CN117138452A - Process and device for efficiently disposing and utilizing causticized slag - Google Patents

Process and device for efficiently disposing and utilizing causticized slag Download PDF

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Publication number
CN117138452A
CN117138452A CN202311358107.9A CN202311358107A CN117138452A CN 117138452 A CN117138452 A CN 117138452A CN 202311358107 A CN202311358107 A CN 202311358107A CN 117138452 A CN117138452 A CN 117138452A
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CN
China
Prior art keywords
tank
washing
separation
separation sedimentation
washing separation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311358107.9A
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Chinese (zh)
Inventor
张天星
孙明坤
曾宪飞
肖正城
王敬福
杨志卿
张扬
蔡娅欣
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Guizhou Huajin Aluminum Co ltd
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Guizhou Huajin Aluminum Co ltd
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Application filed by Guizhou Huajin Aluminum Co ltd filed Critical Guizhou Huajin Aluminum Co ltd
Priority to CN202311358107.9A priority Critical patent/CN117138452A/en
Publication of CN117138452A publication Critical patent/CN117138452A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00Compounds of aluminium
    • C01F7/02Aluminium oxide; Aluminium hydroxide; Aluminates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D36/00Filter circuits or combinations of filters with other separating devices
    • B01D36/04Combinations of filters with settling tanks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/90Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms 
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/80Mixing plants; Combinations of mixers
    • B01F33/81Combinations of similar mixers, e.g. with rotary stirring devices in two or more receptacles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B2101/00Type of solid waste
    • B09B2101/55Slag

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a process and a device for efficiently disposing and utilizing causticized slag, which comprises the following steps: step 1, conveying causticized slurry of a causticized discharging chute to a separation sedimentation device through a pump for sedimentation separation, wherein an overflow pipe of the separation sedimentation device is connected to a decomposition system or an evaporation stock solution system, and an underflow of the separation sedimentation device is connected to filter pressing and then connected to a washing separation sedimentation tank group for washing separation sedimentation; step 2, sequentially conveying the underflow to the next washing separation sedimentation tank by the washing separation sedimentation tank in the washing separation sedimentation tank group; step 3, conveying the underflow precipitate of the tail tank of the washing separation sedimentation tank group to an abrasive machine for processing and fine grinding; step 4, conveying the materials ground by the grinding machine to a pulping groove for pulping; step 5, delivering the slurry prepared by the pulping tank to a thermoelectric desulfurization tower for desulfurization; the invention can utilize the precipitate after causticizing separation, can realize the reutilization of waste resources, changes waste into valuable, and reduces the production cost of enterprises.

Description

Process and device for efficiently disposing and utilizing causticized slag
Technical Field
The invention relates to a process and a device for efficiently disposing and utilizing causticized slag, belonging to the technical field of alumina production.
Background
Along with the gradual depletion of bauxite grade, the impurity content in the ore is gradually increased, and particularly the increasing trend of the impurity content of carbonate in the ore is obvious, in the Bayer process alumina production process, the carbonate in the bauxite enters a Bayer process sodium aluminate solution system in a sodium carbonate form, so that the concentration of the sodium carbonate in the sodium aluminate solution is continuously accumulated, and the operation and consumption of the Bayer process alumina production are seriously influenced. In order to alleviate the influence of sodium carbonate on alumina production, salt elimination causticizing treatment is needed, and sodium carbonate obtained by salt elimination is led to form calcium carbonate sediment through lime milk causticizing to be discharged from a Bayer process system, and calcium aluminate is generated in the causticizing process, so that excessive lime milk is generally required to be added, and unreacted lime milk exists in causticized solids. From this, the solid phase material obtained by salt removal causticization is conventionally called causticized slag from a multiphase system of calcium carbonate, calcium sulfate, residual calcium hydroxide and the like. In the existing alumina production process, the discharged slurry of the causticizing tank is separated and settled firstly, and overflows and is led into a decomposition system or an evaporation stock solution system after separation and settlement, and the underflow sediment is sent to a red mud storage yard for storage through a red mud discharging system, so that when the waste is treated, the red mud storage quantity is increased, and meanwhile, the resource waste is caused.
Therefore, a process and a device for efficiently disposing and utilizing causticized slag are needed, solid precipitates after causticization and separation can be utilized, waste resources are recycled, and waste materials are changed into valuable materials, so that the production cost of enterprises is reduced.
Disclosure of Invention
In view of the above, the invention aims to provide a process and a device for efficiently disposing and utilizing causticized slag, which can utilize solid precipitates after causticization and separation, realize reutilization of waste resources, change waste into valuable, and reduce the production cost of enterprises; can overcome the defects of the prior art.
The invention aims at realizing the following technical scheme:
the invention discloses a process for efficiently disposing and utilizing causticized slag, which comprises the following steps: step 1, conveying the bottom flow of the causticizing discharge chute to a separation sedimentation device through a pump for sedimentation separation, wherein an overflow pipe of the separation sedimentation device is connected to a decomposition system or an evaporation stock solution system, and the bottom flow of the separation sedimentation device is connected to a washing separation sedimentation tank group after being subjected to filter pressing through a filter press for washing separation sedimentation; step 2, sequentially conveying the underflow to the next washing separation sedimentation tank by the washing separation sedimentation tank in the washing separation sedimentation tank group; step 3, conveying the underflow precipitate of the tail tank of the washing separation sedimentation tank group to an abrasive machine for processing and fine grinding; step 4, conveying the materials ground by the grinding machine to a pulping groove for pulping; and 5, conveying the slurry prepared by the pulping tank to a thermoelectric desulfurization tower for desulfurization.
And adding water into the tail tank of the washing separation sedimentation tank group to sequentially perform reverse washing, and finally merging overflow washing liquid of the washing separation first tank of the washing separation sedimentation tank group into the alumina red mud washing sedimentation system.
The device for efficiently disposing and utilizing the causticized slag comprises a causticized discharging groove, wherein the causticized discharging groove is connected with a separation sedimentation device, an overflow pipe connected to a decomposition system or an evaporation stock solution system and an underflow calandria connected with a washing separation sedimentation groove group are arranged on the separation sedimentation device, the underflow calandria is arranged in a tail groove of the washing separation sedimentation groove group and is connected with an abrasive machine, and the abrasive machine is sequentially connected with a pulping groove and a thermoelectric desulfurization tower.
The above-mentioned, the washing separation settling tank in the washing separation settling tank group is equipped with a feeding pipe for conveying the underflow to the next washing separation settling tank and an overflow drain pipe for conveying the overflow to the previous washing separation settling tank, and the feeding pipe and the overflow pipe are respectively equipped with a hydraulic pump.
The tail tank of the washing separation sedimentation tank group is provided with a water adding pipe and an overflow drain pipe, and the overflow drain pipe is sequentially connected to the washing separation head tank of the previous washing separation sedimentation tank.
The filter press is arranged between the separation sedimentation device and the washing separation head tank.
Compared with the prior art, the invention has the beneficial effects that:
1. the invention firstly separates and settles the discharged material of the causticizing discharging chute through a separation and settling device, and conveys the overflow of the separation and settling device to a decomposition system or an evaporation stock solution system, and for the precipitate of the separation and settling device, the precipitate is conveyed to a washing and separation and settling tank group for washing and separation and settling, causticizing slag and alkaline liquor are washed and returned to an alumina production flow, causticizing slag substances of a tail tank are processed and finely ground, and then qualified slurry is prepared and conveyed to a thermoelectric desulfurization tower for desulfurization so as to replace the use of thermoelectric desulfurization limestone powder, thereby realizing the reutilization of causticizing slag waste resources and reducing the production cost.
2. The causticized slag after washing, separating and settling is utilized, so that the waste of resources can be avoided, the storage of the causticized slag in a red mud storage yard can be avoided, and the desulfurization can be performed by combining an alumina production system.
3. The washing separation settling tank in the washing separation settling tank group is provided with a feeding pipe for conveying the underflow to the next washing separation settling tank and an overflow discharge pipe for conveying the overflow to the previous washing separation settling tank, and the feeding pipe and the overflow pipe are respectively provided with a hydraulic pump. The caustic slag is washed and returned to the production flow by reverse washing, separation and sedimentation, so that the alkali loss of the production system is reduced.
4. The calcium carbonate, the calcium oxide and a small amount of attached sodium oxide in the causticized slag are desulfurized through the thermoelectric desulfurization tower, so that limestone powder desulfurization can be completely replaced, and further, the deep fusion utilization of waste resources of an alumina system and the thermoelectric desulfurization system is realized, so that the production cost is reduced.
5. A filter press is arranged between the separation sedimentation device and the washing separation first tank, so that the underflow separated by the separation sedimentation device can be filtered and then sent to the subsequent washing.
Additional advantages, objects, and features of the invention will be set forth in part in the description which follows and in part will become apparent to those having ordinary skill in the art upon examination of the following or may be learned from practice of the invention. The objects and other advantages of the invention may be realized and obtained by means of the instrumentalities and combinations particularly pointed out in the specification.
Drawings
For the purpose of making the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings, in which:
fig. 1 is a schematic diagram of a connection structure according to the present invention.
Wherein the discharge chute 1 is causticized; a separation sedimentation device 2; washing and separating the sedimentation tank group 3; an underflow calandria 4; a tail groove 5; an abrasive machine 6; a pulping tank 7; a thermoelectric desulfurizing tower 8; washing and separating the first groove 9; a filter press 10.
Detailed Description
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. It should be understood that the preferred embodiments are presented by way of illustration only and not by way of limitation.
As shown in fig. 1, the process for efficiently disposing and utilizing causticized slag disclosed by the invention is characterized by comprising the following steps:
step 1, conveying the bottom flow of the causticizing discharge chute 1 to a separation sedimentation device 2 through a pump for sedimentation separation, connecting an overflow pipe of the separation sedimentation device 2 to a decomposition system or an evaporation stock solution system, and connecting the bottom flow of the separation sedimentation device 2 to a washing separation sedimentation tank group 3 after press filtration through a press filter 10 for washing separation sedimentation;
step 2, sequentially conveying the underflow to the next washing separation sedimentation tank by the washing separation sedimentation tank in the washing separation sedimentation tank group 3;
step 3, conveying the underflow precipitate of the tail tank 5 of the washing separation sedimentation tank group to an abrasive machine 6 for fine grinding; adding water into the tail tank 5 of the washing separation sedimentation tank group 3 to perform reverse washing in sequence, and finally merging overflow washing liquid of the washing separation head tank 9 of the washing separation sedimentation tank group 3 into an alumina red mud washing sedimentation system;
step 4, conveying the materials ground by the grinding machine 6 to a pulping groove 7 for pulping;
and 5, conveying the slurry prepared in the pulping tank 7 to a thermoelectric desulfurization tower 8 for desulfurization.
This structure, the device that the high-efficient disposal utilized of causticization sediment, it includes causticization blown down tank 1, and causticization blown down tank 1 is connected with separation sedimentation device 2, has the overflow pipe that is connected to decomposition system or evaporation stoste system and the underflow calandria 4 of being connected with washing separation sedimentation tank group 3 on separation sedimentation device 2, its characterized in that: the tail tank 5 of the washing separation sedimentation tank group 3 is provided with an underflow calandria 4, the underflow calandria 4 is connected with a grinding machine 6, and the grinding machine 6 is sequentially connected with a pulping tank 7 and a thermoelectric desulfurization tower 8.
Furthermore, a feeding pipe and an overflow drain pipe for conveying the underflow to the next washing separation sedimentation tank are arranged on the washing separation sedimentation tank in the washing separation sedimentation tank group 3, and hydraulic pumps are arranged on the feeding pipe and the overflow drain pipe.
Further, a water supply pipe and an overflow drain pipe are provided in the tail tank 5 of the washing separation settling tank group 3, and the overflow drain pipe is sequentially connected to the previous washing separation tank of the washing separation settling tank group 3 and finally connected to the washing separation head tank 9.
Further, a filter press 10 is provided between the separation settling device 2 and the wash separation head tank 9, so that the underflow separated by the separation settling device 2 can be filtered and then sent to the subsequent wash.
When the alkaline slurry is used, the discharged materials of the causticizing discharging chute 1 are separated and settled through the separation and settlement device 2, the overflow of the separation and settlement device 1 is conveyed to a decomposition system for decomposition and utilization, the precipitate of the separation and settlement device 1 is conveyed to the washing and separation and settlement tank group 3 for washing and separation and settlement, the precipitate with the main component of the tail tank 5 being alkali is ground, then the slurry is prepared, the prepared alkaline slurry is utilized for neutralization and desulfurization with sulfur of the thermoelectric desulfurization tower 8, so that the alkaline can be recovered, and the alkaline slurry can be combined with the thermoelectric desulfurization tower for desulfurization, and the production cost is reduced in an alumina production system with huge flow.
The foregoing description is only a preferred embodiment of the present invention, and is not intended to limit the present invention in any way, and any simple modification, equivalent variations and modification made to the above embodiment according to the technical matter of the present invention without departing from the technical scope of the present invention still fall within the scope of the technical scheme of the present invention.

Claims (6)

1. The process for efficiently disposing and utilizing the causticized slag is characterized by comprising the following steps of:
step 1, conveying the bottom flow of the causticizing discharge chute (1) to a separation sedimentation device (2) through a pump for sedimentation separation, wherein an overflow pipe of the separation sedimentation device (2) is connected to a decomposition system or an evaporation stock solution system, and the bottom flow of the separation sedimentation device (2) is connected to a washing separation sedimentation tank group (3) after being subjected to filter pressing through a filter press (10) for washing separation sedimentation;
step 2, sequentially conveying the underflow to the next washing separation sedimentation tank by using the washing separation sedimentation tanks in the washing separation sedimentation tank group (3);
step 3, conveying the underflow precipitate of the tail tank (5) of the washing separation sedimentation tank group to an abrasive machine (6) for fine grinding;
step 4, conveying the ground materials of the grinding machine (6) to a pulping groove (7) for pulping;
and 5, conveying the slurry prepared by the pulping tank (7) to a thermoelectric desulfurization tower (8) for desulfurization.
2. The process for efficiently treating and utilizing causticized slag according to claim 1, wherein: and adding water into the tail tank (5) of the washing separation sedimentation tank group (3) to perform reverse washing in turn, and finally merging overflow washing liquid of the washing separation first tank (9) of the washing separation sedimentation tank group (3) into the alumina red mud washing sedimentation system.
3. The utility model provides a device that high-efficient disposal utilized of causticization sediment, it includes causticization blown down tank (1), and causticization blown down tank (1) are connected with separation sedimentation device (2), have on separation sedimentation device (2) to be connected to the overflow pipe of decomposition system or evaporation stoste system and with washing separation sedimentation tank group (3) be connected underflow calandria (4), its characterized in that: the tail tank (5) of the washing separation sedimentation tank group (3) is provided with an underflow calandria (4), the underflow calandria (4) is connected with a grinding machine (6), and the grinding machine (6) is sequentially connected with a pulping tank (7) and a thermoelectric desulfurization tower (8).
4. The apparatus for efficiently treating and utilizing causticized slag according to claim 3, wherein: the washing separation settling tank in the washing separation settling tank group (3) is provided with a feeding pipe and an overflow drain pipe for conveying the underflow to the next washing separation settling tank, and the feeding pipe and the overflow drain pipe are respectively provided with a hydraulic pump.
5. The apparatus for efficiently treating and utilizing causticized slag according to claim 3, wherein: the tail tank (5) of the washing separation sedimentation tank group (3) is provided with a water adding pipe and an overflow drain pipe, and the overflow drain pipe is sequentially connected to the previous washing separation tank of the washing separation sedimentation tank group (3) and finally connected to the washing separation head tank (9).
6. The apparatus for efficiently treating and utilizing causticized slag according to claim 3, wherein: a filter press (10) is arranged between the separation sedimentation device (2) and the washing separation head tank (9).
CN202311358107.9A 2023-10-19 2023-10-19 Process and device for efficiently disposing and utilizing causticized slag Pending CN117138452A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311358107.9A CN117138452A (en) 2023-10-19 2023-10-19 Process and device for efficiently disposing and utilizing causticized slag

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311358107.9A CN117138452A (en) 2023-10-19 2023-10-19 Process and device for efficiently disposing and utilizing causticized slag

Publications (1)

Publication Number Publication Date
CN117138452A true CN117138452A (en) 2023-12-01

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ID=88912278

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202311358107.9A Pending CN117138452A (en) 2023-10-19 2023-10-19 Process and device for efficiently disposing and utilizing causticized slag

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