CN1171775A - Fluorobutenyl esters - Google Patents
Fluorobutenyl esters Download PDFInfo
- Publication number
- CN1171775A CN1171775A CN95197158A CN95197158A CN1171775A CN 1171775 A CN1171775 A CN 1171775A CN 95197158 A CN95197158 A CN 95197158A CN 95197158 A CN95197158 A CN 95197158A CN 1171775 A CN1171775 A CN 1171775A
- Authority
- CN
- China
- Prior art keywords
- compound
- general formula
- group
- alkyl
- implication
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000002148 esters Chemical class 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 49
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 25
- 150000002367 halogens Chemical class 0.000 claims abstract description 25
- 239000001257 hydrogen Substances 0.000 claims abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
- 241001465754 Metazoa Species 0.000 claims abstract description 13
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 144
- -1 carbalkoxy Chemical group 0.000 claims description 59
- 125000000217 alkyl group Chemical group 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 36
- 239000003795 chemical substances by application Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 23
- 239000001301 oxygen Substances 0.000 claims description 23
- 229910052760 oxygen Inorganic materials 0.000 claims description 23
- 125000004414 alkyl thio group Chemical group 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 21
- 125000003545 alkoxy group Chemical group 0.000 claims description 21
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 21
- 241000238631 Hexapoda Species 0.000 claims description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- 238000002360 preparation method Methods 0.000 claims description 20
- 239000005864 Sulphur Chemical group 0.000 claims description 19
- 239000002585 base Substances 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 18
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 13
- 239000003513 alkali Substances 0.000 claims description 12
- 125000003368 amide group Chemical group 0.000 claims description 12
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 239000010452 phosphate Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 7
- 125000003282 alkyl amino group Chemical group 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 6
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 6
- DCERHCFNWRGHLK-UHFFFAOYSA-N C[Si](C)C Chemical compound C[Si](C)C DCERHCFNWRGHLK-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 150000002829 nitrogen Chemical class 0.000 claims description 5
- 125000002769 thiazolinyl group Chemical group 0.000 claims description 5
- 150000007970 thio esters Chemical class 0.000 claims description 5
- 150000001721 carbon Chemical group 0.000 claims description 4
- 125000001072 heteroaryl group Chemical group 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- 230000007480 spreading Effects 0.000 claims description 3
- 238000003892 spreading Methods 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims description 2
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 claims description 2
- 125000004391 aryl sulfonyl group Chemical group 0.000 claims description 2
- 125000005110 aryl thio group Chemical group 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 125000001188 haloalkyl group Chemical group 0.000 claims description 2
- 150000002431 hydrogen Chemical group 0.000 claims 5
- WQJONRMBVKFKOB-UHFFFAOYSA-N cyanatosulfanyl cyanate Chemical compound N#COSOC#N WQJONRMBVKFKOB-UHFFFAOYSA-N 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 2
- 229910052720 vanadium Inorganic materials 0.000 abstract description 2
- 229910052727 yttrium Inorganic materials 0.000 abstract description 2
- 239000013067 intermediate product Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 40
- 239000002904 solvent Substances 0.000 description 34
- 239000000463 material Substances 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- 239000000243 solution Substances 0.000 description 24
- 239000003995 emulsifying agent Substances 0.000 description 22
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 21
- 238000012360 testing method Methods 0.000 description 19
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 18
- 239000002994 raw material Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 15
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 14
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 14
- 229910052731 fluorine Inorganic materials 0.000 description 13
- 239000011737 fluorine Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 239000002023 wood Substances 0.000 description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 11
- 239000000460 chlorine Substances 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- 241001674048 Phthiraptera Species 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 238000009835 boiling Methods 0.000 description 8
- 125000003917 carbamoyl group Chemical class [H]N([H])C(*)=O 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 7
- 229920000151 polyglycol Polymers 0.000 description 7
- 239000010695 polyglycol Substances 0.000 description 7
- 239000011877 solvent mixture Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 241000256602 Isoptera Species 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 241000244206 Nematoda Species 0.000 description 6
- 125000002877 alkyl aryl group Chemical group 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 230000024241 parasitism Effects 0.000 description 6
- 240000007594 Oryza sativa Species 0.000 description 5
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000036541 health Effects 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 235000010446 mineral oil Nutrition 0.000 description 5
- 229940031815 mycocide Drugs 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- NFDXQGNDWIPXQL-UHFFFAOYSA-N 1-cyclooctyldiazocane Chemical compound C1CCCCCCC1N1NCCCCCC1 NFDXQGNDWIPXQL-UHFFFAOYSA-N 0.000 description 4
- 241001124076 Aphididae Species 0.000 description 4
- 241000238659 Blatta Species 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 241001427559 Collembola Species 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 241000255925 Diptera Species 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 241001608567 Phaedon cochleariae Species 0.000 description 4
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 4
- 241000429635 Xestobium rufovillosum Species 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 239000012973 diazabicyclooctane Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 125000000623 heterocyclic group Chemical group 0.000 description 4
- 239000005645 nematicide Substances 0.000 description 4
- 239000006072 paste Substances 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 238000010025 steaming Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229940032021 tetramune Drugs 0.000 description 4
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 241001143309 Acanthoscelides obtectus Species 0.000 description 3
- 241000238876 Acari Species 0.000 description 3
- 241000256844 Apis mellifera Species 0.000 description 3
- 241000239290 Araneae Species 0.000 description 3
- 241000238421 Arthropoda Species 0.000 description 3
- 235000011303 Brassica alboglabra Nutrition 0.000 description 3
- 240000007124 Brassica oleracea Species 0.000 description 3
- 235000011302 Brassica oleracea Nutrition 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- 241000258937 Hemiptera Species 0.000 description 3
- 241001495069 Ischnocera Species 0.000 description 3
- 241000256259 Noctuidae Species 0.000 description 3
- 241000500439 Plutella Species 0.000 description 3
- 241000238680 Rhipicephalus microplus Species 0.000 description 3
- 241000509427 Sarcoptes scabiei Species 0.000 description 3
- 241000255632 Tabanus atratus Species 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 241000267822 Trogoderma granarium Species 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 238000010171 animal model Methods 0.000 description 3
- 125000001584 benzyloxycarbonyl group Chemical group C(=O)(OCC1=CC=CC=C1)* 0.000 description 3
- 239000008280 blood Substances 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Aalpha Natural products C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 244000144977 poultry Species 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- ZWZVWGITAAIFPS-UHFFFAOYSA-N thiophosgene Chemical compound ClC(Cl)=S ZWZVWGITAAIFPS-UHFFFAOYSA-N 0.000 description 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 2
- ZMYFCFLJBGAQRS-IAGOWNOFSA-N (2S,3R)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@]1(CN2N=CN=C2)[C@@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IAGOWNOFSA-N 0.000 description 2
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 2
- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 2
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 description 2
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
- QDFXRVAOBHEBGJ-UHFFFAOYSA-N 3-(cyclononen-1-yl)-4,5,6,7,8,9-hexahydro-1h-diazonine Chemical compound C1CCCCCCC=C1C1=NNCCCCCC1 QDFXRVAOBHEBGJ-UHFFFAOYSA-N 0.000 description 2
- 239000005660 Abamectin Substances 0.000 description 2
- 241000256118 Aedes aegypti Species 0.000 description 2
- 239000005877 Alpha-Cypermethrin Substances 0.000 description 2
- 241000242266 Amphimallon majalis Species 0.000 description 2
- 241000273311 Aphis spiraecola Species 0.000 description 2
- 241000387313 Aspidiotus Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- 241001674044 Blattodea Species 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- 239000005944 Chlorpyrifos Substances 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- 241000675108 Citrus tangerina Species 0.000 description 2
- 241001498622 Cixius wagneri Species 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 241000256054 Culex <genus> Species 0.000 description 2
- 239000005946 Cypermethrin Substances 0.000 description 2
- 239000005757 Cyproconazole Substances 0.000 description 2
- 241000289763 Dasygaster padockina Species 0.000 description 2
- 239000005892 Deltamethrin Substances 0.000 description 2
- 241001124144 Dermaptera Species 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 2
- 239000005780 Fluazinam Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 206010018498 Goitre Diseases 0.000 description 2
- 241000578422 Graphosoma lineatum Species 0.000 description 2
- 241000771999 Hippobosca Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000005795 Imazalil Substances 0.000 description 2
- 239000005906 Imidacloprid Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241001149911 Isopoda Species 0.000 description 2
- 235000003228 Lactuca sativa Nutrition 0.000 description 2
- 240000008415 Lactuca sativa Species 0.000 description 2
- 241001124553 Lepismatidae Species 0.000 description 2
- 241000257162 Lucilia <blowfly> Species 0.000 description 2
- 241000257166 Lucilia cuprina Species 0.000 description 2
- 241000243786 Meloidogyne incognita Species 0.000 description 2
- 241000501409 Menoponidae Species 0.000 description 2
- 239000005868 Metconazole Substances 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241000238661 Periplaneta Species 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000005924 Pirimiphos-methyl Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000005822 Propiconazole Substances 0.000 description 2
- 241000382353 Pupa Species 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 241001509967 Reticulitermes flavipes Species 0.000 description 2
- 241000125167 Rhopalosiphum padi Species 0.000 description 2
- 241000545593 Scolytinae Species 0.000 description 2
- 241001157780 Scutigera coleoptrata Species 0.000 description 2
- 241000258242 Siphonaptera Species 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 239000005839 Tebuconazole Substances 0.000 description 2
- 241001414989 Thysanoptera Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000005942 Triflumuron Substances 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 244000098338 Triticum aestivum Species 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000000642 acaricide Substances 0.000 description 2
- WCXDHFDTOYPNIE-UHFFFAOYSA-N acetamiprid Chemical compound N#CN=C(C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 230000003042 antagnostic effect Effects 0.000 description 2
- AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 description 2
- 229950000294 azaconazole Drugs 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- KXRPCFINVWWFHQ-UHFFFAOYSA-N cadusafos Chemical compound CCC(C)SP(=O)(OCC)SC(C)CC KXRPCFINVWWFHQ-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- NGDNCZPCIZNCQS-UHFFFAOYSA-N ctk3j8699 Chemical compound Cl=S NGDNCZPCIZNCQS-UHFFFAOYSA-N 0.000 description 2
- 229960001591 cyfluthrin Drugs 0.000 description 2
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 2
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 2
- 229960005424 cypermethrin Drugs 0.000 description 2
- 229960002483 decamethrin Drugs 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 229960003887 dichlorophen Drugs 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 description 2
- 229960002125 enilconazole Drugs 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- RIZMRRKBZQXFOY-UHFFFAOYSA-N ethion Chemical compound CCOP(=S)(OCC)SCSP(=S)(OCC)OCC RIZMRRKBZQXFOY-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 description 2
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 201000003872 goiter Diseases 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229940056881 imidacloprid Drugs 0.000 description 2
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- FCOAHACKGGIURQ-UHFFFAOYSA-N iprobenfos Chemical compound CC(C)OP(=O)(OC(C)C)SCC1=CC=CC=C1 FCOAHACKGGIURQ-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 2
- 230000001069 nematicidal effect Effects 0.000 description 2
- LKPLKUMXSAEKID-UHFFFAOYSA-N pentachloronitrobenzene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LKPLKUMXSAEKID-UHFFFAOYSA-N 0.000 description 2
- 229960000490 permethrin Drugs 0.000 description 2
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 2
- 229950001664 phoxim Drugs 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- QHOQHJPRIBSPCY-UHFFFAOYSA-N pirimiphos-methyl Chemical group CCN(CC)C1=NC(C)=CC(OP(=S)(OC)OC)=N1 QHOQHJPRIBSPCY-UHFFFAOYSA-N 0.000 description 2
- 239000003495 polar organic solvent Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- ROZUQUDEWZIBHV-UHFFFAOYSA-N tecloftalam Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC(Cl)=C1Cl ROZUQUDEWZIBHV-UHFFFAOYSA-N 0.000 description 2
- XLNZEKHULJKQBA-UHFFFAOYSA-N terbufos Chemical compound CCOP(=S)(OCC)SCSC(C)(C)C XLNZEKHULJKQBA-UHFFFAOYSA-N 0.000 description 2
- 239000004308 thiabendazole Substances 0.000 description 2
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 2
- 235000010296 thiabendazole Nutrition 0.000 description 2
- 229960004546 thiabendazole Drugs 0.000 description 2
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 2
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 description 1
- XERJKGMBORTKEO-VZUCSPMQSA-N (1e)-2-(ethylcarbamoylamino)-n-methoxy-2-oxoethanimidoyl cyanide Chemical compound CCNC(=O)NC(=O)C(\C#N)=N\OC XERJKGMBORTKEO-VZUCSPMQSA-N 0.000 description 1
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 1
- OTLLEIBWKHEHGU-TUNUFRSWSA-N (2R,3S,4S,5S)-2-[(2R,3R,4R,5S,6R)-5-[[(2R,3S,4R,5R)-5-(6-aminopurin-9-yl)-3,4-dihydroxyoxolan-2-yl]methoxy]-3,4-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-3,5-dihydroxy-4-phosphonooxyhexanedioic acid Chemical compound C([C@H]1O[C@H]([C@@H]([C@@H]1O)O)N1C=2N=CN=C(C=2N=C1)N)O[C@@H]1[C@@H](CO)O[C@H](O[C@H]([C@H](O)[C@H](OP(O)(O)=O)[C@H](O)C(O)=O)C(O)=O)[C@H](O)[C@H]1O OTLLEIBWKHEHGU-TUNUFRSWSA-N 0.000 description 1
- RYAUSSKQMZRMAI-ALOPSCKCSA-N (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ALOPSCKCSA-N 0.000 description 1
- URDNHJIVMYZFRT-KGLIPLIRSA-N (2r,3r)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pentan-3-ol Chemical compound C([C@H]([C@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1Cl URDNHJIVMYZFRT-KGLIPLIRSA-N 0.000 description 1
- FSJYRLHKLVGCNH-UHFFFAOYSA-N (3-tert-butylphenyl) n-methylcarbamate Chemical compound CNC(=O)OC1=CC=CC(C(C)(C)C)=C1 FSJYRLHKLVGCNH-UHFFFAOYSA-N 0.000 description 1
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
- XUNYDVLIZWUPAW-UHFFFAOYSA-N (4-chlorophenyl) n-(4-methylphenyl)sulfonylcarbamate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)OC1=CC=C(Cl)C=C1 XUNYDVLIZWUPAW-UHFFFAOYSA-N 0.000 description 1
- YSEUOPNOQRVVDY-OGEJUEGTSA-N (5-benzylfuran-3-yl)methyl (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 YSEUOPNOQRVVDY-OGEJUEGTSA-N 0.000 description 1
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 description 1
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 description 1
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 description 1
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 1
- PCKNFPQPGUWFHO-SXBRIOAWSA-N (Z)-flucycloxuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1)=CC=C1CO\N=C(C=1C=CC(Cl)=CC=1)\C1CC1 PCKNFPQPGUWFHO-SXBRIOAWSA-N 0.000 description 1
- CKPCAYZTYMHQEX-NBVRZTHBSA-N (e)-1-(2,4-dichlorophenyl)-n-methoxy-2-pyridin-3-ylethanimine Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=N/OC)/CC1=CC=CN=C1 CKPCAYZTYMHQEX-NBVRZTHBSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 description 1
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- RURQAJURNPMSSK-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3-{[2-(4-ethoxyphenyl)-3,3,3-trifluoropropoxy]methyl}benzene Chemical compound C1=CC(OCC)=CC=C1C(C(F)(F)F)COCC1=CC=CC(OC=2C=CC(Cl)=CC=2)=C1 RURQAJURNPMSSK-UHFFFAOYSA-N 0.000 description 1
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 description 1
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 description 1
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- MGNFYQILYYYUBS-UHFFFAOYSA-N 1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1CCCCC1 MGNFYQILYYYUBS-UHFFFAOYSA-N 0.000 description 1
- DELJNDWGTWHHFA-UHFFFAOYSA-N 1-azaniumylpropyl(hydroxy)phosphinate Chemical compound CCC(N)P(O)(O)=O DELJNDWGTWHHFA-UHFFFAOYSA-N 0.000 description 1
- YIKWKLYQRFRGPM-UHFFFAOYSA-N 1-dodecylguanidine acetate Chemical compound CC(O)=O.CCCCCCCCCCCCN=C(N)N YIKWKLYQRFRGPM-UHFFFAOYSA-N 0.000 description 1
- LIIBSISAILMKHT-UHFFFAOYSA-N 1-fluorobut-1-en-1-ol Chemical compound CCC=C(O)F LIIBSISAILMKHT-UHFFFAOYSA-N 0.000 description 1
- WFOIWBGKCSYBJN-UHFFFAOYSA-N 1-fluorobut-1-ene Chemical class CCC=CF WFOIWBGKCSYBJN-UHFFFAOYSA-N 0.000 description 1
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 description 1
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 description 1
- BCPFWSWROVXGQA-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)guanidine Chemical compound CC(C)(C)CC(C)(C)N=C(N)N BCPFWSWROVXGQA-UHFFFAOYSA-N 0.000 description 1
- HZJKXKUJVSEEFU-UHFFFAOYSA-N 2-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitrile Chemical compound C=1C=C(Cl)C=CC=1C(CCCC)(C#N)CN1C=NC=N1 HZJKXKUJVSEEFU-UHFFFAOYSA-N 0.000 description 1
- XJLITJHUQRBWPN-UHFFFAOYSA-N 2-acetamidoacetic acid;4-[2-(4-carbamimidoylphenyl)iminohydrazinyl]benzenecarboximidamide Chemical compound CC(=O)NCC(O)=O.C1=CC(C(=N)N)=CC=C1NN=NC1=CC=C(C(N)=N)C=C1 XJLITJHUQRBWPN-UHFFFAOYSA-N 0.000 description 1
- OWDLFBLNMPCXSD-UHFFFAOYSA-N 2-chloro-N-(2,6-dimethylphenyl)-N-(2-oxotetrahydrofuran-3-yl)acetamide Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)C1C(=O)OCC1 OWDLFBLNMPCXSD-UHFFFAOYSA-N 0.000 description 1
- QHOINBKBMJLHPY-UHFFFAOYSA-N 2-chloroethyl formate Chemical compound ClCCOC=O QHOINBKBMJLHPY-UHFFFAOYSA-N 0.000 description 1
- SMNDYUVBFMFKNZ-UHFFFAOYSA-N 2-furoic acid Chemical compound OC(=O)C1=CC=CO1 SMNDYUVBFMFKNZ-UHFFFAOYSA-N 0.000 description 1
- 229940044120 2-n-octyl-4-isothiazolin-3-one Drugs 0.000 description 1
- AVGVFDSUDIUXEU-UHFFFAOYSA-N 2-octyl-1,2-thiazolidin-3-one Chemical compound CCCCCCCCN1SCCC1=O AVGVFDSUDIUXEU-UHFFFAOYSA-N 0.000 description 1
- 229940061334 2-phenylphenol Drugs 0.000 description 1
- ZRDUSMYWDRPZRM-UHFFFAOYSA-N 2-sec-butyl-4,6-dinitrophenyl 3-methylbut-2-enoate Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)C=C(C)C ZRDUSMYWDRPZRM-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 description 1
- AUQAUAIUNJIIEP-UHFFFAOYSA-N 3,4,5-trimethylphenyl methylcarbamate Chemical compound CNC(=O)OC1=CC(C)=C(C)C(C)=C1 AUQAUAIUNJIIEP-UHFFFAOYSA-N 0.000 description 1
- BZGLBXYQOMFXAU-UHFFFAOYSA-N 3-(2-methylpiperidin-1-yl)propyl 3,4-dichlorobenzoate Chemical compound CC1CCCCN1CCCOC(=O)C1=CC=C(Cl)C(Cl)=C1 BZGLBXYQOMFXAU-UHFFFAOYSA-N 0.000 description 1
- FSCWZHGZWWDELK-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione Chemical compound O=C1C(C)(C=C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FSCWZHGZWWDELK-UHFFFAOYSA-N 0.000 description 1
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- NMWKWBPNKPGATC-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-benzofuran-1(3H)-one Chemical compound ClC1=C(Cl)C(Cl)=C2COC(=O)C2=C1Cl NMWKWBPNKPGATC-UHFFFAOYSA-N 0.000 description 1
- RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 description 1
- GQCQMFYIFUDARF-UHFFFAOYSA-N 4-bromo-1,1,2-trifluorobut-1-ene Chemical compound FC(F)=C(F)CCBr GQCQMFYIFUDARF-UHFFFAOYSA-N 0.000 description 1
- SBUKOHLFHYSZNG-UHFFFAOYSA-N 4-dodecyl-2,6-dimethylmorpholine Chemical compound CCCCCCCCCCCCN1CC(C)OC(C)C1 SBUKOHLFHYSZNG-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 241001609368 Acamptopappus Species 0.000 description 1
- 241000934064 Acarus siro Species 0.000 description 1
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 1
- 239000005652 Acrinathrin Substances 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000238679 Amblyomma Species 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 241000256186 Anopheles <genus> Species 0.000 description 1
- 241001427556 Anoplura Species 0.000 description 1
- 241000272814 Anser sp. Species 0.000 description 1
- 241000294569 Aphelenchoides Species 0.000 description 1
- 235000003276 Apios tuberosa Nutrition 0.000 description 1
- 244000176051 Apios tuberosa Species 0.000 description 1
- 241000239223 Arachnida Species 0.000 description 1
- 241001480748 Argas Species 0.000 description 1
- 241000238888 Argasidae Species 0.000 description 1
- 241000722809 Armadillidium vulgare Species 0.000 description 1
- 235000011330 Armoracia rusticana Nutrition 0.000 description 1
- 240000003291 Armoracia rusticana Species 0.000 description 1
- 241000238708 Astigmata Species 0.000 description 1
- 241001174347 Atomaria Species 0.000 description 1
- 239000005878 Azadirachtin Substances 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 239000005734 Benalaxyl Substances 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 239000005884 Beta-Cyfluthrin Substances 0.000 description 1
- 239000005874 Bifenthrin Substances 0.000 description 1
- 241001573716 Blaniulus guttulatus Species 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- 241000982105 Brevicoryne brassicae Species 0.000 description 1
- NYQDCVLCJXRDSK-UHFFFAOYSA-N Bromofos Chemical compound COP(=S)(OC)OC1=CC(Cl)=C(Br)C=C1Cl NYQDCVLCJXRDSK-UHFFFAOYSA-N 0.000 description 1
- 239000005741 Bromuconazole Substances 0.000 description 1
- 241000398201 Bryobia praetiosa Species 0.000 description 1
- MYTVVMGUDBRCDJ-UHFFFAOYSA-N Bufencarb Chemical compound CCCC(C)C1=CC=CC(OC(=O)NC)=C1.CCC(CC)C1=CC=CC(OC(=O)NC)=C1 MYTVVMGUDBRCDJ-UHFFFAOYSA-N 0.000 description 1
- 239000005742 Bupirimate Substances 0.000 description 1
- 239000005885 Buprofezin Substances 0.000 description 1
- ZZVVDIVWGXTDRQ-BSYVCWPDSA-N Buthiobate Chemical compound C=1C=CN=CC=1\N=C(/SCCCC)SCC1=CC=C(C(C)(C)C)C=C1 ZZVVDIVWGXTDRQ-BSYVCWPDSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000257160 Calliphora Species 0.000 description 1
- 241000333978 Caloglyphus Species 0.000 description 1
- 241000282836 Camelus dromedarius Species 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEDTXTNSFWUXGQ-UHFFFAOYSA-N Carbophenothion Chemical compound CCOP(=S)(OCC)SCSC1=CC=C(Cl)C=C1 VEDTXTNSFWUXGQ-UHFFFAOYSA-N 0.000 description 1
- 239000005746 Carboxin Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 241000700199 Cavia porcellus Species 0.000 description 1
- 241000255580 Ceratitis <genus> Species 0.000 description 1
- 241001098608 Ceratophyllus Species 0.000 description 1
- 241000282693 Cercopithecidae Species 0.000 description 1
- 241000040710 Chela Species 0.000 description 1
- 241000931705 Cicada Species 0.000 description 1
- 241001414836 Cimex Species 0.000 description 1
- 241001327638 Cimex lectularius Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 239000005654 Clofentezine Substances 0.000 description 1
- 241001465977 Coccoidea Species 0.000 description 1
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 1
- 239000005750 Copper hydroxide Substances 0.000 description 1
- 239000005752 Copper oxychloride Substances 0.000 description 1
- 241001509962 Coptotermes formosanus Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000699800 Cricetinae Species 0.000 description 1
- 241001635274 Cydia pomonella Species 0.000 description 1
- 239000005756 Cymoxanil Substances 0.000 description 1
- KRZUZYJEQBXUIN-UHFFFAOYSA-N Cyprofuram Chemical compound ClC1=CC=CC(N(C2C(OCC2)=O)C(=O)C2CC2)=C1 KRZUZYJEQBXUIN-UHFFFAOYSA-N 0.000 description 1
- 239000005891 Cyromazine Substances 0.000 description 1
- 241000592374 Daktulosphaira vitifoliae Species 0.000 description 1
- 241001128004 Demodex Species 0.000 description 1
- 241001523681 Dendrobium Species 0.000 description 1
- 241001481694 Dermanyssus Species 0.000 description 1
- 241001481695 Dermanyssus gallinae Species 0.000 description 1
- 241000202828 Dermatobia hominis Species 0.000 description 1
- BWLUMTFWVZZZND-UHFFFAOYSA-N Dibenzylamine Chemical compound C=1C=CC=CC=1CNCC1=CC=CC=C1 BWLUMTFWVZZZND-UHFFFAOYSA-N 0.000 description 1
- WGOWCPGHOCIHBW-UHFFFAOYSA-N Dichlofenthion Chemical compound CCOP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl WGOWCPGHOCIHBW-UHFFFAOYSA-N 0.000 description 1
- 239000005759 Diethofencarb Substances 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- 239000005760 Difenoconazole Substances 0.000 description 1
- 239000005893 Diflubenzuron Substances 0.000 description 1
- 239000005761 Dimethomorph Substances 0.000 description 1
- 241001399709 Dinoderus minutus Species 0.000 description 1
- VBKKVDGJXVOLNE-UHFFFAOYSA-N Dioxation Chemical compound CCOP(=S)(OCC)SC1OCCOC1SP(=S)(OCC)OCC VBKKVDGJXVOLNE-UHFFFAOYSA-N 0.000 description 1
- MTBZIGHNGSTDJV-UHFFFAOYSA-N Ditalimfos Chemical compound C1=CC=C2C(=O)N(P(=S)(OCC)OCC)C(=O)C2=C1 MTBZIGHNGSTDJV-UHFFFAOYSA-N 0.000 description 1
- 241000399949 Ditylenchus dipsaci Species 0.000 description 1
- 239000005766 Dodine Substances 0.000 description 1
- OOTHTARUZHONSW-LCYFTJDESA-N Drazoxolon Chemical compound CC1=NOC(=O)\C1=N/NC1=CC=CC=C1Cl OOTHTARUZHONSW-LCYFTJDESA-N 0.000 description 1
- 101001010782 Drosophila melanogaster Fez family zinc finger protein erm Proteins 0.000 description 1
- 241001425472 Dysdercus cingulatus Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000005894 Emamectin Substances 0.000 description 1
- 241000086608 Empoasca vitis Species 0.000 description 1
- 241000122098 Ephestia kuehniella Species 0.000 description 1
- 241001301805 Epilachna Species 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 241000283073 Equus caballus Species 0.000 description 1
- 241000917171 Eriosomatinae Species 0.000 description 1
- 239000005895 Esfenvalerate Substances 0.000 description 1
- 239000005961 Ethoprophos Substances 0.000 description 1
- 239000005769 Etridiazole Substances 0.000 description 1
- FGIWFCGDPUIBEZ-UHFFFAOYSA-N Etrimfos Chemical compound CCOC1=CC(OP(=S)(OC)OC)=NC(CC)=N1 FGIWFCGDPUIBEZ-UHFFFAOYSA-N 0.000 description 1
- 244000004281 Eucalyptus maculata Species 0.000 description 1
- 241000208368 Euonymus alatus Species 0.000 description 1
- 241000060469 Eupoecilia ambiguella Species 0.000 description 1
- 241000371383 Fannia Species 0.000 description 1
- 241000958182 Fannia scalaris Species 0.000 description 1
- 239000005958 Fenamiphos (aka phenamiphos) Substances 0.000 description 1
- 239000005656 Fenazaquin Substances 0.000 description 1
- 239000005775 Fenbuconazole Substances 0.000 description 1
- AYBALPYBYZFKDS-OLZOCXBDSA-N Fenitropan Chemical compound CC(=O)OC[C@@H]([N+]([O-])=O)[C@@H](OC(C)=O)C1=CC=CC=C1 AYBALPYBYZFKDS-OLZOCXBDSA-N 0.000 description 1
- HMIBKHHNXANVHR-UHFFFAOYSA-N Fenothiocarb Chemical compound CN(C)C(=O)SCCCCOC1=CC=CC=C1 HMIBKHHNXANVHR-UHFFFAOYSA-N 0.000 description 1
- 239000005898 Fenoxycarb Substances 0.000 description 1
- 239000005777 Fenpropidin Substances 0.000 description 1
- 239000005778 Fenpropimorph Substances 0.000 description 1
- 239000005657 Fenpyroximate Substances 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- 239000005781 Fludioxonil Substances 0.000 description 1
- 239000005785 Fluquinconazole Substances 0.000 description 1
- 239000005786 Flutolanil Substances 0.000 description 1
- 239000005787 Flutriafol Substances 0.000 description 1
- 241000720914 Forficula auricularia Species 0.000 description 1
- 239000005959 Fosthiazate Substances 0.000 description 1
- 239000005791 Fuberidazole Substances 0.000 description 1
- QTDRLOKFLJJHTG-UHFFFAOYSA-N Furmecyclox Chemical compound C1=C(C)OC(C)=C1C(=O)N(OC)C1CCCCC1 QTDRLOKFLJJHTG-UHFFFAOYSA-N 0.000 description 1
- 241000255896 Galleria mellonella Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 241001660203 Gasterophilus Species 0.000 description 1
- 241001442498 Globodera Species 0.000 description 1
- 241000257324 Glossina <genus> Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 241000241125 Gryllotalpa gryllotalpa Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241001480796 Haemaphysalis Species 0.000 description 1
- 241000257232 Haematobia irritans Species 0.000 description 1
- 241000239389 Heterobostrychus brunneus Species 0.000 description 1
- 241000697035 Heteropriacanthus cruentatus Species 0.000 description 1
- 239000005661 Hexythiazox Substances 0.000 description 1
- 241001480803 Hyalomma Species 0.000 description 1
- 241001251909 Hyalopterus pruni Species 0.000 description 1
- 241000561960 Hybomitra Species 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 241000238729 Hydrotaea Species 0.000 description 1
- 241000832180 Hylotrupes bajulus Species 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 239000005794 Hymexazol Substances 0.000 description 1
- 241001590577 Hypodectes Species 0.000 description 1
- 241000257176 Hypoderma <fly> Species 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 239000005867 Iprodione Substances 0.000 description 1
- 241001467800 Knemidokoptes Species 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 241001631692 Lasiocampa quercus Species 0.000 description 1
- 241000238866 Latrodectus mactans Species 0.000 description 1
- 241000270322 Lepidosauria Species 0.000 description 1
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 241000692237 Lipoptena Species 0.000 description 1
- 241000012186 Litura Species 0.000 description 1
- 241000254025 Locusta migratoria migratorioides Species 0.000 description 1
- 241001220360 Longidorus Species 0.000 description 1
- 241000920471 Lucilia caesar Species 0.000 description 1
- 239000005912 Lufenuron Substances 0.000 description 1
- 241000255134 Lutzomyia <genus> Species 0.000 description 1
- 241001043195 Lyctus brunneus Species 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 241000255685 Malacosoma neustria Species 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 240000004658 Medicago sativa Species 0.000 description 1
- 235000017587 Medicago sativa ssp. sativa Nutrition 0.000 description 1
- 240000000233 Melia azedarach Species 0.000 description 1
- 241001143352 Meloidogyne Species 0.000 description 1
- 241000771995 Melophagus Species 0.000 description 1
- 239000005805 Mepanipyrim Substances 0.000 description 1
- 241001481698 Mesostigmata Species 0.000 description 1
- 239000005807 Metalaxyl Substances 0.000 description 1
- NTAHCMPOMKHKEU-AATRIKPKSA-N Methacrifos Chemical compound COC(=O)C(\C)=C\OP(=S)(OC)OC NTAHCMPOMKHKEU-AATRIKPKSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 239000005916 Methomyl Substances 0.000 description 1
- 239000005918 Milbemectin Substances 0.000 description 1
- 241000656898 Minthea rugicollis Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 241000952627 Monomorium pharaonis Species 0.000 description 1
- 241001351098 Morellia Species 0.000 description 1
- 240000002393 Murraya koenigii Species 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 241000257229 Musca <genus> Species 0.000 description 1
- 241000257159 Musca domestica Species 0.000 description 1
- 239000005811 Myclobutanil Substances 0.000 description 1
- 241001373727 Myobia Species 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 241000406465 Neodiprion Species 0.000 description 1
- 241000359016 Nephotettix Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 241001385056 Niptus hololeucus Species 0.000 description 1
- VJAWBEFMCIINFU-UHFFFAOYSA-N Nitrothal-isopropyl Chemical compound CC(C)OC(=O)C1=CC(C(=O)OC(C)C)=CC([N+]([O-])=O)=C1 VJAWBEFMCIINFU-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 241000562097 Notoedres Species 0.000 description 1
- 241000238633 Odonata Species 0.000 description 1
- 241000257191 Oestridae Species 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 241000384103 Oniscus asellus Species 0.000 description 1
- 241001491877 Operophtera brumata Species 0.000 description 1
- 241000168255 Opiliones Species 0.000 description 1
- 241000233855 Orchidaceae Species 0.000 description 1
- 241000238887 Ornithodoros Species 0.000 description 1
- 241000238814 Orthoptera Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 241000131101 Oryzaephilus surinamensis Species 0.000 description 1
- 241001147398 Ostrinia nubilalis Species 0.000 description 1
- 239000005950 Oxamyl Substances 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 description 1
- JAYZFNIOOYPIAH-UHFFFAOYSA-N Oxydeprofos Chemical compound CCS(=O)CC(C)SP(=O)(OC)OC JAYZFNIOOYPIAH-UHFFFAOYSA-N 0.000 description 1
- 235000003283 Pachira macrocarpa Nutrition 0.000 description 1
- 241000919536 Panstrongylus Species 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 241000721451 Pectinophora gossypiella Species 0.000 description 1
- 241000517306 Pediculus humanus corporis Species 0.000 description 1
- 239000005813 Penconazole Substances 0.000 description 1
- 239000005814 Pencycuron Substances 0.000 description 1
- 241000238675 Periplaneta americana Species 0.000 description 1
- 241001608568 Phaedon Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 241001432757 Philipomyia Species 0.000 description 1
- 241000932963 Philopteridae Species 0.000 description 1
- 241001401863 Phorodon Species 0.000 description 1
- HEMINMLPKZELPP-UHFFFAOYSA-N Phosdiphen Chemical compound C=1C=C(Cl)C=C(Cl)C=1OP(=O)(OCC)OC1=CC=C(Cl)C=C1Cl HEMINMLPKZELPP-UHFFFAOYSA-N 0.000 description 1
- 241001396980 Phytonemus pallidus Species 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000908127 Porcellio scaber Species 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 241000193943 Pratylenchus Species 0.000 description 1
- 241001384632 Priobium carpini Species 0.000 description 1
- 239000005820 Prochloraz Substances 0.000 description 1
- DTAPQAJKAFRNJB-UHFFFAOYSA-N Promecarb Chemical compound CNC(=O)OC1=CC(C)=CC(C(C)C)=C1 DTAPQAJKAFRNJB-UHFFFAOYSA-N 0.000 description 1
- 239000005821 Propamocarb Substances 0.000 description 1
- 239000005823 Propineb Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241000238705 Prostigmata Species 0.000 description 1
- 241001016411 Psorergates Species 0.000 description 1
- 241001649229 Psoroptes Species 0.000 description 1
- 241001534486 Pterolichus Species 0.000 description 1
- 241000517309 Pthirus Species 0.000 description 1
- 241000396245 Ptilinus pectinicornis Species 0.000 description 1
- 241000411574 Ptinus fur Species 0.000 description 1
- 241000231139 Pyricularia Species 0.000 description 1
- 239000005663 Pyridaben Substances 0.000 description 1
- 239000005828 Pyrimethanil Substances 0.000 description 1
- 239000005927 Pyriproxyfen Substances 0.000 description 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 1
- 241001480055 Quercus mongolica Species 0.000 description 1
- 241000201375 Radopholus similis Species 0.000 description 1
- 241001408411 Raillietia Species 0.000 description 1
- 241000590363 Reticulitermes lucifugus Species 0.000 description 1
- 241000590379 Reticulitermes santonensis Species 0.000 description 1
- 241001481703 Rhipicephalus <genus> Species 0.000 description 1
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- 241000722251 Rhodnius Species 0.000 description 1
- 241001510236 Rhyparobia maderae Species 0.000 description 1
- 241000318997 Rhyzopertha dominica Species 0.000 description 1
- 241001495449 Robinia pseudoacacia Species 0.000 description 1
- 241001093501 Rutaceae Species 0.000 description 1
- 241000316887 Saissetia oleae Species 0.000 description 1
- OUNSASXJZHBGAI-UHFFFAOYSA-N Salithion Chemical compound C1=CC=C2OP(OC)(=S)OCC2=C1 OUNSASXJZHBGAI-UHFFFAOYSA-N 0.000 description 1
- 241000124033 Salix Species 0.000 description 1
- 241000257190 Sarcophaga <genus> Species 0.000 description 1
- 241000509416 Sarcoptes Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 241000253973 Schistocerca gregaria Species 0.000 description 1
- 241000522594 Scorpio maurus Species 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 241000254179 Sitophilus granarius Species 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 241000256248 Spodoptera Species 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241000256251 Spodoptera frugiperda Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241001513492 Sternostoma Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 241000282898 Sus scrofa Species 0.000 description 1
- 240000005572 Syzygium cordatum Species 0.000 description 1
- 235000006650 Syzygium cordatum Nutrition 0.000 description 1
- 240000004460 Tanacetum coccineum Species 0.000 description 1
- 239000005658 Tebufenpyrad Substances 0.000 description 1
- 239000005938 Teflubenzuron Substances 0.000 description 1
- 239000005939 Tefluthrin Substances 0.000 description 1
- 241000254109 Tenebrio molitor Species 0.000 description 1
- 241000255588 Tephritidae Species 0.000 description 1
- 241000270708 Testudinidae Species 0.000 description 1
- 239000005840 Tetraconazole Substances 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- GNOOAFGERMHQJE-UHFFFAOYSA-N Thicyofen Chemical compound CCS(=O)C=1SC(C#N)=C(Cl)C=1C#N GNOOAFGERMHQJE-UHFFFAOYSA-N 0.000 description 1
- IRVDMKJLOCGUBJ-UHFFFAOYSA-N Thionazin Chemical compound CCOP(=S)(OCC)OC1=CN=CC=N1 IRVDMKJLOCGUBJ-UHFFFAOYSA-N 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- 239000005843 Thiram Substances 0.000 description 1
- 241000339374 Thrips tabaci Species 0.000 description 1
- OTLLEIBWKHEHGU-UHFFFAOYSA-N Thuringiensin Natural products C1=NC=2C(N)=NC=NC=2N1C(C(C1O)O)OC1COC1C(CO)OC(OC(C(O)C(OP(O)(O)=O)C(O)C(O)=O)C(O)=O)C(O)C1O OTLLEIBWKHEHGU-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 235000014364 Trapa natans Nutrition 0.000 description 1
- 240000001085 Trapa natans Species 0.000 description 1
- 239000005846 Triadimenol Substances 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 241001414833 Triatoma Species 0.000 description 1
- 239000005847 Triazoxide Substances 0.000 description 1
- NHTFLYKPEGXOAN-UHFFFAOYSA-N Trichlamide Chemical compound CCCCOC(C(Cl)(Cl)Cl)NC(=O)C1=CC=CC=C1O NHTFLYKPEGXOAN-UHFFFAOYSA-N 0.000 description 1
- 241001220308 Trichodorus Species 0.000 description 1
- 241000255993 Trichoplusia ni Species 0.000 description 1
- 239000005858 Triflumizole Substances 0.000 description 1
- 239000005859 Triticonazole Substances 0.000 description 1
- 241000215579 Trogoxylon Species 0.000 description 1
- 241000330972 Trombidium Species 0.000 description 1
- 241001267621 Tylenchulus semipenetrans Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 241000061203 Werneckiella Species 0.000 description 1
- 241001471596 Wohlfahrtia magnifica Species 0.000 description 1
- CVQODEWAPZVVBU-UHFFFAOYSA-N XMC Chemical compound CNC(=O)OC1=CC(C)=CC(C)=C1 CVQODEWAPZVVBU-UHFFFAOYSA-N 0.000 description 1
- 235000013447 Xanthosoma atrovirens Nutrition 0.000 description 1
- 240000001781 Xanthosoma sagittifolium Species 0.000 description 1
- 241000201423 Xiphinema Species 0.000 description 1
- 241000254234 Xyeloidea Species 0.000 description 1
- 241001466330 Yponomeuta malinellus Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000005870 Ziram Substances 0.000 description 1
- 240000008866 Ziziphus nummularia Species 0.000 description 1
- GBAWQJNHVWMTLU-RQJHMYQMSA-N [(1R,5S)-7-chloro-6-bicyclo[3.2.0]hepta-2,6-dienyl] dimethyl phosphate Chemical compound C1=CC[C@@H]2C(OP(=O)(OC)OC)=C(Cl)[C@@H]21 GBAWQJNHVWMTLU-RQJHMYQMSA-N 0.000 description 1
- QQODLKZGRKWIFG-RUTXASTPSA-N [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-RUTXASTPSA-N 0.000 description 1
- FZSVSABTBYGOQH-XFFZJAGNSA-N [(e)-(3,3-dimethyl-1-methylsulfanylbutan-2-ylidene)amino] n-methylcarbamate Chemical compound CNC(=O)O\N=C(C(C)(C)C)\CSC FZSVSABTBYGOQH-XFFZJAGNSA-N 0.000 description 1
- FSAVDKDHPDSCTO-WQLSENKSSA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] diethyl phosphate Chemical compound CCOP(=O)(OCC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl FSAVDKDHPDSCTO-WQLSENKSSA-N 0.000 description 1
- QSGNQELHULIMSJ-POHAHGRESA-N [(z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl] dimethyl phosphate Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC=C(Cl)C=C1Cl QSGNQELHULIMSJ-POHAHGRESA-N 0.000 description 1
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 1
- KIPLYOUQVMMOHB-MXWBXKMOSA-L [Ca++].CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O.CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O Chemical compound [Ca++].CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O.CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O KIPLYOUQVMMOHB-MXWBXKMOSA-L 0.000 description 1
- JNVCSEDACVAATK-UHFFFAOYSA-L [Ca+2].[S-]SSS[S-] Chemical compound [Ca+2].[S-]SSS[S-] JNVCSEDACVAATK-UHFFFAOYSA-L 0.000 description 1
- INISTDXBRIBGOC-CGAIIQECSA-N [cyano-(3-phenoxyphenyl)methyl] (2s)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate Chemical compound N([C@@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-CGAIIQECSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- YLFSVIMMRPNPFK-WEQBUNFVSA-N acrinathrin Chemical compound CC1(C)[C@@H](\C=C/C(=O)OC(C(F)(F)F)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YLFSVIMMRPNPFK-WEQBUNFVSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- GMAUQNJOSOMMHI-JXAWBTAJSA-N alanycarb Chemical compound CSC(\C)=N/OC(=O)N(C)SN(CCC(=O)OCC)CC1=CC=CC=C1 GMAUQNJOSOMMHI-JXAWBTAJSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- QGLZXHRNAYXIBU-WEVVVXLNSA-N aldicarb Chemical compound CNC(=O)O\N=C\C(C)(C)SC QGLZXHRNAYXIBU-WEVVVXLNSA-N 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229960002587 amitraz Drugs 0.000 description 1
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- AVKUERGKIZMTKX-NJBDSQKTSA-N ampicillin Chemical compound C1([C@@H](N)C(=O)N[C@H]2[C@H]3SC([C@@H](N3C2=O)C(O)=O)(C)C)=CC=CC=C1 AVKUERGKIZMTKX-NJBDSQKTSA-N 0.000 description 1
- IMHBYKMAHXWHRP-UHFFFAOYSA-N anilazine Chemical compound ClC1=CC=CC=C1NC1=NC(Cl)=NC(Cl)=N1 IMHBYKMAHXWHRP-UHFFFAOYSA-N 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- VEHPJKVTJQSSKL-UHFFFAOYSA-N azadirachtin Natural products O1C2(C)C(C3(C=COC3O3)O)CC3C21C1(C)C(O)C(OCC2(OC(C)=O)C(CC3OC(=O)C(C)=CC)OC(C)=O)C2C32COC(C(=O)OC)(O)C12 VEHPJKVTJQSSKL-UHFFFAOYSA-N 0.000 description 1
- FTNJWQUOZFUQQJ-NDAWSKJSSA-N azadirachtin A Chemical compound C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C\C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-NDAWSKJSSA-N 0.000 description 1
- FTNJWQUOZFUQQJ-IRYYUVNJSA-N azadirachtin A Natural products C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C/C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-IRYYUVNJSA-N 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- ONHBDDJJTDTLIR-UHFFFAOYSA-N azocyclotin Chemical compound C1CCCCC1[Sn](N1N=CN=C1)(C1CCCCC1)C1CCCCC1 ONHBDDJJTDTLIR-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- FYZBOYWSHKHDMT-UHFFFAOYSA-N benfuracarb Chemical compound CCOC(=O)CCN(C(C)C)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 FYZBOYWSHKHDMT-UHFFFAOYSA-N 0.000 description 1
- LJOZMWRYMKECFF-UHFFFAOYSA-N benodanil Chemical compound IC1=CC=CC=C1C(=O)NC1=CC=CC=C1 LJOZMWRYMKECFF-UHFFFAOYSA-N 0.000 description 1
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 1
- YFXPPSKYMBTNAV-UHFFFAOYSA-N bensultap Chemical compound C=1C=CC=CC=1S(=O)(=O)SCC(N(C)C)CSS(=O)(=O)C1=CC=CC=C1 YFXPPSKYMBTNAV-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- OIPMQULDKWSNGX-UHFFFAOYSA-N bis[[ethoxy(oxo)phosphaniumyl]oxy]alumanyloxy-ethoxy-oxophosphanium Chemical compound [Al+3].CCO[P+]([O-])=O.CCO[P+]([O-])=O.CCO[P+]([O-])=O OIPMQULDKWSNGX-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 229950007134 bromofos Drugs 0.000 description 1
- HJJVPARKXDDIQD-UHFFFAOYSA-N bromuconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCC(Br)C1 HJJVPARKXDDIQD-UHFFFAOYSA-N 0.000 description 1
- 235000021329 brown rice Nutrition 0.000 description 1
- DSKJPMWIHSOYEA-UHFFFAOYSA-N bupirimate Chemical compound CCCCC1=C(C)N=C(NCC)N=C1OS(=O)(=O)N(C)C DSKJPMWIHSOYEA-UHFFFAOYSA-N 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- SFNPDDSJBGRXLW-UITAMQMPSA-N butocarboxim Chemical compound CNC(=O)O\N=C(\C)C(C)SC SFNPDDSJBGRXLW-UITAMQMPSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- GYSSRZJIHXQEHQ-UHFFFAOYSA-N carboxin Chemical compound S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 GYSSRZJIHXQEHQ-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- XFDJMIHUAHSGKG-UHFFFAOYSA-N chlorethoxyfos Chemical compound CCOP(=S)(OCC)OC(Cl)C(Cl)(Cl)Cl XFDJMIHUAHSGKG-UHFFFAOYSA-N 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- QGTYWWGEWOBMAK-UHFFFAOYSA-N chlormephos Chemical compound CCOP(=S)(OCC)SCCl QGTYWWGEWOBMAK-UHFFFAOYSA-N 0.000 description 1
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical compound OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- PFIADAMVCJPXSF-UHFFFAOYSA-N chloroneb Chemical compound COC1=CC(Cl)=C(OC)C=C1Cl PFIADAMVCJPXSF-UHFFFAOYSA-N 0.000 description 1
- LFHISGNCFUNFFM-UHFFFAOYSA-N chloropicrin Chemical compound [O-][N+](=O)C(Cl)(Cl)Cl LFHISGNCFUNFFM-UHFFFAOYSA-N 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- HRBKVYFZANMGRE-UHFFFAOYSA-N chlorpyrifos-methyl Chemical compound COP(=S)(OC)OC1=NC(Cl)=C(Cl)C=C1Cl HRBKVYFZANMGRE-UHFFFAOYSA-N 0.000 description 1
- UXADOQPNKNTIHB-UHFFFAOYSA-N clofentezine Chemical compound ClC1=CC=CC=C1C1=NN=C(C=2C(=CC=CC=2)Cl)N=N1 UXADOQPNKNTIHB-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910001956 copper hydroxide Inorganic materials 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- JOXAXMBQVHFGQT-UHFFFAOYSA-J copper;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Cu+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S JOXAXMBQVHFGQT-UHFFFAOYSA-J 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- SCKHCCSZFPSHGR-UHFFFAOYSA-N cyanophos Chemical compound COP(=S)(OC)OC1=CC=C(C#N)C=C1 SCKHCCSZFPSHGR-UHFFFAOYSA-N 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 1
- LSFUGNKKPMBOMG-UHFFFAOYSA-N cycloprothrin Chemical compound ClC1(Cl)CC1(C=1C=CC=CC=1)C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 LSFUGNKKPMBOMG-UHFFFAOYSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- WCMMILVIRZAPLE-UHFFFAOYSA-M cyhexatin Chemical compound C1CCCCC1[Sn](C1CCCCC1)(O)C1CCCCC1 WCMMILVIRZAPLE-UHFFFAOYSA-M 0.000 description 1
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 1
- LVQDKIWDGQRHTE-UHFFFAOYSA-N cyromazine Chemical compound NC1=NC(N)=NC(NC2CC2)=N1 LVQDKIWDGQRHTE-UHFFFAOYSA-N 0.000 description 1
- 229950000775 cyromazine Drugs 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 1
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- WURGXGVFSMYFCG-UHFFFAOYSA-N dichlofluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=CC=C1 WURGXGVFSMYFCG-UHFFFAOYSA-N 0.000 description 1
- BIXZHMJUSMUDOQ-UHFFFAOYSA-N dichloran Chemical compound NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl BIXZHMJUSMUDOQ-UHFFFAOYSA-N 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- UWQMKVBQKFHLCE-UHFFFAOYSA-N diclomezine Chemical compound C1=C(Cl)C(C)=C(Cl)C=C1C1=NNC(=O)C=C1 UWQMKVBQKFHLCE-UHFFFAOYSA-N 0.000 description 1
- 229940004812 dicloran Drugs 0.000 description 1
- VEENJGZXVHKXNB-VOTSOKGWSA-N dicrotophos Chemical compound COP(=O)(OC)O\C(C)=C\C(=O)N(C)C VEENJGZXVHKXNB-VOTSOKGWSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- LNJNFVJKDJYTEU-UHFFFAOYSA-N diethofencarb Chemical compound CCOC1=CC=C(NC(=O)OC(C)C)C=C1OCC LNJNFVJKDJYTEU-UHFFFAOYSA-N 0.000 description 1
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- CJHXCRMKMMBYJQ-UHFFFAOYSA-N dimethirimol Chemical compound CCCCC1=C(C)NC(N(C)C)=NC1=O CJHXCRMKMMBYJQ-UHFFFAOYSA-N 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 description 1
- LBLSDWGRWPNYHR-UHFFFAOYSA-N diphenylmethanone;ethene Chemical compound C=C.C=1C=CC=CC=1C(=O)C1=CC=CC=C1 LBLSDWGRWPNYHR-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- ZHDBTKPXEJDTTQ-UHFFFAOYSA-N dipyrithione Chemical compound [O-][N+]1=CC=CC=C1SSC1=CC=CC=[N+]1[O-] ZHDBTKPXEJDTTQ-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- DOFZAZXDOSGAJZ-UHFFFAOYSA-N disulfoton Chemical compound CCOP(=S)(OCC)SCCSCC DOFZAZXDOSGAJZ-UHFFFAOYSA-N 0.000 description 1
- PYZSVQVRHDXQSL-UHFFFAOYSA-N dithianon Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O PYZSVQVRHDXQSL-UHFFFAOYSA-N 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- NYPJDWWKZLNGGM-RPWUZVMVSA-N esfenvalerate Chemical compound C=1C([C@@H](C#N)OC(=O)[C@@H](C(C)C)C=2C=CC(Cl)=CC=2)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-RPWUZVMVSA-N 0.000 description 1
- 230000012173 estrus Effects 0.000 description 1
- PQLFROTZSIMBKR-UHFFFAOYSA-N ethenyl carbonochloridate Chemical compound ClC(=O)OC=C PQLFROTZSIMBKR-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- HEZNVIYQEUHLNI-UHFFFAOYSA-N ethiofencarb Chemical compound CCSCC1=CC=CC=C1OC(=O)NC HEZNVIYQEUHLNI-UHFFFAOYSA-N 0.000 description 1
- VJYFKVYYMZPMAB-UHFFFAOYSA-N ethoprophos Chemical compound CCCSP(=O)(OCC)SCCC VJYFKVYYMZPMAB-UHFFFAOYSA-N 0.000 description 1
- IGUYEXXAGBDLLX-UHFFFAOYSA-N ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate Chemical compound O=C1C(C(=O)OCC)(C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 IGUYEXXAGBDLLX-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 description 1
- KQTVWCSONPJJPE-UHFFFAOYSA-N etridiazole Chemical compound CCOC1=NC(C(Cl)(Cl)Cl)=NS1 KQTVWCSONPJJPE-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- ZCJPOPBZHLUFHF-UHFFFAOYSA-N fenamiphos Chemical compound CCOP(=O)(NC(C)C)OC1=CC=C(SC)C(C)=C1 ZCJPOPBZHLUFHF-UHFFFAOYSA-N 0.000 description 1
- DMYHGDXADUDKCQ-UHFFFAOYSA-N fenazaquin Chemical compound C1=CC(C(C)(C)C)=CC=C1CCOC1=NC=NC2=CC=CC=C12 DMYHGDXADUDKCQ-UHFFFAOYSA-N 0.000 description 1
- JFSPBVWPKOEZCB-UHFFFAOYSA-N fenfuram Chemical compound O1C=CC(C(=O)NC=2C=CC=CC=2)=C1C JFSPBVWPKOEZCB-UHFFFAOYSA-N 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 description 1
- FKLFBQCQQYDUAM-UHFFFAOYSA-N fenpiclonil Chemical compound ClC1=CC=CC(C=2C(=CNC=2)C#N)=C1Cl FKLFBQCQQYDUAM-UHFFFAOYSA-N 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 description 1
- WDQNIWFZKXZFAY-UHFFFAOYSA-M fentin acetate Chemical compound CC([O-])=O.C1=CC=CC=C1[Sn+](C=1C=CC=CC=1)C1=CC=CC=C1 WDQNIWFZKXZFAY-UHFFFAOYSA-M 0.000 description 1
- BFWMWWXRWVJXSE-UHFFFAOYSA-M fentin hydroxide Chemical compound C=1C=CC=CC=1[Sn](C=1C=CC=CC=1)(O)C1=CC=CC=C1 BFWMWWXRWVJXSE-UHFFFAOYSA-M 0.000 description 1
- WHDGWKAJBYRJJL-UHFFFAOYSA-K ferbam Chemical compound [Fe+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S WHDGWKAJBYRJJL-UHFFFAOYSA-K 0.000 description 1
- GOWLARCWZRESHU-AQTBWJFISA-N ferimzone Chemical compound C=1C=CC=C(C)C=1C(/C)=N\NC1=NC(C)=CC(C)=N1 GOWLARCWZRESHU-AQTBWJFISA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- GBIHOLCMZGAKNG-CGAIIQECSA-N flucythrinate Chemical compound O=C([C@@H](C(C)C)C=1C=CC(OC(F)F)=CC=1)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 GBIHOLCMZGAKNG-CGAIIQECSA-N 0.000 description 1
- MUJOIMFVNIBMKC-UHFFFAOYSA-N fludioxonil Chemical compound C=12OC(F)(F)OC2=CC=CC=1C1=CNC=C1C#N MUJOIMFVNIBMKC-UHFFFAOYSA-N 0.000 description 1
- IPENDKRRWFURRE-UHFFFAOYSA-N fluoroimide Chemical compound C1=CC(F)=CC=C1N1C(=O)C(Cl)=C(Cl)C1=O IPENDKRRWFURRE-UHFFFAOYSA-N 0.000 description 1
- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 description 1
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
- KVGLBTYUCJYMND-UHFFFAOYSA-N fonofos Chemical compound CCOP(=S)(CC)SC1=CC=CC=C1 KVGLBTYUCJYMND-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- DUFVKSUJRWYZQP-UHFFFAOYSA-N fosthiazate Chemical compound CCC(C)SP(=O)(OCC)N1CCSC1=O DUFVKSUJRWYZQP-UHFFFAOYSA-N 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- ZEYJIQLVKGBLEM-UHFFFAOYSA-N fuberidazole Chemical compound C1=COC(C=2N=C3[CH]C=CC=C3N=2)=C1 ZEYJIQLVKGBLEM-UHFFFAOYSA-N 0.000 description 1
- HAWJXYBZNNRMNO-UHFFFAOYSA-N furathiocarb Chemical compound CCCCOC(=O)N(C)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 HAWJXYBZNNRMNO-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229950000289 guanoctine Drugs 0.000 description 1
- WIFXJBMOTMKRMM-UHFFFAOYSA-N halfenprox Chemical compound C=1C=C(OC(F)(F)Br)C=CC=1C(C)(C)COCC(C=1)=CC=CC=1OC1=CC=CC=C1 WIFXJBMOTMKRMM-UHFFFAOYSA-N 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- KGVPNLBXJKTABS-UHFFFAOYSA-N hymexazol Chemical compound CC1=CC(O)=NO1 KGVPNLBXJKTABS-UHFFFAOYSA-N 0.000 description 1
- KQSBZNJFKWOQQK-UHFFFAOYSA-N hystazarin Natural products O=C1C2=CC=CC=C2C(=O)C2=C1C=C(O)C(O)=C2 KQSBZNJFKWOQQK-UHFFFAOYSA-N 0.000 description 1
- AGKSTYPVMZODRV-UHFFFAOYSA-N imibenconazole Chemical compound C1=CC(Cl)=CC=C1CSC(CN1N=CN=C1)=NC1=CC=C(Cl)C=C1Cl AGKSTYPVMZODRV-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 125000003454 indenyl group Chemical class C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000010255 intramuscular injection Methods 0.000 description 1
- 239000007927 intramuscular injection Substances 0.000 description 1
- 238000010253 intravenous injection Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- HOQADATXFBOEGG-UHFFFAOYSA-N isofenphos Chemical compound CCOP(=S)(NC(C)C)OC1=CC=CC=C1C(=O)OC(C)C HOQADATXFBOEGG-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 description 1
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 description 1
- ZLTPDFXIESTBQG-UHFFFAOYSA-N isothiazole Chemical compound C=1C=NSC=1 ZLTPDFXIESTBQG-UHFFFAOYSA-N 0.000 description 1
- SDMSCIWHRZJSRN-UHFFFAOYSA-N isoxathion Chemical compound O1N=C(OP(=S)(OCC)OCC)C=C1C1=CC=CC=C1 SDMSCIWHRZJSRN-UHFFFAOYSA-N 0.000 description 1
- 229960002418 ivermectin Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229960000521 lufenuron Drugs 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- ATTFYOXEMHAYAX-UHFFFAOYSA-N magnesium nickel Chemical compound [Mg].[Ni] ATTFYOXEMHAYAX-UHFFFAOYSA-N 0.000 description 1
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 1
- 229920000940 maneb Polymers 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- KLGMSAOQDHLCOS-UHFFFAOYSA-N mecarbam Chemical compound CCOC(=O)N(C)C(=O)CSP(=S)(OCC)OCC KLGMSAOQDHLCOS-UHFFFAOYSA-N 0.000 description 1
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 description 1
- BCTQJXQXJVLSIG-UHFFFAOYSA-N mepronil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C)=C1 BCTQJXQXJVLSIG-UHFFFAOYSA-N 0.000 description 1
- GKKDCARASOJPNG-UHFFFAOYSA-N metaldehyde Chemical compound CC1OC(C)OC(C)OC(C)O1 GKKDCARASOJPNG-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 description 1
- ZWJNEYVWPYIKMB-UHFFFAOYSA-N methfuroxam Chemical compound CC1=C(C)OC(C)=C1C(=O)NC1=CC=CC=C1 ZWJNEYVWPYIKMB-UHFFFAOYSA-N 0.000 description 1
- MEBQXILRKZHVCX-UHFFFAOYSA-N methidathion Chemical compound COC1=NN(CSP(=S)(OC)OC)C(=O)S1 MEBQXILRKZHVCX-UHFFFAOYSA-N 0.000 description 1
- YFBPRJGDJKVWAH-UHFFFAOYSA-N methiocarb Chemical compound CNC(=O)OC1=CC(C)=C(SC)C(C)=C1 YFBPRJGDJKVWAH-UHFFFAOYSA-N 0.000 description 1
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 description 1
- GEPDYQSQVLXLEU-AATRIKPKSA-N methyl (e)-3-dimethoxyphosphoryloxybut-2-enoate Chemical compound COC(=O)\C=C(/C)OP(=O)(OC)OC GEPDYQSQVLXLEU-AATRIKPKSA-N 0.000 description 1
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 1
- CJPQIRJHIZUAQP-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)alaninate Chemical compound CC=1C=CC=C(C)C=1N(C(C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-UHFFFAOYSA-N 0.000 description 1
- CIEXPHRYOLIQQD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-2-furoylalaninate Chemical compound CC=1C=CC=C(C)C=1N(C(C)C(=O)OC)C(=O)C1=CC=CO1 CIEXPHRYOLIQQD-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- KQSSATDQUYCRGS-UHFFFAOYSA-N methyl glycinate Chemical compound COC(=O)CN KQSSATDQUYCRGS-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- ZLBGSRMUSVULIE-GSMJGMFJSA-N milbemycin A3 Chemical compound O1[C@H](C)[C@@H](C)CC[C@@]11O[C@H](C\C=C(C)\C[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 ZLBGSRMUSVULIE-GSMJGMFJSA-N 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical compound CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- YZBLFMPOMVTDJY-CBYMMZEQSA-N moxidectin Chemical compound O1[C@H](C(\C)=C\C(C)C)[C@@H](C)C(=N/OC)\C[C@@]11O[C@H](C\C=C(C)\C[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 YZBLFMPOMVTDJY-CBYMMZEQSA-N 0.000 description 1
- 229960004816 moxidectin Drugs 0.000 description 1
- 235000019508 mustard seed Nutrition 0.000 description 1
- BLCKKNLGFULNRC-UHFFFAOYSA-L n,n-dimethylcarbamodithioate;nickel(2+) Chemical compound [Ni+2].CN(C)C([S-])=S.CN(C)C([S-])=S BLCKKNLGFULNRC-UHFFFAOYSA-L 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- BUYMVQAILCEWRR-UHFFFAOYSA-N naled Chemical compound COP(=O)(OC)OC(Br)C(Cl)(Cl)Br BUYMVQAILCEWRR-UHFFFAOYSA-N 0.000 description 1
- NCXMLFZGDNKEPB-FFPOYIOWSA-N natamycin Chemical compound O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C[C@@H](C)OC(=O)/C=C/[C@H]2O[C@@H]2C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 NCXMLFZGDNKEPB-FFPOYIOWSA-N 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229940042880 natural phospholipid Drugs 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229940079888 nitenpyram Drugs 0.000 description 1
- DCUJJWWUNKIJPH-UHFFFAOYSA-N nitrapyrin Chemical compound ClC1=CC=CC(C(Cl)(Cl)Cl)=N1 DCUJJWWUNKIJPH-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- PZXOQEXFMJCDPG-UHFFFAOYSA-N omethoate Chemical compound CNC(=O)CSP(=O)(OC)OC PZXOQEXFMJCDPG-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- KZAUOCCYDRDERY-UHFFFAOYSA-N oxamyl Chemical compound CNC(=O)ON=C(SC)C(=O)N(C)C KZAUOCCYDRDERY-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- AMEKQAFGQBKLKX-UHFFFAOYSA-N oxycarboxin Chemical compound O=S1(=O)CCOC(C)=C1C(=O)NC1=CC=CC=C1 AMEKQAFGQBKLKX-UHFFFAOYSA-N 0.000 description 1
- PMCVMORKVPSKHZ-UHFFFAOYSA-N oxydemeton-methyl Chemical group CCS(=O)CCSP(=O)(OC)OC PMCVMORKVPSKHZ-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- OGYFATSSENRIKG-UHFFFAOYSA-N pencycuron Chemical compound C1=CC(Cl)=CC=C1CN(C(=O)NC=1C=CC=CC=1)C1CCCC1 OGYFATSSENRIKG-UHFFFAOYSA-N 0.000 description 1
- WBTYBAGIHOISOQ-UHFFFAOYSA-N pent-4-en-1-yl 2-[(2-furylmethyl)(imidazol-1-ylcarbonyl)amino]butanoate Chemical compound C1=CN=CN1C(=O)N(C(CC)C(=O)OCCCC=C)CC1=CC=CO1 WBTYBAGIHOISOQ-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- MOQRZWSWPNIGMP-UHFFFAOYSA-N pentyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCC MOQRZWSWPNIGMP-UHFFFAOYSA-N 0.000 description 1
- XAMUDJHXFNRLCY-UHFFFAOYSA-N phenthoate Chemical compound CCOC(=O)C(SP(=S)(OC)OC)C1=CC=CC=C1 XAMUDJHXFNRLCY-UHFFFAOYSA-N 0.000 description 1
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 1
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 1
- IOUNQDKNJZEDEP-UHFFFAOYSA-N phosalone Chemical compound C1=C(Cl)C=C2OC(=O)N(CSP(=S)(OCC)OCC)C2=C1 IOUNQDKNJZEDEP-UHFFFAOYSA-N 0.000 description 1
- LMNZTLDVJIUSHT-UHFFFAOYSA-N phosmet Chemical compound C1=CC=C2C(=O)N(CSP(=S)(OC)OC)C(=O)C2=C1 LMNZTLDVJIUSHT-UHFFFAOYSA-N 0.000 description 1
- RGCLLPNLLBQHPF-HJWRWDBZSA-N phosphamidon Chemical compound CCN(CC)C(=O)C(\Cl)=C(/C)OP(=O)(OC)OC RGCLLPNLLBQHPF-HJWRWDBZSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920006215 polyvinyl ketone Polymers 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- JCBJVAJGLKENNC-UHFFFAOYSA-M potassium ethyl xanthate Chemical compound [K+].CCOC([S-])=S JCBJVAJGLKENNC-UHFFFAOYSA-M 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 description 1
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical compound CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 description 1
- PWYIUEFFPNVCMW-UHFFFAOYSA-N propaphos Chemical compound CCCOP(=O)(OCCC)OC1=CC=C(SC)C=C1 PWYIUEFFPNVCMW-UHFFFAOYSA-N 0.000 description 1
- 230000000069 prophylactic effect Effects 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 229940015367 pyrethrum Drugs 0.000 description 1
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 1
- CXJSOEPQXUCJSA-UHFFFAOYSA-N pyridaphenthion Chemical compound N1=C(OP(=S)(OCC)OCC)C=CC(=O)N1C1=CC=CC=C1 CXJSOEPQXUCJSA-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 1
- ITKAIUGKVKDENI-UHFFFAOYSA-N pyrimidifen Chemical compound CC1=C(C)C(CCOCC)=CC=C1OCCNC1=NC=NC(CC)=C1Cl ITKAIUGKVKDENI-UHFFFAOYSA-N 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 229960003811 pyrithione disulfide Drugs 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- JYQUHIFYBATCCY-UHFFFAOYSA-N quinalphos Chemical compound C1=CC=CC2=NC(OP(=S)(OCC)OCC)=CN=C21 JYQUHIFYBATCCY-UHFFFAOYSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- FBQQHUGEACOBDN-UHFFFAOYSA-N quinomethionate Chemical compound N1=C2SC(=O)SC2=NC2=CC(C)=CC=C21 FBQQHUGEACOBDN-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000004007 reversed phase HPLC Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 235000009165 saligot Nutrition 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- HPYNBECUCCGGPA-UHFFFAOYSA-N silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 description 1
- 238000010898 silica gel chromatography Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- QTENRWWVYAAPBI-YCRXJPFRSA-N streptomycin sulfate Chemical compound OS(O)(=O)=O.OS(O)(=O)=O.OS(O)(=O)=O.CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](N=C(N)N)[C@H](O)[C@@H](N=C(N)N)[C@H](O)[C@H]1O.CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](N=C(N)N)[C@H](O)[C@@H](N=C(N)N)[C@H](O)[C@H]1O QTENRWWVYAAPBI-YCRXJPFRSA-N 0.000 description 1
- 238000010254 subcutaneous injection Methods 0.000 description 1
- 239000007929 subcutaneous injection Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
- 239000000829 suppository Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- XQTLDIFVVHJORV-UHFFFAOYSA-N tecnazene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl XQTLDIFVVHJORV-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- WWJZWCUNLNYYAU-UHFFFAOYSA-N temephos Chemical compound C1=CC(OP(=S)(OC)OC)=CC=C1SC1=CC=C(OP(=S)(OC)OC)C=C1 WWJZWCUNLNYYAU-UHFFFAOYSA-N 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229940063650 terramycin Drugs 0.000 description 1
- MYKMOIQAHCMLIR-UHFFFAOYSA-N tert-butyl 2-(methylamino)acetate Chemical compound CNCC(=O)OC(C)(C)C MYKMOIQAHCMLIR-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UBCKGWBNUIFUST-YHYXMXQVSA-N tetrachlorvinphos Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC(Cl)=C(Cl)C=C1Cl UBCKGWBNUIFUST-YHYXMXQVSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229940074152 thuringiensin Drugs 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical group COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- JARYYMUOCXVXNK-CSLFJTBJSA-N validamycin A Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-CSLFJTBJSA-N 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- CHNQZRKUZPNOOH-UHFFFAOYSA-J zinc;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Zn+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S CHNQZRKUZPNOOH-UHFFFAOYSA-J 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/20—N-Aryl derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/12—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/14—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by halogen atoms or by nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/24—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/26—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
- C07C271/28—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/62—Compounds containing any of the groups, X being a hetero atom, Y being any atom, e.g. N-acylcarbamates
- C07C271/66—Y being a hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/50—Compounds containing any of the groups, X being a hetero atom, Y being any atom
- C07C311/52—Y being a hetero atom
- C07C311/53—X and Y not being nitrogen atoms, e.g. N-sulfonylcarbamic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
- C07C329/02—Monothiocarbonic acids; Derivatives thereof
- C07C329/04—Esters of monothiocarbonic acids
- C07C329/06—Esters of monothiocarbonic acids having sulfur atoms of thiocarbonic groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/96—Esters of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
- C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
- C07D295/182—Radicals derived from carboxylic acids
- C07D295/185—Radicals derived from carboxylic acids from aliphatic carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
- C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
- C07D295/205—Radicals derived from carbonic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Fluorobutenyl esters have the formula (I), in which R1 stands for hydrogen or a halogen, and R2 stands for one of the groups, in which V, Y, Z, R3 and R5 have the meanings given in the description. Also disclosed are a process and intermediate products for preparing said esters, as well as their use for controlling animal pests.
Description
The present invention relates to new Fluorobutenyl esters, relate to their preparation method, relate to and use their to control insect pest, especially control agricultural, forestry reach insect, Araneae and the nematode that health circle is run in product and thing material storage protection.
More known fluoro butene compounds have eelworm-killing activity (seeing WO88/00183).But these compound activity intensity and fungicidal spectrum are always dissatisfied fully, can not be satisfactory when especially low ratio use and lower concentration use.
The invention provides the new compound of general formula (I).
(I) R wherein
1Be hydrogen or halogen and R
2Be (a) or base one of (b)
(a) or
(b) wherein Y is oxygen or sulphur, and Z is oxygen, sulphur or NR
4, R
3Be hydrogen, the random alkyl that replaces, thiazolinyl, cycloalkyl, aryl, aralkyl, carbalkoxy, aryloxy carbonyl, arylsulfonyl or heteroaryl, R
4Be hydrogen or the random alkyl that replaces, alkylthio, thiazolinyl, cycloalkyl, aryl, aralkyl or heteroaryl, R
3And R
4A nitrogen-atoms that links to each other with them forms the ring of random replacement, and this ring arbitrarily contains oxygen, sulphur or azo-cycle (this nitrogen is arbitrarily by alkyl, and aryl or aralkyl replaces), or R
2Be (c) base,
(c)
Wherein
V is oxygen or NR
6With
R
5And R
6Independent separately is hydrogen, has the fatty group of 1 to 12 carbon atom, aryl or heterocyclic radical, and they are replaced by 1 substituting group at least, and these substituting groups are selected from alkyl, cyano group, trimethyl silicon based, hydroxyl, alkoxyl group, halogen, nitro, amino, alkylamino, dialkyl amido, SH, alkylthio, phenyl, or by the carboxylic acid group, sulfonic group, phosphate, phosphorous acid base, ester group, the amide group of thioester substrate or the acid mentioned replaces, and this amide group optionally alkyl list replaces or two replacement, or
R
5And R
6Nitrogen-atoms of linking to each other with them forms amino acid or forms and adds an oxygen arbitrarily outward, the heterocycle of sulphur or nitrogen, and they are at least arbitrarily by alkyl, cyano group, trimethyl silicon based, hydroxyl, alkoxyl group, halogen, nitro, amino, alkylamino, dialkyl amido, SH, alkylthio, phenyl or carboxylic acid group, sulfonic group, phosphate or phosphorous acid base, or the ester group of referred carboxylic acid, thioester substrate or amide group replace, and this amide group is arbitrarily replaced or two replacement by the alkyl list, or
R
5At R
6For being OR under the situation of hydrogen
7, COR
7, NR
7R
8, SO
2R
9, or P (=O) R
10R
11In a base, wherein
R
7And R
8Independent separately is hydrogen, alkyl or aryl,
R
9Be hydrogen, alkyl, haloalkyl or aryl,
R
10And R
11Independent separately is hydrogen, alkyl, and aryl, alkoxyl group, aryloxy, alkylthio,
Arylthio, amino, alkylamino, dialkyl amido or virtue are amino,
The present invention also provides the salt of the compound of general formula (I).
The compound of general formula (I) can exist with geometrical isomer and/or optical isomer or the mixture of isomers of forming with difference.The present invention promptly relates to pure isomer and also relates to mixture of isomers.
Have carboxyl or hydroxyl general formula (I) compound can with different positively charged ion in conjunction with salify, for example with basic metal or alkaline-earth metal ions, for example with sodium ion, potassium ion, calcium ion, magnesium ion or quaternary ammonium ion, for example sec.-propyl ammonium ion or pyridinium ion salify.
R wherein
1, R
3, R
5, V, Y, the implication of Z is the same,
General formula of the present invention (Ia) or compound (Ib) can make like this, work as A) the fluoro butenol of general formula (II) with
(II)
Wherein
Y wherein, Z, and R
3Implication the same, have thinner and random alkali to exist during reaction, or β) different (sulfo-) polyisocyanate reactant of general formula (IV),
YCN-R
3 (IV)
Wherein Y and R
3Implication the same, have thinner and random catalyzer to exist during reaction, or B) the fluoro butylene mercaptan of general formula (IIa)
(IIa) R wherein
1Implication the same, with the reaction of the compound of general formula (IIIa),
(IIIa)
Wherein Y and R
3Implication the same, have thinner and random alkali to exist during reaction, or C) compound of logical formula V
(V)
R wherein
1The same with the implication of Y, with the compound reaction of general formula (VI),
H-Z-R
3 (VI)
Wherein Z and R
3Implication the same, have thinner and random alkali to exist during reaction, or D) compound of general formula (VII)
(VII)
R wherein
1The same with the implication of Y, with the compound reaction of general formula (VIII),
H-S-R
3 (VIII)
R wherein
3Implication the same, have thinner and random alkali to exist during reaction,
The compound of general formula (Ic) can be by known compound (wherein some compound can be used as commodity bought) preparation, or from press the currently known methods compound of preparation (referring to preparing embodiment) easily,
The new compound of finding general formula (I) at last has strong biological activity, particularly is suitable for controlling animal pest, especially is controlled at agricultural, forestry, reaches insect, Araneae and the nematode that health circle is run in product and the protection of thing material.
General formula (I) provides the General Definition of compound of the present invention,
Preferred substituted or the substituting group scope listed in the general formula of mentioning in the present interpretive context.
R
1Be preferably hydrogen, fluorine or chlorine
Wherein Y is oxygen or sulphur
Z is an oxygen, sulphur or NR
4
R
3Be hydrogen, or C
1-C
10Alkyl, this alkyl be arbitrarily by halogen, cyano group, and carboxyl, phenyl, it is amino that (this amino is arbitrarily by C
2-C
7Alkylidene group (C
2-C
7Alkanediyl) replace or by identical or different C
1-C
8The alkyl list replaces or two replacement), C
1-C
8Alkoxyl group, C
1-C
8(this aminocarbonyl is arbitrarily by C for alkylthio or aminocarbonyl
2-C
7-alkylidene group (C
2-C
7-alkanediyl) replace, by identical or different C
1-C
8Alkyl, C
1-C
8Haloalkyl, C
1-C
8Alkoxyl group, C
3-C
8Cycloalkyl, C
3-C
8Halogenated cycloalkyl, C
1-C
4Alkyl-C
3-C
8Cycloalkyl, or by phenyl or benzyl replacement, phenyl and benzyl all can be optionally by halogens, cyano group, nitro, C
1-C
8Alkyl, C
1-C
8Haloalkyl, C
1-C
8Alkoxyl group, C
1-C
8Halogenated alkoxy, C
1-C
8Alkylthio or C
1-C
8Halogenated alkylthio replaces), or the C for arbitrarily being replaced by halogen
3-C
8Thiazolinyl, or for arbitrarily by halogen or C
1-C
6The C that alkyl replaces
3-C
8Cycloalkyl, or be phenyl, benzyl, carbobenzoxy or phenyl sulfuryl, they are arbitrarily separately by halogen, cyano group, nitro, C
1-C
8Alkyl, C
1-C
8Haloalkyl, C
1-C
8Alkoxyl group, C
1-C
8Halogenated alkoxy, C
1-C
8Alkylthio, C
1-C
8Halogenated alkylthio, C
1-C
8Carbalkoxy or SCN replace, or are halogen or C
1-C
65 yuan or 6 yuan of heterocycles containing 1 to 3 nitrogen-atoms that alkyl arbitrarily replaces, or be halogen or C
1-C
6The C that alkoxyl group arbitrarily replaces
1-C
8Carbalkoxy.R
4Be preferably hydrogen, or arbitrarily by halogen, cyano group, it is amino that (this amino is arbitrarily by C
2-C
7Alkylidene group (C
2-C
7-alkanediyl) replace or arbitrarily by identical or different C
1-C
8The alkyl list replaces or two replacement), C
1-C
8Alkoxyl group, C
1-C
8(this aminocarbonyl is arbitrarily by C for alkylthio or aminocarbonyl
2-C
7-alkylidene group (C
2-C
7-alkanediyl) replace or by identical or different C
1-C
8Alkyl, C
1-C
8Haloalkyl, C
3-C
8Cycloalkyl, C
3-C
8Halogenated cycloalkyl, C
1-C
4Alkyl-C
3-C
8Cycloalkyl is single to be replaced or two replacement, or is replaced by phenyl or benzyl, and they are separately arbitrarily by halogen, cyano group, nitro, C
1-C
8Alkyl, C
1-C
8Haloalkyl, C
1-C
8Alkoxyl group, C
1-C
8Halogenated alkoxy, C
1-C
8Alkylthio, or C
1-C
8Halogenated alkylthio replaces), or be the C that halogen arbitrarily replaces
1-C
6Alkylthio, or be the C that halogen arbitrarily replaces
3-C
8Thiazolinyl, or be halogen or C
1-C
6The cycloalkyl that alkyl arbitrarily replaces, or be phenyl or benzyl, they are separately arbitrarily by halogen, cyano group, nitro, C
1-C
8Alkyl, C
1-C
8Haloalkyl, C
1-C
8Alkoxyl group, C
1-C
8Halogenated alkoxy, C
1-C
8Alkylthio, C
1-C
8Halogenated alkylthio, C
1-C
8Carbalkoxy or SCN replace, or are halogen or C
1-C
65 yuan or 6 yuan of heterocycles of the random replacement that contains 1 to 3 nitrogen-atoms that alkyl arbitrarily replaces, or R
3And R
4A nitrogen-atoms that links to each other with them forms 4 to 8 yuan of rings, forms arbitrarily by C
1-C
8(this nitrogen is arbitrarily by C for arbitrarily contain oxygen, sulphur or nitrogen that alkyl replaces
1-C
8Alkyl, phenyl or benzyl replace) ring.R
1Especially be preferably fluorine.R
2Especially be preferably the base of following formula
Wherein Y is oxygen or sulphur, and Z is an oxygen, sulphur or NR
4, R
3Be hydrogen, or arbitrarily by fluorine, chlorine, cyano group, carboxyl, phenyl, it is amino that (this amino is arbitrarily by C
2-C
6Alkylidene group (C
2-C
6-alkanediyl) replace or by identical or different C
1-C
6The alkyl list replaces or two replacement), C
1-C
6Alkoxyl group, C
1-C
6(this aminocarbonyl is arbitrarily by C for alkylthio or aminocarbonyl
2-C
6Alkylidene group (C
2-C
6-alkanediyl) replace or by identical or different C
1-C
6Alkyl, C
1-C
6Haloalkyl, C
1-C
6Alkoxyl group, C
3-C
7Cycloalkyl, C
3-C
7Halogenated cycloalkyl, C
1-C
3-alkyl-C
3-C
7Cycloalkyl is single to be replaced or two replacement, or is replaced by phenyl or benzyl, and they are separately arbitrarily by halogen, cyano group, nitro, C
1-C
6Alkyl, C
1-C
6Haloalkyl, C
1-C
6Alkoxyl group, C
1-C
6Halogenated alkoxy, C
1-C
6Alkylthio or C
1-C
6Halogenated alkylthio) C of Qu Daiing
1-C
6Alkyl, or for arbitrarily by fluorine, chlorine or C
1-C
4The C that alkyl replaces
4-C
8Cycloalkyl, or be phenyl, benzyl, carbobenzoxy or benzene sulfuryl, they are separately arbitrarily by fluorine, chlorine, cyano group, nitro, C
1-C
6Alkyl, C
1-C
6Haloalkyl, C
1-C
6Alkoxyl group, C
1-C
6Halogenated alkoxy, C
1-C
6Alkylthio, C
1-C
6Halogenated alkylthio, C
1-C
6Carbalkoxy or SCN replace, or are fluorine, chlorine or C
1-C
4The C that alkoxyl group arbitrarily replaces
1-C
6Carbalkoxy.R
4Especially be preferably hydrogen, or be C
1-C
6Alkyl, the C that fluorine or chlorine arbitrarily replaces
1-C
4Alkylthio, or C
4-C
8Cycloalkyl, or R
3And R
4A nitrogen-atoms that is connected with them forms 4 to 8 yuan of rings, forms arbitrarily by C
1-C
6Alkyl replaces arbitrarily contains oxygen, and (this nitrogen is arbitrarily by C for sulphur or nitrogen
1-C
6Alkyl, phenyl or benzyl replace) ring.R
1It very particularly preferably is fluorine.R
2It very particularly preferably is the base of following formula
Wherein Y is an oxygen, and Z is an oxygen, sulphur or NR
4, R
3Be hydrogen, or arbitrarily by fluorine, chlorine, cyano group, carboxyl, phenyl, it is amino that (this amino is arbitrarily by C
2-C
6Alkylidene group (C
2-C
6-alkanediyl) replace or by identical or different C
1-C
6The alkyl list replaces or two replacement), C
1-C
6Alkoxyl group, C
1-C
6(this aminocarbonyl is arbitrarily by C for alkylthio or aminocarbonyl
2-C
6Alkylidene group (C
2-C
6-alkanediyl) replace or by identical or different C
1-C
4Alkyl, C
1-C
4The alkoxyl group list replaces or two replacement, or is replaced by phenyl or benzyl, and they are separately arbitrarily by halogen, cyano group, nitro, C
1-C
6Alkyl, C
1-C
6Haloalkyl, C
1-C
6Alkoxyl group, C
1-C
6Halogenated alkoxy, C
1-C
6Alkylthio or C
1-C
6Halogenated alkylthio) C of Qu Daiing
1-C
6Alkyl, or be C
1-C
4The C that alkyl arbitrarily replaces
4-C
8Cycloalkyl, or be phenyl, benzyl, carbobenzoxy or benzene sulfuryl, they are separately arbitrarily by fluorine, chlorine, cyano group, nitro, C
1-C
4Alkyl, C
1-C
4Haloalkyl, C
1-C
4Alkoxyl group, C
1-C
4Halogenated alkoxy, C
1-C
4Alkylthio, C
1-C
4Halogenated alkylthio or C
1-C
4Carbalkoxy replaces, or is fluorine, chlorine, or C
1-C
4The C that alkoxyl group arbitrarily replaces
1-C
4Carbalkoxy.R
4Very particularly preferably be hydrogen, or be C
1-C
4Alkyl is the random C that replaces of fluorine or chlorine
1-C
3Alkylthio, or C
4-C
6Cycloalkyl, or R
3And R
4The nitrogen-atoms that links to each other with them together forms 4 to 8 yuan of rings, or forms C
1-C
4Alkyl replaces arbitrarily contains oxygen, and (this nitrogen is arbitrarily by C for sulphur or nitrogen
1-C
4Alkyl or benzyl arbitrarily replace) ring.
General or the preferred definition of above-mentioned group or description is used for end product and is used for raw material and intermediate accordingly.The definition of these groups can mutually combine as required, and that is to say may be in combination between the preferred range separately.
According to the present invention, preferably contain the general formula (Ia) and the compound (Ib) of the combination of the preferred implication of above-mentioned conduct.
According to the present invention, preferably contain above-mentioned general formula (Ia) and compound (Ib) especially as particularly preferred combination.
According to the present invention, preferably contain the general formula (Ia) and the compound (Ib) of above-mentioned conduct combination very particularly preferably very especially.
Further preferred compound group is the compound of general formula (Ic), and particularly wherein Z is that oxygen and R5 are that fatty group is preferably the particularly compound of ethyl of low alkyl group.
In the definition of the given base of context, alkyl, alkyl or alkenyl-and link to each other for example, for example alkoxyl group or alkylthio-be straight or branched in all cases as far as possible with heteroatoms.
With radicals R
5, R
6, R
7, R
8, R
9, R
10And R
11Definition in the term that uses understand as follows:
Term " halogen " means fluorine, chlorine, bromine, iodine.
Term " alkyl " is straight or branched C
1-C
7Alkyl.
Term " low alkyl group " is straight or branched C
1-C
4Alkyl.
Term " fatty group " is saturated or undersaturated, contains the straight or branched alkyl of 1 to 10 carbon atom (or as said), or contains the straight or branched thiazolinyl of 2 to 10 carbon atoms (or as said).
Term " alkoxyl group " is the low alkyl group that connects via Sauerstoffatom.
Term " alkylthio " is the low alkyl group that connects via sulphur atom.
Term " carbalkoxy " is the low-grade carboxylic acid's of carboxyl a alkyl ester.
Term " carboxylic acid group; sulfonic group; the ester of phosphate or phosphorous acid base or the acid mentioned; thioesters or acid amides " means wherein at least one carbon atom by the fatty group of carboxyl substituted, or wherein at least one hydrogen atom by sulfonic group, the fatty group that lower alkyl esters, low alkyl group thioesters or the acid amides of phosphorous acid base or phosphate and the acid mentioned (this acid amides is arbitrarily replaced by 1 or 2 low alkyl groups) replaces.
Term " amino acid " means NR
5R
6Arbitrarily replaced by the amino of natural or alpha-non-natural amino acid.
Term " aromatic base " or " aryl " mean the phenyl with image replacement recited above.
At least any ring that contains 1 non-carbon in term " heterocyclic radical " finger ring.Heteroatoms can be an oxygen, nitrogen, sulphur or other element.The heterocyclic example has thiadiazoles, pyridine, thiazole, isothiazole , oxazole, imidazoles, pyrazoles, triazole, benzothiazole, sulfur heterocyclic ring, morpholine, piperidines, piperazine, or tetramethyleneimine, they are replaced by a substituting group at least, and these substituting groups are from cyano group, and are trimethyl silicon based, hydroxyl, alkoxyl group, halogen, nitro, amino, SH, alkylthio, carboxyl, carbalkoxy, phenyl, carboxylic acid group, sulfonic group, phosphate, phosphorous acid base, or these sour ester, monothioester or acid amides.
According to method A α of the present invention) during the compound of preparation general formula (I), if with for example 3,4,4-three fluoro-fourth-3-enol and chloro ethyl formate are made raw material, can describe reaction with following reaction scheme so:
According to method A β of the present invention) during the compound of preparation general formula (I), if with for example 3,4,4-three fluoro-fourth-3-enol and phenylcarbimide are made raw material, can describe reaction with following reaction scheme so:
According to method B of the present invention) during the compound of preparation general formula (I), if with for example 3,4,4-three fluoro-fourth-3-enol and chloro sulphur methyl-formiate are made raw material, can describe reaction with following reaction scheme so:
According to method C of the present invention) during the compound of preparation general formula (I),, can reaction be described with following reaction scheme so if be raw material with for example chloroformic acid-(3,4,4-three fluoro-fourth-3-alkene)-ester and hexahydroaniline:
According to method D of the present invention) during the compound of preparation general formula (I), if with for example chloro sulphur formic acid-(3,4,4-three fluoro-fourth-3-alkene)-ester and 2, the 6-thebaine is a raw material, can describe reaction with following reaction scheme so:
The method A α of the compound of all above-described preparation general formulas (I), A β, B, C and D are characterised in that under the existence that wherein is reflected at thinner and carry out.
Suitable diluents in these methods is conventional solvent.
Particularly suitable thinner is random halogenated aliphatic hydrocarbon or aromatic hydrocarbon, ether or nitrile, for example hexanaphthene, toluene, chlorobenzene, chloroform, methylene dichloride, ethylene dichloride, dioxane, tetrahydrofuran (THF), ether or acetonitrile.
The method A α of the compound of all above-described preparation general formulas (I), B, C and D are characterised in that wherein reaction is optionally carried out in the presence of alkali.
Method A α, B, alkali suitable among C and the D is conventional proton acceptor, and Shi Yi alkali is alkali metal hydroxide especially, or alkaline earth metal hydroxides, alkaline carbonate, or alkaline earth metal carbonate, or alkali metal hydrocarbonate, or alkali metal bicarbonates, or nitrogenous base.Example comprises sodium hydroxide, calcium hydroxide, salt of wormwood, sodium bicarbonate, triethylamine, dibenzylamine, Diisopropylamine, pyridine, quinoline, diazabicyclo octane (DABCO), diazabicyclo-nonene (DBN) and diazabicyclo hendecene (DBU).
The method A β of the compound of above-described preparation general formula (I) is characterised in that wherein reaction is optionally carried out in the presence of catalyzer.
Suitable catalyzer is for example diazabicyclo octane (DABCO), triethylamine or pyridine or organic tin compound, for example dibutyl tin laurate.
Above-described method A α, A β, B, C in all cases can be in relative wide range with the temperature of reaction among the D.At method A α, B, among C and the D, reaction is generally carried out between-10 ℃ and 150 ℃.Preferably between 0 ℃ and 90 ℃, carry out.In method A β, reaction is generally carried out between 0 ℃ and 120 ℃, preferably carries out between 20 ℃ and 100 ℃.
Method A α formula of (II) and (III) and method B formula of (IIa) and raw material ratio (III) be 1: 1 to 2: 1.
At method A β formula of (II) and material rate (IV) generally at 2: 1 and l: between 2; Being preferably equivalent uses.
The general formula (VII) among logical formula V in method C and raw material (VI) and the method D and the material rate of general formula (VIII) are generally respectively between 1: 1 and 10: 1.
Above-described method A α, A β, B, C and D generally under atmospheric pressure implement.Above-described method A α, A β, B when C and D aftertreatment, with reaction mixture dilute with water for example, uses organic solvent extraction, concentrates organic phase then.
The raw material of the general formula (II) that uses in method A α and A β is known, and can prepare (referring to for example WO 92/15555) by currently known methods.
The general formula (III) or the raw material (IIIa) that also use in method A α and B are known and/or can prepare by currently known methods.General formula (III) or compound (IIIa) for example can be by alcohol, the amine of mercaptan or general formula (VI) makes (referring to for example Houben-Weyl by currently known methods and phosgene or thio phosgene reaction, Methoden der Organischem Chemie, BandE4, S.407 ff., Georg Thieme Verlag Stuttgart, NeW York, 1983).
The different thiocyanide that is used as the general formula (IV) of raw material in method A β is to be used for the synthetic known compound in the organic chemistry.
Though the raw material of the logical formula V that uses in method C is a new compound, can prepare by currently known methods.For example (see above) and phosgene or thio phosgene reaction can make the compound of logical formula V to the compound of general formula (II) according to a conventional method.
The raw material of the general formula (VI) that also uses in method C generally is to be used for the synthetic known compound in the organic chemistry.
The general formula that in method D, uses (VII) though raw material be new compound, can prepare by currently known methods.For example the compound of general formula (IIa) can make the compound of general formula (VII) by method (see above) known per se and phosgene or thio phosgene reaction.
The raw material of the general formula (VIII) that also uses in method D generally is to be used for the synthetic known compound in the organic chemistry.
This class active compound is suitable for controlling pest, especially is controlled at agricultural, and forestry reaches insect, Araneae and the nematode that health circle is run in product and the preservation of thing material.No matter they are to the insect of normal sensitivity or the insect of antagonistic drug, and the growth whole process of described insect or some stage of growth are all had antagonistic activity.Insect above-mentioned comprises:
From Isopoda, for example Oniscus asellus, Armadillidium vulgare and Porcellio Scaber.
From Isopoda, Blaniulus guttulatus for example.
From Chcilopoda, for example the DIWUGONG of Carpophagus belongs to and the kind of common house centipede dragonfly section.
From comprehensive subclass, the common house centipede section of immaculata for example.
From total tail purpose, for example silverfish.
From Collembola, for example the sour jujube of spinosity jumps.
From Orthoptera, Blatta seu periplaneta for example, U.S. blattaria, leucophaea maderae, blatta germanica, tame Xi, mole cricket kind, African migratory locust, different black locust and desert locust.
From Dermaptera, European earwig for example.
From Isoptera, reticulitermes flavipe kind for example.
From Anoplura, for example body louse, blood lice kind and a hair lice kind.
From Mallophaga, for example chew lice kind and poultry lice kind.
From Thysanoptera, for example greenhouse bar hedge thrips and onion thrips.
From Hemiptera, for example flat fleahopper kind, red cotton bug intermedius, square butt stinkbug, bed bug, phodnius prolixus and dimension are hunted the stinkbug kind.
From Hemiptera, wild cabbage aleyrodid for example, cassava aleyrodid, greenhouse whitefly, cotten aphid, brevicoryne brassicae, the tea Fischer conceals knurl aphid, beans winged euonymus aphid, apple aphid, apple aphid, mealy plum aphid, grape phylloxera, goitre woolly aphid kind, grain aphid, knurl aphid kind, phorodon aphid, rhopalosiphum padi, jassids kind, bilobate blunt nose calamity leafhopper, rice green leafhopper, the hard a red-spotted lizard of water wood, black scale, small brown rice planthopper, brown paddy plant hopper, red kidney Aspidiotus, ivy Aspidiotus, mealybug kind and wood louse kind.
From lepidopterous, Pectinophora gossypiella for example, loose looper, Cheimatobia brumata, the thin moth of apple, apple ermine moth, diamond-back moth, malacosoma neustria, the pornography and drug moth, poison moth kind, cotton lyonetid, tangerine lyonetid, the cutworm kind, the cutworm kind, the noctuid kind, Egyptian golden steel bores, real noctuid kind, beet armyworm, lopper worm, pine beauty, the litura noctuid, spodoptera kind, cabbage looper, codling moth, the small white kind, dogstail snout moth's larva kind, Pyrausta nubilalis (Hubern)., Anagasta kuehniella, Galleriamellonella, curtain rain moth, bag rain moth, brownly knit moth, the yellow volume of flax moth, reticulana rolls up moth, spruce bunworm, Clysia ambiguella, the green volume of tea long paper moth and oak moth.
From Coleoptera, furniture death watch beetle for example, lesser grain borer, the awl chest bean weevil of tool quilt belongs to, acanthoscelides obtectus, the North America house longhorn beetle, the willow firefly is chrysomelid, colorado potato beetles, the horseradish ape is chrysomelid, chrysomelid kind, rape golden head flea beetle, the big Epilachna spp of Mexico, the Atomaria linearis kind, saw-toothed grain beetle, flower resembles kind, the grain weevil kind, black grape ear image, the banana collar resembles, Chinese cabbage powder tortoise resembles, and alfalfa leaf resembles, the khapra beetle kind, spot khapra beetle kind, circle khapra beetle kind, powder is moth-eaten plants, the aeneus nitidulid, ptinid kind, golden spider beetle, globose spider beetle, ostomatid kind, tenebrio molitor, Pleonomus kind, the west melolonthid in May, European chafer (Amphimallon majalis) and and the brown New Zealand rib wing melolonthid.
From hymenopteran, for example Neodiprion spp kind, sawfly kind, ant kind, little red ant and wasp kind.
From dipterous, yellow-fever mosquito kind for example, eucalyptus mosquito kind, culex kind, black-tailed fruit flies, housefly kind, latrine fly kind, reddish tone fly kind, the lucilia kind, golden fly kind, cuterbrid kind, stomach fly kind, the Hyppobosca kind, tatukira kind, botfly kind, torsalo kind, the horsefly kind, Tannia kind, black wool mosquito, auspicious bent wheat stem chloropid fly, late wheat straw kind fly, beet spring fly, Mediterranean Sea Ceratitis spp, big trypetid of olive and European daddy-longlegs.
From Siphonaptera, Xanthopsyllacheopis for example, c. leaf flea kind.
From Arachnida, for example Scorpio maurus and Latrodectus mactans.
From acarina, Acarus siro for example, sharp-edged mite kind, turicata kind, Dermanyssus gallinae, tea Fischer goitre mite, the tangerine rust mite that rues, ox tick kind, fan head tick kind, flower tick kind, glass eye tick kind, hard tick kind, the itch mite kind, overworked mite kind, Sarcoptes kind, tarsonemid mite kind, Bryobia praetiosa, golden pawl mite kind and tetranychid kind.
The phytoparasitic nematodes comprises the Pratylenchus kind, Radopholussimilis, Ditylenchus dipsaci, Tylenchulus semipenetrans, narrow body Pleonomus kind, Globodera kind, the Meloidogyne kind, Aphelenchoides kind, Longidorus kind, Xiphinema kind and Trichodorus kind.
The compound of general formula of the present invention (I) has shown outstanding insect and eelworm-killing activity extremely especially.Be used for extremely that leaf is given birth to and during the livings insect of soil, their show strong active, for example show and strong kill mustard seed pestle lavae (Phaedon cochleariae) and water chestnut is believed the Candle-sticks that carries on the back moth (Plutella maculipcunis).When being used for nematicide, they have for example strong Meloidogyne incognita activity extremely.
Compound of the present invention not only has prophylactic effect, also can be used for the leaf system root system pest-resistant evil of uniting of unifying.
The active compound of general formula of the present invention (I) also has fungicidal action further, and the effect of killing Pyricularia oryzea in the rice is for example arranged.
This class active compound can change common formulations into, for example changes solution, emulsifying agent into, wettable powder, suspension agent, pulvis, dust agent, paste, soluble powder, granule, suspension agent-emulsifying agent enriched material, with the natural goods and the synthetics of active compound dipping, and the superfine capsule of making of superpolymer.
These formulations are pressed currently known methods production, for example mix with spreading agent by active compound, promptly mix with liquid solvent and/or solid carrier, optionally use tensio-active agent, promptly use emulsifying agent and/or dispersion agent and/or foam to form agent.
When making water as spreading agent, also can be with an organic solvent as solubility promoter.As liquid solvent, suitable mainly contains: aromatic hydrocarbons, for example dimethylbenzene, toluene or alkylnaphthalene, chlorination aromatic hydrocarbon and chlorinated aliphatic hydrocarbon, for example chlorobenzene, vinylchlorid, methylene dichloride, aliphatic hydrocarbon, for example hexanaphthene or paraffinic hydrocarbons, sherwood oil cut for example, mineral oil and vegetables oil, alcohols, for example butanols or glycerine, and their ether or ester, ketone, acetone for example, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or pimelinketone, intensive polar solvent, for example dimethyl formamide and dimethyl sulfoxide (DMSO) and water.Suitable solid carrier has: the natural material of ammonium salt and grinding for example, kaolin for example, clay, talcum, chalk, quartz, atlapulgite, polynite or diatomite, and the synthetic material that grinds, the silica gel of high dispersive for example, aluminum oxide and silicate, the suitable solid carrier of making granule has: for example pulverize with the fractionated natural rock, calcite for example, marble, float stone, sepiolite and rhombspar, and the synthetic particle of inorganic and organic powder, and the particle of organic materials, for example sawdust, cocoa shell, corn fragment and tobacco rods; Examples of suitable emulsifiers and/or foam form agent to be had: for example non-ionic type and anionic emulsifier, polyoxyethylene fatty acid ester for example, polyoxyethylene aliphatic alcohol ether, alkylaryl polyglycol ether for example, alkyl sulfonic ester, alkyl sulfuric ester, aromatic yl sulphonate and egg white hydrolysate; Suitable dispersion agent has: for example lignin sulfite waste lye and methylcellulose gum.
Tackiness agent, for example carboxymethyl cellulose and powdery, particulate state or glue lactous natural and synthetic superpolymer, for example gum arabic, polyvinyl alcohol and polyvinyl acetate, and natural phospholipid, for example kephalin and Yelkin TTS, and synthetic phosphatide, can be used for prescription.It is further auxilliary that to add agent be mineral oil and vegetables oil.
Also can use tinting material, mineral dye for example, ferric oxide for example, titanium dioxide, with general Lu Shi orchid, and organic dye, for example alizarine dyestuff, azidine dye and metal phthalocyanine dyestuff and trace nutrient, for example iron, manganese, boron, copper, cobalt, the salt of metals such as molybdenum and zinc.
The active compound of the general bag of prescription (wound by weight) 0.1% to 95% preferably contains 0.5% to 90% active compound.
New active compound can exist with its commodity prescription and the form of use, can be by these formulation, as with the mixture of other active compound, for example with insecticide, attractive substance, sterilizing agent, antiseptic-germicide, miticide, nematocides, mycocide are produced the mixture of regulating material or weedicide.Insecticide comprises, phosphoric acid ester for example, carbamate, carboxylicesters, hydrochloric ether, benzene urine, and the chemical combination material by microorganisms particularly.
The example of particularly advantageous composition is as follows: mycocide:
The 2-aminobutane; 2-phenylamino-4-methyl-6-cyclopropyl-pyrimidine; 2 ', 6 '-two bromo-2-methyl-4 '-trifluoromethoxy-4 '-Trifluoromethyl-1,3-thiazole-5-carboxylic acylaniline; 2,6-two chloro-N-(4-trifluoromethyl benzyl) benzamide; (E)-2-methoxyimino-N-methyl-2-(2-phenoxy phenyl) ethanamide; The oxine sulfuric ester; (E)-and 2-{2-[6-(2-cyano-benzene oxygen)-pyrimidine-4-base oxygen] phenyl }-the 3-methoxy acrylate; (E)-methoxyimino [α-(neighbour-toluene oxygen)-O-tolyl] methyl acetate; 2-phenylphenol (OPP), aldimorph, ampropylfos, anilazine, azaconazole, benalaxyl, benodanil, benomyl, Niagara 9044, biphenyl, bitertanol, miewensu, bromuconazole, bupirimate, buthiobate, lime sulfur mixture, Difolatan, Vancide 89, derosal, carboxin, chinomethionate, chloroneb, trichloronitromethane, m-tetrachlorophthalodinitrile, chlozolinate, cufraneb, cymoxanil, cyproconazole, cyprofuram, dichlorophen, diclobutrazol, diclofluanid, diclomezine, dicloran, diethofencarb, difenoconazole, Milcurb, dimethomorph, diniconazole, dinocap, pentanoic, dipyrithione, ditalimfos, the Delan, dodine, drazoxolon, Hinosan, epoxyconazole, the pyridine of second bacterium, etridiazole, fenarimol, fenbuconazole, fenfuram, fenitropan, fenpiclonil, fenpropidin, fenpropimorph, fentinacetate, fentinhydroxide, ferbam, ferimzone, fluazinam, fludioxonil, fluoromide, fluquinconazole, flusilazole, flusulphamide, flutolanil, flutriafol, Phaltan, fosetyl-aluminium, fthalide, fuberidazole, furalaxyl, furmecyclox, Guanoctine, Perchlorobenzene, hexaconazole, hymexazol, imazalil, imibenconazole, iminoctadine, iprobenfos (IBP), iprodione, Fujione, the spring thunder toxin, copper agent, for example: copper hydroxide, copper naphthenate, COPPER OXYCHLORIDE 37,5, copper sulfate, cupric oxide, oxine-copper and Bordeaux mixture.Mancopper, zinc manganese ethylenebisdithiocarbamate, maneb, mepanipyrim, mepronil, metalaxyl, metconazole, methasulphocarb, methfuroxam, Carbatene, metsulphovax, myclobutanil, good fortune magnesium nickel, nitrothal-isopropyl, muarimol, ofurace, axadixyl, oxamocarb, oxycarboxin, pefurazoate, penconazole, pencycuron, phosdiphen, phthalide, myprozine, pipron, polycarbamate, Polyoxin, thiabendazole, prochloraz, procymidone, propamocarb, propiconazole, propineb is decided the bacterium spirit, pyrifenox, pyrimethanil, pyroguilon, quintozene (PCNB), sulphur and sulphur preparation, tebuconazole, tecloftalam, tecnazene, tetraconazole, Apl-Luster, thicyofen, thiophanate methyl, thiram, tolclophosmethyl, tolylfluanid, triadimefon, triadimenol, triazoxide, trichlamide, tricyclazole, tridemorph, triflumizole, triforine, triticonazole, Validacin (Takeda), vinclozolin, zineb, ziram, bactericide: the bromine nitre glycol that goes out, dichlorophen, nitrapyrin, Sankel, kasugamycin, octhilinone, furancarboxylic acid, terramycin, thiabendazole, Streptomycin sulphate, tecloftalam, copper sulfate and other copper agent.Insecticide/miticide/nematocides: abamectin, AC 303630, Ortho 12420, acrinathrin, alanycarb, aldicarb, alphamethrin, amitraz, avermectin, AZ 60541, azadirachtin, R-1582 A, R-1582 M, azocyclotin, bacillus thuringiesis Evil worm prestige, benfuracarb, bensultap, beta-cyfluthrin, bifenthrin, butylbenzene becomes, brofenprox, bromofos A, bufencarb, buprofezin, butocarboxim, butylpyridaben, cadusafos, SevinCarbaryl, carbofuran, carbophenothion, carbosulphan, Padan, CGA l57419, CGA 184699, chloethocarb, chlorethoxyfos, Zaprawa enolofos, chlorfluazuron, chlormephos, Chlorpyrifos 94, chlorpyrifos M, suitable-Chryson, clocythrin, clofentezine, cynock, cycloprothrin, cyfluthrin, cyhalothrin, cyhexatin, cypermethrin, cyromazine, deltamethrin, one zero five nine M, one zero five nine S, methyl 1, diafenthiuron, diazinon, dichlofenthion, SD-1750, dicliphos, Carbicron, Nialate, diflubenzuron, Rogor, dimethylvinphos, dioxathion, thiodemeton, Hinosan, emamectin, esfenvalerate, ethiofencarb, Nialate, ethofenprox, ethoprophos, etrimphos, fenamiphos, fenazaquin, fenbutatinaxide, Sumithion, fenobucarb, fenothiocarb, fenoxycarb, fenpropathrin, fenpyrad, fenpyroximate, Tiguvon, fenvalerate, fipronil, fluazinam, flucycloxuron, flucythrinate, flufenoxuron, flufenprox, fluvalinate, Dyfonate, the peace fruit, fosthiazate, fubfenprox, furathiocarb, phenyl-hexachloride, heptenophos, hexaflumuron, hexythiazox, imidacloprid, iprobenfos, isazophos, isofenphos, isoprocarb , karphos, ivermectin, lambda-cyhalothrin, lufenuron, Phosphothion, mecarbam, Phosdrin, mesulphenfos, Halizan, methacrifos, acephatemet, methidathion, metmercapturon, methomyl, metolcarb, milbemectin, monocrotophos, moxidectin, naled, NC l84, NI 25, nitenpyram, omethoate, oxamyl, oxydemeton methyl M, oxydeprofos, one six zero five A, one six zero five M, permethrin, Tsidial, phorate, zolone, R-1504, phosphamidon, phoxim, Aphox, pirimiphosmethyl M, pirimiphosmethyl A, profenofos, promecarb, Kayaphos, Propoxur, prothiofos, Fac, pymetrozin, pyrachlofos, pyridaphenthion, pyresmethrin, pyrethrum, pyridaben, pyrimidifen, pyriproxyfen , quinalphos, RH 5992, salithion, sebufos, silafluofen, sulphotep, sulprofos, tebufenozid, tebufenpyrad, tebupirimifos, teflubenzuron, tefluthrin, temephos, terbam, terbufos, tetrachlorvinphos, thiafenox, thiodicarb, thiofanox, thiomethon, ethyl pyrazinyl phosphorothioate, thuringiensin, tralomethrin, triarathen, triazoline, triazuron, Trichlorphon, triflumuron, trimethacarb, vamidothion, Cosban, xylylcarb, YI 5301/5302, zetamethrin
Can also with other known activity compound fusion, for example with weedicide or fertilizer and the fusion of promotes growth compound.
Active compound of the present invention can exist with their commodity prescription with the use shape from these formulation further, as with the mixture of synergist.Synergist is the compound that increases the active compound effect, and it is activated that synergist itself is provided with necessity.
Can in big limit, change from the amount of the active compound of the use form of commodity formulation.The concentration of using the active compound of form can be from 0.0000001 to 95% of the weight of active compound, preferably 0.0001 to 1% (by weight).
Compound is by being suitable for using the usual manner of form to use.
When being used for the insect of the product of health circle insect and storage extremely, active compound has outstanding residual action at timber on the clay, to having satisfactory stability with the alkali on the substrate of lime treatment.
Active compound of the present invention not only has the plant of killing, and the effect of the insect in the product of health and preservation can also be killed zooparasite (epizoon) in the animal doctor, for example hard tick, soft ticks, scab mite, sandmite, fly (sting and inhale), the tachinid larva, sends out lice, bird lice and flea at lice.These parasites comprise:
From the Anoplurida purpose, blood lice kind for example, hair mite kind, lice kind, phtirus kind, pipe lice kind;
From neck bean weevil subfamily Mallophaga and thick and Ischnocerina purpose, filoplume lice kind for example, the mallophaga kind, huge poultry louse kind, ox poultry louse kind, the Werneckiella kind, the Lepikentron kind, poultry lice kind is chewed the lice kind, cat poultry louse kind;
From dipterous and orthorrhapha suborder with orthorrhapha, yellow-fever mosquito kind for example, anopheles kind, culex kind, the buffalo gnat kind, true buffalo gnat kind, sand fly kind, Lutzomyia kind, the mosquito Superfamily, spot horsefly kind, hybomitra kind, yellow horsefly kind, Gadfly, Chrysozona, philipomyia kind, the honeybee Hippobosca, Musca, Hydrotaea, matting chela fly belongs to, east horn fly kind, and Morellia belongs to, Fannia, Glossina, Calliphora, Lucilia, Carysomyia, wohlfahrtia magnifica, Sarcophaga, Oestrus, Hypoderma, Gasterophilus, Hippobosca, Lipoptena and Melophagus.
From Siphonaptera, for example, the flea kind, Ctenocephalus, objective flea belongs to, Ceratophyllus.
From Hemiptera, for example, Cimex, Triatoma, Rhodnius and Panstrongylus kind.
From Blattodea, Blatta seu periplaneta for example, periplaneta americana, blatta germanica, brown belt Lian.
From Tyroglyphidae (Acarida) subtribe and Meta order and Mesostigmata purpose, Argas for example, Ornithodoros, the Otabius kind, hard tick belongs to Amblyomma, Boophilus, careless tick belongs to, Haemaphysalis, Hyalomma, Rh, Dermanyssus, Raillietia kind, the Pneumonyssus kind, Sternostoma kind and Vespacarus.
From Actinedida (Prostigmata) order and Acaridida (Astigmata) purpose, for example, honeybee shield mite belongs to, the Cheyletiella kind, the Ornithocheyletia kind, Myobia kind, Psorergates kind, Demodex, Trombidium, black this resembles genus, Tyroglyphus, the saprophage mite belongs to, the Caloglyphus kind, the Hypodectes kind, the Pterolichus kind, overworked mite belongs to, Psoroptes, the ear itch mite belongs to, and itch mite belongs to, Notoedres, Cnemidocoptes, Cytodites kind and Laminosioptes.
For example compare with lucilia cuprina with boophilus microplus, they show outstanding activity.
The active compound of general formula of the present invention (I) also is applicable to the arthropods of the agriculture domestic animal of control harm, for example control endangers ox, sheep, goat, horse, pig, monkey, camel, buffalo, rabbit, chicken, turkey, duck, goose, honeybee, other domestic animal, for example dog, cat, cage bird, cylinder is breeded fish and so-called laboratory animal, hamster for example, guinea pig, the arthropods of rat and mouse.By controlling these arthropodss, purpose is to reduce the mortality ratio of domestic animal and reduces workload (workload in meat, milk, fur, leather, egg, honey or the like), so that might use active compound of the present invention more economical, more simply feeding animals.
In veterinary applications, active compound of the present invention administration for oral administration in known manner is for example with tablet, capsule, beverage, liquid medicine, granule, paste, pill, food is raised agent, suppository etc. are for oral administration, by parenterai administration, for example injection (intramuscular injection, subcutaneous injection, intravenous injection, peritoneal injection or the like), drug delivery implant, intranasal administration, percutaneous dosing is for example with soaker or solution, sprays, injectant and click and enter agent, lotion, the dust agent administration, and by means of the shaping thing that contains active compound, for example by the neck ring that contains active compound, ear muff, tail note, wing band, halter, administrations such as tag device.
When giving livestock, domestic animal is during administrations such as domestic animal, the active compound of general formula (I) can be with prescription (for example powder, emulsion, the flowable materials) administration of the active compound that contains 1 to 80% amount, or directly use, or dilute by 100 to 10000 the factor, or use with the form of chemical bath.
The compound of general formula of the present invention (I) further finds to have the strong effect of killing the insect that can damage farm crop.
Following insect can be used as example and preferred example is mentioned, but without any the meaning that limits.Beetle, for example: the big ox of North America man, the Pilosis edge resembles, the furniture death watch beetle, extremely dead death watch beetle, Ptilinus pectinicornis, Dendrobium pertinex, loose death watch beetle, Priobium carpini, Lyctus brunneus Stephens, africanus powder moth, southern powder moth, bright powder moth, pubescence powder moth, Trogoxylon aequale, minthea rugicollis, material bark beetle kind, black material bark beetle kind, coffee is black long moth-eaten, and Mongolian oak is long moth-eaten, Heterobostrychusbrunneus, long moth-eaten kind, dinoderus minutus.Dermaptera, for example: big wood wasp, the big wood wasp of fir, the big wood wasp of taignus fir, the big wood wasp of augur fir.The termite subject, kalotermitid for example, flavicollis, a fiber crops heap sand termite, different termite, American-European reticulitermes flavipe, Reticulitermessantonensis, Reticulitermes lucifugus, Darwin Australia termite, nevadensis termite, Coptotermes formosanus Shtrari.Bristlefails, for example silverfish.
Industrial goods are interpreted as non-life material in this article, for example are preferably synthetic material, glue, paste, paper and cardboard, skin, wood, Wood products and coating.
The material that especially preferably prevents insect pest infestation is wood and Wood products.
Can be interpreted as construction timber for example, wooden frame with composition of the present invention or the wood and the Wood products that contain the mixture protection of this based composition; railroad tie, bridge parts, trestle; wooden wheel, axle, pallet; container, electric pole, wooden protecting jacket; timber window and timber, glued board, particle board; joiner's instrument, or be used to build house or the thin wooden very common Wood products.
Active compound can be with the form of enriched material or with common prescription, powder agent for example, and granule, solution, suspension agent, emulsifying agent, or paste uses.
The prescription of mentioning can be by the currently known methods preparation of document, for example with active compound and at least a solvent or thinner, emulsifying agent, dispersion agent, and/or tackiness agent or fixing agent, water drive is scolded agent, if appropriate with siccative and ultra-violet stabilizer, mixes with tinting material such as pigment and other auxiliary material if appropriate.
Be used to protect the insecticidal composition of timber and timber or concentrated solution to comprise active compound of the present invention, by weight, concentration is 0.0001 to 95%, is in particular 0.001 to 60%.
The consumption of composition or concentrated solution depends on the kind of the insect on the medium and the situation of insect pest takes place.The best proportion that uses can be determined according to every kind of situation of tested series.But, enough with the active compound of calculating by weight use 0.0001 to 20% of protected material in general, be preferably 0.001 to 10%.
Solvent that uses and/or thinner are the mixture of organic solvent or solvent and/or mixture and/or polar organic solvent or solvent mixture and/or water, examples of suitable emulsifiers and/or the wetting Agent for Printing Inks of oily or buttery organic solvent or low voc solvent.
The preferred organic solvent that uses is higher than 35 as evaporation number, and flash-point is higher than 30 ℃, preferably is higher than 45 ℃ oily or oil-based solvent.This class oily and the oil-based solvent that use are low as volatility, water-fast mineral oil or their aromaticity cut, or contain the solvent mixture of mineral oil, be preferably petroleum solvent, petroleum products and/or alkylbenzene.
The compound that helps using is 170 to 200 ℃ a mineral oil as boiling range, and boiling range is 170 to 220 ℃ a petroleum solvent, and boiling range is 250 to 350 ℃ a spindle oil, and boiling range is 160 to 280 ℃ petroleum products or an aromatic compound, smart terpene or the like.
Using boiling range in preferred embodiments is 180 to 210 ℃ liquid fat hydrocarbon, or boiling range is 180 to 220 ℃ aromatic hydrocarbon and high boiling mixture and/or the spindle oil and/or a chloronaphthalene of aliphatic hydrocarbon, preferably α one chloronaphthalene.
Evaporation number is higher than 35, flash-point is higher than 30 ℃, the organic oily or the oil-based solvent that are preferably the low volatility that is higher than 45 ℃ can part be replaced by the organic chemistry solvent of high or middle volatility, condition is that the evaporation number of the solvent mixture that obtains also is higher than 35, flash-point is higher than 30 ℃, preferably be higher than 45 ℃, and kill insect/fungicidal mixtures or be dissolved in this solvent mixture, maybe can be emulsifiable in this solvent mixture.
In preferred embodiments, organic chemistry solvent or solvent mixture, or the part of fatty polar organic solvent or solvent mixture is substituted.The preferred compound that uses is the fatty organic chemistry solvent of hydroxyl and/or ester and/or ether, glycol ether for example, ester or the like.
The organic chemistry tackiness agent that uses in the scope of the invention is known in synthetic resins and/or the document and energy dilute with water and/or solvable maybe can the dispersion or emulsible bonding dry oil in the organic chemistry solvent that uses, especially by following resin tackiness agent that form or that comprise following resin: acrylate resin, Vinylite, polyvinyl acetate for example, vibrin, polycondensation resin or poly-addition resin, urethane resin, the Synolac of Synolac or modification, resol, hydrocarbon resin, for example indenes/coumarone resin, silicone resin, dryness plant and/or siccative oil and/or based on the physics dry adhesive of natural and/or synthetic resins.
Synthetic resins as tackiness agent can be with emulsion, and the form of dispersion liquid or solvent is used.Pitch or pitch sample material up to 10% weight also can be used as tackiness agent.In addition, also can use tinting material, pigment, water drive is scolded agent, and smell is covered material and inhibitor or the known corrosion inhibitor of document or the like.
According to the present invention, composition or concentrated solution preferably comprise at least a as the Synolac of organic chemistry tackiness agent or the Synolac and/or the dry vegetable oil of modification.The oil-contg of the Synolac that preferably uses according to the present invention surpasses 45% by weight, is preferably 50% to 68%.
Can be fixed agent (mixture) or softening agent (mixture) of all or some tackiness agents above-mentioned replaces.The purpose of these additives is to prevent active compound volatilization and crystallization or precipitation.They preferably replace 0.01 to 30% tackiness agent (tackiness agent of use is defined as 100%).
Softening agent is from phthalate compound, for example from dibutyl phthalate, and dioctyl phthalate (DOP) or benzyl butyl phthalate, from phosphoric acid ester, tributyl phosphate for example is from adipic acid ester, hexanodioic acid two-(2-ethylhexyl) ester for example, from stearate, for example butyl stearate or amyl stearate are from oleic acid ester, butyl oleate for example, from glyceryl ether, or relative high-molecular weight glycol ether, glyceryl ester and p-toluenesulfonic esters.
The chemical fundamentals of fixing agent is the polyvinyl alkyl oxide, for example polyvinyl methyl ether, or ketone, for example benzophenone, or ethylene benzophenone.
Particularly suitable solvent or thinner or water, suitable, be water and one or more above-mentioned organic chemistry solvent or thinner, the mixture of emulsifying agent and dispersion agent.
By the operation of large-scale mill retting, vacuum operating for example, two vacuum operatings or pressurized operation can make timber reach especially effectively protection.
Suitable, the available composition can comprise other insecticide immediately, and is suitable, can contain one or more mycocide again.
The suitable extraneous component that can admix is preferably insecticide and the mycocide of mentioning in WO 94/29268.The compound of mentioning in that file is clearly with being with reference to mixing the application.
The component of admixing very particularly preferably is insecticide, for example Chlorpyrifos 94, phoxim, Silafluofin, alphamethrin, cyfluthrin, cypermethrin, deltamethrin, permethrin, imidacloprid, NI-25, flufenoxuron, hexaflumuron, and triflumuron, and mycocide, for example epoxyconazole, hexaconazole, azaconazole, propiconazole, tebuconazole, cyproconazole, metconazole, imazalil, Pecudin, tolylfluanid, 3-iodo-2-propynyl butyl carbamate, N-octyl group-isothiazoline-3-ketone and 4,5-two chloro-N-octyl group isothiazoline-3-ketone.
From the following examples preparation and the application of active compound of the present invention as can be seen.
Preparation embodiment
Example I-1
CF
2=CF-CH
2-CH
2-O-CO-OC
2H
5 (I-1)
At ice-cooled down past 6.3g (50mmol) 3,4, first Dropwise 5 .4g (50mmol) Vinyl chloroformate in the solution of 4-trifluoro fourth-3-enol and 50ml methylene dichloride, Dropwise 5 .4g (53mmol) triethylamine again.Make solution be warming up to 20 ℃, and continue to stir and spend the night.Product extracts with ethylene dichloride behind the dilute with water, the extraction liquid concentrating under reduced pressure.Residue distills under the 30mmHg column pressure, steams (3,4,4-trifluoro fourth-3-thiazolinyl) ethyl-carbonate at 80 ℃.
Output 2.9g (theoretical amount 30%).
Example I-2
(I-2)
With 3.5g (22.5mmol) isocyanic acid-2,6-difluoro phenyl ester is added to 2.8g (20mmol) 3,4, in the solution of 4-trifluoro fourth-3-enol and 20mi methylene dichloride.After 40 ℃ of stirrings were spent the night, solution with water was washed, and tells organic phase, uses anhydrous magnesium sulfate drying.Removal of solvent under reduced pressure.Residue grinds with hexanaphthene.
Output 5.4g (theoretical amount 96%).
m.p.56-60℃。Example I-3
(I-3)
10 ℃ and stir under toward 5.0g (32mmol) N, Dropwise 5 .65g (30mmol) chloroformic acid 3,4 in the solution of N-hexa-methylene hydroxyl acetamide and 3.1g (30mmol) triethylamine and 50ml methylene dichloride, 4-trifluoro fourth-3-alkene ester.Solution stirring is spent the night, and with the methylene dichloride dilution, washes with water.Tell organic phase, concentrating under reduced pressure, oily residue silica gel chromatography purifying is with chloroform/ethyl acetate (4: 1) wash-out.Obtain the carbonic ether of 4.2g (theoretical amount 45.6%) expectation, be oily matter, logp=2.47.
Obtain the compound of following general formula (I) similarly according to general preparation method: table 1
(I)
*The logarithm of the partition ratio p of logp=compound between hot alcohol and water, real by reversed-phase HPLC
Test is fixed.
Toward 10.1g (0.1mol) triethylamine, drip 3ml (0.05mmol) CS in the solution of 6.0g (0.048mol) Glycocoll hydrochloride methyl esters and 50ml tetrahydrofuran (THF) (THF) under the room temperature
2After about 25 minutes of the stirring at room, slowly add 9.45g (0.05mol) 4-bromo-1,1,2-trifluoro but-1-ene, and at room temperature continue to stir to spend the night.The pressure reducing and steaming solvent, residue dissolves in ether.Solution with water is washed 4 times, anhydrous magnesium sulfate drying, pressure reducing and steaming ether.Residue chromatogram purification (silica gel, HPLC is with 14% ethyl acetate/hexane wash-out).Get the thick product of 7.8g, wherein 4.3g is placed in the refrigerator until crystallization.Decompression is filtered fast down and is dry, obtains the above-described compound of 2.5g, is colorless solid, mp:37-39 ℃.Ultimate analysis: element calculated value measured value C 35.16 35.26H 3.69 3.70N 5.13 5.10S 23.46 23.40 example I-39
Add 6.24g (0.033mol) 4-bromo-1 under ice-cold in the solution of former potassium xanthate of 5g (0.03mol) and 35ml dimethyl formamide (DMF), 1.2-trifluoro but-1-ene continues under the room temperature to stir to spend the night.Mixture inclines in 300ml water and uses extracted with diethyl ether.Ether layer washes with water 4 times, anhydrous magnesium sulfate drying, concentrating under reduced pressure.Obtain the above-described compound of 5.52g, be limpid yellow liquid.Ultimate analysis: element calculated value measured value C 36.51 36.63H 3.94 3.97S 27.85 27.74
According to the method for example I-38, with the Glycocoll hydrochloride tert-butyl ester replacement glycine methyl ester of equivalent.
After the thick product aftertreatment that obtains with 20% ethyl acetate/hexane recrystallization 2 times.Obtain the above-described compound of 2.35g, be colorless solid, mp.70-72 ℃.Ultimate analysis: element calculated value measured value C 41.89 42.04H 5.11 5.05N 4.44 4.43S 20.33 20.27 example I-41
Steps A
41.43g (0.3mol) diethyl phosphite, 9g (0.3mol) Paraformaldehyde 96 and in 60 to 70 ℃ of heating of 3.04g (0.03mol) triethylamine.Thermopositive reaction takes place, and temperature rises to 120 to 125 ℃, and solution becomes is limpid.This solution was in 120 ℃ of stirrings 10 minutes, and cooling adds some methylene dichloride, and solution decompression concentrates.The residue drying under reduced pressure.Obtain 49.6g.Molecular formula is HO-CH
2-P (=O) (OC
2H
5)
2Compound be clarified liq.Step B
Ice-cooled down, the compound and the 20ml CS that obtain in 10g (0.059mol) steps A
2Solution in slowly add 3.89g (0.059mol) 85%KOH.Solution adds the 150ml ether in stirring at room 2 hours, continues to stir 2 hours again.The elimination precipitation is washed drying under reduced pressure with ether.Obtaining the 13.69g molecular formula is
Compound, be yellow solid.Step C
Under the room temperature,, bit by bit add the compound that obtains among 5g (0.0177mol) the step B in the solution of 2-trifluoro but-1-ene and 30mlDMF toward 4g (0.022ml) 4-bromo-1,1.The reaction mixture stirred overnight at room temperature is inclined in 300ml water and is used extracted with diethyl ether.Ether layer washes with water 4 times, and anhydrous magnesium sulfate drying concentrates.Obtain the above-described end product of 4.76g, be limpid yellow liquid.Ultimate analysis: element calculated value measured value C 34.09 34.18H 4.58 4.58S 18.20 18.14 example I-42
Ice-cooled down, the drips of solution of 10.3ml (0.078mol) bromo triethyl silicane and 10ml acetonitrile is added in the solution of the compound of 2.3g (0.0065mol) example I-41 and 15ml acetonitrile.Solution is in stirred overnight at room temperature, the pressure reducing and steaming solvent.Residue and excessive methyl alcohol stirring at room 4 hours.Pressure reducing and steaming methyl alcohol then, the product drying under reduced pressure.Obtain the above-described compound of 1.96g, be colorless solid, mp:73-75 ℃.Ultimate analysis: element calculated value measured value C 24.33 24.38H 2.72 2.70S 21.65 21.75
Use the method for example I-38, replace the Glycocoll hydrochloride methyl esters, make this compound with the equivalent hydrochloric acid sarcosine tert-butyl ester.Be colorless solid, mp:35-37 ℃.Ultimate analysis: element calculated value measured value C 43.76 43.83H 5.51 5.52N 4.25 4.23S 19.47 19.40
Example I-46
According to the method for example I-38, begin to make example I-44 from corresponding precursor, the compound of I-45 and I-46.The preparation of raw material
Ice-cooled and stir down, toward 30g (0.24mol) 3,4, logical 28g (0.28mol) phosgene in 4-trifluoro fourth-3-enol, mixture are then in 20 ℃ of restir 5 hours.After removing excessive phosgene with nitrogen bubble, the distillation of buttery residue.Obtain boiling point and be the colourless muriate 21.2g (theoretical amount 46.8%) of 72-74 ℃/100mm.
Application Example
The critical concentration test of embodiment A test method: Meloidogyne incognita solvent: the acetone emulsifying agent of 4 parts of weight: the alkylaryl polyglycol ether of 1 part of weight
Be to produce the suitable goods of active compound, the active compound of 1 part of weight and the solvent of described amount add the emulsifying agent of described amount, and enriched material is diluted with water to desired concn.
The goods of active compound with closely mixed by the soil of nematode severe contamination to be measured.The concentration of the active compound in the goods does not have actual importance, the amount of the compound of per unit volume only, with ppm (=mg/l) provide, be determinative.The soil of handling is transferred in the pot and is sowed lettuce, and the greenhouse keeps 25 ℃.
The nematode (root nodule) of three weeks back inspection lettuce root parasitism, the degree of functioning of active compound is represented with percentage ratio.If prevent parasitism fully, degree of functioning is 100% so, if parasitic level with not with medicinal treatment but the plant of the equal contrast of soil pollution degree is the same, degree of functioning is 0% so.In this test, for example preparing the degree of functioning that the compound of example I-4 and I-5 shows under the illustration activity compound concentration of 20ppm is 100%.
Embodiment B
Larva test solvent: 7 parts of weight dimethyl formamide emulsifying agents: 1 part of weight alkylaryl polyglycol ether
For producing the goods of suitable active compound, the emulsifier mix of the active compound of 1 part of weight and the solvent of described amount and described amount, enriched material is diluted with water to desired concn.
Dish leaf (Brassica oleracea) injects the goods of the active compound of desired concn with injection method, and with mustard beetle larva (phaedon larva) parasitism, the dish leaf still keeps humidity.
After the special time cycle, measure destructive percentage ratio.100% refers to that all mustard beetle larvas all are killed; 0% refers to that all mustard beetle larvas have no injury.In this test, the compound that for example prepares example I-6 after 7 days produces 100% destruction to larva as illustrative active compound under 0.1% concentration.
Embodiment C plutella test solvent: 7 parts of weight dimethyl formamide emulsifying agents: 1 part of weight alkylaryl polyglycol ether
For producing the goods of suitable active compound, the emulsifier mix of the active compound of 1 part of weight and the solvent of described amount and described amount, enriched material is diluted with water to desired concn.
Dish leaf (Brassica oleracea) injects the goods of the active compound of desired concn, the Candle-sticks (plutella maculipcnnis) of thin silk fabric line back of the body moth on the parasitism when leaf is still moist with injection method.
After the specific time cycle, measure the percentage ratio that Candle-sticks damages.All Candle-sticks are killed and are decided to be 100%; None Candle-sticks is killed and is decided to be 0%.
In this test, after 7 days, for example prepare example I-2, I-4, I-5, I-6 and I-8 are as illustrative active compound, and concentration is that 0.1% o'clock kill ratio to Candle-sticks reaches 100%.Embodiment DSpodoptera test solvent: 7 parts of weight dimethyl formamide emulsifying agents: 1 part of weight alkylaryl polyglycol ether
For producing the goods of suitable active compound, the emulsifier mix of the active compound of 1 part of weight and the solvent of described amount and described amount, enriched material is diluted with water to required concentration.
Dish leaf (Brassica oleracea) injects the goods of the active compound of desired concn with injection method, when the dish leaf is still moist with the Candle-sticks parasitism of owlet moth (Spodoptera frugiperda).
After the specific time cycle, measure the percentage ratio that Candle-sticks damages.All Candle-sticks are killed and are decided to be 100%; None Candle-sticks is killed and is decided to be 0%.
In this test, after 7 days, the compound that for example prepares example I-5 and I-7 is as illustrative active compound, and concentration is that 0.1% o'clock kill ratio to Candle-sticks reaches 100%.
Embodiment E Nephotettix test solvent: 7 parts of weight dimethyl formamide emulsifying agents: 1 part of weight alkylaryl polyglycol ether
For producing the goods of suitable active compound, the emulsifier mix of the active compound of 1 part of weight and the solvent of described amount and described amount, enriched material is diluted with water to desired concn.
Paddy rice seedling (Oryzae sative) injects the active ingredient Tetramune of desired concn with injection method, when rice shoot is still moist with larva (incticeps) parasitism of clear water rice leaf springtail (Nophotettix).
After the time cycle of expectation, measure the percentage ratio that kills larva.The larva of all leaf springtails all is killed and is decided to be 100%, does not have a larva to be killed and is decided to be 0%.
In this experiment, after 6 days, for example prepare example I-2, I-4, I-5, I-6, the compound of I-7 and I-8 are as illustrative active compound, and concentration is 0.1% o'clock, and the kill ratio of springtail larva is reached 100%.
Embodiment F
Test with the drug-fast Parkhurst strain of boophilus microplus resistance/SP-.Experimental animal: the adult female tick solvent of having sucked blood: the ethylene glycol monomethyl ether emulsifying agent of 35 parts of weight: the Nonylphenyl Ether of 35 parts of weight
For producing suitable prescription, the active compound of 3 parts of weight mixes with the solvent-emulsifier mixture of 7 parts of weight pointing out above, and enriched material is diluted with water to desired concn.
10 adult Boophilus microplus res. flooded 1 minute in tested active compound.After transferring in the plastic cup and in the environmental chamber of control, preserving, record the degree that cicada is damaged.
100% is decided to be all ticks all is killed; 0% is decided to be the none tick is killed.In this test, for example prepare example I-5, the compound of I-6 and I-7 is as illustrative active compound, when concentration is 1000ppm, the kill ratio of tick reached 100%.
Embodiment G
With blow fly larva test/growth-restraining effect experimental animal: lucilia cuprina larva solvent: 25 parts of weight ethylene glycol monomethyl ether emulsifying agents: 35 parts of weight nonyl phenol polyglycol ethers
For producing suitable prescription, the active compound of 3 parts of weight mixes with the solvent-emulsifier of 7 parts of weight pointing out above, and the dense emulsion that water will obtain is diluted to desired concn.
In the test tube that about 1cm3 horseflesh and 0.5ml active ingredient Tetramune to be measured is housed, introduce about 20 larvas.After 24 hours and 48 hours, measure the activity of active ingredient Tetramune.With test tube transfer to husky shop fixtures the cup in.After 2 days, remove test tube, pupa is counted.
Judge the activity of active ingredient Tetramune with 1.5 times of fly numbers of hatching afterwards of untreated contrast development time.No fly hatches and is decided to be 100%; All flies all normally hatch and are decided to be 0%.
In this test, for example prepare example I-1, the compound of I-4 and I-8, is ruined the pupa rate and is reached 100% when concentration is 1000ppm as illustrative active compound.
Embodiment H nematicide test (potato and soybean)
United States Patent (USP) 5,389 is pressed in this test, and 680 carry out.This specification sheets clearly enrolls the application.
In this experiment (method 2), the activity that the compound of preparation example I-39 shows when every pot of 1mg concentration is 91 to 100%, and the activity that shows when every pot of 0.2mg concentration is 75 to 90%, the active less than 50% that shows when every pot of 0.04mg concentration.
Claims (11)
1. the compound of general formula (I)
(I) R wherein
1Be hydrogen or halogen and R
2For group (a) or (b)
(a) or
(b) wherein Y is oxygen or sulphur, and Z is oxygen, sulphur or NR
4, R
3Be hydrogen or the random alkyl that replaces, thiazolinyl, cycloalkyl, aryl, aralkyl, carbalkoxy, aryloxy carbonyl, arylsulfonyl or heteroaryl, and R
4Be hydrogen or the random respectively aryl that replaces, alkylthio, thiazolinyl, cycloalkyl, aryl, aralkyl, heteroaryl, or R
3And R
4One of the nitrogen-atoms that links to each other with them forms the ring that arbitrarily contains oxygen, sulphur or nitrogen (this nitrogen is arbitrarily by alkyl, and aryl or aralkyl replaces) that arbitrarily replaces, or is group (C)
(c) wherein V is oxygen or NR
6And R
5And R
6Independent separately is hydrogen, the fatty group of 1 to 12 carbon atom, and aromatic base or heterocyclic radical, they each all arbitrarily replaced by at least one substituting group, substituting group is from alkyl, and cyano group is trimethyl silicon based, hydroxyl, alkoxyl group, halogen, nitro, amino, alkylamino, dialkyl amido, SH, alkylthio, phenyl, or by the carboxylic acid group, sulfonic group, phosphate or phosphorous acid base or these sour esters, thioesters or acid amides replace, and this acid amides is arbitrarily replaced or two replacement by the alkyl list, or R
5And R
6One of the nitrogen-atoms that links to each other with them forms monoamino-acid or arbitrarily contains oxygen in addition, the heterocyclic radical of sulphur or nitrogen, they each all arbitrarily by alkyl, cyano group, trimethyl silicon based, hydroxyl, alkoxyl group, halogen, nitro, amino, alkylamino, dialkyl amido, SH, alkylthio, phenyl or carboxylic acid group, sulfonic group, phosphate or phosphorous acid base or these sour esters, thioesters or amide group list replace, and this amide group is arbitrarily replaced or two replacement by the alkyl list, or R
5Be OR
7, COR
7, NR
7R
8, SO
2R
9Or P (=O) R
10R
11One of base, R in all cases
6Be hydrogen, R
7And R
8Independent separately is hydrogen, alkyl or aryl, R
9Be hydrogen, alkyl, haloalkyl or aryl, and R
10And R
11Independent separately is hydrogen, alkyl, and aryl, alkoxyl group, aryloxy, alkylthio, arylthio, amino, alkylamino, dialkyl amido or virtue are amino, and their salt.
5. the general formula (Ia) or (Ib) method of compound of preparation claim 2 is characterized in that A) the fluorine butenol of general formula (II)
(II) R wherein
1Implication with claim 1 and following compound reaction alpha) react in the presence of the alkali at thinner with being intended to the compound of general formula (III)
(III) wherein Y, Z and R
3Implication with claim 1, or β) with different (sulphur) cyanate of general formula (IV) thinner and be intended to catalyzer in the presence of react,
YCN-R
3(IV) or B) the fluorine butylene mercaptan of general formula (IIa)
(IIa) R wherein
1The same compound with general formula (IIIa) of implication thinner or be intended to alkali in the presence of react,
(IIIa) wherein Y and R
3Implication the same, or C) compound of logical formula V
(V) R wherein
1The compound of and general formula (VI) the same with the implication of Y thinner or be intended to alkali in the presence of react,
H-Z-R
3(VI) wherein Z and R
3Implication the same, or D) compound of general formula (VII)
(VII) R wherein
1The same with the implication of Y, with the compound of general formula (VIII) at thinner or with being intended to reaction in the presence of the alkali,
H-S-R
3(VIII) R wherein
3Implication the same.
8. sterilant is characterized in that they comprise the compound of the general formula of at least a claim 1 (I).
9. use the compound control animal pest of the general formula (I) of claim 1.
10. the method for control animal pest, the compound that it is characterized in that general formula (I) according to claim 1 make it act on that insect goes up and/or their habitat on.
11. the method for compositions of preparation control animal pest is characterized in that the compound of the general formula (I) according to claim 1 mixes with spreading agent and/or tensio-active agent.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/003,987 | 1993-01-15 | ||
DEP4439335.0 | 1994-11-04 | ||
DE4439335A DE4439335A1 (en) | 1994-11-04 | 1994-11-04 | Carbonic acid and carbamic acid fluorobutenyl esters |
US398795P | 1995-10-06 | 1995-10-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1171775A true CN1171775A (en) | 1998-01-28 |
Family
ID=25941669
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN95197158A Pending CN1171775A (en) | 1994-11-04 | 1995-11-02 | Fluorobutenyl esters |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0789683A1 (en) |
JP (1) | JPH10508592A (en) |
CN (1) | CN1171775A (en) |
AU (1) | AU3927195A (en) |
BR (1) | BR9509592A (en) |
CA (1) | CA2204241A1 (en) |
DE (1) | DE4439335A1 (en) |
FI (1) | FI971863A (en) |
HU (1) | HUT77297A (en) |
NO (1) | NO971767L (en) |
WO (1) | WO1996014289A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5866711A (en) * | 1996-09-13 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Fluorocyanate and fluorocarbamate monomers and polymers thereof |
JPWO2004108662A1 (en) * | 2003-05-15 | 2006-07-20 | クミアイ化学工業株式会社 | Phenylsulfonyl carbamate derivatives and plant disease control agents for agriculture and horticulture |
CN116583541A (en) * | 2021-09-24 | 2023-08-11 | 宁德时代新能源科技股份有限公司 | Binder compound, conductive binder, and secondary battery comprising same |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3689662A (en) * | 1970-12-10 | 1972-09-05 | Wayne C Jaeschke | Nematocidel use of 3,4,4-trifluoro-3-butenylthio methylidene compounds |
US4748186A (en) * | 1986-06-30 | 1988-05-31 | Fmc Corporation | S-trifluorobutenyl derivatives and pesticidal uses thereof |
-
1994
- 1994-11-04 DE DE4439335A patent/DE4439335A1/en not_active Withdrawn
-
1995
- 1995-11-02 BR BR9509592A patent/BR9509592A/en unknown
- 1995-11-02 EP EP95937045A patent/EP0789683A1/en not_active Withdrawn
- 1995-11-02 HU HU9702041A patent/HUT77297A/en unknown
- 1995-11-02 WO PCT/EP1995/004298 patent/WO1996014289A1/en not_active Application Discontinuation
- 1995-11-02 CN CN95197158A patent/CN1171775A/en active Pending
- 1995-11-02 AU AU39271/95A patent/AU3927195A/en not_active Abandoned
- 1995-11-02 JP JP8515039A patent/JPH10508592A/en active Pending
- 1995-11-02 CA CA002204241A patent/CA2204241A1/en not_active Abandoned
-
1997
- 1997-04-17 NO NO971767A patent/NO971767L/en unknown
- 1997-04-30 FI FI971863A patent/FI971863A/en unknown
Also Published As
Publication number | Publication date |
---|---|
AU3927195A (en) | 1996-05-31 |
FI971863A0 (en) | 1997-04-30 |
HUT77297A (en) | 1998-03-30 |
NO971767D0 (en) | 1997-04-17 |
MX9703193A (en) | 1997-11-29 |
DE4439335A1 (en) | 1996-05-09 |
NO971767L (en) | 1997-04-17 |
BR9509592A (en) | 1997-09-30 |
JPH10508592A (en) | 1998-08-25 |
EP0789683A1 (en) | 1997-08-20 |
WO1996014289A1 (en) | 1996-05-17 |
CA2204241A1 (en) | 1996-05-17 |
FI971863A (en) | 1997-04-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1071749C (en) | Acylated 5-aminoisothiazoles with insecticidal properties, intermediate products and process for producing them | |
CN1204313A (en) | Cyclopentane-1,3-dione derivatives | |
CN1208408A (en) | Acylated 5-amino-1,2,4-thiadiazoles as pesticides and fungicides | |
CN1100768C (en) | Substituted diphenyl oxazolines | |
US5973162A (en) | Substituted thiazolines and their use for controlling animal pests | |
CN1225632A (en) | Substituted N-(5-isothiazolyl)-thioamides | |
CN1171775A (en) | Fluorobutenyl esters | |
CN1113238A (en) | Substituted pyrazoline derivatives | |
CN1232464A (en) | Substd. N-isothiazolyl-(thio) amides | |
CN1200109A (en) | Fluorobutene acid amides | |
CN1234681C (en) | Amino acid derivatives and their use as pesticides | |
CN1285827A (en) | Substituted guanidine derivatives | |
CN1311780A (en) | Substituted 3-thiocarbamoylpyrazoles | |
CN1172479A (en) | Acylated 5 -aminopyrazoles | |
EP0635500B1 (en) | 5,6-Dihydro-(4H)1,3-oxazine and -thiazine derivatives as insecticides | |
CN1071322C (en) | Process for producing 5,6-dihydro-1,3-oxazines | |
CN1151404A (en) | Substituted tetrahydro-5-nitro-pyrimidines | |
CN1309643A (en) | Diphenylimidazolines | |
EP0970059B1 (en) | Disubstituted biphenyloxazolines | |
CN1211245A (en) | Salts from imidazoline derivatives and their use as a parasite control agent | |
CN1193320A (en) | 1,3-oxa(thio) zine derivatives | |
CN1309650A (en) | Substd. diphenyl oxazolin derivs. with insecticidal effect | |
CN1049894C (en) | Substd. (1,4)-dioxino[2,3-F] benzoimidazole derivs. and their use in pest control | |
CN1126200A (en) | Sulfamide derivatives | |
CN1194638A (en) | Substituted cyanophenyl uracils |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C01 | Deemed withdrawal of patent application (patent law 1993) | ||
WD01 | Invention patent application deemed withdrawn after publication | ||
REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1049990 Country of ref document: HK |