in toughness and a decrease in impact strength of the material.
In conclusion, compared with the traditional glass fiber reinforced polypropylene material, the polypropylene material prepared by the formula proportion has lower odor, gives the material a more excellent appearance on the premise of keeping the good mechanical property of the material, and can also lighten the weight of the glass fiber reinforced PP composite material.
Finally, it is also noted that the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
While preferred embodiments of the present invention have been described, additional variations and modifications in those embodiments may occur to those skilled in the art once they learn of the basic inventive concepts. It is therefore intended that the following claims be interpreted as including the preferred embodiments and all such alterations and modifications as fall within the scope of the invention.
It will be apparent to those skilled in the art that various modifications and variations can be made to the present invention without departing from the spirit or scope of the invention. Thus, it is intended that the present invention also include such modifications and alterations insofar as they come within the scope of the appended claims or the equivalents thereof.
Claims (10)
1. The vacuum glass bead/glass fiber mixed reinforced polypropylene material is characterized by comprising the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent;
the polypropylene resin comprises at least one of high-impact copolymer polypropylene and high-strength homo-polypropylene;
the vacuum glass microspheres are hollow glass microspheres with smooth surfaces and treated by a coupling agent;
the deodorant A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matters composites with porous structures;
the deodorant B is solid or liquid epoxy resin.
2. The vacuum glass bead/glass fiber mixed reinforced polypropylene material according to claim 1, wherein the primary antioxidant is 0.2 parts, the secondary antioxidant is 0.3 parts, the low VOC compatibilizer is 4.0 parts, the odor remover a is 0.5 parts, the odor remover B is 1.5 parts, the nucleating agent is 0.2 parts, the lubricant is 0.5 parts, and the black auxiliary agent is 1.0 part.
3. The vacuum glass bead/glass fiber mixed reinforced polypropylene material according to claim 2, wherein the average particle size of the vacuum glass beads is 22-27 μm; the density of the vacuum glass beads is 0.40-0.45g/cm 3 ；
The glass fiber is chopped glass fiber which is soaked by a coupling agent, and the density of the glass fiber is 2.4-2.7g/cm 3 。
4. The vacuum glass bead/glass fiber mixed reinforced polypropylene material according to claim 3, wherein the primary antioxidant comprises at least one of pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], N' -bis- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl) hexanediamine, and stearyl β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate;
the secondary antioxidant comprises at least one of tris [2, 4-di-tert-butylphenyl ] phosphite, bis (2, 4-dicumylphenyl) pentaerythritol di (phosphorous) acid ester or bis (2, 4-dicumylphenyl) -diphosphite.
5. The vacuum glass bead/glass fiber hybrid reinforced polypropylene material of claim 4, wherein the toughening agent comprises at least one of a linear low density polyethylene, an ethylene-octene copolymer, and an ethylene propylene diene monomer.
6. The vacuum glass bead/glass fiber hybrid reinforced polypropylene material of claim 5, wherein the low VOC compatibilizer comprises at least one of a low VOC maleic anhydride grafted polypropylene, a maleic anhydride grafted polyethylene, a maleic anhydride grafted ethylene-octene copolymer.
7. The vacuum glass bead/glass fiber hybrid reinforced polypropylene material according to claim 6, wherein the nucleating agent comprises at least one of sodium benzoate, potassium benzoate, ultra-fine talc and dibenzylidene sorbitol and derivatives thereof.
8. The vacuum glass bead/glass fiber hybrid reinforced polypropylene material of claim 7, wherein the lubricant comprises maleic anhydride grafted polypropylene wax;
the black auxiliary agent comprises a medium-high pigment superfine carbon black masterbatch taking polypropylene or polyethylene as a carrier.
9. A method for preparing a vacuum glass bead/glass fiber mixed reinforced polypropylene material according to any one of claims 1 to 8, comprising the steps of:
weighing the components, wherein the components comprise the following components in parts by weight: 40-70 parts of polypropylene resin, 10-20 parts of vacuum glass beads, 20-30 parts of glass fibers, 0.2-0.4 part of primary antioxidant, 0.2-0.4 part of secondary antioxidant, 1.0-5.0 parts of flexibilizer, 0.5-6.0 parts of low VOC (volatile organic compound) compatilizer, 0.5-2.0 parts of deodorant A, 1.0-3.0 parts of deodorant B, 0.1-2.0 parts of nucleating agent, 0.5-1.5 parts of lubricant and 0.5-2.0 parts of black auxiliary agent;
drying the polypropylene resin;
uniformly mixing the dried polypropylene resin, the weighed main antioxidant, the weighed auxiliary antioxidant, the weighed toughening agent, the weighed low VOC compatilizer, the weighed deodorant A, the weighed deodorant B, the weighed nucleating agent, the weighed lubricant and the weighed black auxiliary agent in a high-speed mixer to obtain a premix;
setting technological parameters of a double-screw extruder, wherein the processing temperature of the double-screw extruder is 220-245 ℃, and the screw rotating speed of the double-screw extruder is 200-450r/min;
the premix is added into a screw cavity of the double-screw extruder from a main feeding port of the double-screw extruder; the vacuum glass beads are added into the screw cavity from one side feeding port of the double-screw extruder; the glass fiber is added into the screw cavity from the other side feeding port of the double-screw extruder;
and extruding and granulating by the double-screw extruder to obtain the vacuum glass bead/glass fiber mixed reinforced polypropylene material.
10. The method for preparing the vacuum glass bead/glass fiber mixed reinforced polypropylene material according to claim 9, wherein,
the polypropylene resin comprises at least one of high-impact copolymer polypropylene and high-strength homo-polypropylene;
the vacuum glass microspheres are hollow glass microspheres with smooth surfaces and treated by a coupling agent;
the deodorant A comprises at least one of inorganic matters with porous structures, organic matters with porous structures and inorganic matters/organic matters composites with porous structures;
the deodorant B is solid or liquid epoxy resin;
0.2 parts of main antioxidant, 0.3 parts of auxiliary antioxidant, 4.0 parts of low VOC (volatile organic compound) compatilizer, 0.5 parts of deodorant A, 1.5 parts of deodorant B, 0.2 parts of nucleating agent, 0.5 parts of lubricant and 1.0 part of black auxiliary agent.
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