CN117125911A - Fly ash-metakaolin-based conductive geopolymer and preparation method thereof - Google Patents
Fly ash-metakaolin-based conductive geopolymer and preparation method thereof Download PDFInfo
- Publication number
- CN117125911A CN117125911A CN202311185641.4A CN202311185641A CN117125911A CN 117125911 A CN117125911 A CN 117125911A CN 202311185641 A CN202311185641 A CN 202311185641A CN 117125911 A CN117125911 A CN 117125911A
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- metakaolin
- fly ash
- percent
- geopolymer
- carbon fiber
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- 229920000876 geopolymer Polymers 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title abstract description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 42
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 30
- 239000004917 carbon fiber Substances 0.000 claims abstract description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000010881 fly ash Substances 0.000 claims abstract description 26
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 14
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 229920002545 silicone oil Polymers 0.000 claims abstract description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 14
- 239000002002 slurry Substances 0.000 claims abstract description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000010703 silicon Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000005303 weighing Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 4
- 239000002985 plastic film Substances 0.000 claims description 4
- 229920006255 plastic film Polymers 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000001723 curing Methods 0.000 abstract description 28
- 239000004566 building material Substances 0.000 abstract description 7
- 239000007864 aqueous solution Substances 0.000 abstract description 2
- 238000001746 injection moulding Methods 0.000 abstract description 2
- 230000000704 physical effect Effects 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 8
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229940083037 simethicone Drugs 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000004568 cement Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011150 reinforced concrete Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000003469 silicate cement Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
- C04B12/005—Geopolymer cements, e.g. reaction products of aluminosilicates with alkali metal hydroxides or silicates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Abstract
The invention discloses a fly ash-metakaolin-based conductive geopolymer and a preparation method thereof, belonging to the technical field of functional building materials. The preparation method comprises the following steps: fly ash, metakaolin, liquid sodium silicate, sodium hydroxide, chopped carbon fiber, water, dimethyl silicone oil and an organosilicon coupling agent; the mass ratio of the fly ash to the metakaolin is 3:2; the dosages of the liquid sodium silicate, the sodium hydroxide, the chopped carbon fiber, the water, the dimethyl silicone oil and the organic silicon coupling agent are respectively 76.50 percent, 14.00 percent, 0.25 to 2.00 percent, 0.30 to 11.60 percent, 2.00 to 8.00 percent and 1.00 percent of the total mass of the fly ash and the metakaolin; the invention mixes the fly ash, metakaolin and chopped carbon fiber uniformly, then adds the aqueous solution of liquid sodium silicate, sodium hydroxide, dimethyl silicone oil and organosilicon coupling agent, and stirs into uniform slurry, and the conductive geopolymer obtained through injection molding, shaping and curing has excellent physical properties, high hydrophobicity, high conductivity and excellent comprehensive properties.
Description
Technical Field
The invention relates to the technical field of functional building materials, in particular to a fly ash-metakaolin-based conductive geopolymer and a preparation method thereof.
Background
In recent years, functional building materials include not only coating materials, sealing materials, and porous insulating materials applied to the field of building materials, but also cathodic protection materials gradually applied to energy-oriented materials such as conductive materials, electromagnetic field interference, electrostatic discharge, and reinforced concrete structures. However, most of the current researches on functional building materials are focused on cement-based conductive concrete prepared by replacing part of the aggregate with a conductive medium.
The existing common conductive phase materials are mainly graphite, steel fibers, carbon black and chopped carbon fibers. When the conductive building material is prepared and graphite is used as a conductive phase, the sample has good conductivity only when a sufficient amount of graphite is added into a matrix, so that the compressive strength of the sample is greatly reduced, and the practicability is reduced; when the steel fiber is used as a conductive phase, although the mechanical strength of the sample can be increased, the resistivity of the sample is unstable for a long time, and the problems that the steel fiber is easy to agglomerate due to large doping amount and the conductive grid is difficult to form due to small doping amount of the steel fiber exist; the particle size of the carbon black and the presence of reactive groups on the surface of the carbon black affect the conductivity of the sample. In contrast, the chopped carbon fiber is doped as a conductive phase, so that not only can the toughness of a sample be enhanced and the compressive strength of the sample be improved, but also a good conductive network structure can be formed when the doping amount of the chopped carbon fiber is small.
Compared with cement-based conductive concrete, the geopolymer has great advantages in the aspects of technological performance, mechanical performance, flame retardant performance and environmental protection performance, has wide application prospect, and is one of the best materials for replacing silicate cement in the future. Therefore, the invention provides a fly ash-metakaolin-based conductive geopolymer and a preparation method thereof.
Disclosure of Invention
The invention aims to provide a fly ash-metakaolin-based conductive geopolymer and a preparation method thereof, wherein the preparation method is simple in preparation process, low in raw material price, energy-saving and environment-friendly, and the prepared polymer material has high hydrophobicity, high conductivity and excellent comprehensive performance.
In order to achieve the above purpose, the invention provides a fly ash-metakaolin-based conductive geopolymer, which comprises the following raw materials: fly ash, metakaolin, liquid sodium silicate, sodium hydroxide, chopped carbon fiber, water, dimethyl silicone oil and an organosilicon coupling agent; wherein, the mass ratio of the fly ash to the metakaolin is 3:2; based on the total mass of the fly ash and the metakaolin, the dosages of the liquid sodium silicate, the sodium hydroxide, the chopped carbon fiber, the water, the dimethyl silicone oil and the organic silicon coupling agent are respectively 76.50 percent, 14.00 percent, 0.25 to 2.00 percent, 0.30 to 11.60 percent, 2.00 to 8.00 percent and 1.00 percent of the total mass of the fly ash and the metakaolin.
The preparation method of the fly ash-metakaolin-based conductive geopolymer specifically comprises the following steps:
s1, weighing fly ash, metakaolin and chopped carbon fiber according to the formula content, and putting the fly ash, metakaolin and chopped carbon fiber into a stirring device for uniform stirring;
s2, weighing liquid sodium silicate, sodium hydroxide, dimethyl silicone oil, an organosilicon coupling agent and water according to the formula content, and uniformly mixing to form a transparent alkali-activated agent solution;
s3, slowly adding the alkali-activated agent solution prepared in the step S2 into the stirring device in the step S1, and continuously stirring to form uniform slurry;
s4, injecting the slurry prepared in the step S3 into a mould for molding, curing in an incubator, and demolding, curing and curing to obtain the fly ash-metakaolin-based conductive geopolymer.
Preferably, the mold used in the step S4 has a specification of 3cm×3cm, and the mold is sealed by wrapping with a plastic film.
Preferably, in the step S4, the curing is performed in a constant temperature curing box at 60 ℃ for 48 hours.
Preferably, the curing is performed at normal temperature after the demolding in the step S4.
Therefore, compared with the existing functional building material, the fly ash-metakaolin-based conductive geopolymer and the preparation method thereof have the following advantages:
(1) According to the invention, the industrial solid waste fly ash and metakaolin are mixed according to a certain proportion to be used as a matrix material, so that the curing time is effectively shortened;
(2) The invention prepares the multifunctional geopolymer material with high conductivity, surface hydrophobicity and high strength by adding the chopped carbon fiber and the surface hydrophobicity modifier;
(3) The surface hydrophobic conductive geopolymer prepared by the invention has excellent comprehensive performance, can be used in the fields of heating ground, ground snow melting and ice melting, industrial antistatic, power equipment grounding, photoelectric and hot spot conversion of special buildings and the like, and has wide application prospect.
The technical scheme of the invention is further described in detail through the drawings and the embodiments.
Drawings
FIG. 1 is a schematic illustration of a preparation flow of the present invention;
FIG. 2 is a SEM image of the microstructure of conductive geopolymer samples prepared in examples 1-7 of the present invention;
FIG. 3 is a graph showing the water contact angle of conductive geopolymer samples prepared in examples 1-7 of the present invention.
Detailed Description
The present invention will be described in further detail with reference to the drawings and the embodiments, in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not to be construed as limiting the invention.
A fly ash-metakaolin-based conductive geopolymer, which comprises the following raw materials: fly ash, metakaolin, liquid sodium silicate, sodium hydroxide, chopped carbon fiber, water, dimethyl silicone oil and an organosilicon coupling agent; wherein, the mass ratio of the fly ash to the metakaolin is 3:2; based on the total mass of the fly ash and the metakaolin, the dosages of the liquid sodium silicate, the sodium hydroxide, the chopped carbon fiber, the water, the dimethyl silicone oil and the organic silicon coupling agent are respectively 76.50 percent, 14.00 percent, 0.25 to 2.00 percent, 0.30 to 11.60 percent, 2.00 to 8.00 percent and 1.00 percent of the total mass of the fly ash and the metakaolin.
As shown in fig. 1, the preparation method of the fly ash-metakaolin-based conductive geopolymer specifically comprises the following steps:
s1, weighing fly ash, metakaolin and chopped carbon fiber according to the formula content, and putting the fly ash, metakaolin and chopped carbon fiber into a stirring device for uniform stirring;
s2, weighing liquid sodium silicate, sodium hydroxide, dimethyl silicone oil, an organosilicon coupling agent and water according to the formula content, and uniformly mixing to form a transparent alkali-activated agent solution;
s3, slowly adding the alkali-activated agent solution prepared in the step S2 into the stirring device in the step S1, and continuously stirring to form uniform slurry;
s4, injecting the slurry prepared in the step S3 into a mould for molding, wherein the specification of the mould is 3cm multiplied by 3cm, wrapping and sealing the mould by a plastic film, curing for 48 hours in a constant temperature curing box at 60 ℃, demoulding, and curing at normal temperature until the surface hydrophobic alkali-activated fly ash-metakaolin-based conductive geopolymer is obtained.
Example 1
Weighing 54g of fly ash, 36g of metakaolin and 0.225g of chopped carbon fiber, and adding the fly ash and the chopped carbon fiber into a stirring device for uniform stirring; 68.85g of liquid sodium silicate, 12.6g of sodium hydroxide, 1.8g of simethicone, 0.9g of organic silicon coupling agent and 0.27g of water are weighed and uniformly mixed to prepare an alkali-activated agent solution, and then the alkali-activated agent solution is slowly added into a stirring device to be continuously stirred to form uniform slurry; and (3) injecting the prepared slurry into a mold with the specification of 3cm multiplied by 3cm, wrapping and sealing by a plastic film, molding, curing for 48 hours in a constant temperature box at 60 ℃, removing the film, and curing and solidifying under normal temperature conditions to obtain the fly ash-metakaolin-based conductive geopolymer.
Carrying out resistivity test on the prepared sample by adopting a four-electrode method through a six-digit digital multimeter at normal temperature curing for 1 day, 7 days, 14 days, 28 days and 35 days; compressive strength, microstructure and water contact angle were measured at 28 days of curing, and the results are shown in tables 1 and 2 and fig. 2 and 3.
Example 2
The preparation process steps of this example are the same as those of example 1, except that the mass of the chopped carbon fiber, the dimethyl silicone oil and the water used in this example are respectively 0.45g, 2.7g and 1.962g, and the other raw materials are used in the same amount as that of example 1, so that the corresponding fly ash-metakaolin-based conductive geopolymer is prepared without repeated description.
Carrying out resistivity test on the prepared sample by adopting a four-electrode method through a six-digit digital multimeter at normal temperature curing for 1 day, 7 days, 14 days, 28 days and 35 days; compressive strength, microstructure and water contact angle were measured at 28 days of curing, and the results are shown in tables 1 and 2 and fig. 2 and 3.
Example 3
The preparation process steps of this example are the same as those of example 1, except that the mass of the chopped carbon fiber, the mass of the simethicone and the mass of the water used in this example are respectively 0.675g, 3.6g and 3.654g, and the amounts of other raw materials are the same as those of example 1, so that the corresponding fly ash-metakaolin-based conductive geopolymer is prepared without repeated description.
Carrying out resistivity test on the prepared sample by adopting a four-electrode method through a six-digit digital multimeter at normal temperature curing for 1 day, 7 days, 14 days, 28 days and 35 days; compressive strength, microstructure and water contact angle were measured at 28 days of curing, and the results are shown in tables 1 and 2 and fig. 2 and 3.
Example 4
The preparation process steps of this example are the same as those of example 1, except that the mass of the chopped carbon fiber, the mass of the simethicone and the mass of the water used in this example are respectively 0.90g, 4.5g and 5.346g, and the amounts of other raw materials are the same as those of example 1, so that the corresponding fly ash-metakaolin-based conductive geopolymer is prepared without repeated description.
Carrying out resistivity test on the prepared sample by adopting a four-electrode method through a six-digit digital multimeter at normal temperature curing for 1 day, 7 days, 14 days, 28 days and 35 days; compressive strength, microstructure and water contact angle were measured at 28 days of curing, and the results are shown in tables 1 and 2 and fig. 2 and 3.
Example 5
The preparation process steps of this example are the same as those of example 1, except that the mass of the chopped carbon fiber, the mass of the simethicone and the mass of the water used in this example are 1.125g, 5.4g and 7.038g respectively, and the amounts of other raw materials are the same as those of example 1, so that the corresponding fly ash-metakaolin-based conductive geopolymer is prepared without repeated description.
Carrying out resistivity test on the prepared sample by adopting a four-electrode method through a six-digit digital multimeter at normal temperature curing for 1 day, 7 days, 14 days, 28 days and 35 days; compressive strength, microstructure and water contact angle were measured at 28 days of curing, and the results are shown in tables 1 and 2 and fig. 2 and 3.
Example 6
The preparation process steps of this example are the same as those of example 1, except that the mass of the chopped carbon fiber, the mass of the simethicone and the mass of the water used in this example are 1.35g, 6.3g and 8.73g respectively, and the amounts of other raw materials are the same as those of example 1, so that the corresponding fly ash-metakaolin-based conductive geopolymer is prepared without repeated description.
Carrying out resistivity test on the prepared sample by adopting a four-electrode method through a six-digit digital multimeter at normal temperature curing for 1 day, 7 days, 14 days, 28 days and 35 days; compressive strength, microstructure and water contact angle were measured at 28 days of curing, and the results are shown in tables 1 and 2 and fig. 2 and 3.
Example 7
The preparation process steps of this example are the same as those of example 1, except that the mass of the chopped carbon fiber, the mass of the simethicone and the mass of the water used in this example are 1.80g, 7.2g and 10.44g respectively, and the amounts of other raw materials are the same as those of example 1, so that the corresponding fly ash-metakaolin-based conductive geopolymer is prepared without repeated description.
Carrying out resistivity test on the prepared sample by adopting a four-electrode method through a six-digit digital multimeter at normal temperature curing for 1 day, 7 days, 14 days, 28 days and 35 days; compressive strength, microstructure and water contact angle were measured at 28 days of curing, and the results are shown in tables 1 and 2 and fig. 2 and 3.
TABLE 1
TABLE 2
As can be seen from the data in tables 1 and 2, the lowest resistivity and highest compressive strength of the geopolymer prepared in the different examples can reach 2.58 Ω·m and 49.70MPa, respectively; FIG. 2 shows that in the geopolymer microstructures produced in the various examples, the chopped carbon fibers are more uniformly embedded in the geopolymer matrix and as their content increases, conductive network paths are more easily formed and the resistivity is continuously reduced; in addition, the introduction of the chopped carbon fibers is beneficial to improving the compressive strength of the geopolymer. FIG. 3 shows that the geopolymers prepared in the different examples all have good hydrophobic properties and the maximum water contact angle can reach 120 degrees.
The preparation process is simple, raw materials are low in cost, energy-saving and environment-friendly, the fly ash, the metakaolin and the carbon fiber are uniformly mixed, then the aqueous solution mixed by liquid sodium silicate, sodium hydroxide, dimethyl silicone oil and an organosilicon coupling agent is added, the mixture is stirred into uniform slurry, and the uniform slurry is subjected to injection molding, forming and curing to obtain the conductive geopolymer which has excellent mechanical properties, high hydrophobicity and high conductivity and has excellent comprehensive properties.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention and not for limiting it, and although the present invention has been described in detail with reference to the preferred embodiments, it will be understood by those skilled in the art that: the technical scheme of the invention can be modified or replaced by the same, and the modified technical scheme cannot deviate from the spirit and scope of the technical scheme of the invention.
Claims (5)
1. The fly ash-metakaolin-based conductive geopolymer is characterized in that the raw materials used comprise: fly ash, metakaolin, liquid sodium silicate, sodium hydroxide, chopped carbon fiber, water, dimethyl silicone oil and an organosilicon coupling agent; wherein, the mass ratio of the fly ash to the metakaolin is 3:2; based on the total mass of the fly ash and the metakaolin, the dosages of the liquid sodium silicate, the sodium hydroxide, the chopped carbon fiber, the water, the dimethyl silicone oil and the organic silicon coupling agent are respectively 76.50 percent, 14.00 percent, 0.25 to 2.00 percent, 0.30 to 11.60 percent, 2.00 to 8.00 percent and 1.00 percent of the total mass of the fly ash and the metakaolin.
2. The method for preparing the fly ash-metakaolin-based conductive geopolymer according to claim 1, which is characterized by comprising the following steps:
s1, weighing fly ash, metakaolin and chopped carbon fiber according to the formula content, and putting the fly ash, metakaolin and chopped carbon fiber into a stirring device for uniform stirring;
s2, weighing liquid sodium silicate, sodium hydroxide, dimethyl silicone oil, an organosilicon coupling agent and water according to the formula content, and uniformly mixing to form a transparent alkali-activated agent solution;
s3, slowly adding the alkali-activated agent solution prepared in the step S2 into the stirring device in the step S1, and continuously stirring to form uniform slurry;
s4, injecting the slurry prepared in the step S3 into a mould for molding, curing in an incubator, and demolding, curing and curing to obtain the fly ash-metakaolin-based conductive geopolymer.
3. The method for preparing the fly ash-metakaolin-based conductive geopolymer according to claim 2, which is characterized in that: the mold used in the step S4 has a specification of 3cm×3cm, and the mold is wrapped and sealed with a plastic film.
4. The method for preparing the fly ash-metakaolin-based conductive geopolymer according to claim 2, which is characterized in that: and in the step S4, curing for 48 hours in a constant temperature curing box at 60 ℃.
5. The method for preparing the fly ash-metakaolin-based conductive geopolymer according to claim 2, which is characterized in that: and (3) maintaining at normal temperature after demolding in the step S4.
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CN112079593A (en) * | 2020-07-30 | 2020-12-15 | 浙江大学 | Siloxane modified super-hydrophobic geopolymer anticorrosive material and preparation method thereof |
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- 2023-09-14 CN CN202311185641.4A patent/CN117125911A/en active Pending
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Publication number | Priority date | Publication date | Assignee | Title |
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CN112079585A (en) * | 2020-07-30 | 2020-12-15 | 浙江大学 | Super-hydrophobic geopolymer prepared by microcellular foaming and preparation method thereof |
CN112079593A (en) * | 2020-07-30 | 2020-12-15 | 浙江大学 | Siloxane modified super-hydrophobic geopolymer anticorrosive material and preparation method thereof |
Non-Patent Citations (2)
Title |
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孟宪建: "碳纤维对粉煤灰地聚物复合材料性能的影响", 非金属矿, vol. 41, no. 2, pages 51 - 54 * |
王顺风等: "粉煤灰-偏高岭土基地质聚合物的孔结构及抗压强度", 材料导报, vol. 32, no. 8, pages 2757 - 2762 * |
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